Solid Block Or Block-type Copolymer Derived From Reactant Containing Carboxylic Acid Ester Group Patents (Class 525/94)
  • Patent number: 6162868
    Abstract: The present invention relates to a pressure-sensitive adhesive comprising:a mixture of a block copolymer (A) comprising polystyrene blocks and polybutadiene or polyisoprene blocks which are optionally hydrogenated and of a copolymer (B) of ethylene and of an alkyl (meth)acrylate,at least one tackifying resin and optionally a plasticizer,this adhesive being deposited while hot on a substrate.These products are useful for self-adhesive labels and tapes.
    Type: Grant
    Filed: September 24, 1998
    Date of Patent: December 19, 2000
    Assignee: Elf Atochem S.A.
    Inventors: Eric Radigon, Jean Lebez, Jean-Michel Pierrot
  • Patent number: 6143826
    Abstract: A polymer blend comprising:(A) an acrylic resin;(B) a block copolymer consisting essentially of a polymer block of a polymerized aromatic vinyl compound and/or a polymer block of a polymerized methacrylate monoester and a polyolefin polymer block; and(C) a polymer miscible with the acrylic resin (A) and immiscible with the block copolymer (B),wherein the absolute value (.vertline..eta..sub.AC -.eta..sub.B .vertline.) of the difference between the refractive index (.eta..sub.AC) of the blend of the acrylic resin (A) and the polymer (C) and the refractive index (.eta..sub.B) of the block copolymer (B) is 0.01 or less. This polymer block has excellent transparency, softness and other properties.
    Type: Grant
    Filed: September 24, 1997
    Date of Patent: November 7, 2000
    Assignee: Kuraray Co., Ltd.
    Inventors: Takashi Ohnaga, Katsunori Takamoto, Yukihiro Fujieda, Katsuei Takahashi, Kenichi Hamada
  • Patent number: 6090889
    Abstract: This invention discloses a rubbery polymer having improved properties which is comprised of repeat units which are derived from (a) butyl acrylate, or optionally a mixture of butyl acrylate and 2-ethylhexyl acrylate containing up to about 40 percent 2-ethylhexyl acrylate, (b) at least one member selected from the group consisting of methyl methacrylate, ethyl methacrylate, methyl acrylate and ethyl acrylate, (c) acrylonitrile, (d) styrene and (e) a crosslinking agent; wherein a chemical agent or a copolymer containing hydroxyl groups, ester groups, amine groups or carboxylic acid groups is grafted onto said rubbery polymer. The grafting can be done in the presence or in the absence of a carrying polymer matrix which should be inert with regard to the grafting reaction. Fatty alcohols and ethylene vinyl acetate are representative examples of agents which can be grafted onto the rubbery polymer.
    Type: Grant
    Filed: April 23, 1998
    Date of Patent: July 18, 2000
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Agnes Marie Madeleine Louise De Loor, Francois Jean-Marie Breton, Hung Dang Ngoc
  • Patent number: 6013726
    Abstract: A polystyrene-based resin composition containing a styrene-based resin with mainly syndiotactic configuration, a polyamide, and a rubber polymer as main components.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: January 11, 2000
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Akikazu Nakano, Takashi Sumitomo, Keisuke Funaki, Toshikazu Ijitsu, Michihiro Sawada, Masahiko Kuramoto, Masakazu Suzuki
  • Patent number: 5973075
    Abstract: Methods for preparing rigid-rod macromonomers having a polyaromatic backbone, solubilizing side groups, and reactive end groups are provided. Such methods include catalytic reductive coupling of substituted 1,4-dihaloaromatic compounds in the presence of an endcapping moiety.
    Type: Grant
    Filed: June 8, 1998
    Date of Patent: October 26, 1999
    Assignee: Maxdem Incorporation
    Inventors: Robert R. Gagne, Matthew Louis Marrocco, III, Mark Steven Trimmer, Neil H. Hendricks
  • Patent number: 5955546
    Abstract: The invention relates to melt-miscible polyolefin blends, and a process for preparing the melt-miscible blends, of two or more polyolefins. Matching, within defined limits, the segment length of a modifying polyolefin with the segment length of a primary polyolefin, such as polypropylene or an ethylene/alpha-olefin copolymer, provides blends of the "matched" components which blends were heretofore unknown to be melt-miscible. A broad range of polyolefin blend compositions, and of polyolefin blends containing other polymers made compatible or dispersible with the polyolefin blend compositions, are defined, all of the blend compositions having at least one melt-miscible polyolefin phase.
    Type: Grant
    Filed: January 16, 1998
    Date of Patent: September 21, 1999
    Assignee: Regents of the University of Minnesota
    Inventors: Frank S. Bates, Jeffrey H. Rosedale, Mark F. Schulz, Kristoffer Almdal
  • Patent number: 5927029
    Abstract: Seals for automotive body applications (such as, windows, hoods, trunks and doors) and building applications (such as, window glazing gaskets and weather strips) should be dimensional stable, provide low compression set and offer outstanding sealing characteristics over a broad temperature range. They must be capable of sealing out noise, wind and water, while providing long-term ultraviolet light resistance.
    Type: Grant
    Filed: October 14, 1998
    Date of Patent: July 27, 1999
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Hung Dang Ngoc
  • Patent number: 5910526
    Abstract: The specification discloses a polyphenylene oxide delivery system for use in preparing an A-B-A block copolymer adhesive formulation having an increased service temperature. The delivery system comprises a preblend of polyphenylene oxide (PPO) resin having a T.sub.g within the range of from about 150.degree. to about 210.degree. C. and a B-block compatible resin. The PPO/B-block resin preblend enables introduction of more PPO into the composition thereby increasing the service temperature of the adhesive formulation.
    Type: Grant
    Filed: September 14, 1998
    Date of Patent: June 8, 1999
    Assignee: Arizona Chemical Company
    Inventors: Wayne K. Chu, Erwin R. Ruckel
  • Patent number: 5900464
    Abstract: Polar polymers having the following formula:FG--(Q).sub.d --R.sub.n --Z--J--?A(R.sup.1 R.sup.2 R.sup.3)!.sub.x(I)wherein FG is H or a protected or non-protected functional group; Q is a polar hydrocarbyl group derived by incorporation of a polar compound selected from group consisting of esters, amides, and nitriles of acrylic and methacrylic acid, and mixtures thereof; d is an integer from 10 to 2000; R is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; n is an integer from 0 to 5; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; ?A(R.sup.1 R.sup.2 R.sup.3)!.sub.x is a protecting group, in which A is an element selected from Group IVa of the Periodic Table of Elements; R.sup.1, R.sup.2, and R.sup.
    Type: Grant
    Filed: July 10, 1996
    Date of Patent: May 4, 1999
    Assignee: FMC Corporation
    Inventors: Robert J. Letchford, James A. Schwindeman, Conrad W. Kamienski, Roderic P. Quirk
  • Patent number: 5869568
    Abstract: A one-part cold crosslinking emulsion composition containing, in an aqueous medium, a double-structure fine grain comprising the following Component (A) 1 and the following Component (B) 2 covering the same, wherein the following Component (C) is contained in Component (B) 2:(A) a copolymer comprising an epoxy group-containing monomer and an ethylenic unsaturated monomer;(B) a copolymer comprising an unsaturated carboxylic acid and an ethylenic unsaturated monomer; and(C) a low molecular weight monofunctional epoxy compound.
    Type: Grant
    Filed: November 12, 1997
    Date of Patent: February 9, 1999
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventor: Norihisa Maeda
  • Patent number: 5859113
    Abstract: A pigment dispersion useful for forming coating compositions containing dispersed pigment, a carrier liquid and an AB-block polymer dispersant (binder);the AB block polymer has a number average molecular weight of about 5,000-20,000 and contains 20-80% by weight of a polymeric A segment and correspondingly 80-20% by weight of a polymeric B segment; whereinthe polymeric A segment of the block polymer is of polymerized glycidyl (meth)acrylate monomers reacted with an acid from the group of aromatic carboxylic acids or aliphatic carboxylic acids; andthe B segment is of polymerized alkyl (meth)acrylate monomers having 1-12 carbon atoms in the alkyl group, hydroxy alkyl (meth)acrylate monomers having about 1-4 carbon atoms in the alkyl group; andwherein the weight ratio of pigment to binder in the dispersion is about 1/100-200/100.
    Type: Grant
    Filed: July 17, 1997
    Date of Patent: January 12, 1999
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Patrick F. McIntyre, James G. King, Harry J. Spinelli, Henry G. Jakubauskas
  • Patent number: 5859132
    Abstract: Seals for automotive body applications (such as, windows, hoods, trunks and doors) and building applications (such as, window glazing gaskets and weather strips) should be dimensional stable, provide low compression set and offer outstanding sealing characteristics over a broad temperature range. They must be capable of sealing out noise, wind and water, while providing long-term ultraviolet light resistance.
    Type: Grant
    Filed: April 1, 1997
    Date of Patent: January 12, 1999
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Hung Dang Ngoc
  • Patent number: 5849822
    Abstract: A thermoplastic resin composition having transparency and antistatic properties, comprising 100 parts by weight of a thermoplastic resin (A) having a refractive index of 1.52 to 1.61 and a haze of 40 or less, and 5 to 40 parts by weight of a polyetherester (B) which has a sulfonate group and a polyalkylene oxide group, and is substantially immiscible with the thermoplastic resin (A), the difference in refractive index between the thermoplastic resin (A) and the polyetherester (B) being 0.04 or less. The thermoplastic resin composition has a haze of 40% or less and a surface resistivity of 1.times.10.sup.10 to 1.times.10.sup.14 ohm/square.
    Type: Grant
    Filed: August 8, 1996
    Date of Patent: December 15, 1998
    Assignee: Teijin Limited
    Inventors: Nobuaki Kido, Shunichi Matsumura, Takashi Ito
  • Patent number: 5814705
    Abstract: The present invention provides a composition that softens at a predetermined temperature, preferably between about 20.degree. C. and 90.degree. C., and more preferably between about 20.degree. C. and about 62.degree. C., comprising at least one block copolymer having at least two thermal transition temperatures. The composition is characterized by at least two thermal transition temperatures, one of which is a predetermined lower transition temperature, preferably between about 20.degree. C. to 90.degree. C., and more preferably between about 20.degree. C. to about 62.degree. C., and one of which is an upper transition temperature. The present invention also provides a method of making the composition, a method of making biomedical materials and articles, and toys and toy components, with shape-memory properties from the composition, and biomedical materials and articles, and toys and toy components, with shape-memory properties made from the composition.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: September 29, 1998
    Assignee: Thoratec Laboratories Corporation
    Inventors: Robert S. Ward, Judy S. Riffle
  • Patent number: 5789474
    Abstract: The specification discloses an additive composition for use in preparing adhesive formulations, particularly hot melt adhesive formulations based on A-B-A block copolymers which exhibit increased upper service temperatures. The additive composition comprises a preblend of of an A-block compatible reinforcing resin having a number average molecular weight ranging from about 2,000 to about 10,000 Daltons and a polydispersity index of less than about 4.0 and a B-block compatible resin. The A-block compatible reinforcing resin/B-block resin preblend enables introduction of more A-block reinforcing resin into the composition thereby increasing the overall upper service temperature of the adhesive formulation.
    Type: Grant
    Filed: September 17, 1996
    Date of Patent: August 4, 1998
    Assignee: Arizona Chemical Company
    Inventors: Xinya Lu, Wayne K. Chu
  • Patent number: 5756585
    Abstract: A process for manufacturing a star shaped block polymer of formula (PA--PB--PC).sub.n --N--(PD--PE).sub.m wherein PA, PB and PC are respectively vinylaromatic/methacrylic blocks, acrylic blocks and methacrylic blocks. PD is a polymer block selected from vinylaromatic and/or methacrylic monomer units, PE is an acrylic polymer block, n is 2 to 20 and m is 0 to 18 with the proviso that m+n is .ltoreq.20. The process proceeds by anionic polymerization in the presence of a monofunctional initiator of formula (II),(R).sub.p --Mwherein M is an alkali or alkaline earth metal, p is 1 or 2 and R is a straight or branched alkyl radical having 2 to 6 carbon atoms or a C.sub.1 to C.sub.6 substituted alkyl radical.
    Type: Grant
    Filed: February 3, 1995
    Date of Patent: May 26, 1998
    Assignee: Atochem
    Inventors: Philippe Teyssie, Roger Fayt, Sunil K. Varshney, Christian Jacobs
  • Patent number: 5750621
    Abstract: Multiphase polymer blends containa) a polymer (A),b) an A--B block copolymer (B) composed of a block A and a resilient block B andc) a B--C block copolymer (C) composed of a resilient block B and a block Cd) and at least one further polymer (D) which differs from (A),(B) and (C) and is incompatible with the polymer (A),wherein the blocks A, B and C are different from one another, the polymer (A) is compatible with the block A and incompatible with the block C, the polymer (D) is compatible with the block C and incompatible with the block A, the resilient block B has a glass transition temperature below +20.degree. C. and the blocks A, B and C are incompatible with one another.
    Type: Grant
    Filed: November 13, 1996
    Date of Patent: May 12, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Axel Gottschalk, Raimund Stadler, Udo Krappe
  • Patent number: 5721322
    Abstract: The specification discloses a method and additive for increasing the surface activity of non-polar polymeric materials, and a non-polar polymeric material exhibiting increased surface activity. The invention employs an additive of the formulaA-B-A.sup.1wherein each of the A and A.sup.1 blocks which may be the same or different has a number molecular weight in the range of from about 200 to about 1000 daltons and is selected from the group substituted and unsubstituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, aryl and alkylaryl units derived from one or more esters, organic acids, organic halides or organic acid halides, and units derived from alkyl or aryl isocyanates or ester-amides. The B-block is a polyepichlorohydrin unit derived from a polyepichlorohydrin polyol having at least two terminal hydroxyl groups and having an average molecular weight in the range of from about 400 to about 4000 daltons.
    Type: Grant
    Filed: January 24, 1997
    Date of Patent: February 24, 1998
    Assignee: Arizona Chemical Company
    Inventors: Xinya Lu, Eric S. Gardiner
  • Patent number: 5711940
    Abstract: The invention relates to a process for the preparation of a stable microdispersion of particles comprised of acrylic polymers in an organic solvent used as reaction medium in the presence of a stabilizing agent comprised of a block copolymer, characterized in that said acrylic polymer is obtained by radical polymerization of at least one acrylic monomer in the presence of a block copolymer based on polymethyl methacrylate (PMMA) and polytert-butyl acrylate (PtBuA). It also relates to microdispersions which may be obtained by said process as well as to microgels produced from said microdispersions and compositions, particularly cosmetic compositions such as nail varnish.
    Type: Grant
    Filed: June 12, 1996
    Date of Patent: January 27, 1998
    Assignee: LVMH Recherche
    Inventors: Annie Kuentz, Henri-Gerard Riess, Alain Meybeck, Jean-Fran.cedilla.ois Tranchant
  • Patent number: 5710219
    Abstract: The invention relates to melt-miscible polyolefin blends, and a process for preparing the melt-miscible blends, of two or more polyolefins. Matching, within defined limits, the segment length of a modifying polyolefin with the segment length of a primary polyolefin, such as polypropylene or an ethylene/alpha-olefin copolymer, provides blends of the "matched" components which blends were heretofore unknown to be melt-miscible. A broad range of polyolefin blend compositions, and of polyolefin blends containing other polymers made compatible or dispersible with the polyolefin blend compositions, are defined, all of the blend compositions having at least one melt-miscible polyolefin phase.
    Type: Grant
    Filed: September 23, 1994
    Date of Patent: January 20, 1998
    Assignee: Regents of the University of Minnesota
    Inventors: Frank S. Bates, Jeffrey H. Rosedale, Mark F. Schulz, Kristoffer Almdal
  • Patent number: 5670564
    Abstract: Rigid-rod macromonomers, and methods for preparing such macromonomers, having a polyaromatic backbone, solubilizing side groups, and reactive end groups are provided. The macromonomers are chemically incorporated into polymer systems to provide stronger, stiffened polymers.
    Type: Grant
    Filed: June 1, 1995
    Date of Patent: September 23, 1997
    Assignee: Maxdem Incorporated
    Inventors: Robert R. Gagne, Matthew Louis Marrocco, III, Mark Steven Trimmer, Neil H. Hendricks
  • Patent number: 5643996
    Abstract: A composition of inorganic powders comprises inorganic powder, dispersant and binder. The dispersant and/or binder used is a block copolymer of the units methacrylic acid and alkyl methacrylate in which the alkyl radical can comprise from 1 to 8 carbon atoms. The individual blocks of alkyl methacrylate possess an average molecular weight of at least 4000 and the total block copolymer has an average molecular weight of up to 150,000, in each case expressed as number average (M.sub.n).
    Type: Grant
    Filed: March 18, 1996
    Date of Patent: July 1, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Jurgen Rudolph, Wolfgang Meyer, Gerhard Wegner, Friedrich Hessel, Katharina Seitz, Andreas Roosen
  • Patent number: 5643991
    Abstract: This invention relates to a blend comprising:(a) one or more substantially amorphous copolyester resins having a degree of crystallinity of less than 20 percent;(b) from about 5 to about 25 weight percent carbon black; and(c) from about 7 to about 30 weight percent of an impact modifier,wherein the total of the weight percentages of (a), (b), and (c) equal 100 percent.This invention is advantageous in that it provides the advantages of good electroconductivity, lack of brittleness, ability to thermoform into desired shapes, good impact strength, good sealing characteristics and acceptable environmental image.
    Type: Grant
    Filed: May 12, 1995
    Date of Patent: July 1, 1997
    Assignee: Eastman Chemical Company
    Inventors: Candace Michele Stipe, Scott Arnold Hanson, Richard Leon McConnell
  • Patent number: 5585221
    Abstract: An active energy ray-curing resin composition comprises a graft copolymerized polymer and at least one of a monomer having an ethylenically unsaturated bond and a partially esterified epoxy resin.
    Type: Grant
    Filed: March 2, 1994
    Date of Patent: December 17, 1996
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hiromichi Noguchi, Tadayoshi Inamoto, Megumi Munakata
  • Patent number: 5567769
    Abstract: Homogeneous polymer blends are prepared from otherwise thermodynamically immiscible polymers, especially including block copolymers. Thus, polymers such as polystyrene/poly(methyl methacrylate) block copolymer or polystyrene/poly(1,2-butadiene) block copolymer are dissolved under pressure in supercritical fluid solvents such as chlorodifluoromethane and n-butane, respectively, and expanded through a fine nozzle. As the SCF solvent evaporates, the polymer deposits as a substantially homogeneous material.
    Type: Grant
    Filed: January 30, 1995
    Date of Patent: October 22, 1996
    Assignees: The Procter & Gamble Company, The Univ. of Delaware
    Inventors: Annette D. Shine, Steven D. Smith, Isao Noda
  • Patent number: 5565520
    Abstract: Polyolefins, polyolefin blends and elastomer-modified polyolefins containing additives to increase the surface polarity are prepared. They contain AB block copolymers as additives. A method for preparation of polyolefins, polyolefin blends and elastomer-modified polyolefins with a polar surface is defined as well as the method of preparing the polyolefins articles.
    Type: Grant
    Filed: June 1, 1995
    Date of Patent: October 15, 1996
    Assignee: TH. Goldschmidt AG.
    Inventors: Jurgen Fock, Gunter Hahn, Arno Knebelkamp
  • Patent number: 5543266
    Abstract: An active energy ray-curing resin composition comprises (i) a graft copolymerized polymer, (iii) an epoxy resin comprising at least one compound having one or more epoxy groups in the molecule and (iv) a polymerization initiator capable of generating a Lewis acid by irradiation of an active energy ray.
    Type: Grant
    Filed: March 13, 1995
    Date of Patent: August 6, 1996
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hiromichi Noguchi, Tadayoshi Inamoto, Megumi Munakata
  • Patent number: 5540989
    Abstract: The invention relates to a recycable, heat-sealable plastic film for hermetically sealing plastic containers, comprising at least two layers which mutually adhere, (i) a support layer comprised of an impact resistant polystyrene resin and (ii) a sealing layer consisting essentially of: a) 20-100 weight % of a copolymer P consisting essentially of:(p1) 20-90 weight % methyl methacrylate and/or ethyl methacrylate;(p2) 10-80 weight % of at least one monomer of formula I ##STR1## where R.sub.1 represents an C.sub.3-24 alkyl group; and (p3) 0-10 weight %, preferably 1-8 weight %, of a monomer which is copolymerizable with and different from the monomers (p1) and (p2); and(b) 0-80 weight % of a block copolymer containing styrene blocks.
    Type: Grant
    Filed: February 14, 1995
    Date of Patent: July 30, 1996
    Assignee: Roehm GmbH Chemische Fabrik
    Inventors: Jurgen Maul, Werner Siol, Ulrich Terbrack
  • Patent number: 5506307
    Abstract: Polymer melt blends of a homopolymer of propylene or a copolymer of propylene with up to 40 weight percent of another monoolefin, with a homopolymer of one or more of a C.sub.10 to C.sub.30 alkyl (meth)acrylate or a copolymer containing at least 70 weight percent of the one or more C.sub.10 to C.sub.30 ester of an alkyl (meth)acrylate with up to 30 weight percent of one or more of a C.sub.1 to C.sub.9 alkyl (meth)acrylate, the homopolymer or copolymer having a weight-average molecular weight of at least 670,000, exhibit a relative characteristic time, as herein described, at least five (5) times that for the unmodified homo- or copolymer of polypropylene, and a melt strength ratio (as judged by relative sag resistance) at least 5 times that of the unmodified homo- or copolymer of polypropylene. Such blends are useful in thermoforming operations wherein sheet is thermoformed into cartons, containers, appliance housings, and the like.
    Type: Grant
    Filed: April 25, 1995
    Date of Patent: April 9, 1996
    Assignee: Rohm and Haas Company
    Inventor: Nazir A. Memon
  • Patent number: 5500476
    Abstract: A polymer mixture on the basis of a polyalkylene phthalate ester, a copolyether ester and an agent to improve the impact to which an agent to improve the bonding of lacquer systems on an aqueous base has been added. The polymer mixture according to the invention comprises a polyalkylene glycol polymer or a polyalkylene glycol copolymer as an agent to improve the lacquer bonding.
    Type: Grant
    Filed: November 18, 1994
    Date of Patent: March 19, 1996
    Assignee: General Electric Company
    Inventors: Robertus E. de Jong, Jacobus J. C. van der Kort
  • Patent number: 5491192
    Abstract: A non-aqueous dispersion for modifying alkyd-containing coating formulations and a method for manufacturing the non-aqueous dispersion are provided. The non-aqueous dispersion contains from about 10 to about 60 parts by weight of a low molecular weight solution polymer, having a selected glass transition temperature greater than about -10.degree. C., and from about 90 to about 40 parts by weight of a polymer which is insoluble in the non-aqueous medium, and where the soluble polymer is attached to or adsorbed onto the insoluble polymer particles. The non-aqueous dispersion is preferably prepared by dispersion polymerization to form the insoluble polymer in a non-aqueous medium in the presence of the soluble polymer.
    Type: Grant
    Filed: August 28, 1991
    Date of Patent: February 13, 1996
    Assignee: Rohm and Haas Company
    Inventors: Frederick H. Walker, Chao-Jen Chung, Andrew Mercurio
  • Patent number: 5478886
    Abstract: Disclosed herein are block copolymers in which one the repeat units in one type of block is derived from (meth)acrylate esters, and repeat units in a second type of block are derived from .alpha.-fluoroacrylate esters. Also described is a process for making these block copolymers by Group Transfer Polymerization. The block copolymers are useful as for stabilizing emulsions and suspensions and for modifying the surface properties of objects.
    Type: Grant
    Filed: February 1, 1995
    Date of Patent: December 26, 1995
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Young H. Kim
  • Patent number: 5476752
    Abstract: An active energy ray-curing resin composition comprises:(i) a linear polymer having a glass transition temperature of 50.degree. C. or higher and a weight average molecular weight of about 3.0.times.10.sup.4 or higher;(ii) a monomer having an ethylenically unsaturated bond;(iii) an epoxy resin comprising at least one compound having one or more epoxy groups in the molecule; and(iv) a polymerization initiator capable of generating a Lewis acid by irradiation with an active energy ray.
    Type: Grant
    Filed: April 3, 1995
    Date of Patent: December 19, 1995
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hiromichi Noguchi, Tadayoshi Inamoto, Megumi Munakata
  • Patent number: 5428114
    Abstract: An epoxidized diene star polymer having greater than 4 arms and comprising from 0.05 to 5 Meq of di-, tri- and tetra-substituted olefinic epoxides and the molecular weights of the arms are from 1,500 to 15,000.
    Type: Grant
    Filed: May 3, 1994
    Date of Patent: June 27, 1995
    Assignee: Shell Oil Company
    Inventors: James R. Erickson, Steven H. Dillman, Dale L. Handlin, Jr., Carl L. Willis, Robert J. Sutherland
  • Patent number: 5413660
    Abstract: Improved adhesion to a polyolefin, especially polypropylene, of substrates of acrylic-based or other protective polymers, in the form of a plastic film, sheet, or coating or a latex or solvent-based paint, ink, or coating is achieved by use of an intermediate layer, laminate, or veneer of a blend of segmented copolymer of a polyolefin and a poly(methacrylate) which is blended with a core/shell copolymer having a crosslinked rubber core.
    Type: Grant
    Filed: October 26, 1993
    Date of Patent: May 9, 1995
    Assignee: Rohm and Haas Company
    Inventors: Noel G. Harvey, Theodore D. Goldman, Carl M. Hesler
  • Patent number: 5412027
    Abstract: Homogeneous polymer blends are prepared from otherwise thermodynamically immiscible polymers, especially including block copolymers. Thus, polymers such as polystyrene/poly(methyl methacrylate) block copolymer or polystyrene/poly(1,2-butadiene) block copolymer are dissolved under pressure in supercritical fluid solvents such as chlorodifluoromethane and n-butane, respectively, and expanded through a fine nozzle. As the SCF solvent evaporates, the polymer deposits as a substantially homogeneous material.
    Type: Grant
    Filed: November 19, 1993
    Date of Patent: May 2, 1995
    Assignees: The Procter & Gamble Company, The Univ. of Deleware
    Inventors: Annetta D. Shine, Steven D. Smith, Isao Noda
  • Patent number: 5403658
    Abstract: An adhesive composition comprising a) a tackifying resin, b) a styrene-isoprene-styrene block copolymer or a styrene-isoprene block copolymer with styrene blocks as the end blocks and having at least one internal block of an acrylic monomer, and c) a block copolymer of at least one vinyl aromatic hydrocarbon, at least one conjugated diolefin and at least one acrylic monomer, such as an alkyl methacrylate, which is on the end of the copolymer and is attached to a conjugated diolefin block.
    Type: Grant
    Filed: April 15, 1994
    Date of Patent: April 4, 1995
    Assignee: Shell Oil Company
    Inventors: Jeffrey G. Southwick, David R. Hansen
  • Patent number: 5401792
    Abstract: Sprayable hot-melt adhesive compositions are disclosed comprising (A) styrenic block copolymer, (B) tackifying resin, and (C) ethylene copolymer. Methods of preparing and using said compositions are also disclosed.
    Type: Grant
    Filed: November 10, 1993
    Date of Patent: March 28, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Gaddam N. Babu, Dennis D. Hansen
  • Patent number: 5399620
    Abstract: Linear, star or dendrimeric block copolymers are composed of from 10 to 90% by weight of at least one block of one or more acrylates of an alcohol of 1 to 8 carbon atoms and from 10 to 90% by weight of at least one block of one or more methacrylates of an alcohol of 1 to 8 carbon atoms, each block having a number average molecular weight of from 1,000 to 100,000 g/mol and the quotient M.sub.w /M.sub.n (weight average/number average) of each block being less than 2, and said block copolymers may be blended with styrene copolymers or acrylate copolymers and, if required, acrylate rubbers.
    Type: Grant
    Filed: September 16, 1993
    Date of Patent: March 21, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Norbert Niessner, Friedrich Seitz
  • Patent number: 5395884
    Abstract: A novel process for coupling living polymers containing terminal (meth)acrylic units, which enables an increase in molecular weight and/or a defined multi-sequencing and/or a star structure with a defined number of branches, is disclosed. The disclosed process comprises the steps of: (i) anionic polymerization using an initiator system consisting of a bi-functional initiator and a ligand to obtain a living polymer containing living terminal (meth)acrylics units; (ii) reacting it with an aldehyde compound of formula R--(CHO).sub.r in which r>2; and (iii) recovering the final polycondensate by means known per se.
    Type: Grant
    Filed: April 28, 1994
    Date of Patent: March 7, 1995
    Assignee: Elf Atochem S.A.
    Inventor: Yves Gnanou
  • Patent number: 5384362
    Abstract: The invention relates to vinyl sulfonated and non-sulfonated hydroxy functional polyurethane copolymers prepared from macromonomer diols and their use in magnetic recording media. The sulfonated hydroxy functional copolymer comprises: a polyurethane backbone; at least one SO.sub.3 M group pendant from the polyurethane backbone, wherein the polyurethane backbone has an S0.sub.3 M equivalent weight of from about 2,000 to about 100,000, and wherein M is selected from the group consisting of H.sup.+, NR.sub.4.sup.+ wherein R can be H.sup.+ or an alkyl group, Li.sup.+, Na.sup.+, K.sup.+, and mixtures thereof; at least two crosslinkable hydroxy groups pendant from the polyurethane backbone, wherein the polyurethane backbone has a hydroxy equivalent weight of from about 500 to about 50,000; and at least one vinyl polymeric segment B pendant from the polyurethane backbone.
    Type: Grant
    Filed: September 10, 1993
    Date of Patent: January 24, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: James G. Carlson, Jeffrey T. Anderson
  • Patent number: 5384184
    Abstract: A polyester block copolymer having an inherent viscosity of at least 0.6, which comprises (A) 30 to 90% by weight of polyester segments comprising a benzenedicarboxylic acid as the main acid component and a diol having 5 to 12 carbon atoms between the hydroxyl groups as the main glycol component and (B) 70 to 10% by weight of polyester segments comprising an aromatic dicarboxylic acid as the main acid component and ethylene glycol, trimethylene glycol, tetramethylene glycol or 1,4-cyclohexane dimethanol as the main glycol component, wherein (i) when a polyester having an inherent viscosity of at least 0.6 is formed by polycondensation of the components constituting the polyester segments (A), the melting point of the obtained polyester is lower than 50.degree. C. or the obtained polyester is amorphous, and (ii) when a polyester having an inherent viscosity of at least 0.
    Type: Grant
    Filed: September 28, 1993
    Date of Patent: January 24, 1995
    Assignee: Teijin Limited
    Inventors: Noritsugu Saiki, Toshitsugu Matsuki, Masayuki Hayashi
  • Patent number: 5364908
    Abstract: Resin compositions of improved dispersibility and mechanical properties are obtained by polymerizing a polymerizable compound (A), insitu in a melted thermoplastic resin (B), in the presence of a dispersant (C) reactive or compatible with at least one of the resin (B) and polymerizate of (A).Suitable dispersants include those represented by the general formula (1) or (2)R.sub.1 --L(X--M--X--L).sub.n X--M--R.sub.2 (1)R.sub.1 --L(X--M--X--L).sub.n --R.sub.2 (2)wherein R.sub.1 and R.sub.2 are groups, such as hydrocarbyl acyl, alkoxy, hydroxyl, mercapto, amino, epoxy, isocyanate, carboxylic, carboxylic anhydride, carboxylic halide and aldehyde groups; L and M are residues of a polymer having a number average molecular weight of about 500-about 3,000,000, the difference in solubility parameter between the residue L or M and the resin (B) or polymerizate of (A) being not more than 0.
    Type: Grant
    Filed: July 19, 1991
    Date of Patent: November 15, 1994
    Assignee: Sanyo Chemical Industries, Ltd.
    Inventors: Masafumi Oishi, Hiroshi Nishimoto, Takao Ando, Yukio Shibata, Toshiaki Okamoto, Katsura Gohda
  • Patent number: 5360867
    Abstract: This invention relates to novel reactive amino or hydrazino peroxides (hereinafter generally referred to as "AHP's") and derivatives all having a Structure A: ##STR1## in which the definitions of P, R11, R22, X, Q and x, y and z are given in the Summary Of The Invention section, for example, 4,4-di-(t-butylperoxy)pentanohydrazide (I-1), and the use of these novel compounds in curing unsaturated polyester resins, in initiating polymerization of ethylenically unsaturated monomers, for modifying rheology, for crosslinking and curing olefin polymers and elastomers, for producing novel graft and block copolymers, and for producing novel polymers with covalently bound performance additive functions.
    Type: Grant
    Filed: December 17, 1993
    Date of Patent: November 1, 1994
    Assignee: ELF Atochem North America, Inc.
    Inventor: Jose Sanchez
  • Patent number: 5338798
    Abstract: Polycarbonates (PC) can be blended over all compositions with block copolymers containing stereoregular polymethyl methacrylate (s-PMMA) in which at least 60% of the monomer units are in the syndiotactic configuration to form modified but transparent polycarbonates for a number of applications. Additional homopolymers corresponding to the blocks of the copolymer may also be added to even further modify the properties of the polycarbonate while still retaining transparency.
    Type: Grant
    Filed: September 30, 1992
    Date of Patent: August 16, 1994
    Assignees: Istituto Guido Donegani S.p.A., Enichem S.p.A.
    Inventor: Michael A. Drzewinski
  • Patent number: 5318999
    Abstract: The present invention provides a novel dental composition and a method of making shaped dental articles therefrom via photoiniferter polymerization. The dental composition comprises acrylic photoiniferter block polymer, a monomer charge comprising free radically polymerizable acrylic monomer, and a filler and optionally includes pigments, sensitizers, medicaments, stabilizers, accelerators, etc. The dental composition is alternately exposed to a source of radiant energy and shaped in a desired manner in order to form a partially cured dental article. The partially cured dental article is then cured by a final exposure to the radiant energy source, providing a final cured article. The resultant reinforced acrylic copolymer system provides a shaped dental article which can be a denture base, a denture liner or a restorative.
    Type: Grant
    Filed: October 8, 1991
    Date of Patent: June 7, 1994
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Sumita B. Mitra, Mahfuza B. Ali
  • Patent number: 5314962
    Abstract: An acrylate is polymerized by the photo-decomposition of ##STR1## to make a polymeric intermediate containing dithiocarbamate groups at both its ends, and a hard polymer-forming monomer is polymerized by the photo-decomposition of this dithiocarbamate group-containing polymeric intermediate to form blocks of a polymer of said hard polymer-forming monomer on both sides of said polymeric intermediate, thereby forming an ABA type block copolymer.
    Type: Grant
    Filed: June 29, 1993
    Date of Patent: May 24, 1994
    Assignee: Mitsubishi Petrochemical Company Limited
    Inventors: Takayuki Otsu, Shunichi Himori, Takashi Kiriyama
  • Patent number: 5310804
    Abstract: The morphology of a polymer alloy displaying miscibility over some region of composition and temperature may be varied by thermodynamically altering the miscibility, such as raising the temperature for an LCST system, to phase separate the components then quenching the alloy below the glass transition temperature of the matrix phase. Such phase separated alloys have improved toughness.
    Type: Grant
    Filed: June 5, 1992
    Date of Patent: May 10, 1994
    Assignee: Novacor Chemicals (International) S.A.
    Inventors: Gregory Beaucage, Richard S. Stein
  • Patent number: 5290822
    Abstract: An ultra low density polyolefin foam having a density of about 0.6 to about 1.5 pounds per cubic foot comprising a heat-plastified mixture comprising (1) a non-elastomeric olefin polymer resin selected from the group consisting of ethylene homopolymers, non-elastomeric copolymers of ethylene and a copolymerizable monomer, and propylene homopolymers; (2) an elastomer in an amount of about 3 to about 30 wt. parts per 100 wt. parts of said non-elastomeric olefin polymer resin; (3) polystyrene in an amount of about 1 to about 15 wt. parts per 100 wt. parts of said olefin polymer resin; (4) a stability control agent selected from the group consisting of partial esters of long chain fatty acids with polyols, higher alkyl amines, fatty acid amides, and olefinically unsaturated carboxylic acid copolymers, and (5) a hydrocarbon blowing agent having from 1 to 6 carbon atoms and a boiling point between -175.degree. C. and 50.degree. C.
    Type: Grant
    Filed: June 21, 1993
    Date of Patent: March 1, 1994
    Assignee: Astro-Valcour, Inc.
    Inventors: John E. Rogers, Ronnie D. Kisner
  • Patent number: 5284916
    Abstract: Polycarbonates (PC) can be blended over all compositions with block copolymers containing polyaromatic(alkyl)methacrylates (PAAM) to form modified but transparent polycarbonates for a number of applications. Furthermore, additional homopolymers corresponding to those in the block copolymer may also be added to further modify the properties of the polycarbonate while still retaining transparency. Polycarbonate plus PAAM block copolymers containing from 1 to 99% by weight PC behave as transparent materials with the PC and the PAAM block forming a continuous, single phase material.
    Type: Grant
    Filed: September 30, 1992
    Date of Patent: February 8, 1994
    Assignees: Istituto Guido Donegani S.p.A., Enichem S.P.A.
    Inventor: Michael A. Drzewinski