Solid Polymer Derived From A Lactam; From An Amino Carboxylic Acid Or Derivative; From A Polyamine And A Polycarboxylic Acid Or Derivative Patents (Class 525/92B)
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Patent number: 5502098Abstract: A polymer composition for electrical part material comprising, (I) a polymer blend which comprises (A) at least one polymer selected from specific types of polyether imides and polyesters, and (B) at least one polymer selected from specific types of polyphenylene ethers, polyolefins, and polycarbonates, and (II) a copolymer of maleic anhydride and vinyl type compound or (II') an epoxy-modified styrene-type copolymer. The composition has excellent compatibility, heat resistance, mechanical characteristics, platability, moldability, and electric characteristics. It is an ideal material for use as an electrical part material due to its low dielectric constant and low dielectric dissipation factor at high frequency.Type: GrantFiled: June 27, 1994Date of Patent: March 26, 1996Assignees: Cosmo Research Institute, Cosmo Oil Co., Ltd.Inventors: Fumie Watanabe, Takashi Mizoguchi, Masatoshi Iwafune
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Patent number: 5500478Abstract: Thermoplastic resin compositions consisting of 1 to 40 wt % a polyether ester amide (A) and 99 to 60 wt % of at least one thermoplastic resin (B) selected from styrene based resins, further containing (C) 0.1-10% of a modified vinyl polymer containing carboxyl groups, are permanently antistatic, excellent in mechanical properties represented by impact resistance, heat resistance moldability and also in the appearance and gloss of the moldings, and suitable for housings of optical or magnetic recording media.Type: GrantFiled: May 10, 1994Date of Patent: March 19, 1996Assignee: Toray Industries, Inc.Inventors: Tadao Fukumoto, Masatoshi Iwamoto, Akihiko Kishimoto
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Patent number: 5484858Abstract: The properties of polyphenylene ether-polyamide mixtures can be improved by the addition of polysiloxane compounds.Type: GrantFiled: October 18, 1994Date of Patent: January 16, 1996Assignee: General Electric CompanyInventors: Hendrikus J. E. Smits, Roelof van der Meer, Adelbert H. L. Groothuis
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Patent number: 5478885Abstract: The present invention provides a toughened epoxy resin composition comprising:(a) a curable aromatic epoxy resin,(b) an epoxidized low viscosity polydiene polymer wherein the polymer contains from 1.0 to 7.0 milliequivalents of epoxy per gram of polymer, and(c) a curing agent.Type: GrantFiled: April 15, 1994Date of Patent: December 26, 1995Assignee: Shell Oil CompanyInventors: Michael A. Masse, Kailash Dangayach, James Erickson
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Patent number: 5475054Abstract: A resin composition comprising (A) a polyphenylene ether resin, (B) a polyolefin resin, and optionally (C) an elastomer, and (D) an aliphatic polycarboxylic acid derivative represented by the following general formula:(R.sub.1 O).sub.m R(COOR.sub.2).sub.n (CORN.sub.3 R.sub.4).sub.swherein R represents a saturated hydrocarbon group having 2 to 20 carbon atoms with a linear or branched chain; R.sub.1 represents a hydrogen atom or an alkyl, aryl, acyl or carbonyldioxy group having 1 to 10 carbon atoms; each R.sub.2 represents a hydrogen atom or an alkyl or aryl group having 1 to 20 carbon atoms; R.sub.3 and R.sub.4 each represents a hydrogen atom or an alkyl or aryl group having 1 to 10 carbon atoms; m represents a number equal to 1 or 2; (n+s) is larger than or equal to 2 and, n and s are each larger than or equal to 0; (OR.sub.1) is in an alpha or beta position with respect to a carbonyl group, and in which at least two carbonyl groups are separated by 2 to 6 carbon atoms.Type: GrantFiled: September 28, 1994Date of Patent: December 12, 1995Assignee: Sumitomo Chemical Company, LimitedInventors: Hiroomi Abe, Kenji Nagaoka, Takashi Sanada
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Patent number: 5470914Abstract: There are disclosed novel, solid, elastomeric block copolymers with improved resistance to cold flow wherein either 1) the terminal blocks are each a polymer (I polymer) of at least one conjugated diene I, e.g., isoprene, which contains at least five carbon atoms with at least one of each pair of double-bonded carbon atoms in the polymerized diene I units being additionally single-bonded to two carbon atoms; at least one middle or interior block is a hydrogenated polybutadiene (B polymer); and at least one middle or interior block is an essentially straight chain polyethylene (E polymer) resulting from the hydrogenation of a polybutadiene composed of at least 80% of 1,4- units; or 2) the terminal blocks are random IB copolymers of at least one diene I as previously defined and hydrogenated butadiene, and at least one middle or interior block is a straight chain polyethylene (E polymer) as previously defined.Type: GrantFiled: March 13, 1995Date of Patent: November 28, 1995Assignee: Mobil Oil CorporationInventors: Thomas S. Coolbaugh, Frederick C. Loveless, Demetreos N. Matthews
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Patent number: 5461112Abstract: The present invention provides a toughened epoxy resin composition comprising:(a) a curable aromatic epoxy resin,(b) a monohydroxylated epoxidized polydiene polymer which is comprised of at least two polymerizable ethenically unsaturated hydrocarbon monomers wherein at least one is a diene monomer which yields unsaturation suitable for epoxidation, and wherein the polymer contains from 0.5 to 7 milliequivalents of epoxy per gram of polymer, and(c) a curing agent.Type: GrantFiled: May 5, 1995Date of Patent: October 24, 1995Assignee: Shell Oil CompanyInventors: Michael A. Masse, David J. St. Clair, James R. Erickson
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Patent number: 5449721Abstract: Disclosed is a thermoplastic resin composition which comprises:(A) 10-90 parts by weight of a polyphenylene ether resin,(B) 90-10 parts by weight of a polyamide resin,(C) 1-100 parts by weight of a fluorocarbon resin,(D) 0-30 parts by weight of a compatibilizing agent, and(E) 0-100 parts by weight of a rubber-like material, amounts of (C), (D) and (E) being based on 100 parts by weight in total of (A) and (B).The invention provides a thermoplastic resin composition comprising a polyphenylene ether resin and a polyamide resin improved in heat resistance, impact resistance, and flowability, lowered in frictional coefficient and markedly improved in critical PV value by adding a fluorocarbon resin to a PPE/nylon alloy. Further provided is a method for producing a thermoplastic resin composition comprising a polyphenylene ether resin and a polyamide resin which is much improved in slidability.Type: GrantFiled: September 8, 1994Date of Patent: September 12, 1995Assignee: Sumitomo Chemical Co., Ltd.Inventors: Yasuro Suzuki, Yasuhito Ijichi
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Patent number: 5449722Abstract: Disclosed is a thermoplastic resin composition comprising:30 to 97% by weight of at least one of (a) a crystalline thermoplastic resin component and (b) a non-crystalline thermoplastic resin component, 3 to 70% by weight of (c) a rubbery polymer component which is ununiformly mixed with at least one of Component (a) and Component (b) and 0 to 40% by weight of (d) an inorganic filler,wherein Component (c) forms a network and at least one of the ratio of flexural modulus of Component (a) to Component (c) and that of Component (b) to Component (c) is 5 or more.Type: GrantFiled: March 18, 1994Date of Patent: September 12, 1995Assignee: Mitsubishi Petrochemical Co., Ltd.Inventors: Koji Nishida, Kiyoji Takagi, Hironari Sano, Motohiro Seki
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Patent number: 5446092Abstract: A thermoplastic polymer composition comprises: a thermoplastic polymer (a) having polarity on the main chain of the molecule thereof, and a modified block copolymer (b) of a block copolymer comprising:at least one polybutadiene block (B) having a degree of vinylization of not more than 30%, andat least one polymer block (D) comprising units from isoprene and butadiene in a ratio by weight of isoprene/butadiene of 30/70 to 100/0 and having a degree of vinylization of not more than 30%, said polybutadiene block (B) and said polymer block (D) each has a degree of unsaturation of not more than 30%, to said block copolymer a molecular unit containing a carboxyl acid group or derivatives thereof having added, the ratio by weight between said component (a) and said component (b), (a)/(b), being in a range of 2/98 to 98/2.Type: GrantFiled: April 21, 1994Date of Patent: August 29, 1995Assignee: Kuraray Co., Ltd.Inventors: Makoto Nishikawa, Yoshio Hirayama, Shiroh Kishii, Masao Ishii
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Patent number: 5428091Abstract: A thermoplastic resin composition which comprises 100 parts by weight of a composition comprising 95-5 % by weight of at least one polyolefinresin (A) selected from homopolymers of ethylene or .alpha.-olefin or copolymers thereof and these homopolymers or copolymers modified with a polyfunctional compound (E) and/or an unsaturated monomer (L) and 5-95 % by weight of at least one polyphenylene-ether-resin (B) selected from polyphenylene ether, modified polyphenylene ether with the above (E) and/or (L) and a composition comprising the polyphenylene or modified polyphenylene ether and an aromatic vinyl polymer resin (M) and 0.001-10 parts by weight of a dinitrodiamine (D) of the following formula (I). ##STR1## (wherein X represents a divalent chain aliphatic group, a cyclic aliphatic group or an aromatic group which may contain a halogen or an oxygen atom, R.sup.1 represents a hydrogen atom, a chain aliphatic group, a cyclic aliphatic group or an aromatic group and when both of X and R.sup.Type: GrantFiled: December 22, 1993Date of Patent: June 27, 1995Assignee: Sumitomo Chemical Co., Ltd.Inventors: Hiroomi Abe, Takeshi Fujii, Masashi Yamamoto, Shinichi Yachigo, Hideo Nagasaki, Naoki Inui
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Patent number: 5416163Abstract: There are disclosed novel, solid, elastomeric block copolymers with improved resistance to cold flow wherein either 1) the terminal blocks are polymers of at least one conjugated diene I, e.g., isoprene, which contains at least five carbon atoms with at least one of each pair of double-bonded carbon atoms in the polymerized diene I units being additionally single-bonded to two carbon atoms, at least one middle or interior block is a polymer of butadiene, and at least one middle or interior block is a polymer of at least one aryl-substituted olefin, e.g., styrene; or 2) the terminal blocks are random copolymers of at least one diene I as previously defined and butadiene, and at least one middle or interior block is a polymer of at least one aryl-substituted olefin.Type: GrantFiled: October 12, 1994Date of Patent: May 16, 1995Assignee: Mobil Oil CorporationInventors: Thomas S. Coolbaugh, Frederick C. Loveless, Demetreos N. Matthews
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Patent number: 5412027Abstract: Homogeneous polymer blends are prepared from otherwise thermodynamically immiscible polymers, especially including block copolymers. Thus, polymers such as polystyrene/poly(methyl methacrylate) block copolymer or polystyrene/poly(1,2-butadiene) block copolymer are dissolved under pressure in supercritical fluid solvents such as chlorodifluoromethane and n-butane, respectively, and expanded through a fine nozzle. As the SCF solvent evaporates, the polymer deposits as a substantially homogeneous material.Type: GrantFiled: November 19, 1993Date of Patent: May 2, 1995Assignees: The Procter & Gamble Company, The Univ. of DelewareInventors: Annetta D. Shine, Steven D. Smith, Isao Noda
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Patent number: 5409991Abstract: A thermoplastic propylene resin composition of the present invention is obtained by blending an epoxy group containing copolymer (G) and a rubber-like material (H) and/or a modified rubber-like material (I) with a resin omposition composed of a polyamide resin (F) and a polypropylene type resin (E).The thermoplastic propylene resin composition can easily be processed into molded products, films or sheets by injection molding, extrusion molding or the like, giving products which have a good balance in various physical properties and a uniform and smooth appearance. It is suitable for purposes in which especially high heat resistance, impact resistance and low-temperature impact resistance are required.Type: GrantFiled: March 8, 1994Date of Patent: April 25, 1995Assignee: Sumitomo Chemical Company, LimitedInventors: Tatsuyuki Mitsuno, Takeshi Fujii, Masashi Yamamoto, Kentaro Yamaguchi, Kiyoshi Mitsui
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Patent number: 5405909Abstract: A thermoplastic elastomer composition which is useful for bumper, boot, sound absorbing gear, sports shoes etc. is provided by mixing the following (A)-(D).A: 30-58 parts by wt of saturated polyester resin,B: 42-70 parts by wt of an epoxy group-containing ethylene copolymer ofa) 50-99% by wt of ethylene unit,b) 0.1-30% by wt of unsaturated carboxylic acid glycidyl ester unit or unsaturated glycidyl ether unit andc) 0-49% by wt of ethylenically unsaturated ester unitC: 0.01-20 parts by wt of specific polyfunctional compound containing two or more functional groups, andD: 1-30 parts by wt of block copolyether ester elastomer.The amounts of C and D are based on 100 parts of A and B.Type: GrantFiled: October 26, 1993Date of Patent: April 11, 1995Assignee: Sumitomo Chemical Co., Ltd.Inventors: Tadayuki Ohmae, Yoshiki Toyoshima, Kentaro Mashita, Noboru Yamaguchi, Kenzo Chikanari