Mixture Contains Solid Polymer Derived From Reactant Containing A Fused- Or Bridged-ring System Or From Cycloaliphatic Reactant Patents (Class 525/75)
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Patent number: 5352739Abstract: This invention relates to a compatibilized rubber composition and a process for compatibilizing polar/nonpolar rubber blends comprising blending compatiblizers such as ethylene/vinyl acetate copolymer, ethylene/methacrylate copolymer EPDM or EP rubber grafted with a polar monomer such as methyl methacrylate.Type: GrantFiled: November 6, 1992Date of Patent: October 4, 1994Assignee: Exxon Chemical Patents Inc.Inventor: Palanisamy Arjunan
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Patent number: 5334659Abstract: Copolymer compositions useful as impact modifiers are prepared by blending, under reactive conditions, at least one functionalized addition polymer with an excess of at least one functionalized elastomer reactive therewith to form a preblend, and subsequently blending said preblend, under reactive conditions, with a further amount of at least one functionalized addition polymer. The preferred addition polymers and elastomers are carbamate-functionalized styrene-acrylonitrile copolymers and maleic anhydride-grafted EPDM elastomers, respectively. The product of the two-step blending operation is a composition comprising a continuous addition polymer phase and elastomer particles dispersed therein, said elastomer particles containing occluded addition polymer. Said composition is stabilized by copolymer formation between the elastomer particles and the addition polymer.Type: GrantFiled: May 24, 1993Date of Patent: August 2, 1994Assignee: General Electric CompanyInventors: James J. Scobbo, Jr., Gregory J. Stoddard
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Patent number: 5310795Abstract: Novel addition polymers and copolymers derived from carbamate-functionalized vinyl monomers, and optionally one or more conventional vinyl monomers such as acrylonitrile and/or styrene, are disclosed. When the addition polymers or copolymers are melt processed with an elastomer containing moieties reactive with amines, novel addition polymer-rubber copolymers are formed which are useful as compatibilizers and impact modifiers in plastic blends, such as AES.Type: GrantFiled: June 17, 1993Date of Patent: May 10, 1994Assignee: General Electric CompanyInventors: William P. England, Gregory J. Stoddard, James J. Scobbo, Jr.
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Patent number: 5310809Abstract: An olefinic polymer is grafted with a vinyl arylcyclobutene such as 4-vinylbenzocyclobutene. The arylcyclobutene grafted olefinic polymers are useful in a number of industrial applications including electronics, and as coatings, membranes, fibers, structural composites, adhesives, and wrapping and packaging films.Type: GrantFiled: May 20, 1993Date of Patent: May 10, 1994Assignee: The Dow Chemical CompanyInventors: Raul A. Pabon, Jr., Robert A. DeVries
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Patent number: 5304606Abstract: A thermoplastic resin composition according to the present invention comprises a polymer comprising recurring units derived from a polycyclic (meth)acrylate represented by the following formula [I] and a soft polymer in the proportion by weight of the polymer to the soft polymer of 99:1 to 40:60 ##STR1## where m is 0 or a positive integer, n is 0 or 1, R is hydrogen or methyl, R.sup.1 -R.sup.18 are each independently an atom or a group selected from the group consisting of hydrogen, halogen and hydrocarbon groups, R.sup.15 -R.sup.18, linked together, may form a monocyclic or polycyclic group which may have a double bond, or an alkylidene group, p is 0 or 1, and R.sup.a and R.sup.b each independently represent a hydrogen atom or a hydrocarbon group when p is 1.Type: GrantFiled: March 15, 1993Date of Patent: April 19, 1994Assignee: Mitsui Petrochemical Industries, Ltd.Inventor: Yohzoh Yamamoto
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Patent number: 5298551Abstract: The present invention provides a vinyl chloride resin composition having an elevated heat distortion temperature, comprising]I[ [A] a vinyl chloride resin, and[II] [B] cycloolefin ring opening polymer or copolymer formed by ring opening polymerization of a cycloolefin represented by the formula [I], or a hydrogenated product thereof, and/or[C] a cycloolefin random copolymer of ethylene and a cycloolefin represented by the formula [I], said copolymer having an intrinsic viscosity [.eta.], as measured in decalin at 135.degree. C., of 0.05 to 10 dl/g and a glass transition temperature Tg of at least 70.degree. C., ##STR1## wherein n is 0 or 1, and m is 0 or a positive integer.Type: GrantFiled: April 28, 1992Date of Patent: March 29, 1994Assignee: Mitsui Petrochemical Industries, Ltd.Inventor: Youzo Yamamoto
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Patent number: 5290822Abstract: An ultra low density polyolefin foam having a density of about 0.6 to about 1.5 pounds per cubic foot comprising a heat-plastified mixture comprising (1) a non-elastomeric olefin polymer resin selected from the group consisting of ethylene homopolymers, non-elastomeric copolymers of ethylene and a copolymerizable monomer, and propylene homopolymers; (2) an elastomer in an amount of about 3 to about 30 wt. parts per 100 wt. parts of said non-elastomeric olefin polymer resin; (3) polystyrene in an amount of about 1 to about 15 wt. parts per 100 wt. parts of said olefin polymer resin; (4) a stability control agent selected from the group consisting of partial esters of long chain fatty acids with polyols, higher alkyl amines, fatty acid amides, and olefinically unsaturated carboxylic acid copolymers, and (5) a hydrocarbon blowing agent having from 1 to 6 carbon atoms and a boiling point between -175.degree. C. and 50.degree. C.Type: GrantFiled: June 21, 1993Date of Patent: March 1, 1994Assignee: Astro-Valcour, Inc.Inventors: John E. Rogers, Ronnie D. Kisner
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Patent number: 5290837Abstract: A thermoplastic composition based on a polyolefin and a vinyl aromatic polymer, having an improved combination of physical, mechanical and thermal properties, comprising:from 40 to 80% by weight of a vinyl aromatic polymer (A) containing, as an elastomeric component, from 0.5 to 5% by weight of a vinyl aromatic monomer - conjugated diene linear block polymer and from 5 to 15% of a diene rubber, from 5 to 50% by weight of a polyolefin (B) and from 10 to 50% by weight of an olefinic elastomer (C) containing, grafted thereon, a vinyl aromatic polymer, wherein the molar ratio between the vinyl aromatic polymer and the olefinic elastomer in the grafted phrase is greater than 0.8, the sum of components (A), (B) and (C) being equal to 100%.Type: GrantFiled: November 12, 1991Date of Patent: March 1, 1994Assignee: ECP Enichem Polimeri S.r.L.Inventors: Dario Ghidoni, Gian C. Fasulo, Aldo Longo, Italo Borghi
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Patent number: 5283286Abstract: A thermoplastic resin composition is prepared by blending 50-95 wt. % of a copolymer (A) of 10-75 wt. % of .alpha.-methyl styrene, 10-60 wt. % of methyl methacrylate, 5-35 wt. % of acrylonitrile and 0-20 wt. % of a monomer copolymerizable therewith; and 5-50 wt. % of a graft copolymer (B) comprising 50-85 wt. parts of a butadiene-based rubber polymer and 15-50 wt. parts of a vinyl monomer graft-polymerized onto the rubber polymer. The butadiene-based rubber polymer includes 50-98 wt. % of butadiene, 2-50 wt. % of an aromatic polycyclic vinyl monomer represented by a formula (I) below and 0-20 wt. % of a monomer copolymerizable therewith: ##STR1## wherein R denotes an optionally substituted biphenylyl or naphthyl group, and R.sub.1 denotes a hydrogen atom or a methyl group.Type: GrantFiled: May 8, 1992Date of Patent: February 1, 1994Assignee: Kureha Kagaku Kogyo Kabushiki KaishaInventors: Yosuke Takahashi, Yasumasa Komatsu, Hiroshi Hagiwara, Takayuki Katto
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Patent number: 5278237Abstract: Disclosed are a sculpturing resin composition which comprise comprising a polyoctenamer resin and a polyolefin copolymer and/or a modified polyolefin resin, and a process for sculpturing a sculptured product.The sculpturing composition has an excellent property of not shrinking even after elapse a long period of time, and is capable of being molded by hand at moderate temperatures, sculptured or shaved with a chisel, etc., and also being polished or ground with a rasp, etc., in comparison with conventional sculpturing materials.The anti-shrinking property of the polyoctenamer resin is found to be improved specifically by the mixing with a polyolefin copolymer and/or a modified polyolefin resin.Type: GrantFiled: August 7, 1992Date of Patent: January 11, 1994Assignee: DAICEL-Huls Ltd.Inventor: Masami Kita
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Patent number: 5262485Abstract: A thermoplastic resin composition according to the present invention comprises a polymer comprising recurring units derived from a polycyclic (meth)acrylate represented by the following formula [I] and a soft polymer in the proportion by weight of the polymer to the soft polymer of 99:1 to 40:60 ##STR1## wherein m is 0 or a positive integer, n is 0 or 1, R is hydrogen or methyl, R.sup.1 -R.sup.18 are independently an atom or a group selected from the group consisting of hydrogen, halogen and hydrocarbon groups, R.sup.15 -R.sup.18, linked together, may form a monocyclic or polycyclic group which may have a double bond, or an alkylidene group, p is 0 or 1, and R.sup.a and R.sup.b each independently represent a hydrogen atom or a hydrocarbon group when p is 1.Type: GrantFiled: January 16, 1992Date of Patent: November 16, 1993Assignee: Mitsui Petrochemical Industries, Ltd.Inventor: Yohzoh Yamamoto
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Patent number: 5229206Abstract: Adhesive composition comprising a blend consisting essentially of (1) an adhesive composition comprising a tacky pressure-sensitive adhesive, said adhesive preferably selected from rubber-based adhesives, e.g., the thermoplastic elastomers, and (2) a pressure-sensitive adhesive composition comprising a polymer having in its backbone at least a major portion by weight of polymerized monomeric acrylic or methacrylic acid ester of a non-tertiary alcohol having from 1 to 14 carbon atoms with the average number of carbon atoms being about 4 to about 12, and grafted to the backbone, polymeric moieties having a Tg greater than about 20.degree. C. and a weight average molecular weight above about 2,000. The pressure-sensitive adhesive of adhesive composition (1) has moieties, e.g., blocks or grafts, that associate with the polymeric moieties grafted to the backbone of the polymer of adhesive composition (2).Type: GrantFiled: June 30, 1992Date of Patent: July 20, 1993Assignee: Minnesota Mining and Manufacturing CompanyInventor: James D. Groves
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Patent number: 5227409Abstract: A polyurethane adhesive is prepared from a reaction mixture containing small amounts of chain extender material and a high equivalent weight of a polyol and a monoalcohol. An article adhered to a substrate using this adhesive is firmly affixed to the substrate, yet can be removed without leaving residual adhesive on the substrate. In addition, this adhesive can be washed and reused if desired.Type: GrantFiled: March 27, 1992Date of Patent: July 13, 1993Assignee: The Dow Chemical CompanyInventors: Larry W. Mobley, Vivian R. Hofmeister
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Patent number: 5225451Abstract: A foamable composition for producing an ultra low density polyolefin foam having a density of about 0.6 to about 1.5 pounds per cubic foot comprising a heat-plastified mixture comprising (1) an olefin polymer resin selected from the group consisting of ethylene homopolymers and copolymers of ethylene and a copolymerizable monomer; (2) an elastomer in an amount of about 3 to about 30 wt. parts per 100 wt. parts of said olefin polymer resin; (3) polystyrene in an amount of about 1 to about 15 wt. parts per 100 wt. parts of said olefin polymer resin; (4) a stability control agent selected from the group consisting of partial esters of long chain fatty acids with polyols, higher alkyl amines, fatty acid amides, and olefinically unsaturated carboxylic acid copolymers, and (5) a hydrocarbon blowing agent having from 1 to 6 carbon atoms and a boiling point between -175.degree. C. and 50.degree. C.Type: GrantFiled: August 27, 1992Date of Patent: July 6, 1993Assignee: Astro-Valcour, Inc.Inventors: John E. Rogers, Ronnie D. Kisner
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Patent number: 5225483Abstract: A thermoplastic composition is provided which comprises a blend of a thermoplastic, such as a copolymer of styrene and maleic anhydride; polypropylene; a modified elastomeric component, such as EPM or EPDM, which has been modified with a specified functional monomer, such as a 2-substituted-5-norbornene, and an amine-modified maleic anhydride grafted polypropylene. The composition has improved properties.Type: GrantFiled: July 22, 1991Date of Patent: July 6, 1993Assignee: Exxon Chemical Patents Inc.Inventors: Sudhin Datta, Narayanaswami R. Dharmarajan, Jean M. Dekoninck, Donald A. White
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Patent number: 5219935Abstract: A composition universally usable as an impact modifier for synthetic resins comprising(A) from 10 to 80 percent by weight of a polymer of the formula ##STR1## wherein R.sub.1 is hydrogen or methyl, R.sub.2 is C.sub.5 -C.sub.7 cycloalkyl or such cycloalkyl substituted by C.sub.1 -C.sub.12 alkyl, y has a value such that the corresponding monomer or monomers are from 5 to 50 percent by weight of polymer (A), and x has a value such that the corresponding monomer, together with up to 20 percent by weight of one or more optional comonomers, is the balance by weight, and(B) from 20 to 90 percent by weight of an optionally crosslinked polymer having a glass transition temperature, T.sub.g, below 10.degree. C. and preferably less than -10.degree. C., polymer (B) being at least partially bonded covalently to polymer (A).Type: GrantFiled: December 21, 1989Date of Patent: June 15, 1993Assignee: Rohm GmbHInventors: Werner Siol, Jens-Dieter Fischer, Klaus Koralewski, Ulrich Terbrack
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Patent number: 5216107Abstract: The present invention relates to a binder composition containinga) 20 to 70% by weight of oligomerization products of 1,6-diisocyanatohexane, the oligomerization products having isocyanate groups at least partially blocked with blocking agents for isocyanate groups and containing at least 50% by weight, based on the weight of the oligomerization products, of blocked uretdione diisocyanates corresponding to formula (I) ##STR1## wherein R represents the residue formed by removal of the active hydrogen atom from a monofunctional blocking agent, andb) 30 to 80% by weight of a polyol component containing a mixture ofb1) 100 parts by weight of an alkoxylation product of bisphenol A corresponding to formula (II) ##STR2## wherein R' is hydrogen or a methyl group and n is a whole or fractional number from 1 to 2,b2) 20 to 200 parts by weight castor oil andb3) 0 to 40 parts by weight of other organic polyhydroxyl compounds.Type: GrantFiled: July 10, 1991Date of Patent: June 1, 1993Assignee: Bayer AktiengesellschaftInventors: Josef Pedain, Friedrich Schrader, Dieter Mager, Hans-Heribert Burgdorfer
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Patent number: 5210135Abstract: Thermoplastic molding compounds, containingA) 5-95 weight % of a thermoplastic homo-, co- or terpolymer of styrene, alpha-methylstyrene, ring-substituted styrene, methyl methacrylate, acrylonitrile, methacrylonitrile, maleic anhydride, N-substituted maleimide, vinyl acetate or mixtures thereof,B) 5-95 weight % of a graft polymer ofB.1) 5-90 parts by weight of styrene, alpha-methylstyrene, ring-substituted styrene, methyl methacrylate, acrylonitrile, methacrylonitrile, maleic anhydride, N-substituted maleimide, vinyl acetate or mixtures thereof onB.2) 95-10 parts by weight of a rubber with a glass transition temperature .ltoreq.10.degree. C. andC) 0.1-5 parts by weight per 100 parts by weight A+B of a grafted product of resin-forming monomers on an ethylene-propylene-diene terpolymer rubber with a rubber content of 20-60 weight %.Type: GrantFiled: August 26, 1992Date of Patent: May 11, 1993Assignee: Bayer AktiengesellschaftInventors: Herbert Eichenauer, Alfred Pischtschan, Karl-Heinz Ott
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Patent number: 5194497Abstract: Polymer alloys containing resin-like polymers of monomers corresponding to formula (I) ##STR1## in which R.sup.1 =H, CH.sub.3,R.sup.2 =C.sub.1-8 alkylene,R.sup.3 =C.sub.1-4 alkyl,and, optionally, other typical vinyl monomers and thermoplastic polymers or graft polymers.Type: GrantFiled: March 15, 1991Date of Patent: March 16, 1993Assignee: Bayer AktiengesellschaftInventors: Karl-Erwin Piejko, Gerd Fengler, Holger Lutjens, Hans-Eberhard Braese, Christian Lindner, Jurgen Kirsch
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Patent number: 5166240Abstract: There is provided a thermoplastic resin composition and a molded bumper therefrom in which said composition comprises:(I) 1 to 99 parts by weight of a propylene polymer, and(II) 99 to 1 parts by weight of a multi-phase structure thermoplastic resin which is a graft copolymer comprising 5 to 95% by weight of a propylene polymer and 95 to 5% by weigth of a vinyl polymer obtained from at least one vinyl monomer, either of the components being formed with a dispersion phase having a particle diameter of 0.001 to 10 .mu.m.Type: GrantFiled: December 20, 1990Date of Patent: November 24, 1992Assignee: Nippon Petrochemicals Co., Ltd.Inventors: Suehiro Sakazume, Yuichi Orikasa
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Patent number: 5112909Abstract: Modified rubber compositions comprise, by weight, about 15-60% of a highly saturated aliphatic rubber, such as ethylene-propylene-diene rubber, about 25-80% of preferably non-nitrogenous acrylate monomer units; and less than about 5% multi-functional monomer units. The compositions exist as amorphous heterogeneously dispersed phases. The first phase comprises the copolymer rubber, to which polymers of at least 10%, preferably 20%, and more preferably 30% of the other monomer units are grafted. The second phase comprises the other monomers polymerized as homo and copolymers, not grafted to the rubber.The modified rubber composition, preferably non-nitrogenous polyacrylate polymer, and another polymer are mixed together to form a polymer blend having higher impact strength and other important properties.Type: GrantFiled: April 16, 1991Date of Patent: May 12, 1992Assignee: Cyro IndustriesInventors: Daniel D. Zimmerman, Gary Vieiro
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Patent number: 5086307Abstract: A liquid jet recording head comprising a cured product of an active energy-ray-curing resin composition as at least a part of its constitution, said composition comprises:(A) a graft copolymerized polymer having a number average molecular weight of 5,000 or more and a weight average molecular weight of 50,000 or less which comprises a trunk chain composed mainly of structural units derived from at least one monomer (hereinafter referred to as "monomer (a)") selected from the group consisting of alkyl methacrylates, acrylonitrile and stylene and has graft chains having structural units derived from at least one monomer (hereinafter referred to as "Monomer (b)") selected from the group consisting of the monomers represented by the following formula x and other monomers presented by the formula y: ##STR1## (B) a linear polymer having a number average molecular weight of 50,000 or more and a weight average molecular weight of 350,000 or less and having a glass transition temperature of 60.degree. C.Type: GrantFiled: February 13, 1991Date of Patent: February 4, 1992Assignee: Canon Kabushiki KaishaInventors: Hiromichi Noguchi, Tadayoshi Inamoto, Megumi Saito
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Patent number: 5068258Abstract: An improved active energy ray-curing resin composition comprising (i) a graft copolymerized polymer having a number average molecular weight of 5,000 or more and a weight average molecular weight of 50,000 or less: (ii) a linear polymer having a number average molecular weight of 5,000 or more and a weight average molecular weight of 350,000 or less and having a glass transition temperature of 60.degree. C. or more: (iii) a half-esterificated epoxy resin: and (iv) a polymerization initiator capable of generating a Lewis acid by irradiation of an active energy ray. The resin composition can be desirably cured with an active energy ray such as ultraviolet ray or electron beam and it is capable of being laminated in a desired pattern on a copper-coated laminate for use as a printed board or on a plate of metal, glass, ceramics or plastic.Type: GrantFiled: September 15, 1988Date of Patent: November 26, 1991Assignee: Canon Kabushiki KaishaInventor: Hiromichi Noguchi
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Patent number: 5068257Abstract: An improved active energy ray-curing resin composition comprising (i) a graft copolymerized polymer having a number average molecular weight of 5,000 or more and a weight average molecular weight of 50,000 or less: (ii) a linear polymer having a number average molecular weight of 5,000 or more and a weight average molecular weight of 350,000 or less and having a glass transition temperature of 60.degree. C. or more: (iii) a half-esterificated epoxy resin: (iv) a monomer having an ethylenically unsaturated bond: and (v) a polymerization initiator capable of generating a Lewis acid by irradiation of an active energy ray.The resin composition can be desirably cured with an active energy ray such as ultraviolet ray or electron beam and it is capable of being laminated in a desired pattern on a copper-coated laminate for use as a printed board or on a plate of metal, glass, ceramics or plastic.Type: GrantFiled: September 15, 1988Date of Patent: November 26, 1991Assignee: Canon Kabushiki KaishaInventor: Hiromichi Noguchi
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Patent number: 5068259Abstract: An improved active energy ray-curing resin composition comprising (i) a graft copolymerized polymer having a number average molecular weight of 5,000 or more and a weight average molecular weight of 50,000 or less: (ii) a linear polymer having a number average molecular weight of 5,000 or more and a weight average molecular weight of 350,000 or less and having a glass transition temperature of 60.degree. C. or more: (iii) an epoxy resin containing at least one compound having one or more epoxy groups in one molecule, (iv) a monomer having an ethylenically unsaturated bond and (v) a polymerization initiator capable of generating a Lewis acid by irradiation of an active energy ray. The resin composition can be desirably cured with an active energy ray such as ultraviolet ray or electron beam and it is capable of being laminated in a desired pattern on a copper-coated laminate for use as a printed board or on a plate of metal, glass, ceramics or plastic.Type: GrantFiled: September 15, 1988Date of Patent: November 26, 1991Assignee: Canon Kabushiki KaishaInventor: Hiromichi Noguchi
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Patent number: 5068260Abstract: An improved active energy ray-curing resin composition comprising (i) a graft copolymerized polymer having a number average molecular weight of 5,000 or more and a weight average molecular weight of 50,000 or less; (ii) a linear polymer having a number average molecular weight of 5,000 or more and a weight average molecular weight of 350,000 or less and having a glass transition temperature of 60.degree. C. or more: (iii) an epoxy resin containing at least one compound having one or more epoxy groups in one molecule: and (iv) a polymerization initiator capable of generating a Lewis acid by irradiation of an active energy ray. The resin composition can be desirably cured with an active energy ray such as ultraviolet ray or electron beam and it is capable of being laminated in a desired pattern on a copper-coated laminate for use as a printed board or on a plate of metal, glass, ceramics or plastic.Type: GrantFiled: September 15, 1988Date of Patent: November 26, 1991Assignee: Canon Kabushiki KaishaInventor: Hiromichi Noguchi
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Patent number: 5068262Abstract: An improved active energy ray-curing resin composition comprising (i) a graft copolymerized polymer having a number average molecular weight of 5,000 or more and a weight average molecular weight of 50,000 or less: (ii) a linear polymer having a number average molecular weight of 5,000 or more and a weight average molecular weight of 350,000 or less and having a glass transition temperature of 60.degree. C. or more: (iii) an esterified polyurethane obtained from oligoesterdiol or from oligoesterdiol and dihydric isocyanate which has a molecular chain terminal end being esterificated with acrylic acid: and (iv) a photopolymerization initiator.The resin composition can be desirably cured with an active energy ray such as ultraviolet ray or electron beam and it is capable of being laminated in a desired pattern on a copper-coated laminate for use as a printed board or on a plate of metal, glass, ceramics or plastic.Type: GrantFiled: September 15, 1988Date of Patent: November 26, 1991Assignee: Canon Kabushiki KaishaInventor: Hiromichi Noguchi
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Patent number: 5068263Abstract: An improved active energy ray-curing resin composition comprising (i) a graft copolymerized polymer with a trunk chain containing dicyclopentenyl derivative group which has a number average molecular weight of 5,000 or more and a weight average molecular weight of 50,000 or less: (ii) a linear polymer having a number average molecular weight of 5,000 or more and a weight average molecular weight of 350,000 or less and having a glass transition temperature of 60.degree. C. or more: (iii) a monomer having an ethylenically unsaturated bond: and (iv) a photopolymerization initiator capable of generating free radicals with irradiation of an active energy ray. The resin composition can be desirably cured with an active energy ray such as ultraviolet ray or electron beam and it is capable of being laminated in a desired pattern on a copper-coated laminate for use as a printed board or on a plate of metal, glass, ceramics or plastic.Type: GrantFiled: September 15, 1988Date of Patent: November 26, 1991Assignee: Canon Kabushiki KaishaInventor: Hiromichi Noguchi
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Patent number: 5066718Abstract: A compatible polymer mixture of two disparate polymers consisting essentially of:A) 0.1-99.9 wt. % of a copolymer comprised of the following monomer unitsa) 90-10 wt. % methyl acrylate;b) 10-90 wt. % styrene; andc) 0 to <10 wt. % of one or more other monomeric vinyl compounds, other than methyl acrylate and styrene; andB) 99.9-0.1 wt. % of a polymer comprised of the following monomer unitsa) >90 to 100 wt. % methyl methacrylate; andb) 0 to <10 wt. % of at least one monomeric vinyl compound other than methyl methacrylate.Type: GrantFiled: September 18, 1989Date of Patent: November 19, 1991Assignee: Rohm GmbH Chemische FabrikInventors: Werner Siol, Ulrich Terbrack
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Patent number: 5057574Abstract: A process for producing an .alpha.-alkyl-substituted aromatic vinyl copolymer constituted of 60 to 85 parts by weight of the .alpha.Type: GrantFiled: May 14, 1990Date of Patent: October 15, 1991Assignee: Mitsubishi Rayon Company, Ltd.Inventors: Makoto Uchida, Yutaka Toyooka, Kazuo Kishida, Akira Nakata, Naoki Yamamoto
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Patent number: 5049614Abstract: Blends based on vinyl-aromatic polymers having high tenacity and impact strength, comprising:a vinyl-aromatic copolymer containing from 2 to 25% by weight of an ethylenically unsaturated nitrile and a rubber amount not higher than 15% by weight; anda grafted polymer consisting of an elastomeric core having a transition temperature of the second order lower than 10.degree. C. containing, in the grafted form, chains of vinyl monomers.Type: GrantFiled: March 27, 1990Date of Patent: September 17, 1991Assignee: Montedipe S.p.A.Inventor: Gianfranco Biglione
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Patent number: 5010119Abstract: An adhesive composition which contains a thermoplastic elastomeric polymer which includes ethylene propylene rubber, ethylene propylene diene monomer, polyisobutylene butyl rubber, ethylene vinyl acetate graft copolymers thereof with C.sub.3 to C.sub.10 unsaturated mono- and polycarboxylic acids, a tackifiying resin and a encapsulated maleated polymer di- or polyamine cross-linking agent having 2-10 carbon atoms, which is useful as a hot melt or pressure sensitive adhesive having enhanced higher temperature properties. Also claimed is the encapsulated polyamine itself. Preferably, the encapsulating material is maleated polypropylene.Type: GrantFiled: November 25, 1988Date of Patent: April 23, 1991Inventors: Kenneth O. McElrath, Jr., Martha H. Robertson, Wai Yan Chow
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Patent number: 5006602Abstract: A composition consisting essentially of a polyvinylidene fluoride polymer or copolymer having distributed substantially uniformly therethrough elastomeric particles, said elastomer being capable of absorbing hydrocarbons and fixing them in the composition and being present in an amount sufficient to increase the elongation and flexibility of the composition in the presence of hydrocarbons and shaped articles made therefrom.Type: GrantFiled: December 31, 1986Date of Patent: April 9, 1991Assignee: AtochemInventors: Bernard Guerin, Albert Strassel
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Patent number: 5004783Abstract: A polymer blend comprises a high nitrile copolymer and a compatible thermoplastic polymer or copolymer containing polar groups, formed from monomers selected from the group consisting of alkylacrylamides, aliphatic and cyclic methacrylates, unsaturated carboxylic acid anhydrides, vinyl pyrrolidones, heterocyclic ring compounds containing two hetero atoms, lactones and phosphorus-containing monomers that form highly crystalline polymers. Such blends can be used to form films and membranes having improved thermal, mechanical and optical properties.Type: GrantFiled: August 22, 1988Date of Patent: April 2, 1991Assignee: The Standard Oil CompanyInventors: Elena S. Percec, Doreen Y. Takigawa
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Patent number: 5001194Abstract: A functionalized polymeric composition, said polymeric composition comprising a first phase and a second phase. The first phase comprises a first copolymer of a monovinylidene monomer and a comonomer selected to have at least one reactive epoxide functionality. The second phase is dispersed with the first phase. The second phase comprises a copolymer of an olefin monomer and one or more ethylenically unsaturated monomers copolymerizable with the olefin monomer wherein at least one of the ethylenically unsaturated monomers copolymerizable with the olefin monomer comprises a reactive functionality capable of reacting with one or more of the reactive epoxide functionalities of the first copolymer.Type: GrantFiled: July 7, 1989Date of Patent: March 19, 1991Assignee: The Dow Chemical CompanyInventor: David E. Henton
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Patent number: 4997872Abstract: A resinous composition suitable for powder coating comprises (A) 80-98 parts by weight of a polypropylene composition comprising a crystalline propylene polymer grafted with an unsaturated carboxylic acid or an anhydride thereof, (B) 20-2 parts by weight of an ethylene/.alpha.-olefin copolymer having a density of 0.860-0.915 g/cm.sup.3, (C) 0.001-1.0 part by weight of a polymer of vinyl cycloalkane having 6 or more carbon atoms, and (D) 0-10 parts by weight of a metal oxide or a metal hydroxide.Type: GrantFiled: September 8, 1989Date of Patent: March 5, 1991Assignee: Sumitomo Chemical Company, Ltd.Inventors: Tadayuki Ohmae, Hisao Tanaka, Mitsuyuki Okada
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Patent number: 4963613Abstract: An adhesive composition comprising:a polymer latex containing a copolymer which comprises(a) 40 to 80% by weight of a conjugated diene monomer and(b) 0.5 to 30% by weight of a cyanated vinyl monomer,(c) 5 to 35% by weight of vinylpyridine and(d) not more than 53% by weight of an aromatic vinyl monomer; anda resorcin-formalin resin, which composition can adhere various fibers to rubbers.Type: GrantFiled: July 7, 1989Date of Patent: October 16, 1990Assignee: Sumitomo Naugatuck Co., Ltd.Inventors: Yasushi Toyoda, Saburo Mishiba
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Patent number: 4957968Abstract: The present invention relates to an adhesive thermoplastic elastomer composition comprising three major components as follows:(a) at least one polyolefin modified by a chemically reactive functional group such as a carboxylic acid or its derivatives including anhydride, acid chloride, isocyanate, oxazoline, epoxide, amine and hydroxide;(b) at least one other polymer prepared from one or more of the following: ethylene, propylene, butylene, isobutylene, octene-1, 4 methyl pentene-1, hexene-1 or mixtures; and(c) at least one olefinic elastomer, including elastomeric ethylene-propylene copolymers, elastomeric ethylene-propylene terpolymers, polyisoprene, polyisobutylene, ethylene-propylene copoloymer rubber, polybutadiene, natural rubber, elastomeric polyesters, polyurethane elastomers, polyamide elastomers and mixtures.Type: GrantFiled: August 9, 1988Date of Patent: September 18, 1990Assignee: Monsanto CompanyInventors: Ashok M. Adur, Robert C. Constable
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Patent number: 4946895Abstract: A resinous composition suitable for powder coating on metals on which a heat resistant coating layer is formed contains (A) modified polypropylene in which unsaturated carboxylic acid or anhydride is grafted on crystalline propylene/.alpha.-olefin copolymer, (B) ethylene polymer, (C) metal oxide or hydroxide and (D) polymers of C.sub.6 or more vinyl cycloalkane and the composition contains 0.001-1.0% by weight of the vinyl cycloalkane unit.Type: GrantFiled: September 29, 1989Date of Patent: August 7, 1990Assignee: Sumitomo Chemical Company, Ltd.Inventors: Tadayuki Ohmae, Kentaro Mashita, Kizuku Wakatsuki, Toshio Kawakita
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Patent number: 4940754Abstract: Opaque, thermoplastic molding compositions comprising a grafted rubber phase and a matrix phase comprising styrene, acrylonitrile, and from 1 to 18 percent of a lower alkyl methacrylate and having improved colorability are disclosed.Type: GrantFiled: May 17, 1988Date of Patent: July 10, 1990Assignee: The Dow Chemical CompanyInventors: Todd T. Lensmire, Robert J. Donald, Sheldon G. Turley, Bruce J. Tallmadge
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Patent number: 4937286Abstract: Thermoplastic moulding compositions ofA. 90 to 30 parts by weight of a copolymer prepared by solution or bulk polymerization of a.sub.1 30 to 45% by weight of .alpha.-methylstyrene, a.sub.2 26 to 35% by weight of acrylonitrile and a.sub.3 44 to 20% by weight of styrene and/or p-methylstyrene, and with a content of incorporated acrylonitrile of 27-30% by weight,B. 5 to 60 parts by weight of a random copolymer of b.sub.1 18 to 24% by weight of maleic anhydride and b.sub.2 82 to 76% by weight of styrene and/or p-methylstyrene andC. 5 to 40 parts by weight of a graft polymer of 70 to 30% by weight of a mixture of c.sub.1 a vinylaromatic and/or C.sub.1 -C.sub.4 -alkyl and c.sub.2 acrylonitrile, on 30 to 70% by weight of a rubber with a glass transistion temperature of less than -10.degree. C.Type: GrantFiled: October 13, 1987Date of Patent: June 26, 1990Assignee: Bayer AktiengesellschaftInventors: Frank Wingler, Klaus Summermann, Ulrich Jansen, Joachim Doring, Alfred Pischtschan
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Patent number: 4910254Abstract: A film prepared from a compatibilized resin blend comprising an olefin polymer, a polymer of a vinyl aromatic monomer and a compatibilizing amount of a graft copolymer of a vinyl aromatic monomer and an EPDM rubber exhibits improved properties making it highly desirable in such end uses as grocery and trash bags.Type: GrantFiled: September 24, 1987Date of Patent: March 20, 1990Assignee: The Dow Chemical CompanyInventor: Robert T. Johnston
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Patent number: 4906699Abstract: A composition universally usable as an impact modifier for synthetic resins comprising(A) from 10 to 80 percent by weight of a polymer of the formula ##STR1## wherein R.sub.1 is hydrogen or methyl, R.sub.2 is C.sub.5 -C.sub.7 cycloalkyl or such cycloalkyl substituted by C.sub.1 -C.sub.12 alkyl, y has a value such that the corresponding monomer or monomers are from 5 to 50 percent by weight of polymer (A), and x has a value such that the corresponding monomer, together with up to 20 percent by weight of one or more optional comonomers, is the balance by weight, and(B) from 20 to 90 percent by weight of an optionally crosslinked polymer having a glass transition temperature, T.sub.g, below 10.degree. C. and preferably less than -10.degree. C., polymer (B) being at least partially bonded covalently to polymer (A).Type: GrantFiled: December 13, 1988Date of Patent: March 6, 1990Assignee: Rohm GmbHInventors: Werner Siol, Jens-Dieter Fischer, Klaus Koralewski, Ulrich Terbrack
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Patent number: 4904730Abstract: An impact resistant polymeric composition and a process for its production. The composition comprises a rigid polymeric matrix comprising an anionically polymerized copolymer of at least one isopropenyl aromatic monomer and at least one vinyl aromatic monomer, said matrix having dispersed therein an elastomeric phase comprising at least one moderately cross-linked ungrafted rubber and at least one moderately cross-linked lightly-grafted rubber, wherein the lightly-grafted rubber has a graft-to-rubber ratio of 0.9:1 or less. The elastomeric phase is melt agglomerated to provide aggregates having particle sizes in the range from 3,000 to 100,000.Type: GrantFiled: May 30, 1989Date of Patent: February 27, 1990Assignee: The Dow Chemical CompanyInventors: Eugene R. Moore, Thomas D. Traugott
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Patent number: 4897447Abstract: A thermoplastic molding composition and modifier for improving the impact strength and toughness thereof in which the modifier is the combination of (1) an EPM or EPDM rubber grafted with an alpha-beta unsaturated dicarboxylic acid or anhydride or an epoxy functional alpha-beta ethylenically unsaturated hydrocarbon and (2) an epoxy acrylate oligomer of bisphenol A.Type: GrantFiled: December 28, 1987Date of Patent: January 30, 1990Assignee: Copolymer Rubber & Chemical Corp.Inventor: William G. Williams
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Patent number: 4889888Abstract: Elastoplastic compositions comprising a continuous crystalline polyolefin phase and at least two phases discretely dispersed in the polyolefin phase, one of which is a dynamically cured EPDM rubber and the other an amorphous and thermoplastic styrene polymer, in which at least 80% of the dispersed particles has a maximum size preferably below 5 .mu.m.The compositions are prepared by masticating a mixture of the components under conditions of dynamic curing of rubber.Type: GrantFiled: December 9, 1988Date of Patent: December 26, 1989Assignee: Himont IncorporatedInventors: Mauro Bassi, Enea Garagnani, Giuseppe Gorini
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Patent number: 4885337Abstract: Process for the preparation of a thermoplastic moulding composition of 10 to 65% by weight of at least one graft polymer which is obtainable by emulsion polymerization of styrene and acrylonitrile in a weight ratio of 90:10 to 50:50, it being possible for all or some of the styrene to be replaced by .alpha.-methylstyrene or methyl methacrylate, in the presence of at least one rubber base, and the weight ratio of monomers employed to rubber polymer employed being 20:80 to 70:30, and 90 to 35% by weight of a copolymer of styrene and acrylonitrile in a weight ratio of 90:10 to 50:50, it being possible for all or some of the styrene to be replaced by .alpha.-methylstyrene or methyl methacrylate, wherein, to prepare the graft polymer, the grafting monomers and 0.05 to 1.00 part by weight (per 100 parts by weight of grafting monomer) of a mercaptan are added stepwise to the latex of the rubber base over a period of time, the part amount of the monomer added in each time interval .DELTA.t.sub.n+1 being 0.30 to 0.Type: GrantFiled: July 6, 1987Date of Patent: December 5, 1989Assignee: Bayer AktiengesellschaftInventors: Herbert Eichenauer, Alfred Pischtschan, Karl-Heinz Ott
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Patent number: 4882383Abstract: Thermoplastic compositions comprising rubber modified polyalkenyl aromatic resin and a modifying agent having a core-shell structure comprised of an interpenetrating, cross-linked (meth)acrylate core and a cross-linked styrenic resin shell have significantly improved impact strength, thermal resistance and surface appearance following molding into shaped articles.Type: GrantFiled: July 21, 1987Date of Patent: November 21, 1989Assignee: General Electric Co.Inventor: Sai-Pei Ting
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Patent number: 4849473Abstract: Strengthened high impact resistant styrene polymers having improved physical-mechanical properties, particularly a high resilience at room temperature and at lower temperatures, and break elongation, containing as a dispersed phase an olefinic rubber, preferably an ethylene-propylene or an ethylene-propylene-diene rubber and a polyolefin. The amount of the polyolefin may be up to 15% by weight.Type: GrantFiled: May 12, 1987Date of Patent: July 18, 1989Assignee: Montedipe S.p.A.Inventors: Giuseppe Cigna, Gian C. Fasulo, Gianfranco Biglione, Italo Borghi
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Patent number: H758Abstract: A sealant composition comprises a functionalized polymer component which is prepared by grafting enough carboxylic acid, dicarboxylic acid, or derivative thereof onto a polymer component to thereby functionalize the polymer component and provide a resultant sealant composition with adhesive which is resistant to deterioration in the presence of water, said polymer component comprising a multiblock copolymer having at least two end blocks A and at least one midblock B, wherein the A blocks comprise monoalkenyl arene blocks and the B blocks comprise substantially completely hydrogenated conjugated diene polymer blocks.Type: GrantFiled: December 23, 1987Date of Patent: April 3, 1990Inventor: Steven S. Chin