Mixture Contains Solid Block Or Block-type Copolymer Derived From Ethylenically Unsaturated Hydrocarbon Reactants Only At Least One Of Which Contains At Least Four Carbon Atoms Patents (Class 525/95)
  • Patent number: 7241837
    Abstract: The present invention has for its object to provide a damping material which, despite a high damping capacity at and around room temperature, has a small temperature dependence of rigidity at and around room temperature and a damping material having hot-melt processability and a good balance between damping capacity and temperature dependence of rigidity at and around room temperature. This invention provides a damper material composition wherein the ratio of the storage modulus (G?) value at 0° C. to the corresponding value at 40° C. as found by the measurement of dynamic viscoelasticity in the shear mode, namely (G?0° C./G?40° C.), is not greater than 15 and the loss tangent (tan ?) value as found by said measurement is not smaller than 0.4 at 0° C. to 40° C.
    Type: Grant
    Filed: April 5, 2001
    Date of Patent: July 10, 2007
    Assignee: Kaneka Corporation
    Inventors: Shigeru Yaguchi, Katsuhiko Kimura, Taizo Aoyama
  • Patent number: 7230050
    Abstract: A tire component comprising a vulcanized rubber, and from about 3 to about 85 parts by weight, per 100 parts by weight rubber, of a filler dispersed within said vulcanized rubber, where the vulcanized rubber includes the vulcanized residue of a thermoplastic-elastomeric block copolymer defined by the formula ?-?-?-? where ? is a hydrogen atom or a functional group, ? includes an elastomeric block, ? includes a thermoplastic block, and ? includes a hydrogen atom or a functional group.
    Type: Grant
    Filed: September 30, 2005
    Date of Patent: June 12, 2007
    Assignee: Bridgestone Corporation
    Inventors: Christopher G. Robertson, Terrence E. Hogan, William L. Hergenrother, David F. Lawson
  • Patent number: 7196142
    Abstract: Various novel block cationomers comprising polyisobutylene (PIB) and poly(2-dimethylamino)ethyl methacrylate) (PDMAEMA) segments have been synthesized and characterized. The specific targets were various molecular weight diblocks (PDMAEMA+) and triblocks (PDMAEMA+-b-PIB-b-PDMAEMA+) with the PIB blocks in the DPn=50–200?(Mn=3,000–9,000 g/mol) range connected to blocks of PDMAEMA+ cations in the DPn=5–20 range. The overall synthetic strategy for the preparation of these block cationomers comprised four steps: 1) Synthesis by living cationic polymerization of mono- and di-allyltelechelic polyisobutylenes, 2) End group transformation to obtain PIBs fitted with termini capable of mediating the atom transfer radical polymerization (ATRP) of DMAEMA, 3) ATRP of DMAEMA and 4) Quaternization of PDMAEMA to PDMAEMA+I? by CH3I. Kinetic and model experiments provided guidance to develop convenient synthesis methods.
    Type: Grant
    Filed: April 3, 2003
    Date of Patent: March 27, 2007
    Assignee: The University of Akron
    Inventors: Joseph P. Kennedy, Zheng Fang
  • Patent number: 7156944
    Abstract: To obtain an adhesive having both a high initial adhesive capacity and high heat resistance, a fusible adhesive which can be cross-linked by radiation and a low tendency to creep is provided. The adhesive contains 0 to 40 weight percent of at least one elastomer which cannot be cross-linked by radiation, 15 to 40 weight percent of at least one compound containing at least two olefinic double bonds, and 20 to 85 weight percent of at least one tackifier. The adhesive is especially suitable for use on high speed labeling machines.
    Type: Grant
    Filed: January 24, 2005
    Date of Patent: January 2, 2007
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Thomas Moeller, Marcus Heemann, Andreas Ferencz
  • Patent number: 7119146
    Abstract: Compatibilized blends of an isoolefin polymer and an unsaturated diene polymer are prepared by utilizing a compatibilizing agent comprising a block/graft copolymer containing poly- or copoly-isoolefin segments and C4 to C6 alkyl-substituted styrene polymer segments, such as poly(t-butylstyrene) segments.
    Type: Grant
    Filed: August 19, 2002
    Date of Patent: October 10, 2006
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Mun Fu Tse, Hsien Chang Wang, Ramanan Krishnamoorti, Andy H. Tsou
  • Patent number: 7090924
    Abstract: This invention concerns a thermosetting resin system that is useful in the manufacture of high performance prepreg, laminate and composite materials as well as the prepregs, laminates and composites made from the thermosetting resin composition.
    Type: Grant
    Filed: December 4, 2002
    Date of Patent: August 15, 2006
    Assignee: Isola USA Corp.
    Inventors: Jyoti Sharma, Martin Choate, Steve Peters, Kevin Rafferty
  • Patent number: 7081498
    Abstract: The present invention is directed to pressure-sensitive adhesive compositions and pressure-sensitive adhesive constructions fabricated using the pressure-sensitive adhesive compositions. The pressure-sensitive adhesive compositions comprise about 10 to about 40% of a styrene-isoprene block copolymer, about 5 to about 30% of a styrene-butadiene block copolymer, about 30 to about 65% of an aromatically modified tackifying resin, about 8 to about 30% of a plasticizing oil and optionally about 0.2 to about 2% of an antioxidant, wherein the percentages are based on the total weight of the composition.
    Type: Grant
    Filed: April 8, 2004
    Date of Patent: July 25, 2006
    Assignee: Morgan Adhesives Company
    Inventors: Scott Allen Moeller, Gary A. McMaster, Timothy Smith
  • Patent number: 7033676
    Abstract: A binder mixture comprises at least one polymer (A) with saturated main chain that is not a polyester and at least one polyester (B) with a saturated and/or unsaturated main chain, where (i) one of the two components (A) or (B) contains structural units I and/or II, or both components (A) and (B) contain structural units I and/or II, ?in which the index n is an integer from 1 to 10; and where (ii) at least polyester (B) that contains no structural units I and/or II contains maleic and/or fumaric esters incorporated in its main chain.
    Type: Grant
    Filed: January 21, 2000
    Date of Patent: April 25, 2006
    Assignee: BASF Coatings AG
    Inventors: Rainer Blum, Jorge Prieto
  • Patent number: 7026396
    Abstract: Provided are an aromatic vinyl polymer resin composition capable of being molded into resin foam sheets having good surface smoothness and glossiness well balanced with the mechanical strength thereof even when the expansion ratio in molding is increased, and resin foam sheets and containers of the composition. The resin composition comprises (A) from 80 to 98% by mass of an aromatic vinyl polymer resin having a weight-average molecular weight measured through GPC of from 200,000 to 400,000, a ratio of weight-average molecular weight to number-average molecular weight ranging from 2.2 to 3.6, a number of branches of from 0.1 to 1.0 in one molecule having an absolute molecular weight of 1,190,000 measured through GPC-MALLS, and a melt flow rate of from 1.5 to 3.5 g/10 min, and (B) from 2 to 20% by mass of a styrene-diene block copolymer or its hydrogenate. This is molded into a resin foam sheet through extrusion foaming, and the sheet is thermoformed into containers.
    Type: Grant
    Filed: July 17, 2002
    Date of Patent: April 11, 2006
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Shogo Hirota, Ryozo Okumura, Makoto Wakabayashi
  • Patent number: 7015285
    Abstract: This invention provides a composition and method for improving adhesion between a resinous thermoplastic substrate and polyurethane foam, said composition comprising at least one polyphenylene ether, at least one poly(alkenylaromatic) compound, and at least one carboxylic acid containing copolymer and optionally, further comprising at least one curing catalyst. Another embodiment of the invention provides articles derived from the composition of the present invention.
    Type: Grant
    Filed: December 18, 2002
    Date of Patent: March 21, 2006
    Assignee: General Electric
    Inventors: Vijay Mhetar, Ganesh Kannan
  • Patent number: 6987140
    Abstract: To provide a mouth guard composition which hardly generates plastic deformation and which is high in fluidity during the formation after heating and softening and superior in fitness, and which even after repeated use of a mouth guard prepared therefrom, is free from sticking with respect to its surface and does not cause an offensive smell. The mouth guard composition is constituted of 39˜98% by weight of a styrene block copolymer; 1˜60% by weight of at least one thermoplastic resin selected from the group consisting of an alicyclic saturated hydrocarbon-based resin, a terpene resin, and an aliphatic petroleum resin; and 1˜40% by weight of at least one wax selected from the group consisting of a mineral wax, a synthetic wax, a vegetable-based wax, and an animal-based wax.
    Type: Grant
    Filed: July 8, 2002
    Date of Patent: January 17, 2006
    Assignee: GC Corporation
    Inventors: Hiroshi Kamohara, Takaharu Takeshita
  • Patent number: 6964798
    Abstract: A multiple layer structure comprising a first and a second skin layer, each skin layer composed of a polypropylene containing polymer, and a radio frequency (“RF”) susceptible layer adhered to and between the first and second skin layers. The RF layer has a first component of a propylene based polymer, a second component of a non-propylene polyolefin, a third component of a radio frequency susceptible polymer, and a fourth component of a polymeric compatibilizing agent.
    Type: Grant
    Filed: March 21, 2002
    Date of Patent: November 15, 2005
    Assignee: Baxter International Inc.
    Inventors: Gregg Nebgen, Keith Anderson, Mike Scharf
  • Patent number: 6933342
    Abstract: The present invention relates to a composition which comprises at least one triblock copolymer, one terpene resin, one liquid component and one ethylene-vinyl acetate copolymer, and also to a process for preparing this composition, and to its use.
    Type: Grant
    Filed: July 29, 2004
    Date of Patent: August 23, 2005
    Assignee: Bayer Aktiengesellschaft
    Inventors: Roland Parg, Martin Hoch
  • Patent number: 6913807
    Abstract: An isothiocyanate-containing composition is provided in which bleeding of the composition is suppressed and even if an isothiocyanate volatilizes, the adhesion strength is retained. An isothiocyanate-containing composition is provided wherein an isothiocyanate is mixed into a mixture of a rubber adhesive having a softening point of less than 100° C. and a hydrogenated terpene resin having a softening point of less than 100° C. by an amount of 0.5-15 wt % of an isothiocyanate relative to the total amount of the mixture. The composition has a viscosity at 90° C. of 3000-40000 mPa.s and an adhesion strength of 1 N/25 mm or over when used as an adhesive to laminate two films, irrespective of whether or not the isothiocyanate has volatilized.
    Type: Grant
    Filed: May 30, 2003
    Date of Patent: July 5, 2005
    Assignee: Rengo Co., Ltd.
    Inventors: Kiyoshi Kamei, Hidenao Saito
  • Patent number: 6906120
    Abstract: An adhesive for thermoplastic film is formed from a composition comprising a blend of a poly(arylene ether), a thermosetting resin, a toughening agent, an optional plasticizer, and a cure agent. The adhesive finds particular utility in circuit board applications.
    Type: Grant
    Filed: August 22, 2000
    Date of Patent: June 14, 2005
    Assignee: General Electric
    Inventors: Michael J. Davis, James Estel Tracy, Geoffrey Henry Riding, Gary William Yeager
  • Patent number: 6894113
    Abstract: The present invention relates to a thermoset material with improved impact resistance comprising: 99 to 20% of a thermoset resin, and 1 to 80% of an impact modifier comprising at least one copolymer comprising S-B-M, B-M and M-B-M blocks, wherein: each block is connected to the other by means of a covalent bond or of an intermediate molecule connected to one of the blocks via a covalent bond and to the other block via another covalent bond, M is a PMMA homopolymer or a copolymer comprising at least 50% by weight of methyl methacrylate, B is incompatible with the thermoset resin and with the M block and its glass transition temperature Tg is less than the operating temperature of the thermoset material, and S is incompatible with the thermoset resin, the B block and the M block and its Tg or its melting temperature is greater than the Tg of B. S is advantageously polystyrene and B polybutadiene.
    Type: Grant
    Filed: May 17, 2001
    Date of Patent: May 17, 2005
    Assignee: Atofina
    Inventors: Francois Court, Ludwik Leibler, Jean-Pierre Pascault, Sophie Ritzenthaler
  • Patent number: 6875804
    Abstract: The syndiotactic polystirene resin composition according to the present invention is superior in compatibility between a syndiotactic polystyrene and a rubber component and mechanical properties such as impact strength, in which a syndiotactic polystyrene-maleic anhydride (sPS-MA) and a hydrogenated styrene/butadiene/styrene-maleic anhydride (SEBS-MA) are employed as compatibilizers and a diamine compound is added as a coupling agent. The compatibilizers and coupling agents improve polarity of both the syndiotactic polystyrene and the rubber component and impact strength of the syndiotactic polystyrene composition.
    Type: Grant
    Filed: December 18, 2000
    Date of Patent: April 5, 2005
    Assignee: Samsung Atofina Co., Inc.
    Inventors: Xuequan Zhang, Jae Gon Lim
  • Patent number: 6849339
    Abstract: Laminates include a thermoplastic substrate layer, a clear coat layer, and a tie layer. The tie layer most preferably includes an adhesive-enhancing effective amount of a branched or linear styrenic block copolymer which adhesively bonds the substrate and clear coat layers one to another. Advantageously, the tie layer includes a blend of the styrenic block copolymer and a tackifier resin, preferably a terpene resin. The laminate may be employed to manufacture a variety of shaped articles, most preferably automotive trim components.
    Type: Grant
    Filed: November 27, 2001
    Date of Patent: February 1, 2005
    Assignee: Guardian Industries Corporation
    Inventors: Subir K. Dey, Subhash H. Patel
  • Patent number: 6846571
    Abstract: A polymer blend suitable for use in automotive floor covering applications includes 100 parts by weight of a radial block copolymer having the general formula (AB)nBA, wherein n is greater than 1, each block A is a monoalkenyl arene polymer block and each block B is an elastomeric conjugated diene polymer block; from about 5 to about 200 parts by weight of a mineral oil; and from about 5 to about 300 parts by weight of a 1-olefin polymer. The resulting polymer blend may be formed into sheet materials which are recyclable, and which may exhibit low gloss and excellent tactility similar to vulcanized rubber. Further, the polymer blends of this invention may exhibit excellent grain retention, abrasion resistance, heat stability, and ultraviolet light stability.
    Type: Grant
    Filed: October 3, 2002
    Date of Patent: January 25, 2005
    Inventor: Raj K. Agrawal
  • Patent number: 6846877
    Abstract: An olefinic thermoplastic vulcanizate is blended with a rubber-modified monovinylidene aromatic monomer, utilizing a flexible block copolymer as compatabilizing agent. The resulting composition demonstrates improved miscibility and bonding characteristics and increased hardness not previously achievable using unmodified thermoplastic vulcanizates.
    Type: Grant
    Filed: December 26, 2002
    Date of Patent: January 25, 2005
    Assignee: Advanced Elastomer Systems, L.P.
    Inventors: Sunny Jacob, Kathleen Perevosnik, Joseph E. Pfeiffer
  • Patent number: 6838500
    Abstract: An adhesive composition and tapes utilizing the adhesive compositions are disclosed. A tape utilizing the adhesive composition of the present invention particularly suitable for use in closure systems associated with air ducts and air connectors is disclosed. A composition particularly suitable for use as an antioxidant in adhesive compositions is disclosed.
    Type: Grant
    Filed: February 7, 2002
    Date of Patent: January 4, 2005
    Inventors: Stuart D. Carlisle, Jerry M. Serra
  • Publication number: 20040266951
    Abstract: A polyphenylene sulfide resin composition including a polyphenylene sulfide resin having a specific amount of oligomers and a specific amount of a functional group, an amorphous thermoplastic resin having a glass transition temperature (Tg) of 120° C. or higher, and an additive having a specific amount of a functional group. The moldings obtained from this polyphenylene sulfide resin composition have a good toughness (impact strength) and weld strength. The use of this polyphenylene sulfide resin composition as a material for secondary battery cases makes it possible to maintain the initial electrolytic performance over a long period of time.
    Type: Application
    Filed: April 19, 2004
    Publication date: December 30, 2004
    Inventors: Yoshikuni Akiyama, Minoru Sakata, Kuniaki Minonishi
  • Patent number: 6821635
    Abstract: The present invention is a blend of a monovinylidene aromatic polymer, a rubber modified monovinylidene aromatic polymer, and a monovinyl aromatic-conjugated diene copolymer, which can be used to produce cost effective, transparent packaging materials with a good toughness, which materials can be produced using conventional thermoforming equipment. The blend comprises: a) from 49 to 70 weight percent based on the total weight of the blend, of a monovinylidene aromatic polymer having a weight average molecular weight (Mw) of from 210,000 to 400,000 and a melt flow of less than 12.0 g/10 min.
    Type: Grant
    Filed: February 19, 2003
    Date of Patent: November 23, 2004
    Assignee: Dow Global Technologoies Inc.
    Inventors: John L. Sugden, Phillip A. Wagner
  • Patent number: 6812285
    Abstract: A thermoplastic elastomer composition for a powder material used for slush molding. The thermoplastic elastomer composition consists of a polypropylene resin and 20 to 500 parts by mass of a hydrogenated block copolymer per 100 parts by mass of the polypropylene resin. The hydrogenated block copolymer has a) at least one polymer block A with a primary component that is a vinyl aromatic hydrocarbon monomer unit and b) at least one polymer block B with a primary component that is a hydrogenated butadiene monomer unit. The polymer block B has a hydrogenation degree of at least 90%. The vinyl aromatic hydrocarbon in the hydrogenated block copolymer is present in an amount more than 5 mass % and less than 25 mass %. The polymer block B before hydrogenation contains 62 mol % or more 1, 2 bonds on average. The melt flow rate (MFR) of the thermoplastic elastomer composition is at least 10 g/10 min at 230° C. under a load of 2.16 kgf in accordance with Japanese Industrial Standards (JIS) K7210.
    Type: Grant
    Filed: October 26, 2001
    Date of Patent: November 2, 2004
    Assignee: Mitsuboshi Belting Ltd.
    Inventors: Hirohide Enami, Kenrou Ono, Kenji Kubomoto, Yoshihiro Toda
  • Publication number: 20040214951
    Abstract: Block copolymers having a polyisobutylene segment and a polycycloaliphatic diene polymer segment are presented. Star block copolymers with 2 to 16 block copolymer arms, wherein each of the arms has a polyisobutylene segment and a polycycloaliphatic diene polymer segment, are presented. The star block copolymers are synthesized via the “core first” method.
    Type: Application
    Filed: April 25, 2003
    Publication date: October 28, 2004
    Inventors: Joseph P. Kennedy, Ralf M. Peetz, Ahmed F. Moustafa
  • Patent number: 6797782
    Abstract: A process of producing particles for diagnostic reagent, including a step of polymerizing a polymerizable monomer in the presence of a matrix particle having a magnetic substance layer containing at least one of Fe2O3 and Fe3O4 on the surface thereof and having a mean particle size of 0.4-200 &mgr;m to form a polymer layer on the magnetic substance layer.
    Type: Grant
    Filed: March 21, 2003
    Date of Patent: September 28, 2004
    Assignee: JSR Corporation
    Inventors: Ichiro Ozaki, Satoshi Katayose, Mikio Hikata, Kejun Fan, Mitsuhiro Murata
  • Patent number: 6794449
    Abstract: An adhesive composition is provided for adhering together roofing materials such as EPDM rubber and thermoplastic polyolefin (TPO). The adhesive composition includes a rubbery polymer comprising a blend of a thermoplastic block copolymer selected from the group consisting of a styrene-butadiene-styrene block copolymer, a styrene-isoprene-styrene block copolymer, a styrene-ethylene/butylene-styrene block copolymer, a styrene-ethylene/propylene block copolymer and an ethylene-propylene block copolymer and combinations thereof and a polyisobutylene. Roofing articles incorporating the adhesive composition are also provided. The composition is a pressure sensitive adhesive that allows roofing articles to be applied in a peel and stick manner.
    Type: Grant
    Filed: April 11, 2002
    Date of Patent: September 21, 2004
    Assignee: Adco Products, Inc.
    Inventor: Dennis K. Fisher
  • Patent number: 6787604
    Abstract: The present invention relates to a composition which comprises at least one triblock copolymer, one terpene resin, one liquid component and one ethylene-vinyl acetate copolymer, and also to a process for preparing this composition, and to its use.
    Type: Grant
    Filed: March 21, 2003
    Date of Patent: September 7, 2004
    Assignee: Bayer Aktiengesellschaft
    Inventors: Roland Parg, Martin Hoch
  • Patent number: 6764761
    Abstract: A method, system and apparatus for performing peritoneal dialysis are provided. To this end, in part, a film is provided. The film includes a layer of a polymer blend having from about 90% to about 99% by weight of a first component containing a styrene and hydrocarbon copolymer and from about 10% to about 1% of a high melt strength polypropylene.
    Type: Grant
    Filed: May 24, 2002
    Date of Patent: July 20, 2004
    Assignee: Baxter International Inc.
    Inventors: Bruce Ming-Da Eu, Sherwin Shang, Tahua Yang, Michael T. K. Ling, Loren M. Lundtveit
  • Patent number: 6759465
    Abstract: A thermoplastic composition which is obtained by melt-kneading (1) 55 to 75 wt. % crystalline polypropylene resin together with (2) 10 to 30 wt. % elastomer comprising either a rubber containing a vinyl aromatic compound or a mixture thereof with an ethylene/&agr;-olefin random copolymer rubber and (3) 15 to 25 wt. % talc having an average particle diameter of 3 &mgr;m or smaller. The composition satisfies specific requirements with respect to: the long period obtained by X-ray small-angle scattering attributable to the vinyl aromatic-containing rubber in a blend obtained by melt-kneading the ingredients (1) and (2); the shape and diameter of the elastomer particles present near the polypropylene/elastomer interface in the blend; and the difference between the glass transition point of the ingredient (1) and that of the composition attributable to the crystalline polypropylene homopolymer parts.
    Type: Grant
    Filed: December 22, 2000
    Date of Patent: July 6, 2004
    Assignees: Sumitomo Chemical Company, Limited, Toyota Jidosha Kabushiki Kaisha
    Inventors: Moriyasu Shimojo, Kenichi Ohkawa, Susumu Kanzaki, Takayuki Nagai, Takao Nomura, Masatoshi Matsuda, Hisayuki Iwai
  • Patent number: 6747094
    Abstract: A high-impact thermoplastic resin composition comprising: (A) 5 to 95 parts by weight of a thermoplastic elastomer comprising a partially or completely crosslinked saturated rubber-like polymer and a polyolefinic resin and/or a polystyrene-based resin, or a mixture of said thermoplastic elastomer and a polyolefinic resin; and (B) 95 to 5 parts by weight of at least one thermoplastic resin selected from the group consisting of polystyrene-based resins, polyamide-based resins, polyurethane-based resins, polycarbonate-based resins, polyphenylene ether-based resins, polyester-based resins, acrylic resins, polyacetal-based resins and polyphenylene sulfide-based resins, the total of the components (A) and (B) being 100 parts by weight, wherein the amount of the saturated rubber-like polymer in the composition is 1 to 40% by weight.
    Type: Grant
    Filed: May 17, 2001
    Date of Patent: June 8, 2004
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventors: Hideo Kinoshita, Ikuji Ohtani, Takeshi Yasui
  • Patent number: 6743860
    Abstract: The present invention relates to a thermoplastic resin composition comprising (a) 100 parts by weight of a block copolymer comprising at least two polymeric blocks A composed mainly of a vinyl aromatic compound and at least one polymeric block B composed mainly of a conjugated diene compound, or a hydrogenated block copolymer thereof, (d) 5 to 50 parts by weight of an organic peroxide, and (e) 10 to 80 parts by weight of one or more substances selected from the group consisting of multifunctional vinyl compounds and multifunctional (meth)acrylate compounds. The present invention provides a master batch of an organic peroxide in which the organic peroxide is so uniformly dispersed in a thermoplastic resin that crosslinking and/or decomposition occur uniformly, a method of preparing the same, a thermoplastic resin composition obtained using the master batch and a method of preparing the same.
    Type: Grant
    Filed: August 2, 2002
    Date of Patent: June 1, 2004
    Assignee: Riken Technos Corporation
    Inventor: Hiroki Mizuno
  • Patent number: 6734247
    Abstract: An improved tough, transparent polymer alloy comprised of 90 to 20 weight percent of a brittle polymer with a weight average molecular weight greater than 180,000; 0 to 60 weight percent of a rubbery polymer; 0 to 80 weight percent of a ductile polymer; and between greater than 0.4, i.e. between 0.5 and 3 weight percent of a plasticizer, i.e. mineral oil which resides in the brittle polymer. The brittle polymer can have molecular weights between 220,000 and 300,000, and may be as high as 400,000. In one of the preferred embodiments the brittle polymer is a copolymer of styrene and methyl methacrylate which copolymer ranges between 50 and 55 weight percent, the rubbery polymer is 0 weight percent, the ductile polymer is a styrene butadiene block copolymer ranging between 45 and 50 weight percent, and the mineral oil is 1.5 weight percent. Notched IZOD impact strength ranges between 1.0 to 6.0 ft-lb./in., preferably between 2.0 and 4.5 ft-lb./in. The haze can be less than 1.5% or it can be between 1 and 4%.
    Type: Grant
    Filed: December 13, 2001
    Date of Patent: May 11, 2004
    Assignee: Nova Chemicals Inc.
    Inventors: Allen Maxwell Donn, Richard Albert Cooper
  • Patent number: 6713545
    Abstract: A universal masterbatch composition for adding fillers and particularly pigment to polymers, having up to 85%, by weight, of at least one filler, up to 25%, by weight, of at least one viscosity modifier and a remainder quantity of a styrene butadiene block copolymer. The composition further includes up to 5%, by weight, of at least one processing aid and up to 2%, by weight of at least one antioxidant.
    Type: Grant
    Filed: December 22, 2000
    Date of Patent: March 30, 2004
    Assignee: Cabot Corporation
    Inventors: Nicole Petiniot, Philippe Rasquin
  • Patent number: 6706813
    Abstract: To provide a curable composition excellent in flexibility and heat resistance. A curable composition which comprises (A) a block copolymer having at least one kind of block formed from an aliphatic hydrocarbon compound and (B) an isobutylene polymer having a silicon group bound to a hydrolyzable group or a hydroxyl group. That composition can be used as sealants, adhesives, pressure sensitive adhesives, compositions for gaskets, double layer glazing spacers and so on.
    Type: Grant
    Filed: December 3, 2001
    Date of Patent: March 16, 2004
    Assignee: Kaneka Corporation
    Inventors: Makoto Chiba, Shintaro Komitsu
  • Patent number: 6699943
    Abstract: The present invention is directed to a curable, water-based coating composition utilized in waterborne coating systems. The coating composition is the reaction product of a water-based copolymer prepared by free-radical polymerization, and a cross-linking agent. The copolymer is the reaction product of a first block and a second block. The first block is the reaction product of a first ethylenically unsaturated monomer, acrylic acid, and a second ethylenically unsaturated monomer, methyl methacrylate, as well as the reaction product of a vinylaromatic hydrocarbon monomer, diphenylethylene. The second block is the reaction product of a plurality of ethylenically unsaturated monomers, styrene, 2-ethylhexyl methacrylate, cyclohexyl methacrylate, and carbonate-modified glycidyl methacrylate including a carbonate functional group that is subsequently converted into a carbamate functional group by ammonium hydroxide.
    Type: Grant
    Filed: December 22, 2000
    Date of Patent: March 2, 2004
    Assignee: BASF Corporation
    Inventors: Swaminathan Ramesh, Paul Lessek, Wolfgang Bremser
  • Patent number: 6696520
    Abstract: An elastomeric thermoplastic polyolefin composition comprising (i) an heterophasic olefin polymer composition comprising a crystalline propylene homopolymer of copolymer fraction and an elastomeric ethylene copolymer fraction and (ii) an elastomeric polymer having a hardness equal to or less than 90 points selected from the group consisting of copolymers of ethylene, ethylene-methyl acrylate copolyers, saturated or unsaturated styrene block copolymers and unsaturated norbornene polymers.
    Type: Grant
    Filed: October 14, 1998
    Date of Patent: February 24, 2004
    Assignee: Basell Poliolefine Italia S.p.A.
    Inventors: Giampaolo Pellegatti, Vittorio Braga, Roberto Bonari
  • Patent number: 6683123
    Abstract: A process for producing a thermoplastic molding composition is disclosed. The process entails introducing a solid polymeric resin, optionally containing residual moisture, into an extruder, operating under conditions designed to melt the resin and charging water into the melt while in the extruder to yield wet, molten resin that contains water in an amount of at least about 2 percent. The wet, molten resin is then devolatilized to yield dry resin having water content not exceeding 0.3 percent. Molding compositions thus produced have improved properties. In a preferred embodiment, the process results in a molding composition that contains a fine dispersion of a discontinuous phase in a continuous polymeric phase.
    Type: Grant
    Filed: September 12, 2000
    Date of Patent: January 27, 2004
    Assignee: Bayer Polymers LLC
    Inventor: Henry A. Kozlowski
  • Patent number: 6660797
    Abstract: This invention provides a propylene-based composition for the molded polypropylene resin articles excellent in resistance to scratching and moldability, and well-balanced properties between high rigidity and high impact strength, and also provides a method for molding the above propylene-based composition, thereby providing high-performance industrial parts and automobile parts, in particular automobile interior parts.
    Type: Grant
    Filed: October 10, 2001
    Date of Patent: December 9, 2003
    Assignee: Japan Polychem Corporation
    Inventors: Yoshihiro Banno, Yoshihiro Sobajima, Akira Kobayashi, Masaaki Isoi
  • Patent number: 6653401
    Abstract: Disclosed is a thermoplastic elastomer composition which comprises (A) a thermoplastic resin containing a polystyrene resin, (B) a rubber-like polymer obtained by partially or completely crosslinking an ethylene-&agr;-olefin copolymer and (C) a compatibilizing agent, the amount of the component (B) being 40-90 parts by weight and the amount of the component (C) being 0.1-40 parts by weight based on 100 parts by weight of the components (A), (B) and (C) in total. According to the present invention, an elastomer composition excellent in abrasion resistance can be provided.
    Type: Grant
    Filed: March 2, 2001
    Date of Patent: November 25, 2003
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventors: Hideo Kinoshita, Ikuji Ohtani, Takeshi Yasui
  • Patent number: 6649695
    Abstract: Linear or star block copolymers which have at least one polymer block A which is essentially composed of isobutene units and at least two polymer blocks B which are essentially composed of units which are derived from vinylaromatic monomers are used as resilient sealing material. In particular, such sealing materials are used for sealing the edge joints in insulation glass panes, and insulation glass panes have a flexible edge joint seal which contains one of the block copolymers.
    Type: Grant
    Filed: February 6, 2002
    Date of Patent: November 18, 2003
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans Peter Rath, Arno Lange, Helmut Mach, Konrad Knoll
  • Patent number: 6632541
    Abstract: An olefin based copolymer composition having excellent weather resistance and excellent recycling properties having an olefin based copolymer obtained by copolymerizing two or more olefins, wherein the olefins are selected from the group consisting of ethylene, propylene and alpha olefins having 4 to 20 carbon atoms, and the total number of carbon atoms of the two or more selected olefins is 6 or more in combination with other component(s).
    Type: Grant
    Filed: February 10, 1999
    Date of Patent: October 14, 2003
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Hirofumi Johoji, Hidetake Hozumi, Tadaaki Nishiyama
  • Patent number: 6630536
    Abstract: A pressure-sensitive adhesive composition comprises: 100 parts by weight of a rubber component that is solid in an ordinary temperature; 30 to 170 parts by weight of a rubber component that is liquid in an ordinary temperature; and 50 to 400 parts by weight of a tackifier, wherein the amount of the tackifier is 25 to 80 parts by weight based on 100 parts by weight of the total amount of the rubber components.
    Type: Grant
    Filed: August 28, 2001
    Date of Patent: October 7, 2003
    Assignee: Nitto Denko Corporation
    Inventors: Masayoshi Kuniya, Yasuyuki Sasaki, Tsuyoshi Kasahara
  • Publication number: 20030181586
    Abstract: The present invention relates to a composition which comprises at least one triblock copolymer, one terpene resin, one liquid component and one ethylene-vinyl acetate copolymer, and also to a process for preparing this composition, and to its use.
    Type: Application
    Filed: March 21, 2003
    Publication date: September 25, 2003
    Inventors: Roland Parg, Martin Hoch
  • Patent number: 6624247
    Abstract: A polypropylene-based resin film of a resin composition (C) comprising: 40 to 95 wt % of a propylene-based copolymer (A) selected from a propylene random copolymer (i) of propylene with ethylene and/or &agr;-olefin and a propylene-based copolymer (ii) composed of 1 to 30 wt % of a component (a) obtained by copolymerizing propylene, an &agr;-olefin and ethylene in a first step; and 70 to 99 wt % of a component (b) obtained by copolymerizing those in the subsequent step, in which the copolymerization ratio is different from that in the first step; and 5 to 60 wt % of a polypropylene-ethylene and/or &agr;-olefin block copolymer (B) having a CXS of 5.0 wt % or more, wherein the CXS has a content of ethylene and/or the &agr;-olefin of 14 to 35 mol %, and wherein the heat-seal temperature of the film of the (C) is lower by 3° C. or more than those of respective films of the (A) and (B).
    Type: Grant
    Filed: July 11, 2001
    Date of Patent: September 23, 2003
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Takanori Kume, Shigeki Kishiro, Eisuke Shiratani
  • Publication number: 20030158336
    Abstract: The present invention has for its object to provide a damping material which, despite a high damping capacity at and around room temperature, has a small temperature dependence of rigidity at and around room temperature and a damping material having hot-melt processability and a good balance between damping capacity and temperature dependence of rigidity at and around room temperature.
    Type: Application
    Filed: February 13, 2003
    Publication date: August 21, 2003
    Inventors: Shigeru Yaguchi, Katsuhiko Kimura, Taizo Aoyama
  • Patent number: 6598637
    Abstract: There is disclosed a pneumatic tire having a rubber component comprising a sulfur cured rubber composition composed of, based on 100 parts by weight of rubber (phr): (a) 99 to 50 parts by weight of a first rubber containing olefinic unsaturation; and (b) 1 to 50 parts by weight of a second rubber which is different from said first rubber and which is an elastomeric block copolymer of (1) from 15 to 65 percent by weight, based on the total block copolymer, of butadiene, and (2) from 35 to 85 percent by weight, based on the total block copolymer, of styrene, which block copolymer has: (a) at least two blocks A which have polymerized units of styrene, a glass transition temperature Tg above 25° C.
    Type: Grant
    Filed: July 10, 2001
    Date of Patent: July 29, 2003
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Annette Lechtenböhmer, Maurice Peter Catharina Jozef Klinkenberg
  • Patent number: 6579940
    Abstract: The present invention provides functionally modified thermoplastic elastomeric compounds composed of at least one polystyrene hard domain, at least one polyolefin rubber domain and at least one cross-linkable compound interspersed within one or more of the domains. Methods for making and using these thermoplastic elastomeric compounds are also provided as are articles made from these compounds along with methods for making such articles.
    Type: Grant
    Filed: October 28, 1999
    Date of Patent: June 17, 2003
    Assignee: Edwards Lifesciences Corporation
    Inventor: Jeffrey S. Dove
  • Patent number: 6579583
    Abstract: The invention provides a flexible plastic formulation capable of being extruded, blow-molded, ethylene oxide and radiation sterilized. The plastic formulation of the invention comprises: a) from about 60 to about 94 percent by weight of a copolymer consisting essentially of ethylene and vinyl acetate units; b) from about 5 to about 25 percent by weight of a block copolymer, the block copolymer consisting essentially of a central block copolymer molecule including generally equal proportions of ethylene and butylene units, and terminal blocks of polystyrene; and c) from about 1 to about 15 percent by weight of an ultra-low density polyethylene material. The plastic formulations of the invention are useful in the manufacture of blood bags, tubing and the like.
    Type: Grant
    Filed: November 13, 2001
    Date of Patent: June 17, 2003
    Assignee: Baxter International Inc.
    Inventor: Indrajit Patel
  • Patent number: 6576310
    Abstract: A medical tubing having rigidity, flexibility, transparency and heat resistance and, additionally, acceptable flexural modulus and tensile strength and further having no stickiness between surfaces of the tubing is provided. The medical tubing is composed of a resin composition containing a low-density ethylene/&agr;-olefin copolymer having a density of 0.860-0.900 g/cm3 polymerized with a metallocene catalyst and a styrene/ethylene-butylene/olefin block copolymer.
    Type: Grant
    Filed: January 8, 2001
    Date of Patent: June 10, 2003
    Assignee: Nipro Corporation
    Inventor: Mamoru Shimada