Solid Block Or Block-type Copolymer Derived From Saturated Reactants Only Patents (Class 525/92A)
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Patent number: 6162545Abstract: An agent for providing an electrostatic coating property and improving the water resistance of a coating film comprises 100 weight parts of an aromatic ring-containing polyetheresteramide (A) derived from a polyamide having carboxyl groups at both ends and having a number average molecular weight of 500 to 5,000 and an alkylene oxide adduct of bisphenols having a number average molecular weight of 1,600 to 3,000; and 5 to 100 weight parts of a vinyl copolymer comprising as essential constituent units a vinyl monomer (b1) having a sulfonic acid (or sulfonate) group and at least one monomer (b2) selected from vinyl monomers having a functional group that is reactive with (A).Type: GrantFiled: February 10, 1999Date of Patent: December 19, 2000Assignees: Honda Giken Kogyo Kabushiki Kaisha, Sanyo Chemical Industries, Ltd.Inventors: Shiro Kamiyama, Katsumi Kohama, Hisashi Masuda, Takeo Okada, Eiji Inada
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Patent number: 6147152Abstract: A polypropylene resin composition is diclosed which comprises (a) 50-80% by weight of a specific polypropylene/ethylene-propylene copolymer composition, (b) 5-40% by weight of a specific ethylene/.alpha.-olefin copolymer rubber, (c) 1-10% by weight of a specific hydrogenated diene block copolymer, and (d) 10-30% by weight of talc, wherein the polypropylene component of the component (a) has a melt flow rate of 100-1,000 g/10 min and a C.sub.f value (cross fractionation ratio) of not more than 0.5. The resin composition has excellent flowability and can impart excellent rigidity, high-temperature rigidity and impact resistance, and well-balanced combination thereof to the molded articles.Type: GrantFiled: May 4, 1999Date of Patent: November 14, 2000Assignees: Toyota Jidosha Kabushiki Kaisha, Chisso CorporationInventors: Yoshihiro Kanome, Takao Nomura, Kouichi Hatada, Shinei Gima, Teruaki Hayashida, Osamu Kojima, Ken Shimizu, Hiroaki Hase
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Patent number: 6127507Abstract: A composition comprising in admixture with a polymer, preferably a polyurethane, and a compatible surface-modifying macromolecule having (i) a central portion of a segmented block oligomeric copolymer comprising at least one polar hard segment, and (ii) .varies.-.omega. terminal polyfluoro oligomeric groups, in a surface modifying enhancing amount. The composition is of use in providing articles having improved surface properties, particularly, medical devices having improved resistance to enzyme degradation with acceptable blood compatibility.Type: GrantFiled: November 24, 1998Date of Patent: October 3, 2000Inventor: Paul J. Santerre
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Patent number: 6121374Abstract: The invention relates to a thermoplastic composition comprising at least one polymer (M) forming a matrix in which are dispersed at least one polymer (S) and at least one polymer (K) and such that its tensile strength is greater than that of a composition comprising only (M) and (S), the proportion by weight of (M) being the same.Type: GrantFiled: May 27, 1998Date of Patent: September 19, 2000Assignee: Elf Atochem SAInventors: Thibaut Montanari, Chrystelle Guibouin, Marius Hert, Patrice Perret, Jacques Thomasset, Didier Roumilhac
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Patent number: 6069202Abstract: Desirable thermoplastic vulcanizates can be prepared from a polar engineering thermoplastic; a halogenated copolymer of p-alkylstyrene and an isomonoolefin having from 4 to 7 carbon atoms; and either an ethylene rubbery polymer or a diene based rubbery polymer or combinations thereof. The ethylene rubbery polymer desirably has at least one pendant carboxylic acid group, amine group, epoxy group, hydroxyl group or an anhydride of two carboxylic acid groups or combinations thereof. Desirable diene based rubbery polymers include epoxidized natural rubber and epoxidized homopolymers and copolymers of dienes.Type: GrantFiled: December 10, 1997Date of Patent: May 30, 2000Assignee: Advanced Elastomer Systems, L.P.Inventors: Krishna Venkataswamy, Jacques Horrion
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Patent number: 6062283Abstract: A pneumatic tire having an air permeation preventive layer comprising a low permeability thermoplastic elastomer composition comprising a thermoplastic elastomer having a thermoplastic resin composition as a continuous phase and a rubber composition as a dispersed phase, in which a barrier resin composition is contained, which low permeability thermoplastic elastomer composition has a phase structure in which the barrier resin composition is dispersed in the form of a flat state in the thermoplastic elastomer, is abundant in flexibility, is superior in gas permeation preventive property, and enables the tire to be reduced in weight.Type: GrantFiled: January 28, 1998Date of Patent: May 16, 2000Assignee: The Yokohama Rubber Co., Ltd.Inventors: Jiro Watanabe, Noriaki Kuroda, Gou Kawaguchi, Tetsuji Kawazura, Hidekazu Takeyama, Yoshihiro Soeda, Kazuo Suga, Yoshiaki Hashimura, Osamu Ozawa
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Patent number: 6054533Abstract: A compatibilized blend of a thermoplastic elastomer and a polyolefin. The compatibilizer is a thermoplastic polyurethane formed by the reaction of a substantially hydrocarbon intermediate such as a polybutadiene polyol, a diisocyanate such as MDI, and an amine or diol chain extender such as neopentyl glycol. The compatibilizer has high amounts of soft segments therein and imparts improved properties to blends of a thermoplastic elastomer and polyolefin such as good impact resistance, good tensile strength, good tear resistance, and good delamination resistance.Type: GrantFiled: October 15, 1997Date of Patent: April 25, 2000Assignee: The B.F. Goodrich CompanyInventors: Julius Farkas, Charles Patrick Jacobs, Dennis Lee Lawson, Gary Franklin Wilson
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Patent number: 6051649Abstract: The invention relates to films made of compositions comprising:at least one polyamide (A),at least one polymer (B) comprising polyamide blocks and polyether blocks,at least one polyolefin (C), andat least one functionalized polyolefin (D); such that the impact strength (Dart Test) is greater than that of a film containing the same proportions of (A), (C) and (D) but not containing (B).Type: GrantFiled: January 30, 1997Date of Patent: April 18, 2000Assignee: Elf Atochem S.A.Inventors: Patrick Alex, Denis Melot
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Patent number: 6046274Abstract: The invention relates to a flexible composition comprising a vinyl chloride polymer and a block copolymer. The latter comprises a poly(ethylene oxide) block and a block of a polymer which is miscible with the vinyl chloride polymer, other than the latter itself. The invention also relates to a poly(ethylene oxide)/poly-.epsilon.-caprolactone diblock copolymer which can be used in this composition, as well as to the use of this composition for the manufacture of an article and to an article comprising this composition.Type: GrantFiled: January 28, 1998Date of Patent: April 4, 2000Assignee: Solvay (Societe Anonyme)Inventors: Dominique Grandjean, Zdenek Hruska, Danny Van Hoyweghen, Henri Wautier
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Patent number: 6034168Abstract: A water sensitive hot melt adhesive composition based on polyalkyleneimine copolymers for use with articles such as paper products, disposable nonwoven products, tapes, labels and packaging materials. By varying the amount of copolymer included in the composition as well as by varying the chain structure and the ratio of soluble versus insoluble repeating units in the copolymer, an adhesive may be formulated to modify the degree of solubility from 100% to 0% soluble in water and/or other performance characteristics. The adhesive composition includes about 10% to about 70%, by weight, of a polyalkyleneimine copolymer or a blend of one or more polyalkyleneimine copolymers; about 0% to about 70%, by weight, of a tackifying resin; about 10% to about 70%, by weight, of a compatible plasticizer; and about 0.1% to about 3% by weight of one or more antioxidant.Type: GrantFiled: October 23, 1998Date of Patent: March 7, 2000Assignee: Ato Findley, Inc.Inventor: Baoyu Wang
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Patent number: 6020427Abstract: Low oil swell, processable carboxylated nitrile rubber thermoplastic vulcanizate compositions having high melting points are made utilizing a processing aid, for example, maleated polyethylene, and addition type curing agents such as bisoxazolines or bisimidazolines. The compositions generally contain polar thermoplastic high melting point crystalline polymers such as polyester as a continuous phase with the carboxylated nitrile rubber being dispersed therein.Type: GrantFiled: December 10, 1997Date of Patent: February 1, 2000Assignee: Advanced Elastomer Systems, L.P.Inventors: Tonson Abraham, Sabet Abdou-Sabet
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Patent number: 6017999Abstract: A saturated polyester resin composition excellent in impact resistance is prepared by melt kneading (A) 30-58 parts by weight of a saturated polyester resin, (B) 42-70 parts by weight of an epoxy group-containing ethylene copolymer comprising (a) 50-99% by weight of ethylene unit, (b) 0.1-30% by weight of unsaturated carboxylic acid glycidyl ester unit or unsaturated glycidyl ether unit, and (c) 0-49% by weight of ethylenically unsaturated ester compound unit, (C) 0.Type: GrantFiled: September 27, 1994Date of Patent: January 25, 2000Assignee: Sumitomo Chemical Company, LimitedInventors: Tadayuki Ohmae, Yoshiki Toyoshima, Kentaro Mashita, Noboru Yamaguchi, Kenzo Chikanari
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Patent number: 6013728Abstract: A combination of polymeric components provides desired characteristics in forming medical instruments such as catheters and balloons for dilatation catheters. For example, a balloon material is formed from a blend of polymeric components, including a first crystalline polymeric component and a second softening polymeric component. Where the first two components are generally incompatible, the balloon material can also include a third compatibilizing agent to facilitate blending the first two polymeric components together. The first polymeric component can be a branched or straight chain polyamide having a molecular weight of at least about 5000, or a polyester prepared from aromatic dicarboxylic acids having 8 to 14 carbon atoms or aliphatic dicarboxylic acids having from 2 to 12 carbon atoms, and at least one glycol having the formula HO(CH.sub.2).sub.n OH, where n is an integer from 2 to 10, neopentyl glycol and cyclohexane dimethanol.Type: GrantFiled: May 15, 1997Date of Patent: January 11, 2000Assignee: Advanced Cardiovascular Systems, Inc.Inventors: Ziyun Chen, Tai Cheng, Ketan Muni, Udayan Patel, Robert Saltman
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Patent number: 5994470Abstract: Disclosed is a golf ball having excellent shot feel, control properties as well as satisfactory flight performance and cut resistance. The golf ball of the present invention has a core and a cover for covering the core, wherein the cover has a stiffness modulus of 100 to 250 MPa, and is prepared from a resin composition comprising, as a base resin, a mixture of the following resin (A) and resin (B) in a weight ratio of 60:40 to 90:10:resin (A): an ionomer resin (i) obtained by neutralizing with metal ion at least a part of carboxyl groups in a copolymer of ethylene and an .alpha., .beta.-unsaturated carboxylic acid, or a mixture of the ionomer resin (i) and an ionomer resin (ii) obtained by neutralizing with metal ion at least a part of carboxyl groups in a terpolymer of ethylene, an .alpha., .beta.-unsaturated carboxylic acid and an .alpha., .beta.Type: GrantFiled: December 8, 1995Date of Patent: November 30, 1999Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Hiroaki Tanaka, Yoshikazu Yabuki, Yoshinori Sano
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Patent number: 5985392Abstract: Composite including a rubber/thermoplastic blend adherent by itself to a thermoplastic material; the blend is in the form of a thermoplastic matrix containing rubber nodules functionalized and vulcanized during the mixing with the thermoplastic. Composite articles obtained by overmoulding the vulcanized rubber/thermoplastic blend onto the thermoplastic.Type: GrantFiled: January 2, 1997Date of Patent: November 16, 1999Assignee: Elf Atochem S.A.Inventors: Marius Hert, Patrick Alex, Martine Cerf, Christian Dousson
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Patent number: 5891951Abstract: A polystyrene-based resin composition containing a styrene-based resin with mainly syndiotactic configuration and filler as main components. Styrene-based resins of mainly syndiotactic configuration include polystyrene, poly(alkylstyrene), poly(halogenated styrene), poly(alkoxystyrene), styrene copolymers comprised of polymerized units of at least of styrene, alkylstyrene, halogenated styrene and alkoxystyrene, and mixtures thereof.Type: GrantFiled: June 5, 1995Date of Patent: April 6, 1999Assignee: Idemitsu Kosan Co., Ltd.Inventors: Akikazu Nakano, Takashi Sumitomo, Keisuke Funaki, Toshikazu Ijitsu, Michihiro Sawada, Masahiko Kuramoto, Masakazu Suzuki
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Patent number: 5886097Abstract: Thermoplastic resin compositions consisting of 1 to 40 wt % a polyether ester amide (A) and 99 to 60 wt % of at least one thermoplastic resin (B) selected from styrene based resins, further containing (C) 0.1-10% of a modified vinyl polymer containing carboxyl groups, are permanently antistatic, excellent in mechanical properties represented by impact resistance, heat resistance moldability and also in the appearance and gloss of the moldings, and suitable for housings of optical or magnetic recording media.Type: GrantFiled: September 17, 1997Date of Patent: March 23, 1999Assignee: Toray Industries, Inc.Inventors: Tadao Fukumoto, Masatoshi Iwamoto, Akihiko Kishimoto
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Patent number: 5886098Abstract: A polyetheresteramide having good heat resistance, permanent antistatic property and superior compatibility with thermoplastic resins and a resin composition containing the polyetheresteramide are disclosed, wherein the polyetherester-amide consists essentially of a polyamide oligomer with carboxylic chain ends having a number average molecular weight between 200 and 5,000 and a bisphenol compound with oxyalkylene units having a number average molecular weight between 300 and 3,000. Antistatic resin compositions with good antistatic property and heat resistance are obtained from compositions comprising 3 to 40% by weight of the polyetheresteramide and 60 to 97% by weight of thermoplastic resins. The antistatic resin compositions can contain as compatibilizers vinyl polymers having functional groups such as carboxyl and epoxy groups or block polymers containing polyolefin blocks and aromatic vinyl polymer blocks.Type: GrantFiled: November 10, 1997Date of Patent: March 23, 1999Assignee: Sanyo Chemical Industries, Ltd.Inventors: Yasuhiro Ueda, Eiichi Senda, Yoshitsugu Takai, Tokiko Kokubu, Toshiaki Okamoto, Eiji Ichihara
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Patent number: 5883195Abstract: Novel thermoplastic polymer alloys adopted for easy conversion, e.g., by injection molding or extrusion techniques, into useful shaped articles having improved mechanical properties, for example, high impact strengths, include a polyamide, e.g., nylon 6 or nylon 12, a thermoplastic elastomer, e.g., ABS, MBS or EPDM, and a polyetheramide, advantageously a polyetheresteramide.Type: GrantFiled: June 25, 1997Date of Patent: March 16, 1999Assignee: AtochemInventors: Jean-Jacques Couchoud, Michel Glotin, Bernard Guerin, Georges Parmeland
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Patent number: 5840801Abstract: The invention disclosed herein relates to methods for vulcanizing elastomeric materials. The method comprises providing a mixture of ZnO and an amphiphilic triblock copolymer selected from the group consisting of rosin and C.sub.18 -C.sub.24 fatty acid esters of polyethylene glycol and the use of the mixture for vulcanizing an elastomeric component with sulfur. The mixture not only improves the dispersion of zinc salts in the elastomeric composition but also reduces mold fouling by reducing the migration of zinc salts to the interfacial area of the elastomeric composition.Type: GrantFiled: June 24, 1996Date of Patent: November 24, 1998Assignee: Arizona Chemical CompanyInventor: Eric S. Gardiner
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Patent number: 5804629Abstract: Molding materials comprise polyarylene ethers, copolymers containing units which are derived from aromatic vinyl compounds and cyclic .alpha.,.beta.-unsaturated carboxylic anhydrides and carboximides, and furthermore fillers and rubber impact modifiers.Type: GrantFiled: June 13, 1994Date of Patent: September 8, 1998Assignee: BASF AktiengesellschaftInventors: Martin Weber, Norbert Guentherberg
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Patent number: 5733538Abstract: A hemocompatible surface-modifying additive is provided for modifying polyurethane or polyurethane urea substrates. The additive has a polyurethane or polyurethane urea hard block or an alternative block which is miscible with the poly(urethane) or poly(urethane-urea) base polymer, a polysiloxane hydrophobic soft block, an optional hydrophilic spacer and a peptide selected from the group consisting of Arg-Gly-Asp, X-Arg-Gly-Asp, Arg-Gly-Asp-X and X-Arg-Gly-Asp-X', wherein X and X' are amino acids.Type: GrantFiled: June 7, 1995Date of Patent: March 31, 1998Assignee: Thoratec Laboratories, Inc.Inventor: Judy S. Riffle
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Patent number: 5721322Abstract: The specification discloses a method and additive for increasing the surface activity of non-polar polymeric materials, and a non-polar polymeric material exhibiting increased surface activity. The invention employs an additive of the formulaA-B-A.sup.1wherein each of the A and A.sup.1 blocks which may be the same or different has a number molecular weight in the range of from about 200 to about 1000 daltons and is selected from the group substituted and unsubstituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, aryl and alkylaryl units derived from one or more esters, organic acids, organic halides or organic acid halides, and units derived from alkyl or aryl isocyanates or ester-amides. The B-block is a polyepichlorohydrin unit derived from a polyepichlorohydrin polyol having at least two terminal hydroxyl groups and having an average molecular weight in the range of from about 400 to about 4000 daltons.Type: GrantFiled: January 24, 1997Date of Patent: February 24, 1998Assignee: Arizona Chemical CompanyInventors: Xinya Lu, Eric S. Gardiner
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Patent number: 5700885Abstract: An extruder screw having a plurality of plasticating sections sufficient for plasticating polymeric materials of different bulk density.Type: GrantFiled: October 27, 1995Date of Patent: December 23, 1997Assignee: The Dow Chemical CompanyInventors: Hoang T. Pham, Chad A. Strait, Richard O. Kirk
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Patent number: 5691412Abstract: A polyamide/aliphatic polyester block copolymer (A) comprising a polyamide block and an aliphatic polyester block, (B) satisfying the expression, T.sub.1 -T<100-C (in which T is the melting point (.degree.C.) of the above block copolymer, T.sub.1 is the melting point (.degree.C.) of a polyamide composed of the polyamide block and C is the content (wt. %) of the polyamide block), (C) exhibiting the extraction amount which satisfies the expression, when extracted in tetrahydrofuran, E<(100-C).times.0.4 (in which E is the extraction amount (wt. %) when the block copolymer is refluxed in tetrahydrofuran, and C is the content (wt. %) of the polyamide block) and (D) having an intrinsic viscosity, measured at 35.degree. C., in the range of from 0.5 to 5; a process for the production thereof; a fiber formed therefrom; and an intimate blend comprising a thermoplastic resin having no or poor compatibility with polyamide and the block copolymer.Type: GrantFiled: May 25, 1995Date of Patent: November 25, 1997Assignee: Teijin LimitedInventors: Shunichi Matsumura, Takashi Ito, Takanori Miyoshi
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Patent number: 5670564Abstract: Rigid-rod macromonomers, and methods for preparing such macromonomers, having a polyaromatic backbone, solubilizing side groups, and reactive end groups are provided. The macromonomers are chemically incorporated into polymer systems to provide stronger, stiffened polymers.Type: GrantFiled: June 1, 1995Date of Patent: September 23, 1997Assignee: Maxdem IncorporatedInventors: Robert R. Gagne, Matthew Louis Marrocco, III, Mark Steven Trimmer, Neil H. Hendricks
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Patent number: 5665822Abstract: Thermoplastic elastomers (TPEs) containing side chain crystalline (SCC) blocks. The SCC blocks my be hard (A) blocks or the soft (B) blocks (or both) in the TPE. Some of these TPEs are novel, e.g. those in which A blocks are SCC blocks, and the B blocks are polyethers, polyacrylates, polyamides, polyurethanes or polysiloxanes. The SCC-containing TPEs are particularly useful as matrix materials for other components which are dispersed therein, e.g. energetic solids and other thermally responsive materials.Type: GrantFiled: April 14, 1993Date of Patent: September 9, 1997Assignee: Landec CorporationInventors: Steven P. Bitler, Ray F. Stewart, David A. Kamp, Robert G. Freelin, Valentine Y. Yoon
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Patent number: 5658984Abstract: A permanent anti-static polycarbonate resin composition is comprises(a) 50-95 parts by weight of an aromatic polycarbonate resin,(b) 2-40 parts by weight of a block copolyamide resin,(c) 0-50 parts by weight of an aromatic polyester resin, and(d) 1-30 parts by weight of a multi-layered polymer having a structure comprising a core composed of a rubber-like polymer prepared from an alkyl acrylate monomer in which the carbon number of the alkyl group is 2-8, and an outer shell layer formed on the surface of the core and composed of a glass-like polymer prepared from an aromatic vinyl monomer or an aromatic vinyl monomer and a vinyl monomer copolymerizable therewith.Type: GrantFiled: December 21, 1995Date of Patent: August 19, 1997Assignee: Mitsubishi Engineering-Plastics CorporationInventors: Kazuhiko Ishii, Goro Shimaoka, Michio Nakata
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Patent number: 5650231Abstract: A polymeric resin for optical fiber strips is formed from a mixture comprising a first base polymer selected from an epoxy acrylate and a urethane acrylate and a copolymer in a proportion of between 0.5% and 20% by weight of said mixture which is compatible with said first polymer and carries polysiloxane chains.Type: GrantFiled: June 6, 1995Date of Patent: July 22, 1997Assignee: Alcatel CableInventors: Jean-Yves Barraud, Sophie Gervat
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Patent number: 5639833Abstract: The invention is directed to molding materials containingA) from 1 to 99% by weight of polyarylene ethers having repeating units I ##STR1## where t and q may each be an integer 0, 1, 2 or 3,T, Q and Z may each be a chemical bond or --O--, --S--, --SO.sub.2 --, S.dbd.O, C.dbd.O, --N.dbd.N--, R.sup.a C.dbd.CR.sup.b -- or --CR.sup.c R.sup.d --, with the proviso that at least one of the groups T, Q and Z is --SO.sub.2 -- or C.dbd.O,R.sup.a and R.sup.b,R.sup.c and R.sup.d, andAr and Ar.sup.1 are as defined in the specification,B) from 1 to 99% by weight of copolyamides containingb.sub.1) from 30 to 44 mol % of units which are derived from terephthalic acid,b.sub.2) from 6 to 20 mol % of units which are derived from isophthalic acid,b.sub.3) from 43 to 49.5 mol % of units which are derived from hexamethylenediamine,b.sub.4) from 0.5 to 7 mol % of units which are derived from aliphatic cyclic diamines of 6 to 30 carbon atoms andb.sub.5) from 0 to 4 mol % of further polyamide-forming monomers which differ from b.sub.Type: GrantFiled: August 10, 1995Date of Patent: June 17, 1997Assignee: BASF AktiengesellschaftInventors: Martin Weber, Herbert Fisch, Gunter Pipper, Axel Gottschalk
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Patent number: 5637407Abstract: Composite including a rubber/thermoplastic blend adherent by itself to a thermoplastic material; the blend is in the form of a thermoplastic matrix containing rubber nodules functionalized and vulcanized during the mixing with the thermoplastic. Composite articles obtained by overmoulding the vulcanized rubber/thermoplastic blend onto the thermoplastic.Type: GrantFiled: November 10, 1994Date of Patent: June 10, 1997Assignee: Elf Atochem S. A.Inventors: Marius Hert, Patrick Alex, Martine Cerf, Christian Dousson
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Patent number: 5616418Abstract: Polyblend compositions well adopted for the production of a wide variety of useful shaped articles having improved physical/chemical properties, e.g., fibers, films, sheets, composites, and the like, comprise (a) at least one polyamide thermoplastic elastomer, e.g., a polyetheresteramide, and (b) at least one modified polyolefin, e.g, an optionally maleized copolymerizate of ethylene and vinyl acetate, a copolymerizate of ethylene and (meth)acrylic acid, a copolymerizate of ethylene, vinyl acetate and (meth)acrylic acid and/or an alkyl (meth)acrylate, a copolymerizate of ethylene, an alkyl (meth)acrylate and, optionally, maleic anhydride, or maleized SBS, SIS or SEBS.Type: GrantFiled: December 28, 1994Date of Patent: April 1, 1997Assignee: AtochemInventors: Thierry Vasselin, Michel Vuachet
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Patent number: 5596042Abstract: Olefin thermoplastic elastomers which comprise a partially crosslinked thermoplastic elastomer comprising a crystalline polyolefin resin (A), a block copolymer (B) which is composed of a polymer block of styrene or its derivative and a specific isoprene polymer block, and an olefin rubber (C), and thermoplastic elastomer laminates, having a substrate formed from a specific olefin thermoplastic elastomer or a crystalline polyolefin resin and a skin layer formed from the above-mentioned olefin thermoplastic elastomer, which are excellent in mechanical strength, heat resistance, heat aging resistance, weathering resistance and scratch resistance have been provided by the present invention.Type: GrantFiled: April 4, 1996Date of Patent: January 21, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Yuichi Itoh, Kyoko Kobayashi, Akira Uchiyama, Toru Takehara
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Patent number: 5574101Abstract: An acrylic resin composition comprising at least one polyamide elastomer consisting of hard segments and soft segments in a specified ratio, an acrylic resin and optionally at least one electrolyte, which has excellent permanent antistatic properties, is good in transparency, has a very faint color, is inexpensive, and is only slightly deteriorated in transparency even when immersed in water.Type: GrantFiled: May 26, 1995Date of Patent: November 12, 1996Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Kiyoshi Kawakami, Yuzuru Ishibashi, Toshio Suzuki
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Patent number: 5550190Abstract: The composition of the present invention is a thermoplastic elastomer composition obtained by dynamically crosslinking (A) 51-95% by weight of a thermoplastic polyester elastomer and (B) 49-5% by weight of a rubber during kneading. The composition is excellent in all of hardness, tensile strength, tensile elongation, compression set, thermal aging resistance, oil resistance and molded product appearance, and is suitably used as a material for automobile parts such as joint boot and the like.Type: GrantFiled: March 27, 1992Date of Patent: August 27, 1996Assignees: Japan Synthetic Rubber Co., Ltd., NTN CorporationInventors: Ko Hasegawa, Toshio Teramoto, Tatsuo Nakajima, Takeyoshi Konomoto
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Patent number: 5523337Abstract: Hydroxy-terminated telechelic rubber polymers and block copolymers of flexible polymers with unsaturated polyester resins improve the elongation and flexural elongation of in-mold coating compositions for fiber reinforced plastics (FRP). An FRP in-mold coating composition based upon vinyl ester resin, ethylenically unsaturated monomers, and at least one of telechelic hydroxy terminated flexible polymers and the block copolymers of functionally terminated flexible polymers with unsaturated polyester polymers are described.Type: GrantFiled: October 27, 1994Date of Patent: June 4, 1996Assignee: GenCorp Inc.Inventors: Krishna G. Banerjee, I. Glen Hargis, Earl G. Melby, Douglas S. McBain
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Patent number: 5500476Abstract: A polymer mixture on the basis of a polyalkylene phthalate ester, a copolyether ester and an agent to improve the impact to which an agent to improve the bonding of lacquer systems on an aqueous base has been added. The polymer mixture according to the invention comprises a polyalkylene glycol polymer or a polyalkylene glycol copolymer as an agent to improve the lacquer bonding.Type: GrantFiled: November 18, 1994Date of Patent: March 19, 1996Assignee: General Electric CompanyInventors: Robertus E. de Jong, Jacobus J. C. van der Kort
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Patent number: 5500478Abstract: Thermoplastic resin compositions consisting of 1 to 40 wt % a polyether ester amide (A) and 99 to 60 wt % of at least one thermoplastic resin (B) selected from styrene based resins, further containing (C) 0.1-10% of a modified vinyl polymer containing carboxyl groups, are permanently antistatic, excellent in mechanical properties represented by impact resistance, heat resistance moldability and also in the appearance and gloss of the moldings, and suitable for housings of optical or magnetic recording media.Type: GrantFiled: May 10, 1994Date of Patent: March 19, 1996Assignee: Toray Industries, Inc.Inventors: Tadao Fukumoto, Masatoshi Iwamoto, Akihiko Kishimoto
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Patent number: 5496876Abstract: Improved thermoplastic compositions adopted for easy conversion, e.g., by injection molding or extrusion techniques, into useful shaped articles having high flexibility, and good tear resistance and elasticity, include a polyetheramide, advantageously a polyetheresteramide, and a styrene/diene copolymer, e.g., a copolymer of styrene with butadiene or isoprene, notably a linear or branched chain styrene/butadiene/styrene or styrene/isoprene/styrene copolymer.Type: GrantFiled: September 28, 1994Date of Patent: March 5, 1996Assignee: AtochemInventors: Jean-Pierre Jacquemin, Gerard Deleens
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Patent number: 5488086Abstract: A polycarbonate resin composition which is superior in impact resistance, fluidity, solvent resistance, wear resistance and sliding characteristics. The polycarbonate resin composition comprises (A) a mixture of polycarbonate (PC) and a polycarbonate-polydimethylsiloxane (PC-PDMS) copolymer and (B) at least one of (i) a thermoplastic resin such as a thermoplastic crystalline resin or a thermoplastic amorphous resin and (ii) a rubber elastomer.Type: GrantFiled: March 10, 1994Date of Patent: January 30, 1996Assignee: Idemitsu Petrochemical Co., Ltd.Inventors: Takashi Umeda, Masaya Okamoto
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Patent number: 5470914Abstract: There are disclosed novel, solid, elastomeric block copolymers with improved resistance to cold flow wherein either 1) the terminal blocks are each a polymer (I polymer) of at least one conjugated diene I, e.g., isoprene, which contains at least five carbon atoms with at least one of each pair of double-bonded carbon atoms in the polymerized diene I units being additionally single-bonded to two carbon atoms; at least one middle or interior block is a hydrogenated polybutadiene (B polymer); and at least one middle or interior block is an essentially straight chain polyethylene (E polymer) resulting from the hydrogenation of a polybutadiene composed of at least 80% of 1,4- units; or 2) the terminal blocks are random IB copolymers of at least one diene I as previously defined and hydrogenated butadiene, and at least one middle or interior block is a straight chain polyethylene (E polymer) as previously defined.Type: GrantFiled: March 13, 1995Date of Patent: November 28, 1995Assignee: Mobil Oil CorporationInventors: Thomas S. Coolbaugh, Frederick C. Loveless, Demetreos N. Matthews
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Patent number: 5418275Abstract: There are disclosed a polystyrene composition which comprises 100 parts by weight of a syndiotactic polystyrene (SPS)(a) and 1 to 100 parts by weight of a high molecular compound comprising 5 to 95% by weight of polyphenylene ether (PPO) and/or modified PPO and 95 to 5% by weight of a rubbery elastomer (b) and optionally, 1 to 350 parts by weight of an inorganic filler (d) and also a polystyrene composition which comprises 100 parts by weight of the component (a), 0.1 to 30 parts by weight of the component (b) and 1 to 100 parts by weight of a rubbery elastomer (c) and optionally, 1 to 350 parts by weight of the component (d). The above compositions are greatly improved in impact resistance, elongation and retention of physical properties during recycling without detriment to heat resistance and modulus of elasticity.Type: GrantFiled: September 9, 1993Date of Patent: May 23, 1995Assignee: Idemitsu Kosan Co., Ltd.Inventors: Akihiko Okada, Nobuyuki Sato
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Patent number: 5418291Abstract: A resin composition comprising(a) a polyphenylene ether resin or a mixture of it and a polystyrene resin,(b) a co-oligomer of ethylene and an alpha-olefin,(c) optionally an elastomeric hydrogenated A-B-A block copolymer, and(d) optionally an elastomeric hydrogenated A-B block copolymer.The chemical resistance of the polyphenylene ether is improved.Type: GrantFiled: January 18, 1994Date of Patent: May 23, 1995Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Hideo Uno, Hiroshi Murayama, Yasumasa Norisue, Ryu Iwasaki