Solid Block Or Block-type Copolymer Derived From Reactant Containing Carboxylic Acid Ester Group Patents (Class 525/94)
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Patent number: 6162868Abstract: The present invention relates to a pressure-sensitive adhesive comprising:a mixture of a block copolymer (A) comprising polystyrene blocks and polybutadiene or polyisoprene blocks which are optionally hydrogenated and of a copolymer (B) of ethylene and of an alkyl (meth)acrylate,at least one tackifying resin and optionally a plasticizer,this adhesive being deposited while hot on a substrate.These products are useful for self-adhesive labels and tapes.Type: GrantFiled: September 24, 1998Date of Patent: December 19, 2000Assignee: Elf Atochem S.A.Inventors: Eric Radigon, Jean Lebez, Jean-Michel Pierrot
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Patent number: 6143826Abstract: A polymer blend comprising:(A) an acrylic resin;(B) a block copolymer consisting essentially of a polymer block of a polymerized aromatic vinyl compound and/or a polymer block of a polymerized methacrylate monoester and a polyolefin polymer block; and(C) a polymer miscible with the acrylic resin (A) and immiscible with the block copolymer (B),wherein the absolute value (.vertline..eta..sub.AC -.eta..sub.B .vertline.) of the difference between the refractive index (.eta..sub.AC) of the blend of the acrylic resin (A) and the polymer (C) and the refractive index (.eta..sub.B) of the block copolymer (B) is 0.01 or less. This polymer block has excellent transparency, softness and other properties.Type: GrantFiled: September 24, 1997Date of Patent: November 7, 2000Assignee: Kuraray Co., Ltd.Inventors: Takashi Ohnaga, Katsunori Takamoto, Yukihiro Fujieda, Katsuei Takahashi, Kenichi Hamada
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Patent number: 6090889Abstract: This invention discloses a rubbery polymer having improved properties which is comprised of repeat units which are derived from (a) butyl acrylate, or optionally a mixture of butyl acrylate and 2-ethylhexyl acrylate containing up to about 40 percent 2-ethylhexyl acrylate, (b) at least one member selected from the group consisting of methyl methacrylate, ethyl methacrylate, methyl acrylate and ethyl acrylate, (c) acrylonitrile, (d) styrene and (e) a crosslinking agent; wherein a chemical agent or a copolymer containing hydroxyl groups, ester groups, amine groups or carboxylic acid groups is grafted onto said rubbery polymer. The grafting can be done in the presence or in the absence of a carrying polymer matrix which should be inert with regard to the grafting reaction. Fatty alcohols and ethylene vinyl acetate are representative examples of agents which can be grafted onto the rubbery polymer.Type: GrantFiled: April 23, 1998Date of Patent: July 18, 2000Assignee: The Goodyear Tire & Rubber CompanyInventors: Agnes Marie Madeleine Louise De Loor, Francois Jean-Marie Breton, Hung Dang Ngoc
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Patent number: 6013726Abstract: A polystyrene-based resin composition containing a styrene-based resin with mainly syndiotactic configuration, a polyamide, and a rubber polymer as main components.Type: GrantFiled: June 5, 1995Date of Patent: January 11, 2000Assignee: Idemitsu Kosan Co., Ltd.Inventors: Akikazu Nakano, Takashi Sumitomo, Keisuke Funaki, Toshikazu Ijitsu, Michihiro Sawada, Masahiko Kuramoto, Masakazu Suzuki
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Patent number: 5973075Abstract: Methods for preparing rigid-rod macromonomers having a polyaromatic backbone, solubilizing side groups, and reactive end groups are provided. Such methods include catalytic reductive coupling of substituted 1,4-dihaloaromatic compounds in the presence of an endcapping moiety.Type: GrantFiled: June 8, 1998Date of Patent: October 26, 1999Assignee: Maxdem IncorporationInventors: Robert R. Gagne, Matthew Louis Marrocco, III, Mark Steven Trimmer, Neil H. Hendricks
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Patent number: 5955546Abstract: The invention relates to melt-miscible polyolefin blends, and a process for preparing the melt-miscible blends, of two or more polyolefins. Matching, within defined limits, the segment length of a modifying polyolefin with the segment length of a primary polyolefin, such as polypropylene or an ethylene/alpha-olefin copolymer, provides blends of the "matched" components which blends were heretofore unknown to be melt-miscible. A broad range of polyolefin blend compositions, and of polyolefin blends containing other polymers made compatible or dispersible with the polyolefin blend compositions, are defined, all of the blend compositions having at least one melt-miscible polyolefin phase.Type: GrantFiled: January 16, 1998Date of Patent: September 21, 1999Assignee: Regents of the University of MinnesotaInventors: Frank S. Bates, Jeffrey H. Rosedale, Mark F. Schulz, Kristoffer Almdal
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Patent number: 5927029Abstract: Seals for automotive body applications (such as, windows, hoods, trunks and doors) and building applications (such as, window glazing gaskets and weather strips) should be dimensional stable, provide low compression set and offer outstanding sealing characteristics over a broad temperature range. They must be capable of sealing out noise, wind and water, while providing long-term ultraviolet light resistance.Type: GrantFiled: October 14, 1998Date of Patent: July 27, 1999Assignee: The Goodyear Tire & Rubber CompanyInventor: Hung Dang Ngoc
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Patent number: 5910526Abstract: The specification discloses a polyphenylene oxide delivery system for use in preparing an A-B-A block copolymer adhesive formulation having an increased service temperature. The delivery system comprises a preblend of polyphenylene oxide (PPO) resin having a T.sub.g within the range of from about 150.degree. to about 210.degree. C. and a B-block compatible resin. The PPO/B-block resin preblend enables introduction of more PPO into the composition thereby increasing the service temperature of the adhesive formulation.Type: GrantFiled: September 14, 1998Date of Patent: June 8, 1999Assignee: Arizona Chemical CompanyInventors: Wayne K. Chu, Erwin R. Ruckel
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Patent number: 5900464Abstract: Polar polymers having the following formula:FG--(Q).sub.d --R.sub.n --Z--J--?A(R.sup.1 R.sup.2 R.sup.3)!.sub.x(I)wherein FG is H or a protected or non-protected functional group; Q is a polar hydrocarbyl group derived by incorporation of a polar compound selected from group consisting of esters, amides, and nitriles of acrylic and methacrylic acid, and mixtures thereof; d is an integer from 10 to 2000; R is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; n is an integer from 0 to 5; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; ?A(R.sup.1 R.sup.2 R.sup.3)!.sub.x is a protecting group, in which A is an element selected from Group IVa of the Periodic Table of Elements; R.sup.1, R.sup.2, and R.sup.Type: GrantFiled: July 10, 1996Date of Patent: May 4, 1999Assignee: FMC CorporationInventors: Robert J. Letchford, James A. Schwindeman, Conrad W. Kamienski, Roderic P. Quirk
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Patent number: 5869568Abstract: A one-part cold crosslinking emulsion composition containing, in an aqueous medium, a double-structure fine grain comprising the following Component (A) 1 and the following Component (B) 2 covering the same, wherein the following Component (C) is contained in Component (B) 2:(A) a copolymer comprising an epoxy group-containing monomer and an ethylenic unsaturated monomer;(B) a copolymer comprising an unsaturated carboxylic acid and an ethylenic unsaturated monomer; and(C) a low molecular weight monofunctional epoxy compound.Type: GrantFiled: November 12, 1997Date of Patent: February 9, 1999Assignee: National Starch and Chemical Investment Holding CorporationInventor: Norihisa Maeda
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Patent number: 5859113Abstract: A pigment dispersion useful for forming coating compositions containing dispersed pigment, a carrier liquid and an AB-block polymer dispersant (binder);the AB block polymer has a number average molecular weight of about 5,000-20,000 and contains 20-80% by weight of a polymeric A segment and correspondingly 80-20% by weight of a polymeric B segment; whereinthe polymeric A segment of the block polymer is of polymerized glycidyl (meth)acrylate monomers reacted with an acid from the group of aromatic carboxylic acids or aliphatic carboxylic acids; andthe B segment is of polymerized alkyl (meth)acrylate monomers having 1-12 carbon atoms in the alkyl group, hydroxy alkyl (meth)acrylate monomers having about 1-4 carbon atoms in the alkyl group; andwherein the weight ratio of pigment to binder in the dispersion is about 1/100-200/100.Type: GrantFiled: July 17, 1997Date of Patent: January 12, 1999Assignee: E. I. du Pont de Nemours and CompanyInventors: Patrick F. McIntyre, James G. King, Harry J. Spinelli, Henry G. Jakubauskas
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Patent number: 5859132Abstract: Seals for automotive body applications (such as, windows, hoods, trunks and doors) and building applications (such as, window glazing gaskets and weather strips) should be dimensional stable, provide low compression set and offer outstanding sealing characteristics over a broad temperature range. They must be capable of sealing out noise, wind and water, while providing long-term ultraviolet light resistance.Type: GrantFiled: April 1, 1997Date of Patent: January 12, 1999Assignee: The Goodyear Tire & Rubber CompanyInventor: Hung Dang Ngoc
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Patent number: 5849822Abstract: A thermoplastic resin composition having transparency and antistatic properties, comprising 100 parts by weight of a thermoplastic resin (A) having a refractive index of 1.52 to 1.61 and a haze of 40 or less, and 5 to 40 parts by weight of a polyetherester (B) which has a sulfonate group and a polyalkylene oxide group, and is substantially immiscible with the thermoplastic resin (A), the difference in refractive index between the thermoplastic resin (A) and the polyetherester (B) being 0.04 or less. The thermoplastic resin composition has a haze of 40% or less and a surface resistivity of 1.times.10.sup.10 to 1.times.10.sup.14 ohm/square.Type: GrantFiled: August 8, 1996Date of Patent: December 15, 1998Assignee: Teijin LimitedInventors: Nobuaki Kido, Shunichi Matsumura, Takashi Ito
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Patent number: 5814705Abstract: The present invention provides a composition that softens at a predetermined temperature, preferably between about 20.degree. C. and 90.degree. C., and more preferably between about 20.degree. C. and about 62.degree. C., comprising at least one block copolymer having at least two thermal transition temperatures. The composition is characterized by at least two thermal transition temperatures, one of which is a predetermined lower transition temperature, preferably between about 20.degree. C. to 90.degree. C., and more preferably between about 20.degree. C. to about 62.degree. C., and one of which is an upper transition temperature. The present invention also provides a method of making the composition, a method of making biomedical materials and articles, and toys and toy components, with shape-memory properties from the composition, and biomedical materials and articles, and toys and toy components, with shape-memory properties made from the composition.Type: GrantFiled: June 7, 1995Date of Patent: September 29, 1998Assignee: Thoratec Laboratories CorporationInventors: Robert S. Ward, Judy S. Riffle
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Patent number: 5789474Abstract: The specification discloses an additive composition for use in preparing adhesive formulations, particularly hot melt adhesive formulations based on A-B-A block copolymers which exhibit increased upper service temperatures. The additive composition comprises a preblend of of an A-block compatible reinforcing resin having a number average molecular weight ranging from about 2,000 to about 10,000 Daltons and a polydispersity index of less than about 4.0 and a B-block compatible resin. The A-block compatible reinforcing resin/B-block resin preblend enables introduction of more A-block reinforcing resin into the composition thereby increasing the overall upper service temperature of the adhesive formulation.Type: GrantFiled: September 17, 1996Date of Patent: August 4, 1998Assignee: Arizona Chemical CompanyInventors: Xinya Lu, Wayne K. Chu
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Patent number: 5756585Abstract: A process for manufacturing a star shaped block polymer of formula (PA--PB--PC).sub.n --N--(PD--PE).sub.m wherein PA, PB and PC are respectively vinylaromatic/methacrylic blocks, acrylic blocks and methacrylic blocks. PD is a polymer block selected from vinylaromatic and/or methacrylic monomer units, PE is an acrylic polymer block, n is 2 to 20 and m is 0 to 18 with the proviso that m+n is .ltoreq.20. The process proceeds by anionic polymerization in the presence of a monofunctional initiator of formula (II),(R).sub.p --Mwherein M is an alkali or alkaline earth metal, p is 1 or 2 and R is a straight or branched alkyl radical having 2 to 6 carbon atoms or a C.sub.1 to C.sub.6 substituted alkyl radical.Type: GrantFiled: February 3, 1995Date of Patent: May 26, 1998Assignee: AtochemInventors: Philippe Teyssie, Roger Fayt, Sunil K. Varshney, Christian Jacobs
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Patent number: 5750621Abstract: Multiphase polymer blends containa) a polymer (A),b) an A--B block copolymer (B) composed of a block A and a resilient block B andc) a B--C block copolymer (C) composed of a resilient block B and a block Cd) and at least one further polymer (D) which differs from (A),(B) and (C) and is incompatible with the polymer (A),wherein the blocks A, B and C are different from one another, the polymer (A) is compatible with the block A and incompatible with the block C, the polymer (D) is compatible with the block C and incompatible with the block A, the resilient block B has a glass transition temperature below +20.degree. C. and the blocks A, B and C are incompatible with one another.Type: GrantFiled: November 13, 1996Date of Patent: May 12, 1998Assignee: BASF AktiengesellschaftInventors: Axel Gottschalk, Raimund Stadler, Udo Krappe
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Patent number: 5721322Abstract: The specification discloses a method and additive for increasing the surface activity of non-polar polymeric materials, and a non-polar polymeric material exhibiting increased surface activity. The invention employs an additive of the formulaA-B-A.sup.1wherein each of the A and A.sup.1 blocks which may be the same or different has a number molecular weight in the range of from about 200 to about 1000 daltons and is selected from the group substituted and unsubstituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, aryl and alkylaryl units derived from one or more esters, organic acids, organic halides or organic acid halides, and units derived from alkyl or aryl isocyanates or ester-amides. The B-block is a polyepichlorohydrin unit derived from a polyepichlorohydrin polyol having at least two terminal hydroxyl groups and having an average molecular weight in the range of from about 400 to about 4000 daltons.Type: GrantFiled: January 24, 1997Date of Patent: February 24, 1998Assignee: Arizona Chemical CompanyInventors: Xinya Lu, Eric S. Gardiner
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Patent number: 5711940Abstract: The invention relates to a process for the preparation of a stable microdispersion of particles comprised of acrylic polymers in an organic solvent used as reaction medium in the presence of a stabilizing agent comprised of a block copolymer, characterized in that said acrylic polymer is obtained by radical polymerization of at least one acrylic monomer in the presence of a block copolymer based on polymethyl methacrylate (PMMA) and polytert-butyl acrylate (PtBuA). It also relates to microdispersions which may be obtained by said process as well as to microgels produced from said microdispersions and compositions, particularly cosmetic compositions such as nail varnish.Type: GrantFiled: June 12, 1996Date of Patent: January 27, 1998Assignee: LVMH RechercheInventors: Annie Kuentz, Henri-Gerard Riess, Alain Meybeck, Jean-Fran.cedilla.ois Tranchant
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Patent number: 5710219Abstract: The invention relates to melt-miscible polyolefin blends, and a process for preparing the melt-miscible blends, of two or more polyolefins. Matching, within defined limits, the segment length of a modifying polyolefin with the segment length of a primary polyolefin, such as polypropylene or an ethylene/alpha-olefin copolymer, provides blends of the "matched" components which blends were heretofore unknown to be melt-miscible. A broad range of polyolefin blend compositions, and of polyolefin blends containing other polymers made compatible or dispersible with the polyolefin blend compositions, are defined, all of the blend compositions having at least one melt-miscible polyolefin phase.Type: GrantFiled: September 23, 1994Date of Patent: January 20, 1998Assignee: Regents of the University of MinnesotaInventors: Frank S. Bates, Jeffrey H. Rosedale, Mark F. Schulz, Kristoffer Almdal
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Patent number: 5670564Abstract: Rigid-rod macromonomers, and methods for preparing such macromonomers, having a polyaromatic backbone, solubilizing side groups, and reactive end groups are provided. The macromonomers are chemically incorporated into polymer systems to provide stronger, stiffened polymers.Type: GrantFiled: June 1, 1995Date of Patent: September 23, 1997Assignee: Maxdem IncorporatedInventors: Robert R. Gagne, Matthew Louis Marrocco, III, Mark Steven Trimmer, Neil H. Hendricks
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Patent number: 5643996Abstract: A composition of inorganic powders comprises inorganic powder, dispersant and binder. The dispersant and/or binder used is a block copolymer of the units methacrylic acid and alkyl methacrylate in which the alkyl radical can comprise from 1 to 8 carbon atoms. The individual blocks of alkyl methacrylate possess an average molecular weight of at least 4000 and the total block copolymer has an average molecular weight of up to 150,000, in each case expressed as number average (M.sub.n).Type: GrantFiled: March 18, 1996Date of Patent: July 1, 1997Assignee: Hoechst AktiengesellschaftInventors: Jurgen Rudolph, Wolfgang Meyer, Gerhard Wegner, Friedrich Hessel, Katharina Seitz, Andreas Roosen
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Patent number: 5643991Abstract: This invention relates to a blend comprising:(a) one or more substantially amorphous copolyester resins having a degree of crystallinity of less than 20 percent;(b) from about 5 to about 25 weight percent carbon black; and(c) from about 7 to about 30 weight percent of an impact modifier,wherein the total of the weight percentages of (a), (b), and (c) equal 100 percent.This invention is advantageous in that it provides the advantages of good electroconductivity, lack of brittleness, ability to thermoform into desired shapes, good impact strength, good sealing characteristics and acceptable environmental image.Type: GrantFiled: May 12, 1995Date of Patent: July 1, 1997Assignee: Eastman Chemical CompanyInventors: Candace Michele Stipe, Scott Arnold Hanson, Richard Leon McConnell
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Patent number: 5585221Abstract: An active energy ray-curing resin composition comprises a graft copolymerized polymer and at least one of a monomer having an ethylenically unsaturated bond and a partially esterified epoxy resin.Type: GrantFiled: March 2, 1994Date of Patent: December 17, 1996Assignee: Canon Kabushiki KaishaInventors: Hiromichi Noguchi, Tadayoshi Inamoto, Megumi Munakata
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Patent number: 5567769Abstract: Homogeneous polymer blends are prepared from otherwise thermodynamically immiscible polymers, especially including block copolymers. Thus, polymers such as polystyrene/poly(methyl methacrylate) block copolymer or polystyrene/poly(1,2-butadiene) block copolymer are dissolved under pressure in supercritical fluid solvents such as chlorodifluoromethane and n-butane, respectively, and expanded through a fine nozzle. As the SCF solvent evaporates, the polymer deposits as a substantially homogeneous material.Type: GrantFiled: January 30, 1995Date of Patent: October 22, 1996Assignees: The Procter & Gamble Company, The Univ. of DelawareInventors: Annette D. Shine, Steven D. Smith, Isao Noda
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Patent number: 5565520Abstract: Polyolefins, polyolefin blends and elastomer-modified polyolefins containing additives to increase the surface polarity are prepared. They contain AB block copolymers as additives. A method for preparation of polyolefins, polyolefin blends and elastomer-modified polyolefins with a polar surface is defined as well as the method of preparing the polyolefins articles.Type: GrantFiled: June 1, 1995Date of Patent: October 15, 1996Assignee: TH. Goldschmidt AG.Inventors: Jurgen Fock, Gunter Hahn, Arno Knebelkamp
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Patent number: 5543266Abstract: An active energy ray-curing resin composition comprises (i) a graft copolymerized polymer, (iii) an epoxy resin comprising at least one compound having one or more epoxy groups in the molecule and (iv) a polymerization initiator capable of generating a Lewis acid by irradiation of an active energy ray.Type: GrantFiled: March 13, 1995Date of Patent: August 6, 1996Assignee: Canon Kabushiki KaishaInventors: Hiromichi Noguchi, Tadayoshi Inamoto, Megumi Munakata
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Patent number: 5540989Abstract: The invention relates to a recycable, heat-sealable plastic film for hermetically sealing plastic containers, comprising at least two layers which mutually adhere, (i) a support layer comprised of an impact resistant polystyrene resin and (ii) a sealing layer consisting essentially of: a) 20-100 weight % of a copolymer P consisting essentially of:(p1) 20-90 weight % methyl methacrylate and/or ethyl methacrylate;(p2) 10-80 weight % of at least one monomer of formula I ##STR1## where R.sub.1 represents an C.sub.3-24 alkyl group; and (p3) 0-10 weight %, preferably 1-8 weight %, of a monomer which is copolymerizable with and different from the monomers (p1) and (p2); and(b) 0-80 weight % of a block copolymer containing styrene blocks.Type: GrantFiled: February 14, 1995Date of Patent: July 30, 1996Assignee: Roehm GmbH Chemische FabrikInventors: Jurgen Maul, Werner Siol, Ulrich Terbrack
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Patent number: 5506307Abstract: Polymer melt blends of a homopolymer of propylene or a copolymer of propylene with up to 40 weight percent of another monoolefin, with a homopolymer of one or more of a C.sub.10 to C.sub.30 alkyl (meth)acrylate or a copolymer containing at least 70 weight percent of the one or more C.sub.10 to C.sub.30 ester of an alkyl (meth)acrylate with up to 30 weight percent of one or more of a C.sub.1 to C.sub.9 alkyl (meth)acrylate, the homopolymer or copolymer having a weight-average molecular weight of at least 670,000, exhibit a relative characteristic time, as herein described, at least five (5) times that for the unmodified homo- or copolymer of polypropylene, and a melt strength ratio (as judged by relative sag resistance) at least 5 times that of the unmodified homo- or copolymer of polypropylene. Such blends are useful in thermoforming operations wherein sheet is thermoformed into cartons, containers, appliance housings, and the like.Type: GrantFiled: April 25, 1995Date of Patent: April 9, 1996Assignee: Rohm and Haas CompanyInventor: Nazir A. Memon
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Patent number: 5500476Abstract: A polymer mixture on the basis of a polyalkylene phthalate ester, a copolyether ester and an agent to improve the impact to which an agent to improve the bonding of lacquer systems on an aqueous base has been added. The polymer mixture according to the invention comprises a polyalkylene glycol polymer or a polyalkylene glycol copolymer as an agent to improve the lacquer bonding.Type: GrantFiled: November 18, 1994Date of Patent: March 19, 1996Assignee: General Electric CompanyInventors: Robertus E. de Jong, Jacobus J. C. van der Kort
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Patent number: 5491192Abstract: A non-aqueous dispersion for modifying alkyd-containing coating formulations and a method for manufacturing the non-aqueous dispersion are provided. The non-aqueous dispersion contains from about 10 to about 60 parts by weight of a low molecular weight solution polymer, having a selected glass transition temperature greater than about -10.degree. C., and from about 90 to about 40 parts by weight of a polymer which is insoluble in the non-aqueous medium, and where the soluble polymer is attached to or adsorbed onto the insoluble polymer particles. The non-aqueous dispersion is preferably prepared by dispersion polymerization to form the insoluble polymer in a non-aqueous medium in the presence of the soluble polymer.Type: GrantFiled: August 28, 1991Date of Patent: February 13, 1996Assignee: Rohm and Haas CompanyInventors: Frederick H. Walker, Chao-Jen Chung, Andrew Mercurio
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Patent number: 5478886Abstract: Disclosed herein are block copolymers in which one the repeat units in one type of block is derived from (meth)acrylate esters, and repeat units in a second type of block are derived from .alpha.-fluoroacrylate esters. Also described is a process for making these block copolymers by Group Transfer Polymerization. The block copolymers are useful as for stabilizing emulsions and suspensions and for modifying the surface properties of objects.Type: GrantFiled: February 1, 1995Date of Patent: December 26, 1995Assignee: E. I. Du Pont de Nemours and CompanyInventor: Young H. Kim
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Patent number: 5476752Abstract: An active energy ray-curing resin composition comprises:(i) a linear polymer having a glass transition temperature of 50.degree. C. or higher and a weight average molecular weight of about 3.0.times.10.sup.4 or higher;(ii) a monomer having an ethylenically unsaturated bond;(iii) an epoxy resin comprising at least one compound having one or more epoxy groups in the molecule; and(iv) a polymerization initiator capable of generating a Lewis acid by irradiation with an active energy ray.Type: GrantFiled: April 3, 1995Date of Patent: December 19, 1995Assignee: Canon Kabushiki KaishaInventors: Hiromichi Noguchi, Tadayoshi Inamoto, Megumi Munakata
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Patent number: 5428114Abstract: An epoxidized diene star polymer having greater than 4 arms and comprising from 0.05 to 5 Meq of di-, tri- and tetra-substituted olefinic epoxides and the molecular weights of the arms are from 1,500 to 15,000.Type: GrantFiled: May 3, 1994Date of Patent: June 27, 1995Assignee: Shell Oil CompanyInventors: James R. Erickson, Steven H. Dillman, Dale L. Handlin, Jr., Carl L. Willis, Robert J. Sutherland
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Patent number: 5413660Abstract: Improved adhesion to a polyolefin, especially polypropylene, of substrates of acrylic-based or other protective polymers, in the form of a plastic film, sheet, or coating or a latex or solvent-based paint, ink, or coating is achieved by use of an intermediate layer, laminate, or veneer of a blend of segmented copolymer of a polyolefin and a poly(methacrylate) which is blended with a core/shell copolymer having a crosslinked rubber core.Type: GrantFiled: October 26, 1993Date of Patent: May 9, 1995Assignee: Rohm and Haas CompanyInventors: Noel G. Harvey, Theodore D. Goldman, Carl M. Hesler
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Patent number: 5412027Abstract: Homogeneous polymer blends are prepared from otherwise thermodynamically immiscible polymers, especially including block copolymers. Thus, polymers such as polystyrene/poly(methyl methacrylate) block copolymer or polystyrene/poly(1,2-butadiene) block copolymer are dissolved under pressure in supercritical fluid solvents such as chlorodifluoromethane and n-butane, respectively, and expanded through a fine nozzle. As the SCF solvent evaporates, the polymer deposits as a substantially homogeneous material.Type: GrantFiled: November 19, 1993Date of Patent: May 2, 1995Assignees: The Procter & Gamble Company, The Univ. of DelewareInventors: Annetta D. Shine, Steven D. Smith, Isao Noda
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Patent number: 5403658Abstract: An adhesive composition comprising a) a tackifying resin, b) a styrene-isoprene-styrene block copolymer or a styrene-isoprene block copolymer with styrene blocks as the end blocks and having at least one internal block of an acrylic monomer, and c) a block copolymer of at least one vinyl aromatic hydrocarbon, at least one conjugated diolefin and at least one acrylic monomer, such as an alkyl methacrylate, which is on the end of the copolymer and is attached to a conjugated diolefin block.Type: GrantFiled: April 15, 1994Date of Patent: April 4, 1995Assignee: Shell Oil CompanyInventors: Jeffrey G. Southwick, David R. Hansen
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Patent number: 5401792Abstract: Sprayable hot-melt adhesive compositions are disclosed comprising (A) styrenic block copolymer, (B) tackifying resin, and (C) ethylene copolymer. Methods of preparing and using said compositions are also disclosed.Type: GrantFiled: November 10, 1993Date of Patent: March 28, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: Gaddam N. Babu, Dennis D. Hansen
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Patent number: 5399620Abstract: Linear, star or dendrimeric block copolymers are composed of from 10 to 90% by weight of at least one block of one or more acrylates of an alcohol of 1 to 8 carbon atoms and from 10 to 90% by weight of at least one block of one or more methacrylates of an alcohol of 1 to 8 carbon atoms, each block having a number average molecular weight of from 1,000 to 100,000 g/mol and the quotient M.sub.w /M.sub.n (weight average/number average) of each block being less than 2, and said block copolymers may be blended with styrene copolymers or acrylate copolymers and, if required, acrylate rubbers.Type: GrantFiled: September 16, 1993Date of Patent: March 21, 1995Assignee: BASF AktiengesellschaftInventors: Norbert Niessner, Friedrich Seitz
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Patent number: 5395884Abstract: A novel process for coupling living polymers containing terminal (meth)acrylic units, which enables an increase in molecular weight and/or a defined multi-sequencing and/or a star structure with a defined number of branches, is disclosed. The disclosed process comprises the steps of: (i) anionic polymerization using an initiator system consisting of a bi-functional initiator and a ligand to obtain a living polymer containing living terminal (meth)acrylics units; (ii) reacting it with an aldehyde compound of formula R--(CHO).sub.r in which r>2; and (iii) recovering the final polycondensate by means known per se.Type: GrantFiled: April 28, 1994Date of Patent: March 7, 1995Assignee: Elf Atochem S.A.Inventor: Yves Gnanou
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Patent number: 5384362Abstract: The invention relates to vinyl sulfonated and non-sulfonated hydroxy functional polyurethane copolymers prepared from macromonomer diols and their use in magnetic recording media. The sulfonated hydroxy functional copolymer comprises: a polyurethane backbone; at least one SO.sub.3 M group pendant from the polyurethane backbone, wherein the polyurethane backbone has an S0.sub.3 M equivalent weight of from about 2,000 to about 100,000, and wherein M is selected from the group consisting of H.sup.+, NR.sub.4.sup.+ wherein R can be H.sup.+ or an alkyl group, Li.sup.+, Na.sup.+, K.sup.+, and mixtures thereof; at least two crosslinkable hydroxy groups pendant from the polyurethane backbone, wherein the polyurethane backbone has a hydroxy equivalent weight of from about 500 to about 50,000; and at least one vinyl polymeric segment B pendant from the polyurethane backbone.Type: GrantFiled: September 10, 1993Date of Patent: January 24, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: James G. Carlson, Jeffrey T. Anderson
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Patent number: 5384184Abstract: A polyester block copolymer having an inherent viscosity of at least 0.6, which comprises (A) 30 to 90% by weight of polyester segments comprising a benzenedicarboxylic acid as the main acid component and a diol having 5 to 12 carbon atoms between the hydroxyl groups as the main glycol component and (B) 70 to 10% by weight of polyester segments comprising an aromatic dicarboxylic acid as the main acid component and ethylene glycol, trimethylene glycol, tetramethylene glycol or 1,4-cyclohexane dimethanol as the main glycol component, wherein (i) when a polyester having an inherent viscosity of at least 0.6 is formed by polycondensation of the components constituting the polyester segments (A), the melting point of the obtained polyester is lower than 50.degree. C. or the obtained polyester is amorphous, and (ii) when a polyester having an inherent viscosity of at least 0.Type: GrantFiled: September 28, 1993Date of Patent: January 24, 1995Assignee: Teijin LimitedInventors: Noritsugu Saiki, Toshitsugu Matsuki, Masayuki Hayashi
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Patent number: 5364908Abstract: Resin compositions of improved dispersibility and mechanical properties are obtained by polymerizing a polymerizable compound (A), insitu in a melted thermoplastic resin (B), in the presence of a dispersant (C) reactive or compatible with at least one of the resin (B) and polymerizate of (A).Suitable dispersants include those represented by the general formula (1) or (2)R.sub.1 --L(X--M--X--L).sub.n X--M--R.sub.2 (1)R.sub.1 --L(X--M--X--L).sub.n --R.sub.2 (2)wherein R.sub.1 and R.sub.2 are groups, such as hydrocarbyl acyl, alkoxy, hydroxyl, mercapto, amino, epoxy, isocyanate, carboxylic, carboxylic anhydride, carboxylic halide and aldehyde groups; L and M are residues of a polymer having a number average molecular weight of about 500-about 3,000,000, the difference in solubility parameter between the residue L or M and the resin (B) or polymerizate of (A) being not more than 0.Type: GrantFiled: July 19, 1991Date of Patent: November 15, 1994Assignee: Sanyo Chemical Industries, Ltd.Inventors: Masafumi Oishi, Hiroshi Nishimoto, Takao Ando, Yukio Shibata, Toshiaki Okamoto, Katsura Gohda
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Patent number: 5360867Abstract: This invention relates to novel reactive amino or hydrazino peroxides (hereinafter generally referred to as "AHP's") and derivatives all having a Structure A: ##STR1## in which the definitions of P, R11, R22, X, Q and x, y and z are given in the Summary Of The Invention section, for example, 4,4-di-(t-butylperoxy)pentanohydrazide (I-1), and the use of these novel compounds in curing unsaturated polyester resins, in initiating polymerization of ethylenically unsaturated monomers, for modifying rheology, for crosslinking and curing olefin polymers and elastomers, for producing novel graft and block copolymers, and for producing novel polymers with covalently bound performance additive functions.Type: GrantFiled: December 17, 1993Date of Patent: November 1, 1994Assignee: ELF Atochem North America, Inc.Inventor: Jose Sanchez
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Patent number: 5338798Abstract: Polycarbonates (PC) can be blended over all compositions with block copolymers containing stereoregular polymethyl methacrylate (s-PMMA) in which at least 60% of the monomer units are in the syndiotactic configuration to form modified but transparent polycarbonates for a number of applications. Additional homopolymers corresponding to the blocks of the copolymer may also be added to even further modify the properties of the polycarbonate while still retaining transparency.Type: GrantFiled: September 30, 1992Date of Patent: August 16, 1994Assignees: Istituto Guido Donegani S.p.A., Enichem S.p.A.Inventor: Michael A. Drzewinski
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Patent number: 5318999Abstract: The present invention provides a novel dental composition and a method of making shaped dental articles therefrom via photoiniferter polymerization. The dental composition comprises acrylic photoiniferter block polymer, a monomer charge comprising free radically polymerizable acrylic monomer, and a filler and optionally includes pigments, sensitizers, medicaments, stabilizers, accelerators, etc. The dental composition is alternately exposed to a source of radiant energy and shaped in a desired manner in order to form a partially cured dental article. The partially cured dental article is then cured by a final exposure to the radiant energy source, providing a final cured article. The resultant reinforced acrylic copolymer system provides a shaped dental article which can be a denture base, a denture liner or a restorative.Type: GrantFiled: October 8, 1991Date of Patent: June 7, 1994Assignee: Minnesota Mining and Manufacturing CompanyInventors: Sumita B. Mitra, Mahfuza B. Ali
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Patent number: 5314962Abstract: An acrylate is polymerized by the photo-decomposition of ##STR1## to make a polymeric intermediate containing dithiocarbamate groups at both its ends, and a hard polymer-forming monomer is polymerized by the photo-decomposition of this dithiocarbamate group-containing polymeric intermediate to form blocks of a polymer of said hard polymer-forming monomer on both sides of said polymeric intermediate, thereby forming an ABA type block copolymer.Type: GrantFiled: June 29, 1993Date of Patent: May 24, 1994Assignee: Mitsubishi Petrochemical Company LimitedInventors: Takayuki Otsu, Shunichi Himori, Takashi Kiriyama
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Patent number: 5310804Abstract: The morphology of a polymer alloy displaying miscibility over some region of composition and temperature may be varied by thermodynamically altering the miscibility, such as raising the temperature for an LCST system, to phase separate the components then quenching the alloy below the glass transition temperature of the matrix phase. Such phase separated alloys have improved toughness.Type: GrantFiled: June 5, 1992Date of Patent: May 10, 1994Assignee: Novacor Chemicals (International) S.A.Inventors: Gregory Beaucage, Richard S. Stein
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Patent number: 5290822Abstract: An ultra low density polyolefin foam having a density of about 0.6 to about 1.5 pounds per cubic foot comprising a heat-plastified mixture comprising (1) a non-elastomeric olefin polymer resin selected from the group consisting of ethylene homopolymers, non-elastomeric copolymers of ethylene and a copolymerizable monomer, and propylene homopolymers; (2) an elastomer in an amount of about 3 to about 30 wt. parts per 100 wt. parts of said non-elastomeric olefin polymer resin; (3) polystyrene in an amount of about 1 to about 15 wt. parts per 100 wt. parts of said olefin polymer resin; (4) a stability control agent selected from the group consisting of partial esters of long chain fatty acids with polyols, higher alkyl amines, fatty acid amides, and olefinically unsaturated carboxylic acid copolymers, and (5) a hydrocarbon blowing agent having from 1 to 6 carbon atoms and a boiling point between -175.degree. C. and 50.degree. C.Type: GrantFiled: June 21, 1993Date of Patent: March 1, 1994Assignee: Astro-Valcour, Inc.Inventors: John E. Rogers, Ronnie D. Kisner
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Patent number: 5284916Abstract: Polycarbonates (PC) can be blended over all compositions with block copolymers containing polyaromatic(alkyl)methacrylates (PAAM) to form modified but transparent polycarbonates for a number of applications. Furthermore, additional homopolymers corresponding to those in the block copolymer may also be added to further modify the properties of the polycarbonate while still retaining transparency. Polycarbonate plus PAAM block copolymers containing from 1 to 99% by weight PC behave as transparent materials with the PC and the PAAM block forming a continuous, single phase material.Type: GrantFiled: September 30, 1992Date of Patent: February 8, 1994Assignees: Istituto Guido Donegani S.p.A., Enichem S.P.A.Inventor: Michael A. Drzewinski