Mixture Contains Solid Block Or Block-type Copolymer Derived From Ethylenically Unsaturated Hydrocarbon Reactants Only At Least One Of Which Contains At Least Four Carbon Atoms Patents (Class 525/95)
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Patent number: 11846371Abstract: A flexible conduit used for transportation of hydrocarbon fluids for off-shore and on-shore oil and gas applications includes an inner pressure sheath, at least one reinforcing layer at least partially disposed around the pressure sheath, an outer protective sheath at least partially disposed around the at least one reinforcing layer, and optionally a thermally insulating layer disposed between the at least one reinforcing layer and the outer protective sheath. At least one of the inner pressure sheath, outer protective sheath, and the thermally insulating layer is manufactured using a thermoplastic blend (TPB) composition. The TPB compositions disclosed herein are useful for the formation of at least one polymer layer of the thermoplastic umbilical hoses used for transportation of hydrocarbon fluids.Type: GrantFiled: September 10, 2019Date of Patent: December 19, 2023Assignee: ExxonMobil Chemical Patents Inc.Inventors: Antonios K. Doufas, Krishnan Anantha Narayana Iyer, Michael J. Goncy, Andrew A. Takacs, Wanli Wang
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Patent number: 10889712Abstract: A thermoplastic elastomeric network is taught. The thermoplastic elastomer network includes hyperbranched styrenic block copolymers and styrenic block copolymers physically crosslinked though aggregation. Additionally, the hyperbranched styrenic block copolymers of the thermoplastic elastomeric network are a plurality of styrenic block copolymers chemically crosslinked.Type: GrantFiled: September 18, 2018Date of Patent: January 12, 2021Assignee: THE UNIVERSITY OF AKRONInventors: Joseph P. Kennedy, Turgut Nugay, Nihan Nugay
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Patent number: 10329417Abstract: A sound damping article is formed from a thermoplastic elastomer compound that includes styrenic block copolymer, high softening point tackifier, plasticizer, and secondary polymer. The styrenic block copolymer has a Copolymer Tan Delta Peak Temperature and the thermoplastic elastomer compound has a Compound Tan Delta Peak Temperature. The Compound Tan Delta Peak Temperature is greater than the Copolymer Tan Delta Peak Temperature. The sound damping article exhibits useful vibration damping properties while also exhibiting beneficial sound and/or noise damping properties at or above room temperature.Type: GrantFiled: February 10, 2016Date of Patent: June 25, 2019Assignee: PolyOne CorporationInventor: Jiren Gu
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Patent number: 10329419Abstract: A thermoplastic elastomer compound includes styrenic block copolymer that is high vinyl styrene-(ethylene/butylene)-styrene block copolymer and high softening point tackifier. The high vinyl styrene-(ethylene/butylene)-styrene block copolymer has a Copolymer Tan Delta Peak Temperature and the thermoplastic elastomer compound has a Compound Tan Delta Peak Temperature. The Compound Tan Delta Peak Temperature is greater than the Copolymer Tan Delta Peak Temperature. The thermoplastic elastomer compound exhibits useful damping properties at or above room temperature while also advantageously possessing improved stability for processing and/or applications at high temperatures and upon exposure to weathering.Type: GrantFiled: February 10, 2016Date of Patent: June 25, 2019Assignee: PolyOne CorporationInventor: Jiren Gu
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Patent number: 10329418Abstract: An article is formed from a thermoplastic elastomer compound that includes styrenic block copolymer and high softening point tackifier. The styrenic block copolymer has a Copolymer Tan Delta Peak Temperature and the thermoplastic elastomer compound has a Compound Tan Delta Peak Temperature. The Compound Tan Delta Peak Temperature is greater than the Copolymer Tan Delta Peak Temperature. The article exhibits useful damping properties at or above room temperature while also exhibiting low compression set, which makes the article especially suitable for use as a seal or a gasket.Type: GrantFiled: February 10, 2016Date of Patent: June 25, 2019Assignee: PolyOne CorporationInventor: Jiren Gu
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Patent number: 10308791Abstract: The present invention relates to a thermally curable composition comprising: (a1) a solid rubber in an amount of 2.5% by mass or more, (a2) an olefinic double bond-containing polymer which is liquid or pasty at 22° C. in an amount of less than 5% by mass, (a3) a hydrocarbon resin in an amount of, in total with said component (a2), 5% by mass or more and 20% by mass or less, and (a4) a liquid polydiene in an amount of 15% by mass or more based on the total mass of the composition as a component (a); and at least one selected from the group consisting of the following (b1) to (b3): (b1) sulfur and one or more accelerator(s), (b2) peroxidic vulcanization system or disulfidic vulcanization system, and (b3) quinones, quinone dioximes or dinitrosobenzene, as a vulcanization system (b).Type: GrantFiled: June 8, 2017Date of Patent: June 4, 2019Assignee: Henkel AG & Co. KGaAInventors: Makoto Ohkubo, Shingo Tsuno, Takao Tsukimori
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Patent number: 10272721Abstract: A pneumatic tire including an inner liner made of a polymer sheet is provided, and the polymer sheet is made of a polymer composition. The polymer composition includes a polymer component of a styrene-isobutylene-styrene triblock copolymer by greater than or equal to 5 mass % and less than or equal to 80 mass %, and a rubber component of at least one kind selected from the group consisting of natural rubber, isoprene rubber, and isobutylene-isoprene rubber by greater than or equal to 20 mass % and less than or equal to 95 mass %. The polymer composition includes sulfur by greater than or equal to 0.1 mass parts and less than or equal to 5 mass parts with respect to the polymer component by 100 mass parts. The polymer sheet has a thickness T1 of 0.6 mm<T1?4.0 mm.Type: GrantFiled: April 23, 2013Date of Patent: April 30, 2019Assignee: SUMITOMO RUBBER INDUSTRIES, LTD.Inventors: Takeo Nakazono, Mutsuki Sugimoto
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Patent number: 10197208Abstract: Pipe with an outer diameter of from 90 to 630 mm and a minimum wall thickness of higher than 3.6 mm, having (a) an extrapolated time-to-failure (ASTM F2023 and ASTM F2769-10, performed on 16 mm SDR 7.4 pipe) of at least 50 years (for classification code CL5), (b) a time to failure (ISO 1167, performed on 32 mm SDR 11 pipe) of at least 10000 hours (110° C. under hoop stress of 2.6 MPa), and (c) a resistance to slow crack growth (ISO 13479 (80° C., 9.2 bar, performed on 110 mm SDR 11 pipe)) of at least 5000 hrs. The pipe contains a copolymer of ethylene and an a-olefin, and has (a) a density (D) in the range 933-948 kg/m3, (b) a melt index (MI2) in the range 0.15-2.0 g/10 min, and (c) a melt elastic modulus G? (G?=500 Pa) in the range 40 to 150 Pa.Type: GrantFiled: August 1, 2013Date of Patent: February 5, 2019Assignee: INEOS EUROPE AGInventors: Dominique Jan, Loic Poullin
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Patent number: 10066096Abstract: A method of producing a structure containing a phase-separated structure, which includes mixing a block copolymer which includes a hydrophobic polymer block and a hydrophilic polymer block and is incapable of forming a phase-separated structure, with a homopolymer compatible with the hydrophilic polymer block or a homopolymer compatible with the hydrophobic polymer block.Type: GrantFiled: March 21, 2016Date of Patent: September 4, 2018Assignee: TOKYO OHKA KOGYO CO., LTD.Inventors: Tsuyoshi Kurosawa, Tasuku Matsumiya, Masahito Yahagi, Hitoshi Yamano, Ken Miyagi, Daiju Shiono, Taku Hirayama, Katsumi Ohmori
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Patent number: 10005935Abstract: Films comprising a resin matrix, an entanglement polymer, and a latent curative, wherein the resin has a functionality of at least 2.0 and a viscosity of at least 0.1 Pascal-seconds, and the film is dimensionally stable at 25° C. The films are particularly useful for the bonding of elastomers to rigid substrates, such as rubber to metal, and contain no volatile organic compounds (VOCs), and are shelf stable for extended periods of time.Type: GrantFiled: April 29, 2016Date of Patent: June 26, 2018Assignee: LORD CorporationInventors: Timothy Fornes, Christopher Cox
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Patent number: 9550869Abstract: We disclose a monovinylarene-conjugated diene block copolymer containing a plurality of monovinylarene-conjugated diene mixed blocks, wherein each mixed block contains conjugated diene units and monovinylarene units in a weight ratio of about 0.05 to about 0.33. We also disclose a composition containing (a) from about 50 parts by weight to about 95 parts by weight of the monovinylarene-conjugated diene block copolymer and (b) from about 5 parts by weight to about 50 parts by weight of polystyrene; wherein the monovinylarene-conjugated diene block copolymer and the polystyrene total 100 parts by weight.Type: GrantFiled: April 15, 2015Date of Patent: January 24, 2017Assignee: Chevron Phillips Chemical Company LPInventors: John Mark Brown, Nathan E. Stacy, Carleton E. Stouffer, John D. Wilkey, Michael A. Smith
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Patent number: 9359537Abstract: It is an object to provide a block copolymer composition for a viscous adhesive, which will be a viscous adhesive composition excellent in balance of the adhesive properties such as tack strength and tackiness, having a low melt viscosity, and excellent solubility, coating properties, ejection stability, and surface skin quality. The block copolymer composition for a viscous adhesive having: a component (a) in an amount of 50 mass % or more and 90 mass % or less; and a component (b) in an amount of 10 mass % or more and 50 mass % or less; a content of the vinyl aromatic monomer unit being 25 to 50 mass %; a viscosity of the 15 mass % toluene solution being 10 to 40 mPa·s; and a number average molecular weight ratio of the component (b) to the component (a) being 2.0 to 4.0.Type: GrantFiled: July 18, 2013Date of Patent: June 7, 2016Assignees: Asahi Kasei Chemicals Corporation, Japan Elastomer Co., Ltd.Inventors: Shigeo Nakajima, Takahiro Hisasue, Kenji Ebara, Yukinori Nakamichi
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Patent number: 9040627Abstract: Provided is an artificial turf yarn having improved heat resistance, durability, softness and extensibility. The artificial turf yarn contains two components: an olefin block copolymer (OBC) and a linear low density polyethylene (LLDPE). The yarn includes from about 10 wt % to about 80 wt % of the OBC and from about 20 wt % to about 90 wt % of the LLDPE which produces an artificial turf yarn with improved softness and toughness while maintaining heat resistance.Type: GrantFiled: March 30, 2011Date of Patent: May 26, 2015Assignee: Dow Global Technologies LLCInventors: Jill M. Martin, Peter Sandkuehler
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Patent number: 9040628Abstract: We disclose a monovinylarene-conjugated diene block copolymer containing a plurality of monovinylarene-conjugated diene mixed blocks, wherein each mixed block contains conjugated diene units and monovinylarene units in a weight ratio of about 0.05 to about 0.33. We also disclose a composition containing (a) from about 50 parts by weight to about 95 parts by weight of the monovinylarene-conjugated diene block copolymer and (b) from about 5 parts by weight to about 50 parts by weight of polystyrene; wherein the monovinylarene-conjugated diene block copolymer and the polystyrene total 100 parts by weight.Type: GrantFiled: November 20, 2012Date of Patent: May 26, 2015Assignee: Chevron Phillips Chemical Company LPInventors: John Mark Brown, Michael A. Smith, Nathan E. Stacy, Carleton E. Stouffer, John D. Wilkey
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Publication number: 20150119817Abstract: A thermoplastic elastomer stopper that meets the desired material properties of a stopper for a syringe assembly is disclosed. The compression set of the thermoplastic elastomer stopper of the present disclosure is ?50% when measured at 25% compression for 22 hrs at 70 degree C. The hardness of the thermoplastic elastomer stopper of the present disclosure is 40-70 Shore A. The viscosity of a thermoplastic elastomer stopper of the present disclosure is ?70 Pa·s at 1,000 s?1 shear rate, ?12.0 Pa·s at 10,000 s?1 shear rate, and ?3.0 Pa·s at 50,000 s?1 shear rate when measured using a capillary rheometer at 205 degree C. (Die: Roundhole 20 mm length/1 mm diameter/180 degree inlet, Piston: d=15 mm, and melting time=7 min). The present non-lubricated stopper exhibits the required functional performance of a lubricated stopper.Type: ApplicationFiled: October 28, 2014Publication date: April 30, 2015Inventors: Shishir Prasad, Gheorghe Cojocariu, Sathya Kaliyamoorthy, Chad Smith, Ankur Kulshrestha, Richard G. Giddes, Gerald Bonczynski, Kweku Addae-Mensah
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Publication number: 20150050442Abstract: Polymer composition comprising a propylene copolymer and a styrenic based elastomer.Type: ApplicationFiled: March 25, 2013Publication date: February 19, 2015Inventors: Markus Gahleitner, Martina Sandholzer, Klaus Bernreitner
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Publication number: 20150045509Abstract: There are provided a hot-melt adhesive, which is excellent in solvent resistance and is excellent in adhesion to an adherend (specifically, a polyimide film) containing an electrolytic solution of a battery therein, and also can contribute to an improvement in performances of electric instruments; and an electric instrument produced by using such hot-melt adhesive. A hot-melt adhesive for electric instruments, comprising an olefin based modified polymer (A), the olefin based modified polymer (A) being a modified polymer having a functional group containing silicon, is excellent in resistance to an electrolytic solution of a battery (that is, electrolytic solution resistance or solvent resistance), and also exhibits improved adhesion of the hot-melt adhesive to an adherend (plastic film such as a polyimide film) containing the electrolytic solution therein.Type: ApplicationFiled: October 24, 2014Publication date: February 12, 2015Inventors: Itsuro Tomatsu, Kenji Matsuda, Ai Takamori
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Publication number: 20150037524Abstract: A sustainable thermoplastic composition made by forming a mixture of virgin polypropylene and post-industrial-recycled material (PIR). The PIR may include a thermoplastic, elastomeric-polymer and a spunbond component. The mixture is melt-blended in an extruder. Extruded materials made from the mixture demonstrate little variance in the results of the IZOD Impact Test of materials containing 30 to 70 percent PIR, and a material containing 100 percent virgin polypropylene. In addition, the extruded materials containing 30 to 70 percent PIR demonstrate a substantially constant strain at yield, that strain at yield being substantially equal to that demonstrated by a material containing 100 percent virgin polypropylene.Type: ApplicationFiled: December 23, 2013Publication date: February 5, 2015Applicant: Kimberly-Clark Worldwide, Inc.Inventors: Brent Merrik Thompson, James Hongxue Wang, Gregory James Wideman
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Patent number: 8946331Abstract: Disclosed is a polypropylene resin composition including: 100 parts by weight of (A) a propylene-based block copolymer including polymer components (I) and (II), wherein the polymer component (I) is a propylene polymer having an intrinsic viscosity [?]I of 0.1-5 dl/g, the polymer component (II) is a propylene polymer comprising propylene units and units of at least one comonomer selected from the group consisting of ethylene and ?-olefins having 4-12 carbon atoms and having an intrinsic viscosity [?]II of from 1-20 dl/g and the content of the polymer component (II) is 1-70% by weight; and 0.001-5 parts by weight of (B) a nucleating agent composed of particles having an average particle diameter, as measured by the laser diffraction method, of 0.01-3 mm wherein particles having particle diameters of not less than 10 mm account for less than 5% by weight of all the particles of the nucleating agent.Type: GrantFiled: January 5, 2006Date of Patent: February 3, 2015Assignee: Sumitomo Chemical Company, LimitedInventors: Yoshiaki Oobayashi, Tsuyoshi Watanabe
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Patent number: 8921484Abstract: Disclosed herein is a polymeric composition. The polymeric composition includes: (A) a propylene-based polymer; (B) an ethylene/a-olefin polymer; (C) a block composite comprising: i) a propylene-based crystalline polymer; ii) an ethylene/a-olefin polymer; and iii) a block copolymer comprising a propylene-based crystalline block and an ethylene/a-olefin block. The polymeric composition provides improved heat seals when formed into film, film layer, or flexible containers such as retort pouch.Type: GrantFiled: September 29, 2011Date of Patent: December 30, 2014Assignee: Dow Global Technologies LLCInventors: Wenbin Liang, Kim L. Walton, Gary R. Marchand
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Patent number: 8895645Abstract: A modified-asphalt composition prepared by introducing a diene end-capped block copolymer with a molten asphalt composition, where the block copolymer is defined by the formula ?-(D-V-d)x where each D is independently a polydiene block, each V is independently a vinyl aromatic block, each d is a polydiene end cap, ? is a coupling moiety, and x is an integer from 2 to 10.Type: GrantFiled: November 8, 2013Date of Patent: November 25, 2014Assignees: Firestone Polymers, LLC, Heritage Research GroupInventors: Christine Rademacher, Timothy Reece, Herb Wissel, Daniel Graves, Peter Boerner
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Patent number: 8865835Abstract: There is provided an encapsulant material for solar cells which facilitates production of a solar cell module and is excellent in flexibility, heat resistance, transparency, etc., and a solar cell module produced using the encapsulant material. The present invention relates to an encapsulant material for solar cells which includes a resin composition (C) containing an ethylene-?-olefin random copolymer (A) capable of satisfying the following condition (a) and an ethylene-?-olefin block copolymer (B) capable of satisfying the following condition (b): (a) a heat of crystal fusion is from 0 to 70 J/g as measured in differential scanning calorimetry at a heating rate of 10° C./min; and (b) a crystal fusion peak temperature is 100° C. or higher and a heat of crystal fusion is from 5 to 70 J/g as measured in differential scanning calorimetry at a heating rate of 10° C./min.Type: GrantFiled: July 16, 2010Date of Patent: October 21, 2014Assignee: Mitsubishi Plastics, Inc.Inventors: Kouichirou Taniguchi, Jun Nishioka, Ryota Yamamoto, Yo Miyashita
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Patent number: 8853326Abstract: An RF-weldable thermoplastic elastomer composition, including a thermoplastic elastomer of non-RF-weldable or poorly RF-weldable character, e.g., a styrenic copolymer/olefinic polymer blend thermoplastic elastomer, and polyol in an amount that is less than 1% by weight, based on weight of the thermoplastic elastomer, and is effective to enhance RF-weldability of the thermoplastic elastomer. The composition may also contain an antistatic ionomer, in an amount that is less than 15% by weight, based on weight of the thermoplastic elastomer. Films of such composition are usefully employed to form RF-welded film articles, such as blood bags, IV fluid bags, glucose bags, urine bags, stool bags, biological sample bags, pouches, covers, and liners.Type: GrantFiled: July 20, 2012Date of Patent: October 7, 2014Assignee: Polyzen Inc.Inventors: Tilak M. Shah, Kimberly Ogburn, Christopher D. Strom
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Publication number: 20140288228Abstract: The present invention relates to polypropylene compositions with a balance of high strength, good clarity, excellent stress whitening resistance, and excellent impact properties—especially at low temperatures—for use in demanding plastics applications. Blends consist of both homopolymer and random copolymer polypropylene fractions, as well as propylene-ethylene elastomers and styrenic based elastomers. The invention also covers molded articles made from these blends.Type: ApplicationFiled: March 18, 2014Publication date: September 25, 2014Applicant: Asahi Kasei Plastics North America, Inc.Inventors: Sameer G. MEHTA, Michael James BALOW, Vaibhav Vishnu APTE, Laura Therese Shereda
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Patent number: 8822598Abstract: Embodiments of the invention provide crystalline block composites and their use as compatibilizers.Type: GrantFiled: June 21, 2011Date of Patent: September 2, 2014Assignee: Dow Global Technologies LLCInventors: Colin Li Pi Shan, Edmund M. Carnahan, Gary R. Marchand, Kim L. Walton, Thomas Karjala, Jeffrey D. Weinhold
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Patent number: 8822597Abstract: A process for producing rubber modified polymers having an increased rubber phase volume, including feeding a vinyl aromatic monomer and an elastomer to a polymerization reactor to form a reaction mixture, polymerizing the reaction mixture, combining a copolymer to the polymerized reaction mixture to form a combined mixture, subjecting the combined mixture to further polymerization, and obtaining a rubber modified polymer product from the further polymerization.Type: GrantFiled: April 28, 2011Date of Patent: September 2, 2014Assignee: Fina Technology, Inc.Inventors: Carlos DeAnda, Graciela Morales, Jose M. Sosa, David Knoeppel
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Patent number: 8822599Abstract: Embodiments of the invention provide crystalline block composites and their use as compatibilizers. The crystalline block composites comprise i) a crystalline ethylene based polymer; ii) a crystalline alpha-olefin based polymer and iii) a block copolymer comprising a crystalline ethylene block and a crystalline alpha-olefin block.Type: GrantFiled: June 21, 2011Date of Patent: September 2, 2014Assignee: Dow Global Technologies LLCInventors: Colin Li Pi Shan, Kim L. Walton, Gary R. Marchand, Edmund M. Carnahan, Thomas Karjala
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Patent number: 8816006Abstract: Compositions suitable for film comprise at least one ethylene/?-olefin interpolymer, wherein the ethylene/?-olefin interpolymer may have, for example, a Mw/Mn from about 1.7 to about 3.5, at least one melting point, Tm, in degrees Celsius, and a density, d, in grams/cubic centimeter, wherein the numerical values of Tm and d correspond to the relationship: Tm>?2002.9+4538.5(d)?2422.2(d)2.Type: GrantFiled: March 15, 2006Date of Patent: August 26, 2014Assignee: Dow Global Technologies LLCInventors: David W. Fuchs, Pradeep Jain, Mehmet Demirors, Pak-Meng Cham, Yunwa W. Cheung
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Patent number: 8809417Abstract: The present invention relates to a pressure sensitive paste composition for skin application. The paste comprises 10-50% (w/w) based on the total paste formulation of a blend of polar polyethylene copolymer(s) and polar oil.Type: GrantFiled: December 18, 2009Date of Patent: August 19, 2014Assignee: Coloplast A/SInventor: Dorrit Diana Israelson
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Patent number: 8802774Abstract: Embodiments of the invention provide block composites comprising a soft copolymer, a hard polymer and a block copolymer having a soft segment and a hard segment, wherein the hard segment of the block copolymer is the same composition as the hard polymer in the block composite and the soft segment of the block copolymer is the same composition as the soft copolymer of the block composite and their use as impact modifiers.Type: GrantFiled: October 1, 2010Date of Patent: August 12, 2014Assignee: Dow Global Technologies LLCInventors: Edmund M. Carnahan, Colin LiPiShan, Kim L. Walton, Gary R. Marchand, Benjamin C. Poon, Phillip D. Hustad, Brian A. Jazdzewski, Didem Oner-Deliormanli
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Publication number: 20140213728Abstract: The present invention provides a hydrogenated block copolymer which has an excellent balance in a transparency, optical property, flexibility, mechanical property, moldability, heat resistance, gas barrier property, low moisture absorbency and non-adsorptive property of chemical. Also, the present invention has an object to provide a resin composition containing the hydrogenated block copolymer as a resin component, and a film and container containing the composition. The present invention relates to a hydrogenated block copolymer containing a Block A of a hydrogenated vinyl aromatic polymer and a Block B of a polymer containing isobutylene.Type: ApplicationFiled: March 31, 2014Publication date: July 31, 2014Applicant: MITSUBISHI CHEMICAL CORPORATIONInventors: Naoyuki KOSAKA, Toshihisa Ishihara, Kenjiro Takayanagi
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Patent number: 8785554Abstract: Embodiments of the invention provide crystalline block composites and their use as compatibilizers. The crystalline block composites comprise i) a crystalline ethylene based polymer; ii) a crystalline alpha-olefin based polymer and iii) a block copolymer comprising a crystalline ethylene block and a crystalline alpha-olefin block.Type: GrantFiled: June 21, 2011Date of Patent: July 22, 2014Assignee: Dow Global Technologies LLCInventors: Colin Li Pi Shan, Kim L. Walton, Gary R. Marchand, Edmund M. Carnahan, Eddy I. Garcia-Meitin, Thomas Karjala
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Patent number: 8760040Abstract: The present invention relates to one of energy conversion devices, actuator and a dielectric layer used in the actuator. The present invention provides a polymer blend composition capable of easily controlling the ability of converting electrical energy to mechanical energy, which is prepared by blending a piezoelectric polymer with a flexible elastomeric block copolymer showing an effective miscibility therewith, and a tunable actuator using the same.Type: GrantFiled: November 3, 2011Date of Patent: June 24, 2014Assignee: Korea Institute of Science and TechnologyInventors: Chong-Min Koo, Kyung-Youl Baek, Soon-Man Hong, Seung-Sang Hwang, Hee-La Kwak, Kyung-ho Min, Jin-Hong Lee, Kie-Yong Cho, Sang-Hee Park
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Patent number: 8734956Abstract: The present invention provides a polybutylene terephthalate resin composition which satisfies performances such as high durability in an environment of heating and cooling cycles and adhesion properties to an addition-reaction type silicone rubber. Specifically, provided is the polybutylene terephthalate resin composition, exhibiting excellent adhesion properties to the addition-reaction type silicone rubber, including: (A) 100 parts by weight of polybutylene terephthalate resin; (B) 5 to 30 parts by weight of a styrene-based thermoplastic elastomer containing 40% by weight or less of styrene component; and (C) 20 to 100 parts by weight of glass fiber.Type: GrantFiled: December 24, 2008Date of Patent: May 27, 2014Assignee: Wintech Polymer Ltd.Inventors: Kouichi Sakata, Hiroyuki Amano
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Patent number: 8722799Abstract: There is provided a thermoplastic elastomer composition having excellent flexibility, mechanical properties, scratch resistance, abrasion resistance, and low-temperature characteristics. A crosslinked thermoplastic elastomer composition comprising 5 to 70 parts by mass of (C) a hydrogenated product of a block copolymer having at least one conjugated diene monomer unit block and at least one vinyl aromatic monomer unit block, and 20 to 150 parts by mass of (D) an olefin-based resin, based on 100 parts by mass of the total of (A) an ethylene-?-olefin copolymer comprising an ethylene unit and an ?-olefin unit having 3 to 20 carbon atoms, and (B) a copolymer having at least one hydrogenated copolymer block mainly composed of a conjugated diene monomer unit and a vinyl aromatic monomer unit, wherein a mass ratio ((A)/(B)) of the (A) component and the (B) component is from 20/80 to 75/25.Type: GrantFiled: December 4, 2009Date of Patent: May 13, 2014Assignee: Asahi Kasei Chemicals CorporationInventors: Yutaka Eguchi, Shinichi Shibayama, Yoshifumi Araki
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Patent number: 8722800Abstract: The present invention provides a composition for a stretchable film, which achieves a high-level balance between a high elastic modulus and a small permanent elongation, which is excellent in adhesive force when laminated with a non-woven fabric or the like, and also has good formability.Type: GrantFiled: June 24, 2010Date of Patent: May 13, 2014Assignee: Zeon CorporationInventors: Ryouji Oda, Sadaharu Hashimoto
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Publication number: 20140127445Abstract: The present invention relates to molding and overmolding compositions for delicate components. More particularly the invention relates to compositions for low pressure molding and overmolding, making these compositions particularly well suited for electronic devices. The molding and overmolding composition is suitable for low pressure injection molding processes, particularly at 0.5 to 200 bars at 70° C. to 240° C.Type: ApplicationFiled: March 14, 2013Publication date: May 8, 2014Applicant: Henkel CorporationInventors: Cynthia L. Cain, Charles W. Paul, Maria Cristina Barbosa DeJesus
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Publication number: 20140070131Abstract: A composition for a refrigerator gasket is provided. The composition includes, as a polymer base, a blend of an olefin/?-olefin (OAO) copolymer having a melting point of at least 100° C. and a styrene block copolymer (SBC). The polymer base has a melt index (190° C., 5 kg) of 0.01 to 15 g/10 min.Type: ApplicationFiled: September 12, 2013Publication date: March 13, 2014Applicant: FINE CHEMICAL CO., LTD.Inventor: Sung Yull LEE
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Publication number: 20130330392Abstract: It is provided an implantable device including a polymer blend that contains a polymer formed of fluorinated monomers and hydrocarbon monomers and another biocompatible polymer.Type: ApplicationFiled: August 14, 2013Publication date: December 12, 2013Applicant: Abbott Cardiovascular Systems Inc.Inventor: Stephen D. Pacetti
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Patent number: 8592522Abstract: The object of the present invention is to provide an oxygen-absorbing resin composition having a high oxygen absorbability and capable of absorbing oxygen for a long period of time. The present invention provides an oxygen-absorbing resin composition comprising polyolefin resin (A) obtained by polymerizing an olefin having 2 to 8 carbon atoms, resin (B) which is other than resin (A) and which acts as a trigger for the oxidation of resin (A), and transition metal catalyst (C), wherein resin (B) is dispersed in the matrix of resin (A) so that the oxidation reaction of matrix resin (A) is caused and thus oxygen is absorbed when the oxygen-absorbing resin composition is brought into contact with oxygen. This oxygen absorbing resin composition has a high oxygen absorbability and is advantageous in cost because oxygen is absorbed in resin (A).Type: GrantFiled: February 23, 2005Date of Patent: November 26, 2013Assignee: Toyo Seikan Kaisha, Ltd.Inventors: Ikuo Komatsu, Hiroaki Goto, Shigenobu Murakamai, Takayuki Ishihara
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Patent number: 8592018Abstract: Provided are a tube which has good transparency, flexibility, and solvent adhesion, and also has excellent clamp resistance, anti-conglutination property, and kink resistance, and a medical device using the tube.Type: GrantFiled: March 9, 2010Date of Patent: November 26, 2013Assignee: Kuraray Co., Ltd.Inventors: Yosuke Uehara, Nobuhiro Moriguchi, Shigenao Kuwahara, Hidetaka Oonuma
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Patent number: 8586637Abstract: The present invention pertains to products and processes relating to compatible polymer blends comprising at least one sulfonated polymer and at least one non-sulfonated polymer. The sulfonated polymers may be produced using a number of sulfonating agents including a coordination complex of sulfur trioxide. The polymeric blended materials described herein are useful in a variety of applications, including as coatings for medical devices, protective clothing and fabric, laboratory equipment, vascular stents and shunts, absorbent materials and separation membranes, three-dimensional constructs, devices, and other uses.Type: GrantFiled: June 24, 2008Date of Patent: November 19, 2013Assignees: Dais Analytic Corporation, Aegis Biosciences, L.L.C.Inventors: David John Vachon, Liwei Cao, Gary Wnek
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Patent number: 8580890Abstract: The present invention concerns a heterophasic propylene copolymer of high melt flow for injection molding, which comprise a propylene polymer matrix and a rubber. The heterophasic propylene copolymers of the present invention are characterized by a high viscosity of the rubber phase and a well-defined ratio of the intrinsic viscosities of the rubber phase and the propylene polymer matrix, thus resulting in improved mechanical properties. The present invention further relates to a process for the production of such heterophasic propylene copolymers, their use and articles produced with them.Type: GrantFiled: July 2, 2009Date of Patent: November 12, 2013Assignee: Total Petrochemicals Research FeluyInventors: Rita De Luca, Philippe Hoslet
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Patent number: 8580874Abstract: A modified-asphalt composition prepared by introducing a diene end-capped block copolymer with a molten asphalt composition.Type: GrantFiled: April 18, 2008Date of Patent: November 12, 2013Assignees: Firestone Polymers, LLC, Heritage Research GroupInventors: Herb Wissel, Peter Boerner, Daniel Graves, Christine Rademacher, Timothy Reece
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Publication number: 20130281626Abstract: This invention relates to methods for producing an alkene terminated polystyrene, including: contacting a styrenic block copolymer and an alkene in the presence of a metathesis catalyst under conditions sufficient to produce an alkene terminated polystyrene having an unsaturation functionality of at least 0.7 and a MWD of about 1.5 or less. Methods for producing functionalized polymers and polyethylene blend composition comprising these functionalized polymers are also disclosed.Type: ApplicationFiled: April 18, 2012Publication date: October 24, 2013Inventors: Mun F. Tse, Aspy K. Mehta, Joann M. Canich, Matthew W. Holtcamp, John R. Hagadorn, Charles J. Ruff
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Publication number: 20130260632Abstract: Films and film laminates include a blend of polymers, the blend including an elastomeric block copolymer in an amount from about 51% to about 95% by weight of the blend; and a polystyrenic polymer in an amount from about 1% to about 25% of the weight of the blend, wherein the polystyrenic polymer is selected from the group consisting of polystyrenic homopolymers and polystyrenic random interpolymers. The films and laminates are elastic in the cross machine direction and have a relatively high modulus, or stiffness, in the machine-direction.Type: ApplicationFiled: September 5, 2012Publication date: October 3, 2013Inventors: Oomman P. Thomas, James L. Austin, Jose Augusto Vidal de Siqueira
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Patent number: 8530019Abstract: Articles having a Shore A hardness of 50 to 95 and made from polyolefin compositions comprising an ethylene-alpha-olefin interpolymer (random or block or a mixture of the two) are paintable without the need for a primer or other surface treatment with paints free of phthalate-based plasticizer and designed to paint SBS- or SEBS-type rubber based compositions. These polyolefin compositions are free of (1) phthalate-based plasticizer, (2) halogen-containing polymer, and (3) leachable, small polymeric units derived from styrene monomer. In addition, the content of the alpha-olefin in the polyolefin composition is at least 9.7 mole percent.Type: GrantFiled: February 22, 2010Date of Patent: September 10, 2013Assignee: Dow Global Technologies LLCInventors: Robert Hai-Feng He, Stephen Yau-Sang Cheng, Shuwen Peng, Jose Manu Rego, Gloria Stucchi
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Patent number: 8497321Abstract: A tacky resin composition which has proper initial tackiness, is sufficiently inhibited from rising in tackiness with time, can keep tackiness at a proper range even when it receives a slight heat history or is stored for a long time, has very small dependence on peeling speed, and can provide high transparency to a pressure-sensitive adhesive film or sheet as required, and a pressure-sensitive adhesive film or sheet for the surface protection of an article, which is obtained form the tacky resin composition. The tacky resin composition comprises (A) 5 to 80 parts by weight of an olefin polymer (component A), (B) 5 to 80 parts by weight of an ethylene/unsaturated ester copolymer (component B) and (C) 1 to 60 parts by weight of a styrene-based elastomer and/or an olefin-based elastomer (component C) based on 100 parts by weight of the total of the components A, B and C.Type: GrantFiled: January 28, 2009Date of Patent: July 30, 2013Assignee: Du Pont-Mitsui Polychemicals Co., Ltd.Inventors: Masataka Aoyama, Yoshitaka Hironaka, Hisao Gonohe
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Patent number: 8497322Abstract: A homogenous blend comprising from 10% to 90% by weight of a metallocene catalyzed polyethylene (mPE) and from 90% to 10% by weight of styrene-butadiene block copolymers comprising from 5% to 40% by weight of 1,3 butadiene monomer units and from 60% to 95% by weight of styrene monomer unites. The blend of the invention is used to make peelable films for food packaging applications.Type: GrantFiled: June 19, 2012Date of Patent: July 30, 2013Assignee: Total Petrochemicals Research FeluyInventor: Pascal Fourcade
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Patent number: 8476366Abstract: Embodiments of the invention provide block composites and their use in thermoplastic vulcanizate compounds.Type: GrantFiled: October 1, 2010Date of Patent: July 2, 2013Assignee: Dow Global Technologies, LLCInventors: Kim L. Walton, Brian W. Walther, Robert T. Johnston, Jose M. Rego, Xiaosong Wu