With Solid Polymer Derived From Ethylenic Reactants Only Patents (Class 525/57)
  • Patent number: 7015266
    Abstract: The invention is a polyvinyl alcohol film having an YI value of at most 20, which is formed of a modified polyvinyl alcohol having a degree of polymerization of from 1500 to 5000, an ethylene unit content of from 1 to 4 mol % and a 1,2-glycol bond content of at most 1.4 mol %. The polyvinyl alcohol film gives polarizing films that contain no impurities and have good polarization performance, durability and hue stability.
    Type: Grant
    Filed: March 13, 2003
    Date of Patent: March 21, 2006
    Assignee: Kuraray Co., Ltd.
    Inventors: Takanori Isozaki, Tetsushi Hayashi, Toshio Nakai, Naoki Fujiwara
  • Patent number: 7015267
    Abstract: A method for increasing the crystallization rate of a polyethylene terepthalate (PET) prepared based on terepthalic acid (TPA) and ethylene glycol monomers, by adding into said TPA-based PET an effective amount of a polyethylene terepthalate prepared based on dimethyl terephthalate (DMT), in an amount sufficient for said thermally formable composition to have an increase in crystallization temperature as required for the final end-use application.
    Type: Grant
    Filed: December 17, 2002
    Date of Patent: March 21, 2006
    Assignee: General Electric Company
    Inventors: Herve Cartier, Franciscus Petrus Maria Mercx, Antonius Adrianus Marinus de Vries, Sanjay Mishra, Luc Govaerts
  • Patent number: 7012117
    Abstract: The present invention provides a water-dispersant resin composition for perforating a printed wiring board excellent in preciseness of the processing position and plating throwing power when perforating, a sheet for perforating using the composition, a process for perforating a printed wiring board using the sheet. More specifically, the present invention provides a water-dispersant resin composition for perforating a printed wiring board comprising a water-soluble polymer (A) and a polymer compound (B) containing the compound represented by the following formula (1) as a copolymer component, a sheet for perforating using the composition, and a process for perforating a printed wiring board using the sheet. (wherein, R represents hydrogen or a methyl group, and n represents an integer of 10 to 22).
    Type: Grant
    Filed: July 16, 2002
    Date of Patent: March 14, 2006
    Assignee: The Nippon Synthetic Chemical Industry Co., Ltd.
    Inventors: Tsukasa Izumi, Hiroaki Satoh
  • Patent number: 7012116
    Abstract: This invention relates, in general, to blend compositions of an unmodified poly vinyl alcohol and a thermoplastic elastomer and thermoplastic film and fiber structures comprising these blend compositions. More specifically, this invention relates to substantially water-free films and fibers comprising unmodified polyvinyl alcohol and a thermoplastic elastomer.
    Type: Grant
    Filed: August 1, 2000
    Date of Patent: March 14, 2006
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: David Michael Schertz, James Hongxue Wang, Gregory J. Wideman, William S. Pomplun
  • Patent number: 7005169
    Abstract: Biaxially oriented polyester films which have a polyester-containing base layer (B) which additionally comprises poly(m-xyleneadipamide) and has been provided on at least one side with an overlayer (A) which has been coated with a barrier layer (D), said barrier layer comprising polyvinyl alcohol and a copolymer of maleic acid and acrylic acid, feature improved optical properties such as high gloss and low opacity and very good barrier properties, in particular toward the passage of oxygen, and, as a consequence of their insensitivity toward moisture, are suitable as a packaging material for foods or other consumable items.
    Type: Grant
    Filed: January 20, 2004
    Date of Patent: February 28, 2006
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Oliver Klein, Herbert Peiffer, Gottfried Hilkert
  • Patent number: 6992130
    Abstract: The invention provides a polyvinyl acetal having a degree of acetalization of from 45 to 80 mol %, which is obtained through acetalization of a polyvinyl alcohol that contains from 1 to 15 mol % of ?-olefin units and has a 1,2-glycol bond content of from 1 to 3 mol %, a degree of polymerization of from 100 to 2000 and a degree of hydrolysis of from 80.0 to 99.99 mol %. The polyvinyl acetal has good waterproofness and good compatibility with plasticizer. Having the advantages, it is favorable for interlayer films for laminated glass, binders for ceramic forming, binders for ink or paint, and coating liquids for thermally-developable photographic materials.
    Type: Grant
    Filed: July 17, 2003
    Date of Patent: January 31, 2006
    Assignee: Kuraray Co., Ltd.
    Inventors: Takeshi Kusudou, Yousuke Kumaki, Naoki Fujiwara
  • Patent number: 6991837
    Abstract: Biaxially oriented polyester films which have a polyester-containing base layer (B) which additionally comprises poly(m-xyleneadipamide) and which is coated on at least one side with a barrier layer (D), the barrier layer comprising polyvinyl alcohol and a copolymer of maleic acid and acrylic acid, feature improved optical properties such as high gloss and low opacity, and very good barrier properties, in particular with respect to oxygen passage, and are also suitable as packaging materials for foods or other consumable items as a consequence of their insensitivity toward moisture.
    Type: Grant
    Filed: January 20, 2004
    Date of Patent: January 31, 2006
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Oliver Klein, Herbert Peiffer, Gottfried Hilkert
  • Patent number: 6960376
    Abstract: The oxygen absorptive resin composition of the present invention includes: a thermoplastic resin (a) having carbon-carbon double bonds; a gas barrier resin (b) having an oxygen transmission rate of 500 ml·20 ?m/m2·day·atm or less (20° C. 65% RH); and a transition metal salt (c). This resin composition and molded articles formed using the resin composition effectively absorb and scavenge oxygen when used to package products susceptible to degradation by oxygen, such as foods and drinks.
    Type: Grant
    Filed: February 26, 2003
    Date of Patent: November 1, 2005
    Assignee: Kuraray Co., Ltd.
    Inventors: Shinji Tai, Hiroyuki Shimo, Masakazu Nakaya, Hideo Takamatsu, Mizuho Maeda
  • Patent number: 6949298
    Abstract: A styrene/hydrogenated diene block copolymer characterized in that it has in side chains at least one kind of functional groups selected from the group consisting of a boronic acid group and a boron-containing group capable of converting into a boronic acid group in the presence of water, the content of the functional groups in the copolymer is 100 to 2,000 ?eq/g, and the weight ratio of the styrene units to hydrogenated diene units contained in the copolymer is from 5/95 to 70/30. By thus incorporating a sufficient amount of boron-containing groups, a highly reactive styrene/hydrogenated diene block copolymer is provided.
    Type: Grant
    Filed: January 30, 2002
    Date of Patent: September 27, 2005
    Assignee: Kuraray Co., Ltd.
    Inventors: Kaoru Ikeda, Hiroshi Kawai
  • Patent number: 6906146
    Abstract: Disclosed is a process for esterifying and/or transesterifying a polymer having a polyethylenic backbone and pendant acid and/or ester moieties comprising contacting a melt of the polymer with a transesterifying compound so that the polymer undergoes esterification and/or transesterification but not alcoholysis. The esterified or transesterified polymer also has pendant ester moieties which differ in kind and/or number from the unreacted polymer. In one embodiment, the process also comprises adding an amount of a transition metal salt that is effective to promote oxygen scavenging. Also in a further embodiment, the process comprises irradiating the transesterified polymer with actinic radiation to reduce the induction period before oxygen scavenging commences. Also disclosed are compositions comprising a component which comprises an ethylenic or polyethylenic backbone and a pendant or terminal moiety comprising a benzylic, allylic, or ether-containing radical.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: June 14, 2005
    Assignee: Phillips Petroleum Company
    Inventors: Ta Yen Ching, Kiyoshi Katsumoto
  • Patent number: 6881492
    Abstract: A composition suitable for forming a primer layer on a polymer sheet comprising: a) polyethyleneimine; b) latex; wherein the latex has a Tg lower than 25° C. and c) a hydrophilic colloid material. A method of coating the composition is also disclosed.
    Type: Grant
    Filed: September 27, 2002
    Date of Patent: April 19, 2005
    Assignee: Eastman Kodak Company
    Inventors: Yuanqiao Rao, DeBasis Majumdar, Robert J. Kress, David E. Decker
  • Patent number: 6872774
    Abstract: The present invention is directed to a multi-layer golf ball having a core, an intermediate layer and a cover. The intermediate layer has a non-ionomeric composition that includes an ethylene/acid polymer and a non-ionomeric stiffening polymer. The stiffening polymer provides the non-ionomeric composition with a flexural modulus and a hardness that are greater than those of the ethylene/acid polymer.
    Type: Grant
    Filed: December 16, 2002
    Date of Patent: March 29, 2005
    Assignee: Acushnet Company
    Inventors: Michael J. Sullivan, Michael D. Jordan, Derek A. Ladd
  • Patent number: 6841618
    Abstract: The present invention provides a thermoplastic polymer composition which is obtained through dynamic vulcanization performed by mixing an ethylene-vinyl alcohol copolymer (I), a modified block copolymer (II) which comprises an aromatic vinyl polymer block and a conjugated diene polymer block and which has a functional group consisting of a carboxyl group and/or its derivative, and an amine crosslinking agent (III), wherein the ethylene-vinyl alcohol copolymer (I) has an ethylene content of from 10 to 60 mole % and has a melt flow rate of from 1 to 20 g/10 minutes, and the amount of the functional group consisting of a carboxyl group and/or its derivative which the modified block copolymer (II) has is from 2 to 20 groups per molecule. The thermoplastic polymer composition is excellent in both barrier properties to gases, organic liquids and the like and flexibility.
    Type: Grant
    Filed: February 21, 2003
    Date of Patent: January 11, 2005
    Assignee: Kuraray Co., Ltd.
    Inventor: Haruhisa Masuda
  • Patent number: 6835758
    Abstract: A method for curing an active single phase water compatible actinic radiation curable composition, comprising: irradiating a water compatible non emulsion, non dispersing compound, water, and a maleimide derivative.
    Type: Grant
    Filed: August 27, 2003
    Date of Patent: December 28, 2004
    Assignee: Sun Chemical Corporation
    Inventors: David Anthony Biro, Mikhail Laksin, Yoshinobu Sakurai, Hisatomo Yonehara, Katsuji Takahashi
  • Publication number: 20040254286
    Abstract: Polyester compositions comprising microfibers are disclosed. The compositions are made by contacting microfibers with polymerizable components, such as monomers, suitable for making polyesters, and polymerizing the polymerizable components. The microfibers can be provided in the form of a slurry. The microfibers provide improved properties to the polyesters for use in making molded parts, films and fibers.
    Type: Application
    Filed: March 25, 2004
    Publication date: December 16, 2004
    Inventors: Steven M. Hansen, Richard Allen Hayes, Sam Louis Samuels, Arnold Frances
  • Patent number: 6831142
    Abstract: The invention relates to absorptive, crosslinked polymers which are based on partly neutralized, monoethylenically unsaturated monomers carrying acid groups, and have improved properties, in particular in respect of their capacity for transportation of liquids in the swollen state, and which have been after-crosslinked on their surface at temperatures of at least 150° C. with a combination of polyol as after-crosslinking compound and a cation in the form of an aqueous solution.
    Type: Grant
    Filed: March 4, 2003
    Date of Patent: December 14, 2004
    Assignee: Stockhausen GmbH & Co. KG
    Inventors: Richard Mertens, Harren Jörg
  • Publication number: 20040249065
    Abstract: A method for producing biodegradable plastic from natural materials containing polysaccharides and oligosaccharides by treating the polysaccharide-containing or oligosaccharide-containing materials with a basic aqueous solution, subsequently treating the mixture with a modifying material to create an anionic product, and then contacting the anionic product with proteins to produce the biodegradable plastic material. The process provides relatively inexpensive methods for preparing biodegradable plastics that are useful for manufacturing various articles and also to provide an environmental solution that will reduce the amount of natural wastes that could be practically utilized for the benefit of mankind.
    Type: Application
    Filed: June 9, 2003
    Publication date: December 9, 2004
    Inventors: Christopher H. Schilling, David S. Karpovich, Piotr Tomasik
  • Publication number: 20040210000
    Abstract: A method of improving ink stability. A block co-polymer is added to either an under-/overprinting vehicle or an ink vehicle. The polymer increases chemical interactions between the ink the print media. The under-/overprinting vehicle and the ink vehicle interact through electrostatic interactions while the polymer increases smearfastness by interacting with the print media through non-covalent interactions.
    Type: Application
    Filed: May 7, 2004
    Publication date: October 21, 2004
    Inventor: David M. Schut
  • Patent number: 6806353
    Abstract: A biodegradable plant protein composite is described. The composite includes a plant protein, which is preferably soy protein, and a polylactide. The composite also preferably includes a compatibilizer, a cross-linking agent, and a plasticizer. The composites of this invention offer the advantages of being water resistant and biodegradable.
    Type: Grant
    Filed: October 12, 2001
    Date of Patent: October 19, 2004
    Assignee: Iowa State University Research Foundation, Inc.
    Inventors: Jinwen Zhang, Perminus Mungara, Jay-Lin Jane
  • Patent number: 6790499
    Abstract: A mixture of a polyester, such as poly(ethylene terephthalate) PET, and an additive combination, when extrusion compounded exhibits a lower residual acetaldehyde content than does PET alone when similarly treated. The additive combination comprises compounds selected from at least two groups wherein the groups are (i.) poly(vinyl alcohol) or ethylene/vinyl alcohol copolymer, (ii.) polyhydric alcohols and (iii.) polyacrylamide, polymethacrylamide or copolymer of acrylamide or methacrylamide. The invention pertains to any polyester used in the manufacture of bottles or containers which in turn are used to store consumer materials, especially food, beverages and most especially water.
    Type: Grant
    Filed: December 20, 2001
    Date of Patent: September 14, 2004
    Assignee: Ciba Speicalty Chemicals Corporation
    Inventors: Stephen M Andrews, Paul A. Odorisio, Dirk Simon
  • Publication number: 20040166449
    Abstract: The present invention has an object of the present invention to provide a polyvinyl acetal resin for heat-developable photosensitive materials as well as a heat-developable photosensitive material while solving such problems as coating solution pot life, coloration of heat-developable photosensitive material, fog, poor gradation, insufficient sensitivity and poor undeveloped film storability and making it possible for the materials to acquire good image characteristics.
    Type: Application
    Filed: March 2, 2004
    Publication date: August 26, 2004
    Applicant: SEKISUI CHEMICAL CO., LTD.
    Inventor: Yoshitaka Miyake
  • Patent number: 6777491
    Abstract: A multilayered article and vessel, which are superior in the properties, such as shock resistance, rigidity, an ability to barrier against gasoline and interlayer adhesion, and are permissible of being recycled for reuse, comprising a base layer (A1) comprising a polyetylene resin (a1) having an MFR (ASTM D 1238, 190° C., 2160 g) of 0.001 to 0.5 g/10 min. and a density of 0.945 to 0.980 g/cm3, an adhesive layer (A2) comprising a modified etylene/&agr;-olefin copolymer (a2) which is modified by having grafted thereon an unsaturated carboxylic acid or its derivative and has a density of 0.900 to 0.940 and a barriering layer (B) comprising an ethylene/vinyl alcohol copolymer (b), wherein the Izod impact strength (with notch) (ASTM D 256, −40° C.
    Type: Grant
    Filed: August 11, 2000
    Date of Patent: August 17, 2004
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Hideshi Kawachi, Hiromi Shigemoto, Yuichiro Terashi
  • Patent number: 6759480
    Abstract: The invention relates to thermoplastic compositions comprising: −40 to 97 parts of a thermoplastic polymer (M) forming a matrix, chosen from polyamides, polyamide block copolymers, fluoro polymers, polycarbonate, styrene resins, PMMA, thermoplastic polyurethanes (TPU), copolymers containing polyester blocks and polyether blocks, polycarbonate-polyester alloys, polyketones, PVC and ethylene-vinyl alcohol copolymers (EVOH), −60 to 3 parts of (B) comprising: either an ethylene-alkyl (meth)acrylate copolymer (B1), the alkyl having at least 5 carbon atoms, which copolymer (B1) carries a functional group or a blend of an ethylene-alkyl (meth)acrylate copolymer (B2), the alkyl having at least 5 carbon atoms, which copolymer (B2) does not carry a functional group, and of an impact modifier which carries a functional group.
    Type: Grant
    Filed: September 26, 2000
    Date of Patent: July 6, 2004
    Assignee: Atofina
    Inventors: Alain Bouilloux, Christophe Lacroix, Jean-Marc Le Blevec, Thibaut Montanari
  • Patent number: 6759476
    Abstract: A flexible thermal control composite comprising a natural or synthetic polymer and an endotherm dispersed, distributed and suspended within said natural or synthetic polymer i.e. “P”olymer “C”ontaining an “E”ndothermic “A”gent (PCEA). The PCEA can be formed into thin and thick films. It can be drawn, molded, extruded and spun into fibers or all dimensions. It can be formed and chopped into PCEA mulch. Irrespective its final form, the PCEA can be used in insulating, thermoprotecting, heat absorbing applications on the one hand, and heat maintenance applications of all types on the other.
    Type: Grant
    Filed: July 13, 2000
    Date of Patent: July 6, 2004
    Inventor: Claude Q. C. Hayes
  • Patent number: 6753370
    Abstract: A resin composition comprises a copolymer (A) comprising ethylene as a major component produced with a single-site catalyst, and an ethylene-vinyl alcohol copolymer (B) having an ethylene content of 20-60 mol. % and a degree of hydrolysis of 95% or above, the resin composition satisfying the equation (1): 1/99≦{weight of (A)}/{weight of (B)}≦<99/1  (1) A preferred resin composition comprises a copolymer (A) which has a density of 0.90-0.94 g/cm3 and the resin composition further comprises a carboxylic acid-modified polyolefin (C) and satisfies the equations (2) and (3): 60/40≦{weight of (A)}/{(weight of (B)}≦: 99/1  (2) 0.1/99.9≦X≦: 20/80  (3) wherein X={weight of (C)}/{total weight of (A) and (B)}. Another preferred resin composition comprises a copolymer (A) which has a density of 0.85-0.
    Type: Grant
    Filed: March 7, 2002
    Date of Patent: June 22, 2004
    Assignee: Kuraray Co., Ltd.
    Inventors: Shigeki Nakatsukasa, Hiroyuki Ohgi, Kazuyori Yoshimi
  • Patent number: 6737013
    Abstract: A ceramic-molding binder includes a vinyl alcohol polymer having an ethylene unit content of 2 to 19 mole %, a polymerization degree of 200 to 2,000, a degree of saponification of 80 to 99.99 mole %, and a carboxylic acid and lactone ring content of 0.02 to 0.4 mole %. The use of the ceramic-molding binder provides green moldings with better formability and handling properties during the formation of smaller green moldings of more complex shape, and also provides ceramic products of good quality, higher yields, and fewer ceramic cracks when obtained by sintering such green moldings.
    Type: Grant
    Filed: November 2, 2000
    Date of Patent: May 18, 2004
    Assignee: Kuraray Co., Ltd
    Inventors: Takeshi Kusudou, Toshiyuki Akasawa
  • Patent number: 6730464
    Abstract: The present invention has an object of the present invention to provide a polyvinyl acetal resin for heat-developable photosensitive materials as well as a heat-developable photosensitive material while solving such problems as coating solution pot life, coloration of heat-developable photosensitive material, fog, poor gradation, insufficient sensitivity and poor undeveloped film storability and making it possible for the materials to acquire good image characteristics. The present invention is constituted of a polyvinyl acetal resin for heat-developable photosensitive materials which is a polyvinyl acetal resin synthesized by the acetalization reaction between a polyvinyl alcohol and an aldehyde and which comprises having a degree of polymerization of 200 to 3,000, a residual acetyl group content of 0 to 25 mole percent and a residual hydroxyl group content of 17 to 35 mole percent, as calculated while regarding one acetal group as two acetalized hydroxyl groups, a water content of not more than 2.
    Type: Grant
    Filed: September 17, 2002
    Date of Patent: May 4, 2004
    Assignee: Sekisui Chemical Co., Ltd.
    Inventor: Yoshitaka Miyake
  • Patent number: 6730722
    Abstract: The invention provides cross-linkable polymer powder compositions containing a) at least one water-soluble polyhydroxy compound; b) at least one boric acid complex compound which is of limited solubility in water that is, it has a water solubility of less than 10 g per liter at normal conditions; and optionally c) a water-soluble film-forming polymer consisting of one or more free-radical polymerizable, ethylenically unsaturated monomers. The compositions are useful as a constituent in adhesives, plaster, jointing mortars, paints and binders for coating compositions, textiles, paper and the like.
    Type: Grant
    Filed: February 2, 2001
    Date of Patent: May 4, 2004
    Assignee: Wacker-Chemie GmbH
    Inventors: Herbert Eck, Hans Donislreiter
  • Patent number: 6727002
    Abstract: The present invention relates to a single- or multilayer product containing &agr;-olefin-vinyl alcohol copolymers and at least one &agr;-olefin-vinyl acetate copolymer, wherein the amount of vinyl acetate repeat units present in the &agr;-olefin vinyl acetate copolymer is in the range from 35 to 99.99% by weight, and these repeat units have good flexibility which permits processing films or other thin-walled items which are transparent after stretching or thermoforming, and to a process for producing the same, and to their use as packaging films.
    Type: Grant
    Filed: August 5, 2002
    Date of Patent: April 27, 2004
    Assignee: Bayer Aktiengesellschaft
    Inventors: Martin Hoch, Ulrich Itter, Roland Parg, Claus Wrana, Helmut Schulte, Peter Schwarz, Ralph Ulrich
  • Patent number: 6723778
    Abstract: An aqueous composition that includes (A) a butadiene polymer latex that is prepared by an emulsion polymerization in the presence of a styrene sulfonate stabilizer and (B) a phenolic resin. A preferred aqueous butadiene polymer latex is one that is prepared by emulsion polymerization of at least 60 weight percent dichlorobutadiene monomer (based on the amount of total monomers used to form the butadiene polymer), in the presence of a styrene sulfonate stabilizer.
    Type: Grant
    Filed: March 20, 2002
    Date of Patent: April 20, 2004
    Assignee: Lord Corporation
    Inventors: Helmut W. Kucera, Thomas Rizzo
  • Patent number: 6713119
    Abstract: A coating for a prosthesis, for example a stent, and a composition for forming the coating is disclosed. The coating can serve as a primer, allowing substances, such as polymers, to be effectively secured by the prosthesis. Alternatively, the coating can serve as a reservoir, allowing for the local and sustained release of a therapeutic substance to biological tissues. The composition can be formed from an ethylene vinyl alcohol copolymer and a dimethylsulfoxide solvent, with or without a therapeutic substance. Alternatively, the composition can be formed from an ethylene vinyl alcohol copolymer, a dimethylsulfoxide solvent, and a wetting fluid, with or without a therapeutic substance. The composition is applied to a surface of the prosthesis and essentially all of the dimethylsulfoxide solvent or dimethylsulfoxide solvent/wetting fluid is removed or allowed to evaporate to form the coating.
    Type: Grant
    Filed: December 23, 1999
    Date of Patent: March 30, 2004
    Assignee: Advanced Cardiovascular Systems, Inc.
    Inventors: Syed F. A. Hossainy, Deborra Sanders-Millare, Judy A. Guruwaiya, Daniel A. Castro, Sameer Harish, Steven Z. Wu
  • Publication number: 20040058178
    Abstract: Herein is disclosed a modified ethylene vinyl alcohol polymer (EVOH) comprising an oxygen scavenging functional group.
    Type: Application
    Filed: June 19, 2003
    Publication date: March 25, 2004
    Applicant: Chevron Phillips Chemical Company LP.
    Inventors: Hu Yang, Ta Yen Ching, Gangfeng Cai
  • Patent number: 6709735
    Abstract: A film with excellent oxygen barrier properties is disclosed. A barrier coating used thereon is also disclosed, including polyvinyl alcohol and a copolymer of maleic acid and acrylic acid, and wherein the copolymer of maleic acid and acrylic acid has a weight average molecular weight of about 3500 to about 5000. The barrier coating is typically less than about 1 micrometer in thickness and provides an oxygen barrier of less than about 0.3 cc.mil/100 in2/day/atm when tested at 23 degrees Celsius and 0 percent relative humidity according to ASTM D3985. A method of stripping low molecular eight fractions from the copolymer is also disclosed. Metallized coated film according to the present invention shows surprising barrier properties.
    Type: Grant
    Filed: November 12, 2002
    Date of Patent: March 23, 2004
    Assignee: Mitsubishi Polyester Film, LLC
    Inventors: Robert Posey, Edwin C. Culbertson
  • Patent number: 6683120
    Abstract: A bioadhesive composition for use as a skin adhesive, the composition formed by polymerizing with cross-linking and/or entanglement an aqueous reaction mixture comprising effective amounts of at least one monomer dissolved or suspended therein and capable of forming a hydrogel on polymerization, optionally at least one cross-linking agent for the monomer, and water, said composition having an elastic modulus (G′) and a viscous modulus (G″), wherein the degree of polymerization and/or the degree of cross-linking and/or entanglement are selected to control the skin adhesion properties of the bioadhesive composition having regard to the rate of change of tan delta (G″÷G″) against frequency in a diagnostic portion of the frequency range 0.01 to 300 rad/s, typically the lower end of the said frequency range below about 100 rad/s.
    Type: Grant
    Filed: July 27, 2001
    Date of Patent: January 27, 2004
    Assignee: First Water Limited
    Inventor: Hugh Semple Munro
  • Patent number: 6664332
    Abstract: A resin composition suitable for forming ink receptive layer of recording sheets and having excellent ink receptivity, feathering prevention, gloss and weatherability, which comprises (A) an oxyalkylene group-containing polyvinyl alcohol resin and (B) a cationic group-containing polyvinyl alcohol resin, wherein a 15% by weight aqueous solution of the resin composition has a transparency according to JIS K 6726 of at least 50%.
    Type: Grant
    Filed: July 17, 2002
    Date of Patent: December 16, 2003
    Assignee: The Nippon Synthetic Chemical Industry Co., Ltd.
    Inventor: Masaru Saeki
  • Patent number: 6657004
    Abstract: The present invention provides a film for packaging chemical agents, which contains an oxyalkylene unit-containing polyvinyl alcohol resin (A) and a carboxyl-containing polyvinyl alcohol resin (B), and preferably further containing a sulfo-containing polyvinyl alcohol resin (C). This film shows fine solubility in water even after a long-term packaging of an acidic chemical agent or alkaline chemical agent, and is superior in mechanical strength. Thus, the film for packaging chemical agents of the present invention is suitably used for packaging a chemical agent, such as powdered soap, synthetic detergent, agricultural chemical, antibacterial, deodorant, insecticide and the like, which is cast into water when in use.
    Type: Grant
    Filed: May 15, 2001
    Date of Patent: December 2, 2003
    Assignee: The Nippon Synthetic Chemical Industry Co., Ltd.
    Inventor: Tomoyoshi Mizutani
  • Patent number: 6653372
    Abstract: A process for preparing an addition-polymer powder suitable for modifying a binding mineral building material by drying an aqueous addition-polymer dispersion whose film has a glass transition temperature Tg≦30° C. and to which a drying assistant has been added comprises adding to the aqueous addition-polymer dispersion before drying only a drying assistant which will have a plasticizing or deplasticizing effect in the ready-to-use mix of the binding mineral building material with water and admixing the resulting dry addition-polymer powder with at least one assistant in the form of a finely divided solid which will have an opposite effect to the drying assistant added before drying.
    Type: Grant
    Filed: June 4, 1997
    Date of Patent: November 25, 2003
    Assignee: BASF Aktiengesellschaft
    Inventors: Joachim Pakusch, Joachim Roser, Maximilian Angel, Andree Dragon
  • Patent number: 6653393
    Abstract: To provide a paintwork coating composition that is harmless to the environments and humans and enables a paintwork to be fully coated by the application of only a small quantity of coating composition and also provide a coating cloth that provides a smooth rubbing work in the coating process and can develop a good water-repellent property and a good antifouling property, water dispersion comprising polytetrafluoroethylene and perfluoropolyether is prepared as the coating composition, and also the coating composition is impregnated in a cloth having a basis weight of (unit representing mass per unit area of fabric, a gram number per square meter) 30-300 g/m2 and a density of 0.02-0.3 g/cm3 under load condition of 1.961 KPa.
    Type: Grant
    Filed: April 19, 2001
    Date of Patent: November 25, 2003
    Assignee: Soft99 Corporation
    Inventors: Makoto Ishii, Junichi Nonaka, Ryutaro Hidaka
  • Patent number: 6653400
    Abstract: This invention provides a method for producing a saponified ethylene-vinyl acetate copolymer in which visible imperfections (particularly fish eyes) of the saponified copolymer is inhibited. In this invention, a mixture solution is prepared by adding water to a methanol solution after saponifying an ethylene-vinyl acetate copolymer, and insoluble materials are removed from this mixture solution. Various types of filter or centrifugal separator are used to remove insoluble materials. It is preferable that the weight ratio of methanol to water is from 5:5 to 9:1, the concentration of the saponified copolymer is from 30 to 60 wt %, and the temperature is from 55 to 80° C. This method is particularly suitable for producing a saponified ethylene-vinyl acetate copolymer having an ethylene content of 20 to 70 mol % and a saponification degree of at least 95 mol %.
    Type: Grant
    Filed: June 28, 2001
    Date of Patent: November 25, 2003
    Assignee: Kuraray Co., Ltd.
    Inventors: Takaharu Kawahara, Toshio Tuboi
  • Publication number: 20030215624
    Abstract: Electrospinning of EVOH copolymer fiber is accomplished by dissolving the copolymers in a 2-propanol/water solution. The mixture is heated until the EVOH copolymers are fully dissolved in the solution. The copolymers fibers are then electrospun after the mixture is allowed to cool. Additionally, fully hydrolyzed PVA was able to be electrospun through use of a non-ionic surfactant. This electrospun matrix can be stabilized against disintegration and water by soaking of the matrix in methanol.
    Type: Application
    Filed: April 4, 2003
    Publication date: November 20, 2003
    Inventors: John M. Layman, Gary Wnek, El-Refaie Kenawy
  • Patent number: 6649323
    Abstract: A lithographic printing plate precursor comprises a substrate, a free radical polymerizable photosensitive layer comprising a light-sensitive composition on the substrate, and a water-soluble overcoat layer on the photosensitive layer, wherein the overcoat layer comprises polyvinyl alcohol, and a further component that is not amphoteric and is poly(1-vinylimidazole) or a copolymer of 1-vinylimidazole and at least one further monomer. The photosensitive layer comprises a free radical polymerizable component and a photoinitiator.
    Type: Grant
    Filed: January 21, 2000
    Date of Patent: November 18, 2003
    Assignee: Kodak Polychrome Graphics LLC
    Inventors: Socrates Peter Pappas, Harald Baumann, Udo Dwars, Celin M. Savariar-Hauck, Hans-Joachim Timpe
  • Patent number: 6649700
    Abstract: A thermosetting powder coating composition prepared by a wet process, which contains a mixture comprising (a) an epoxy-containing acrylic resin, (b) a polycarboxylic acid compound curing agent, (c) fine crosslinked resin particles and, optionally, (d) a resin that exists in the liquid form at room temperature.
    Type: Grant
    Filed: September 21, 2001
    Date of Patent: November 18, 2003
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Masami Yabuta, Yutaka Harada, Atsushi Yamada, Yasuhiko Nakae, Kazuhiko Nishimura, Haruhiko Sato
  • Patent number: 6639049
    Abstract: The invention relates to a process for the preparation of polymers stabilized with protective colloids in the form of water-redispersible powders or aqueous dispersions thereof having a reduced content of volatile components, by a) polymerizing by emulsion or suspension polymerization, one or more monomers from the group consisting of vinyl esters, (meth)acrylates, vinyl aromatics, olefins, 1,3-dienes and vinyl halides and optionally further monomers copolymerizable therewith, b) aftertreating the polymer dispersion thus obtained by means of postpolymerization, distillation, and/or introduction of steam or inert gas to obtain a residual content of volatile, nonaqueous components of <2000 ppm, and c) spray drying of aftertreated polymer dispersion to a residual content of volatile, nonaqueous components of <400 ppm, the dispersion being adjusted prior to spray drying to a solids content of <45% by weight before spraying, the spray drying performed with gas at an inlet temperature of >120° C.
    Type: Grant
    Filed: November 9, 2001
    Date of Patent: October 28, 2003
    Assignee: Wacker Polymer Systems & Co. KG
    Inventor: Hans-Peter Weitzel
  • Patent number: 6635709
    Abstract: A dispersion stabilizer for suspension polymerization of a vinyl compound containing a vinyl alcohol polymer (A) having a content of an ethylene unit of 0.5 to 10 mol %, a degree of saponification of 60 mol % or more and a degree of polymerization of 600 or more and a vinyl alcohol polymer (B) selected from the group consisting of a vinyl alcohol polymer (B1) having a content of an ethylene unit of 0.5 to 10 mol %, a degree of saponification of 20 to 80 mol % and a degree of polymerization of 100 to 600, a vinyl alcohol polymer (B2) having a degree of saponification of 20 to 60 mol % and a degree of polymerization of 100 to 600 and a vinyl alcohol polymer (B3) having a content of an ethylene unit of 0.5 to 10 mol %, a degree of saponification of 90 mol % or more and a degree of polymerization of 1,000 or more.
    Type: Grant
    Filed: July 19, 2001
    Date of Patent: October 21, 2003
    Assignee: Kuraray Co., Ltd.
    Inventors: Masaki Kato, Naokiyo Inomata, Seiji Tanimoto
  • Patent number: 6632869
    Abstract: A process for preparing copolymers based on vinyl esters and ethylene and, if desired, further comonomers in the form of their aqueous dispersions, having a solids content of greater than 65% and a Brookfield viscosity (20 s−1) of less than 10,000 mPa·s, by means of free-radically initiated polymerization of one or more monomers selected from vinyl esters and ethylene and, if desired, further monomers copolymerizable therewith, in the presence of one or more protective colloids, polymerization being conducted in the presence of from 2 to 15% by weight of seed latex, based on the amount of vinyl ester, said process comprising a) polymerizing without adding emulsifier, and in the presence of one or more polyvinyl alcohols protective colloids having a degree of hydrolysis of from 80 to 95 mol % and a Höppler viscosity in 4% strength aqueous solution of from 3 to 30 mPa·s, and b) introducing the seed latex in a fraction of from 30 to 75% by weight before beginning the polymerization and
    Type: Grant
    Filed: July 16, 2001
    Date of Patent: October 14, 2003
    Assignee: Wacker Polymer Systems GmbH & Co. KG
    Inventor: Hans-Peter Weitzel
  • Patent number: 6617397
    Abstract: The surface energy of polymeric substrates is increased by the application or incorporation of novel amphiphilic block copolymers. The block copolymer additives comprise a linear hydrophilic polymer or oligomer and a random hyperbranched polymer or oligomer and is completely or partially terminated with lipophilic end groups. The polymeric articles or constructions which benefit from the application or incorporation of the amphiphilic block copolymers in the areas of anti-fog, dissipation of static electricity, paintability, dyeability, printability, wicking of moisture, adhesion and polymer compatibility include carpet fibers, composite fibers, agricultural films, nonwoven coverstock, exterior automotive bumper fascia, packaging, hygienic products, incompatible polymer blends, laminated articles and eyewear.
    Type: Grant
    Filed: March 4, 2002
    Date of Patent: September 9, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: John James McNamara, Anunay Gupta, David Devore
  • Patent number: 6602937
    Abstract: A redispersible synthetic resin powder comprising particles of a polymer made from at least one monomer selected from the group consisting of ethylenically unsaturated monomers and diene monomers, and a polyvinyl alcohol resin having at least one functional group selected from the group consisting of acetoacetoxy group and mercapto group and having a block character [&eegr;] of 0.3 to 0.6, wherein said polyvinyl alcohol resin is adsorbed onto the surface of said particles. The powder has excellent redispersibility, blocking resistance, film forming property and water resistance, can be easily dispersed into water to form emulsions and is also useful as an admixture for cement and mortar.
    Type: Grant
    Filed: May 23, 2001
    Date of Patent: August 5, 2003
    Assignee: Nippon Synthetic Industry Co., Ltd.
    Inventors: Kouji Hara, Mitsuo Shibutani, Kiyoharu Kitamura
  • Patent number: 6599598
    Abstract: The oxygen resin composition of the present invention includes: a thermoplastic resin (a) having carbon-carbon double bonds; a gas barrier resin (b) having an oxygen transmission rate of 500 ml·20 &mgr;m/m2·day·atm or less (20° C. 65% RH); and a transmission matel salt (c). This resin composition and molded articles formed using the resin composition effectively absorb and scavenge oxygen when used to package products susceptible to degradation by oxygen, such as foods and drinks.
    Type: Grant
    Filed: March 3, 2000
    Date of Patent: July 29, 2003
    Assignee: Kuraray Co., Ltd.
    Inventors: Shinji Tai, Hiroyuki Shimo, Masakazu Nakaya, Hideo Takamatsu, Mizuho Maeda
  • Publication number: 20030125451
    Abstract: A process for preparing aqueous dispersions or water-redispersible polymer powders of polyvinyl-alcohol-stabilized polymers based on vinyl ester(s), and ethylene, by continuous emulsion polymerization with no seed latex, and optionally drying the dispersion, by
    Type: Application
    Filed: October 31, 2002
    Publication date: July 3, 2003
    Applicant: Wacker Polymer Systems GmbH & Co. KG
    Inventors: Hans-Peter Weitzel, Robert Braunsperger
  • Patent number: 6576704
    Abstract: The method of treating a saponified ethylene vinyl acetate copolymer (A) with an acid (B) and/or its salt (C) which comprises feeding a saponified ethylene-vinyl acetate copolymer (A′) in which the acid (B) and/or salt (C) has been incorporated in advance to a column reactor from its top, simultaneously feeding an aqueous solution of the acid (B) and/or salt (C) from the bottom of the reactor to thereby effect a countercurrent contact of (A′) with the aqueous solution of (B) and/or (C), withdrawing the excess of the aqueous solution of acid (B) and/or salt (C) from the reactor top, and continuously withdrawing the treated saponified ethylene-vinyl acetate copolymer from the reactor bottom.
    Type: Grant
    Filed: December 12, 2000
    Date of Patent: June 10, 2003
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yoshiharu Nagao, Youichi Neki, Masahiko Taniguchi, Kenji Ninomiya