Solid Graft Or Graft-type Copolymer Contains Backbone Derived From Ethylenic Reactants Only Patents (Class 525/69)
  • Patent number: 7304111
    Abstract: A problem of the invention is to provide a propylene copolymer which is excellent in adhesion to crystalline propylene-based polymers and which is excellent in solubility and compatibility with polar resins, a process for producing the same, and a composition containing the subject polypropylene copolymer. The invention is concerned with a polypropylene copolymer, which is characterized by having a polymer principal chain (A) derived from a propylene-based polymer having (1) a prescribed requirement as defined by the 13C-NMR spectral measurement and having (2) a melting point [Tm] by a differential scanning calorimeter of not higher than 100° C., or a crystal melting heat of less than 5 J/g; and a side chain containing a polymer chain (B) which is different from the principal chain, with a weight ratio of (A)/(B) being in the range of from 20/1 to 1/20, a composition containing the subject copolymer, and a process for producing the subject copolymer.
    Type: Grant
    Filed: August 22, 2005
    Date of Patent: December 4, 2007
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Masato Onoe, Kazuyuki Hata
  • Patent number: 7300978
    Abstract: This invention relates to a process for stabilising and at the same time phase compatibilising plastics or plastic compositions by incorporating polymeric compounds obtainable by reacting a compound selected from the group consisting of the sterically hindered phenols, sterically hindered amines, lactones, sulfides, phosphites, benzotriazoles, benzophenones and 2-(2-hydroxyphenyl)-1,3,5-triazines, which compounds contain at least one reactive group, with a compatibilisator.
    Type: Grant
    Filed: February 23, 2004
    Date of Patent: November 27, 2007
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Rudolf Pfaendner, Heinz Herbst, Kurt Hoffmann, Samuel Evans, Alfred Steinmann
  • Patent number: 7300977
    Abstract: This method for preparing an acrylic-modified chlorinated polyolefin resin comprises graft-copolymerizing an acid-modified chlorinated polyolefin resin with a monomer mixture containing a (meth)acrylate ester monomer having one hydroxyl group and another vinyl monomer in the presence of a cyclic ether compound. Also, the cyclic ether compound may be added in an amount of 1 to 100 parts by weight based on 100 parts by weight of the acid-modified chlorinated ployolefin resin, and the cyclic ether compound may be dioxane and/or 1,3-dioxolane.
    Type: Grant
    Filed: February 17, 2004
    Date of Patent: November 27, 2007
    Assignee: Fujikura Kasei Co., Ltd.
    Inventors: Mitsuo Najima, Takashi Isogai
  • Patent number: 7294673
    Abstract: A method of modifying a polymeric material whereby the polymeric material is modified to give a highly durable surface without decreasing its strength. Namely, a polymeric material is modified by the method comprising a combination of an impregnation step, an activation step, a step of grafting a monomer and a step of a treatment with a hydrophilic polymer. Thus, the hydrophilic nature, adhesiveness, and so forth of polymeric materials such as polyolefins can be improved without causing any decrease in the practical strength. The thus obtained polymeric materials are usable in articles with a need for high water absorptivity and high adhesiveness, for example, water-absorbing materials and water-retaining materials for medical, sanitary, cosmetic articles or supplies, agricultural materials, synthetic papers, filters and fiber products for clothes, for improving adhesiveness of composite materials and the like.
    Type: Grant
    Filed: June 28, 2002
    Date of Patent: November 13, 2007
    Assignee: FiberMark Gessner GmbH & Co.
    Inventor: Hitoshi Kanazawa
  • Patent number: 7282541
    Abstract: A process for preparing a functionalized propylene-based polymer and a functionalized polymer having a propylene-based polymer backbone is disclosed. The propylene-based polymer backbone can further comprise one or more alpha olefins.
    Type: Grant
    Filed: March 30, 2006
    Date of Patent: October 16, 2007
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Jean-Roch Schauder, Abdelhadi Sahnoune, Sudhin Datta
  • Patent number: 7279528
    Abstract: Resins and oligomer materials and/or combinations thereof grafted with an unsaturated acid or anhydride, such as maleic anhydride, are disclosed herein. The grafted materials are useful in adhesive formulations, particularly in hot melt adhesive applications.
    Type: Grant
    Filed: September 19, 2002
    Date of Patent: October 9, 2007
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Anne Vera Macedo, Kenneth Lewias, John Richard Shutt
  • Patent number: 7273653
    Abstract: A resin film of a two-layer-construction comprising: (a) a resin layer R1 including a non-stretched resin film which contains a thermoplastic polyester resin containing 3 to 30 percent by weight in a weight fraction in the entire resin of a granular resin with a grain diameter of 0.1 to 5 ?m, the granular resin being a modified polyolefin resin containing 2 to 20 percent by weight of a functional group derived from carboxylic acid in terms of carboxylic acid, and (b) a polyester resin layer R0 containing at least one of polyethylene terephthalate and isophthalic acid copolymerized polyethylene terephthalate, as a basic skeleton, wherein the resin layer R1 and the resin layer R2 are laminated to each other.
    Type: Grant
    Filed: November 18, 2005
    Date of Patent: September 25, 2007
    Assignee: JFE Steel Corporation
    Inventors: Yasuhide Yoshida, Hiroki Iwasa, Hiroshi Kubo, Takeshi Suzuki, Akihiro Furuta, Keiji Sugawara, Masaaki Yamashita
  • Patent number: 7262247
    Abstract: The present invention provides a binder resin solution composition, and a coating, ink, and adhesive containing the composition as an active ingredient, the binder resin solution composition having a solid content of 10 to 50 wt. % and comprising (a) a chlorinated polyolefin prepared by chlorinating to a chlorine content of 10 to 40 wt. % an ethylene-propylene-butene ternary random copolymer having an ethylene content of 3.0 to 3.7 mol %, 1-butene content of 2.4 to 2.8 mol %, and melting point of 129 to 133° C., and (b) an organic solvent.
    Type: Grant
    Filed: June 26, 2002
    Date of Patent: August 28, 2007
    Assignees: Toyo Kasei Kogyo Company Limited, Mitsui Chemicals, Inc.
    Inventors: Kenji Kashihara, Tetsuji Nishioka, Tatsuo Tsuneka, Shoji Maekawa, Isao Wada
  • Patent number: 7256236
    Abstract: Disclosed are methods for advantageously producing maleated polypropylenes having a relatively high percentage of bound maleic anhydride, based on the total amount of maleic anhydride moieties present in the grafting reaction product, and the maleated polypropylenes produced therefrom. The methods produce maleated polypropylenes wherein at least about 60% of the maleic anhydride moieties in the grafting reaction product are bound to the polypropylene.
    Type: Grant
    Filed: May 6, 2002
    Date of Patent: August 14, 2007
    Assignee: Honeywell International Inc.
    Inventor: Scott M. Hacker
  • Patent number: 7253231
    Abstract: A novel highly grafted, multi-functional olefin copolymer is provided comprising an additive reaction product of a method comprising reacting acylating agent with an olefin copolymer having a number average molecular weight greater than about 1,000 in the presence of a free radical initiator and essentially free of hydrocarbon solvent in an extruder to provide an olefin copolymer intermediate comprising an acylated olefin copolymer having a degree of grafting (DOG) of at least 0.5 wt. %, which copolymer intermediate's molecular weight is reduced, vacuum stripped of unreacted components, pelletized, dissolved in a neutral oil (preferably with inert gas sparging), and further reacted with a polyamine to provide a grafted multi-functional olefin copolymer viscosity modifier, and lubricating oil concentrates and compositions containing the same and uses thereof.
    Type: Grant
    Filed: January 31, 2005
    Date of Patent: August 7, 2007
    Assignee: Afton Chemical Corporation
    Inventors: Cathy C. Devlin, Charles A. Passut, Joe S. Bradley, Michael A. Danylo, Yoon Song, Sanjay Srinivasan, Zhaoyao Joe Qiu, Errol Joseph Olivier, Patric Meessen, Gerhard Van Vliet, Gerardus Arnoldus Rademakers, Johannes Hendrik Geesink
  • Patent number: 7253232
    Abstract: The instant invention relates to a composition of a thermoplastic polymer and a triblock-copolymer or grafted comb copolymer, with enhanced melt flow during processing. Further aspects of the invention are the triblock-copolymers or grafted comb polymers itself, a method for their production and their use as compatibilizers and meltflow enhancing additives. Yet another aspect of the invention are functional alkoxyamines, which are useful for the preparation of the triblock-copolymers or grafted comb polymers.
    Type: Grant
    Filed: September 18, 2003
    Date of Patent: August 7, 2007
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Rudolf Pfaendner, Jochen Fink, Wiebke Wunderlich-Wippert, Andreas Kramer
  • Patent number: 7230065
    Abstract: The present invention relates to miscible blends of the polycarbonate of bisphenol A and polyesters from aromatic dicarboxylic acids, 1,4-cyclohexanedimethanol, ethylene glycol, and 2,2?-(sulfonylbis(4,1-phenyleneoxy)-bis(ethanol).
    Type: Grant
    Filed: July 12, 2005
    Date of Patent: June 12, 2007
    Assignee: Eastman Chemical Company
    Inventors: Wesley Raymond Hale, Sam Richard Turner, Gary Wayne Connell
  • Patent number: 7226985
    Abstract: Disclosed are polymer compositions comprising: (A) a first component comprising about 1 to 99 percent by weight at least one polyester (A) comprising: (1) diacid residues selected from the group consisting of terephthalic acid residues, isophthalic acid residues and mixtures thereof, and (2) diol residues selected from the group consisting of 1,4 -cyclohexanedimethanol residues, ethylene glycol residues and mixtures thereof; wherein the molar ratio of 1,4-cyclohexanedimethanol to ethylene glycol is less than 0.
    Type: Grant
    Filed: July 12, 2005
    Date of Patent: June 5, 2007
    Assignee: Eastman Chemical Company
    Inventors: Wesley Raymond Hale, David Gayle Salyer
  • Patent number: 7223804
    Abstract: A thermoplastic composition comprises polycarbonate, an impact modifier having a pH of about 3 to about 7, and a flame retardant essentially free of bromine and chlorine.
    Type: Grant
    Filed: December 30, 2003
    Date of Patent: May 29, 2007
    Assignee: General Electric Company
    Inventors: Yuxian An, Ye-Gang Lin, Rajendra Kashinath Singh
  • Patent number: 7217763
    Abstract: The present invention relates to acrylonitrile-butadiene-styrene copolymer transparent resin having superior chemical resistance and transparency and preparation thereof, and particularly to acrylonitrile-butadiene-styrene copolymer transparent resin having superior chemical resistance and transparency by graft-copolymerzing on a) conjugated diene rubber latex, b) methacrylate alkylester or acrylate alkylester compound, c) aromatic vinyl compound and d) vinyl cyanide compound, and preparation thereof. In addition, according to the present invention, chemical resistance and ESCR can be further improved by further adding e) polyester-amide copolymer to the acrylonitrile-butadiene-styrene copolymer transparent resin.
    Type: Grant
    Filed: October 24, 2002
    Date of Patent: May 15, 2007
    Assignee: LG Chem, Ltd.
    Inventors: Jeong-Su Choi, Sung-Hee Kim, Hyoung-Min Bahn, Keun-Hoon Yoo
  • Patent number: 7199187
    Abstract: A sheet excellent in mechanical performance such as folding endurance is provided. A sheet having a substrate layer using an impact-resistant styrene type resin containing 2 to 15 wt % of rubber particles having a peak at less than 2 ?m and an impact-resistant styrene type resin containing 0.2 to 10 wt % of rubber particles having a peak at 2 ?m or more in a distribution of volume-based particle diameters, or a sheet having a substrate layer comprising an impact-resistant styrene type resin (A) containing 10 to 15 wt % of rubber having a volume average particle diameter of from 0.5 ?m to 1.5 ?m and an impact-resistant styrene type resin (B) containing 5 to 10 wt % of rubber having a volume average particle diameter of from 2.0 ?m to 3.0 ?m wherein (A) is from 50 to 95 wt % and (B) is from 5 to 50 wt % on the basis of the total amount of both components, and a surface layer formed on at least its one surface, is provided.
    Type: Grant
    Filed: November 15, 2002
    Date of Patent: April 3, 2007
    Assignee: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Takeshi Miyakawa, Minoru Oda, Masafumi Hiura
  • Patent number: 7195818
    Abstract: A sealable multi-layer opaque film. In particular, a sealable multi-layer opaque film that is moisture permeable and water resistant. The sealable multi-layer opaque film is an oriented multilayer film with a core layer comprising an orientation-enhancing polymer, a polypropylene homopolymer and a beta crystal nucleator of polypropylene and at least one sealable skin layer.
    Type: Grant
    Filed: May 1, 2002
    Date of Patent: March 27, 2007
    Assignee: ExxonMobil Oil Corporation
    Inventors: Dan-Cheng Kong, Michael D. Cleckner
  • Patent number: 7186778
    Abstract: Thermoplastic molding compositions containing grafted polymers produced with different initiator systems are disclosed. The compositions are distinguished by a combination of good toughness and reduced opacity. As a result, appreciably smaller quantities of pigment are needed to color the molding composition.
    Type: Grant
    Filed: November 30, 2001
    Date of Patent: March 6, 2007
    Assignee: Bayer Aktiengesellschaft
    Inventor: Herbert Eichenauer
  • Patent number: 7175918
    Abstract: The present invention relates to polyolefin compositions that incorporate an acrylic/polyether comb-branched copolymer, articles made from the compositions, such as polyolefin films and polyolefin fibers, and methods for making the compositions and the articles.
    Type: Grant
    Filed: April 27, 2004
    Date of Patent: February 13, 2007
    Assignees: Equistar Chemicals, LP, Lyondell Chemical Technology, L.P.
    Inventors: Anil W. Saraf, Steven A. Schwartz, Edward T. Shawl, Michael Bridges, Venki Chandrashekar
  • Patent number: 7144951
    Abstract: A process is disclosed that comprises solution grafting a hydrocarbon polymer prepared from at least C2 to C28 polymerizable hydrocarbon, said polymer having a number average molecular weight in the range of from about 5,000 to about 500,000, with an ethylenically unsaturated C3 to C10 carboxylic acid material, using a free radical initiator, in the presence of an aromatic ester oil of the formula (I) wherein R1, R2, R3, R4, R5, and R6 are independently selected from the group consisting of hydrogen, —COOR7, —COOR8, —COOR9, —COOR10, —COOR11, and —COOR12, provided that no more than 5 of R1, R2, R3, R4, R5 and R6 are hydrogen, and R7, R8, R9, R10, R11, and R12 are independently selected from the group consisting of alkyl and alkylesters
    Type: Grant
    Filed: September 14, 2001
    Date of Patent: December 5, 2006
    Assignee: Crompton Corporation
    Inventors: Karl Duyck, Theodore E. Nalesnik, Uyen Thanh Tran
  • Patent number: 7129293
    Abstract: A crosslinked polymer or polymer fine particles which can be obtained through copolymerization of at least a macromonomer having a polyethylene glycol segment, a comonomer having tertiary amine groups in its side chains and a crosslinking agent are provided. Said crosslinked polymer can be provided in the form of polymer nano- or micro-spheres; and also as conjugate nano- or micro-spheres with their core parts fixing or encapsulating metal or semiconductor ultrafine particles.
    Type: Grant
    Filed: April 23, 2003
    Date of Patent: October 31, 2006
    Assignees: Japan Science and Technology Agency, NOF Corporation
    Inventors: Kazunori Kataoka, Yukio Nagasaki, Hidenori Otsuka, Atsuhiko Ogura, Takehiko Ishii, Hisato Hayashi, Teppei Uno
  • Patent number: 7122596
    Abstract: Provided are a leather-like sheet fabricated by infiltrating an aqueous resin dispersion (A) into a fibrous substrate, which satisfies a requirement (I) that the aqueous resin dispersion, (A) comprises essentially a main resin (a) stabilized with a surfactant, a polymer (b) having a polyoxyethylene group in its side chains, and a surfactant (c), a requirement (II) that the main resin (a) comprises an urethane resin (a1) and/or an urethane-acrylic composite resin (a2), and the resin skeleton contains from 1 to 10 mmols of a carboxyl group per 100 g of the resin, a requirement (III) that the polymer (b) is obtained through polymerization of a polyoxyethylene group-having ethylenic unsaturated monomer (b1) and any other ethylenic unsaturated monomer (b2) in a ratio by mass (b1)/(b2)=60/40 to 100/0, and a requirement (IV) that the percentage, % by mass (?) of the polyoxyethylene group in the polymer (b) and the number of mols (?) of the amino group per gram of the polymer (b) satisfy 35??+?×20000?60; and an indus
    Type: Grant
    Filed: August 5, 2003
    Date of Patent: October 17, 2006
    Assignee: Kuraray Co., Ltd.
    Inventors: Mitsuru Kato, Kimio Nakayama, Nobuo Takaoka
  • Patent number: 7119145
    Abstract: Pre-formed polymer particles are chemically modified by free radical-initiated surface graft modification. The resulting resin is specifically adapted to provide enhanced chromatographic performance throughout chromatographic separations.
    Type: Grant
    Filed: January 24, 2003
    Date of Patent: October 10, 2006
    Assignee: Phenomenex, Inc.
    Inventors: Arthur R. Dixon, Emmet E. Welch, Shahana Huq
  • Patent number: 7067587
    Abstract: A novel graft polymer useful in various uses that has a polyolefin backbone having polyolefin segments excellent in moldability can be obtained by homopolymerizing a novel polyolefin macromonomer or polymerizing the novel polyolefin macromonomer in the coexistence of other olefins depending on need, wherein the macromonomer has at the terminal of its polyolefin chain a vinyl group whose ?-position may be substituted, and the macromonomer can be efficiently obtained by a method, for example, successively carrying out i) a step of producing a polyolefin having a hydroxyl group at the terminal of the polyolefin chain and ii) a step of converting the terminal hydroxyl group of the polyolefin in chain into an acryloyl group, a methacryloyl group or a styryl group.
    Type: Grant
    Filed: August 29, 2003
    Date of Patent: June 27, 2006
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Hideyuki Kaneko, Shin-ichi Kojoh, Nobuo Kawahara, Shingo Matsuo, Tomoaki Matsugi, Junji Saito, Sadahiko Matsuura, Kazuhisa Miyazaki, Norio Kashiwa
  • Patent number: 7067196
    Abstract: A coextrusion binder and a multilayer structure containing the binding wherein the binder contains a composition comprising (I) syndiotactic polypropylene and (II) at least one polymer being: (A), a polyethylene or a copolymer of ethylene, (B), any of (B1) isotactic polypropylene homopolymer of copolymer, (B2) poly(1-butene) homo- or copolymer or (B3) polystyrene homo- or copolymer, and a blend of (A) and (B), said composition being grafted with a functional monomer such that each of I and II is at least partially grafted with said functional monomer.
    Type: Grant
    Filed: June 14, 2001
    Date of Patent: June 27, 2006
    Assignee: Arkema
    Inventors: Jean-Laurent Pradel, Patrice Robert
  • Patent number: 7060751
    Abstract: A thermoplastic molding composition comprising a graft polymer is disclosed. The graft polymer contains: a) a continuous phase containing the polymerized product of at least one vinylaromatic monomer and at least one ethylenically unsaturated nitrile monomer, and b) a disperse phase containing ethylene/?-olefin rubber that is grafted with the polymerization product of at least one vinylaromatic monomer and at least one ethylenically unsaturated nitrile monomer. The weight average molecular weight of the continuous phase is 130,000 to 275,000 g/mole and the disperse phase is characterized in that its, weight average particle size is less than 0.90 ?m. The molding composition is characterized in improved resistance to weathering.
    Type: Grant
    Filed: December 15, 2003
    Date of Patent: June 13, 2006
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gisbert Michels, Holger Warth, Pierre Vanhoorne
  • Patent number: 7049368
    Abstract: The present invention relates to a rubber modified thermoplastic resin composition comprising a discontinuous elastomeric phase dispersed in a rigid thermoplastic phase, wherein at least a portion of the rigid thermoplastic phase is grafted to the elastomeric phase, which is prepared by a method comprising the steps of: (a) polymerizing a mixture of monomers in a first stage in the presence of the elastomeric phase, at least one of which monomers is selected from the group consisting of vinyl aromatic monomers and at least one of which monomers is selected from the group consisting of monoethylenically unsaturated nitrile monomers, followed by (b) polymerizing one or more monomers in at least one subsequent stage in the presence of the elastomeric phase from (a), wherein the one or more monomers comprise at least one monomer selected from the group consisting of (C1-C12)alkyl- and aryl-(meth)acrylate monomers. The method is also provided.
    Type: Grant
    Filed: May 5, 2004
    Date of Patent: May 23, 2006
    Assignee: General Electric
    Inventors: Albin Peter Berzinis, Satish Kumar Gaggar
  • Patent number: 7045574
    Abstract: Acid anhydride denatured chlorinated polyolefin (component A) which is composed of a copolymer of propylene and ?-olefin wherein the chlorine contents is 15 to 24% by weight, denatured amount of acid anhydride is 0.6 to 2.0%, weight average molecular weight is 40000 to 120000, and acrylic denatured alkyd resin (component B) which is comprised of alkyd resin polymer part (b1) whose iodine value is 80 or more and oil length is 35 to 70, and acrylic resin polymer part (b2) whose glass-transition temperature is not less than 50° C. wherein the weight average molecular weight is 10000 to 100000, weight ratio of the alkyd part and acrylic part is in a range of from 25/75 to 75/25, are used in a range of from 80/20 to 20/80 (A/B).
    Type: Grant
    Filed: November 15, 2000
    Date of Patent: May 16, 2006
    Assignees: Nippon Bee Chemical Co., Ltd., Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Koji Funakoshi, Hiroshi Iida, Takeshi Ogawa, Takashi Yamamoto
  • Patent number: 7041733
    Abstract: It has been discovered that certain compounds serve as particle size regulators when employed together with peroxide initiators for the polymerization of vinylaromatic monomers in the presence of diene polymers. Suitable compounds that can control particle size include, but are not necessarily limited to, cobalt naphthenate, zinc naphthenate, iron octoate, calcium octoate, zinc octoate, zinc neodecanoate, potassium octoate, copper naphthenate, calcium versalate, and the like. Use of these metal carboxylates when vinylaromatic monomers are polymerized in the presence of polybutadienes and peroxide initiators results in reduced polybutadiene particles. Grafting and morphology characteristics may also be improved.
    Type: Grant
    Filed: October 23, 2003
    Date of Patent: May 9, 2006
    Assignee: Fina Technology, Inc.
    Inventors: Cyril Chevillard, Jose M. Sosa
  • Patent number: 7041734
    Abstract: A gel composition that is the combination of or reaction product of ingredients comprising a thermoplastic elastomer copolymer comprising polystyrene-b-poly(ethylene-ethylene/propylene)-b-polystyrene, a nylon-grafted elastomer, and an extender.
    Type: Grant
    Filed: May 28, 2004
    Date of Patent: May 9, 2006
    Assignee: Bridgestone Corporation
    Inventors: Xiaorong Wang, Victor J. Foltz
  • Patent number: 7030188
    Abstract: Improved multi-phase polypropylene composites are provided. The compositions are comprised of a polypropylene base resin, a non-compatible dispersed phase which can be a polymer or filler material and a propylene-ethylene copolymer grafted with a carboxylic acid or carboxylic acid derivative.
    Type: Grant
    Filed: April 1, 2004
    Date of Patent: April 18, 2006
    Assignee: Equistar Chemicals, LP
    Inventors: Maged G. Botros, Mark P. Mack, James H. Meas, Clifford C. Lee
  • Patent number: 7022763
    Abstract: A branched olefin copolymer demonstrating excellent performance in various uses, comprising a building block (A) represented by formula (1) below and a building block (B) represented by formula (2) below, obtained by e.g.
    Type: Grant
    Filed: October 9, 2003
    Date of Patent: April 4, 2006
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Tomoaki Matsugi, Nobuo Kawahara, Hideyuki Kaneko, Shingo Matsuo, Shin-ichi Kojoh, Norio Kashiwa
  • Patent number: 6982299
    Abstract: A low gloss thermoplastic molding composition comprising a grafted acrylate rubber (ASA) and a process for its preparation are disclosed. The composition contains an effective amount of a gloss-reducing agent that is the reaction product of (i) compound having two or more maleic anhydride groups per molecule and (ii) compound having two or more terminal primary amine groups per molecule. The incorporation of the gloss reducing agent in the inventive composition may be by blending the reaction product or, in the alternative, blending the reactants (i) and (ii) in the molten ASA under process conditions designed to bring about the in situ formation of the inventive gloss reducing agent.
    Type: Grant
    Filed: August 29, 2002
    Date of Patent: January 3, 2006
    Assignees: Lanxess Corporation, Bayer Aktiengesellschaft
    Inventors: Moh-Ching Oliver Chang, Allen R. Padwa, Chuan-Ju Chen, Daniel Dufour
  • Patent number: 6956083
    Abstract: Single ion conductors comprising polymer electrolytes prepared by grafting a salt compound onto a comb-branch polymer or dendrimer are disclosed having superior properties.
    Type: Grant
    Filed: May 31, 2002
    Date of Patent: October 18, 2005
    Assignee: The Regents of the University of California
    Inventors: John Borland Kerr, Shanger Wang, Yong Bong Han, Gao Liu, Jun Hou, Steven Edward Sloop
  • Patent number: 6949607
    Abstract: Thermoplastic resin compositions containing a rubber-reinforced thermoplastic resin (A) obtained by graft polymerizing a monomeric mixture (b) in the presence of a rubber-like polymer (a), and a copolymer (B) obtained by polymerizing an aromatic vinyl compound, a vinyl cyanide compound and optionally other copolymerizable monomeric compound(s), which copolymer (B) being a mixture of a copolymer (B1) having Mw of 50,000 to 110,000 and a copolymer (B2) having Mw of 115,000 to 400,000. The content of the rubber-like polymer (a) content in the rubber-reinforced thermoplastic resin (A) is 10 to 25% by weight, the vinyl cyanide monomeric unit in the acetone soluble matter is 15 to 40% by weight, and the ratios of Mw to Mn and MZ to Mn of the acetone soluble matter being 2 to 5 and 5 to 11, respectively.
    Type: Grant
    Filed: May 13, 2003
    Date of Patent: September 27, 2005
    Assignee: Techno Polymer Co., Ltd.
    Inventors: Tadashi Nagahara, Masanori Suzuki, Kazuki Iwai
  • Patent number: 6939923
    Abstract: A method for functionalizing a crosslinked polymer bead. The method comprises the steps of: (a) swelling the bead in a first solvent or solvent mixture to a volume from 200% to 310% of its volume when dry; and (b) contacting the bead with a functionalizing reagent in a second solvent or solvent mixture capable of swelling the bead to a volume from 200% to 310% of its volume when dry.
    Type: Grant
    Filed: August 7, 2003
    Date of Patent: September 6, 2005
    Assignee: Rohm and Haas Company
    Inventors: James Charles Bohling, Marlin Kenneth Kinzey, John Joseph Maikner, William Joseph Zabrodski
  • Patent number: 6921792
    Abstract: Disclosed are a chemically modified polyolefin elastomer composition that is highly compatible with thermoplastics and useful in improving the low temperature impact strength of thermoplastics, and a method for preparing the chemically modified polyolefin elastomer composition. The elastomer composition includes a polyolefin resin and a chemically modified ethylene-?-olefin elastomer mixed with the polyolefin resin. The chemically modified ethylene-?-olefin elastomer includes an ethylene-?-olefin elastomer backbone and grafted branches from the backbone. The branches includes polymers of one or more monomers comprising an unsaturated organic compound containing at least one carbonyl group. The method of producing the composition includes mixing an ethylene-?-olefin elastomer and a polyolefin resin to provide a mixture thereof, to which added is one or more monomers having an unsaturated organic compound containing at least one carbonyl group.
    Type: Grant
    Filed: February 7, 2002
    Date of Patent: July 26, 2005
    Assignee: Kumho Polychem Co., Ltd.
    Inventors: Sang Bae Kim, Sung Su Na, Yeon Won Jeyong
  • Patent number: 6908964
    Abstract: A poly(arylene ether)-polyolefin composition is prepared by melt-blending a poly(arylene ether), a poly(alkenyl aromatic) resin, a hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene, and an unhydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene to form a first blend, and melt-blending the first blend and a polyolefin and additional hydrogenated block copolymer to form a second blend. A reinforcing filler and/or an ethylene/alpha-olefin elastomeric copolymer may, optionally, be added during formation of the second blend or in an additional step. Multiple mixing elements, low throughput, and high extruder rotations per minute may be used to achieve high energy mixing of the first and second blends. Compositions prepared by the method exhibit an improved balance of impact strength, stiffness, and heat resistance, as well as reduced variability of physical properties.
    Type: Grant
    Filed: July 10, 2003
    Date of Patent: June 21, 2005
    Assignee: General Electric
    Inventors: Adeyinka Adedeji, John C. Haylock, Robert Hossan, William Eugene Pecak, Mark Victor Vendon
  • Patent number: 6906135
    Abstract: A process for the production of a graft copolymer comprises reacting an irradiated polymer in a reaction mixture comprising a first phase and a second phase. The first phase comprises a source of at least one non-water soluble monomer and the second phase comprises water and optionally, a water miscible organic solvent. The first and second phases are substantially immiscible and non-emusifiel. A high degree on monomer conversion is achieved.
    Type: Grant
    Filed: October 17, 2001
    Date of Patent: June 14, 2005
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Kenneth Ekman, Robert Peltonen, Mats Sundell
  • Patent number: 6906134
    Abstract: The present invention relates to ABS thermoplastic resin and preparation thereof, and particularly to a process for preparing an ABS graft copolymer comprising the step of introducing to a) 40 to 80 weight parts of rubber latex comprising i) 10 to 50 weight parts of large diameter polybutadiene rubber latex having a particle diameter of 2500 to 3500 ?, gel contents of 60 to 80%, and a swelling index to 12 to 30, and ii) 50 to 90 weight parts of large diameter rubber latex having a particle diameter of 2500 to 3500 ?, gel contents of 81 to 97%, and a swelling index of 18 to 40, b) 20 to 60 weight parts of a monomer mixture of two or more kinds selected from a group consisting of aromatic vinyl compounds and vinyl cyanide compounds to prepare a graft copolymer, wherein 5 to 30 wt % of the monomer mixture is introduced as a batch and simultaneously 70 to 95 wt % of the monomer mixture is started to be continuously introduced in an emulsified state, and a thermoplastic resin composition using the same.
    Type: Grant
    Filed: October 9, 2002
    Date of Patent: June 14, 2005
    Assignee: LG Chem, Ltd.
    Inventors: Joo-Byung Chai, Chan-Hong Lee, Byung-Tae Yang, Geon-Soo Kim
  • Patent number: 6900267
    Abstract: Methods of carrying out a reactive extrusion processes are described that include combining at least one polymer, oligomer, or combination thereof, a carbon dioxide containing fluid, and at least one reactant in an extruder to form a mixture such that the carbon dioxide containing fluid comes into intimate contact with the at least one polymer, oligomer, or combination thereof and assists in a reaction between the at least one polymer, oligomer, or combination thereof and the at least one reactant, and wherein the at least one polymer, oligomer, or combination thereof is modified upon reaction with the at least one reactant.
    Type: Grant
    Filed: December 12, 2002
    Date of Patent: May 31, 2005
    Assignees: North Carolina State University, The University of North Carolina at Chapel Hill
    Inventors: Joseph Royer, Joseph M. DeSimone, George W. Roberts, Saad A. Khan
  • Patent number: 6900268
    Abstract: The invention relates to a method of grafting unsaturated carboxylic acid derivatives onto thermoplastic polymers, which comprises heating a mixture of thermoplastic polymer, unsaturated carboxylic acid or carboxylic acid derivative and a hydroxy-lamine ester having at least one structural unit of formula (I) or (I?) wherein X is hydrogen, C1-C36alkyl, C2-C36alkenyl, C2-C18alkynyl, C6-C10aryl, —O—C1-C18alkyl —O—C6-C10aryl, —NH—C1-C18alkyl, —NH—C6-C10aryl, —N(C1-C6alkyl)2; X? is a direct bond or C1-C36alkylene, C2-C36alkenylene, C2-C36alkynylene, —(C1-C6alkylene)-phenyl-(C1-C6alkylene) or a group in a processing apparatus for thermoplastic polymers, to above the softening point/melting point of the thermoplastic polymer and allowing the components of the mixture to react with one another
    Type: Grant
    Filed: May 7, 2002
    Date of Patent: May 31, 2005
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Jochen Fink, Michael Roth, Rudolf Pfaendner, Peter Nesvadba, Andreas Kramer
  • Patent number: 6894112
    Abstract: The invention relates to thermoplastic molding materials containing the following main components: A) 2 to 97.9 wt. % of at least one polyester; B) 0 to 95.9 wt. % of at least one polycarbonate; C) 1 to 80 wt. % of at least one graft polymer which is made up of c1) 40 to 80 wt. % of a graft base consisting of a rubber elastic polymer based on alkyl acrylates with 1 to 8 C-atoms in the alkyl radical and with a glass transition temperature of less than 10° C., c2) 20 to 60 wt. % of a graft support consisting of c21) 60 to 95 wt. % styrene or substituted styrenes of general formula (I), wherein R represents an alkyl radical with 1 to 8 C-atoms or a hydrogen atoms and R1 represents an alcohol radical with 1 to 8 C-atoms and the value of n is 1, 2 or 3 and c22) 5 to 40 wt. % of at least one unsaturated nitrile; D) 1 to 80 wt. % of a copolymer consisting of d1) 60 to 95 % styrene or substituted styrenes of general formula (I) or mixtures thereof and d2) 5 to 40 wt. % of at least one unsaturated nitrile; E) 0.
    Type: Grant
    Filed: November 10, 2000
    Date of Patent: May 17, 2005
    Assignee: BASF Aktiengesellschaft
    Inventors: Martin Weber, Walter Heckmann
  • Patent number: 6884844
    Abstract: A multimodal polymer particle composition containing two or more populations of polymer particles having a total rubbery weight fraction of less than 90 weight percent is provided. Also disclosed is a process for preparing multimodal polymer particle compositions that can be dried to a powder. Multimodal polymer particle dispersions are disclosed for preparing impact modifiers that can be dried to a powder. Also provided are polymeric compositions having a matrix resin component and impact modifiers prepared from multimodal polymer particles.
    Type: Grant
    Filed: December 2, 2002
    Date of Patent: April 26, 2005
    Assignee: Rohm and Haas Company
    Inventors: Raymond Gerard Hamilton, Morris Christopher Wills, Jennifer Lynn Petoff, Joseph Robert Adamo
  • Patent number: 6884850
    Abstract: Propylene ethylene copolymers with an ethylene content between 8 and 32 mole % have been grafted with maleic anhydride and a peroxide. The functionality level is higher than what is reported with polypropylene.
    Type: Grant
    Filed: October 17, 2001
    Date of Patent: April 26, 2005
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Jean-Roch H. Schauder, Sudhin Datta
  • Patent number: 6875520
    Abstract: The invention concerns a mixture comprising by weight, the total being 100%, 1 to 100% if a polyamide block copolymer consisting of a basic polyolefin chain and on an average at least a polyamide graft wherein: the grafts are fixed to the basic chain by the radicals of an unsaturated monomer (X) having a function capable of reacting with a polyamide with amine terminal, the radicals of the unsaturated monomer (X) are fixed to the basic chain by grafting or copolymerization from its double bond; 99 to 0% of a flexible polyolefin with elastic modulus in flexure less than 50 MPa at 23° C. and having a crystalline melting point ranging between 60° C. and 100° C. Said mixtures are useful for making films, tanks, geomembrane protective fabrics produced by extrusion, products obtained by calendering, thermocladding/forming, protective films for electric cables and skins using slush molding technique.
    Type: Grant
    Filed: October 8, 2001
    Date of Patent: April 5, 2005
    Assignee: Atofina
    Inventors: Francois Court, Marius Hert, Patrice Robert, Martin Baumert
  • Patent number: 6870003
    Abstract: A process for producing modified thermoplastic resin by subjecting a thermoplastic resin to a modifying reaction in a molten state, comprising performing the modifying reaction using carbon dioxide as the reaction medium, wherein carbon dioxide is used in a proportion of 2-200 parts by weight per 100 parts by weight of the thermoplastic resin, whereby the efficiency and the uniformity of the reaction can be increased to a high extent while attaining considerable decrease in the remaining amount of the unreacted components in the resulting modified thermoplastic resin without having recourse to the use of an organic reaction solvent, so that the production can be realized easily at a low cost in an efficient manner.
    Type: Grant
    Filed: February 25, 2002
    Date of Patent: March 22, 2005
    Assignee: Mitsui Chemical, Inc.
    Inventors: Shigeo Nishikawa, Haruo Inoue, Naohiro Yamada
  • Patent number: 6861472
    Abstract: A thermoplastic composition includes specified amounts of a poly(arylene ether), a homopolymer of an alkenyl aromatic monomer, a polyolefin, a hydrogenated block copolymer, and an unhydrogenated block copolymer, but the composition is substantially free of any rubber-modified poly(alkenyl aromatic) resin. The composition provides high stiffness and high impact strength and is suitable for molding a variety of articles, including automotive underhood components.
    Type: Grant
    Filed: November 1, 2001
    Date of Patent: March 1, 2005
    Assignee: General Electric Company
    Inventors: Adeyinka Adedeji, Thomas J. Hartle, John C. Haylock
  • Patent number: 6861473
    Abstract: Methods of producing macromolecular compositions and using same are provided. The method includes preparing a resin material; forming an acetyl group on the resin material; and oxidizing the acetyl group via a one-step reaction including reacting a sulfoxide and an acid with the acetyl group to form a ketoaldehyde group. The macromolecular compositions are capable of removing an effective amount of one or more constituents from a physiological solution, such as urea during dialysis therapy.
    Type: Grant
    Filed: February 28, 2003
    Date of Patent: March 1, 2005
    Assignees: Baxter International Inc., Baxter Healthcare S.A.
    Inventors: Mitchell J. Poss, Henk Blom, Alex Odufu, Robert Smakman
  • Patent number: 6861471
    Abstract: The present invention provides a coating composition for polyolefin resins, comprising a resin obtained by graft-copolymerizing at least one member selected from the group consisting of an ?,?-unsaturated carboxylic acid and an acid anhydride thereof with at least one member selected from the group consisting of polypropylene and a propylene-?-olefin copolymer, chlorinating the graft copolymer to give an acid-modified chlorinated polyolefin, linking a (meth)acrylic ester having one hydroxyl group to the polyolefin via an ester linkage, and then graft-copolymerizing (meth)acrylic acid monomers with the polyolefin; and a process for producing the composition.
    Type: Grant
    Filed: April 10, 2002
    Date of Patent: March 1, 2005
    Assignee: Toyo Kasei Kogyo Company Limited
    Inventors: Takafumi Masuda, Shoji Maekawa, Shigeru Sugiyama, Shin-ichi Akiyama