Abstract: Polymerization of a mono-.alpha.-olefine monomer is effected by contacting the gaseous monomer with a solid phase comprising polymer and catalyst at a pressure and temperature which are such that the temperature is in the range from tp + 0.1.degree. C up to tp + 5.0.degree. C, where tp is the temperature at which the monomer condenses at a pressure which is equal to the monomer partial pressure within the polymerization vessel.
Abstract: Alpha olefins are polymerized alone or in admixture at comparatively low pressures to produce polymers employing a two-component catalyst wherein one component is an organozinc or organomagnesium compound, e.g. zinc diethyl, magnesium diphenyl, propyl magnesium chloride, etc. The other component is a salt, oxide or hydroxide of a metal of Group IV-B, V-B or VI-B of the Periodic System, including thorium and uranium.
Type:
Grant
Filed:
July 1, 1958
Date of Patent:
December 13, 1977
Assignee:
Studiengesellschaft Kohle m.b.H.
Inventors:
Karl Ziegler, deceased, Heinz Breil, Erhard Holzkamp, Heinz Martin
Abstract: Novel amorphous copolymers of mono-olefins or of mono-olefins and non-conjugated dienes with unsaturated derivatives of imides are disclosed. These copolymers containing from 99.9 to 80% by weight of non-polar units derived from at least two mono-olefins containing 2 to 18 carbon atoms, particularly ethylene and propene or ethylene and butene-1, and possibly one or more non-conjugated dienes, and from 0.1 to 20% units derived from an imide having the formula ##STR1## wherein Z is an alkenyl radical containing 2 to 16 carbon atoms, andA designates a saturated or unsaturated divalent hydrocarbon radical which contains 2 to 12 carbon atoms and which may possibly carry amino, halogeno or carboxyl groups.Some of said copolymers may be used as polymer additives in lubricating compounds to improve their viscosity index and to disperse the slurry which they may contain.
Type:
Grant
Filed:
December 3, 1975
Date of Patent:
December 13, 1977
Assignee:
Societe Nationale Elf Aquitaine (SNEA)
Inventors:
Gilbert Marie, Andre Lang, Gilbert Chapelet