With Ethylenic Reactant Patents (Class 525/59)
  • Patent number: 10327965
    Abstract: In an absorbent article a three-dimensional opening hole mesh sheet, having a face which faces skin of a wearer of the absorbent article and a reverse or opposite side face within the absorbent article, is combined with an absorber which includes an air-laid pulp non-woven fabric. The mesh sheet has an array of mechanically embossed concave portions forming protrusions on the skin-facing face of the mesh sheet and recesses on the reverse or opposite face, i.e., the unexposed face inside the absorbent article.
    Type: Grant
    Filed: July 25, 2014
    Date of Patent: June 25, 2019
    Assignee: Daio Paper Corporation
    Inventor: Yoshimi Norimoto
  • Patent number: 9941518
    Abstract: Cathode binder composition having excellent binding properties and oxidation resistance. Also, cathode slurry, cathode, and lithium ion secondary battery produced using the cathode binder composition. The cathode binder composition contains a graft copolymer in which a monomer containing acrylonitrile as the main component is grafted onto polyvinyl alcohol having an average degree of polymerization of 300 to 3000 and a degree of saponification of 70 to 100% by mol. The cathode slurry contains the cathode binder composition, a cathode active material, and a conductive auxiliary. The cathode is produced using the cathode slurry. The lithium ion secondary battery contains a cathode prepared in this manner.
    Type: Grant
    Filed: October 6, 2014
    Date of Patent: April 10, 2018
    Assignee: DENKA COMPANY LIMITED
    Inventors: Yasuaki Sakurai, Jun Yoshida, Jun Watanabe
  • Patent number: 9902795
    Abstract: A process for the preparation of a completely biocompatible and reabsorbable hydrogel, through the use of alkoxides of polymers and/or resins containing hydroxyl functions. The invention also relates to the hydrogel obtainable with the method and uses thereof. In particular, the invention relates to the use of the hydrogel for the preparation of an injectable filler for correcting and/or treating different types of tissue deficits.
    Type: Grant
    Filed: September 17, 2007
    Date of Patent: February 27, 2018
    Assignee: PHARMAFILL SRL
    Inventor: Gerardo Balestrieri
  • Patent number: 9893359
    Abstract: Cathode binder composition having excellent binding properties and oxidation resistance. Also, cathode slurry, cathode, and lithium ion secondary battery produced using the cathode binder composition. The cathode binder composition contains a graft copolymer in which a monomer containing acrylonitrile as the main component is grafted onto polyvinyl alcohol having an average degree of polymerization of 300 to 3000 and a degree of saponification of 70 to 100% by mol. The cathode slurry contains the cathode binder composition, a cathode active material, and a conductive auxiliary. The cathode is produced using the cathode slurry. The lithium ion secondary battery contains a cathode prepared in this manner.
    Type: Grant
    Filed: October 6, 2014
    Date of Patent: February 13, 2018
    Assignee: DENKA COMPANY LIMITED
    Inventors: Yasuaki Sakurai, Jun Yoshida, Jun Watanabe
  • Patent number: 9593174
    Abstract: Acetoacetyl group-containing polyvinyl alcohol resin powder composition containing a C1 to C3 alcohol in an amount of 0.5 to 4 wt % is produced by allowing a powdery polyvinyl alcohol resin to react with diketene, washing the resulting acetoacetyl group-containing polyvinyl alcohol resin particles with the C1 to C3 alcohol to remove an unreacted portion of the diketene, and drying the intermediate acetoacetyl group-containing polyvinyl alcohol resin particles composition at a temperature of 40° C. to 120° C. at a pressure of not higher than 20 kPa after the washing. The acetoacetyl group-containing polyvinyl alcohol resin powder composition thus produced is highly soluble in water.
    Type: Grant
    Filed: October 10, 2014
    Date of Patent: March 14, 2017
    Assignee: THE NIPPON SYNTHETIC CHEMICAL INDUSTRY CO., LTD.
    Inventor: Yoshihito Yamauchi
  • Patent number: 9574146
    Abstract: Polymeric compositions obtainable by free-radical polymerization of at least two different alkyl (meth)acrylates in the presence of at least one ethylene-vinyl ester copolymer, the alkyl (meth)acrylates used being a mixture comprising alkyl (meth)acrylates having linear C12- to C60-alkyl radicals and different alkyl (meth)acrylates having linear C1- to C11-alkyl radicals and/or branched C4- to C60-alkyl radicals and/or cyclic C5- to C20-alkyl radicals. The use of such polymeric compositions as pour point depressants for crude oils, mineral oils or mineral oil products.
    Type: Grant
    Filed: December 17, 2013
    Date of Patent: February 21, 2017
    Assignee: BASF SE
    Inventors: Ivette Garcia Castro, Kai Gumlich, Stefan Frenzel, Maria Heuken, Rouven Konrad, Karin Neubecker
  • Patent number: 9574022
    Abstract: The present invention relates to a method for preparing a polymer based on N-vinyl lactam monomer units, which comprises a step (E) for controlled radical polymerization of a composition comprising: monomers containing (and most often consisting of) N-vinyl lactam monomers, either identical or different (and generally identical); an agent for controlling the radical polymerization, for example comprising a thiocarbonylthio group —S(C?S)—; and a radical polymerization initiator which is a redox system comprising a reducing agent (Red) and an oxidizing agent (Ox).
    Type: Grant
    Filed: September 22, 2011
    Date of Patent: February 21, 2017
    Assignees: RHODIA OPERATIONS, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (C.N.R.S.)
    Inventors: Mathias Destarac, Aymeric Guinaudeau, Stéphane Mazieres, James Wilson
  • Patent number: 9267167
    Abstract: A method includes providing a container, introducing a substance into the container, and introducing a readily dissolvable film into the container such that the dissolvable film overlies the substance within the container. An alternative method includes providing a container, providing a readily dissolvable film, the film comprising a substance carried by the film, and introducing the film into the container.
    Type: Grant
    Filed: June 24, 2005
    Date of Patent: February 23, 2016
    Assignee: Becton, Dickinson and Company
    Inventors: Michael Justin Lizzi, Donald Copertino
  • Patent number: 9056316
    Abstract: Semi-interpenetrating polymeric networks are described. More specifically, the semi-interpenetrating polymeric networks include at least two polymers that are closely associated. The first polymer is an ionic polymer that is not crosslinked. The second polymer is a cross-linked polymer that can be either another ionic polymer or a non-ionic polymer. Methods of making the semi-interpenetrating polymeric networks, articles containing the semi-interpenetrating polymeric networks, and methods of using the semi-interpenetrating polymeric networks are also described. The semi-interpenetrating polymeric networks can function as ion exchange resins.
    Type: Grant
    Filed: June 17, 2011
    Date of Patent: June 16, 2015
    Assignee: 3M INNOVATIVE PROPERTIES COMPANY
    Inventors: Del R. Lawson, James I. Hembre, Jerald K. Rasmussen, Catherine A. Bothof, Kannan Seshadri, Robert T. Fitzsimons, Jr., Andrew W. Rabins, Taib K. Ansera
  • Publication number: 20150079519
    Abstract: A photosensitive compound represented by formula (1) or formula (2). (Chemical formula 1) (In formula (1) and formula (2), n is an integer of 1-3; R1 is a linear or branched alkyl group having 1-6 carbon atoms or an alkylene group having 2-6 carbon atoms formed from two R1 together; R2 is —NR3R4; R3 and R4 are each independently a linear or branched alkyl group or alkenyl group having 1-6 carbon atoms, a linear or branched alkylene group having 2-6 carbon atoms formed by R3 and R4 together, or a linear or branched alkylene group or alkenylene group having 3-8 carbon atoms optionally containing an oxygen atom or nitrogen atom.
    Type: Application
    Filed: February 28, 2013
    Publication date: March 19, 2015
    Inventor: Toru Shibuya
  • Patent number: 8809490
    Abstract: A method for producing a solution containing at least an unsaturated carboxylic acid-modified vinyl alcohol polymer is characterized by reacting a vinyl alcohol polymer and an unsaturated carboxylic acid compound in the presence of an acid catalyst soluble in the reaction system or a solid acid catalyst, and a gas barrier film is obtained by using the same. An example thereof is a method for producing a solution (A) containing an unsaturated carboxylic acid-modified vinyl alcohol polymer (b), the method comprising following two steps of: (1) a reaction step in which the unsaturated carboxylic acid-modified vinyl alcohol polymer (b) is formed by reacting a vinyl alcohol polymer and an unsaturated carboxylic acid compound (a) in the presence of an acid catalyst soluble in the reaction system; and (2) an ion exchange step in which at least the acid catalyst of acidic compounds is removed by an anion exchange resin.
    Type: Grant
    Filed: May 31, 2007
    Date of Patent: August 19, 2014
    Assignee: Tohcello Co., Ltd.
    Inventors: Kou Tsurugi, Yoshihisa Inoue, Isao Hara, Hiroyoshi Watanabe, Tomoyoshi Hakamata, Akira Nomoto, Osamu Nakamura
  • Patent number: 8729185
    Abstract: Provided is a method for producing a 2-cyanoethyl group-containing organic compound having a high ratio of replacement by cyanoethyl groups and a high dielectric constant. More specifically, provided is a method for producing a 2-cyanoethyl group-containing organic compound comprising a step of reacting acrylonitrile with a hydroxyl group-containing organic compound in the presence of a quaternary ammonium salt as a catalyst through a Michael addition.
    Type: Grant
    Filed: March 27, 2012
    Date of Patent: May 20, 2014
    Assignees: Shin-Etsu Chemical Co., Ltd., Matsugaki Chemical Industries Co., Ltd.
    Inventors: Ikuo Fukui, Kazuhisa Hayakawa, Soji Tanioka, Masahiro Ohgata, Masaaki Kajitani
  • Patent number: 8664333
    Abstract: An object of the present invention is to provide a new acetoacetic ester group-containing polyvinyl alcohol-based resin that contains less amount of water-insoluble matter and is excellent in transparency and viscosity stability when converted into an aqueous solution, and that realizes excellent water resistance by combined use of a crosslinking agent. The invention provides an acetoacetic ester group-containing polyvinyl alcohol-based resin containing a structural unit represented by the general formula (1): wherein at least one of R1 and R2 represents an acetoacetyl group, R3, R4, R5, R6, R7 and R8 each independently represents an arbitrary substituent, and X represents a single bond or an arbitrary bonding chain.
    Type: Grant
    Filed: August 18, 2006
    Date of Patent: March 4, 2014
    Assignee: The Nippon Synthetic Chemical Industry Co., Ltd.
    Inventors: Mitsuo Shibutani, Masahiro Saito
  • Publication number: 20140051798
    Abstract: The present invention provides a durable, external surfactant free, cationic, water based jet ink polymer which when formulated into an ink jet ink results in a printing that has an excellent adhesion to metal or plastic substrates. Such a jet ink polymer is suitable performance replacement of solvent soluble polymers currently in commercial use. The hybridized copolymer comprises a hydrophobic functional polymeric backbone comprised of a polysiloxane polymer, a polyolefin polymer, or a functional polyvinyl polymer. The hybridized copolymer also comprises a plurality of copolymeric side chains attached to the backbone, comprising a polymerizable amine-containing unsaturated monomer, and a polymerizable unsaturated monomer. The use of the inks of the present invention enhances performance criteria such as print-head open time, ink stability, and resistance to typical water based cleaners.
    Type: Application
    Filed: August 15, 2012
    Publication date: February 20, 2014
    Applicant: PENN COLOR, INC.
    Inventors: Michael D. SPIEGEL, Charles B. RYBNY
  • Publication number: 20140048746
    Abstract: The present disclosure relates to a polyvinyl copolymer in which one or more side-chain sulfonic acids are attached on the hydroxy group of polyvinyl alcohol or a polyvinyl phenol and a preparation method thereof, a dopant including the same, a conductive polymer composite including the dopant with a conductive polymer and a preparation method thereof, wherein the electrical conductivity, dispersibility, solubility, heat-resistance and environment-resistance of the conductive polymer composite can be enhanced by using the dopant including the copolymer.
    Type: Application
    Filed: October 25, 2013
    Publication date: February 20, 2014
    Applicant: Ajou University Industry-Academic Cooperation Foundation
    Inventors: Suck Hyun Lee, O Pil Kwon, Tae Ja Kim
  • Publication number: 20140038048
    Abstract: In one aspect, a binder for an electrode of a lithium rechargeable battery, which increases adhesion between the electrode and an active material by saving characteristics of two monomers by grafting an acryl group to a vinyl alcohol group, and an electrode for a rechargeable battery comprising the same are provided. The electrode can improve charge and discharge cycle life characteristics of the rechargeable battery.
    Type: Application
    Filed: March 13, 2013
    Publication date: February 6, 2014
    Applicant: SAMSUNG SDI CO., LTD.
    Inventors: Byungjoo Chung, Namseon Kim, Kwangshik Choi, Yangsoo Kim
  • Publication number: 20140038049
    Abstract: In one aspect, a binder for an electrode of a lithium rechargeable battery, which increases adhesion between the electrode and an active material by saving characteristics of two monomers by grafting an acryl group to a vinyl alcohol group, and an electrode for a rechargeable battery comprising the same are provided. The electrode can improve charge and discharge cycle life characteristics of the rechargeable battery.
    Type: Application
    Filed: July 31, 2013
    Publication date: February 6, 2014
    Applicant: Samsung SDI Co., Ltd.
    Inventors: Byungjoo CHUNG, Namseon KIM, Kwangshik CHOI, Yangsoo KIM
  • Patent number: 8617678
    Abstract: Providing a crosslinkable composition and a crosslinking agent is objected to, which are capable forming a crosslinked product that is superior in retort resistance, with suppressed bleeding out from the crosslinked product, and that has favorable interlayer adhesiveness when formed into a multilayered structure crosslinked product. The present invention provides a crosslinkable composition containing (A) a polymer having an SP value of no less than 9.5 (cal/cm3)1/2 and no greater than 16.5 (cal/cm3)1/2, and (B) a crosslinking agent having one or more polar groups that include an oxygen atom and a nitrogen atom not constituting an aromatic ring, and two or more polymerizable groups. The difference between the SP value of the polymer (A) and the SP value of the crosslinking agent (B) is preferably no greater than 2 (cal/cm3)1/2, and more preferably no greater than 1 (cal/cm3)1/2. A decomposition temperature of the crosslinking agent (B) is preferably no less than 240° C.
    Type: Grant
    Filed: March 10, 2011
    Date of Patent: December 31, 2013
    Assignee: Kuraray Co., Ltd.
    Inventors: Kaoru Ikeda, Kazuhiro Kurosaki
  • Publication number: 20130302268
    Abstract: A composition for treating or preventing inflammatory-related conditions includes as an active principle a carrier which exhibits a plurality of a scavenger structure capable of mitigating the activity of a mediator of inflammatory-related conditions. The scavenger structure includes a nucleophilic centre complying with the formula X1(—R?—)(—R?)mHnwhere: a) X1 is a single-bonded heteroatom selected amongst N, O and S and exhibits a free electron pair; b) m is 0 or 1 and n is 1 or 2; c) —R?— is a bivalent organic group providing attachment to the carrier via one of its free valences and to X1 at the other free valence; and d) R?— is a monovalent organic group attached to the X1 via its free valence. A method for treating or preventing inflammatory-related conditions in an individual suffering from such conditions includes: providing the composition; and contacting the mediator within or separate from the individual.
    Type: Application
    Filed: January 25, 2012
    Publication date: November 14, 2013
    Applicant: IPR-Systems Sweden AB, C/O Tim Bowden
    Inventors: Tim Bowden, Kristoffer Bergman, Thomas Strand, Lennart Soderberg
  • Publication number: 20130289135
    Abstract: The present invention relates to compositions comprising a polymeric substrate comprising at least one volume excluding polymer. In one embodiment, the present invention provides polymeric articles that are capable of acting as osmotic drivers. The articles are capable of maintaining a desired water balance by moving water in or out of a substrate to maintain cation concentration equilibrium between the substrate and its environment.
    Type: Application
    Filed: June 27, 2013
    Publication date: October 31, 2013
    Inventors: Brian J. Tighe, Muriel Nasso, Beverley Benning, Frank F. Molock, JR.
  • Patent number: 8552102
    Abstract: The present invention relates to a novel resin composition useful as a coating agent or a binder for medicines, drugs for animals, agricultural chemicals, fertilizers, foods or the like, which contains a polyvinyl alcohol copolymer as a main component. More particularly, the present invention relates to a resin composition, characterized in that the composition is obtained by copolymerizing a polyvinyl alcohol having an average polymerization degree of 1300 or less, and at least one polymerizable vinyl monomer in a weight ratio of 6:4 to 9:1.
    Type: Grant
    Filed: August 31, 2012
    Date of Patent: October 8, 2013
    Assignees: Shionogi & Co., Ltd., Nisshin Kasei Co., Ltd., Daido Chemical Corporation
    Inventors: Makoto Noami, Toshiro Fujii, Yoshihiro Furuya, Noboru Hoshi, Toshio Shimamoto, Shunji Uramatsu
  • Publication number: 20130209817
    Abstract: An object of the invention is to provide a novel alkyl-modified PVA capable of exerting superior thickening properties while maintaining high water solubility, and also capable of having high water resistance in a state being hardened without using an especial crosslinking agent. In addition, another object is to provide a composition, a thickener, a coating material for papers, a coated paper, an adhesive and a film containing the alkyl-modified PVA. Provided is an alkyl-modified vinyl alcohol polymer containing (a) a monomer unit represented by the following general formula (I): wherein, R1 represents a linear or branched alkyl group having 8 to 29 carbon atoms; and R2 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, and has a viscosity average degree of polymerization of no less than 200 and no greater than 5,000, a degree of saponification of no less than 20 mol % and no greater than 99.99 mol %, and a content of the monomer unit (a) of no less than 0.
    Type: Application
    Filed: June 8, 2011
    Publication date: August 15, 2013
    Applicant: Kuraray Co., Ltd.
    Inventors: Shinsuke Nii, Masato Nakamae, Yuta Taoka, Yasutomo Saito
  • Publication number: 20130029070
    Abstract: Providing a crosslinkable composition and a crosslinking agent is objected to, which are capable forming a crosslinked product that is superior in retort resistance, with suppressed bleeding out from the crosslinked product, and that has favorable interlayer adhesiveness when formed into a multilayered structure crosslinked product. The present invention provides a crosslinkable composition containing (A) a polymer having an SP value of no less than 9.5 (cal/cm3)1/2 and no greater than 16.5 (cal/cm3)1/2, and (B) a crosslinking agent having one or more polar groups that include an oxygen atom and a nitrogen atom not constituting an aromatic ring, and two or more polymerizable groups. The difference between the SP value of the polymer (A) and the SP value of the crosslinking agent (B) is preferably no greater than 2 (cal/cm3)1/2, and more preferably no greater than 1 (cal/cm3)1/2. A decomposition temperature of the crosslinking agent (B) is preferably no less than 240° C.
    Type: Application
    Filed: March 10, 2011
    Publication date: January 31, 2013
    Applicant: KURARAY CO., LTD.
    Inventors: Kaoru Ikeda, Kazuhiro Kurosaki
  • Publication number: 20130020739
    Abstract: The flexographic printing plate precursor for laser engraving of the present invention includes, above a support, a crosslinked relief-forming layer formed by subjecting a resin composition containing a chain-polymerizable monomer (A), a crosslinking agent (B) that crosslinks in a step-growth reaction, and a crosslinkable polymer (C) having a crosslinkable group that reacts with the crosslinking agent (B) to chain polymerization and step-growth crosslinking reactions, the crosslinked relief-forming layer having a storage modulus E? (MPa) at a frequency of 100 Hz and 25° C. satisfying the relationship (a) below and having a maximum tensile elongation L (%) at break at 25° C. satisfying the relationship (b) below.
    Type: Application
    Filed: March 28, 2011
    Publication date: January 24, 2013
    Applicant: FUJIFILM CORPORATION
    Inventor: Katsuhiro Yamashita
  • Publication number: 20130017744
    Abstract: A repellent composition including an aqueous continuous phase and a graft copolymer dispersed in the aqueous continuous phase. The graft copolymer has a water soluble polymer trunk having hydroxyl groups and a branch having a C6-perfluoroalkyl group bonded to the polymer trunk at a carbon atom substituted with the hydroxyl group. Also disclosed is a method of making the graft copolymer and a substrate treated with the repellent composition.
    Type: Application
    Filed: March 29, 2011
    Publication date: January 17, 2013
    Applicant: DAIKIN INDUSTRIES, LTD.
    Inventors: Hisako Nakamura, Takashi Enomoto, Anthony A. Parker, Joseph J. Marcinko, Franklin A. Adamsky, Bradley H. Hartong
  • Publication number: 20120294821
    Abstract: The present invention is a compound for counteracting thiol- and amine-based malodors in consumer, industrial and textile products.
    Type: Application
    Filed: May 20, 2011
    Publication date: November 22, 2012
    Applicant: International Flavors & Fragrances Inc.
    Inventors: Johan Gerwin Lodewijk Pluyter, Xiao Huang, Takashi Sasaki
  • Publication number: 20120259067
    Abstract: Provided is a method for producing a 2-cyanoethyl group-containing organic compound having a high ratio of replacement by cyanoethyl groups and a high dielectric constant. More specifically, provided is a method for producing a 2-cyanoethyl group-containing organic compound comprising a step of reacting acrylonitrile with a hydroxyl group-containing organic compound in the presence of a quaternary ammonium salt as a catalyst through a Michael addition.
    Type: Application
    Filed: March 27, 2012
    Publication date: October 11, 2012
    Inventors: Ikuo Fukui, Kazuhisa Hayakawa, Soji Tanioka, Masahiro Ohgata, Masaaki Kajitani
  • Publication number: 20120252957
    Abstract: Polymers useful as in non-enzymatic saccharification processes are provided. Provided are also methods for hydrolyzing cellulosic materials into monosaccharides and/or oligosaccharides using these polymeric acid catalysts.
    Type: Application
    Filed: February 27, 2012
    Publication date: October 4, 2012
    Applicant: Midori Renewables, Inc.
    Inventors: John M. Geremia, Brian M. Baynes
  • Patent number: 8277844
    Abstract: The present invention relates to a novel resin composition useful as a coating agent or a binder for medicines, drugs for animals, agricultural chemicals, fertilizers, foods or the like, which contains a polyvinyl alcohol copolymer as a main component. More particularly, the present invention relates to a resin composition, characterized in that the composition is obtained by copolymerizing a polyvinyl alcohol having an average polymerization degree of 1300 or less, and at least one polymerizable vinyl monomer in a weight ratio of 6:4 to 9:1.
    Type: Grant
    Filed: August 5, 2004
    Date of Patent: October 2, 2012
    Assignees: Shionogi & Co., Ltd., Nisshin Kasei Co., Ltd., Daido Chemical Corporation
    Inventors: Makoto Noami, Toshiro Fujii, Yoshihiro Furuya, Noboru Hoshi, Toshio Shimamoto, Shunji Uramatsu
  • Patent number: 8277932
    Abstract: Membranes, methods of making membranes, and methods of separating gases using membranes are provided. The membranes can include at least one hydrophilic polymer, at least one cross-linking agent, at least one base, and at least one amino compound. The methods of separating gases using membranes can include contacting a gas stream containing at least one of CO2, H2S, and HCl with one side of a nonporous and at least one of CO2, H2S, and HCl selectively permeable membrane such that at least one of CO2, H2S, and HCl is selectively transported through the membrane.
    Type: Grant
    Filed: June 20, 2011
    Date of Patent: October 2, 2012
    Assignee: The Ohio State University Research Foundation
    Inventor: W. S. Winston Ho
  • Patent number: 8227543
    Abstract: The invention relates to a flexible thermoplastic composition resistant to the ageing effects of oil, said composition comprising a grafted copolymer containing polyamide blocks and consisting of a polyolefin backbone and at least one polyamide graft. According to the invention, the grafts are attached to the core by the residues of an unsaturated monomer (X) having a function that can react with a polyamide comprising an amine end or a carboxylic acid end; the residues of the unsaturated monomer (X) are attached to the backbone by grafting or copolymerization from the double bond thereof; and the composition comprises between 40 to 90 wt % of the polyolefin core comprising the unsaturated monomer (X); between 5 to 40 wt % of polyamide grafts; and between 5 to 40% of at least one polymer selected from a saponified ethylene/vinyl acetate copolymer and a polyamide.
    Type: Grant
    Filed: February 6, 2008
    Date of Patent: July 24, 2012
    Assignee: Arkema France
    Inventors: Stephane Bizet, Jean-Jacques Flat
  • Patent number: 8198364
    Abstract: There are provided poly(vinyl alcohol) polymers and copolymers containing vinyl alcohol or vinyl acetate and derivatives thereof such as poly(ethylene glycol)-grafted poly(vinyl alcohol) polymers or polyether-grafted poly(vinyl alcohol) polymers. These polymers can contain various functional groups. Such polymers can be use as polymer matrix or solid support for various chemical substrates such as organic substrates and reagents. Cross-linked poly(vinyl alcohol) polymers and copolymers are also provided. Methods for preparing such polymers as well as several of their uses are also included.
    Type: Grant
    Filed: June 14, 2007
    Date of Patent: June 12, 2012
    Assignee: Valorisation-Recherche, Limited Partnership
    Inventors: Julian Xiao-Xia Zhu, Pardin Christophe, Juntao Luo, William A. Lubell, Tarek Kassem
  • Patent number: 8188184
    Abstract: An environmentally safe additive and vehicle system are provided for water-based and oil-based printing inks, paints, coatings and adhesives which can be rapidly transferred, dispersed, dispensed, spread, dried and cured. The low cost, stable additive and vehicle system enhance multiple color, high speed printing with sharp, highly defined images and superior quality, and can be used on many different types of substrates, such as paper, paperboard, cardboard, clay coated board, foil, plastic, glass, metal, wood and composites. The additive may be formed by the reaction product of a photoinitiator, such as an UV-activated polyelectrolyte, and a monomer, such as an acrylate or a methacrylate in an aqueous solution. In other embodiments, the additive is formed from a carboxylic acid or anhydride and alkylalkanolamine monomer or a dialkylaminoalkyl acrylate or methacrylate monomer in an aqueous solution.
    Type: Grant
    Filed: November 30, 2010
    Date of Patent: May 29, 2012
    Assignee: Omnitech Environmental, LLC
    Inventors: Leroy John Cook, Richard T. Skov
  • Publication number: 20120083523
    Abstract: According to an aspect of the present invention, implantable or insertable medical devices are provided, which contain one or more polymeric regions. These polymeric regions, in turn, contain one or more polymers, at least one of which is a copolymer that includes the following: (a) one or more unsaturated hydrocarbon monomer species and (b) one or more heteroatom-containing monomer species.
    Type: Application
    Filed: December 8, 2011
    Publication date: April 5, 2012
    Applicant: BOSTON SCIENTIFIC SCIMED, INC.
    Inventors: Robert E. RICHARD, Marlene C. SCHWARZ, Rudolf FAUST
  • Patent number: 8101668
    Abstract: This invention provides a novel graft polymer that has excellent proton conductivity, is capable of regulating hydrogen permeability, methanol permeability, and the like, and can serve as a starting material for a polymer electrolyte membrane, which facilitates moisture balance control and efficient operation of a fuel cell. A polymer electrolyte membrane composed of such graft polymer is also provided. This graft polymer comprises a main chain comprising a hydroxyl group-containing polymer and a graft chain comprising a polymer containing a sulfonic acid group-containing monomer.
    Type: Grant
    Filed: March 15, 2006
    Date of Patent: January 24, 2012
    Assignees: Toyota Jidosha Kabushiki Kaisha, Yamaguchi University
    Inventors: Shigeharu Takagi, Mitsuru Higa
  • Publication number: 20110274939
    Abstract: A hydrophilizing agent that maintains a favorable wettability for dew condensation even after a long-term use; a hydrophilizing method; and an aluminum-containing metal material treated by the hydrophilizing method and having excellent wettability for dew condensation are provided. The hydrophilizing agent contains a modified polyvinyl alcohol obtained by graft polymerization of at least one type of N-vinyl lactam onto polyvinyl alcohol, thereby having a polymer and/or copolymer of the N-vinyl lactam in a side chain and a water-soluble cross-linking agent which can bind to a lactam moiety and/or a hydroxyl group of the modified polyvinyl alcohol. By applying and drying the hydrophilizing agent, a hydrophilic film having excellent wettability for dew condensation is formed.
    Type: Application
    Filed: January 21, 2010
    Publication date: November 10, 2011
    Applicants: DENSO CORPORATION, NIHON PARKERIZING CO., LTD.
    Inventors: Toshihisa Kataoka, Shinji Aoyagi, Masato Otake
  • Patent number: 8039543
    Abstract: A composition includes a first cylcoolefin substituted with at least one epoxy group and an aromatic amine. The composition is capable of bonding to a filler having a corresponding binding site. The composition is compatible with a metathesis catalyst capable of catalyzing a ring-opening metathesis polymerization reaction when contacted with the first cycloolefin. An associated method is also provided.
    Type: Grant
    Filed: September 4, 2007
    Date of Patent: October 18, 2011
    Assignee: General Electric Company
    Inventors: Xiaolan Wei, Wendy Wen-Ling Lin, Warren Rosal Ronk
  • Patent number: 8039544
    Abstract: A composition includes a first cylcoolefin substituted with at least one epoxy group and an aromatic amine. The composition is capable of bonding to a filler having a corresponding binding site. The composition is compatible with a metathesis catalyst capable of catalyzing a ring-opening metathesis polymerization reaction when contacted with the first cycloolefin. An associated method is also provided.
    Type: Grant
    Filed: September 4, 2007
    Date of Patent: October 18, 2011
    Assignee: General Electric Company
    Inventors: Xiaolan Wei, Wendy Wen-Ling Lin
  • Patent number: 8030398
    Abstract: Provided is a (meth)acrylic resin emulsion comprising, as a dispersant, a vinyl alcohol polymer having a degree of saponification of from 80 to 95 mol % and a degree of polymerization of from 400 to 2000 and, as a dispersoid, a polymer comprising at least one type of monomer units selected from acrylate monomer units and methacrylate monomer units, which has a “factor a” of at least 0.3 that indicates the particle size distribution width of the emulsion and of which the film formed at 20° C. to have a thickness of 500 ?m has a tensile strength of at least 100 kg/cm2. The emulsion is excellent in all its film strength, film transparency and mechanical stability and further in its alkali resistance.
    Type: Grant
    Filed: March 31, 2004
    Date of Patent: October 4, 2011
    Assignee: Kuraray Co., Ltd.
    Inventors: Seiji Tanimoto, Naoki Fujiwara
  • Patent number: 8030369
    Abstract: The invention relates to a biomedical molding, in particular a contact lens, which is obtainable by crosslinking, in a mold, an aqueous solution of a crosslinkable polyvinyl alcohol (PVA) prepolymer comprising at least 0.5 weight-%, based on the entire formulation, of a non-reactive PVA, wherein the number-average molecular weight of the non-reactive PVA is higher than that of the crosslinkable PVA. A contact lens of the invention has an improved wearing comfort.
    Type: Grant
    Filed: October 5, 2005
    Date of Patent: October 4, 2011
    Assignee: Novartis AG
    Inventor: Lynn Cook Winterton
  • Patent number: 7985809
    Abstract: There is provided a method of making a polymer solution comprising polymerizing one or more monomer in a solvent, wherein said monomer comprises one or more ethylenically unsaturated monomer that is a multi-functional Michael donor, and wherein said solvent comprises 40% or more by weight, based on the weight of said solvent, one or more multi-functional Michael donor.
    Type: Grant
    Filed: June 13, 2008
    Date of Patent: July 26, 2011
    Assignee: Rohm and Haas Company
    Inventors: Gerhard Erich Krawczyk, Kevin Michael Miller
  • Publication number: 20110117413
    Abstract: Battery separators are disclosed which include an ion selective polymeric film, composite film, or multi-layer containing an immobilized chelating agent.
    Type: Application
    Filed: November 19, 2009
    Publication date: May 19, 2011
    Inventors: Yichun Wang, Tatjana Mezini, Anna Maria Bofinger, Javit A. Drake, Paul A. Christian
  • Publication number: 20110097527
    Abstract: A shaped article including a modified ethylene-vinyl alcohol copolymer (C), wherein the modified ethylene-vinyl alcohol copolymer (C) is a product obtained by modifying an unmodified ethylene-vinyl alcohol copolymer (A) with an epoxy compound (B) having a double bond and has a degree of modification with the epoxy compound (B) of 0.1 to 10 mol % based on the monomer units of the ethylene-vinyl alcohol copolymer (A), and at least a part of the modified ethylene-vinyl alcohol copolymer (C) is crosslinked, and the gel fraction of the shaped article is 3% by weight or more. Thereby, a shaped article which contains almost no harmful crosslinking agent and which is excellent in hot water resistance, heat resistance and a gas barrier property is provided.
    Type: Application
    Filed: April 17, 2007
    Publication date: April 28, 2011
    Applicant: Kuraray Co., Ltd
    Inventors: Kaoru Ikeda, Masakazu Nakaya, Kazuhiro Kurosaki, Tomoyuki Watanabe
  • Publication number: 20100184223
    Abstract: The present invention relates to a biomaterial for cell or tissue culture, based on a polymeric carrier, which contains at least one crosslinkable hydrophilic polymer. The polymer is functionalized with groups that are selected from maleimide, vinylsulfonic, acrylate, alkyl halide, azirine, pyridyl, thionitrobenzene acid groups, or arylating groups. The invention relates further to a method of production of said biomaterial, and the use of particular functionalizing groups for the production of a biomaterial for the cultivation of tissue and/or cells. The biomaterial can have biofactors that exert a particular action on cells.
    Type: Application
    Filed: January 11, 2010
    Publication date: July 22, 2010
    Inventor: Helmut Wurst
  • Publication number: 20100160496
    Abstract: The present invention provides an acrylic acid ester copolymer emulsion composition, and redispersible powders made therefrom. The acrylic acid ester copolymer emulsion composition comprises polyvinyl alcohol having a degree of saponification of 85 mol % or more, and an average degree of polymerization of 300 to 1400; hydrophilic ethylenic unsaturated monomers having a water solubility of 1% or more; hydrophobic ethylenic unsaturated monomers having a water solubility of less than 1%; and a lipophilic initiator. The acrylic acid ester copolymer composition according to the present invention has excellent polymerization stability, and improved water resistance, alkali resistance, and fluidity, and the redispersible powders prepared by a spray-dry of the acrylic acid ester copolymer composition have improved water redispersibility, and thus, can be used in various fields such as an additive to a hydraulic material, a powder paint, and an adhesive.
    Type: Application
    Filed: September 21, 2007
    Publication date: June 24, 2010
    Inventor: Jeong Woo Son
  • Patent number: 7732527
    Abstract: The invention relates to water-soluble polymers reduced in molecular weight, a process for production of the same, and usage thereof.
    Type: Grant
    Filed: February 19, 2004
    Date of Patent: June 8, 2010
    Assignee: Hymo Corporation
    Inventor: Motosuke Ono
  • Patent number: 7723424
    Abstract: Silane-modified polyvinyl alcohols are obtained by treating vinyl alcohol polymers with one or more ethylenically unsaturated, silane-containing monomers at elevated temperature.
    Type: Grant
    Filed: November 14, 2006
    Date of Patent: May 25, 2010
    Assignee: Wacker Chemie AG
    Inventors: Abdulmajid Hashemzadeh, Karl Ernst Fickert
  • Patent number: 7700314
    Abstract: PEG-IFN-? conjugates, where a PEG moiety is covalently bound to Cys17 of human IFN-?, are produced by a process of site specific PEGylation with a thiol reactive PEGylating agent. A pharmaceutical composition and a method for treating infections, tumors and autoimmune and inflammatory diseases are also provided. The invention further relates to a method for the stepwise attachment of PEG moieties in series to a polypeptide, and more particularly to IFN-?.
    Type: Grant
    Filed: February 13, 2007
    Date of Patent: April 20, 2010
    Assignee: Merck Serono SA
    Inventors: Nabil El-Tayar, Michael J. Roberts, Milton Harris, Wayne Sawlivich
  • Patent number: 7674854
    Abstract: It is an object of the present invention to provide a method of producing a polyvinyl acetal resin by which a polyvinyl acetal resin having a high acetalization degree can be produced even in a solid catalyst system, a polyvinyl butyral resin produced by the above-mentioned production method of a polyvinyl acetal resin, and a method of producing an esterified polyvinyl alcohol resin by which the esterification can be performed at high efficiency even in a solid catalyst system. The present invention is a method of producing a polyvinyl acetal resin, wherein a solution or a suspension containing a polyvinyl alcohol resin and a carbonyl compound is pressurized in the presence of a solid catalyst.
    Type: Grant
    Filed: August 4, 2004
    Date of Patent: March 9, 2010
    Assignee: Sekisui Chemical Co., Ltd.
    Inventors: Toshio Tada, Yohei Nishimura, Katsunori Toyoshima
  • Patent number: 7670523
    Abstract: Regrind is mixed with at least one low density metallocene polyethylene to increase the amount of regrind that can be used in a thermoformed article.
    Type: Grant
    Filed: January 25, 2007
    Date of Patent: March 2, 2010
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Anthony Poloso, Allen T Mika