Solid Block Or Block-type Copolymer Derived From Reactant Containing Carboxylic Acid Ester Group Patents (Class 525/94)
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Patent number: 11834573Abstract: Disclosed herein are processes for preparing a resin-extended rubber by mixing at least one thermoplastic resin with a resin-rubber-solvent cement comprising at least one conjugated diene monomer-containing rubber and the resin-extended rubber resulting from such processes. Also disclosed is a resin-extended rubber-solvent-cement comprising at least one conjugated diene monomer-containing rubber, at least one non-polar solvent, and at least one thermoplastic resin as well as a rubber composition comprising a resin-extended rubber.Type: GrantFiled: August 23, 2021Date of Patent: December 5, 2023Assignee: Bridgestone Americas Tire Operations, LLCInventor: Benjamin C. Galizio
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Patent number: 11608418Abstract: A method of preparing self-adhesive polyester elastomer composite membrane includes the following steps: mix methyl formate or ethyl acetate with thermoplastic polyester elastomer (TPEE) powder or granules; add a modifier, a photo initiator or a thermal initiator; continue mixing to prepare uniformed mixture; after drying uniformed mixture prepare a polyester elastomer membrane through an injection laminating process and apply pressure sensitive adhesive on one side of the polyester elastomer membrane. Prepared membrane poses good bonding characteristics to textile materials and can be used in production of clothing.Type: GrantFiled: May 27, 2020Date of Patent: March 21, 2023Assignee: TAIWAN TEXTILE FEDERATION, R.O.C.Inventors: Shu-Hui Huang, Sheng-Jen Lin, Yao-Hung Kuo, Jian-Fan Chen, Yun-Chin Kuo, Yu-Chuan Lin
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Patent number: 11572460Abstract: The present invention relates to a thermoplastic elastomer for carbon fiber reinforced plastic bonding lamination, which is contained in a layer to be laminated on a layer composed of a carbon-fiber reinforced plastic, wherein the thermoplastic elastomer for carbon fiber reinforced plastic bonding lamination contains a styrene-based thermoplastic elastomer and a polymer modified by an ?,?-unsaturated carboxylic acid, the styrene-based thermoplastic elastomer contains components (a) to (d), and a concentration of an ?,?-unsaturated carboxylic acid derived from the polymer modified by the ?,?-unsaturated carboxylic acid is 0.01 to 10% by mass.Type: GrantFiled: September 16, 2019Date of Patent: February 7, 2023Assignee: MCPP Innovation LLCInventor: Hiroyuki Mori
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Patent number: 11262338Abstract: Modified thermoplastic hydrocarbon thermoplastic resins are provided, as well as methods of their manufacture and uses thereof in rubber compositions. The modified thermoplastic resins are modified by decreasing the relative quantity of the dimer, trimer, tetramer, and pentamer oligomers as compared to the corresponding unmodified thermoplastic resin polymers, resulting in a product that exhibits a greater shift in the glass transition temperature of the elastomer(s) used in tire formulations. This translates to better viscoelastic predictors of tire tread performance, such as wet grip and rolling resistance. The modified thermoplastic resins impart remarkable properties on various rubber compositions, such as tires, belts, hoses, brakes, and the like. Automobile tires incorporating the modified thermoplastic resins are shown to possess excellent results in balancing the properties of rolling resistance, tire wear, snow performance, and wet braking performance.Type: GrantFiled: August 10, 2020Date of Patent: March 1, 2022Assignee: Eastman Chemical CompanyInventors: Mark Arigo, Terri Roxanne Carvagno, Jacobus Gillis De Hullu, Sebastian Finger, Hubert Hirschlag, Janine Klomp, Mutombo Joseph Muvundamina, Fabian Peters, Carla Recker, Christopher George Robertson, Peter Versluijs
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Patent number: 10920062Abstract: The present invention relates to a composition comprising two different (meth)acrylic polymers and a multistage polymer. In particular the present invention it relates to polymeric composition comprising two different (meth)acrylic polymers and a multistage polymer. The invention also relates to a process for manufacturing such polymeric composition. More particularly the present invention relates also to a process for preparing an impact modified composition comprising two different (meth)acrylic polymers and a multistage polymer.Type: GrantFiled: June 29, 2017Date of Patent: February 16, 2021Assignee: Arkema FranceInventors: Pierre Escale, Pierre Gerard, Aline Couffin, Raber Inoubli
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Patent number: 10908077Abstract: Methods and systems are provided for detecting mechanophore damage in a composite material where the mechanophores are embedded in a matrix of the composite material. A mechanical load is applied to the composite material. A damage precursor signal is generated as a result of the mechanical load and is detected before yield of the mechanophore embedded composite material. Detecting the damage precursor signal may include illuminating the mechanophore embedded composite material with UV light to excite the embedded mechanophores, capturing fluorescent emissions of the embedded mechanophores with a UV camera, and filtering light received at the UV camera based on an emission wavelength of the mechanophores. Alternatively, the damage precursor signal may be detected using spectra from an evanescent wave distorted by the mechanophore embedded composite material using an attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR) system.Type: GrantFiled: December 14, 2018Date of Patent: February 2, 2021Assignee: ARIZONA BOARD OF REGENTS ON BEHALF OF ARIZONA STATE UNIVERSITYInventors: Aditi Chattopadhyay, Bonsung Koo, Lenore Dai, Ryan Gunckel, Jack Miller
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Patent number: 10858488Abstract: Provided is a thermoplastic resin composition that can be firmly bonded to an adherend with an active energy ray-curable adhesive provided therebetween, and provided are a molded product and a film each including such a thermoplastic resin composition. Also provided are a thermoplastic resin composition that is less likely to be whitened even when the adhesive permeates thereinto and a molded product and a film each including such a thermoplastic resin composition. The thermoplastic resin composition according to the present disclosure contains 70 to 95 mass % of a thermoplastic resin and 5 to 30 mass % of a multilayer structure polymer (C) having a multilayer particle structure, and the multilayer structure polymer (C) has a median diameter Da of no less than 200 nm and less than 500 nm when the median diameter Da is measured through a laser diffraction/scattering technique with the thermoplastic resin composition dissolved in acetone.Type: GrantFiled: May 24, 2017Date of Patent: December 8, 2020Assignee: KURARAY CO., LTD.Inventors: Kaori Maeda, Noboru Higashida, Takao Hoshiba
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Patent number: 10844216Abstract: The present invention relates to a polymer composition comprising: a. poly(butylene terephthalate); b. glass fibres; and c. 1.5-10.0 wt % polyethylene with regard to the total weight of the polymer composition. Such polymer composition provides a desired combination of properties to enable the use in the production of thin-walled connectors, in that such polymer composition has a desirably high heat deflection temperature, good melt flow properties, high Charpy impact strength and high tensile strain at break.Type: GrantFiled: August 8, 2017Date of Patent: November 24, 2020Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventor: Chris van der Weele
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Patent number: 10550234Abstract: An acrylic resin film comprising 50 to 99 parts by mass of a methacrylic resin (A) comprising not less than 80% by mass of a structural unit derived from methyl methacrylate, and 50 to 1 part by mass of a block copolymer (B) comprising 40 to 90% by mass of methacrylic acid ester polymer block[s] (b1) and 10 to 60% by mass of acrylic acid ester polymer block[s] (b2), provided that the total of the methacrylic resin (A) and the block copolymer (B) is 100 parts by mass, wherein the methacrylic resin (A) and the block copolymer (B) satisfy the inequations (1) and (2): 0.5?Mw(A)/Mw(b1)?2.3??(1) 30000?Mw(b2)?120000??(2) in which Mw(A) is the weight average molecular weight of the methacrylic resin (A), Mw(b1) is the largest weight average molecular weight among the methacrylic acid ester polymer block[s] (b1) and Mw(b2) is the largest weight average molecular weight among the acrylic acid ester polymer block[s] (b2).Type: GrantFiled: November 25, 2014Date of Patent: February 4, 2020Assignee: KURARAY Co., Ltd.Inventors: Kaori Maeda, Takuya Tsujimoto, Toru Takahashi
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Patent number: 10435553Abstract: The present invention provides a resin composition including a vinylidene fluoride-based resin (A), having a crystal melting enthalpy of 10 to 45 J/g as measured with a differential scanning calorimeter, and having (2) IHv of 60 or less as obtained by (1) a light scattering measurement.Type: GrantFiled: March 9, 2018Date of Patent: October 8, 2019Assignee: Mitsubishi Chemical CorporationInventors: Tatsuhiro Hiraoka, Masashi Ikawa, Eiko Okamoto, Hiroshi Hosokawa, Kikue Irie
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Patent number: 10190029Abstract: The invention relates to a polyurethane (PU) reactive hot melt adhesive removable at elevated temperature as well as having a high bonding strength at room temperature.Type: GrantFiled: December 20, 2016Date of Patent: January 29, 2019Assignee: Henkel AG & Co. KGaAInventors: Uwe Franken, Claudia Meckel-Jonas, Hongxia Zhao, Yang Cao, Xiao Han
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Patent number: 9714338Abstract: An object of the present invention is to provide a polymer composition having properties resembling those of natural rubber, e.g. good durability (fracture resistance, wear resistance, and crack growth resistance), and a method for manufacturing the polymer composition. Specifically, the present invention provides a method for manufacturing a polymer composition including a mixture of polyisoprene and polystyrene/polybutadiene, comprising: polymerizing styrene monomer or butadiene monomer in the presence of a catalyst to synthesize polystyrene or polybutadiene; adding isoprene monomer to the polystyrene or polybutadiene thus synthesized, to synthesize polyisoprene and thus generate said mixture, wherein content of the styrene monomer or the butadiene monomer is set to be 10 mol % or less with respect to the total quantity of the styrene monomer/the butadiene monomer and the isoprene monomer.Type: GrantFiled: July 11, 2013Date of Patent: July 25, 2017Assignee: BRIDGESTONE CORPORATIONInventors: Satoru Tamaki, Shojiro Kaita, Junko Matsushita
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Patent number: 9695314Abstract: A resin composition contains an aromatic polycarbonate resin, an aromatic polyester resin, an acrylic triblock copolymer composed of a polymer block containing an acrylic acid ester unit and a polymer block containing a methacrylic acid ester unit, a glycidyl group-containing polyethylene copolymer, an organic phosphorus flame retardant, and a flame retardant antidrip agent.Type: GrantFiled: January 26, 2015Date of Patent: July 4, 2017Assignee: FUJI XEROX CO., LTD.Inventors: Akira Imada, Yuto Hanioka, Yuji Araki
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Patent number: 9553227Abstract: Provided are an optical element and a concentrating photovoltaic device which are each capable of preventing warpage and deformation of an optical functional pattern formed in a surface thereof due to stress even in an environment with extreme temperature changes. An optical element (4) of a concentrating photovoltaic device (1) concentrating sunlight includes: a glass substrate (5) and a sheet-like molded body (6) which is made of an organic resin and includes a Fresnel lens pattern (6a) in a surface and has the other surface bonded to the glass substrate (5). The sheet-like molded body (6) has a tensile elastic modulus of 1500 MPa or less, a linear expansion coefficient of 7.0×10?5/° C. or less, an average transmittance of 85% or more in a wavelength range from 350 to 1850 nm at a thickness of 400 ?m, and a haze value of 1.0% or less.Type: GrantFiled: July 9, 2013Date of Patent: January 24, 2017Assignee: KURARAY CO., LTD.Inventors: Koji Abe, Shinji Hiramatsu, Katsuhiro Fujita
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Patent number: 9255170Abstract: A block copolymer is provided. The block copolymer according to an exemplary embodiment includes a first block represented by Chemical Formula 1 and a second block represented by Chemical Formula 2: wherein COM1 and COM2 are independently selected from a polystyrene moiety, polymethylmethacrylate moiety, polyethylene oxide moiety, polyvinylpyridine moiety, polydimethylsiloxane moiety, polyferrocenyldimethylsilane moiety, and polyisoprene moiety, R1 is hydrogen or an alkyl group with 1 to 10 carbon atoms, Ph is a phenyl group, a is 1 to 50, R2 is hydrogen or an alkyl group with 1 to 10 carbon atoms, and b is 1 to 50.Type: GrantFiled: November 21, 2013Date of Patent: February 9, 2016Assignees: SAMSUNG DISPLAY CO., LTD., KOREA UNIVERSITY RESEARCH AND BUSINESS FOUNDATION, SOGANG UNIVERSITY RESEARCH FOUNDATIONInventors: Min Hyuck Kang, Su Mi Lee, Myung Im Kim, Tae Woo Kim, Seung-Won Park, Xie Lei, Na Na Kang, Bong-Jin Moon, Joona Bang, Sang Hoon Woo, Jin Yeong Lee, Hyun Jung Jung, June Huh
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Patent number: 9030762Abstract: The present invention relates to a polyester resin including a diol constitutional unit and a dicarboxylic acid constitutional unit as main constitutional units, in which the diol constitutional unit contains from 70 to 95% by mol of a constitutional unit derived from ethylene glycol and from 5 to 30% by mol of a constitutional unit derived from tricyclodecane dimethanol or pentacyclopentadecane dimethanol, and the dicarboxylic acid constitutional unit contains 50% by mol or more of a constitutional unit derived from a naphthalenedicarboxylic acid, and an optical lens obtained by molding the polyester resin. According to the present invention, there are provided a polyester resin that has a high refractive index and a low Abbe number and can be molded into a good optical lens, and an optical lens obtained by molding the polyester resin.Type: GrantFiled: December 7, 2011Date of Patent: May 12, 2015Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Takuya Minezaki, Takeshi Hirokane
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Patent number: 9028933Abstract: The present invention is a shrink label, comprising a heat-shrinkable multilayer resin film comprising an intermediate layer comprising a polystyrene type resin and outer surface layers comprising a polyester type resin, with said intermediate layer interposed therebetween, as a base film, wherein the polystyrene type resin composing said intermediate layer is an aromatic vinyl hydrocarbon-conjugated diene copolymer, and said intermediate layer is bonded to said outer surface layers with an adhesive layer comprising a hydrogen addition product of an aromatic vinyl hydrocarbon-conjugated diene copolymer, having at least one functional group selected from the group consisting of a carboxylic group, an acid anhydride group, an amino group, an epoxy group and a hydroxyl group in a molecule.Type: GrantFiled: February 16, 2006Date of Patent: May 12, 2015Assignee: Gunze LimitedInventors: Naoyuki Maruichi, Takanori Nozaki, Akira Morikawa
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Patent number: 9000099Abstract: The invention provides compositions comprising at least one propylene-based polymer, at least one peroxide and at least one coagent.Type: GrantFiled: July 10, 2008Date of Patent: April 7, 2015Assignee: Dow Global Technologies LLCInventors: William J. Harris, John D. Weaver, Nelson G. Rondan, Drew A. Davidock
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Publication number: 20150010743Abstract: A film including poly(vinylidene fluoride) and a block copolymer with at least two endblock polymeric units that are each derived from a first monoethylenically unsaturated monomer selected from a methacrylate, acrylate, styrene, or combination thereof; and at least one midblock polymeric unit is derived from a second monoethylenically unsaturated monomer selected from a methacrylate, acrylate, vinyl ester, or combination thereof, each endblock having a glass transition temperature of at least 50° C., and each midblock having a glass transition temperature no greater than 20° C. The film may further include poly(methyl methacrylate). The film may be a multilayer film with a first outer layer and a second outer layer opposite the first outer layer. The multilayer film may include a multiplicity of interior layers between the first and second outer layers, or the first outer layer may be adjacent to the second outer layer. Articles and methods are also disclosed.Type: ApplicationFiled: January 30, 2013Publication date: January 8, 2015Applicant: 3INNOVATIVE PROPERTIES COMPANYInventors: Rajesh K. Katare, Timothy J. Hebrink, Mark B. O'Neill
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Publication number: 20140370442Abstract: Block copolymers and methods of making patterns of organic thin films using the block copolymers. The block copolymers comprise a fluorinated block. Thin films of the block copolymers have microdomains that can be aligned. As a result the patterns of organic thin films having smaller dimensions than the pattern of incident deep-UV or e-beam radiation can be formed. For example, the block copolymers can be used in lithography, filtration, and templating applications.Type: ApplicationFiled: September 6, 2012Publication date: December 18, 2014Applicant: CORNELL UNIVERSITYInventors: Christopher K. Ober, Rina Maeda, Nam-ho You, Teruaki Hayakawa
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Patent number: 8871856Abstract: The invention relates to compositions comprising two structured linear copolymers selected from the group consisting of block copolymers and gradient copolymers, these copolymers being prepared by different controlled polymerization techniques and the difference in the polydispersities of these copolymers, ?(Mw/Mn), being ?0.25. The invention further relates to the production of such blends and to their use as wetting agents and dispersants.Type: GrantFiled: October 9, 2007Date of Patent: October 28, 2014Assignee: BYK-Chemie GmbHInventors: Bernd Göebelt, Jurgen Omeis, Sabine Johann, Sandra O'Shea
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Patent number: 8802775Abstract: The invention relates to aqueous formulations comprising silane-modified polymeric binders having a siloxane content and inorganic nanoparticles, a process for the preparation thereof and the use thereof for the preparation of aqueous coating compositions.Type: GrantFiled: August 17, 2012Date of Patent: August 12, 2014Assignee: Bayer MaterialScience AGInventors: Arno Nennemann, Christoph Irle, Nusret Yuva, Alice Münzmay
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Patent number: 8772408Abstract: The present invention relates to aqueous binder dispersions based on silane-modified polymeric binders and inorganic nanoparticles, a process for the preparation thereof and the use thereof for the production of high quality coatings, in particular clear lacquers.Type: GrantFiled: August 17, 2012Date of Patent: July 8, 2014Assignee: Bayer Intellectual Property GmbHInventors: Michael Mager, Markus Mechtel, Nusret Yuva, Alice Münzmay
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Patent number: 8760040Abstract: The present invention relates to one of energy conversion devices, actuator and a dielectric layer used in the actuator. The present invention provides a polymer blend composition capable of easily controlling the ability of converting electrical energy to mechanical energy, which is prepared by blending a piezoelectric polymer with a flexible elastomeric block copolymer showing an effective miscibility therewith, and a tunable actuator using the same.Type: GrantFiled: November 3, 2011Date of Patent: June 24, 2014Assignee: Korea Institute of Science and TechnologyInventors: Chong-Min Koo, Kyung-Youl Baek, Soon-Man Hong, Seung-Sang Hwang, Hee-La Kwak, Kyung-ho Min, Jin-Hong Lee, Kie-Yong Cho, Sang-Hee Park
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Publication number: 20140148552Abstract: The present invention provides a biomimetic agent for anti-fouling coating and a method for making the same. The biomimetic agent comprises a block, random, or alternating copolymer having a general formula (1): AUnBUm, where AU represents a repeating unit comprising an anchoring moiety, BU represents a repeating unit comprising a zwitterionic moiety or a pseudo-zwitterionic moiety, m is an integer of 5˜120 and n is an integer of 5˜120.Type: ApplicationFiled: November 30, 2012Publication date: May 29, 2014Applicant: CHUNG YUAN CHRISTIAN UNIVERSITYInventors: Yung Chang, Ruoh-Chyu Ruaan, Hui-Shan Yang, Kueir-Rarn Lee, Juin-Yih Lai
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Publication number: 20140127445Abstract: The present invention relates to molding and overmolding compositions for delicate components. More particularly the invention relates to compositions for low pressure molding and overmolding, making these compositions particularly well suited for electronic devices. The molding and overmolding composition is suitable for low pressure injection molding processes, particularly at 0.5 to 200 bars at 70° C. to 240° C.Type: ApplicationFiled: March 14, 2013Publication date: May 8, 2014Applicant: Henkel CorporationInventors: Cynthia L. Cain, Charles W. Paul, Maria Cristina Barbosa DeJesus
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Publication number: 20140107294Abstract: An extended film and a manufacturing method thereof are provided. The extended film includes a poly(lactic acid) and a block copolymer, wherein the block polymer includes a first block, a second block and a third block that connected with each other by chemical bonds. The extended film is formed by steps of mixing poly(lactic acid) and the block copolymer to form a mixture, compressing the mixture to form a board body and extending the board body to form an extended film, thereby forming an extended film having properties of high thermal-resistance and high transparency, the film thus obtained is applicable for packaging use.Type: ApplicationFiled: December 26, 2012Publication date: April 17, 2014Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTEInventors: Chien-Pang WU, Jyh-Horng WU, Kuo-Chen SHIH, Chi-Yuan HUNG, Chia-Hao LI, Yao-Zu WU, Chuh-Yung CHEN
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Patent number: 8697811Abstract: A curable resin composition, which contains, with respect to 100 parts of an epoxy resin, 1 to 70 parts of an epoxy resin curing agent and 1 to 50 parts of an acrylic block copolymer, and the acrylic block copolymer contains (?) at least one polymer block A composed of a structural unit derived from an alkyl methacrylate and at least one polymer block B composed of a structural unit derived from an alkyl acrylate, has a weight average molecular weight (Mw) of 30,000 to 300,000 and a molecular weight distribution (Mw/Mn) of 1.5 or less, and contains 3 to 60 percent by mass of the polymer block A. In addition, a cured resin is formed from the above curable resin composition.Type: GrantFiled: February 12, 2009Date of Patent: April 15, 2014Assignees: Kuraray Co., Ltd., HyogoInventors: Hajime Kishi, Yumi Kunimitsu, Jin Imade, Shinya Oshita, Yoshihiro Morishita, Mitsunori Asada
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Patent number: 8647739Abstract: The present invention relates to the field of nanostructured acrylic polymer materials having both very good optical properties and good mechanical and surface properties. The invention relates to an acrylic resin composition containing a PMMA matrix (component 1) having a glass transition temperature of greater than 0° C., dispersed in which is an acrylic block copolymer (component 2). Characteristically, the composition of the invention contains from 60 to 80% by weight of said PMMA matrix, and from 20 to 40% by weight of said block copolymer. According to another aspect, the invention relates to a transparent flat article containing the aforementioned acrylic resin composition, having the following features: a thickness ranging from 300 to 900 microns, preferably from 400 to 700 micrometers; a light transmission at least equal to 91%; a haze of less than or equal to 2%; and no appearance of haze when the temperature rises to 80° C.Type: GrantFiled: September 25, 2009Date of Patent: February 11, 2014Assignee: Arkema FranceInventor: Pierre Gerard
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Publication number: 20140030538Abstract: The subject of the present invention is a semi-rigid or flexible and low-gloss impact-reinforced acrylic material. The acrylic material according to the invention comprises a nanostructured matrix constituted of at least one thermoplastic acrylic block copolymer and at least one highly crosslinked acrylic copolymer. The matrix comprises at least one thermoplastic acrylic block copolymer. The highly crosslinked acrylic copolymer comprises, as sole monomer or as predominate monomer, MMA, that is to say that it comprises, by weight, more than 50%, advantageously more than 65% of MMA. The acrylic material according to the invention comprises from 60% to 99% by weight of matrix for 40% to 1% by weight of crosslinked copolymer. These materials may be converted by injection molding, extrusion, co-extrusion, extrusion-blow molding for producing parts, profiles, sheets or films for example.Type: ApplicationFiled: April 5, 2012Publication date: January 30, 2014Applicant: Arkema FranceInventors: Jean-Marc Boutillier, Jean-Pierre Disson
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Publication number: 20140024779Abstract: A polymer composition comprising star macromolecules is provided. Each star macromolecule has a core and five or more arms, wherein the number of arms within a star macromolecule varies across the composition of star molecules. The arms on a star are covalently attached to the core of the star; each arm comprises one or more (co)polymer segments; and at least one arm and/or at least one segment exhibits a different solubility from at least one other arm or one other segment, respectively, in a reference liquid of interest.Type: ApplicationFiled: September 25, 2013Publication date: January 23, 2014Applicant: ATRP Solutions, Inc.Inventors: Wojciech Jakubowski, Patrick McCarthy, Nicolay Tsarevsky, James Spanswick
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Publication number: 20140018440Abstract: According to an aspect of the present invention, internal medical devices are provided, which contain at least one surface region that comprises a polymer brush. The polymer brush, in turn, contains one or more types of hydrophobic polymer chains and one or more types of hydrophilic polymer chains.Type: ApplicationFiled: September 18, 2013Publication date: January 16, 2014Applicant: Boston Scientific Scimed, Inc.Inventor: Mark Boden
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Patent number: 8629213Abstract: The invention relates to a composition including at least one elastomer and at least one supramolecular polymer. The supramolecular polymer is obtained by the reaction of at least one trifunctional compound (A), having first and second functions, with: at least one compound (B) having at least one reactive group capable of reacting with the first functions of (A) and at least one associative group; and at least one at least bifunctional compound (C) having functions capable of reacting with the second functions of compound (A) in order to form ester, thioester and amide bridges.Type: GrantFiled: September 21, 2010Date of Patent: January 14, 2014Assignee: Arkema FranceInventors: Manuel Hidalgo, Christelle Plaut, Alfredo Defrancisci
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Patent number: 8598272Abstract: A blend polymer composition includes a styrene-based polymer, a non-styrene-based polymer, and a compatibilizer having a block copolymer. The block copolymer includes: a first block including a first monomer unit having an epoxy group, and a second monomer unit selected from an acrylate-based monomer unit, a methacrylate-based monomer unit, and a combination thereof; and a second block including a styrene-based monomer unit. The block copolymer has an epoxy equivalent ranging from 1000 g/eq to 20000 g/eq and a molecular weight distribution index ranging from 1.0 to 2.0.Type: GrantFiled: January 5, 2011Date of Patent: December 3, 2013Assignee: Chi Mei CorporationInventors: Jui-Hsi Hsu, Ming-Chou Kao
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Publication number: 20130316234Abstract: A modifier for polyvinylidene fluoride (PVDF), which improves the adhesion of PVDF to a metal, a binder resin composition for battery and a battery using the PVDF modifier are provided. The modifier for polyvinylidene fluoride herein is a modifier in which the peeling strength of a specific cured film to an aluminium foil is 20 g/cm or more, and the specific cured film is obtained from a mixture of 6 parts by mass of the modifier for polyvinylidene fluoride and 14 parts by mass of a polyvinylidene fluoride composition. The modifier preferably contains a macromonomer copolymer (X), obtained by polymerizing both a macromonomer (A) having unsaturated double bonds and a vinyl monomer (B) having polar groups. The macromonomer (A) is preferably a methacrylic acid ester-based macromonomer (A-1). The vinyl monomer (B) is preferably a methacrylate, and a fluoroalkyl methacrylate.Type: ApplicationFiled: January 5, 2012Publication date: November 28, 2013Applicant: MITSUBISHI RAYON CO., LTD.Inventors: Fumino Momose, Mitsufumi Nodono
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Publication number: 20130289205Abstract: Disclosed is a resin composition for laser engraving, comprising: (Component A) a macroinitiator having a structure represented by any one of Formulae I to V below obtained by step-growth polymerization; and (Component B) a polymerizable compound.Type: ApplicationFiled: April 24, 2013Publication date: October 31, 2013Applicant: FUJIFILM CorporationInventor: Atsushi SUGASAKI
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Publication number: 20130281573Abstract: Provided are: a fiber-reinforced composite material which has mode I interlaminar fracture toughness, mode II interlaminar fracture toughness and compressive strength under heat and humidity conditions at the same time; an epoxy resin composition for obtaining the fiber-reinforced composite material; and a prepreg which is obtained using the epoxy resin composition. An epoxy resin composition for fiber-reinforced composite materials, which contains at least the following constituent elements (A), (B), (C) and (D). (A) An epoxy resin (B) Resin particles that satisfy the following conditions (b1)-(b3) and are insoluble in an epoxy resin (b1) The particle size distribution index is 1.0-1.8. (b2) The particle sphericity is 90 or more. (b3) The glass transition temperature of the particles is 80-180° C. (C) At least one elastomer component that is selected from among block copolymers containing a block having a glass transition temperature of 20° C.Type: ApplicationFiled: January 20, 2012Publication date: October 24, 2013Applicant: TORAY INDUSTRIES, INC.Inventors: Yuko Goto, Nobuyuki Tomioka, Yuji Echigo, Hiroaki Sakata, Shiro Honda, Hiroshi Taiko
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Publication number: 20130240481Abstract: The present invention relates to a composition including: a component (A) being a block copolymer including a block PA bonded to one, or two or more blocks incompatible with the block PA and whose etching selectivity to the block PA is greater than one; and a component (B) being at least one polymer selected from the group consisting of a random copolymer and a homopolymer, wherein the polymer of the component (B) is compatible with at least one block other than the block PA within the blocks constituting the block copolymer of the component (A), and is incompatible with the block PA.Type: ApplicationFiled: March 7, 2013Publication date: September 19, 2013Applicant: TOKYO OHKA KOGYO CO., LTD.Inventors: Takahiro Senzaki, Ken Miyagi, Kenichiro Miyashita
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Publication number: 20130225753Abstract: A polymer composition comprising a methacrylic resin (A) having not less than 50% by mass of repeated units derived from methyl methacrylate, a block copolymer (B) having a polymer block (a) composed of repeated units derived from an alkyl(meth)acrylate ester and a polymer block (b) composed of repeated units derived from a conjugated diene compound and flowable polyorganosiloxane (C), wherein the amount of the block copolymer (B) is 1 to 80 parts by mass relative to 100 parts by mass of the methacrylic resin (A), the amount of the flowable polyorganosiloxane (C) is 0.05 to 0.5 part by mass relative to 100 parts by mass of the block copolymer (B), and a phase composed of the block copolymer (B) is dispersed in a continuous phase composed of the methacrylic resins (A).Type: ApplicationFiled: August 31, 2011Publication date: August 29, 2013Applicant: KURARAY CO., LTD.Inventors: Katsuji Miyake, Hiroshi Ozawa, Hiroyuki Konishi
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Publication number: 20130217827Abstract: An object of the present invention is to provide a methacrylic resin composition which exhibits excellent flexibility, elasticity, impact resistance, and plasticity and moldability while transparency inherent to methacrylic resins is maintained. A methacrylic resin composition to be produced is composed of 10 to 99 parts by mass of a methacrylic resin (A) containing not less than 80 mass % of a methyl methacrylate unit and 90 to 1 part by mass of a block copolymer (B) containing 10 to 60 mass % of a methyl methacrylate polymer block (b1) and 90 to 40 mass % of an acrylate polymer block (b2) and having a refractive index of 1.485 to 1.495 (the total of (A) and (B) is 100 parts by mass).Type: ApplicationFiled: October 24, 2011Publication date: August 22, 2013Applicant: Kuraray Co., Ltd.Inventors: Hiroshi Ozawa, Toru Takahashi, Atsushi Matsumura, Kenichi Hamada, Yoshihiro Morishita, Toyoaki Kurihara
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Publication number: 20130217805Abstract: An epoxy resin composition containing an epoxy resin [A1], epoxy resin [B1], epoxy resin [C1] and curing agent [D] wherein [A1] is a bisphenol-type epoxy resin with a softening point of 90° C. or more, [B1] is a tri- or higher functional amine-type epoxy resin, [C1] is a bisphenol F-type epoxy resin with a number average molecular weight of 450 or less, and the epoxy resins [A1] to [C1] satisfy the following contents per 100 parts by mass of total epoxy resin content: [A1] 20 to 50 parts by mass, [B1] 30 to 50 parts by mass and [C1] 10 to 40 parts. The present invention provides low-viscosity epoxy resin compositions that are excellent in impregnating reinforcing fibers and capable of producing cured resins with excellent modulus and toughness, as well as prepregs and fiber-reinforced composite materials based on those epoxy resin compositions.Type: ApplicationFiled: September 26, 2011Publication date: August 22, 2013Applicant: TORAY INDUSTRIES, INC.Inventors: Mami Hayashi, Takayuki Fujiwara, Jun Misumi, Kenichi Yoshioka
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Publication number: 20130164468Abstract: A heat-shrinkable film having a layer made of a mixed resin containing a polylactic acid resin and a polyolefin resin as the main components, wherein the mass ratio of the polylactic acid resin and the polyolefin resin is 95/5 to 50/50, the polylactic acid resin is a copolymer of D-lactic acid and L-lactic acid or a mixed resin of the copolymer, the D/L ratio of D-lactic acid and L-lactic acid is 3/97 to 15/85 or 85/15 to 97/3, the storage elastic modulus of the polyolefin resin or the soft acrylic resin at 20° C. is ?100 MPa as measured at an oscillation frequency of 10 Hz and a strain of 0.1%, the film is stretched in at least one direction, and the heat shrinkage ratio of the film in the main shrinking direction is ?20% as measured after the film is immersed in 80° C. water for 10 seconds.Type: ApplicationFiled: February 26, 2013Publication date: June 27, 2013Applicant: Mitsubishi Plastics, Inc.Inventor: Mitsubishi Plastics, Inc.
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Patent number: 8450412Abstract: A composition is prepared by melt blending specific amounts of a polyamide, a flame retardant that includes brominated polystyrene, a polymeric flame retardant synergist, and a compatibilizing agent. The polymeric flame retardant synergist can be a poly(arylene ether), a poly(arylene ether)-polysiloxane block copolymer, or a mixture thereof. The composition is useful for molding automotive and electrical parts.Type: GrantFiled: December 22, 2009Date of Patent: May 28, 2013Assignee: Sabic Innovative Plastics IP B.V.Inventors: Mark Elkovitch, Sai-Pei Ting, Robert Russell Gallucci
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Patent number: 8415438Abstract: Disclosed is a new method and compositions from the method consisting of block copolycarbonate/phosphonates that exhibit an excellent combination of flame resistance, hydrolytic stability, high Tg, low melt viscosity, low color and high toughness. Also disclosed are polymer mixtures or blends comprised of these block copolycarbonate/phosphonate compositions and commodity and engineering plastics and articles produced therefrom. Further disclosed are articles of manufacture produced from these materials, such as fibers, films, coated substrates, moldings, foams, adhesives and fiber-reinforced articles, or any combination thereof.Type: GrantFiled: October 26, 2010Date of Patent: April 9, 2013Assignee: FRX Polymers, Inc.Inventor: Dieter Freitag
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Patent number: 8383748Abstract: Process for the preparation of impact-strengthened cast PMMA sheets comprising the following stages: 1. a mixture comprising: at least one alkoxyamine Z(-T)n, in which Z denotes a polyvalent group and n an integer greater than 2, preferably of between 2 and 10, advantageously between 2 and 8, and the monomer(s) intended to form a central block B is heated to a temperature sufficient to activate the alkoxyamine and polymerize the monomer(s); 2. the central block B, optionally mixed with the unconsumed monomer(s) from stage 1, is reactivated in the presence of the monomer(s) intended to form the branches A; 3. MAM and optionally at least one comonomer M which can be copolymerized by the radical route with MMA and at least one radical initiator are added to the mixture obtained in stage 2; 4. the mixture from stage 3 is cast in a mould and then heated.Type: GrantFiled: December 9, 2005Date of Patent: February 26, 2013Assignee: Arkema FranceInventors: Olivier Guerret, Jean-Yves Chenard, Yannick Ederle
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Patent number: 8378024Abstract: The present invention relates to a low surface gloss styrene resin composition. The composition of the present invention is composed of (A) 80-99.9 weight % of the basic resin comprising rubber-modified styrene resin and (B) 0.1-20 weight % of syndiotactic polystyrene, the matting agent. The composition also includes (C) hydrogenated styrene block copolymer comprising styrene block and butadiene rubber block as a compatibilizer by 0.1-20 weight % for the total weight of the low surface gloss styrene resin composed of (A) the basic resin and (B) the matting agent and additionally includes (D) a plasticizer by 0.1-30 weight %. The composition of the present invention has excellent weatherability and impact-resistance in addition to the low surface gloss properties, so that it can be applied in various products, particularly exterior products for structures such as sidings and window frames, etc.Type: GrantFiled: January 30, 2008Date of Patent: February 19, 2013Assignee: LG Chem, Ltd.Inventors: Yun-kyoung Cho, Seon-mo Son, Bong-keun Lee, Tae-bin Ahn, Han-jong You, Sung-tae Ahn
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Patent number: 8362148Abstract: The present invention provides a curable composition comprising: (a) a resin composition being liquid at 23° C. and comprising monomers or oligomers or a mixture of monomers and oligomers polymerizable by a ring-opening reaction; (b) an impact modifier containing one or more block copolymers having at least one block composed of methyl methacrylate and (c) one or more polymerization initiators. The curable resin composition can be used for curable coatings per se and in specific for stereolithography and other applications such as three dimensional printing applications where a 3D object is formed.Type: GrantFiled: March 12, 2008Date of Patent: January 29, 2013Assignee: 3D Systems, Inc.Inventors: Loic Messe, Carole Chapelat
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Patent number: 8357754Abstract: A process for producing a microporous polymeric object to improve the degree of freedom for its various properties, compared to conventional processes, includes: mixing a block copolymer made of three or more kinds of segments with a polymer, wherein one or more of the segments are made of monomer units having a first functional group forming ionic and/or hydrogen bond, the segments constitute a co-continuous structure having mutually-independent and continuous regions due to a phase separation based on incompatibility between the segments, and the polymer has, at other than polymer chain terminals, a second functional group forming such bond with the first functional group, thereby allowing the segments to associate with the polymer at many points; forming a co-continuous structure including a region composed of the polymer and the segments due to the phase separation; and removing the polymer from the region by weakening the bond between the functional groups.Type: GrantFiled: May 8, 2012Date of Patent: January 22, 2013Assignee: Nitto Denko CorporationInventors: Takahisa Konishi, Takuji Shintani, Yushu Matsushita, Atsushi Takano, Takeshi Asari
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Patent number: 8338534Abstract: A process for producing a microporous polymeric object to improve the degree of freedom for its various properties, compared to conventional processes, includes: mixing a block copolymer made of three or more kinds of segments with a polymer, wherein one or more of the segments are made of monomer units having a first functional group forming ionic and/or hydrogen bond, the segments constitute a co-continuous structure having mutually-independent and continuous regions due to a phase separation based on incompatibility between the segments, and the polymer has, at other than polymer chain terminals, a second functional group forming such bond with the first functional group, thereby allowing the segments to associate with the polymer at many points; forming a co-continuous structure including a region composed of the polymer and the segments due to the phase separation; and removing the polymer from the region by weakening the bond between the functional groups.Type: GrantFiled: January 7, 2008Date of Patent: December 25, 2012Assignee: Nitto Denko CorporationInventors: Takahisa Konishi, Takuji Shintani, Yushu Matsushita, Atsushi Takano, Takeshi Asari
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Publication number: 20120286627Abstract: The present invention relates to a polymer blend composition comprising a dielectric elastomer, an actuator film manufactured using the same, and an actuator comprising the film. The polymer blend composition according to the present invention comprises a block copolymer having excellent compatibility with the dielectric elastomer and excellent dielectric properties, and thus displacement values suitable for the purpose can be obtained by a simple method of adjusting a composition of the polymer blend. Moreover, the film manufactured using the same has high dielectric constant, low dielectric loss and high electromechanical displacement, and thus the film exhibits excellent dielectric properties when it is applied in a dielectric layer for an actuator.Type: ApplicationFiled: May 8, 2012Publication date: November 15, 2012Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGYInventors: Chong-Min KOO, Soon-Man HONG, Kyung-Youl BAEK, Seung-Sang HWANG, Youn-Duk PARK, Kyung-Ho MIN, Jin-Hong LEE, Yun-Jae LEE, Ji-Young JUNG, Jang-Woo LEE