Contains Two Or More Graft Or Graft-type Copolymers Or A Graft Or A Graft Type Copolymer And At Least One Block Or Block-type Copolymer Patents (Class 525/71)
-
Patent number: 6100345Abstract: The present invention provides a thermally resistant resin composition containing PS and PPO, wherein at least one of PS and PPO has an acid group and the acid group is neutralized with a basic metal compound containing a metal element of the group 2B, 3B, 4B or 5B of the periodic table; thermally resistant PS and PPO each with an acid group which is also neutralized in the same manner as described above; and a method for miscible preparation of PS and PPO, wherein at least one of PS and PPO has an acid group and the acid group is neutralized similarly.Type: GrantFiled: October 29, 1998Date of Patent: August 8, 2000Assignee: Sony CorporationInventors: Yasuhito Inagaki, Tsutomu Noguchi, Hidemi Tomita
-
Patent number: 6096829Abstract: Disclosed is a syndiotactic, polystyrenic resin composition comprising (A) 100 parts by weight of a component composed of (a) from 10 to 98% by weight of a styrene-based polymer having a syndiotactic configuration and (b) from 2 to 90% by weight of a polyolefin, (B) from 0.5 to 50 parts by weight of a styrene-olefin copolymer having a styrene content of from 40 to 85% by weight, (E) from 0 to 200 parts by weight, relative to 100 parts by weight of the component (b) of (A), of at least one selected from paraffinic oils, paraffinic waxes, mineral oils and siloxanic oils. The composition can be formed into articles having good heat resistance, a high modulus of elasticity and good toughness. In addition, the articles are advantageous in that their surface layers are hardly peeled.Type: GrantFiled: August 20, 1999Date of Patent: August 1, 2000Assignee: Idemitsu Petrochemical Co., Ltd.Inventors: Shinji Chino, Akihiko Okada, Nobuyuki Satoh
-
Patent number: 6093772Abstract: An immiscible polymer system is disclosed, said system itself ecomprising a stable mixture of polymers that are individually miscible with the polymers to be compatibilized. The compositions consisting of this polymer mixture may be obtained by extrusion.Type: GrantFiled: January 29, 1998Date of Patent: July 25, 2000Assignee: Elf Atochem S.A.Inventor: Philippe Bussi
-
Patent number: 6080815Abstract: The present invention relates to a process for producing a thermoplastic resin having high impact strength and good surface gloss, which comprises graft copolymerizing at least a vinyl cyanide compound and at least an aromatic vinyl compound for a short period of less than about 3 hours in the presence of rubber latex having high gel content. The rubber latex can be a mixture of two or more rubber latices having different particle size. The graft copolymer has the characteristics such that the degree of the inner occlusion into the resin is decreased and the degree of surface grafting is increased. Thereby, the resulted thermoplastic resin has a very high impact strength and good surface gloss, and the processability is greatly improved. In addition, when the graft copolymer is polymerized the level of coagulum formation is greatly decreased.Type: GrantFiled: June 10, 1998Date of Patent: June 27, 2000Assignee: LG Chemical LimitedInventors: Chang-Hong Lee, Young-Min Kim, Jin-Nyoung Yoo
-
Patent number: 6077907Abstract: Molded polyolefin articles of improved dimensional stability at elevated temperatures and improved stiffness and consist of mixtures of modified propylene polymers, which are synthesized by free radical coupling reactions or polymer-like reactions of functionalized polypropenes, and of unmodified propylene polymers, crystalline copolymers of propylene and .alpha.-olefins, elastic copolymers of ethylene and .alpha.-olefins, largely amorphous polypropylenes, non-isotactic propylene homopolymers, and auxiliary materials.The molded polyolefin articles, produced by blow molding or injection molding are suitable for use in the packaging industry, for use in the domestic appliances industry, to meet the requirements of laboratories and hospitals, for gardening and agricultural implements, for transporting containers for components in the automobile industry, and for components of machines and of electric and electronic equipment.Type: GrantFiled: June 18, 1998Date of Patent: June 20, 2000Assignee: Borealis AGInventors: Manfred Raetzsch, Achim Hesse, Norbert Reichelt, Ulf Panzer, Markus Gahleitner, Max Wachholder, Karl Kloimstein
-
Patent number: 6072002Abstract: A thermoplastic molding composition which features improved impact and flow properties as well as reduced opacity is disclosed. The composition contains(A) 15 to 50 percent of a grafted rubber which contains (a) a crosslinked rubber substrate which contains, as a core, about 1 to 25% relative to its weight of at least one vinylaromatic polymer, and (b) a grafted phase, and(B) 85 to 50 percent of a copolymeric matrix.The composition, which contains no additional grafted rubber components, is also characterized in that (i) the substrate amounts to 60 to 90 percent, and grafted phase amounts to 40 to 10 percent, relative to the weight of the grafted rubber and that (ii) the grafted rubber has a monomodal size distribution and that (iii) the grafted rubber has a weight average particle size of about 0.2 to 1.0 microns.Type: GrantFiled: October 21, 1997Date of Patent: June 6, 2000Assignee: Bayer CorporationInventors: Moh Ching Oliver Chang, Richard M. Auclair
-
Patent number: 6069202Abstract: Desirable thermoplastic vulcanizates can be prepared from a polar engineering thermoplastic; a halogenated copolymer of p-alkylstyrene and an isomonoolefin having from 4 to 7 carbon atoms; and either an ethylene rubbery polymer or a diene based rubbery polymer or combinations thereof. The ethylene rubbery polymer desirably has at least one pendant carboxylic acid group, amine group, epoxy group, hydroxyl group or an anhydride of two carboxylic acid groups or combinations thereof. Desirable diene based rubbery polymers include epoxidized natural rubber and epoxidized homopolymers and copolymers of dienes.Type: GrantFiled: December 10, 1997Date of Patent: May 30, 2000Assignee: Advanced Elastomer Systems, L.P.Inventors: Krishna Venkataswamy, Jacques Horrion
-
Patent number: 6063868Abstract: The use of a thermoplastic molding composition differing from ABS and comprising, based on a total of 100% by weight of amounts of components A and B, and, if desired, C and/or D,a: as component A, from 1 to 99% by weight, preferably from 15 to 60% by weight, in particular from 25 to 50% by weight, of a particulate emulsion polymer with a glass transition temperature of below 0.degree. C. and with a median particle size of from 50 to 1000 nm, preferably from 50 to 500 nmb: as component B, from 1 to 99% by weight, preferably from 40 to 85% by weight, in particular from 50 to 75% by weight, of at least one amorphous or partly crystalline polymer,c: as component C, from 0 to 50% by weight of polycarbonates, andd: as component D, from 0 to 50% by weight of fibrous or particulate fillers or mixtures of thesefor producing housings for security equipment.Type: GrantFiled: January 22, 1999Date of Patent: May 16, 2000Assignee: BASF AktiengesellschaftInventors: Herbert Naarmann, Graham Edmund McKee, Alfred Pirker, Hans-Josef Sterzel, Franz Brandstetter, Bernd-Steffen von Bernstorff, Bernhard Rosenau, Ulrich Endemann, Burkhard Straube
-
Patent number: 6063867Abstract: The present invention provides a method for creating durable blends of polystyrene and polyolefin. The blends of the present invention have improved mechanical properties evidenced by measurement of impact strength, tensile strength, and elongation at break. Polyolefin is first crosslinked by creating a melt of polyolefin and a small amount of peroxide in a mixer at elevated temperature. The crosslinked polyolefin is then melt-blended with polystyrene at elevated temperature. Finally, a styrene-butadiene-styrene block copolymer is mixed into the melt. The method of the present invention can be applied to various blend systems of otherwise incompatible polymers provided it contains at least one component and a compatibilizer that are crosslinkable.Type: GrantFiled: February 12, 1998Date of Patent: May 16, 2000Assignee: The Hong Kong University of Science & TechnologyInventors: Zhi Wang, Chi-Ming Chan, Jiarui Shen
-
Patent number: 6063854Abstract: The use of a thermoplastic molding composition differing from ABS and comprising, based on a total of 100% by weight of amounts of components A and B, and, if desired, C and/or D,a: as component A, from 1 to 99% by weight, preferably from 15 to 60% by weight, in particular from 25 to 50% by weight, of a particulate emulsion polymer with a glass transition temperature of below 0.degree. C. and with a median particle size of from 50 to 1000 nm, preferably from 50 to 500 nmb: as component B, from 1 to 99% by weight, preferably from 40 to 85% by weight, in particular from 50 to 75% by weight, of at least one amorphous or partly crystalline polymer,c: as component C, from 0 to 50% by weight of polycarbonates, andd: as component D, from 0 to 50% by weight of fibrous or particulate fillers or mixtures of thesefor producing moldings for sanitary and bathroom fittings.Type: GrantFiled: January 25, 1999Date of Patent: May 16, 2000Assignee: BASF AktiengesellschaftInventors: Herbert Naarmann, Graham Edmund Mc Kee, Alfred Pirker, Hans-Josef Sterzel, Franz Brandstetter, Bernd-Steffen von Bernstorff, Bernhard Rosenau, Ulrich Endemann, Burkhard Straube
-
Patent number: 6057384Abstract: Ink-jet inks for ink-jet printing are provided which include a vehicle and a colorant, the colorant associated with a primer core/shell polymer to form a primer/colorant combination, and the primer/colorant combination, upon printing on a print medium, encapsulated by a durable core/shell polymer. The primer core/shell polymer serves to promote adhesion of the durable core/shell polymer to the colorant and to disperse the colorant in the ink and the durable core/shell polymer serves to provide a smear-fast film upon drying of the ink on a print medium. The primer core/shell polymer comprises a hydrophobic core and a hydrophilic shell comprising a polar component, while the durable core/shell polymer comprises a hydrophobic core comprising a first T.sub.g component, which, when homopolymerized, has a glass trnnsition temperature, T.sub.g, between -150.degree. C. to +25.degree. C. and a second T.sub.g component, which, when homopolymerized, has a glass transition temperature above +25.degree. C.Type: GrantFiled: July 21, 1998Date of Patent: May 2, 2000Assignee: Hewlett-Packard CompanyInventors: Khe C Nguyen, Sivapackia Ganapathiappan
-
Patent number: 6054532Abstract: The present invention teaches a method for enabling the formation of a high damping, soft polymer gel. The method includes: reacting a poly(alkenyl benzene-co-maleimide) polymer with a maleated polyalkylene and a maleated hydrogenated block copolymer and an alkyl diamine grafting agent under substantially dry conditions sufficient to form a hydrogenated block copolymer-polyalkylene grafted poly(alkenyl benzene-co-maleimide) polymer product; and, dispersing the hydrogenated block copolymer-polyalkylene grafted poly(alkenyl benzene-co-maleimide) polymer product with an extender oil sufficient to form the gel. The present invention also contemplates a polymer gel composition, a polymer composition and an article manufactured from the polymer gel composition.Type: GrantFiled: May 6, 1998Date of Patent: April 25, 2000Assignee: Bridgestone CorporationInventors: Xiaorong Wang, Victor J. Foltz, James E. Hall, Hideo Takeichi, Takahiro Matsuse, Naruhiko Mashita, Shinichi Toyosawa
-
Patent number: 6051650Abstract: A rubber-reinforced thermoplastic resin composition is disclosed. The rubber-reinforced thermoplastic resin composition comprises a thermoplastic resin matrix having dispersed therein particles of a graft polymer, the particles of a graft polymer comprising particles of a rubber polymer having emulsion-graft-polymerized to the surface thereof two or more kinds of vinyl compounds copolymirizable with the rubber polymer, wherein the surface graft coverage of the vinyl compounds graft-polymerized to the surface of the particles of a rubber polymer as determined by equation (m1) is 80% or more and the average thickness of the vinyl compounds graft-polymerized to the surface of the particles of a rubber polymer is from 5 to 25 nm:Surface graft coverage (%)=(s2/s1).times.Type: GrantFiled: March 17, 1998Date of Patent: April 18, 2000Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Shigeru Endo, Makiko Nagao, Toshinori Yamanaka
-
Patent number: 6051651Abstract: The invention relates to a chlorofluorocarbon resistant resin composition characterized by comprising an agglomerated graft polymer (Y) occurring in clusters having a weight average particle diameter of 0.8-2.0 .mu.m as formed from a small particle diameter graft polymer (y) obtained in a grafting degree of 10-40 weight % by polymerizing 60-20 weight % of a monomer mixture comprising 30-45 weight % of a vinyl cyanide compound and 70-55 weight % of an aromatic vinyl compound in the presence of 40-80 weight % of a rubber like polymer having a weight average particle diameter of 0.05-0.2 .mu.m and a copolymer (Z) obtained by polymerizing 35-45 weight % of a vinyl cyanide compound with 65-55 weight % of an aromatic vinyl compound and having an intrinsic viscosity of 0.6-0.9, the rubber like polymer accounting for 15-25 weight % of the total composition. The resin composition of the invention is superior to the conventional resin composition in chlorofluorocarbon resistance.Type: GrantFiled: July 2, 1998Date of Patent: April 18, 2000Assignee: Nippon A&L Inc.Inventors: Osamu Nakajima, Michio Hoshikawa, Tetsuya Yamamoto, Hiromichi Aoki, Hiroshi Kojima
-
Patent number: 6048610Abstract: A primer coating composition for use in polyolefin-backed pressure sensitive tape comprising a maleic anhydride modified chlorinated polyolefin covalently bonded to a maleic anhydride modified A-B-A block copolymer, where A is a thermoplastic polystyrene and B is a rubber midblock, by means of a crosslinking agent capable of reacting with the maleic anhydride functional groups in said polyolefin and said block copolymer a polyolefin-backed pressure sensitive tape employing the primer coating composition; and a method for manufacturing a polyolefin-backed pressure sensitive tape employing the primer coating composition are described.Type: GrantFiled: October 31, 1997Date of Patent: April 11, 2000Assignee: Intertape Polymer Group, Inc.Inventors: Richard St. Coeur, William E. Hatfield, John Tynan
-
Patent number: 6048930Abstract: The present invention teaches a method for enabling the formation of a high damping compound. The method includes: reacting a poly(alkenyl benzene-co-maleimide) polymer with a maleated polyalkylene and an alkyl diamine under substantially dry conditions sufficient to form a polyalkylene grafted poly(alkenyl benzene-co-maleimide) polymer product; and, dispersing the polyalkylene grafted poly(alkenyl benzene-co-maleimide) polymer product within a rubber formulation to form a relatively high damping compound. The present invention also contemplates a rubber compound composition and an article manufactured from the composition.Type: GrantFiled: May 6, 1998Date of Patent: April 11, 2000Assignee: Bridgestone CorporationInventors: Xiaorong Wang, Victor J. Foltz
-
Patent number: 6046273Abstract: The thermal stability of alpha-substituted acrylate graft copolymers can be improved by (a) making a graft copolymer comprising a backbone of a propylene polymer material having graft polymerized thereto monomers comprising (i) a 1-3 C alkyl-substituted acrylic acid and (ii) an ester of a 1-3 C alkyl-substituted acrylic acid, wherein the total amount of polymerized monomers is about 20 to about 240 parts per hundred parts of the propylene polymer material and the amount of (i) is about 1 to about 20%, based on the total weight of monomers, and (b) removing any unreacted grafting monomer from the resulting grafted propylene polymer material, decomposing any unreacted initiator, and deactivating any residual free radicals in the material.Type: GrantFiled: February 27, 1998Date of Patent: April 4, 2000Assignee: Montell North America Inc.Inventor: Abuzar Syed
-
Patent number: 6043315Abstract: A functionalized copolymer of the formulaA--B--Z--XwhereA is a block of vinylaromatic monomers of 8 to 20, preferably 8 to 12, carbon atoms,B is a block of alkadiene monomers of 4 to 12, preferably 4 to 8, carbon atoms,Z is a fundamental building block of a compound having sterically hindering groups andX is a functionalized fundamental building block,a process for its preparation, thermoplastic molding materials containing said copolymer, processes for their preparation, the use for the production of moldings and moldings comprising said molding materials.Type: GrantFiled: November 20, 1997Date of Patent: March 28, 2000Assignee: BASF AktiengesellschaftInventors: Axel Gottschalk, Ralf Engelhardt, Jurgen Koch, Robert Weiss
-
Patent number: 6031031Abstract: A thermoplastic molding composition comprisesA) from 1 to 97% by weight of a thermoplastic polyesterB) from 1 to 97% by weight of a polycarbonateC) from 1 to 40% by weight of an elastomer containing oxazoline groups and having a glass transition temperature (T.sub.g).ltoreq.0.degree. C.D) from 0.05 to 5% by weight of a bisoxazolineE) from 0 to 70% by weight of other additives and processing aids,where the total of the percentages by weight of components A) to E) is 100%.Type: GrantFiled: September 3, 1998Date of Patent: February 29, 2000Assignee: BASF AktiengesellschaftInventors: Martin Weber, Rolf Mulhaupt
-
Patent number: 6025437Abstract: There are disclosed a self-crosslinked polymer solid electrolyte, a composite solid electrolyte, and a method of manufacturing the same. A high-energy ray is irradiated to a block-graft copolymer composed of a polymer block chain A represented by formula I and a polymer block chain B represented by formula III in order to crosslink the entire the system. A nonaqueous electrolytic solution is then added to the block-graft polymer to obtain a self-crosslinked polymer solid electrolyte. The self-crosslinked polymer solid electrolyte and an electrically insulating material are combined to obtain a composite solid electrolyte.Type: GrantFiled: March 3, 1998Date of Patent: February 15, 2000Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Kazuhiro Hirahara, Toru Nakanishi, Yoshinobu Isono, Atsushi Takano
-
Patent number: 6015625Abstract: An adhesive resin composition contains at least a partially or wholly graft-modified .alpha.-olefin/aromatic vinyl compound random copolymer having a graft quantity of an unsaturated carboxylic acid or its derivative ranging from 0.01 to 30% by weight. A laminate comprises (I) a polyester resin layer or a polycarbonate layer, (II) an adhesive layer formed from the above-mentioned adhesive resin composition and (III) a saponified olefin/vinyl acetate copolymer layer. The adhesive resin composition is free from lowering of adhesive strength even when contacted with, for example, hot water. The laminate has excellent gas barrier properties and is capable of being subjected to retorting treatment.Type: GrantFiled: September 24, 1998Date of Patent: January 18, 2000Assignee: Mitsui Chemicals, Inc.Inventors: Kenichi Morizono, Keiji Okada, Hiromi Shigemoto, Hideshi Kawachi
-
Patent number: 6013202Abstract: A composition of matter useful for strippable shields for electric power cables comprises:a base polymer which is a copolymer of ethylene with a mono-unsaturated ester;conductive carbon black in an amount to give the composition an electrical resistivity below 500 .OMEGA.m; andas adhesion-controlling additive, a copolymer of ethylene with a mono-unsaturated ester containing from 0.5 to 2% by weight of side-chains each of which comprises an inflexible ring structure bonded to a backbone carbon atom of the copolymer with at most five atoms interposed between them.The compositions have the advantage of being less rubbery than current strippable-screen compositions and can be made successfully with copolymers of lower ester content.Type: GrantFiled: July 29, 1998Date of Patent: January 11, 2000Assignee: BICC General UK Cables LimitedInventors: Mark Richard Easter, Fiona Eleanor Keen
-
Patent number: 6009923Abstract: A tubeless pneumatic vehicle tire having an interliner ply having reduced resistance to air permeability. The interliner rubber composition is a a graft copolymer of a butyl rubber or a halogenated butyl rubber backbone having pendently grafted thereto a polymerized metal salt of an unsaturated carboxylic acid.Type: GrantFiled: December 11, 1997Date of Patent: January 4, 2000Assignee: Bridgestone CorporationInventors: William L. Hergenrother, Joseph K. Valaitis
-
Patent number: 6008297Abstract: A polyamide resin composition superior in the shock resitance, especially low temperature shock resistence, in the rigidity and in the water absorption resistance, which comprises(A) 98-50 % by weight of a polyamide,(B) 1-40 % by weight of a modified ethylene/.alpha.-olefin copolymer having an MFR (190.degree. C.) of 0.05-50 g/10 min., obtained by a graft-copolymerization of 100 parts by weight of an ethylene/.alpha.-olefin copolymer (B-1) having an ethylene content of 40-93 mole % and a density of lower than 0.900 g/cm.sup.3, with, grafted thereon, 0.01-5 parts by weight of an unsaturated dicarboxylic acid or its derivative (B-2), and(C) 1-40 % by weight of at least one ethylenic copolymer selected from the group consisting of an ethylene/.alpha.-olefin copolymer (C-1) having an .alpha.-olefin content of 10 mole % or less, an Mw/Mn of 2.5 or lower and an MFR (190.degree. C.) of 0.05-50 g/10 min. and a modified ethylen/.alpha.Type: GrantFiled: May 15, 1998Date of Patent: December 28, 1999Assignee: Mitsui Chemicals, Inc.Inventors: Yasuo Tanaka, Youji Hayakawa
-
Patent number: 6008294Abstract: The invention is a thermoformable polymer blend omprising:A) from 9 to 90 parts by weight of a monovinylidene aromatic polymer or an impact modified monovinylidene aromatic polymer, comprising from 1 to 25 weight percent of a rubber and 75 to 99 weight percent of a monovinylidene aromatic polymer matrix having a weight average molecular weight (M.sub.w) from 50,000 to 400,000, said weight percents being based on the total weight of said impact modified, monovinylidene aromatic polymer;B) from 9 to 90 parts by weight on an olefin polymer, selected from the group consisting of homopolymers of ethylene or propylene and copolymers of ethylene with one or more C.sub.Type: GrantFiled: November 26, 1997Date of Patent: December 28, 1999Assignee: The Dow Chemical CompanyInventors: Jeffrey E. Bonekamp, Robert J. Donald, Steven B. Swartzmiller, Andre J. Uzee
-
Patent number: 5998544Abstract: Graft copolymers are prepared by anionic polymerization which comprises reacting polymers (A) having at least one anionic chain end with polymers (B) which contain at least one nitrile group, in the presence of a solvent.Type: GrantFiled: October 9, 1997Date of Patent: December 7, 1999Assignee: BASF AktiengesellschaftInventors: Axel Gottschalk, Ralf Engelhardt, Martin Weber, Konrad Knoll
-
Patent number: 5993951Abstract: Disclosed is a transparent plastic sheet obtained by co-polymerizing 100 parts by weight of methyl methacrylate with 0.1 to 2.0 parts by weight of methacrylic acid and 0.1 to 1.5 parts by weight of glycidyl methacrylate, and having a thickness of not greater than 4 inches, wherein the angular deviation satisfies specified conditions according to the thickness of the sheet and wherein the degree of swelling is not greater than 2.50. This transparent plastic sheet shows neither coloring nor sink marks on the surface, has excellent craze resistance and low long-term water absorption percentage, and is hence suitable for use as an aircraft windshield.Type: GrantFiled: March 2, 1998Date of Patent: November 30, 1999Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Minoru Shimizu, Yoshifumi Kubota, Jun Nakauchi
-
Patent number: 5994464Abstract: According to the present invention there is provided a cyanoacrylate adhesive composition having high shear bond strength, peeling bond strength and impact bond strength and superior particularly in hot-cold cycle resistance and heat resistance. The cyanoacrylate adhesive composition contains (a) a cyanoacrylate monomer, (b) an elastomer miscible or compatible with the cyanoacrylate monomer, and (c) a core-shell polymer having a core of a rubbery polymer and a shell of a glassy polymer, the core-shell polymer being compatible but not miscible with the cyanoacrylate monomer.Type: GrantFiled: May 30, 1997Date of Patent: November 30, 1999Assignee: Three Bond., Ltd.Inventors: Nobuo Ohsawa, Hiroyuki Mikuni, Tatsuo Fujii, Hiroshi Takeuchi
-
Patent number: 5990202Abstract: Ink-jet inks for ink-jet printing are provided which include a vehicle and a colorant, the colorant encapsulated by or associated with a primer core/shell polymer to form a primer/colorant combination, and the primer/colorant combination, upon printing on a print medium, encapsulated by a durable core/shell polymer. The primer core/shell polymer serves to provide adhesion of the durable core/shell polymer to the colorant and the durable core/shell polymer serves to provide a smear-fast film upon drying of the ink on a print medium. The primer core/shell polymer comprises a hydrophobic core and a hydrophilic shell comprising a polar component, while the durable core/shell polymer comprises a hydrophobic core comprising a low T.sub.g component, which, when homopolymerized, has a glass transition temperature, T.sub.g, below 25.degree. C. and a high T.sub.g component, which, when homopolymerized, has a glass transition temperature above 25.degree. C.Type: GrantFiled: December 24, 1997Date of Patent: November 23, 1999Assignee: Hewlett-Packard CompanyInventors: Khe C Nguyen, Sivapackia Ganapathiappan
-
Patent number: 5990220Abstract: A propylene resin composition having suitability to coating is disclosed which comprises (a) 100 parts by weight of a propylene-ethylene block copolymer comprising 60 to 95% by weight of a crystalline polypropylene unit and 5 to 40% by weight of an ethylene-propylene random copolymer unit, (b) 2 to 120 parts by weight of an ethylene-.alpha.-olefin copolymer obtained by polymerization using a metallocene catalyst, containing 20 to 65% by weight of an .alpha.-olefin having 3 to 8 carbon atoms, and having a melt flow rate of 0.5 to 40 g/10 min and a density of 0.85 to 0.90 g/cm.sup.3, (c) 0.1 to 120 parts by weight of a filler selected from talc, mica, and a fibrous filler, (d) 5 to 40% by weight of a propylene polymer having grafted thereto 0.1 to 25% by weight, based on the total polymer, of maleic anhydride or a hydroxyl-containing maleic anhydride derivative, and (e) 0 to 10% by weight of a hydroxyl-terminated diene polymer or a hydrogenation product thereof.Type: GrantFiled: February 6, 1997Date of Patent: November 23, 1999Assignee: Japan Polychem CorporationInventors: Yoshihiro Sobajima, Hironari Fujii, Masashi Shimouse
-
Patent number: 5985997Abstract: A continuous bulk polymerization process for making a high gloss, high impact strength polystyrene based resin having a bimodal particle size distribution containing capsule particles having an average size of 0.2 to 0.6 microns and cellular particles having an average particle size of 1.2 to 8.0 microns. The process comprises three reaction zones in series where styrene and a styrene-butadiene copolymer are fed to the first reaction zone which is maintained at pre-phase inversion conditions and no particles are allowed to form. The capsule particles form in the second reaction zone which is maintained at post-phase inversion conditions. Polybutadiene is introduced into the third reaction zone which is also maintained at post-phase inversion conditions. The cellular morphology particles form in the third reaction zone.Type: GrantFiled: May 23, 1997Date of Patent: November 16, 1999Assignee: Chevron Chemical CompanyInventors: Kenneth E. Bowen, Michael J. Hanner
-
Patent number: 5981657Abstract: The present invention provides a thermally resistant resin composition containing PS and PPO, wherein at least one of PS and PPO has an acid group and the acid group is neutralized with a basic metal compound containing a metal element of the group 2B, 3B, 4B or 5B of the periodic table; thermally resistant PS and PPO each with an acid group which is also neutralized in the same manner as described above; and a method for miscible preparation of PS and PPO, wherein at least one of PS and PPO has an acid group and the acid group is neutralized similarly.Type: GrantFiled: August 20, 1996Date of Patent: November 9, 1999Assignee: Sony CorporationInventors: Yasuhito Inagaki, Tsutomu Noguchi, Hidemi Tomita
-
Patent number: 5969041Abstract: This invention relates to graft polymers of the ABS type which are produced in emulsion, and to thermoplastic molding compositions which are based thereon and which exhibit a very considerably increased notched bar impact strength compared with known ABS molding compositions and which at the same time exhibit high hardness values or high modulus values and good thermoplastic processability.Type: GrantFiled: June 30, 1997Date of Patent: October 19, 1999Assignee: Bayer AGInventors: Herbert Eichenauer, Adolf Schmidt, Heinrich Alberts
-
Patent number: 5962131Abstract: Process for the production of preoriented filaments from polyester-based polymer mixtures by spinning the polymer mixtures with a draw-off speed v of at least 2500 m/min, a second amorphous, thermoplastically processable copolymer having a glass transition temperature of more than 100.degree. C. being added to the polyester, wherein the ratio of the melt viscosity of the copolymer to the melt viscosity of the polyester is 1:1 to 10:1, in that the amount of copolymer added to the polyester is at least 0.05 wt.Type: GrantFiled: August 5, 1998Date of Patent: October 5, 1999Assignee: Degussa AktiengesellschaftInventors: Helmut Schwind, Wolfgang Janas, Klaus Dorn, Peter Kempf, Dietmar Wandel, Joachim Cziollek, Ulrich Thiele, Alexander Klein, Heinz-Dieter Schumann
-
Patent number: 5959030Abstract: Directly paintable polymer compositions contain (1) a thermoplastic olefin, (2) a maleic anhydride-grafted propylene homopolymer or random copolymer, (3) a maleic anhydride-grafted olefin polymer material, (4) a functionalized polymer that reacts with the maleic anhydride groups of the grafted polymers, and, optionally, (5) a maleic anhydride-grafted ethylene polymer. The amount of (2)+(3) or (2)+(3)+(5) is at least 16 parts but less than 27 parts per hundred parts of the thermoplastic olefin.Type: GrantFiled: January 22, 1997Date of Patent: September 28, 1999Assignee: Montell North America Inc.Inventor: Dominic A. Berta
-
Patent number: 5955540Abstract: Rubber-modified monovinylidene aromatic copolymers having an enhanced combination of gloss, toughness and melt flow characteristics are provided by a process wherein a rubber latex having a specified particle size is partially agglomerated, emulsion graft polymerized to a specified graft copolymer to rubber (G/R) ratio and a specified graft copolymer molecular weight and further agglomerated during subsequent dewatering and/or melt compounding operations.Type: GrantFiled: March 26, 1998Date of Patent: September 21, 1999Assignee: The Dow Chemical CompanyInventors: Robert P. Dion, David W. Mitchell, Patricia B. Leng
-
Patent number: 5952423Abstract: Plastic compositions, containers useful in the storage of red blood cells, and methods for providing such red blood cell storage containers and for storing red blood cells are disclosed. The plastic composition includes a polyolefin copolymer and a plasticizer. The flexibility of such plastic compositions and containers made thereof is substantially unchanged upon heating to a high temperature relative to its flexibility before such heating.Type: GrantFiled: July 18, 1997Date of Patent: September 14, 1999Assignee: Baxter International Inc.Inventors: Shaye-Wen Shang, Michael Tung-Kiung Ling, Lecon Woo
-
Patent number: 5948859Abstract: A thread wound golf ball having good shot feel and controllability as well as excellent flight performance which comprises a center composed of a vulcanized molded article of a rubber composition, a thread rubber layer formed on the center and a cover covering the thread rubber layer, wherein the center has a diameter of from 30 to 38 mm and a deformation amount, formed by applying an initial load of 10 kg to a final load of 30 kg to the center, of from 1 to 2.5 mm and the cover is formed from a heated mixture of an ionomer resin, an maleic anhydride-modified thermoplastic resin and an epoxidated thermoplastic resin having a JIS-A hardness of 30 to 90.Type: GrantFiled: December 6, 1996Date of Patent: September 7, 1999Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Yoshinori Sano, Akira Kato
-
Patent number: 5948860Abstract: Disclosed is a propylene polymer composition comprising (a) a propylene polymer, (b) an olefin type elastomer and (c) a polar group-containing olefin polymer composition obtained by heating (c-1) an olefin polymer containing a carboxyl group or an acid anhydrous group in its molecule and (c-2) an amino compound, each in a specific amount. Also disclosed is a propylene polymer composition comprising (a) a propylene polymer, (b) an olefin type elastomer, (c-1) an olefin polymer containing a carboxyl group or an acid anhydrous group in its molecule and (c-2) an amino compound, each in a specific amount. The propylene polymer compositions of the present invention are excellent in properties of being coated with various coatings.Type: GrantFiled: January 9, 1997Date of Patent: September 7, 1999Assignee: Mitsui Chemicals, Inc.Inventors: Shoji Hiraoka, Masayoshi Yamaguchi, Hajime Inagaki, Mikio Hashimoto
-
Patent number: 5945481Abstract: A case for memory disks having excellent antistatic properties, which comprises a thermoplastic resin composition comprising 100 parts by weight of the following component (A), 3 to 30 parts by weight of the following component (B) and 5 to 40 parts by weight of the following component (C):component (A): a crystalline propylene resin having a melt flow rate (MFR) of 1 to 80 g/10 min;component (B): a thermoplastic elastomer selected from (b.sup.1) olefin copolymer elastomers having a Mooney viscosity (ML.sub.1+4 (100.degree. C.)) of 10 to 85, and (b.sup.2) hydrogenated products of a block copolymer of styrene or a derivative thereof and a conjugated diene, containing 15 to 50% by weight of styrene or a derivative thereof, having a weight-average molecular weight of 50,000 to 220,000; andcomponent (C): an acrylamide copolymer.Type: GrantFiled: July 9, 1997Date of Patent: August 31, 1999Assignee: Mitsubishi Chemical CorporationInventors: Toshikazu Mizutani, Jichio Deguchi
-
Patent number: 5942575Abstract: Process for manufacturing vinyl-aromatic polymers reinforced with rubber and with bimodal morphology of the rubber phase, which process comprises:blending a first stream of a first vinyl-aromatic prepolymer, containing a fine-particle rubber phase prepared in a reactor of PFR type, with a second stream consisting of a larger-particle prepolymer, prepared in a CFSTR (Continuous Flow Stirred Tank Reactor);completing the polymerization until a rubber-reinforced vinyl-aromatic polymer with bimodal morphology is obtained, which is characterized by a considerable improvement in mechanical synergism associated with excellent aesthetic properties.Type: GrantFiled: September 24, 1997Date of Patent: August 24, 1999Assignee: Enichem S.p.A.Inventors: Luca Monti, Giuseppe Romagnoli
-
Patent number: 5939490Abstract: Compositions are provided for compatibilized blends comprising compatibilizing poly(phenylene ether) resins and epoxy-functional polyolefins that exhibit improved resistance to delamination while providing high impact strength and other improved physical properties. Articles made from the compositions are useful for automotive lighting and under hood components.Type: GrantFiled: June 12, 1997Date of Patent: August 17, 1999Assignee: General Electric CompanyInventors: Sterling Bruce Brown, John Robert Campbell, Chorng-Fure Robin Hwang, Steven Thomas Rice, Patric A. Rodgers, James Joseph Scobbo, Jr., John Bennie Yates
-
Patent number: 5932653Abstract: This invention is directed to a composition comprising a complex reaction product of an oil soluble cobalt soap and an oil soluble overbased calcium soap which serves as a "loss of dry" inhibitor, particularly in an oil-based paint, and as an accelerator with gel-time stabilizer and color development inhibitor characteristics in polyester polymerization.Type: GrantFiled: May 22, 1997Date of Patent: August 3, 1999Assignee: Troy CorporationInventor: Milton Nowak
-
Patent number: 5932654Abstract: The present invention provides a primer composition for polyolefins which has sufficient adhesion to polyolefin base materials and excellent resistance to gasohol and high pressure washing of cars. This primer composition for polyolefins comprises: acid anhydride-modified polypropylene chloride (A), which includes polypropylene chloride moiety (a1) and acid anhydride moiety (a2) as bonded thereto, and has a chlorine content of 19.5 to 20.5 wt %, an acid anhydride moiety content of 0.8 to 1.2 wt %, and a weight-average molecular weight of 30,000 to 36,000; and acryl-modified polypropylene chloride (B), which includes polypropylene chloride moiety (b1) and acrylic polymer chain moiety (b2) as grafted thereon, and has a weight-average molecular weight of 30,000 to 200,000, wherein: polypropylene chloride moiety (b1) has a chlorine content of 20 to 30 wt %; acrylic polymer chain moiety (b2) has a glass transition temperature of 60.degree. C.Type: GrantFiled: November 15, 1997Date of Patent: August 3, 1999Assignees: Honda Giken Kogyo Kabushiki Kaisha, Nippon Bee Chemical Co., Ltd.Inventors: Takeshi Ogawa, Katsuo Miyazaki, Makoto Hashimoto
-
Patent number: 5932655Abstract: A thermoplastic molding composition which features improved impact and reduced opacity is disclosed. The composition which contains (A) 2 to 59 percent of a first grafted rubber having a weight average particle size of 0.05 to 0.30 microns, and (B) 6 to 56 percent of a second grafted rubber having a weight average particle size of 0.31 to 1.00 microns, and (C) 35 to 75 percent of a copolymeric matrix. The total rubber content of the composition is 10 to 40 percent relative to the total weight of (A), (B) and (C). The grafted rubber, both occurrences, contains a grafted phase and a core-shell phase. The grafted phase contains a styrenic copolymer and the core-shell phase, both occurrences, contains a core containing at least one crosslinked vinylaromatic polymer, and an elastomeric shell. The copolymeric matrix (C) contains a styrenic copolymer.Type: GrantFiled: November 19, 1997Date of Patent: August 3, 1999Assignee: Bayer CorporationInventors: Richard M. Auclair, Moh Ching Oliver Chang
-
Patent number: 5916953Abstract: A tough, strong, stiff glass-filled polyolefin composition comprisesa propylene polymer having an nmr tacticity index of at least 94 and a molecular weight distribution of about 7 to 15;a stiffness-enhancing amount of glass fiber;an impact-modifying amount of a plastomer copolymer of ethylene with a C.sub.4 -C.sub.6 alpha-olefin having a density of about 0.865 to about 0.910 g/cc; anda functionalized olefin polymer in a sufficient amount to act as a compatibility agent between polymeric materials and the glass fiber.Type: GrantFiled: March 14, 1997Date of Patent: June 29, 1999Assignee: BP Amoco CorporationInventors: Philip Jacoby, Mark Allen Sherman
-
Patent number: 5914370Abstract: There are disclosed a thermoplastic resin composition which comprises a styrenic resin comprising a modified styrenic polymer in which a compound having an unsaturated group and a polar group is bonded to the skeleton of a styrenic polymer having syndiotactic configuration (SPS) or to an end or an intermediate position of a substituent of the SPS, or the mixture of the above modified styrenic polymer and an unmodified SPS; and an inorganic filler, as well as a thermoplastic resin composition which comprises the aforesaid styrenic resin; and an other thermoplastic resin. The compositions are excellent in water resistance, impact resistance, heat resistance, modulus of elasticity and dynamical properties and capable of improving the adhesiveness to the inorganic filler or compatibility with the other resin without impairing the crystallization of the SPS and deteriorating the long-term heat resistant stability of the compositions.Type: GrantFiled: November 10, 1997Date of Patent: June 22, 1999Assignee: Idemitsu Kosan Co., Ltd.Inventors: Akihiko Okada, Akitoshi Masuyama
-
Patent number: 5910526Abstract: The specification discloses a polyphenylene oxide delivery system for use in preparing an A-B-A block copolymer adhesive formulation having an increased service temperature. The delivery system comprises a preblend of polyphenylene oxide (PPO) resin having a T.sub.g within the range of from about 150.degree. to about 210.degree. C. and a B-block compatible resin. The PPO/B-block resin preblend enables introduction of more PPO into the composition thereby increasing the service temperature of the adhesive formulation.Type: GrantFiled: September 14, 1998Date of Patent: June 8, 1999Assignee: Arizona Chemical CompanyInventors: Wayne K. Chu, Erwin R. Ruckel
-
Patent number: 5910538Abstract: A thermoplastic molding composition containing a blend of polycarbonate, vinyl copolymer, such as SAN, and a graft polymer, such as ABS is disclosed. The invention resides in the finding that the incorporation of a compatibilizing agent which comprises a polymeric resin having a number average molecular weight of at least about 21,000 and which is miscible with the grafted phase of the graft polymer and which contains secondary amine reactive groups in its structure yields stable compositions having improved mechanical properties especially at low temperatures.Type: GrantFiled: April 24, 1998Date of Patent: June 8, 1999Assignee: Bayer CorporationInventors: Allen R. Padwa, Venkatarayaloo Janarthanan
-
Patent number: 5902845Abstract: A rubber-modified styrenic resin composition comprising 100 parts by weight of a rubber-modified styrenic resin (A) having 10 to 40% by weight of the content of a soft component particle and a mean particle diameter of the said particle of 0.1 to 1.2 .mu.m, and 1 to 30 parts by weight of fine particles having a mean particle diameter of 0.1 to 5 .mu.m and not having a glass transition temperature between -130 to 90.degree. C.A rubber-modified styrenic resin composition having superior plane impact strength, rigidity and gloss, and its molded article are provided.Type: GrantFiled: March 1, 1996Date of Patent: May 11, 1999Assignee: Sumitomo Chemical Company, LimitedInventors: Shuji Yoshimi, Hayato Kihara, Takahiro Ishii