Solid Polymer Derived From Polyhydroxy Reactant And Polycarboxylic Acid Or Derivative Patents (Class 525/92F)
  • Patent number: 5496885
    Abstract: There are disclosed a thermoplastic resin composition which comprises(a) 4 to 95% by weight of a polyphenylene ether,(b) 95 to 4% by weight of a saturated polyester,(c) 0.5 to 40% by weight of an impact modifier and(d) 0.01 to 50% by weight of a compatibilizer and(e) 0.1 to 3 parts by weight of a polycarbonate based on 100 parts by weight of the above (a) to (d) in total; and a process for preparing a thermoplastic resin composition which comprises the steps of melting and kneading(a) 50 to 95% by weight of a polyphenylene ether,(e) 0.
    Type: Grant
    Filed: May 27, 1993
    Date of Patent: March 5, 1996
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Kiyoji Takagi, Koji Nishida, Tosio Itou
  • Patent number: 5491192
    Abstract: A non-aqueous dispersion for modifying alkyd-containing coating formulations and a method for manufacturing the non-aqueous dispersion are provided. The non-aqueous dispersion contains from about 10 to about 60 parts by weight of a low molecular weight solution polymer, having a selected glass transition temperature greater than about -10.degree. C., and from about 90 to about 40 parts by weight of a polymer which is insoluble in the non-aqueous medium, and where the soluble polymer is attached to or adsorbed onto the insoluble polymer particles. The non-aqueous dispersion is preferably prepared by dispersion polymerization to form the insoluble polymer in a non-aqueous medium in the presence of the soluble polymer.
    Type: Grant
    Filed: August 28, 1991
    Date of Patent: February 13, 1996
    Assignee: Rohm and Haas Company
    Inventors: Frederick H. Walker, Chao-Jen Chung, Andrew Mercurio
  • Patent number: 5489640
    Abstract: Disclosed are compositions having the characteristic of improved heat distortion temperature for compositions comprising a poly(phenylene ether) resin, a polyester resin, a polycarbonate resin, a reinforcing filler, and a heat enhancing non-fibrous filler in combination with a poly(tetrafluoroethylene) resin. The compositions may further comprise at least one additive from the group consisting of impact modifiers, non-elastomeric polymers of an alkenyl aromatic compound and an additive package. The flow of such compositions can be further improved with the addition of an optional flow promoting terpene phenol material without significant loss of the physical properties.
    Type: Grant
    Filed: September 1, 1994
    Date of Patent: February 6, 1996
    Assignee: General Electric Company
    Inventor: Geoffrey H. Riding
  • Patent number: 5484824
    Abstract: A thermoplastic resin composition which contains a resin composition containing a crystalline polypropylene component, an ethylene-butene-1 copolymer rubber and an ethylene-propylene copolymer rubber; a modified polypropylene; a saturated polyester resin; and an epoxy group-containing copolymer; and optionally talc exhibits high low-temperature impact strength, stiffness and Rockwell hardness and a small coefficient of linear expansion, which composition gives an injection-molded article suitably used for a bumper for automobile.
    Type: Grant
    Filed: May 23, 1995
    Date of Patent: January 16, 1996
    Assignees: Sumitomo Chemical Company, Limited, Toyota Jidosha Kabushiki Kaisha
    Inventors: Hiroomi Abe, Takeshi Fujii, Masashi Yamamoto, Takeyoshi Nishio, Takao Nomura
  • Patent number: 5478885
    Abstract: The present invention provides a toughened epoxy resin composition comprising:(a) a curable aromatic epoxy resin,(b) an epoxidized low viscosity polydiene polymer wherein the polymer contains from 1.0 to 7.0 milliequivalents of epoxy per gram of polymer, and(c) a curing agent.
    Type: Grant
    Filed: April 15, 1994
    Date of Patent: December 26, 1995
    Assignee: Shell Oil Company
    Inventors: Michael A. Masse, Kailash Dangayach, James Erickson
  • Patent number: 5470914
    Abstract: There are disclosed novel, solid, elastomeric block copolymers with improved resistance to cold flow wherein either 1) the terminal blocks are each a polymer (I polymer) of at least one conjugated diene I, e.g., isoprene, which contains at least five carbon atoms with at least one of each pair of double-bonded carbon atoms in the polymerized diene I units being additionally single-bonded to two carbon atoms; at least one middle or interior block is a hydrogenated polybutadiene (B polymer); and at least one middle or interior block is an essentially straight chain polyethylene (E polymer) resulting from the hydrogenation of a polybutadiene composed of at least 80% of 1,4- units; or 2) the terminal blocks are random IB copolymers of at least one diene I as previously defined and hydrogenated butadiene, and at least one middle or interior block is a straight chain polyethylene (E polymer) as previously defined.
    Type: Grant
    Filed: March 13, 1995
    Date of Patent: November 28, 1995
    Assignee: Mobil Oil Corporation
    Inventors: Thomas S. Coolbaugh, Frederick C. Loveless, Demetreos N. Matthews
  • Patent number: 5461112
    Abstract: The present invention provides a toughened epoxy resin composition comprising:(a) a curable aromatic epoxy resin,(b) a monohydroxylated epoxidized polydiene polymer which is comprised of at least two polymerizable ethenically unsaturated hydrocarbon monomers wherein at least one is a diene monomer which yields unsaturation suitable for epoxidation, and wherein the polymer contains from 0.5 to 7 milliequivalents of epoxy per gram of polymer, and(c) a curing agent.
    Type: Grant
    Filed: May 5, 1995
    Date of Patent: October 24, 1995
    Assignee: Shell Oil Company
    Inventors: Michael A. Masse, David J. St. Clair, James R. Erickson
  • Patent number: 5449722
    Abstract: Disclosed is a thermoplastic resin composition comprising:30 to 97% by weight of at least one of (a) a crystalline thermoplastic resin component and (b) a non-crystalline thermoplastic resin component, 3 to 70% by weight of (c) a rubbery polymer component which is ununiformly mixed with at least one of Component (a) and Component (b) and 0 to 40% by weight of (d) an inorganic filler,wherein Component (c) forms a network and at least one of the ratio of flexural modulus of Component (a) to Component (c) and that of Component (b) to Component (c) is 5 or more.
    Type: Grant
    Filed: March 18, 1994
    Date of Patent: September 12, 1995
    Assignee: Mitsubishi Petrochemical Co., Ltd.
    Inventors: Koji Nishida, Kiyoji Takagi, Hironari Sano, Motohiro Seki
  • Patent number: 5446092
    Abstract: A thermoplastic polymer composition comprises: a thermoplastic polymer (a) having polarity on the main chain of the molecule thereof, and a modified block copolymer (b) of a block copolymer comprising:at least one polybutadiene block (B) having a degree of vinylization of not more than 30%, andat least one polymer block (D) comprising units from isoprene and butadiene in a ratio by weight of isoprene/butadiene of 30/70 to 100/0 and having a degree of vinylization of not more than 30%, said polybutadiene block (B) and said polymer block (D) each has a degree of unsaturation of not more than 30%, to said block copolymer a molecular unit containing a carboxyl acid group or derivatives thereof having added, the ratio by weight between said component (a) and said component (b), (a)/(b), being in a range of 2/98 to 98/2.
    Type: Grant
    Filed: April 21, 1994
    Date of Patent: August 29, 1995
    Assignee: Kuraray Co., Ltd.
    Inventors: Makoto Nishikawa, Yoshio Hirayama, Shiroh Kishii, Masao Ishii
  • Patent number: 5428068
    Abstract: This invention relates to a thermosetting unsaturated polyester or vinyl ester resin compositions modified with AB or ABA block copolymers. The A blocks are unsaturated polyester while the B blocks are flexible poller having a Tg of 0.degree. C. or lower. The blocks are generally separately prepared having a variety of terminal groups such as hydroxyl, carboxyl, amine, or isocyanate groups, but low molecular weight A blocks can be prepared in situ on the B blocks, The functionality of the blocks can be controlled to get AB or ABA diblocks and polyblocks, These modified unsaturated polyester or vinyl ester resin compositions have higher flexural strain to failure and are generally tougher than standard resins without modification. Control of the reaction conditions and the functionality of the blocks prior to coupling minimizes the formation of A(BA).sub.n where n is an integer above 1.
    Type: Grant
    Filed: January 7, 1993
    Date of Patent: June 27, 1995
    Assignee: GenCorp Inc.
    Inventors: Douglas S. McBain, Andrew L. Ratermann, Earl G. Melby, Kevin P. LaJudice