Non-metal Material Is Organic Nitrogen-containing Compound Patents (Class 526/141)
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Patent number: 10995168Abstract: The present invention relates to a process for the preparation of ethylene polymers using a number of reactors arranged in series comprising the steps in which a) ethylene, a diluent, a catalyst, a co-catalyst and optionally comonomers and hydrogen are introduced into a first reactor, b) polymerization of ethylene and optionally comonomers is carried out in the reaction mixture of said first reactor to make ethylene polymers, c) reaction mixture is discharged from said first reactor, d) said reaction mixture and fresh ethylene and optionally comonomers and hydrogen are introduced into the consecutive reactor to make additional ethylene polymers, e) said reaction mixture is discharged from said consecutive reactor and introduced into the further consecutive reactor, if any, with fresh ethylene and optionally comonomers and hydrogen to make additional ethylene polymers, steps c) and d) are repeated until the last reactor of the series, f) reaction mixture is discharged from last reactor of the series and ethylType: GrantFiled: March 4, 2019Date of Patent: May 4, 2021Assignee: TOTAL RESEARCH & TECHNOLOGY FELUYInventors: Mieke Dams, Daniel Siraux
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Patent number: 10932994Abstract: The present invention relates to a kit of parts comprising Part A and Part B, Part A comprising: ascorbic acid, component(s) comprising an ascorbic acid moiety or derivative(s) thereof, optionally polymerizable component(s) without acidic moieties, optionally polymerizable component(s) with acidic moieties, and optionally filler(s), Part B comprising polymerizable component(s) without acidic moieties, polymerizable component(s) with acidic moieties, transition metal component(s), organic peroxide(s), and optionally filler(s), The invention is also directed to a redox initiator system comprising ascorbic acid, component(s) comprising an ascorbic acid moiety or derivative(s) thereof, transition metal component(s), preferably comprising a copper or iron ion containing salt, organic peroxide(s), preferably comprising a hydroperoxide or di-peroxide. The kit of parts and redox initiator system are particularly useful in the dental field.Type: GrantFiled: July 7, 2015Date of Patent: March 2, 2021Assignee: 3M Innovative Properties CompanyInventors: Reinhold Hecht, Manfred Ludsteck, Andrea Stippschild-Boxler, Gioacchino Raia, Rainer A. Guggenberger
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Patent number: 10005861Abstract: Methods for controlling the productivity of an olefin polymer in a polymerization reactor system using a halogenated hydrocarbon compound are disclosed. The productivity of the polymer can be increased via the addition of the halogenated hydrocarbon compound.Type: GrantFiled: April 26, 2017Date of Patent: June 26, 2018Assignee: Chevron Phillips Chemical Company LPInventors: Errun Ding, William B. Beaulieu
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Patent number: 9260542Abstract: A method of forming a polymer includes a step of polymerizing a compound having formula 1 with a Ziegler-Natta catalyst to form a polymer having formula 2: wherein: R is a fluorinated C1-18 alkyl group, a fluorinated ether group, or a fluorinated silane ether; and n is a number from about 20 to 500 on average.Type: GrantFiled: April 3, 2012Date of Patent: February 16, 2016Assignee: GM Global Technology Operations LLCInventors: Timothy J. Fuller, Lijun Zou
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Patent number: 9115224Abstract: A supported catalyst system comprising a phosphinimine ligand containing catalyst on an alumina support treated with a metal salt has improved reactor continuity in a dispersed phase reaction in terms of initial activation and subsequent deactivation. The resulting catalyst has a lower consumption of ethylene during initiation and a lower rate of deactivation. Preferably the catalyst is used with an antistatic agent.Type: GrantFiled: March 26, 2012Date of Patent: August 25, 2015Assignee: NOVA CHEMICALS (INTERNATIONAL) S.A.Inventors: Lee Douglas Henderson, Peter Phung Minh Hoang, Ian Ronald Jobe, Xiaoliang Gao
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Patent number: 9000107Abstract: A process for preparing a polydiene, the process comprising the step of: polymerizing conjugated diene monomer in the presence of a (hydrocarbyloxyhydrocarbyl)amine, where said step of polymerizing employs a lanthanide-based catalyst system.Type: GrantFiled: January 31, 2012Date of Patent: April 7, 2015Assignee: Bridgestone CorporationInventors: Zengquan Qin, Jason T. Poulton
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Patent number: 8993692Abstract: A process for polymerizing ethylene to produce an ethylene-based polymer including contacting ethylene with a Ziegler-Natta procatalyst, an alkylaluminum cocatalyst and a self limiting agent selected from the group of aliphatic, cycloaliphatic, substituted cycloaliphatic or aromatic esters, anhydrides and amides such that the self limiting agent reduces polymerization rates to no greater than 40% of the polymerization rate in the absence of the self limiting agent at temperatures equal to or greater than 120° C. is provided.Type: GrantFiled: June 29, 2011Date of Patent: March 31, 2015Assignee: Dow Global Technologies LLCInventors: Robert J. Jorgensen, Sean W. Ewart, Richard E. Campbell, Jr., Daryoosh Beigzadeh, Robert D. Froese, Peter M. Margl
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Patent number: 8952111Abstract: Olefin polymerization is carried out with a supported phosphinimine catalyst which has been treated with a long chain substituted amine compound.Type: GrantFiled: September 19, 2011Date of Patent: February 10, 2015Assignee: Nova Chemicals (International) S.A.Inventors: Peter Phung Minh Hoang, Benjamin Milton Shaw, Patrick Lam, Victoria Ker, Cliff Robert Baar, Lee Douglas Henderson, Charles Ashton Garret Carter, Yan Jiang
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Patent number: 8921251Abstract: The invention relates to the field of producing polymers and copolymers of olefin oligomers produced by a trimerization reaction of olefin monomers. There is disclosed a process which comprises producing olefin oligomers with the aid of a trimerization catalyst system prepared using UHF irradiation for activating individual components of the trimerization catalyst system. The use of the trimerization catalyst system thus improved and having increased activity provides for increased effectiveness in the production of olefin oligomers from ethylene or other olefin monomers, inter alia, at a low pressure of ethylene. The olefin oligomers thus produced are then polymerized or copolymerized using processes known in the art. The technical effect consists in increasing the effectiveness of the production of olefin oligomers which are then used in a polymerization or copolymerization reaction.Type: GrantFiled: January 28, 2011Date of Patent: December 30, 2014Assignee: Open Joint Stock Company “Sibur Holding”Inventors: Timur Mikhailovich Zilbershtein, Maxim Vladimirovich Lipskikh, Alexei Alexandrovich Nosikov, Georgy Viktorovich Nesyn
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Publication number: 20140357818Abstract: Olefin polymerization is carried out with a supported phosphinimine catalyst which has been treated with a long chain substituted amine compound.Type: ApplicationFiled: August 19, 2014Publication date: December 4, 2014Applicant: NOVA Chemicals (International) S.A.Inventors: Peter Phung Minh Hoang, Victoria Ker, Charles Ashton Garret Carter, Sergio Alejandro Guillen-Castellanos, Yan Jiang
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Patent number: 8895466Abstract: The present invention discloses an active metallocene catalyst system prepared with a hafnium-based metallocene catalyst system and an activating agent comprising an aluminoxane and a sterically hindered Lewis base.Type: GrantFiled: May 24, 2013Date of Patent: November 25, 2014Assignee: Total Research & Technology FeluyInventors: Vincenzo Busico, Roberta Cipullo, Roberta Pellecchia, Abbas Razavi
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Patent number: 8809221Abstract: The present invention discloses new class of nitrogen containing external donor systems. These donor systems are used in titanium supported on magnesium dichloride pro-catalyst system for polymerization of propylene. The external donor systems of the present invention in combination with silane show the kinetics control for diester catalyst polymerization process along with stereo regularity control of product. The polypropylene produced using nitrogen containing external donor systems of the present invention have broad molecular weight distribution.Type: GrantFiled: May 7, 2012Date of Patent: August 19, 2014Assignee: Reliance Industries LimitedInventors: Harshad Ramdas Patil, Priyanshu Bharatkumar Vyas, Virendrakumar Gupta
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Patent number: 8809473Abstract: A method for altering the polymer architecture of ethylene copolymers made with a supported phosphinimine polymerization catalyst. The method involves changing the amount of a catalyst modifier added to a reactor separately from or together with a supported phosphinimine polymerization catalyst.Type: GrantFiled: September 16, 2011Date of Patent: August 19, 2014Assignee: Nova Chemicals (International) S.A.Inventors: Peter Phung Minh Hoang, Benjamin Milton Shaw, Patrick Lam, Victoria Ker, Cliff Robert Baar
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Patent number: 8802584Abstract: A supported catalyst system comprising a phosphinimine ligand containing catalyst on a porous inorganic support treated with a metal salt has improved reactor continuity in a dispersed phase reaction in terms of initial activation and subsequent deactivation. The resulting catalyst has a lower consumption of ethylene during initiation and a lower rate of deactivation. Preferably the catalyst is used with an antistatic agent.Type: GrantFiled: March 27, 2012Date of Patent: August 12, 2014Assignee: Nova Chemicals (International) S.A.Inventors: Lee Douglas Henderson, Peter Phung Minh Hoang, Ian Ronald Jobe, Xiaoliang Gao
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Patent number: 8664343Abstract: A polymerization catalyst composition for preparing cis 1,4-polydienes is provided. The catalyst composition comprises (a) a metal-containing compound, said metal being a transition metal or a lanthanide metal; (b) a carbene, (c) an alkylating agent, and optionally (d) a halogen-containing compound with the proviso that the halogen-containing compound must be present when none of the metal-containing compound and the alkylating agent contain a labile halogen atom. Also provided is a process for producing a polydiene comprising reacting a conjugated diene in the presence of the polymerization catalyst composition.Type: GrantFiled: June 9, 2009Date of Patent: March 4, 2014Assignee: Bridgestone CorporationInventors: Zengquan Qin, Jason T. Poulton
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Patent number: 8648001Abstract: A catalyst for polymerization of olefins formed from (A) a solid catalyst component containing magnesium, titanium, halogen, and an electron donor compound, (B) an organoaluminum compound shown by the formula, R6pAlQ3-p, and (C) an aminosilane compound shown by the formula, R3nSi(NR4R5)4-n; and a process for producing a catalyst for polymerization of olefins in the presence of the catalyst are provided. A novel aminosilane compound, a catalyst component for polymerization of olefins having a high catalytic activity, capable of producing polymers with high stereoregularity in a high yield, and exhibiting an excellent hydrogen response, a catalyst, and a process for producing olefin polymers using the catalyst are provided.Type: GrantFiled: November 4, 2011Date of Patent: February 11, 2014Assignee: Toho Titanium Co., Ltd.Inventors: Motoki Hosaka, Takefumi Yano, Maki Sato, Kohei Kimura
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Patent number: 8614162Abstract: Disclosed are catalyst compositions having an external electron donor which includes one or more of the following compositions: a phosphite, a phosphonite, a pyrophosphite, and/or a diphosphazane. Ziegler-Natta catalyst compositions containing the present external electron donor exhibit strong activity and produce propylene-based olefins with high isotacticity and high melt flow rate.Type: GrantFiled: December 11, 2012Date of Patent: December 24, 2013Assignee: Dow Global Technologies LLCInventor: Joseph N. Coalter, III
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Patent number: 8551903Abstract: Disclosed is a process for producing a procatalyst composition having an amide ester internal electron donor. The process includes pre-halogenating a procatalyst precursor before reaction with the amide ester and forming the procatalyst composition. Ziegler-Natta catalyst compositions containing the present procatalyst composition exhibit improved catalyst activity and/or improved catalyst selectivity and produce propylene-based olefins with broad molecular weight distribution.Type: GrantFiled: February 24, 2011Date of Patent: October 8, 2013Assignee: Dow Global Technologies LLCInventors: Linfeng Chen, Clark C. Williams, Tak W. Leung, Tao Tao, Kuanqiang Gao, James X. Shu
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Patent number: 8541333Abstract: A catalyst component for olefin polymerization comprising an ?-cyanosuccinate compound as an internal electron donor, a catalyst comprising the catalyst component, and use of the catalyst in olefin polymerization. When used in propylene polymerization, the catalyst can exhibit good catalytic activity and good hydrogen response, and the resulting polymer can have a good isotacticity and a good molecular weight distribution.Type: GrantFiled: August 13, 2010Date of Patent: September 24, 2013Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical CorporationInventors: Lunjia Xie, Yongtai Ling, Yu Tian, Zaixing Feng, Siyuan Zhao, Qing Hu, Zhufang Sun, Yu Kang
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Patent number: 8497330Abstract: Methods for gas phase olefin polymerization are provided. The method can include combining a spray dried catalyst system with a diluent to produce a catalyst slurry. The catalyst system can include a metallocene compound. Ethylene, a continuity additive, and the catalyst slurry can be introduced to a gas phase fluidized bed reactor. The reactor can be operated at conditions sufficient to produce a polyethylene. The spray dried catalyst system can have a catalyst productivity of at least 12,000 grams polyethylene per gram of the catalyst system.Type: GrantFiled: December 22, 2010Date of Patent: July 30, 2013Assignee: Univation Technologies, LLCInventors: F. David Hussein, Kevin J. Cann, Ann M. Schoeb-Wolters, Phuong A. Cao, Bruce J. Savatsky, Eric J. Markel, Daniel P. Zilker, Jr., Garth R. Giesbrecht
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Patent number: 8466081Abstract: Disclosed are halogenated amide esters that are suitable as internal electron donors in procatalyst compositions. Ziegler-Natta catalyst compositions containing the present procatalyst compositions exhibit improved catalyst activity and/or improved catalyst selectivity and produce propylene-based olefins with broad molecular weight distribution.Type: GrantFiled: February 24, 2011Date of Patent: June 18, 2013Assignee: Dow Global Technologies LLCInventors: Linfeng Chen, Tak W. Leung, Tao Tao, Kuanqiang Gao, James X. Shu
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Patent number: 8445609Abstract: An object of the present invention is to provide a method for producing an olefin polymer, with which an olefin polymer having good particle properties can be produced in high activity, fouling inside the polymerization vessel, such as a vessel wall or an impeller, can be effectively prevented, and a long-term stable operation is achieved. A method for producing an olefin polymer according to the present invention is characterized by including (co)polymerizing at least one olefin selected from the group consisting of ethylene and ?-olefins having 3 to 20 carbon atoms in a polymerization vessel in the presence of (A) a solid catalyst component for olefin polymerization, (B) an aliphatic amide, and (C) an organoaluminum compound.Type: GrantFiled: April 21, 2010Date of Patent: May 21, 2013Assignees: Mitsui Chemicals, Inc., Prime Polymer Co., Ltd.Inventors: Yasushi Tohi, Ken Yoshitsugu, Naoya Akiyama, Toshio Fujita, Masatoshi Chinaka
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Patent number: 8399375Abstract: The invention relates to a supported metallocene catalyst composition and a process for the preparation of polyolefin using the same. A supported metallocene catalyst composition according to the invention is prepared by bringing a compound of a group IV transition metal into contact with an inorganic or organic porous carrier treated with an ionic compound. Advantages of a supported metallocene catalyst composition of the invention include an increase in the catalyst activity during polymerization of slurry and an olefin compound in the vapor phase even at a low content of metallocene metal components within the carrier, and an improvement in solving process problems such as fouling, sheeting, plugging or the like.Type: GrantFiled: March 26, 2009Date of Patent: March 19, 2013Assignees: SK Global Chemical Co., Ltd., SK Innovation Co., Ltd.Inventors: Seungyeol Han, Myungahn Ok, Young-Soo Ko, Chang-il Lee
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Patent number: 8158735Abstract: This invention relates to (meth)acrylate-based polymerizable compositions and adhesive systems prepared therefrom, which include a alkylated borohydride or tetraalkyl borane metal or ammonium salt and a polymerizable siloxane. The inventive compositions and adhesive systems are particularly well suited for bonding applications which involve at least one low energy bonding surface, for example, the polyolefins, polyethylene, and polypropylene.Type: GrantFiled: July 28, 2008Date of Patent: April 17, 2012Assignee: Loctite (R&D) LimitedInventors: Brendan J. Kneafsey, Edward P. Scott
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Publication number: 20120041162Abstract: [Object] An object of the present invention is to provide a method for producing an olefin polymer, with which an olefin polymer having good particle properties can be produced in high activity, contamination inside the polymerization vessel, such as a vessel wall or an impeller, can be effectively prevented, and a long-term stable operation is achieved. [Means for Achieving the Object] A method for producing an olefin polymer according to the present invention is characterized by including (co)polymerizing at least one olefin selected from the group consisting of ethylene and ?-olefins having 3 to 20 carbon atoms in a polymerization vessel in the presence of (A) a solid catalyst component for olefin polymerization, (B) an aliphatic amide, and (C) an organoaluminum compound.Type: ApplicationFiled: April 21, 2010Publication date: February 16, 2012Inventors: Yasushi Tohi, Ken Yoshitsugu, Naoya Akiyama, Toshio Fujita, Masatoshi Chinaka
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Patent number: 7960486Abstract: The purpose of the present invention is provite a process for producing an olefin polymer, which can produce an olefin polymer having a higher molecular weight even in the presence of hydrogen and can obtain an olefin polymer having good powder characteristics by lowering hydrogen concentration efficiently in polymerizing an olefin in the presence of hydrogen by use of a gas phase reaction vessel. There is provided a process for producing an olefin polymer comprising the steps of: using a gas phase reaction vessel; polymerizing an olefin by use of a catalyst for olefin polymerization in the presence of hydrogen; adding a hydrogenation catalyst into the gas phase reaction vessel; and adding a polymerization activity depressant.Type: GrantFiled: August 3, 2009Date of Patent: June 14, 2011Assignee: Sumitomo Chemical Company, LimitedInventors: Yuki Aso, Noriyuki Satou, Shin-ichi Kumamoto
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Publication number: 20110130531Abstract: Methods for gas phase olefin polymerization are provided. The method can include combining a spray dried catalyst system with a diluent to produce a catalyst slurry. The catalyst system can include a metallocene compound. Ethylene, a continuity additive, and the catalyst slurry can be introduced to a gas phase fluidized bed reactor. The reactor can be operated at conditions sufficient to produce a polyethylene. The spray dried catalyst system can have a catalyst productivity of at least 12,000 grams polyethylene per gram of the catalyst system.Type: ApplicationFiled: December 22, 2010Publication date: June 2, 2011Inventors: F. David Hussein, Kevin J. Cann, Ann M. Schoeb-Wolters, Phuong A. Cao, Bruce J. Savatsky, Eric J. Markel, Daniel P. Zilker, JR., Garth R. Giesbrecht
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Patent number: 7932330Abstract: A process for producing a modified particle, which comprises the step of contacting a compound (a) defined by the formula, M1L13, a compound (b) defined by the formula, R1t-1TH, a compound (c) or (e) defined by the formula, R2m-uM2(OH)u or R24-nJ(OH)n, respectively, and a particle (d) with one another; a carrier comprising a modified particle produced by said process; a catalyst component (A) comprising a modified particle produced by said process; a process for producing a catalyst for addition polymerization, which comprises the step of contacting said catalyst component (A), a transition metal compound (B) and an optional organoaluminum compound (C) with one another; and a process for producing an addition polymer, which comprises the step of addition polymerizing an addition-polymerizable monomer in the presence of a catalyst for addition polymerization produced by said process.Type: GrantFiled: April 7, 2008Date of Patent: April 26, 2011Assignee: Sumitomo Chemical Company, LimitedInventors: Hideki Oshima, Makoto Satoh
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Publication number: 20110082268Abstract: A modified Ziegler-Natta catalyst system, a method for preparing the catalyst system, and a process for polymerizing an olefin in the presence of the catalyst system are disclosed. The catalyst system comprises a titanium or vanadium compound, an aluminum compound, and an indazole. Improved comonomer incorporation and the ability to regulate molecular weight are achieved in the manufacture of polyolefins.Type: ApplicationFiled: October 2, 2009Publication date: April 7, 2011Inventors: Sandor Nagy, Joachim T.M. Pater, Giampiero Morini
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Publication number: 20110082230Abstract: A procedure for improved temperature control in controlled radical polymerization processes is disclosed. The procedure is directed at controlling the concentration of the persistent radical in ATRP and NMP polymerizations procedures and the concentration of radicals in a RAFT polymerization process by feeding a reducing agent or radical precursor continuously or intermittently to the reaction medium through one of more ports.Type: ApplicationFiled: December 18, 2009Publication date: April 7, 2011Inventors: Wojciech Jakubowski, James Spanswick
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Publication number: 20110082269Abstract: A modified Ziegler-Natta catalyst system, a method for preparing the catalyst system, and a process for polymerizing an olefin in the presence of the catalyst system are disclosed. The catalyst system comprises a titanium compound, an aluminum compound, and a nitroso compound. Improved polyolefin properties, such as high molecular weight, are obtained.Type: ApplicationFiled: October 2, 2009Publication date: April 7, 2011Inventors: Sandor Nagy, Joachim T.M. Pater, Giampiero Morini
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Publication number: 20110082270Abstract: A modified Ziegler-Natta catalyst system, a method for preparing the catalyst system, and a process for polymerizing an olefin in the presence of the catalyst system are disclosed. The catalyst system comprises a titanium or vanadium compound, an aluminum compound, and a pyridazine. Improved properties such as increased molecular weight and narrowed molecular weight distribution are obtained.Type: ApplicationFiled: October 2, 2009Publication date: April 7, 2011Inventors: Sandor Nagy, Joachim T.M. Pater, Giampiero Morini
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Patent number: 7919569Abstract: The present invention relates to a process for the polymerization of olefins, comprising the steps of introducing at least one olefin, at least one polymerization catalyst, at least one cocatalyst and at least one cocatalyst aid, and optionally a scavenger, into a polymerization reactor, and polymerizing the olefin, wherein the cocatalyst aid is a reaction product prepared separately prior to the introduction into the reactor by reacting at least one metal alkyl compound of group IIA or IIIA of the periodic system of elements and at least one compound (A) of the formula RmXR?n, wherein R is a branched, straight, or cyclic, substituted or unsubstituted, hydrocarbon group having 1 to 30 carbon atoms, R? is hydrogen or any functional group with at least one active hydrogen, X is at least one heteroatom selected from the group of O, N, P or S or a combination thereof, and wherein n and m are each at least 1 and are such that the formula has no net charge.Type: GrantFiled: May 12, 2006Date of Patent: April 5, 2011Assignee: Saudi Basic Industries CorporationInventors: Wei Xu, Vugar O. Aliyev, Sirajudeen Mohamed, Atieh Abu-Raqabah
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Patent number: 7897707Abstract: A composition useful for activating catalysts for olefin polymerization is provided. The composition is derived from at least: carrier; organoaluminoxy compound; N,N-dimethylaniline and pentaflurophenol in amounts such that them are at least two equivalents of pentafluorophenol per equivalent of the N,N-dimethylaniline.Type: GrantFiled: July 2, 2007Date of Patent: March 1, 2011Assignee: Albemarle CorporationInventors: Lubin Luo, Zhike Wang, Steven P. Diefenbach
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Patent number: 7871952Abstract: A modified Ziegler-Natta catalyst system, a method for preparing the catalyst system, and a process for polymerizing an olefin in the presence of the catalyst system are disclosed. The catalyst system comprises a titanium or vanadium compound, an aluminum compound, and a 2-hydroxypyridine N-oxide. Improved properties such as increased molecular weight are obtained.Type: GrantFiled: October 2, 2009Date of Patent: January 18, 2011Assignee: Equistar Chemicals, LPInventors: Sandor Nagy, Joachim T. M. Pater, Giampiero Morini
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Publication number: 20100216956Abstract: Compositions and polydiene production processes involving catalyst systems comprising at least one lanthanide-containing compound, at least one alkylating agent, at least one halogen source, and at least one N,N-dihydrocarbylhydroxylamine.Type: ApplicationFiled: February 23, 2009Publication date: August 26, 2010Inventors: Steven Luo, Jason T. Poulton, Daniel F. Graves
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Patent number: 7741417Abstract: A process for polymerizing propylene is provided. The process comprises contacting propylene and optionally one or more monomers with a catalyst system comprising a bis-indenyl Group 4 metallocene compound supported on silica, the silica treated with one or more organoaluminum compounds and one or more heterocyclic compounds, under slurry conditions in the presence of hydrogen at a temperature of about 50° C. to about 160° C. and a pressure of from about 3 MPa to about 5 MPa to provide a catalyst activity of greater than 30,000 pounds of product per pound of catalyst; and then recovering isotactic polypropylene having a melt flow rate of 20 dg/min or less as measured according to ASTM D-1238 at 230° C. and 2.16 kg.Type: GrantFiled: August 31, 2006Date of Patent: June 22, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Gary L. Casty, Evan J. Piland
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Patent number: 7732540Abstract: A process for producing an olefin copolymerization catalyst, comprising the step of contacting, with one another, (A) a solid catalyst component containing a titanium atom, a magnesium atom and a halogen atom, (B) an organoaluminum compound and/or organoaluminumoxy compound, and (C) a nitrogen-containing aromatic heterocyclic compound, whose one or more carbon atoms adjacent to its nitrogen atom are linked to an electron-withdrawing group, or a group containing an electron-withdrawing group; and a process for producing an olefin copolymer using the an olefin copolymerization catalyst.Type: GrantFiled: November 26, 2007Date of Patent: June 8, 2010Assignee: Sumitomo Chemical Company, LimitedInventors: Shinya Nakahara, Shin-ichi Kumamoto
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Patent number: 7732543Abstract: Curable compositions contain (i) a free radical polymerizable organosilicon monomer, oligomer or polymer; (ii) an organoborane amine complex; optionally (iii) an amine reactive compound having amine reactive groups; and optionally (iv) a component capable of generating a gas when mixed with a compound bearing active hydrogen and a catalyst. The curable compositions can be used as a rubber, tape, adhesive, foam, pressure sensitive adhesive, protective coating, thin film, thermoplastic monolithic molded part, thermosetting monolithic molded part, sealant, gasket, seal, or o-ring, die attachment adhesive, lid sealant, encapsulant, potting compound, or conformal coating. The compositions can also be used in composite articles of manufacture such as integrally bonded device including electrical and electronic connectors and scuba diving masks, in which substrates are coated or bonded together with the composition and cured.Type: GrantFiled: December 13, 2005Date of Patent: June 8, 2010Assignee: Dow Corning CorporationInventors: Cheryl Lynn Loch, Dongchan Ahn, Nick Evan Shephard, James Steven Tonge, Patricia Ann Olney
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Patent number: 7714084Abstract: Cobaloxime derivatives and methods of producing cobaloxime derivatives are disclosed herein. Methods of producing decolorized homo- and co-polymers through polymerization of monomers in presence of the cobaloxime derivatives and decolorization of the produced polymer by exposing the polymer to a sorbent and, optionally, a solvent are also disclosed herein.Type: GrantFiled: November 9, 2006Date of Patent: May 11, 2010Assignee: E.I. du Pont de Nemours and CompanyInventors: Gregory A. Nikiforov, Alexei A. Gridnev
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Publication number: 20100029873Abstract: The present application relates to a new catalyst system for the polymerization of olefins, comprising a new ionic activator having the formula: [R1R2R3AH]+ [Y]?, wherein [Y]? is a non-coordinating anion (NCA), A is nitrogen or phosphorus, R1 and R2 are hydrocarbyl groups or heteroatom-containing hydrocarbyl groups and together form a first, 3- to 10-membered non-aromatic ring with A, wherein any number of adjacent ring members may optionally be members of at least one second, aromatic or aliphatic ring or aliphatic and/or aromatic ring system of two or more rings, wherein said at least one second ring or ring system is fused to said first ring, and wherein any atom of the first and/or at least one second ring or ring system is a carbon atom or a heteroatom and may be substituted independently by one or more substituents selected from the group consisting of a hydrogen atom, halogen atom, C1 to C10 alkyl, C5 to C15 aryl, C6 to C25 arylalkyl, and C6 to C25 alkylaryl, and R3 is a hydrogen atom or C1 to C10 alkyType: ApplicationFiled: August 1, 2008Publication date: February 4, 2010Inventors: Donna J. Crowther, Peijun Jiang, George Rodriguez
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Patent number: 7642324Abstract: Ligands, compositions, and metal-ligand complexes that incorporate heterocycle-amine compounds are disclosed that are useful in the catalysis of transformations such as the polymerization of monomers into polymers. The catalyst have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, propylene or styrene. The catalysts also polymerize propylene to form isotactic polypropylene.Type: GrantFiled: April 29, 2008Date of Patent: January 5, 2010Assignee: Symyx Solutions, Inc.Inventors: Gary M. Diamond, Anne M. LaPointe, Margarete K. Leclerc, James Longmire, Victor Nava-Salgado, James A. W. Shoemaker, Pu Sun
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Patent number: 7642216Abstract: Ligands, compositions, and metal-ligand complexes that incorporate heterocycle-amine compounds are disclosed that are useful in the catalysis of transformations such as the polymerization of monomers into polymers. The catalyst have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, propylene or styrene. The catalysts also polymerize propylene to form isotactic polypropylene.Type: GrantFiled: April 29, 2008Date of Patent: January 5, 2010Assignee: Symyx Solutions, Inc.Inventors: Gary M. Diamond, Anne M. LaPointe, Margarete K. Leclerc, James Longmire, Victor Nava-Salgado, James A. W. Shoemaker, Pu Sun
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Patent number: 7605215Abstract: A process for producing an olefin copolymerization catalyst, comprising the step of contacting, with one another, (A) a solid catalyst component containing a titanium atom, a magnesium atom and a halogen atom, (B) an organoaluminum compound and/or organoaluminumoxy compound, and (C) a nitrogen-containing aromatic heterocyclic compound, whose one or more carbon atoms adjacent to its nitrogen atom are linked to an electron-donating group, or a group containing an electron-donating group; and a process for producing an olefin copolymer using the an olefin copolymerization catalyst.Type: GrantFiled: November 26, 2007Date of Patent: October 20, 2009Assignee: Sumitomo Chemical Company, LimitedInventors: Shinya Nakahara, Shin-ichi Kumamoto
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Patent number: 7598200Abstract: The present invention discloses a method for preparing an heterogeniseded catalyst component comprising the steps of: a) providing a halogenated precursor component of formula (I) —X—[—CH2]—CH3 b) reacting the halogenated precursor with an ionic liquid precursor in a solvent to prepare an ionic liquid; IL+X? c) optionally, reacting the intermediate IL+X? with a salt C+A?, wherein C+ is a cation that can be selected from K+, Na+, NH4+, and A? is an anion that can be selected from PF6?, SbF6?, BF4?, (CF3—SO2)2N?CIO4—, CF3SO3?, NO3— or CF3CO2?.Type: GrantFiled: March 1, 2005Date of Patent: October 6, 2009Assignee: Total Petrochemicals Research FeluyInventors: Olivier Lavastre, Fabien Bonnette, Abbas Razavi
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Patent number: 7547751Abstract: The invention related to a process for the polymerization of at least one aliphatic C2-20 or aromatic C4-20 hydrocarbyl mono- or multiolefin in the presence of a catalyst and an aluminum comprising co-catalyst, wherein the catalyst comprises a composition of a metal-organic reagent, a spectator ligand and optionally at least one equivalent of a hydrocarbylating agent. The invention further relates to a polymer obtainable by the process of the invention.Type: GrantFiled: August 3, 2004Date of Patent: June 16, 2009Assignee: DSM IP Assets B.V.Inventors: Edwin IJpeij, Henricus Arts, Gerardus van Doremaele, Felix Beijer, Francis van der Burgt, Martin Zuideveld
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Patent number: 7473746Abstract: A process for polymerizing unsaturated monomers is disclosed. The process comprises polymerizing, in the presence of a late transition metal catalyst (LTMC), a variety of unsaturated monomers which are traditionally, some of which are exclusively, made by free radical polymerizations. The LTMC polymerization provides the polymer with improved properties such as no free radical residue and narrow molecular weight distribution.Type: GrantFiled: February 24, 2005Date of Patent: January 6, 2009Assignee: Equistar Chemicals, LPInventors: Jia-Chu Liu, Shao-Hua Guo
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Publication number: 20080319148Abstract: A process for producing a modified particle, which comprises the step of contacting a compound (a) defined by the formula, M1L13, a compound (b) defined by the formula, R1t-1TH, a compound (c) or (e) defined by the formula, R2m-uM2(OH)u or R24-nJ(OH)n, respectively, and a particle (d) with one another; a carrier comprising a modified particle produced by said process; a catalyst component (A) comprising a modified particle produced by said process; a process for producing a catalyst for addition polymerization, which comprises the step of contacting said catalyst component (A), a transition metal compound (B) and an optional organoaluminum compound (C) with one another; and a process for producing an addition polymer, which comprises the step of addition polymerizing an addition-polymerizable monomer in the presence of a catalyst for addition polymerization produced by said process.Type: ApplicationFiled: April 7, 2008Publication date: December 25, 2008Inventors: Hideki Oshima, Makoto Satoh
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Publication number: 20080287618Abstract: The present invention discloses articles having excellent dimensional stability, solid state mechanical properties and barrier properties that are produced with a polyethylene resin prepared with a catalyst system based on a bridged bisindenyl ligand.Type: ApplicationFiled: November 18, 2005Publication date: November 20, 2008Applicant: Total Petrochemicals Research FeluyInventor: Eric Maziers
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Patent number: 7408012Abstract: This invention relates to (meth)acrylate-based polymerizable compositions and adhesive systems prepared therefrom, which include a alkylated borohydride or tetraalkyl borane metal or ammonium salt and a polymerizable siloxane. The inventive compositions and adhesive systems are particularly well suited for bonding applications which involve at least one low energy bonding surface, for example, the polyolefins, polyethylene, and polypropylene.Type: GrantFiled: April 18, 2005Date of Patent: August 5, 2008Assignee: Loctite (R&D) LimitedInventors: Brendan J. Kneafsey, Edward P. Scott