Solid Polymer Derived From Saturated 1,2-epoxy Reactant Containing More Than One 1,2-epoxy Group Per Molecule Patents (Class 525/92H)
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Patent number: 6111016Abstract: A thermoplastic resin composition can be obtained by adding about 0.1 to 20 parts by weight of a diene-series block copolymer (2) to 100 parts by weight of a resin composition containing a polycarbonate-series resin (1) as a basic component of which the proportion of terminal hydroxy groups relative to the whole of the terminals is 1 mole % or above (about 5 to 40 mole %). The polycarbonate-series resin base may further comprise a thermoplastic resin composition (3) such as a rubber-modified styrenic resin. The block copolymer component (2) includes an epoxy-modified block copolymer, etc. When added an organophosphorus compound as a flame retardant (4), or a fluorine-containing resin as a flame-retartant auxiliary (5), a halogen-free flame-retardant thermoplastic resin composition can be obtained. A thermoplastic resin with an improved flowability and impact strength can be obtained by modifying a polymer blend of the polycarbonate-series resin and the styrenic-series resin in quality.Type: GrantFiled: July 17, 1998Date of Patent: August 29, 2000Assignee: Daicel Chemical Industries, Ltd.Inventors: Masahiro Katayama, Masaaki Ito, Yoshihiro Otsuka
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Patent number: 6008286Abstract: The present invention provides a primer composition comprising an aliphatic isocyanate-containing compound, a nonhalogenated hydrocarbon polymer containing organic functional groups, a halogenated hydrocarbon polymer optionally containing organic functional groups, and an organic solvent.Type: GrantFiled: July 18, 1997Date of Patent: December 28, 1999Assignee: 3M Innovative Properties CompanyInventor: James D. Groves
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Patent number: 6005050Abstract: There is disclosed an impact resistant polystyrene composition which comprises 5 to 98% by weight of an (a) styrenic polymer having a syndiotactic configuration and 2 to 95% by weight of a (b) styrene/diolefin diblock copolymer, styrene/diolefin/styrene triblock copolymer or styrene/diolefin random compolymer, each having a hydrogenation rate of 70 to 98 mol %, and optionally a (c) rubbery elastomer having an olefinic component or polyolefin, a (d) poly(phenylene ether), etc. The above composition is greatly enhanced in its impact resistance and elongation properties without deterioration of heat resistant stability of color tone, etc.Type: GrantFiled: January 13, 1997Date of Patent: December 21, 1999Assignee: Idemitsu Petrochemical Co., Ltd.Inventors: Akihiko Okada, Nobuyuki Sato, Akitoshi Masuyama
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Patent number: 5989723Abstract: A conductive polyester-based alloy sheet having three layers laminated together by co-extrusion, which comprises one substrate layer and two surface layers, wherein the surface layers are conductive and comprise polyester, acrylonitrile-butadiene-styrene (abbreviated as ABS) and/or polystyrene (abbreviated as PS), a compatibilizer, and a toughening agent, wherein the surface layers have a surface conductivity of not more than 10.sup.8 ohms. The melt flow index of the material for the conductive layers during the extrusion step is not less than 5.0 g/min (loading, 10 Kg; temperature, 250.degree. C.). The substrate layer is made from acrylonitrile-butadiene-styrene and/or polystyrene.Type: GrantFiled: May 16, 1997Date of Patent: November 23, 1999Assignee: Far Eastern Textile Ltd.Inventors: Tsan Hung Tsai, Rong Shiun Pan, Cheng Chung Wu, Yuan Hwey Hsu, Jen Hao Wei, Shung Mine Hong
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Patent number: 5969043Abstract: An epoxy resin composition for powder coatings which comprises (a) 40 to 95 parts by weight of a solid epoxy resin having at least two epoxy groups in a molecule, an epoxy equivalent of 400 to 2500, and a softening point of 50.degree. C. to 150.degree. C., and (b) 5 to 60 parts by weight of an epoxidized polydiene polymer having a main structure of general Formula (I) in which aliphatic double bonds are partially epoxidized.Type: GrantFiled: April 3, 1998Date of Patent: October 19, 1999Assignee: Shell Oil CompanyInventors: Riichiro Maruta, Takako Watanabe, Yojiro Yamamoto
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Patent number: 5965269Abstract: An adhesive comprising (1) 100 parts by weight of a combination of an epoxy resin having a weight average molecular weight of less than 5,000 and a curing agent, (2) 10 to 40 parts by weight of a high-molecular weight component being compatible with the epoxy resin and having a weight average molecular weight of 30,000 or above, (3) 20 to 100 parts by weight of a high-molecular weight component being incompatible with the epoxy resin and having a weight average molecular weight of 30,000 or above, and (4) 0.1 to 5 parts by weight of a cure accelerator. The adhesive is excellent not only in moisture resistance, heat resistance, adhesive strength at high temperature, heat dissipation, reliability of insulation, crack resistance and flexibility but also in circuit filling and tight adhesion, and exhibits suitable flow properties.Type: GrantFiled: October 3, 1997Date of Patent: October 12, 1999Assignee: Hitachi Chemical Company, Ltd.Inventors: Teiichi Inada, Kazunori Yamamoto, Yasushi Shimada, Yasushi Kumashiro
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Patent number: 5932656Abstract: A process for curing epoxidized diene polymers for use in adhesives, sealants, and coatings which comprises contacting the polymer with an aromatic anhydride curing agent at an epoxy/anhydride molar ratio from 0.5/1 to 2.0/1.0, optionally, and from 0.1 to 10 phr of an accelerator at a temperature of from 100 to for a period of 10 minutes to six hours.Type: GrantFiled: November 20, 1997Date of Patent: August 3, 1999Assignee: Shell Oil CompanyInventor: Michael Alan Masse
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Patent number: 5922815Abstract: The present invention provides an improved process for producing blends of tackifying resins and low molecular weight polyphenylene ether resins. This invention involves combining the resin solutions or redissolving one of the resins once isolated, in the other resin solution and isolation of the resin blend by devolatilization, precipitation, evaporation, spray drying, and/or stripping of the organic solvent.Type: GrantFiled: December 15, 1997Date of Patent: July 13, 1999Assignee: General Electric CompanyInventors: David Frederick Aycock, Gary Gelvin, Marc G. Davidson
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Patent number: 5741856Abstract: A process for curing epoxidized diene polymers for use in adhesives, sealants, and coatings which comprises contacting the polymer with an aromatic anhydride curing agent at an epoxy/anhydride molar ratio from 0.5/1 to 2.0/1.0, optionally, and from 0.1 to 10 phr of an accelerator at a temperature of from 100.degree. to 200.degree. C. for a period of 10 minutes to six hours.Type: GrantFiled: February 10, 1997Date of Patent: April 21, 1998Assignee: Shell Oil CompanyInventor: Michael Alan Masse
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Patent number: 5721316Abstract: A process for incorporation of epoxidized polydienes into aromatic epoxy resins which comprises (a) blending the epoxidized polydiene into a curing agent in a ratio of 1:20 to 1:4, (b) reacting the epoxidized polydiene and a curing agent at a temperature of from 100.degree. to 150.degree. C. over a time from 10 to 100 minutes, (c) mixing the pre-reacted epoxidized polydiene and curing agent with the aromatic epoxy resin and accelerator, and (d) curing the aromatic epoxy resin by heating the full mixture of paragraph (c) to a temperature of from 110.degree. to 170.degree. C. for from 2 to 6 hours.Type: GrantFiled: July 3, 1996Date of Patent: February 24, 1998Assignee: Shell Oil CompanyInventors: Michael Alan Masse, Kailash Dangayach, James Robert Erickson
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Patent number: 5665822Abstract: Thermoplastic elastomers (TPEs) containing side chain crystalline (SCC) blocks. The SCC blocks my be hard (A) blocks or the soft (B) blocks (or both) in the TPE. Some of these TPEs are novel, e.g. those in which A blocks are SCC blocks, and the B blocks are polyethers, polyacrylates, polyamides, polyurethanes or polysiloxanes. The SCC-containing TPEs are particularly useful as matrix materials for other components which are dispersed therein, e.g. energetic solids and other thermally responsive materials.Type: GrantFiled: April 14, 1993Date of Patent: September 9, 1997Assignee: Landec CorporationInventors: Steven P. Bitler, Ray F. Stewart, David A. Kamp, Robert G. Freelin, Valentine Y. Yoon
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Patent number: 5650231Abstract: A polymeric resin for optical fiber strips is formed from a mixture comprising a first base polymer selected from an epoxy acrylate and a urethane acrylate and a copolymer in a proportion of between 0.5% and 20% by weight of said mixture which is compatible with said first polymer and carries polysiloxane chains.Type: GrantFiled: June 6, 1995Date of Patent: July 22, 1997Assignee: Alcatel CableInventors: Jean-Yves Barraud, Sophie Gervat
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Patent number: 5523337Abstract: Hydroxy-terminated telechelic rubber polymers and block copolymers of flexible polymers with unsaturated polyester resins improve the elongation and flexural elongation of in-mold coating compositions for fiber reinforced plastics (FRP). An FRP in-mold coating composition based upon vinyl ester resin, ethylenically unsaturated monomers, and at least one of telechelic hydroxy terminated flexible polymers and the block copolymers of functionally terminated flexible polymers with unsaturated polyester polymers are described.Type: GrantFiled: October 27, 1994Date of Patent: June 4, 1996Assignee: GenCorp Inc.Inventors: Krishna G. Banerjee, I. Glen Hargis, Earl G. Melby, Douglas S. McBain
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Patent number: 5499409Abstract: The present invention provides a toughened cycloaliphatic epoxy resin composition useful as a coating comprising:(a) a curable cycloaliphatic epoxy resin,(b) an epoxidized low viscosity polydiene polymer wherein the polymer contains from 2.0 to 6.0 milliequivalents of epoxy per gram of polymer,(c) a curing agent,(d) an aromatic epoxy resin, and(e) a hydroxy functional material.Type: GrantFiled: July 18, 1994Date of Patent: March 19, 1996Assignee: Shell Oil CompanyInventor: David J. St. Clair
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Patent number: 5478885Abstract: The present invention provides a toughened epoxy resin composition comprising:(a) a curable aromatic epoxy resin,(b) an epoxidized low viscosity polydiene polymer wherein the polymer contains from 1.0 to 7.0 milliequivalents of epoxy per gram of polymer, and(c) a curing agent.Type: GrantFiled: April 15, 1994Date of Patent: December 26, 1995Assignee: Shell Oil CompanyInventors: Michael A. Masse, Kailash Dangayach, James Erickson
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Patent number: 5461112Abstract: The present invention provides a toughened epoxy resin composition comprising:(a) a curable aromatic epoxy resin,(b) a monohydroxylated epoxidized polydiene polymer which is comprised of at least two polymerizable ethenically unsaturated hydrocarbon monomers wherein at least one is a diene monomer which yields unsaturation suitable for epoxidation, and wherein the polymer contains from 0.5 to 7 milliequivalents of epoxy per gram of polymer, and(c) a curing agent.Type: GrantFiled: May 5, 1995Date of Patent: October 24, 1995Assignee: Shell Oil CompanyInventors: Michael A. Masse, David J. St. Clair, James R. Erickson
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Patent number: 5420202Abstract: The present invention provides a toughened cycloaliphatic epoxy resin composition comprising:(a) a curable cycloaliphatic epoxy resin,(b) an epoxidized low viscosity polydiene polymer wherein the polymer contains from 2.0 to 6.0 milliequivalents of epoxy per gram of polymer, and(c) a curing agent.Type: GrantFiled: April 15, 1994Date of Patent: May 30, 1995Assignee: Shell Oil CompanyInventors: David J. St. Clair, James R. Erickson