With Ethylenic Reactant Patents (Class 525/59)
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Patent number: 5102949Abstract: Ethylenically unsaturated carbamates are prepared by reaction of unsaturated isocyanates with the hydroxy groups of polyvinyl acetals. The ethylenically unsaturated carbamates either alone or formulated with unsaturated co-reactants such as (meth)-acryloyl monomers and oligomers, maleates and fumarates provide radiation curable coating compositions.Type: GrantFiled: August 19, 1991Date of Patent: April 7, 1992Assignee: Monsanto CompanyInventors: William A. Dupont, George E. Sheldrick
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Patent number: 5096965Abstract: Polymeric blends of (a) linear alternating polymer of carbon monoxide and at least one ethylenically unsaturated hydrocarbon with (b) reaction product of carbon monoxide and ethylenically unsaturated hydrocarbon with other polymeric material selected from polymeric polyols and diene rubbers are obtained when the linear alternating polymer is produced in the presence of the other polymeric material.Type: GrantFiled: June 22, 1989Date of Patent: March 17, 1992Assignee: Shell Oil CompanyInventors: Antonius A. Broekhuis, Eit Drent
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Patent number: 5075401Abstract: A graft copolymer is made by grafting, by a free radical reaction mechanism in aqueous solution, water soluble ethylenically unsaturated monomeric material on to a water soluble substrate having hydroxyl groups, and the free radicals are formed on the substrate using an oxidizing metal capable of being reduced by the substrate to a lower valency state (for instance cerium) and persulphate or other peroxy compound capable of oxidizing the metal back to a higher valency state. The process is preferably conducted as a reverse phase polymerization process and the invention includes also a novel reverse phase emulsion comprising a dispersion of reverse phase polymer particles of a graft copolymer of carboxymethyl cellulose, dextran or starch with acrylamide and acrylic acid and/or AMPS.Type: GrantFiled: August 25, 1989Date of Patent: December 24, 1991Assignee: Allied Colloids Ltd.Inventor: Lian-Sheng Zhang
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Patent number: 5066691Abstract: An adhesive composition for metal-clad laminates which comprises:(a) 100 parts by weight of a polyvinylbutyral having an average polymerization degree of from 500 to 3,000 and a degree of butyralization of at least 60 mol %,(b) from 10 to 200 parts by weight of an epoxidized polybutadiene per 100 parts by weight of the polyvinylbutyral, the epoxidized polybutadiene having a number average molecular weight of from 1,000 to 10,000 and an epoxy equivalent weight of from 200 to 2,000, and(c) from 1 to 10 parts by weight of a hardener for the epoxidized polybutadiene per 100 parts by weight of the epoxidized polybutadiene.Type: GrantFiled: November 29, 1989Date of Patent: November 19, 1991Assignee: Hitachi Chemical Co., Ltd.Inventors: Toshihisa Kumakura, Ken Nanaumi, Ryoichi Ikezawa, Hideki Eriguchi
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Patent number: 5061603Abstract: Photopolymerizable polyvinyl alcohols including a group of formula ##STR1## wherein R.sub.1 represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted aralkyl group, or a hydrogen atom; R.sub.2 represents a substituted or unsubstituted alkyl group, a primary, secondary or tertiary amino group, a cyano, hydroxy or nitro group, a halogen or hydrogen atom or, together with the pyridine ring to which it is attached, part of a quinolyl group; R.sub.3 represents a chlorine or hydrogen atom or, together with the benzene ring to which it is attached, part of a naphthyl group; and X.sup.- represents an anion, and photocurable compositions for producing screen printing stencils including such polyvinyl alcohol derivatives. Compositions of the invention show high light sensitivity with low levels of photocrosslinkable groups grafted to the polyvinyl alcohol.Type: GrantFiled: December 12, 1989Date of Patent: October 29, 1991Assignee: Sericol Group LimitedInventors: John Hamilton, Peter Dickinson
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Patent number: 5057390Abstract: A photosensitive composition characterized by comprising:(a) a vinyl alcohol polymer containing the following structural unit A and having a saponification degree of a vinyl ester unit of not less than 70 mol %: ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 each represents H or a hydrocarbon group having 1 to 4 carbon atoms;(b) a radically polymerizable ethylenic unsaturated compound; and,(c) a photopolymerization initiator,having flexiblity and impact resistance which can maintain sufficient softness but are not broken particularly even at low temperature and low humidity so that resin plates showing high printing quality can be obtained from the photosensitive composition.Type: GrantFiled: November 20, 1986Date of Patent: October 15, 1991Assignee: Kuraray Company, Ltd.Inventors: Toshiaki Sato, Junnosuke Yamuchi, Takuji Okaya
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Patent number: 5055518Abstract: Ethylenically unsaturated carbamates are prepared by reaction of unsaturated isocyanates with the hydroxy groups of polyvinyl acetals. The ethylenically unsaturated carbamates either alone or formulated with unsaturated co-reactants such as (meth)-acryloyl monomers and oligomers, maleates and fumarates provide radiation curable coating compositions.Type: GrantFiled: August 3, 1989Date of Patent: October 8, 1991Assignee: Monsanto CompanyInventors: William A. Dupont, George E. Sheldrick
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Patent number: 5051468Abstract: Polymers having the general idealized structure: ##STR1## wherein a, b and c represent the number of monomer units of each respective monomer, the sum of a and b is 200 to 5000, b is the product of a multiplied by 0 though 0.25, c/(a+b)=0.0001 to 0.006, m is 5 to 21, and the sum of m and n is 10 to 42, and aqueous solutions comprising such polymers, are disclosed.Type: GrantFiled: December 30, 1988Date of Patent: September 24, 1991Assignee: Aqualon CompanyInventor: Paquita E. Barnum
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Patent number: 5039519Abstract: A hair cosmetic composition comprising fine particles of a crosslinked polymer, which are insoluble in water and ethanol and do not form a film at normal temperature, is disclosed. A conventionally known film-forming polymer may also be formulated optionally. The hair cosmetic is free from stiffness, stickiness, or excessive gloss imparted to the hair which are the defects of conventional hair cosmetics using only conventional film-forming polymers, and provides excellent hair conditioning and hair-resetting effects.Type: GrantFiled: June 11, 1990Date of Patent: August 13, 1991Assignee: Kao CorporationInventors: Takeshi Inoue, Tadasu Hikichi, Yukihiro Fukuyama, Akihiro Kondo
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Patent number: 5021505Abstract: A photosensitive poly(vinyl alcohol) derivative comprising units of the fula ##STR1## wherein R.sub.1 is alkylene, R.sub.2 is hydrogen or a lower alkoxy, ##STR2## is a quaternary aromatic nitrogen-containing heterocycle, X.sup.- is SO.sub.3.sup.- or CO.sub.2.sup.-, m is 0 or 1, and n is an integer of 1 to 6 capable of being developed with an aqueous developing solution.Type: GrantFiled: December 1, 1989Date of Patent: June 4, 1991Assignees: Director General of the Agency of Industrial Science and Technology, Toyo Gosei Kogyo Co., Ltd.Inventors: Kunihiro Ichimura, Noriaki Tochizawa, Hideo Kikuchi
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Patent number: 5017649Abstract: The condensation of .beta.-dicarbonyl compounds with .alpha.,.beta.-unsaturated compounds is promoted by amidine and guanidine compounds.Type: GrantFiled: January 19, 1988Date of Patent: May 21, 1991Assignee: Eastman Kodak CompanyInventor: Robert J. Clemens
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Patent number: 4992509Abstract: Polyvinyl acetal resin, use thereof as an adhesion promoting additive, method of producing same, and adhesive composition comprising sameAn acrylate- or methacrylate-substituted polyvinyl acetal resin of formula I: ##STR1## wherein the weight percentages of the X, Y and Z groups are variable, R is a hydrogen atom or an alkyl group, andR.sub.1 is hydrogen atom or a methyl group, is described.The resin of formula I is produced by acrylating or methacrylating a polyvinyl acetal resin of formula II: ##STR2## in which the weight percentages of the X', Y' and Z' groups are variable, particularly in the range 68 to 88% X, 6 to 19% Y' and 1 to 26% Z.The compounds of formula I are used to promote adhesion of acrylate or methacrylate ester based adhesive compositions to polyester plastic substrates.Type: GrantFiled: October 3, 1988Date of Patent: February 12, 1991Assignee: Loctite CorporationInventor: Stephen J. Harris
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Patent number: 4987183Abstract: The present invention relates to a novel cationic polymer processing U.V. absorbing ability which is produced by the ester bonding of a cationic U.V. absorber to the terminal of the polymer. Unlike conventional nonionic U.V. absorbing polymers or nonionic or anionic U.V. absorbers, the U.V. absorber according to the present invention exhibits an improved substantivity to several anionic substrates, for example, hair, skin, and the like, due to the presence of a positively charged substituent group.Type: GrantFiled: June 20, 1989Date of Patent: January 22, 1991Assignee: Pacific Chemical Co., Ltd.Inventors: Young D. Kim, Byung J. Ha
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Patent number: 4972012Abstract: The polyvinyl chloride (PVC) resin-based composition of the invention gives a molded article which suffers little from the disadvantageous phenomenon of surface whitening as is sometimes unavoidable when a conventional PVC resin-made article is prolongedly kept under adverse conditions as in hot water or in a high-temperature, high-humidity atmosphere. The composition characteristically comprises a limited amount of a partially saponified polyvinyl alcohol having an average degree of polymerization of 150 to 600 and a degree of saponification of 20 to 55% as a special additive in an amount of 0.8 to 5.0% by weight based on the PVC resin. The resin composition is also less subject to the disadvantage of a decrease in the transparency of the resin articles even when the resin composition is compounded with a metal-containing heat stabilizer such as organotin mercaptides.Type: GrantFiled: September 13, 1989Date of Patent: November 20, 1990Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Tadashi Amano, Hajime Kitamura
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Patent number: 4965313Abstract: The invention discloses a novel modified polyvinyl butyral polymer having photocurability and heat-curability containing an ethylenically unsaturated moiety, which is introduced by the reaction of, for example, N-methylol acrylamide with a part of the hydroxyl groups, in addition to the vinyl butyral moiety, vinyl acetate moiety and vinyl alcohol moiety constituting conventional polyvinyl butyral resins. The inventive polymer is useful for various types of adhesives, coating materials, interlayers of laminated shatter-proof glass and the like similarly to unmodified polyvinyl butyral resins but with a possibility of broadened utilizability and absence of the problems due to evaporation of organic solvents.Type: GrantFiled: June 7, 1989Date of Patent: October 23, 1990Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Yoshiro Onda, Soji Tanioka
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Patent number: 4952655Abstract: Water-soluble copolymers having a K value of from 15 to 120 (determined on the sodium salt according to H. Fikentscher in aqueous solution at 25.degree. C., a pH of 7 and a polymer concentration of the Na salt of 1% by weight) contain, in the polymerized form,(a) from 99.5 to 80 mol % of one or more monoethylenically unsaturated C.sub.3 -C.sub.6 -monocarboxylic acids and(b) from 0.5 to 20 mol % of one or more comonomers which possess two or more ethylenically unsaturated, non-conjugated double bonds, are derived from esters and are obtainable by esterification of(b1) monoethylenically unsaturated C.sub.3 -C.sub.6 -monocarboxylic acids with(b2) polyhydric alcohols of 2 to 6 carbon atoms, polyalkylene glycols, polyglycerols, polyvinyl alcohol and monohydric, monoethylenically unsaturated C.sub.3 -C.sub.Type: GrantFiled: April 19, 1988Date of Patent: August 28, 1990Assignee: BASF AktiengesellschaftInventors: Hans-Peter Seelmann-Eggebert, Dieter Boeckh, Heinrich Hartmann, Wolfgang Trieselt, Alexander Kud
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Patent number: 4937284Abstract: Modified polyolefin comprising a polyolefin linked to a hydrolyzable silane which is reactable with polyvinyl alcohol and being chemically bound to polyvinyl alcohol by the silane, and method for preparing the same.Type: GrantFiled: August 23, 1988Date of Patent: June 26, 1990Assignee: Neste OyInventor: Christer Bergstrom
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Patent number: 4912184Abstract: A process for producing monodisperse vinyl polymer fine particles is disclosed, which comprises polymerizing at least one monomer selected from the group consisting of vinyl aromatic compounds, acrylic esters, and methacrylic esters as dissolved in an organic solvent or a mixed solvent of water and an organic solvent, which is capable of dissolving said monomer or monomers but incapable of dissolving a produced polymer, wherein said polymerizing is carried out in the presence of partially saponified polyvinyl alcohol having a degree of saponification of from 5 to 75 mol % and a number average degree of polymerization of from 100 to 3,000 as a dispersion stabilizer and in the presence of a polymerization initiator. Monodisperse polymer particles having a particle size of the order of micron with a narrow size distribution can be obtained through the one-step polymerization.Type: GrantFiled: February 3, 1988Date of Patent: March 27, 1990Assignee: Fuji Xerox Co., Ltd.Inventors: Yutaka Akasaki, Naoya Yabuuchi, Tatsuro Ohki
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Patent number: 4891300Abstract: A photosensitive resin composition comprising a photosensitive saponified poly(vinyl acetate) derivative containing in the backbone thereof at least one of a first group of photosensitive units which are represented by the general formula (I) ##STR1## wherein represents a vinyl alcohol residue in the backbone of the saponified poly(vinyl acetate) derivative; Y represents a member selected from the group consisting of the following general formulae (II) and (III) ##STR2## m denotes an integer of 1-6; n denotes 0 or 1; R.sub.1 represents a member selected from a hydrogen atom, an unsubstituted alkyl and an unsubstituted aralkyl group, a hydroxyl group, a carbamoyl group, an ether bond and an unsaturated bond; R.sub.2 represents a member selected from a hydrogen atom and a lower alkyl group; and X.sup.Type: GrantFiled: September 23, 1987Date of Patent: January 2, 1990Assignees: Director-General of Agency of Industrial Science & Technology Ministry of International Trade and Industry, Oji Kako Co., Ltd.Inventors: Kunihiro Ichimura, Hiroshi Itoh, Shuuichi Nakazato, Hideaki Takazawa
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Patent number: 4868241Abstract: Polymers are disclosed comprising a poly(vinyl alcohol) backbone with the following groups or combination of groups bound to the backbone:(A) (substituted alkyl)benzoyl groups; or(B) (substituted alkyl)benzoyl groups, and (vinyl)benzoyl groups; or(C) (substituted alkyl)benzoyl groups, and (halo)benzoyl groups or (2-carboxy-3,4,5,6-tetrachloro) benzoyl groups;(D) (substituted alkyl)benzoyl groups, (vinyl) benzoyl groups, and (halo)benzoyl groups or (2-carboxy-3,4,5,6-tetrachloro)benzoyl groups;(E) (vinyl)benzoyl groups, and (halo)benzoyl groups or (2-carboxy-3,4,5,6-tetrachloro) benzoyl groups; or(F) (halo)benzoyl groups.Each of these polymers can optionally contain, bound to the poly(vinyl alcohol) backbone, (trialkylsily) benzoyl groups.The benzoyl groups are randomly bound to the poly(vinyl alcohol) by ester linkages. Residual pendant hydroxy groups remain after the attachment of the benzoyl groups.Type: GrantFiled: December 29, 1986Date of Patent: September 19, 1989Assignee: American Cyanamid CompanyInventors: Laura J. Hiscock, Bruce H. Baretz, Richard L. Webb
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Patent number: 4837290Abstract: A composition of matter comprising an acrylamido-acyl or methacrylamido-acyl oligomer derived from at least one nucleophilic oligomer having at least one amino-, hydroxyl-, or thiol-substituted polyoxyalkylene, polyalkyleneimine, polyester, polyolefin, polyacrylate, or polysiloxane oligomer, said nucleophilic oligomer having a molecular weight in the range of 200 to 20,000 is disclosed. Also disclosed are free radically polymerizable monomer-containing compositions containing said oligomers as well as acrylamido- and methacrylamido-acylated polymers which are thermal or photocured products of said oligomers. In addition, a process is disclosed for providing said acrylamido- and methacrylamido-acylated oligomers which are useful, for example, in coatings, films, printing inks, adhesives, and saturants.Type: GrantFiled: July 11, 1988Date of Patent: June 6, 1989Assignee: Minnesota Mining and Manufacturing CompanyInventors: Jerald K. Rasmussen, Steven M. Heilmann, Frederick J. Palensky
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Patent number: 4837272Abstract: A process for the cross-linking of olefin-polymers such as polyethylene which comprises reacting the polymer with a free radical generator to form a polymer having free radicals and reacting the polymer having free radicals with a tetrafunctional organo zirconate which has at least one functional group that is reactive with the free radicals on the polymer followed by contact thereof with moisture or water, optionally in the presence of a condensation reaction catalyst.Type: GrantFiled: July 27, 1987Date of Patent: June 6, 1989Inventor: Donald W. Kelley
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Patent number: 4833201Abstract: The polymerization of acetylene in the presence of polymers using certain nickel catalysts results in polyacetylene-containing polymer products which are readily processed while retaining their electrical properties.Type: GrantFiled: January 12, 1988Date of Patent: May 23, 1989Assignee: Bayer AktiengesellschaftInventors: K. H. Aleksander Ostoja Starzewski, Josef Witte
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Patent number: 4826917Abstract: Polymerization of acrylic or methacrylic acid and a water-soluble acrylic or methacrylic acid salt in the presence of a carboxyl group-containing polyvinyl alcohol resin gives highly water-absorbing resins with the water absorbency, water absorption rate, water insolubility and other characteristics well balanced therein.Type: GrantFiled: May 6, 1987Date of Patent: May 2, 1989Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki KaishaInventors: Susumu Kondo, Tetsuo Moriya
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Patent number: 4824904Abstract: The present invention relates to resin compositions and laminates using saponified ethylene-vinyl acetate copolymers containing a polyether component. Formed products and laminates obtained from the resin compositions are flexible, excellent in flexural fatigue resistance and gas barrier properties and extremely useful as flexible laminates.Type: GrantFiled: March 19, 1987Date of Patent: April 25, 1989Assignee: Kuraray Co., Ltd.Inventors: Akimasa Aoyama, Takeshi Moritani, Kiyoshi Yonezu, Takuji Okaya
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Patent number: 4778847Abstract: Carboxylates of hydroxyl-containing polymers are prepared by reacting a finely dispersed hydroxyl-containing polymer with a carboxylic anhydride in the heterogeneous phase in the presence of a tertiary amine as a catalyst by a method in which an N-alkylimidazole, where alkyl is of 1 to 10 carbon atoms, is used as the catalyst.Type: GrantFiled: September 24, 1986Date of Patent: October 18, 1988Assignee: BASF AktiengesellschaftInventors: Gunnar Schornick, Gunther Schulz, Walter Mann
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Patent number: 4764406Abstract: Disclosed herein is a smokable food-packaging film comprising at least one layer of a mixture of 45 to 85 wt % polyamide, 10 to 45 wt % copolymer of olefin and vinyl alcohol, and 5 to 30 wt % polyolefin, in which the mixture falls in the pantagonal range defined in FIG. 1 by linear lines connecting the points A, B, C, D and E, respectively, said layer having the properties of a permability to 50% concentration of methanol of not less than 200 g/m.sup.2.day.atm at a temperature of 60.degree. C. and a relative humidity of 0% and an oxygen gas-permeability of not more than 50 cc/m.sup.2.day.atm at a temperature of 30.degree. C. and a relative humidity of 60% and a water vapor-transmission rate of not more than 70 g/m.sup.2.day at a temperature of 40.degree. C. and a relative humidity of 90%.Type: GrantFiled: August 4, 1986Date of Patent: August 16, 1988Assignee: Kureha Kagaku Kogyo Kabushiki KaishaInventors: Nobuyuki Hisazumi, Shinichiro Funabashi, Yoshihiko Tomioka
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Patent number: 4749730Abstract: The invention described herein comprises a two component sealant composition and process for applying the same for repair of ruptures, holes, cracks, etc., in hoses, pipes, tires, etc. The first component is an alpha-cyanoacrylate glue which is applied as a layer covering the rupture or crack and after a very short period the second component, a powder, is applied to the surface of the alpha-cyanoacrylate. This second component comprises a polymerization initiator having hydroxyl and/or carboxylate groups therein, such as carbohydrate, i.e., saccharides, etc., hydrolyzed polyvinylacetate, etc. A particularly preferred initiator is alginate.Type: GrantFiled: November 3, 1986Date of Patent: June 7, 1988Assignee: Renbec International Corp.Inventor: Rene C. Jimenez
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Patent number: 4746700Abstract: A process for preparing a vinyl alcohol copolymer, which comprises adding at least one specific olefin derivative containing phenyl group to a solution of vinyl ester copolymer when the predetermined polymerization conversion has been attained, removing an unpolymerized monomer and hydrolyzing the copolymer. The hydrolyzed copolymer easily gives transparent film which has not fish eyes or surface roughness without generation of fumes or bad odors and coloration during molding.Type: GrantFiled: February 26, 1986Date of Patent: May 24, 1988Assignee: Nippon Fohsei Kagaku Kogyo Kabushiki KaishaInventor: Hiroshi Takida
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Patent number: 4714768Abstract: A new compound is disclosed, N-(chlorocarbonyloxy-5-norbornene-2,3-dicarboximide I, in addition to processes for its production and employment of the compound as starting product for the manufacture of non-symmetrical carbonate, urethane-protected amino acid or peptide, activated carrier and carrier-ligand-complexes. The new compound is reacted with alcohols as well as with hydroxyl-group-containing or amino-group-containing polymers.Type: GrantFiled: August 27, 1984Date of Patent: December 22, 1987Assignee: Akademie Der Wissenschaften Der DDRInventors: Peter Henklein, Manfred Becker, Werner Buttner, Fritz Loth, Horts Dautzenberg, Klaus Forner, Rudolf Dolling, Karl-Heinz Graul, Wolf-Rainer Halatsch, Christian Rupprich
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Patent number: 4710539Abstract: A heat activatable adhesive or sealant organic resin composition comprising(1) a liquid, ethylenically unsaturated monomer, oligomer or prepolymer of the formula: ##STR1## wherein R is H or CH.sub.3, R.sub.1 is an organic moiety and n is at least 2,(2) a thermal initiator selected from the group consisting of substituted or unsubstituted pinacols, azo compounds, thiurams, organic peroxides and mixtures thereof, and(3) a thermoplastic adhesive material selected from the group consisting of polyesters, polyvinyl acetals, polyamides, butadiene-acrylonitrile copolymers, styrene-butadiene copolymers, styrene-isoprene copolymers, styrene-ethylene-butylene copolymers, ethylene-vinyl acetate copolymers, ethylene-ethyl acrylate copolymers, ethylene propylene diene monomer and mixtures thereof.The composition after application to the parts to be bonded or sealed forms a thermoset bond or seal on application of heat thereto, preferably by electromagnetic techniques including dielectric and induction heating.Type: GrantFiled: April 22, 1983Date of Patent: December 1, 1987Assignee: W. R. Grace & Co.Inventors: Bahram Siadat, Charles R. Morgan
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Patent number: 4708981Abstract: Water-insoluble proton-conducting polymers which may be formed into membranes which are used in gas separation or gas sensing processes comprise an interpenetrating polymer network. This IPN is formed from the interaction between a host polymer and a guest polymer which is subsequently cross-linked or cured. The host polymer blend is formed from a phosphoric acid or sulfuric acid and a polymer or copolymer of a compound which possesses repeat units such as, for example, hydroxy ethylene, vinyl sulfonic acid, ethylene imine, etc, while the guest polymer is formed from a monofunctional monomer such as methacrylic acid and a difunctional cross-linking agent such as methylenebisacrylamide.Type: GrantFiled: December 11, 1985Date of Patent: November 24, 1987Assignee: UOP Inc.Inventors: Joseph J. Zupancic, Raymond J. Swedo, Sandra Petty-Weeks
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Patent number: 4699950Abstract: The present invention relates to a polymer having a thiol group at one end of the molecule, which is obtained by subjecting the monomers capable of radical polymerization to radical polymerization in the presence of a thiolcarboxylic acid and then treating the resulting polymer with an alkali or acid; to a process for producing the same; and to a block copolymer based on the polymer having a thiol group at the end.The polymer having a thiol group at one end is difficult of forming disulfide linkages by oxidation and thus difficult of becoming insoluble. It is also a highly reactive material that will find wide use in varied application areas. The block copolymer based on the polymer having a thiol group at the end is superior in compatibility and will find wide use in varied application areas.Type: GrantFiled: July 8, 1985Date of Patent: October 13, 1987Assignee: Kuraray Co., Ltd.Inventors: Toshiaki Sato, Junnosuke Yamauchi, Takuji Okaya
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Patent number: 4670506Abstract: Organic aprotic solvent soluble polymers which are derivatives of a polyvinyl alcohol, having a weight average molecular weight of at least about 2,000, and containing from about 0.5 to about 90 percent, based on the number of hydroxyl groups in said polyvinyl alcohol, of units of the formula ##STR1## wherein R.sub.1 and R.sub.2 are independently alkylene, arylene, cycloaliphatic, aralkylene or aralkarylene, n is 0 or 1, A.sub.1 is a carbamoyloxy or ureido linking group, A is an oxa, imino or ureido group, R.sub.3 is hydrogen or methyl, R.sub.4 is hydrogen, or when R.sub.3 is hydrogen, methyl or also -COOR.sub.5 where B.sub.5 is hydrogen or lower alkyl, and crosslinked hydrogel contact lenses made therefrom and their preparation.Type: GrantFiled: December 23, 1985Date of Patent: June 2, 1987Assignee: Ciba-Geigy CorporationInventors: Merrill Goldenberg, Karl F. Mueller
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Patent number: 4665123Abstract: Organic aprotic solvent insoluble polymers which are derivatives of a polyvinyl alcohol, having a weight average molecular weight of at least about 2,000, and containing from about 0.5 to about 90 percent, based on the number of hydroxyl groups in said polyvinyl alcohol, of an addition reaction product of units of the formula ##STR1## with a vinylic monomer, wherein R.sub.1 and R.sub.2 are independently alkylene, arylene, cycloaliphatic, aralkylene or aralkarylene, n is 0 or 1, A.sub.1 is a carbamoyloxy or ureido linking group, A is an oxa, imino or ureido group, R.sub.3 is hydrogen or methyl, R.sub.4 is hydrogen, or when R.sub.3 is hydrogen, methyl or also --COOR.sub.5 where R.sub.5 is hydrogen or lower alkyl, and hydrogel contact lenses made therefrom and their preparation.Type: GrantFiled: December 13, 1985Date of Patent: May 12, 1987Assignee: Ciba-Geigy CorporationInventor: Merrill Goldenberg
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Patent number: 4654294Abstract: A photosensitive composition which comprises:(a) a vinyl alcohol polymer having at least one thiol group in the molecule thereof,(b) an ethylenically unsaturated compound which is radically polymerizable, and,(c) a photoinitiator,and is free from the defect of the removal of the vinyl alcohol polymer at the hardened regions upon development with water.Type: GrantFiled: March 18, 1986Date of Patent: March 31, 1987Assignee: Kuraray Co., Ltd.Inventors: Toshiaki Sato, Junnosuke Yamauchi, Takuji Okaya
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Patent number: 4652511Abstract: A process for producing a resin composition which comprises suspension-polymerizing at least one vinyl monomer in an aqueous medium in the presence of a dispersing agent, said suspension polymerization being carried out using a nonionic dispersant as said dispersing agent in the presence of a high-molecular-weight vinyl polymer having a weight average molecular weight of at least 500,000 obtained by emulsion polymerization.Type: GrantFiled: April 19, 1985Date of Patent: March 24, 1987Assignee: Fujikura Kasei Co., Ltd.Inventors: Hikoji Ueda, Akira Otsu, Kenji Sano, Katuyuki Takano
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Patent number: 4639500Abstract: A resin composition curable by active energy rays characterized in containing a compound represented by a following structural formula (I).Type: GrantFiled: July 27, 1984Date of Patent: January 27, 1987Assignee: Sanyo-Kokusaku Pulp Company, LimitedInventor: Motonobu Kubo
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Patent number: 4614761Abstract: A process for producing a curable resin having unsaturated groups in the side chains through urethane linkages, which comprises reacting (A) a polymer having hydroxyl groups in the side chains with (B) an unsaturated monoisocyanate obtained by reacting 1 mole of a diisocyanate with more than 1 but less than 1.8 moles of an unsaturated monoalcohol.Type: GrantFiled: March 18, 1985Date of Patent: September 30, 1986Assignee: Showa Highpolymer Co., Ltd.Inventors: Eiichiro Takiyama, Katsuhisa Morita
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Patent number: 4605589Abstract: A vinyl acetate-ethylene copolymer binder emulsion prepared by the copolymerization of vinyl acetate and ethylene in the presence of a polyvinyl alcohol which is 50 to 99 mole % hydrolyzed and has a 100 to 375 degree of polymerization such that it demonstrates a viscosity of about 2.4 to 4 as a 4% aqueous solution at 20.degree. C. Nonwoven fabrics bond with such copolymers possess surprisingly improved softness while maintaining toughness.Type: GrantFiled: October 25, 1984Date of Patent: August 12, 1986Assignee: Air Products and Chemicals, Inc.Inventor: Gus G. Orphanides
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Patent number: 4593052Abstract: Polymerizable compositions contain (A) a cationically polymerizable material, such as an epoxide resin, a phenoplast or a cyclic vinyl ether, (B) a hydroxy compound such as styreneallyl alcohol copolymer, and (c) an aromatic iodosyl salt of formula ##STR1## where R.sup.3 and R.sup.4, which may be the same or different, each represent a monovalent aromatic radical having from 4 to 25 carbon atoms, x denotes 1, 2 or 3, and Z.sup.x- denotes an x-valent anion of a protic acid.Suitable salts of formula II include diphenyliodosyl hexafluorophosphate and tetrafluoroborate. The compositions may be photopolymerized or they may be thermally polymerized in the presence, as catalyst for the iodosyl salt, of a salt or complex of a d-block transition metal, a stannous salt, an organic peroxide or an activated .alpha.-hydroxy compound.The compositions may be used as surface coatings and adhesives, and in the preparation of printing plates, printed circuits and reinforced composites.Type: GrantFiled: November 19, 1984Date of Patent: June 3, 1986Assignee: Ciba-Geigy CorporationInventor: Edward Irving
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Patent number: 4590131Abstract: Disclosed in a packaging material having at least one layer comprising an ethylene-vinyl alcohol copolymer having a vinyl alcohol content of 40 to 80 mole % and a residual vinyl ester content lower than 4 mole %, wherein the ethylene-vinyl alcohol copolymer consists of a composition comprising a plurality of copolymers differing in the vinyl alcohol content, said composition shows a plurality of endothermic peaks in a fusion curve by a differential scanning calorimeter, the composition has fusion characteristics satisfying requirements represented by the following formulae: ##EQU1## wherein Sc represents an area of a triangle defined by a base line connecting the skirt of a high temperature side peak to the skirt of a low temperature side peak in two adjacent peaks in said fusion curve and lines connecting the skirts of both the peaks to the trough between both the peaks, Sa represents an area of the high temperature side peak above said triangle, Sb represents an area of the low temperature side peak above sType: GrantFiled: October 5, 1984Date of Patent: May 20, 1986Assignee: Toyo Seikan Kaisha, Ltd.Inventors: Jinichi Yazaki, Kazuhiko Tsurumaru
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Patent number: 4581394Abstract: An agent for forming a surface-protecting layer on a coated paper, which comprises an aqueous solution of an alkali metal salt, ammonium salt or amine salt of a graft copolymer and an epoxy group-containing cross-linking agent incorporated in the aqueous solution, said graft copolymer comprising (A) 10 to 60% by weight of a polyvinyl alcohol polymer selected from the group consisting of partially saponified polyvinyl alcohols, polyvinyl alcohols containing copolymerized units of a vinyl monomer having carboxyl group, and polyvinyl alcohol having the recurring vinyl alcohol units esterified with a higher fatty acid, (B) 20 to 70% by weight of acrylamide or methacrylamide, (C) 5 to 30% by weight of at least one member selected from the group consisting of acrylonitrile, methacrylonitrile, lower alkyl esters of acrylic acid and methacrylic acid and hydroxyl lower alkyl esters of acrylic acid and methacrylic acid, and (D) 5 to 20% by weight of at least one vinyl monomer containing a carboxyl group.Type: GrantFiled: November 6, 1984Date of Patent: April 8, 1986Assignee: Showa Denko Kabushiki KaishaInventors: Eiichi Yoshida, Tetsuhiko Yamaguchi, Susumu Tago, Kunio Imamura
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Patent number: 4540743Abstract: The acylation of polyvinyl alcohols is carried out by a process in which these alcohols are esterified with an activated carboxylic acid derivative in the presence of, as the catalyst, an aminopyridine derivative of the general formula (I) ##STR1## where R.sup.1 and R.sup.2 are each alkyl, or R.sup.1 and R.sup.2 together form an alkylene radical. The acylation is particularly advantageously carried out in the heterogeneous phase. The acylated polyvinyl alcohols prepared in this manner are used in photopolymerizable and/or photocrosslinkable mixtures.Type: GrantFiled: June 25, 1984Date of Patent: September 10, 1985Assignee: BASF AktiengesellschaftInventors: Guenther Schulz, Guenther Wallbillich
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Patent number: 4537667Abstract: Radiation-curable linear addition polymers or copolymers are disclosed having a weight average molecular weight of from about 1,500 to about 15,000 of polymerized monoethylenically unsaturated monomers, which may include up to 25% by weight of an hydroxy-functional monomer, and which carries an hydroxyl group at most of its ends, reacted with a monoethylenically unsaturated monomer carrying a single functional group reactive with the hydroxyl group, so that the polymer carries monoethylenically unsaturated groups bonded to an average of from 1.6 to 5 of the hydroxyl groups per polymer molecule. The preferred radiation-curable polymers are liquid to slowly flowable at room temperature in the absence of organic solvent, and the monoethylenically unsaturated groups are preferably acrylate groups to enable an ultraviolet cure.Type: GrantFiled: April 25, 1984Date of Patent: August 27, 1985Assignee: DeSoto, Inc.Inventors: Timothy E. Bishop, George Pasternack, John M. Zimmerman
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Patent number: 4523983Abstract: This invention relates to a reactive plastisol dispersion comprising(1) a polyvinyl acetal thermoplast in particle form;(2) a liquid plasticizer member of the group consisting of(a) at least one an ethylenically unsaturated monomer, oligomer or prepolymer of the formula: ##STR1## wherein R is H or CH.sub.3, R.sub.1 is an organic moiety and n is 1 or more,(b) at least one unsaturated polyester containing the group: ##STR2## wherein R.sub.2 and R.sub.3 are organic moieties, x is 0-20 and y is 1-20; and(c) a mixture of (a) and (b);and, optionally, either(3) a free radical thermal initiator or(4) a photoinitiator for crosslinking.The reactive plastisol dispersion when fluxed can be useful as a sealant or adhesive.Type: GrantFiled: April 30, 1984Date of Patent: June 18, 1985Assignee: W. R. Grace & Co.Inventor: Shiow C. Lin
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Patent number: 4522913Abstract: Mono(meth)acrylate or di(meth)acrylate of 2-methylpropylene glycol. The diacrylate, or a low molecular weight oligomer thereof, with polymeric filler and sensitizer is useful as a photosensitive component.Type: GrantFiled: June 21, 1984Date of Patent: June 11, 1985Assignee: Daicel Chemical Industries, Ltd.Inventors: Tatsuya Kanno, Yuzo Toga
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Patent number: 4514540Abstract: The disclosure is of a copolymer reaction product of(A) 20 to 60 equivalent percent of a polymeric fatty acid;(B) 0 to 60 equivalent percent of a dicarboxylic acid;(C) 15 to 50 equivalent percent of a monocarboxylic acid; and(D) 5 to 25 equivalent percent of a synthetic polymeric resin having a crystalline chain structure, said resin having active carboxyl and/or hydroxyl groups capable of reaction with acid/amine groups; with(E) 50 to 80 equivalent percent of an organic polyamine.The copolymer is useful in flexographic ink compositions and such are advantageously water reducible (thinnable).Type: GrantFiled: September 26, 1983Date of Patent: April 30, 1985Assignee: Union Camp CorporationInventor: Michael C. Peck
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Patent number: 4463128Abstract: This invention relates to a reactive plastisol dispersion comprising(1) a polyvinyl acetal thermoplast in particle form;(2) a liquid plasticizer member of the group consisting of(a) at least one an ethylenically unsaturated monomer, oligomer or prepolymer of the formula: ##STR1## wherein R is H or CH.sub.3, R.sub.1 is an organic moiety and n is 1 or more,(b) at least one unsaturated polyester containing the group: ##STR2## wherein R.sub.2 and R.sub.3 are organic moieties, x is 0-20 and y is 1-20; and(c) a mixture of (a) and (b);and, optionally, either(3) a free radical thermal initiator or(4) a photoinitiator for crosslinking.The reactive plastisol dispersion when fluxed can be useful as a sealant or adhesive.Type: GrantFiled: May 9, 1983Date of Patent: July 31, 1984Assignee: W. R. Grace & Co.Inventor: Shiow C. Lin
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Patent number: 4448929Abstract: A protective colloid for use in an interfacial polymerization process comprising a graft copolymer of polyvinyl alcohol and methyl vinyl ether/maleic acid.Type: GrantFiled: June 1, 1982Date of Patent: May 15, 1984Assignee: Stauffer Chemical CompanyInventors: Marius Rodson, Herbert B. Scher