Mixing Of Solid Graft Or Graft-type Copolymer With Other Solid Polymer Wherein One Of Said Solid Polymers Is Not Derived From Ethylenic Reactants Only; Mixing Of Said Polymer Mixture With A Chemical Treating Agent; Or Mixing Of Graft Or Graft-type Copolymer With A Sicp Or Spfi; Or Processes Of Forming Or Reacting; Or The Resultant Product Of Any Of The Above Operations Patents (Class 525/63)
- With saturated 1,2-epoxy reactant containing more than one 1,2-epoxy group per mole or polymer derived therefrom; or with solid copolymer derived from at least one unsaturated 1,2-epoxy reactant wherein the epoxy reactant contains more than one 1,2-epoxy group per mole and at least one saturated reactant (Class 525/65)
- With solid polymer derived from at least one nitrogen-containing reactant wherein at least one of the reactants forming the solid polymer is saturated; or with SPFI wherein at least one of the necessary ingredients contains a nitrogen atom or with a reaction product thereof; or with nitrogen-containing SICP (Class 525/66)
- With solid polymer derived from at least one hal-C(=O)-hal, O-C(=O)-O or hal-C(=O)-O- reactant wherein at least one of the reactants forming the solid polymer is saturated; or with SPFI wherein at least one of the necessary ingredients is a hal-C(=O)-hal, O-C(=O)-O, or hal-C(=O)-O containing reactant or reaction product thereof; or with a SICP containing a hal-C(=O)- or O-C(=O)-O- group (Class 525/67)
- With solid polymer derived from at least one phenolic reactant wherein at least one of the reactants forming the solid polymer is saturated; or with SPFI wherein at least one of the necessary ingredients is a phenolic reactant or with a reaction product thereof; or with phenolic-containing SICP (Class 525/68)
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Patent number: 12030972Abstract: The present invention relates to a composition comprising an aqueous dispersion of polymeric composite microspheres comprising an aqueous dispersion of polymeric composite microspheres that comprise a polysiloxane and a polymer, as defined herein, and a suspension polymerization process for making the composition. The composition is useful for making defect free coatings with a relatively low coefficient of friction.Type: GrantFiled: May 16, 2022Date of Patent: July 9, 2024Assignees: Rohm and Haas Company, Dow Silicones CorporationInventors: Ibrahim Eryazici, Joseph Grant, Joshua M. Katzenstein, Yihan Liu, Edwin A. Nungesser, Brett L. Zimmerman
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Patent number: 11993542Abstract: Disclosed are a multifunctional cement hydration heat control material and a manufacturing method therefor. The cement hydration heat control material in is a comb polymer having three side chain structures, the three side chain structures are respectively a carboxyl group, a sugar alcohol group, and a polyether structure, and the main chain of the polymer is a carbon chain structure formed by free-radical polymerization of a double bond in a double bond compound monomer. The multifunctional cement hydration heat control material can achieve integration of cement hydration heat control performance, water reduction performance, and shrinkage reduction performance in a same molecule, can achieve control focusing on a performance by means of structural adjustment, does not need multi-component compounding during use, and is more convenient. The control material is non-toxic and water-soluble, can be made to have an appropriate concentration, and is convenient to use.Type: GrantFiled: November 14, 2019Date of Patent: May 28, 2024Assignees: SOBUTE NEW MATERIALS CO., LTD., BOTE NEW MATERIALS TAIZHOU CO., LTD., ZHENJIANG SOBUTE NEW MATERIAL CO., LTD.Inventors: Jiaping Liu, Rui Wang, Qian Tian, Wenbin Wang, Lei Li, Yujiang Wang, Hua Li, Ting Yao, Yang Chu
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Patent number: 11795310Abstract: Methods of making an environmentally acceptable shaped article. In an embodiment method comprises machining a sheet comprising crumb rubber within a polyolefin matrix into a plurality of particles to form a reground mixture; and processing the reground mixture at an elevated temperature into a mold to form said shaped article, wherein the shaped article has a substantially more evenly dispersed mixture of said crumb rubber within the matrix of said shaped article than within the matrix of said sheet or the particles of the reground mixture.Type: GrantFiled: November 23, 2017Date of Patent: October 24, 2023Assignee: MULTY HOME LIMITED PARTNERSHIPInventors: Derek Erdman, Stephen Dixon
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Patent number: 11686094Abstract: A method is provided for forming an adhered membrane roof system that meets Factory Mutual (FM) 4470/4474 standards for wind uplift. The method comprises applying a bond adhesive to a substrate on a roof to form an adhesive layer and applying a membrane directly to the adhesive layer. The bond adhesive includes a moisture-curable polymer.Type: GrantFiled: December 21, 2021Date of Patent: June 27, 2023Assignee: Holcim Technology LtdInventors: Jiansheng Tang, Joseph Carr
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Patent number: 11518881Abstract: An overmolded thermoplastic article includes a substrate portion molded from a thermoplastic resin compound and an overmold portion molded from a thermoplastic elastomer compound. The thermoplastic resin compound includes thermoplastic polymer resin. The thermoplastic elastomer compound includes thermoplastic elastomer and polysiloxane as a mold release agent, and is free of wax. The overmold portion is bonded onto the substrate portion with a peel strength at least comparable to that of an overmolded thermoplastic elastomer compound containing wax as a mold release agent instead of the polysiloxane. Undesirable effects observed with the use of wax as a mold release agent in overmolded thermoplastic elastomer compounds such as blooming and ease of scratching/marring can be reduced, while desirable properties such as silky feel of the surface of the overmold portion and good bonding of the overmold portion onto the substrate portion can be at least maintained.Type: GrantFiled: November 13, 2017Date of Patent: December 6, 2022Assignees: Avient Corporation, GLS Thermoplastic Alloys (Suzhou) Co., Ltd.Inventors: Jiren Gu, Hanxing Wei
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Patent number: 11485855Abstract: The present invention relates to a composition, preferably a polycarbonate composition, for production of a thermoplastic moulding compound, comprising or consisting of polycarbonate and/or polyestercarbonate, two different rubber-modified vinyl copolymers in a weight ratio of 20:80 to 90:10, wherein both rubber-modified vinyl copolymers contain vinyl copolymer incorporated in the rubber particles as a separate disperse phase, and wherein one of the vinyl copolymers contains at least one alkyl (meth)acrylate, and to the moulding compound itself, to the use of the composition or moulding compound for production of moulded articles, and to the moulded articles themselves.Type: GrantFiled: March 26, 2019Date of Patent: November 1, 2022Assignee: Covestro Intellectual Property GmbH & Co. KGInventor: Andreas Seidel
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Patent number: 11434358Abstract: The present invention relates to a matrix copolymer including a cellulose nanocrystal derivative, an alkyl (meth)acrylate-based monomer unit, an aromatic vinyl-based monomer unit, and a vinyl cyan-based monomer unit; a graft copolymer including a cellulose nanocrystal derivative, a conjugated diene-based polymer, an alkyl (meth)acrylate-based monomer unit, an aromatic vinyl-based monomer unit, and a vinyl cyan-based monomer unit; and a thermoplastic resin composition including at least one thereof. In accordance with the present invention, provided is a thermoplastic resin composition having improved processability, impact strength, tensile strength and chemical resistance while maintaining transparency.Type: GrantFiled: May 14, 2019Date of Patent: September 6, 2022Assignee: LG CHEM, LTD.Inventors: Hye Jeong Ok, Seok Goo Jang, Sang Hoo Park, Hyung Seop Shim, Jeong Su Choi, Keun Hoon Yoo, Won Seok Lee, Roo Da Lee, Ho Hoon Kim, Jong Ju Lee
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Patent number: 11370867Abstract: The present invention relates to a composition comprising an aqueous dispersion of polymeric composite microspheres comprising an aqueous dispersion of polymeric composite microspheres that comprise a polysiloxane and a polymer, as defined herein, and a suspension polymerization process for making the composition. The composition is useful for making defect free coatings with a relatively low coefficient of friction.Type: GrantFiled: February 5, 2020Date of Patent: June 28, 2022Assignees: Rohm and Haas Company, Dow Silicones CorporationInventors: Ibrahim Eryazici, Joseph Grant, Joshua M. Katzenstein, Yihan Liu, Edwin A. Nungesser, Brett L. Zimmerman
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Patent number: 11292233Abstract: A laminated sheet with a cover material, an adhesive cover tape, and an electronic component packaging container molded. A laminated sheet having a surface layer on both sides of a substrate layer, and the substrate layer includes 30 to 70 mass % of a component mentioned below, 70 to 30 mass % of a component mentioned below, and 0 to 30 mass % of a recycled material of the laminated sheet to the total mass of the substrate layer. The component is a rubber modified (meth)acrylic acid ester-vinyl aromatic hydrocarbon copolymer having a conjugated diene rubber component content of 5 to 15 mass %. The component is a vinyl aromatic hydrocarbon-conjugated diene block copolymer containing 15 to 30 mass % of monomeric units derived from conjugated dienes. The component is at least one polymer selected from the group consisting of a vinyl aromatic hydrocarbon polymer and a rubber modified vinyl aromatic hydrocarbon polymer.Type: GrantFiled: January 23, 2019Date of Patent: April 5, 2022Assignee: DENKA COMPANY LIMITEDInventors: Ryosuke Yanaka, Yusuke Masuda
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Patent number: 11260642Abstract: Disclosed herein are embodiments of methods that utilize dry adhesion tuning of a composite structure to adhere substrates. In some embodiments, the disclosed methods utilize dry adhesion between a composite structure and a substrate and further dynamically control the resulting dry adhesion strength through a heating step, which facilitates rigidity tuning of a core component of the composite structure and/or facilitates thermal control of the interface between the substrate and the composite structure. Also disclosed herein are array devices and other products comprising the disclosed composite structures.Type: GrantFiled: January 31, 2018Date of Patent: March 1, 2022Assignees: Board of Regents of the Nevada System of Higher Education, on behalf of the University of Nevada, Reno, The Trustees of the University of PennsylvaniaInventors: Wanliang Shan, Kevin Turner
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Patent number: 11208573Abstract: A coating composition contains: (A) 60 to 99% by weight of a urethane-based resin emulsion having film-forming ability in terms of a solid content ratio; and (B) 1 to 40% by weight of a silicone-acrylic graft copolymer resin emulsion having an average particle size of 180 nm or less in terms of a solid content ratio, wherein a weight ratio of a polyorganosiloxane represented by a specific chemical formula to an acrylic acid ester unit or a methacrylic acid ester unit is 30:70 to 99:1.Type: GrantFiled: October 1, 2019Date of Patent: December 28, 2021Assignee: NISSIN CHEMICAL INDUSTRY CO., LTD.Inventor: Kentaro Watanabe
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Patent number: 11174382Abstract: It becomes possible to produce a thermoplastic resin composition having a sea-island structure by a kneading step of kneading a thermoplastic elastomer and/or rubber material having an alkoxysilyl group, in which the alkoxysilyl group is grafted to the thermoplastic elastomer and/or rubber material, and a thermoplastic resin in a melt state in a kneading machine and a dynamic crosslinking step of adding a water component into the kneading machine, forming a silanol group by a hydrolysis reaction of the alkoxysilyl group in the thermoplastic elastomer and/or rubber material having an alkoxysilyl group and the water component in the kneading machine, and subsequently forming a siloxane bond by a condensation reaction between the silanol groups.Type: GrantFiled: March 23, 2018Date of Patent: November 16, 2021Assignee: INOAC CORPORATIONInventors: Yoshihisa Takamori, Kentaro Iwanaga
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Patent number: 11161974Abstract: Provided is a thermoplastic resin composition and a molded article excellent in balance of color developability and low-temperature impact resistance, where a polyorganosiloxane-containing graft copolymer in which a rubber (A) containing a polyorganosiloxane (A1) and a vinyl polymer (A2) is grafted with a vinyl monomer (b), wherein the vinyl polymer (A2) includes 90 to 100% by mass of a monofunctional vinyl monomer (a1) and 10 to 0% by mass of a polyfunctional vinyl monomer (a2) with respect to 100% by mass of the vinyl polymer (A2), wherein the glass transition temperature of the homopolymer of the monofunctional vinyl monomer (a1) is 0° C. or higher, and the peak of tan ? of the polyorganosiloxane-containing graft copolymer is in the range of ?125° C. to ?90° C.Type: GrantFiled: December 5, 2019Date of Patent: November 2, 2021Assignee: Mitsubishi Chemical CorporationInventors: Kenta Takemasu, Ayaka Wakita, Shinji Matsuoka, Mitsufumi Nodono, Naotaka Suenaga
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Patent number: 10731035Abstract: A thermoplastic molding composition containing A) 20 to 99.9 wt % of a thermoplastic polyamide, B) 0.1 to 40 wt % of an alkenylsuccinic acid derivative obtained by reaction of polyiso-butene (B1) having a number-average molecular weight Mn of 10,000 to 50,000 at temperatures of 180° C. to 250° C. with maleic acid or derivatives thereof (B2) in a stoichiometric ratio of at least 2 equivalents of ?,?-unsaturated mono- and dicarboxylic acid or derivatives thereof (B2) per reactive double bond in the polyisobutene (B1) for a duration of at least 15 minutes to 10 hours and up to 10 bar of positive pressure, wherein the derivatives are anhydrides, mono- or dialkyl esters, and mixed esters, and wherein the reactive double bonds are the sum total of the terminal ?- and ?-double bonds in the polyisobutene (B1), and C) 0 to 60 wt % of further additives, wherein the weight percentages for the components A) to C) sum to 100%.Type: GrantFiled: June 8, 2017Date of Patent: August 4, 2020Assignee: BASF SEInventors: Ruth Lohwasser, Natalie Beatrice Janine Herle, Rosa Corberan Roc, Axel Hust
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Patent number: 10611936Abstract: The present invention relates to a method for making low VOC construction adhesive. It could pass VOC regulation of Californian Rule 1168 SCAQMD which VOC content <70 g/L. The procedure is using solvent to dissolve petroleum resin and styrene-butadiene rubber first. Then add filler to stir properly. During production, the temperature must be controlled under 40° C. In order to make VOC content <70 g/L, we choose methyl acetate, cyclohexane, and acetone as raw materials. Methyl acetate and acetone are exempt solvent in Californian Rule 102 SCAQMD. When calculating VOC content of adhesive, methyl acetate and acetone are not included.Type: GrantFiled: March 15, 2019Date of Patent: April 7, 2020Assignee: Nan Pao Resins Chemical Co., Ltd.Inventor: Joo Sing Tan
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Patent number: 10563026Abstract: A heat-shrinkable polyester film is made from a polyester resin composition which includes an amorphous polyalkylene benzenedicarboxylate resin and a polyester elastomer resin. The polyester elastomer resin includes hard segments and soft segments, and is prepared by copolycondensation of an aromatic dicarboxylic acid and a diol component. The diol component includes a C2-C4 alkylene glycol for the hard segments and a polyethylene glycol with an average molecular weight not greater than 400 for the soft segments. The soft segments of the polyester elastomer resin are in an amount ranging from 1 part by weight to 2 parts by weight based on 100 parts by weight of the polyester resin composition.Type: GrantFiled: May 24, 2018Date of Patent: February 18, 2020Assignee: Far Eastern New Century CorporationInventors: Li-Ling Chang, Chun-Chia Hsu, Shu-Chuan Lee, Roy Wu
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Patent number: 10479885Abstract: A thermoplastic resin composition includes: a first rubber-modified vinyl graft copolymer obtained by grafting a monomer mixture including an aromatic vinyl monomer and a vinyl cyanide monomer to a diene rubber polymer; a second rubber-modified vinyl graft copolymer obtained by grafting a monomer mixture including an aromatic vinyl monomer and a vinyl cyanide monomer to an acrylate rubber polymer; a first aromatic vinyl-vinyl cyanide copolymer having a weight average molecular weight of about 250,000 g/mol to about 450,000 g/mol and including about 25 wt % to about 31 wt % of a repeat unit derived from a vinyl cyanide monomer; a second aromatic vinyl-vinyl cyanide copolymer having a weight average molecular weight of about 70,000 g/mol to about 150,000 g/mol and including about 33 wt % to about 42 wt % of a repeat unit derived from a vinyl cyanide monomer; and a third aromatic vinyl-vinyl cyanide copolymer having a weight average molecular weight of about 70,000 g/mol to about 150,000 g/mol and including abouType: GrantFiled: September 8, 2017Date of Patent: November 19, 2019Assignee: Lotte Advanced Materials Co., Ltd.Inventors: Sung Oh Eim, Young Chul Kwon
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Patent number: 10453420Abstract: This disclosure relates to a base film, a laminated structure including the same, and a display device. More specifically, this disclosure relates to a base film that includes a polymer having a cyclic olefin-based repeat unit containing exo-isomers above a specific content and a copolymer including a styrene-based repeat unit and a maleimide-based repeat unit, exhibits a high glass transition temperature and thus has excellent heat resistance, and has high light transmittance, a laminated structure including the same, and a display device.Type: GrantFiled: September 29, 2014Date of Patent: October 22, 2019Assignee: LG Chem, Ltd.Inventors: Jeong Wook Mun, Jung Woo Kim, Sung-Ho Chun, Dai Seung Choi
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Patent number: 10407522Abstract: A nanoparticle includes a copolymer comprising a vinyl-aromatic monomer and a heterocyclic monomer. The copolymer is crosslinked with a multifunctional crosslinking agent polymerizable through an addition reaction. A nanoparticle and elastomer composition is disclosed. Several methods of mixing heterocyclic and non-heterocyclic monomer nanoparticles into an elastomer are also disclosed. These methods include mixing in a multi-elements static mixer and an intermeshing mixer with venting, among others.Type: GrantFiled: August 29, 2016Date of Patent: September 10, 2019Assignee: Bridgestone CorporationInventors: William L. Hergenrother, Waruna C. B. Kiridena, James H. Pawlow, James D. Ulmer, Christopher G. Robertson, Michael Davis, Jeffrey Quinn
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Patent number: 10336894Abstract: The invention is directed to a polypropylene composition comprising (A) a propylene-based polymer, (B) talc and (C) a functionalized polypropylene grafted with an acid or acid anhydride functional group, wherein components (A) and (C) are different, wherein the amount of the talc in the composition is 0.025-4 wt % of the total composition and the amount of the functionalized polypropylene is 0.005-0.75 wt % of the total composition.Type: GrantFiled: November 26, 2015Date of Patent: July 2, 2019Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Henrica Norberta Alberta Maria Steenbakkers-Menting, Maria Soliman, Franciscus Elisabeth Jacobus Essers, Kathleen Ann Vandewiele
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Patent number: 10240036Abstract: An eco-friendly fire-retardant polymer composition, a molded article made from the composition, and a method of manufacturing the molded article. The composition includes: a thermoplastic resin containing polycarbonate; a bio-based resin containing polytrimethylene terephthalate extracted from a biomaterial; and an impact modifier containing a core-shell type elastomer.Type: GrantFiled: October 15, 2015Date of Patent: March 26, 2019Assignee: SAMSUNG ELECTRONICS CO., LTD.Inventors: Song Won Hyun, In Kim, Kyeong Pang
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Patent number: 10138364Abstract: The invention relates to a thermoplastic composition containing the components A and B and optionally the additional components C and D, the sum of which equals 100 wt. %. The molding compound consists of: a) 60 to 75 wt. % of one or more styrene copolymers A, b) 25 to 40 wt. % of one or more graft copolymers B, c) 0 to 15 wt. % of a rubber C which is different from component B, and d) 0 to 5 wt. % of one or more additives D. The composition contains 0.2 to 3.0 wt. %, based on the total weight of the components A to D, of oligomers, can be readily processed, and leads to scratch-resistant molded parts.Type: GrantFiled: January 27, 2015Date of Patent: November 27, 2018Assignee: INEOS STYROLUTION GROUP GMBHInventors: Norbert Niessner, Philipp Boeckmann, Roland Walker, Marcus Reining
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Patent number: 9034959Abstract: A polycarbonate resin composition includes: (D) about 1 to about 10 parts by weight of a silicon-based resin; (E) about 1 to about 10 parts by weight of a core-shell graft copolymer; and (F) about 1 to about 20 parts by weight of a flame retardant, with respect to about 100 parts by weight of a base resin including: (A) about 70 to about 90 wt % of a polycarbonate resin; (B) about 9 to about 25 wt % of a polysiloxane-polycarbonate copolymer; and (C) about 1 to about 10 wt % of an aromatic vinyl-based graft copolymer. The polycarbonate resin composition can have improved releaseability and external appearance, and excellent impact strength and coloring.Type: GrantFiled: June 24, 2013Date of Patent: May 19, 2015Assignee: Cheil Industries Inc.Inventors: Kyuong-Sik Chin, Jong-Tae Yoon, Seung-Shik Shin
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Patent number: 9029463Abstract: The present invention relates to a polycarbonate composition comprising polyalkyl(alkyl)acrylate having a specific molecular weight and an impact modifier, as well as to moulded bodies obtainable from these compositions. Compositions according to the present invention exhibit superior properties, in particular with respect of low-temperature strength and melt flowability.Type: GrantFiled: May 18, 2009Date of Patent: May 12, 2015Assignee: Bayer Materialsciene AGInventors: Andreas Seidel, Evgueni Avtomonov, Dieter Wittmann, Achim Feldermann
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Patent number: 9023949Abstract: Conventionally, a photocurable resin can be used for forming a soft cured product but is difficult to have thick film curability and exhibit moisture resistance. A photocurable composition containing components (A) to (D), in which a ratio of a (meth)acrylate monomer having an aromatic group in the component (C) is 30 to 100%: the component (A): an isoprene polymer having a (meth)acrylic group, the component (B): an isoprene polymer having a hydroxyl group, the component (C): at least one kind of (meth)acrylate monomers selected from a (meth)acrylate monomer having an aromatic group and an alkyl (meth)acrylate monomer, and the component (D): a hydrogenated terpene resin.Type: GrantFiled: March 6, 2014Date of Patent: May 5, 2015Assignee: Three Bond Fine Chemical Co., Ltd.Inventors: Yusuke Imai, Naoya Otsuki, Huo Chuanjia
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Publication number: 20150119526Abstract: A thermoplastic resin composition having advantages including tensile strength, sliding properties and heat resistance is obtained by blending (I) a thermoplastic resin containing N, S or Cl with (II) an acrylic-modified polyorganosiloxane obtained from emulsion/graft polymerization of a mixture comprising (i) a polyorganosiloxane, (ii) a (meth)acrylate monomer, and (iii) a copolymerizable monomer.Type: ApplicationFiled: October 30, 2014Publication date: April 30, 2015Applicant: Nissin Chemical Industry Co., Ltd.Inventors: Kentaro WATANABE, Yukihiro MASUDA
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Patent number: 8969479Abstract: The invention relates to a process for preparing a dispersion-based or hotmelt pressure-sensitive adhesive based on at least one polymer, which involves crosslinking the at least one polymer, the polymer having functional groups Y, the polymer additionally being admixed with at least one kind of functionalized particles which have at least one polymeric base unit, characterized in that the particles have a monomer as base unit, the monomer having at least one kind of functional groups Z which are not able to enter into any reaction with the functional group Y and which, by thermal energy, electromagnetic radiation, particulate radiation and/or sound energy, are converted into the group X, the crosslinking of the polymer being brought about at least in part by a reaction of the functional groups X of the particles and of the functional groups Y of the polymer, and additionally to pressure-sensitive adhesives based on at least one crosslinked polymer component, wherein the crosslinking of the polymer componentType: GrantFiled: October 23, 2008Date of Patent: March 3, 2015Assignee: tesa SEInventors: Alexander Prenzel, Jennifer Beschmann
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Publication number: 20150038634Abstract: The present invention provides a composition including at least one polymerizable liquid component having at least one rubber impact modifier; at least one polymerization initiator, and at least one polymer component.Type: ApplicationFiled: July 30, 2014Publication date: February 5, 2015Inventors: Benjamin Jiemin SUN, Camelia GHERGULESCU, Andrew YOUNG
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Patent number: 8906273Abstract: A method of making a thermoplastic composition comprises melt extruding a poly(arylene ether) powder to form a first pelletized poly(arylene ether); and melt extruding the first pelletized poly(arylene ether) to form a second pelletized poly(arylene ether), wherein the second pelletized poly(arylene ether) has a level of butyraldehyde less than the first pelletized poly(arylene ether) and the second pelletized poly(arylene ether) has a level of trimethylanisole less than the first pelletized poly(arylene ether).Type: GrantFiled: August 22, 2011Date of Patent: December 9, 2014Assignee: Sabic Global Technologies B.V.Inventors: Montgomery M. Alger, Robert Hossan, Torben P. Kempers, Geoffrey H. Riding, David J. Swanson, Michael L. Todt
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Publication number: 20140349185Abstract: A binder resin composition for secondary battery electrodes is described as containing a polymer (A) that has a structural unit represented by general formula (1) and a water-insoluble particulate polymer (B-1) and/or a water-soluble polymer (B-2) where (A), (B-1) and (B-2) are defined as described. A slurry for secondary battery electrodes contains the binder resin composition, an active material and a solvent. An electrode for secondary batteries is provided with a collector and an electrode layer that is arranged on the collector, where the electrode layer contains an active material and the binder resin composition. Alternatively, the electrode layer is obtained by applying the slurry for secondary battery electrodes to the collector, and drying the slurry thereon.Type: ApplicationFiled: January 11, 2013Publication date: November 27, 2014Applicant: MITSUBISHI RAYON CO., LTD.Inventors: Fumino Momose, Haruki Okada, Ayako Shimonaka, Mitsufumi Nodono, Daisuke Fujikawa, Hikaru Momose, Akihiro Ishii
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Publication number: 20140329920Abstract: Disclosed herein are compositions including a polycarbonate-siloxane copolymer and a silicone-based graft copolymer. The compositions may include one or more additional polymers, such as a bisphenol-A polycarbonate. The compositions may include additional components, such as anti-drip agents, and/or flame retardant salt additives. Also disclosed herein are articles including the compositions, methods of using the compositions, and processes for preparing the compositions.Type: ApplicationFiled: April 24, 2014Publication date: November 6, 2014Inventor: Niles Richard ROSENQUIST
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Publication number: 20140309371Abstract: A dynamically vulcanized alloy contains at least one isobutylene-containing elastomer, at least one thermoplastic resin, and an anhydride functionalized oligomer grafted to the thermoplastic resin. In the alloy, the elastomer is present as a dispersed phase of small vulcanized or partially vulcanized particles in a continuous phase of the thermoplastic resin and the alloy is substantially absent of any sulfonamides.Type: ApplicationFiled: November 12, 2012Publication date: October 16, 2014Inventors: Maria D. Ellul, Ronald De Young, Dennis Kumor
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Patent number: 8852747Abstract: The invention relates to coextrusion binders including renewable and/or biodegradable polymers having good adhesion properties: at least one renewable and/or biodegradable polymer (A) grafted with a functional monomer including at least one reactive function, the grafting ratio being <1% in weight of the grafted polymer (A); at least one non-grafted renewable and/or biodegradable polymer (B) identical to (A) or compatible with (A) optionally a softener (C); and optionally a starch-based material (D). The invention also relates to multilayered structures including the binder of the present invention, in which the layers are preferably made of renewable and/or biodegradable compounds. The multilayered structures are advantageously useful in the field of food packaging.Type: GrantFiled: May 14, 2008Date of Patent: October 7, 2014Assignee: Arkema FranceInventors: Fabrice Chopinez, Johann Laffargue, Jeau-Laurent Pradel, Damien Rauline, Samuel Devisme
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Patent number: 8759437Abstract: In a composite component assembled from at least one component piece comprising a polyamide molding composition with at least one component piece comprising a vulcanized elastomer, the polyamide molding composition comprises at least 40% by weight of a mixture of the following constituents: a) 60 to 99 parts by weight of polyamide and b) 1 to 40 parts by weight of a graft copolymer obtainable using the following monomers: a) 0.5% to 25% by weight, based on the graft copolymer, of a polyamine having at least 4 nitrogen atoms and also ?) 75% to 99.5% by weight, based on the graft copolymer, of polyamide-forming monomers selected from lactams, ?-amino carboxylic acids and/or equimolar combinations of diamine and dicarboxylic acid, wherein the parts by weight of a) and b) sum to 100. The presence of the graft copolymer effectuates improved adherence between the component pieces.Type: GrantFiled: May 3, 2011Date of Patent: June 24, 2014Assignee: Evonik Degussa GmbHInventors: Andreas Pawlik, Harald Haeger
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Patent number: 8703293Abstract: Provided herein re a composition and a coating or a device (e.g., absorbable stent) that includes a PEGylated hyaluronic acid and a PEGylated non-hyaluronic acid biocompatible polymer and the methods of use thereof.Type: GrantFiled: April 1, 2010Date of Patent: April 22, 2014Assignee: Advanced Cardiovascular Systems, Inc.Inventors: Lothar W. Kleiner, Connie S. Kwok
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Patent number: 8703869Abstract: The invention relates to impact-modified polycarbonate compositions which are distinguished by high heat resistance and good melt flow behavior. In addition, the moldings produced from the compositions according to the invention in an injection-molding process can be metallised, the resulting metallised moldings having a surface with a particularly high and, in particular, homogeneous gloss. The invention thus also provides the metallised moldings produced from the compositions according to the invention.Type: GrantFiled: March 23, 2010Date of Patent: April 22, 2014Assignee: Bayer Materialscience AGInventors: Andreas Seidel, Eckhard Wenz, Hans-Jü{umlaut over ( )}rgen Klankers
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Patent number: 8697245Abstract: A biodegradable injection mouldable polymer composition including on a dry weight basis from 45-85% w/w by weight of a starch and/or a modified high amylose starch, from 2-15% w/w by weight of a water soluble polymer preferably selected from polyvinyl alcohol, polyvinyl acetate and copolymers of ethylene and vinyl alcohol which have a melting point compatible with the molten state of the starch components, and from 5-45% w/w by weight of one or more polyol plasticizers having a molecular weight in the range of 50-6000, more preferably 50-2500, and still more preferably 100-400 and preferably selected from the group consisting of sorbitol, glycerol, maltitol, xylitol, mannitol, erythritol, polyglycerol, glycerol trioleate, tributyl citrate, acetyl tri-ethyl citrate, glyceryl triacetate, 2,2,4-trimethyl-1,3-pentanediol diisobutyrate, polyethylene oxide, ethylene glycol, diethylene glycol or polyethylene glycol; more preferably glycerol, maltitol, sorbitol, erythritol and xylitol.Type: GrantFiled: August 6, 2007Date of Patent: April 15, 2014Assignee: Plantic Technologies Ltd.Inventors: Kishan Khemani, Nicholas John McCaffrey, Rulande Henderson
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Patent number: 8686092Abstract: A series of resins were synthesized using a range of bio-based materials to control the molecular architecture, and therefore the properties, of the inventive resins. The utility of these resins was demonstrated in the formulation of powder coatings, such as ?-hydroxy amide crosslinked and hybrid types. Generally, the bio-based resins flowed out on heating faster than conventional petrochemically-based resins, allowing the use of lower temperatures in the curing oven than is typically possible and a more active catalyst system, especially in the carboxylic acid-epoxy crosslinked hybrid coating formulations.Type: GrantFiled: January 26, 2012Date of Patent: April 1, 2014Assignee: Battelle Memorial InstituteInventors: Bhima R. Vijayendran, Jerry L. King, II, Katherine P. Mitchell, Michael C. Clingerman, Jeffrey T. Cafmeyer
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Patent number: 8618214Abstract: Provided is a fiber-reinforced composite. The composite has a propylene polymer including 90 wt % or more of propylene monomeric units based on the weight of the propylene polymer; a plurality of fibers of a solid, flexible material grafted to the propylene polymer; and an elastomer. The fibers are present in the composite at 10 wt % to 80 wt % based on the total weight of the composite. The propylene polymer is present in the composite at from 30 wt % to 95 wt % based on the total weight of the composite. The elastomer is present in the composite at from 5 wt % to 50 wt % based on the total weight of the composite. Greater than 50 wt % of the fibers are dispersed within the propylene polymer based on the total weight of the fibers in the composite. There is also provided a process for making a fiber-reinforced composite.Type: GrantFiled: December 17, 2010Date of Patent: December 31, 2013Assignee: ExxonMobil Research and Engineering CompanyInventors: Andy Haishung Tsou, John Henry Dunsmuir, Donald Andrew Winesett
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Publication number: 20130338311Abstract: A variety of molded bodies having high weatherability, impact resistance, designability, and the like, and a polyorganosiloxane latex and a graft copolymer used as the raw material therefor are provided. A polyorganosiloxane latex having a mass average particle diameter (Dw) of a polyorganosiloxane particle of 100 to 200 nm, and a ratio of the mass average particle diameter (Dw) to a number average particle diameter (Dn) (Dw/Dn) of 1.0 to 1.7. A polyorganosiloxane-containing vinyl-based copolymer (g) obtained by polymerizing one or more vinyl-based monomers in the presence of the latex. A graft copolymer (G) obtained by graft polymerizing one or more vinyl-based monomers in the presence of the copolymer. A thermoplastic resin composition including the graft copolymer (Ga) and a thermoplastic resin (Ha) except for the graft copolymer (Ga). A molded body obtained by molding the resin composition. A lamp housing for vehicle lighting including the molded body obtained by molding the composition.Type: ApplicationFiled: February 9, 2012Publication date: December 19, 2013Applicants: UMG ABS, LTD., MITSUBISHI RAYON CO., LTD.Inventors: Ayaka Wakita, Toshihiro Kasai, Hidemichi Kouno, Shigenari Takeda
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Patent number: 8575268Abstract: Disclosed is a thermoplastic resin composition containing a graft material and an organic peroxide group dispersion medium in which the graft material is dispersed. The graft material is obtained by melt-mixing a metal oxide fine particle having an organic peroxide group on the surface and a thermoplastic resin, and has a structure in which the thermoplastic resin is grafted to the metal oxide fine particle. The organic peroxide group on the surface of the metal oxide fine particle is preferably a peroxymonocarbonate group. The organic peroxide group on the surface of the metal oxide fine particle is preferably obtained by reacting a hydroxy group of a silicon oxide fine particle with an amino-modified silane coupling agent, thereby introducing an amino group to the surface of the silicon oxide fine particle, and then reacting the amino group with a compound having an ethylenically unsaturated group and an organic peroxide group.Type: GrantFiled: August 26, 2008Date of Patent: November 5, 2013Assignee: NOF CorporationInventors: Masumi Takamura, Kazuaki Mima
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Publication number: 20130289208Abstract: A monovinylaromatic polymer composition can include a bio-sourced polymer dispersed phase and optionally a rubber dispersed phase. The bio-sourced polymer dispersed phase can be predominantly made of particles having a size of less than 10 ?m. The monovinylaromatic polymer composition can be made by admixing a monovinylaromatic monomer, bio-sourced polymer, and optionally rubber at conditions effective to polymerize at least a part of the monovinylaromatic monomer and generate a compatibilizer. The monovinylaromatic polymer composition can be made by admixing a monovinylaromatic monomer, functionalized bio-sourced polymer(s) or mixtures of bio-sourced polymer(s) and functionalized bio-sourced polymer(s), and optionally rubber at conditions effective to polymerize at least a part of the monovinylaromatic monomer.Type: ApplicationFiled: March 20, 2013Publication date: October 31, 2013Applicant: Total Petrochemicals FranceInventor: Michel Duc
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Patent number: 8569415Abstract: There is provided a resin which, in spite of having excellent impact resistance because of containing a rubber ingredient, can be molded into a haze-free and beautiful state across the entire surface of molded products even if the molded products are large-sized injection molded products, and is suitable for molded products on which a vapor deposition layer is formed by the direct vapor deposition method, and is suitable for molded products which are joined by the hot plate welding method, particularly molded products such as housing members of automotive lamps, which require weatherability. Also provided is a graft copolymer (B) obtained by polymerizing a (meth)acrylate monomer (b1) a homopolymer of which has a glass transition temperature exceeding 0° C. in the presence of a composite rubber (A) containing a polyorganosiloxane (A1) and a poly(meth)acrylate (A2), and then polymerizing an aromatic vinyl monomer (b2) and a cyanided vinyl monomer (b3).Type: GrantFiled: July 10, 2008Date of Patent: October 29, 2013Assignees: Mitsubishi Rayon Co., Ltd., Techno Polymer Co., Ltd.Inventors: Tsuneki Wakita, Toshihiro Kasai, Masaki Maeda, Yasunobu Kaneko
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Patent number: 8552112Abstract: The present invention provides a weather resistant thermoplastic resin with low gloss and a method of preparing the same. The thermoplastic resin of the present invention comprises a (meth)acrylic acid alkyl ester-based polymer (A) and a (meth)acrylic acid alkyl ester-based oligomeric prepolymer (B), and an aromatic vinyl-cyanide vinyl based copolymer (C), wherein the (meth)acrylic acid alkyl ester-based polymer (A) and the (meth)acrylic acid alkyl ester-based oligomeric prepolymer (B) form a network-shaped disperse phase and the aromatic vinyl-cyanide vinyl based copolymer (C) forms a continuous phase.Type: GrantFiled: December 29, 2010Date of Patent: October 8, 2013Assignee: Cheil Industries Inc.Inventors: So Young Kwon, Young Sub Jin, Sung Kwan Kim, Byeong Do Lee
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Patent number: 8545971Abstract: A multi-component article comprising a first component comprising a biodegradable polymer, and a second component comprising a polyolefin and a reactive modifier. A method of preparing a multi-layer film comprising coextruding first and second film layers, wherein the first layer comprises a polylactic acid and the second layer comprises a polyolefin and an epoxy-functionalized polyolefin. A method of preparing a multi-component fiber comprising coextruding a core component and a sheath component, wherein the core component comprises a polyolefin and an epoxy-functionalized polyolefin and the sheath component comprises a polylactic acid.Type: GrantFiled: June 30, 2008Date of Patent: October 1, 2013Assignee: Fina Technology, Inc.Inventors: Fengkui Li, Tim J. Coffy, Michel Daumerie
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Patent number: 8481645Abstract: A stabilizer polymer and coating compositions containing the stabilizer polymer are provided. The stabilizer polymer preferably includes a polyester backbone and a plurality of carbon-carbon double bonds. A coating composition is provided that preferably includes the stabilizer polymer, an acrylic component, and a thermoplastic dispersion. In a preferred embodiment, the acrylic component is included in the stabilizer polymer.Type: GrantFiled: March 31, 2008Date of Patent: July 9, 2013Assignee: Valspar Sourcing, Inc.Inventors: Nicolas Payot, Georges Sion, Benoit Prouvost, Paul Stenson
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Patent number: 8466233Abstract: A polylactic acid-based resin composition including a polylactic acid (A), a multilayered polymer (B) and a multilayered polymer (C), wherein the content of each of the multilayered polymer (B) and the multilayered polymer (C) is 0.5 to 8% by mass of the whole resin composition; the multilayered polymer (B) and the multilayered polymer (C) are each constituted of a core layer(s) and a shell layer(s); the core layer constituting the multilayered polymer (B) contains an acrylic rubber; and the core layer constituting the multilayered polymer (C) contains a composite rubber containing an acrylic component and a silicone component.Type: GrantFiled: November 29, 2010Date of Patent: June 18, 2013Assignee: Unitika Ltd.Inventors: Keisuke Kimura, Kazue Ueda
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Patent number: 8466214Abstract: Processes for making a core and core-shell copolymers are provided herein. Processes for making crosslinked elastomeric core particles includes emulsion polymerizing, in the presence of a radical polymerization initiator, a polymerization mixture containing at least one ethylenic elastomeric monomer, at least one crosslinking agent, and at least one sulfur-containing additive of the formula I below, where R and Z are defined herein. The core-shell copolymers formed are useful for example as additives in polymer matrices such as for modifying impact strength and improving optical properties.Type: GrantFiled: August 4, 2009Date of Patent: June 18, 2013Assignee: Arkema FranceInventors: Rosangela Pirri, Philippe Hajji
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Patent number: 8445581Abstract: The present invention provides a biocompatible prepolymer comprising hydrophilic and hydrophobic segments, wherein the hydrophobic segments have at least one ethylenically unsaturated functional group and at least 5% of the segments have two or more ethylenically unsaturated functional groups and water. The invention further provides a biocompatible prepolymer composition comprising hydrophilic and hydrophobic prepolymers, wherein at least one of the hydrophobic prepolymers has at least one ethylenically unsaturated functional group and at least 5% of the prepolymers have two or more ethylenically unsaturated functional groups and water. The invention further provides use of the prepolymer or prepolymer compositions of the invention in biomedical applications such as tissue engineering, as bone substitutes or scaffolds, and in wound treatment.Type: GrantFiled: August 2, 2007Date of Patent: May 21, 2013Assignee: Polynovo Biomaterials Pty LimitedInventors: Pathiraja Arachchillage Gunatillake, Roshan Tyrrel Anton Mayadunne, Raju Adhikari, Heng Chy Taing, Tam Phuong Thi Le, Jerome Anthony Werkmeister, John Alan Maurice Ramshaw, Jacinta Frances White, Tracy Ann Tebb
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Publication number: 20130102731Abstract: Grafted compounds are formed by reacting (1) a first compound having both an aziridinyl group and a polymeric group with (2) a second compound having at least one acidic group. This reaction results in the opening of the aziridinyl ring on the first compound by the acidic group on the second compound and the formation of an attachment group that connects polymeric group of the first compound to the second compound. In some embodiments, the second compound is a polymeric material having multiple acidic groups and the product of the reaction of the first compound with the second compound results in the formation of a grafted copolymer.Type: ApplicationFiled: May 19, 2011Publication date: April 25, 2013Applicant: 3M INNOVATIVE PROPERTIES COMPANYInventors: Jason D. Clapper, Kevin M. Lewandowski, Mark F. Ellis, Craig E. Hamer