Mixture Contains Two Or More Solid Block Or Block-type Copolymers Patents (Class 525/89)
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Patent number: 12091541Abstract: A solid organic material comprising at least one amphiphilic block copolymer of the methacrylic type, the block copolymer being dispersed in a polymer matrix, the block copolymer having a number-average molar mass (Mn) greater than or equal to 20 000 g/mol; a method for preparing said solid organic material; use of said solid organic material for antibacterial, antimicrobial, antiviral, anti-inflammatory and/or antifungal applications; a medical device comprising said solid organic material.Type: GrantFiled: July 6, 2018Date of Patent: September 17, 2024Assignees: Centre national de la recherche scientifique, UNIVERSITÉ D'AIX MARSEILLE, Ecole Centrale de MarseilleInventors: Didier Gigmes, Yohann Guillaneuf, Catherine Guillaneuf, Marc René Sauveur Maresca, Cédric Ysacco
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Patent number: 12084568Abstract: A thermoplastic elastomer composition for overmolding a predominantly polyamide substrate, a method for the preparation of an overmolded article, and an overmolded article having a layer of thermoplastic elastomer is provided. The thermoplastic elastomer composition comprises a thermoplastic vulcanizate, an olefinic block copolymer, and a maleated functionalized polyolefin copolymer. The method for the preparation of the overmolded article comprises heating the thermoplastic elastomer composition followed by applying the heated composition to at least a portion of the predominantly polyamide substrate.Type: GrantFiled: June 9, 2023Date of Patent: September 10, 2024Assignee: Star Thermoplastic Alloys and Rubbers, LLCInventors: Prakash Sanjeevaiah, Krishna Venkataswamy, Pei-Zhen Jian
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Patent number: 12049528Abstract: Provided herein are curable compositions for use in a high temperature lithography-based photopolymerization process, and telechelic block polymers and methods of using such polymers in curable compositions to produce medical devices such as orthodontic appliances comprising the polymeric compositions comprising the telechelic block polymers.Type: GrantFiled: April 25, 2022Date of Patent: July 30, 2024Assignee: ALIGN TECHNOLOGY, INC.Inventors: Umesh Upendra Choudhary, Jessica Kalay Su, Michael Christopher Cole, Jennifer Marie Chavez
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Patent number: 11873392Abstract: Disclosed are a polypropylene-based resin composition comprising 5 to 47 parts by mass of a propylene-based polymer (A) having an MFR of 50 to 150 g/10 min and an amount of a decane-soluble part of 6% by mass or more, 0 to 30 parts by mass of a propylene homopolymer (B) having an MFR of 10 to 500 g/10 min, 23 to 30 parts by mass of an ethylene-?-olefin copolymer (C) which is a random copolymer composed of ethylene and an ?-olefin having 4 to 8 carbon atoms, and has a density of 0.850 to 0.890 g/cm3 and an MFR of 0.5 to 30 g/10 min, and 30 to 40 parts by mass of an inorganic filler (D) having an average particle size of over 3.0 ?m and less than 5.0 ?m [the total amount of the components (A) to (D) is 100 parts by mass]; and an automobile exterior member obtained by injection-molding or press-molding the composition.Type: GrantFiled: November 10, 2016Date of Patent: January 16, 2024Assignee: PRIME POLYMER CO., LTD.Inventors: Akira Minowa, Shuichi Takahashi, Yusuke Fukuda, Hiroyuki Ikeno
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Patent number: 11820111Abstract: A tile comprising the following components: A) a first film formed from a first composition comprising the following: i) a functionalized olefin-based polymer comprising one or more chemical groups selected from the following: a) a carboxylic acid, and/or b) an anhydride, and, optionally, c) an amino or an amine; and ii) a functionalized styrenic block copolymer, comprising, in polymerized form, styrene, and ethylene and/or at least one alpha-olefin, and comprising one or more chemical groups selected from the following: a) a carboxylic acid, and/or b) an anhydride; and B) a substrate comprising at least one layer formed from a second composition comprising a propylene-based polymer; and wherein the first film covers at least one surface of the substrate.Type: GrantFiled: October 23, 2018Date of Patent: November 21, 2023Assignee: Dow Global Technologies LLCInventors: Susan G. Brown, Qichun Wan, Ronald J. Weeks, Mark T. Jablonka, Rennisha R. Wickham, Colin LiPiShan, Miguel Alberto de Jesus Prieto
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Patent number: 11787979Abstract: An adhesive composition, an adhesive film comprising the same, a backplate film comprising the adhesive film, and a plastic organic light emitting display comprising the adhesive film are provided. The adhesive composition includes a (meth)acrylate-based resin, and a polymer having a melting temperature (Tm) of 35° C. or higher, wherein the polymer is a copolymer of a monofunctional polysiloxane and two or more types of monomers.Type: GrantFiled: July 29, 2019Date of Patent: October 17, 2023Inventors: Seongwook Kang, Yoonkyung Kwon, Byungsu Park, Hui Je Lee, Sanghun Han
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Patent number: 11746231Abstract: A transparent static-dissipative polycarbonate (PC) resin composition includes the following components: 70-95 parts by weight of PC resin, 5-30 parts by weight of antistatic agent masterbatch and 0.5-1.5 parts by weight of a transesterification inhibitor. The antistatic agent masterbatch includes the following components by mass percentage: 40-60% of an antistatic agent, 0.5-1.6% of a transesterification accelerator, 1-3% of an assistant cross-linkinger, and the balance of PC resin. A method for preparing the transparent static-dissipative PC resin composition includes the following steps: (I) preparing the components of the transparent static-dissipative PC resin composition according to the formulation, and mixing the components evenly to obtain a premix; and (II) adding the premix into a twin-screw extruder, melting, extruding, cooling and pelletizing, to obtain a target product.Type: GrantFiled: January 22, 2021Date of Patent: September 5, 2023Assignees: SHANGHAI KUMHOSUNNY PLASTICS CO., LTD., SHANGHAI KUMHOSUNNY (JINSHAN) PLASTICS CO., LTD.Inventors: Chao Zha, Ting Zhou, Minqi Xin
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Patent number: 11713390Abstract: A thermoplastic elastomer composition for overmolding a predominantly polyamide substrate, a method for the preparation of an overmolded article, and an overmolded article having a layer of thermoplastic elastomer is provided. The thermoplastic elastomer composition comprises a thermoplastic vulcanizate, an olefinic block copolymer, and a maleated functionalized polyolefin copolymer. The method for the preparation of the overmolded article comprises heating the thermoplastic elastomer composition followed by applying the heated composition to at least a portion of the predominantly polyamide substrate.Type: GrantFiled: December 23, 2020Date of Patent: August 1, 2023Assignee: Star Thermoplastic Alloys & Rubbers, Inc.Inventors: Prakash Sanjeevaiah, Krishna Venkataswamy, Pei-Zhen Jian
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Patent number: 11466148Abstract: The present invention is directed to a polyolefin composition (C) containing a heterophasic propylene copolymer (TERHECO) and a styrenic thermoplastic (sTPE), wherein the heterophasic propylene copolymer (TERHECO) consists of units derived from propylene, ethylene and 1-hexene. Further the present invention is directed to articles made from the polyolefin composition (C) as well as to the production of sterilized articles.Type: GrantFiled: April 28, 2020Date of Patent: October 11, 2022Assignee: Borealis AGInventors: Jingbo Wang, Markus Gahleitner, Klaus Bernreitner, Pauli Leskinen
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Patent number: 11292897Abstract: A composition comprising (A) from 10 wt % to 90 wt % of a propylene component including at least one propylene based polymer having a propylene content of at least 50.0 wt %, based on the total weight of the propylene based polymer, and a melt flow rate from 0.5 g/10 min to 200.0 g/10 min (ASTM D-1238 at 230° C., 2.16 kg); (B) from 1 wt % to 60 wt % of a polyolefin elastomer; (C) from 1 wt % to 20 wt % of a block composite comprising (i) an ethylene-propylene copolymer, (ii) an isotactic polypropylene copolymer, and (iii) a block copolymer including an ethylene-propylene soft block that has a same composition as the ethylene-propylene copolymer of the block composite and an isotactic polypropylene hard block that has a same composition as the isotactic polypropylene copolymer of the block composite; and (D) optionally, from 0.1 wt % to 10 wt % of an antioxidant.Type: GrantFiled: May 24, 2017Date of Patent: April 5, 2022Assignee: Dow Global Technologies LLCInventors: Olaf Henschke, Yahong Zhang, Wei Li, Hang Wu, Takahiko Ohmura, Yushan Hu, Ming Ming, Krischan Jeltsch
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Patent number: 10767033Abstract: A coupled block copolymer composition with a combination of high viscosity at manufacturing, finishing and handling conditions, low viscosity at asphalt blending conditions and suitable viscosity stability is provided for use in asphalt compositions. The composition comprises: (i) a diblock copolymer, (ii) at least a linear triblock copolymer having a peak molecular weight that is 1.5 to 3.0 times the peak molecular weight of the diblock copolymer, and (iii) at least a multiarm coupled block copolymer having a peak molecular weight that is 1.5 to 9.0 times the peak molecular weight of the diblock copolymer, and mixtures thereof. The block copolymer composition is characterized as having a melt viscosity at 110° C. or less of greater than 2.0E7 Poise and a coupling efficiency after 24 hours at 180° C. is less than 25%.Type: GrantFiled: May 18, 2018Date of Patent: September 8, 2020Assignee: Kraton Polymers LLCInventors: Robert Q Kluttz, Erica Jellema, Donn A. Dubois, Sebastian Puchalski, Carl L. Willis, Christopher M. Lubbers
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Patent number: 10472514Abstract: A block copolymer composition including: 10% by mass or more and 90% by mass or less of a component (a), and 10% by mass or more and 90% by mass or less of a component (b), wherein the component (a) is a block copolymer containing a polymer block (A) primarily including a vinyl aromatic monomer unit and a polymer block (B) primarily including a conjugated diene monomer unit, wherein the block copolymer has a weight average molecular weight of 30,000 or higher and 150,000 or lower; and the component (b) is a block copolymer containing a polymer block (A) primarily including a vinyl aromatic monomer unit and a polymer block (B) primarily including a conjugated diene monomer unit.Type: GrantFiled: January 22, 2015Date of Patent: November 12, 2019Assignees: Asahi Kasei Kabushiki Kaisha, Japan Elastomer Co., Ltd.Inventors: Takahiro Hisasue, Shigeo Nakajima, Yoshifumi Araki, Yukinori Nakamichi
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Patent number: 10414957Abstract: This invention claims low application temperature hot melt adhesive compositions including at least about 15% by weight of a first styrene block copolymer with a melt flow rate of at least about 15 g/10 minutes (190° C., 2.16 kgs) and a diblock content of no greater than about 10% by weight.Type: GrantFiled: March 16, 2016Date of Patent: September 17, 2019Assignee: H.B. Fuller CompanyInventors: Ameara S. Mansour, Kevin P. Davis, David B. Malcolm, Mark S. Kroll, Steven R. Vaughan, Timothy W. Roska, Evan Yuan
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Patent number: 9976053Abstract: The invention relates to a block copolymer film nanostructured into nanodomains, obtained from a base block copolymer having a molecular weight of greater than 50 kg/mol, and preferably greater than 100 kg/mol and less than 250 kg/mol, and at least one block of which comprises styrene, and at least one other block of which comprises methyl methacrylate. This film is characterized in that the styrene-based block is formed by a copolymer of styrene and diphenylethylene (DPE).Type: GrantFiled: June 1, 2015Date of Patent: May 22, 2018Assignee: ARKEMA FRANCEInventors: Christophe Navarro, Celia Nicolet, Xavier Chevalier
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Patent number: 9932463Abstract: The present disclosure relates to a curable transparent rubber composition containing one or more synthetic isoprene polymers, a styrenic block copolymer, a curing agent, and additives that do not influence transparency of the final composition. Once cured, the curable transparent rubber composition has a haze of less than 30% and a total light transmission of more than 80%. The disclosure further relates to a cured transparent rubber composition made thereof, and a manufacturing process for the cured composition. The present disclosure also relates to an article including the rubber composition, in particular for tubes, medical stoppers, catheters, dental dams and other medical applications and artificial nipples.Type: GrantFiled: March 29, 2016Date of Patent: April 3, 2018Assignee: Kraton Polymers U.S. LLCInventors: Arie Willem Van Der Waal, Joris Smit
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Patent number: 9856599Abstract: The present invention provides a coated yarn and a method for manufacturing a coated yarn having outstanding physical properties, the method comprising: collecting thermoplastic polyurethane in virgin form, or from scraps remaining after usage, for example, those used for airbag patterns in a shoe manufacturing process, or from scraps remaining after other thermoplastic polyurethane is processed; mixing the various kinds of thermoplastic polyurethane with various additives; compounding the resultant mixture using an extruder to prepare a thermoplastic polyurethane compound for a coated yarn; and coating the surface of a yarn made from polyester, nylon, spandex, etc. with the compound using an extruder.Type: GrantFiled: June 25, 2014Date of Patent: January 2, 2018Inventor: Heedae Park
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Patent number: 9732215Abstract: A block copolymer composition with a good balance of physical properties suitable for various types of packaging such as food product containers, beverage containers, industrial containers and blister packs, having excellent transparency, gloss, strength, rigidity and formability, having excellent anti-blocking properties and anti-sticking properties, and excelling in the aforementioned properties even when used in mixture with vinyl aromatic hydrocarbon-type polymers is offered.Type: GrantFiled: May 2, 2013Date of Patent: August 15, 2017Assignee: DENKA COMPANY LIMITEDInventors: Tadashi Sawasato, Eiji Sato, Hitoshi Nakazawa, Shinya Uekusa
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Patent number: 9546266Abstract: A polyamide composition comprises a polyamide, an anhydride-functional copolymer reactive with the polyamide, and a poly (ethylene-co-methacrylic acid) ionomer. A pneumatic tire assembly includes an inner liner which is formed from the polyamide composition. The inner liner comprises the reaction product of the polyamide and the anhydride-functional copolymer, as well as the (ethylene-co-methacrylic acid) ionomer.Type: GrantFiled: March 4, 2014Date of Patent: January 17, 2017Assignee: BASF SEInventors: Stephen Hanley, Zhenguo Liu
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Patent number: 9441066Abstract: An oxygen scavenger composition for food packaging application comprising (I) a polymeric resin, (II) one or more oligomeric photosensitizers, (III) a metal salt, preferably Cu stearate or Mn stearate; (IV) a sacrificial oxidizable substrate, and optionally (V) additional components.Type: GrantFiled: November 29, 2010Date of Patent: September 13, 2016Assignee: BASF SEInventors: Edoardo Menozzi, Enrico Galfré
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Patent number: 9350046Abstract: An electrochemical battery cell of a lithium ion battery has a physically cross-linked gel electrolyte situated between a negative electrode and a positive electrode. The gel electrolyte includes a block co-polymer host and a liquid electrolyte, which can transport lithium ions, absorbed into the block co-polymer host. The block co-polymer host includes poly(alkylene oxide) block units and physically cross-linkable block units. A few preferred physically cross-linkable block units that may be employed include polyamide block units and poly(terephthalate)ester block units.Type: GrantFiled: July 18, 2012Date of Patent: May 24, 2016Assignee: GM Global Technology Operations LLCInventor: Xiaosong Huang
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Patent number: 9290646Abstract: A molded article made from and/or containing a polymeric composition made from and/or containing a high melt flow rate polypropylene homopolymer composition, a compatibilizer, a polyethylene-based elastomer, and talc is provided. An automobile part, including bumper facias, body side-molding, instrumental panels, side pillars, and door trims, with improved coefficients of linear thermal expansion is also provided.Type: GrantFiled: October 4, 2013Date of Patent: March 22, 2016Assignee: Equistar Chemicals, LPInventors: Todd A. Glogovsky, Brent Mrozinski
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Patent number: 9206304Abstract: Composition having a melt flow rate MFR2 (230° C.) measured according to ISO 1133 in the range of 15 to 30 g/10 min, said composition comprises a heterophasic propylene copolymer (H-PP1), a high melt flow polypropylene (HMF-PP), a styrenic block copolymer (SBC) and a mineral filler (F), wherein (a) the heterophasic propylene copolymer (H-PP1) has a xylene cold soluble (XCS) content measured according to ISO 6427 in the range of 22.0 to 50.0 wt.-% and comprises (a1) a polypropylene matrix (M1) and (a2) an elastomeric copolymer (E1) comprising units derived from propylene and ethylene and/or C4 to C12 ?-olefin, (b) the melt flow rate MFR2 (230° C.) measured according to ISO 1133 of the high melt flow polypropylene (HMF-PP) is higher than the melt flow rate MFR2 (230° C.) measured according to ISO 1133 of the heterophasic propylene copolymer (H-PP1), and (c) the high melt flow polypropylene (HMF-PP) has melt flow rate MFR2 (230° C.) measured according to ISO 1133 of at least 40.0 g/10 min.Type: GrantFiled: April 15, 2011Date of Patent: December 8, 2015Assignee: Borealis AGInventors: Klaus Lederer, Erwin Kastner
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Patent number: 9138970Abstract: Disclosed is a thermally shrinkable laminated film which is produced by laminating an intermediate layer comprising a block copolymer resin composition containing a specific block copolymer directly between a front layer and a back layer each comprising a polyester resin, and which has good interlayer adhesion strength. Specifically disclosed is a thermally shrinkable laminated film which is produced by stretching a three-layered laminated sheet along at least one axis so that the interlayer adhesion strength becomes 0.6 N/15 mm or more, wherein the three-layered laminated sheet has an intermediate layer and a front layer and a back layer, the intermediate layer comprises a resin composition comprising two types of block copolymers each having a specific structure and a specific composition at a predetermined mass ratio, and each of the front layer and the back layer comprises a polyester resin.Type: GrantFiled: September 28, 2010Date of Patent: September 22, 2015Assignee: DENKI KAGAKU KOGYO KABUSHIKI KAISHAInventors: Eiji Sato, Masayuki Ohishi, Hitoshi Nakazawa
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Patent number: 9139723Abstract: A polypropylene resin composition includes 1 to 30 wt % of homopolypropylene having a melt index of 2 to 6 g/10 min at 230° C. and 2.16 kg, and an isotacticity index of 97% or more, 1 to 40 wt % of homopolypropylene having a melt index of 16 to 22 g/10 min at 230° C. and 2.16 kg, and an isotacticity index of 96% or more, and 20 to 40 wt % of a glass fiber having an excellent rigidity supplementation effect as an inorganic filler for improving heat resistance, mechanical properties, and 1 to 10 wt % of denatured polypropylene as a compatibilizer maximizes compatibility of the polypropylene resin and the glass fiber, based on a total weight of the composition. The composition has excellent rigidity, short-term heat resistance, long-term heat resistance, and fusion strength, at a reduced weight and production cost.Type: GrantFiled: December 19, 2013Date of Patent: September 22, 2015Assignees: HYUNDAI MOTOR COMPANY, Kia Motors CorporationInventors: Jee-Young Youn, Hyeok-Jung Lim
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Patent number: 9062137Abstract: There is provided as an antistatic agent that preserves antistatic properties for a long period of time and that does not impair the appearance and transparency of a resin into which the antistatic agent is kneaded, and a resin composition containing the antistatic agent. The antistatic agent including a block copolymer; a thermoplastic resin composition including the antistatic agent; and a film or sheet including the composition.Type: GrantFiled: July 26, 2011Date of Patent: June 23, 2015Assignee: TOHO CHEMICAL INDUSTRY CO., LTD.Inventor: Tetsuhiro Utsumi
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Patent number: 9056975Abstract: An elastomeric composition, and method of making the same, useful for forming thin films and sheets, comprising 55-60% hydrogenated SEEPS having a number average molecular weight of 90,000 to 100,000, 7-12% polystyrene, 15-30% oil, and 5 to 20% of an aliphatic hydrogenated hydrocarbon resin.Type: GrantFiled: February 14, 2012Date of Patent: June 16, 2015Assignee: KURARAY AMERICA, INC.Inventors: Brian K. Chapman, Heith A. Foster
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Patent number: 9028933Abstract: The present invention is a shrink label, comprising a heat-shrinkable multilayer resin film comprising an intermediate layer comprising a polystyrene type resin and outer surface layers comprising a polyester type resin, with said intermediate layer interposed therebetween, as a base film, wherein the polystyrene type resin composing said intermediate layer is an aromatic vinyl hydrocarbon-conjugated diene copolymer, and said intermediate layer is bonded to said outer surface layers with an adhesive layer comprising a hydrogen addition product of an aromatic vinyl hydrocarbon-conjugated diene copolymer, having at least one functional group selected from the group consisting of a carboxylic group, an acid anhydride group, an amino group, an epoxy group and a hydroxyl group in a molecule.Type: GrantFiled: February 16, 2006Date of Patent: May 12, 2015Assignee: Gunze LimitedInventors: Naoyuki Maruichi, Takanori Nozaki, Akira Morikawa
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Publication number: 20150079389Abstract: Adhesive compound as a permeant barrier, comprising (i) block copolymers having a construction A-B-A, (A-B)n, (A-B)nX, or (A-B-A)nX, where X is the radical of the coupling reagent, n is a whole number between 2 and 10, A is a polymer made of a vinyl aromatic compound and B is a polymer block made of an alkene or diene, wherein this polymer block can also be hydrated, with the condition that at least part of the A blocks is sulfonated, optionally with two-block copolymers in the form of A-B as an admixture component, and (ii) at least one tackifier resin.Type: ApplicationFiled: March 25, 2013Publication date: March 19, 2015Inventors: Thorsten Krawinkel, Klaus Keite-Telgenbüsher, Judith Grünauer, Jan Ellinger
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Publication number: 20150073094Abstract: The present invention relates to a process for producing nanostructured films obtained from block copolymers exhibiting a dispersity index of between 1.1 and 2, limits included, without nanostructuring defects, on a surface, in order for this treated surface to be able to be used as masks for applications in microelectronics.Type: ApplicationFiled: September 9, 2014Publication date: March 12, 2015Applicants: ARKEMA FRANCE, CNRS, UNIVERSITÉ DE BORDEAUX, INSTITUT POLYTECHNIQUE DE BORDEAUXInventors: Christophe Navarro, Xavier Chevalier, Celia Nicolet, Ilias Iliopoulos, Raluca Tiron, Guillaume Fleury, Georges Hadziioannou
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Patent number: 8975329Abstract: A composition useful for the injection molding of fluid engineering parts includes specific amounts of a high molecular weight poly(phenylene ether), a polystyrene, and glass fibers. The composition provides improved hydrostability and reduces or eliminates the butadiene monomer that is present in comparative compositions containing rubber-modified polystyrene. Fluid engineering articles prepared from the composition are described.Type: GrantFiled: November 26, 2012Date of Patent: March 10, 2015Assignee: SABIC Global Technologies B.V.Inventors: Christiaan Johannes Henricus Koevoets, Marcellus Antonius Adrianus Verhagen, Erik Stam
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Publication number: 20150064630Abstract: A method is disclosed to form a row of mutually spaced elongate lithography features along an axis on a substrate, for instance for use as contact electrodes for a NAND device. The method involves directing alignment of self-assemblable block copolymer (BCP) composition in a trench in a resist layer on the substrate, having the substrate as base, with an epitaxy feature in the trench to cause the ordered BCP layer to have elongate domains stretching across the trench width, substantially parallel to each other and to the substrate. The ordered BCP layer is then used as a resist to pattern the substrate. A BCP composition adapted to assemble with spaced discontinuous elongate elliptical domains is disclosed. The method may allow for sub-resolution contact arrays to be formed using UV lithography.Type: ApplicationFiled: March 19, 2013Publication date: March 5, 2015Applicant: ASML Netherlands B.V.Inventors: Sander Frederik Wuister, Emiel Peeters
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Patent number: 8957154Abstract: A disk-like nanoparticle includes a core layer that comprises a cross-linked multi-vinyl substituted aromatic hydrocarbon and a shell layer that comprises tri-block copolymer chains, each having a first, a second, and a third block. The first and third blocks of the tri-block copolymer chains comprise vinyl aromatic monomer units and are crosslinked with the core. The second block comprises conjugated diene monomer units and comprises a top and bottom axial surface of the disk-like nanoparticle. In the case of a nanoparticle having A-B-C tri-block copolymer chains, the third block comprises a top and bottom axial surface of the disk-like nanoparticle.Type: GrantFiled: October 15, 2012Date of Patent: February 17, 2015Assignee: Bridgestone CorporationInventors: Xiaorong Wang, Victor J Foltz, Yuan-Yong Yan
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Patent number: 8932152Abstract: A center of a golf ball is formed from a composition having a flexural modulus from 150-450 MPa, a maximum loss factor (tan ?) between ?20 and 0° C. of 0.08 or less, a rebound resilience of 55% or more, and a slab hardness ranging from 40-60 in Shore D hardness. The center composition includes, as a resin component, 30 to 70 mass % of (A) a modified polyester elastomer having a Shore A hardness of 95 or less; 70-30 mass % of (B) a binary ionomer resin having a Shore D hardness of 65 or more, a flexural modulus of 300 MPa or more, and a melt flow rate (190° C., 2.16 kg) of 1.0 g/10 min or more; and 0-50 mass % of (C) a thermoplastic resin other than (A) and (B) components (provided that a total content of (A), (B), and (C) components is 100 mass %).Type: GrantFiled: October 4, 2012Date of Patent: January 13, 2015Assignee: Dunlop Sports Co. Ltd.Inventor: Satoko Okabe
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Patent number: 8933171Abstract: Disclosed are cold flow resistant and dimensionally stable compositions containing a diene rubber and a conjugated diene monovinylarene block copolymer, and generally, these compositions have solutions viscosities and cold flows that are less than that of the diene rubber. Methods for reducing cold flow and for storage-stabilizing bales of diene rubbers also are disclosed.Type: GrantFiled: March 8, 2013Date of Patent: January 13, 2015Assignee: Chevron Phillips Chemical Company LPInventors: Cliff C. Pettey, David L. Hartsock, Jinping Joe Zhou
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Patent number: 8921485Abstract: The present invention relates to a moisture-curable adhesive composition applicable to production of automobile interior parts, having excellent adhesion to polyolefins such as polypropylene and polyethylene, and having excellent heat resistance. More specifically, the present invention relates to an adhesive composition comprising: a styrene block copolymer (A) having at least one unsaturated bond, a hydrogenated styrene block copolymer (B) having a styrene content of 15% by weight or more, a silane compound (C) having an unsaturated bond, an acid-modified polyolefin resin (D), and a polymerization initiator (E).Type: GrantFiled: December 11, 2008Date of Patent: December 30, 2014Assignee: Sunstar Giken Kabushiki KaishaInventors: Atsushi Uno, Yoshimi Shibata
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Publication number: 20140377533Abstract: Pressure sensitive adhesive compositions containing 92 to 99.9 parts of a block copolymer adhesive composition and 0.1 to less than 8 parts of an acrylic adhesive composition are described. Tapes including such adhesives, and methods of making such tapes are also described.Type: ApplicationFiled: September 12, 2014Publication date: December 25, 2014Inventors: Robert D. Waid, Panu K. Zoller, Gregory B. Gadbois
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Patent number: 8912270Abstract: Processes for enhancing blown film processability and the blown films formed thereby are described herein. One embodiment of the processes generally includes providing a first propylene based heterophasic copolymer having a first melt flow rate, modifying the first propylene based heterophasic copolymer to form a second heterophasic polymer having a second melt flow rate, wherein the second melt flow rate is greater than the first melt flow rate, contacting the first heterophasic polymer, the second heterophasic copolymer or a combination thereof with a plurality of additives, wherein the plurality of additives include a nucleator, polyethylene and mineral oil to form a modified heterophasic copolymer and blowing the modified heterophasic polymer into a film.Type: GrantFiled: December 21, 2011Date of Patent: December 16, 2014Assignee: Fina Technology, Inc.Inventors: Rodolfo Mier, Mark B. Miller
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Patent number: 8865823Abstract: A poly(phenylene ether)-poly(hydroxy ether)-poly(phenylene ether) (PPE-PHE-PPE) triblock copolymer is formed by reaction of a monohydroxy-terminated poly(phenylene ether) with a diepoxy-terminated poly(hydroxy ether) in the presence of a base. The PPE-PHE-PPE triblock copolymer is useful as a compatibilizer in blends of polar polymers and non-polar polymers. The PPE-PHE-PPE triblock copolymer is also useful as a compatibilizer for non-polar polymers and polar fillers.Type: GrantFiled: February 1, 2013Date of Patent: October 21, 2014Assignee: Sabic Global Technologies B.V.Inventor: Edward Norman Peters
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Patent number: 8853311Abstract: In one embodiment, a block copolymer-containing composition includes PS-b-PXVP and a lithium salt, where “X” is 2 or 4. All lithium salt is present in the composition at no greater than 1 ppm by weight. In one embodiment, a homogenous block copolymer-including comprising has PS-b-PXVP present in the composition at no less than 99.99998% by weight, where “X” is 2 or 4. Methods of forming such compositions are disclosed.Type: GrantFiled: September 11, 2012Date of Patent: October 7, 2014Assignee: Micron Technology, Inc.Inventors: Dan Millward, Scott Sills
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(METH)ACRYLATE-FUNCTIONAL POLYACRYLATE RESINS WITH NARROW BUT BIMODAL MOLECULAR WEIGHT DISTRIBUTIONS
Publication number: 20140283983Abstract: The present invention is directed to compositions useful for maintaining sealing force over time while under compression in compressive gaskets. Additionally, methods of preparing and using the sealing compositions and improving sealing performance using such compositions are provided.Type: ApplicationFiled: March 19, 2014Publication date: September 25, 2014Applicant: HENKEL US IP LLCInventors: Joel D. Schall, John G. Woods, Anthony F. Jacobine, Alfred A. DeCato, Eric Hernandez Edo -
Patent number: 8835557Abstract: An object of the present invention is to provide a polymer composition for an inner liner, that is excellent in air permeation resistance and adhesion with an adjacent rubber, and a pneumatic tire using the same. In the polymer composition for an inner liner, a polymer component contains 99 to 50% by mass of a styrene-isobutylene-styrene triblock copolymer, and at least one of a styrene-isoprene-styrene triblock copolymer and a styrene-isobutylene diblock copolymer in a total amount of 1 to 50% by mass.Type: GrantFiled: September 8, 2010Date of Patent: September 16, 2014Assignee: Sumitomo Rubber Industries, Ltd.Inventor: Mutsuki Sugimoto
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Patent number: 8835560Abstract: Elastomeric block copolymers having star-shaped molecular architecture, where the star-shaped molecular architecture has at least two different arms of the star, a process for producing the elastomeric block copolymers, the use of the elastomeric block copolymers for producing moldings, or as adhesive layer in multilayer foils; as seal; as adhesion promoter or thermoplastic component in wood-plastics composites; as hot-melt adhesive component; for impact-modifying thermoplastics or elastomers, or for compatibilization, and to foils, foams, thermomoldings, injection moldings, flexible tubing, or profile extrudates composed of at least one elastomeric block copolymer.Type: GrantFiled: October 27, 2011Date of Patent: September 16, 2014Assignee: Styrolution GmbHInventors: Konrad Knoll, Daniel Wagner, Andrea Colombo, Geert Verlinden
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Patent number: 8809457Abstract: An adhesive composition including a hydrocarbon resin, a modified elastomer that is bonded with at least one functional group-containing atom group, and a solvent.Type: GrantFiled: September 27, 2012Date of Patent: August 19, 2014Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Hirofumi Imai, Koki Tamura, Atsushi Kubo, Takahiro Yoshioka
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Publication number: 20140227447Abstract: A block copolymer formulation is provided including a block copolymer blend including a first poly(acrylate)-b-poly(silyl acrylate) block copolymer; and, a second poly(acrylate)-b-poly(silyl acrylate) block copolymer. Also provided are substrates treated with the block copolymer formulation.Type: ApplicationFiled: February 8, 2013Publication date: August 14, 2014Applicant: ROHM AND HAAS ELECTRONIC MATERIALS LLCInventors: Phillip Hustad, Peter Trefonas, Xinyu Gu, Shih-Wei Chang, Valeriy Ginzburg, Erin Vogel, Daniel Murray
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Publication number: 20140221552Abstract: A poly(phenylene ether)-poly(hydroxy ether)-poly(phenylene ether) (PPE-PHE-PPE) triblock copolymer is formed by reaction of a monohydroxy-terminated poly(phenylene ether) with a diepoxy-terminated poly(hydroxy ether) in the presence of a base. The PPE-PHE-PPE triblock copolymer is useful as a compatibilizer in blends of polar polymers and non-polar polymers. The PPE-PHE-PPE triblock copolymer is also useful as a compatibilizer for non-polar polymers and polar fillers.Type: ApplicationFiled: February 1, 2013Publication date: August 7, 2014Applicant: SABIC INNOVATIVE PLASTICS IP B.V.Inventor: Edward Norman Peters
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Patent number: 8791196Abstract: Provided is an adhesive composition for labels, which can be easily applied at a relatively low temperature and has satisfactory die cutting properties so that the adhesive composition can contribute to an improvement of the productivity of labels, and which is capable of producing labels having excellent holding power and tackiness. There is disclosed an adhesive composition for labels comprising: a block copolymer A represented by the following general formula (A); a polymer C, which is a polymer having a glass transition temperature of ?30° C. or lower, or a block copolymer that has a polymer block having a glass transition temperature of ?30° C. or lower at an end of the polymer chain; and a tackifier resin D.Type: GrantFiled: March 29, 2010Date of Patent: July 29, 2014Assignee: Zeon CorporationInventors: Ryouji Oda, Sadaharu Hashimoto
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Patent number: 8759445Abstract: A mixture which comprises a) from 5 to 95% by weight of a copolymer A which comprises one or more copolymer blocks (B/S)A each composed of from 65 to 95% by weight of vinylaromatic monomers and from 35 to 5% by weight of dienes and of a glass transition temperature TgA in the range from 40° to 90° C., b) from 95 to 5% by weight of a block copolymer B which comprises at least one hard block S composed of from 95 to 100% by weight of vinylaromatic monomers and of from 0 to 5 by weight of dienes, and comprises one or more copolymer blocks (B/S)A each composed of from 65 to 95% by weight of vinylaromatic monomers and of from 35 to 5% by weight of dienes and of a glass transition temperature TgA in the range from 40° to 90° C., and comprises one or more copolymer blocks (B/S)B each composed of from 20 to 60% by weight of vinylaromatic monomers and of from 80 to 40% by weight of dienes and of a glass transition temperature TgB in the range from ?70° to 0° C.Type: GrantFiled: June 23, 2009Date of Patent: June 24, 2014Assignee: Styrolution GmbHInventors: Matthias Müller, Konrad Knoll, Christof Mehler, Helmut Steininger, Norbert Güntherberg, Daniel Wagner, Michael Schuster, Geert Verlinden, Florian Greger
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Patent number: 8722800Abstract: The present invention provides a composition for a stretchable film, which achieves a high-level balance between a high elastic modulus and a small permanent elongation, which is excellent in adhesive force when laminated with a non-woven fabric or the like, and also has good formability.Type: GrantFiled: June 24, 2010Date of Patent: May 13, 2014Assignee: Zeon CorporationInventors: Ryouji Oda, Sadaharu Hashimoto
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Patent number: 8722799Abstract: There is provided a thermoplastic elastomer composition having excellent flexibility, mechanical properties, scratch resistance, abrasion resistance, and low-temperature characteristics. A crosslinked thermoplastic elastomer composition comprising 5 to 70 parts by mass of (C) a hydrogenated product of a block copolymer having at least one conjugated diene monomer unit block and at least one vinyl aromatic monomer unit block, and 20 to 150 parts by mass of (D) an olefin-based resin, based on 100 parts by mass of the total of (A) an ethylene-?-olefin copolymer comprising an ethylene unit and an ?-olefin unit having 3 to 20 carbon atoms, and (B) a copolymer having at least one hydrogenated copolymer block mainly composed of a conjugated diene monomer unit and a vinyl aromatic monomer unit, wherein a mass ratio ((A)/(B)) of the (A) component and the (B) component is from 20/80 to 75/25.Type: GrantFiled: December 4, 2009Date of Patent: May 13, 2014Assignee: Asahi Kasei Chemicals CorporationInventors: Yutaka Eguchi, Shinichi Shibayama, Yoshifumi Araki
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Patent number: 8716390Abstract: The present invention relates to a solid pigment preparation comprising, each percentage being based on the total weight of the preparation, (A) at least 60% by weight of a pigment component comprising one or more pigments and optionally a filler; (B) 1% by weight to 39% by weight of at least one nonionic water-soluble surface-active additive based on polyethers having an HLB value of greater than 10, (C) 1% by weight to 39% by weight of at least one nonionic surface-active additive based on polyethers having an HLB value of less than 10; (D) 0% by weight to 10% by weight of an additive component comprising at least one further additive, the sum total of the weight fractions not exceeding 100% by weight. The present invention further relates to processes for production thereof and to processes for coloring macromolecular materials.Type: GrantFiled: November 17, 2009Date of Patent: May 6, 2014Assignee: BASF SEInventors: Hans Ulrich Reisacher, Uwe Mauthe