Fluorine Containing Monomer Contains Nitrogen Atom Patents (Class 526/248)
  • Patent number: 8110336
    Abstract: A resin comprising a structural unit represented by the formula (I): wherein Q1 and Q2 represent a fluorine atom etc., U represents a C1-C20 divalent hydrocarbon group in which one or more —CH2— may be replaced by —O— etc., X1 represents —O—CO— etc., and A+ represents an organic counter ion.
    Type: Grant
    Filed: September 18, 2009
    Date of Patent: February 7, 2012
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Ichiki Takemoto, Nobuo Ando
  • Patent number: 8071704
    Abstract: Provided are surface modified contact lenses formed from one or more fumaric- or itaconic-containing prepolymers having reactive functionality that is complimentary to surface modifying polymers.
    Type: Grant
    Filed: September 30, 2008
    Date of Patent: December 6, 2011
    Assignee: Bausch & Lomb Incorporated
    Inventors: Weihong Lang, Yu-Chin Lai
  • Patent number: 8071687
    Abstract: This invention relates to an adhesive comprising a polymer composition comprising at least 50 mol % of one or more C3 to C40 olefins where the polymer composition has (a) a Dot T-Peel of 1 Newton or more on Kraft paper; (b) an Mw of at least 7000 to 80,000; (c) a branching index (g?) of from 0.4 to 0.90 measured at the Mz of the polymer composition; (d) a heat of fusion of 1 to 70 J/g; and (e) a heptane insoluble fraction of 70 weight % or less, based upon the weight of the polymer composition, where the heptane insoluble fraction has branching index g? of 0.9 or less as measured at the Mz of the polymer composition.
    Type: Grant
    Filed: August 2, 2007
    Date of Patent: December 6, 2011
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Peijun Jiang, Armenag Hagop Dekmezian, Jo Ann Marie Canich, Charles Lewis Sims, Ramin Abhari, Cesar Alberto Garcia-Franco, David Raymond Johnsrud
  • Patent number: 8034532
    Abstract: A topcoat material for application on top of a photoresist material is disclosed. The topcoat material comprises an acid-inert compound. The topcoat material also comprises a polymer or an oligomer or a cage structure which shows negligible intermixing with the imaging layer and is soluble in aqueous base developer. A method of forming a patterned material layer on a substrate and a coated substrate comprising the topcoat material is also disclosed.
    Type: Grant
    Filed: April 28, 2006
    Date of Patent: October 11, 2011
    Assignee: International Business Machines Corporation
    Inventors: Robert David Allen, Phillip Joe Brock, Carl E. Larson, Ratnam Sooriyakumaran, Linda Karin Sundberg, Hoa D Truong
  • Publication number: 20110244247
    Abstract: An intermediate transfer media, such as a belt, that includes a fluoropolyimide polymer.
    Type: Application
    Filed: March 30, 2010
    Publication date: October 6, 2011
    Applicant: XEROX CORPORATION
    Inventors: Jin Wu, Yu Qi, Nan-Xing Hu, Yuhua Tong
  • Publication number: 20110190404
    Abstract: The invention relates to a fluorocarbon polymer material comprising a backbone with the following unit: wherein: Z is a quaternary ammonium group, Y1 and Y2 are each independently an oxygen heteroatom or a sulphur heteroatom, A is a fluorinated or perfluorinated straight chain having from 2 to 6 carbon atoms, R1 represents a phenyl or aryl group or a —CR2R3— group, and R4 is selected from the group consisting of a hydrogen atom, a straight or branched, cyclic or acyclic, alkyl or halogenated alkyl group, and a group represented by the following formula: m is an integer comprised between 0 and 10, preferably between 0 and 3; m?, n and r are integers, each independently equal to 0 or 1; and s is equal to 0 or 1, provided that when s is equal to 0, then R4 is different from the hydrogen atom.
    Type: Application
    Filed: February 2, 2011
    Publication date: August 4, 2011
    Applicants: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, ECOLE NATIONALE SUPERIEURE DE CHIMIE DE MONTPELLIER
    Inventors: Audrey MARTINENT, Ali ALAAEDDINE, Bruno AMEDURI, Philippe CAPRON
  • Patent number: 7956124
    Abstract: A composition which provides surface effects to substrates comprising a polymer containing at least one urea linkage prepared by (i) reacting (1) at least one organic diioscyanate, polyisocyanate, or mixture thereof, and (2) at least one fluorochemical compound of Formula I Rf—O(CF2CF2)r(CH2CH2)q(R1)sXH??Formula (I) ?wherein Rf is a linear or branched C1 to C7 perfluoroalkyl optionally interrupted by one to three oxygen atoms, r is 1 to 3, q is 1 to 3, s is 0 or 1, X is O, S, or NR2 wherein R2 is H, or C1 to C6 alkyl, and R1 is a divalent radical selected from —S(CH2)n—, p is 1 to 50, and R3, R4 and R5 are each independently H or C1 to C6 alkyl; (ii) and then reacting with (3) water, a linking agent, or a mixture thereof.
    Type: Grant
    Filed: November 20, 2008
    Date of Patent: June 7, 2011
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Sheng Peng, Stephen James Getty, Timothy Edward Hopkins, Ying Wang
  • Patent number: 7947791
    Abstract: The present invention provides a fluorinated polymer excellent in the crosslinking reactivity, crosslinked rubber physical properties and chemical resistance, and its crosslinked rubber. A fluorinated polymer comprising repeating units (a) based on at least one monomer selected from the group consisting of ethylenic unsaturated compounds each having a hydroxyphenyl group, repeating units (b) based on at least one fluoromonomer selected from the group consisting of tetrafluoroethylene, hexafluoropropylene, vinylidene fluoride, 3,3,3-trifluoropropene, 1,3,3,3-tetrafluoropropene, 1,1,2-trifluoroethylene, vinyl fluoride, 1,2-difluoroethylene and CF2?CF—O—Rf (wherein Rf is a C1-8 saturated perfluoroalkyl group or a perfluoro(alkoxyalkyl) group) and, if necessary, repeating units (c) based on at least one hydrocarbon monomer selected from the group consisting of ethylene, propylene and CH2?CH—O—R1.
    Type: Grant
    Filed: March 19, 2009
    Date of Patent: May 24, 2011
    Assignee: Asahi Glass Company, Limited
    Inventors: Jumpei Nomura, Toshikazu Yoneda, Mitsuru Seki, Hiroki Kamiya, Hiroshi Funaki, Takehiro Kose
  • Publication number: 20110108814
    Abstract: An object of the invention is to provide a polymer compound having a high hole transport capacity, excellent in electrochemical stability, and suitable to film formation according to a wet film formation method. Another object of the invention is to provide an organic electroluminescence element having a high current efficiency, a low drive voltage, and a long derive lifetime. The polymer compound has a crosslinking group bonding to the arylamine moiety in the repeating unit via at least one single bond therebetween.
    Type: Application
    Filed: April 1, 2009
    Publication date: May 12, 2011
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Koichiro Iida, Kyoko Endo, Yanjun Li, Kazuki Okabe, Masayoshi Yabe
  • Publication number: 20110095165
    Abstract: Disclosed herein are polymeric molds that can be used to make molded articles. The polymeric molds are made from cyclic olefin polymers that may be formed by ring opening metathesis polymerization (ROMP) of a polycyclic monomer having two or more reactive double bonds and a cyclic monomer comprising one reactive double bond. Fluorinated monomers may be used. The polymeric molds may be structured molds in that they have at least one microstructured feature having a dimension of less than about 2 mm, or less than about 500 um. The polymeric molds may also have a plurality of such microstructured features. Also disclosed herein are methods of making the polymeric molds, methods of making molded articles therefrom, and the molded articles.
    Type: Application
    Filed: April 28, 2009
    Publication date: April 28, 2011
    Inventors: Joseph D. Rule, Kevin M. Lewandowski
  • Patent number: 7858540
    Abstract: Ballistic resistant fabrics and articles that retain superior ballistic resistance performance after exposure to liquids such as sea water and organic solvents, such as gasoline and other petroleum-based products. The fabrics are formed from high performance fibers coated with a nitrile rubber binder polymer having an acrylonitrile content of from about 15 wt. % to about 50 wt. %, and are optionally coated with a binder that is a blend of a nitrile rubber and a fluorine-containing material.
    Type: Grant
    Filed: December 21, 2007
    Date of Patent: December 28, 2010
    Assignee: Honeywell International Inc.
    Inventors: Henry G. Ardiff, Ashok Bhatnagar, David A. Hurst, Brian D. Arvidson, Lori L. Wagner
  • Patent number: 7833690
    Abstract: The present invention relates to photoacid generating compounds, lithographic resists comprising photoacid generating compounds, and to various lithographic processes techniques, and applications.
    Type: Grant
    Filed: October 6, 2006
    Date of Patent: November 16, 2010
    Assignee: The University of North Carolina at Charlotte
    Inventors: Kenneth E. Gonsalves, Mingxing Wang
  • Publication number: 20100248324
    Abstract: A functional TFE copolymer fine powder is described, wherein the TFE copolymer is a polymer of TFE and at least one functional comonomer, and wherein the TFE copolymer has functional groups that are pendant to the polymer chain. The functional TFE copolymer fine powder resin is paste extrudable and expandable. Methods for making the functional TFE copolymer are also described. The expanded functional TFE copolymer material may be post-reacted after expansion.
    Type: Application
    Filed: March 24, 2009
    Publication date: September 30, 2010
    Inventors: Ping Xu, Jack J. Hegenbarth, Xin Kang Chen
  • Publication number: 20100233419
    Abstract: A composition comprising a copolymer having repeating units in any sequence of Formula I wherein Rf is a straight or branched perfluoroalkyl group having from about 1 to about 20 carbon atoms, or a mixture thereof, which is optionally interrupted by at least one oxygen atom, X3 is oxygen or X1, each X1 is independently an organic divalent linking group having from about 1 to about 20 carbon atoms, optionally containing an oxygen, nitrogen, or sulfur, or a combination thereof, G is F or CF3, A is an amide, j is zero or positive integer, X2 is an organic linking group, Y is O, N or S, h is zero when Y is N, and h is one when Y is O or S, Z is H, a straight or branched alkyl group having from about 1 to about 4 carbon atoms, or halide, B is H or wherein Rf, X1, X3, G, A, and j are as defined above, provided that when B is H, j is a positive integer, m is a positive integer, q is zero or a positive integer when Y is O, and q is a positive integer when Y is N or S, p is zero or a positive integer
    Type: Application
    Filed: May 26, 2010
    Publication date: September 16, 2010
    Applicant: E.I.DU PONT DE NEMOURS AND COMPANY
    Inventor: Weiming Qiu
  • Publication number: 20100221971
    Abstract: Disclosed is a water-repellent/oil-repellent agent which is composed of a fluorine-containing polymer containing a repeating unit (A) derived from a fluorine-containing monomer having a fluoroalkyl group or a fluoroalkenyl group, and a repeating unit (B) derived from a monomer having an imide group at a weight ratio of from 10/90 to 95/5 (repeating unit (A)/repeating unit (B)). Also disclosed is a thermoplastic resin composition which is obtained by adding such a water-repellent/oil-repellent agent into a thermoplastic resin. Since the fluorine-containing polymer is improved in heat resistance, the water-repellent/oil-repellent agent is capable of imparting a wide range of thermoplastic resins with excellent water repellency and oil repellency.
    Type: Application
    Filed: January 22, 2007
    Publication date: September 2, 2010
    Applicant: DAIKIN INDUSTRIES, LTD.
    Inventors: Kouji Kubota, Norimasa Uesugi
  • Patent number: 7771743
    Abstract: A family of infection resistant and biocidal polymeric materials incorporates an infection resistant biguanide such as chlorhexidine or polyhexanide pendant to the polymer chain, chemically linked to the polymer through the biguanide group secondary nitrogen atoms. The disclosure extends to the use of such polymeric materials in articles of manufacture and particularly in medical devices, and the preparation of the materials as polymer resins from which articles can be made, as solutions and emulsions which can be used for coating performed articles, and in situ on the surface of preformed polymeric articles.
    Type: Grant
    Filed: April 28, 2000
    Date of Patent: August 10, 2010
    Assignee: BioInteractions, Ltd.
    Inventors: Ajay Kumar Luthra, Shivpal Singh Sandhu
  • Patent number: 7754624
    Abstract: Fluoroalkyl amidoalkyl alcohols of the formula are disclosed and their corresponding (meth)acrylate esters. These fluoroalkyl amidoalkyl (meth)acrylate monomers can be copolymerized with a wide variety of conventional ethylenically unsaturated monomers. The resulting copolymers are useful as water, oil- and grease-proofing agents for paper, textiles and hard surfaces such as masonry and wood.
    Type: Grant
    Filed: June 18, 2007
    Date of Patent: July 13, 2010
    Inventor: Shobha Kantamneni
  • Patent number: 7754838
    Abstract: A composition comprising a copolymer having repeating units in any sequence of Formula I wherein Rf is a straight or branched perfluoroalkyl group having from about 1 to about 20 carbon atoms, or a mixture thereof, which is optionally interrupted by at least one oxygen atom, X3 is oxygen or X1, each X1 is independently an organic divalent linking group having from about 1 to about 20 carbon atoms, optionally containing an oxygen, nitrogen, or sulfur, or a combination thereof, G is F or CF3, A is an amide, j is zero or positive integer, X2 is an organic linking group, Y is O, N or S, h is zero when Y is N, and h is one when Y is O or S, Z is H, a straight or branched alkyl group having from about 1 to about 4 carbon atoms, or halide, B is H or wherein Rf, X1, X3, G, A, and j are as defined above, provided that when B is H, j is a positive integer, m is a positive integer, q is zero or a positive integer when Y is O, and q is a positive integer when Y is N or S, p is zero or a positive integer
    Type: Grant
    Filed: August 8, 2006
    Date of Patent: July 13, 2010
    Assignee: E.I. du Pont de Nemours and Company
    Inventor: Weiming Qiu
  • Patent number: 7754795
    Abstract: A coating composition having (i) an aqueous dispersion of fluoropolymer particles comprising a non-melt processible polymer of tetrafluoroethylene, (ii) a fluorinated surfactant, (iii) a non-ionic non-fluorinated surfactant and (iv) a non-fluorinated polymer, wherein the fluorinated surfactant is selected from fluorinated carboxylic acids or salts thereof of the general formula (I): [Rf—O-L-COO?]iXi+??(I) wherein L represents a linear partially or fully fluorinated alkylene group or an aliphatic hydrocarbon group, Rf represents a linear partially or fully fluorinated aliphatic group or a linear partially or fully fluorinated aliphatic group interrupted with one or more oxygen atoms, Xi+ represents a cation having the valence i and i is 1, 2 or 3.
    Type: Grant
    Filed: May 25, 2006
    Date of Patent: July 13, 2010
    Assignee: 3M Innovative Properties Company
    Inventors: Klaus Hintzer, Michael Jürgens, Harald Kaspar, Herbert Koenigsmann, Kai Helmut Lochhaas, Andreas R. Maurer, Werner Schwertfeger, Tilman Zipplies, Ludwig Mayer, Michael C. Dadalas, George G. I. Moore, Jay F. Schulz, Richard M. Flynn
  • Patent number: 7754917
    Abstract: Fluoroalkyl amidoalkyl alcohols of the formula are disclosed and their corresponding (meth)acrylate esters. These fluoroalkyl amidoalkyl (meth)acrylate monomers can be copolymerized with a wide variety of conventional ethylenically unsaturated monomers. The resulting copolymers are useful as water, oil- and grease-proofing agents for paper, textiles and hard surfaces such as masonry and wood.
    Type: Grant
    Filed: June 18, 2007
    Date of Patent: July 13, 2010
    Assignee: Huntsman International LLC
    Inventor: Shobha Kantamneni
  • Patent number: 7728087
    Abstract: A method for polymerizing, in an aqueous medium, at least one fluorinated monomer in the presence of a non-copolymerizable, non-fluorinated surfactant. The surfactant is generally selected from a non-ionic surfactant, a primary anionic surfactant, or a combination thereof. Fluorinated surfactants are not utilized. The resulting partially fluorinated polymer in the aqueous medium is either a semi-crystalline polymer or a crystalline polymer.
    Type: Grant
    Filed: December 23, 2005
    Date of Patent: June 1, 2010
    Assignee: 3M Innovative Properties Company
    Inventors: Klaus Hintzer, Harald Kaspar, Helmut Traunspurger, Tilman Zipplies
  • Publication number: 20100130690
    Abstract: A PTFE resin does not require the hot coining method and is more difficult to deform than conventional PTFE resins. A polytetrafluoroethylene molded body is obtained from a crosslinking polytetrafluoroethylene that possesses at least one type of reactive functional group selected from the group that comprises cyano group (—CN), a first functional group and a second functional group. The first functional group is represented by: The second functional group is represented by (where R1 and R2 are independently selected from a hydrogen atom, a halogen atom, —OR3, —N(R3)2, and —R3, and where R3 is an alkyl group of from 1 to 10 carbon atoms that optionally contains fluorine or hydrogen atoms). The polytetrafluoroethylene substantially does not flow even when heated up to or above its melting point, and is baked after it is compression molded.
    Type: Application
    Filed: October 31, 2006
    Publication date: May 27, 2010
    Applicant: DAIKIN INDUSTRIES, LTD.
    Inventors: Yoshinori Nanba, Meiten Koh
  • Publication number: 20100099804
    Abstract: Disclosed herein are polymer compounds, a method for preparing thereof. More specifically, provided are polymer compounds with well-connected, narrow size distribution free-volume element and a method for preparing the polymer compounds by thermal rearrangement for aromatic polyimides containing ortho-positioned functional groups in the solid state.
    Type: Application
    Filed: October 10, 2008
    Publication date: April 22, 2010
    Applicant: Industry-University Cooperation Foundation, HANYANG UNIVERSITY
    Inventors: Young-Moo LEE, Ho-Bum Park, Chul-Ho Jung, Sang-Hoon Han
  • Publication number: 20100060834
    Abstract: The present invention relates to a novel polyimide copolymer, a method of preparing the polyimide copolymer, a liquid crystal aligning layer including the polyimide copolymer, a method of producing the liquid crystal aligning layer, and a liquid crystal display including the liquid crystal aligning layer. The liquid crystal aligning layer that includes the polyimide copolymer according to the present invention is advantageous in that when ultraviolet rays are radiated on movable chains of the polyamic acid copolymer to perform alignment before a polyimide copolymer is imidized and heat treatment is then performed to conduct imidization, thermal stability is excellent, residual images are not formed, and alignment of liquid crystals is excellent.
    Type: Application
    Filed: January 7, 2008
    Publication date: March 11, 2010
    Inventors: Xing-Zhong Fang, Kyung-Jun Kim, Byung-Hyun Lee, Jung-Ho Jo, Dong-Hyun Oh, Wan-Hee Goh, Sang-Kook Kim, Hye-Ran Seong, Hye-Won Jeong, Yun-Jeong Lee
  • Publication number: 20100047660
    Abstract: Featured are novel heterocycle substituted hydroquinones, aromatic copolymers and homopolymers bearing main and side chain polar pyridine units. These polymers exhibit good mechanical properties, high thermal and oxidative stability, high doping ability and high conductivity values. These novel polymers can be used in the preparation and application of MEA on PEMFC type single cells. The combination of the above mentioned properties indicate the potential of the newly prepared materials to be used as electrolytes in high temperature PEM fuel cells.
    Type: Application
    Filed: August 24, 2009
    Publication date: February 25, 2010
    Inventors: Maria Geormezi, Nora Gourdoupi
  • Patent number: 7666949
    Abstract: A curative composition comprising a cation and an anion of the formula Anq?Qpm+, wherein m, n, p, and q are positive integers, wherein m*p=n*q, wherein Qm+ is an organo onium, and Aq? is an anion, provided that at least one Aq? is selected from the formula: wherein each R independently is H, halo, alkyl, aryl, aralkyl, or cycloalkyl, and which also may be halogenated, fluorinated, or perfluorinated, wherein two or more of R and R? groups may together form a ring, wherein each R group independently may contain one or more heteroatom(s), wherein R? can be the same as R, with the proviso that R? cannot be halo. Also provided are a fluoropolymer composition including this curative, a method of making a fluoropolymer, and fluoropolymer articles containing curable or cured fluoropolymer compositions.
    Type: Grant
    Filed: June 13, 2008
    Date of Patent: February 23, 2010
    Assignee: 3M Innovative Properties Company
    Inventors: Werner M. A. Grootaert, Eric W. Adair, Miguel A. Guerra
  • Patent number: 7638575
    Abstract: Disclosed is a surface treating agent containing fluorine-containing polymer having: (A) a repeating unit derived from a fluorine-containing compound which is represented by the following formula: CH2?C(—X)—C(?O)—Y—[—(CH2)m-Z-]p—(CH2)n-Rf??(I) (wherein X is a hydrogen atom or a methyl group), (B) a repeating unit derived from a monomer containing no fluorine atom, if necessary and (C) a repeating unit derived from a crosslinkable monomer, if necessary. This surface treating agent has excellent water repellency, oil repellency and antifouling property.
    Type: Grant
    Filed: March 25, 2005
    Date of Patent: December 29, 2009
    Assignee: Daikin Industries, Ltd.
    Inventors: Ikuo Yamamoto, Yutaka Ohira, Yoshio Funakoshi, Shinichi Minami
  • Patent number: 7635527
    Abstract: A polymer light emitting material, wherein the material has a light emitting mechanism based on transition from an excited triplet state to a ground state or transition through an excited triplet state to a ground state of an electron energy level, and the material comprises a nonionic light emitting part which constitutes a part of the polymer or is bound to the polymer. The polymer light emitting material exhibits high light emission efficiency above 5%, which is the limit of external quantum efficiency of fluorescence and can be designed so as to have a large area and hence are suitable for mass production of organic light emitting devices.
    Type: Grant
    Filed: February 6, 2008
    Date of Patent: December 22, 2009
    Assignee: Showa Denko K.K.
    Inventors: Masataka Takeuchi, Shuichi Naijo, Naoko Ito, Koro Shirane, Takeshi Igarashi, Yoshiaki Takahashi, Motoaki Kamachi
  • Patent number: 7632903
    Abstract: Crosslinked polymeric materials are described that contain pendant amine capture groups. The amine capture groups include N-sulfonylaminocarbonyl groups that can react with amine-containing materials by a nucleophilic displacement reaction. Reaction mixtures used to prepare the crosslinked polymeric materials, articles containing the crosslinked polymeric materials, methods of making articles, and methods of immobilizing an amine-containing material are also described.
    Type: Grant
    Filed: April 30, 2009
    Date of Patent: December 15, 2009
    Assignee: 3M Innovative Properties Company
    Inventors: Charles M. Leir, George G. I. Moore, Rahul R. Shah, Karl E. Benson
  • Publication number: 20090269587
    Abstract: Provided herein are the polymers shown below. The value n is a positive integer. R1 is an organic group, and each R2 is H or a chemisorbed group, with at least one R2 being a chemisorbed group. The polymer may be a nanostructured film. Also provided herein is a method of: converting a di-p-xylylene paracyclophane dimer to a reactive vapor of monomers; depositing the reactive vapor onto a substrate held at an angle relative to the vapor flux to form nanostructured poly(p-xylylene) film; reacting the film with an agent to form hydrogen atoms that are reactive with a precursor of a chemisorbed group, if the film does not contain the hydrogen atoms; and reacting the hydrogen atoms with the precursor. Also provided herein is a device having a nanostructured poly(p-xylylene) film on a pivotable substrate. The film has directional hydrophobic or oleophobic properties and directional adhesive properties.
    Type: Application
    Filed: April 28, 2009
    Publication date: October 29, 2009
    Applicant: The Government of the United States of America, as represented by the Secretary of the Navy
    Inventors: Walter J. Dressick, Melik C. Demirel, Alok Singh
  • Patent number: 7560517
    Abstract: The present invention relates to a fluoropolymer comprising repeating units derived from one or more gaseous fluorinated olefins and having one or more cure sites comprising (a) a halogen capable of participating in a peroxide cure reaction or (b) a nitrile group, said fluoropolymer further comprising repeating units derived from one or more fluorinated allyl ethers of the formula: CF2?CF—CF(Z)—O—Rf??(I) wherein Z represents F or CF3 and Rf represents a fluorinated alkyl group that may contain one or more catenary oxygen atoms. The fluoropolymer can be cured to a fluoroelastomer. The invention also relates to a curable fluoroelastomer composition comprising the fluoropolymer and a curing agent.
    Type: Grant
    Filed: November 16, 2005
    Date of Patent: July 14, 2009
    Assignee: 3M Innovative Properties Company
    Inventors: Klaus Hintzer, Michael Jurgens, Harald Kaspar, Kai Helmut Lochhaas, Werner Schwertfeger
  • Publication number: 20090163105
    Abstract: Ballistic resistant fabrics and articles that retain superior ballistic resistance performance after exposure to liquids such as sea water and organic solvents, such as gasoline and other petroleum-based products. The fabrics are formed from high performance fibers coated with a nitrile rubber binder polymer having an acrylonitrile content of from about 15 wt. % to about 50 wt. %, and are optionally coated with a binder that is a blend of a nitrile rubber and a fluorine-containing material.
    Type: Application
    Filed: December 21, 2007
    Publication date: June 25, 2009
    Inventors: Henry G. Ardiff, Ashok Bhatnagar, David A. Hurst, Brian D. Arvidson, Loril Wagner
  • Patent number: 7544754
    Abstract: Crosslinked polymeric materials are described that contain pendant amine capture groups. The amine capture groups include N-sulfonylaminocarbonyl groups that can react with amine-containing materials by a nucleophilic displacement reaction. Reaction mixtures used to prepare the crosslinked polymeric materials, articles containing the crosslinked polymeric materials, methods of making articles, and methods of immobilizing an amine-containing material are also described.
    Type: Grant
    Filed: September 30, 2005
    Date of Patent: June 9, 2009
    Assignee: 3M Innovative Properties Company
    Inventors: Charles M. Leir, George G. I. Moore, Rahul R. Shah, Karl E. Benson
  • Patent number: 7544751
    Abstract: Polymerization products formed from a monomeric mixture comprising (a) one or more first monomers of the general formula I: A-L-R1—(X—CF?CF2)n??(I) wherein R1 represents one or more inertly substituted groups; X is independently a group which links the inertly substituted groups and the trifluorovinyl group; L is an optional linking group; A is CO2Z, SO2Z, PO3Z, or OPO3Z wherein Z is hydrogen or an alkali metal and n is an integer of 1 to about 1000; (b) one or more second crosslinking monomers comprising at least three trifluorovinyl groups and (c) one or more prepolymers comprising one or more trifluorovinyl groups are provided. Also provided are biomedical devices formed from such polymerization products.
    Type: Grant
    Filed: July 28, 2008
    Date of Patent: June 9, 2009
    Assignee: Bausch & Lomb Incorporated
    Inventors: Derek Schorzman, Joseph C. Salamone
  • Publication number: 20090093602
    Abstract: A process for the polymerization of a true tetrafluoroethylene (TFE) copolymer of the fine powder type is provided, wherein the copolymer contains polymerized comonomer units of at least one comonomer other than TFE in concentrations of at least or exceeding 1.0 weight percent, and which can exceed 5.0 weight percent, wherein the copolymer is expandable, that is, the copolymer may be expanded to produce strong, useful, expanded TFE copolymeric articles having a microstructure of nodes interconnected by fibrils.
    Type: Application
    Filed: October 4, 2007
    Publication date: April 9, 2009
    Inventor: Lawrence A. Ford
  • Publication number: 20090092655
    Abstract: Provided are surface modified contact lenses formed from one or more fumaric- or itaconic-containing prepolymers having reactive functionality that is complimentary to surface modifying polymers.
    Type: Application
    Filed: September 30, 2008
    Publication date: April 9, 2009
    Inventors: Weihong Lang, Yu-Chin Lai
  • Publication number: 20090061353
    Abstract: Disclosed is a fluorine-containing polymer compound containing first and second repeating units respectively represented by formulas (a-1) and (a-2), wherein R3 represents a fluorine atom or fluorine-containing alkyl group, each of W and W1 independently represents a bivalent linking group, R2 represents an acid-labile protecting group, each of R4, R5 and R6 independently represents a hydrogen atom, fluorine atom or monovalent organic group, and at least two of R4, R5, R6 and W or W1 may be combined to form a cyclic structure in formula (a-1) or (a-2). This polymer compound has a weight-average molecular weight of 1,000 to 1,000,000 and can provide a resist composition capable of forming a pattern with no swelling and no pattern falling down.
    Type: Application
    Filed: August 28, 2008
    Publication date: March 5, 2009
    Applicant: CENTRAL GLASS COMPANY, LIMITED
    Inventors: Yoshimi ISONO, Jonathan Joachim JODRY, Satoru NARIZUKA, Kazuhiro YAMANAKA
  • Patent number: 7479530
    Abstract: A polymer comprising one or more macromonomer units selected from the group consisting of polysiloxane, perfluoroalkylpolyether (PFPE), fluorinated poly(meth)acrylate, polyalkyl (meth)acrylate, polyolefin and fluorinated polyolefin, and one or more charged units (such as an anionic, cationic or zwitter-ionic monomer), formed from a polymerization medium containing an aqueous solution of charged units and use of this polymer as an intraocular lens for the implantation into or onto the cornea. Another aspects relates to a process for coating the above polymer with an adhesive comprising covalently coupling co-reactive surface functional groups of a natural or synthetic polymer with functional groups present (or introduced) on the surface of the macromonomer containing polymer, followed by covalently coupling a multifunctionally activated compound having at least one functional group that is co-reactive to the reactive groups of the natural or synthetic polymer.
    Type: Grant
    Filed: May 21, 2003
    Date of Patent: January 20, 2009
    Assignee: Commonwealth Scientific and Industrial Research Organisation
    Inventors: Timothy Charles Hughes, Grace Yim Ngan Chan
  • Patent number: 7473748
    Abstract: A superacidic ester group is useful in the production of ionomers for polymer electrolyte fuel cells. A polymer is produced from said vinyl monomer. A process produces a polymer containing a superacidic group. The vinyl monomer contains a haloalkyl ester group of a superacid, wherein the number of carbon atoms of the haloalkyl ester group is no more than 10, and the halogen in the haloalkyl group is chlorine and/or fluorine. A polymer containing said vinyl monomer as a repeating unit can be converted to a polymer containing a superacid group using at least one procedure of 1) heat treating at 50°C. to 350°C., and 2) contacting with a protic compound.
    Type: Grant
    Filed: January 21, 2005
    Date of Patent: January 6, 2009
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventors: Nobuto Hoshi, Nobuyuki Uematsu, Oliver Gronwald, Takehiro Koga, Masanori Ikeda
  • Patent number: 7470745
    Abstract: A composition which provides surface effects to substrates comprising a polymer containing at least one urea linkage prepared by (i) reacting (1) at least one organic diioscyanate, polyisocyanate, or mixture thereof, and (2) at least one fluorochemical compound of Formula I Rf—O(CF2CF2)r(CH2CH2)q(R1)sXH??Formula (I) wherein Rf is a linear or branched C1 to C7 perfluoroalkyl optionally interrupted by one to three oxygen atoms, r is 1 to 3, q is 1 to 3, s is 0 or 1, X is O, S, or NR2 wherein R2 is H, or C1 to C6 alkyl, and R1 is a divalent radical selected from —S(CH2)n—, p is 1 to 50, and R3, R4 and R5 are each independently H or C1 to C6 alkyl; (ii) and then reacting with (3) water, a linking agent, or a mixture thereof.
    Type: Grant
    Filed: November 13, 2006
    Date of Patent: December 30, 2008
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Sheng Peng, Stephen James Getty, Timothy Edward Hopkins, Ying Wang
  • Publication number: 20080293888
    Abstract: A diamine compound of formula (I) is proposed as well as polymers, copolymers, polyamic acids, polyamic acid esters, or polyimides based on such compound.
    Type: Application
    Filed: December 19, 2006
    Publication date: November 27, 2008
    Applicant: ROLIC AG
    Inventors: Thomas Bachels, Zoubair Mohammed Cherkaoui, Guy Marck, Olivier Muller, Joachim Reichardt, Andreas Schuster, Hubert Seiberle, Peggy Studer, Thomas Peglow, Jean-Francois Eckert
  • Publication number: 20080281065
    Abstract: The present invention provides a fluoropolymer capable of giving fluorine-containing molded materials and laminates excellent in moldability, productivity, interlaminar bonding and stress cracking resistance, in particular stress cracking resistance upon contacting with various liquid chemicals, without impairing such characteristics intrinsic in fluororesins as chemical resistance, solvent resistance, weathering resistance, antifouling properties, liquid chemical impermeability and nonstickiness. The present invention provides a fluoropolymer which is an oligomer-containing or oligomer-free fluoropolymer, wherein said oligomer has a molecular weight not higher than 10,000 and amounts to not more than 0.05% by mass relative to the fluoropolymer.
    Type: Application
    Filed: July 18, 2008
    Publication date: November 13, 2008
    Applicant: DAIKIN INDUSTRIES, LTD.
    Inventors: Takahiro KITAHARA, Tomohiro Kino, Megumi Sato, Eiji Fujita
  • Patent number: 7435785
    Abstract: Provided is a method of manufacturing a perhalogenated elastomer comprising using an onium compound to coagulate a latex comprising polymer particles, the polymer particles consisting essentially of interpolymerized units of one or more perhalogenated comonomer(s) and at least one cure site monomer, wherein the coagulation is performed essentially free of metal ions and metal salts. Also provided is an elastomeric composition comprising a curable perhalogenated elastomer comprising interpolymerized units derived from a nitrogen-containing cure site monomer and coagulated with an onium compound, wherein the elastomer is capable of curing without adding further components and wherein the composition is essentially free of metal ions and metal salts. Also provided are fluoropolymer articles and methods of making fluoropolymer compositions and articles.
    Type: Grant
    Filed: October 23, 2007
    Date of Patent: October 14, 2008
    Assignee: 3M Innovative Properties Company
    Inventors: Guy Van Gool, Alain Verschuere, Werner M. A. Grootaert
  • Patent number: 7435498
    Abstract: A method is provided for making a crosslinked polymer electrolyte, typically in the form of a membrane for use as a polymer electrolyte membrane in an electrolytic cell such as a fuel cell, by trimerization of nitrile groups contained on groups pendant from the polymer. The resulting polymer electrolyte membrane comprises a highly fluorinated polymer comprising: a perfluorinated backbone, first pendent groups which comprise sulfonic acid groups, and crosslinks comprising trivalent groups according to the formula: The first pendent groups are typically according to the formula: —R1—SO3H, where R1 is a branched or unbranched perfluoroalkyl or perfluoroether group comprising 1-15 carbon atoms and 0-4 oxygen atoms, most typically —O—CF2—CF2—CF2—CF2—SO3H or —O—CF2—CF(CF3)—O—CF2—CF2—SO3H.
    Type: Grant
    Filed: May 22, 2006
    Date of Patent: October 14, 2008
    Assignee: 3M Innovative Properties Company
    Inventors: Michael A. Yandrasits, Steven J. Hamrock, Werner M. Grootaert, Miguel A. Guerra, Naiyong Jing
  • Patent number: 7425600
    Abstract: Polymerization products formed from a monomeric mixture comprising (a) one or more first monomers of the general formula I: A-L-R1—(X—CF?CF2)n??(I) wherein R1 represents one or more inertly substituted groups; X is independently a group which links the inertly substituted groups and the trifluorovinyl group; L is an optional linking group; A is CO2Z, SO2Z, PO3Z, or OPO3Z wherein Z is hydrogen or an alkali metal and n is an integer of 1 to about 1000; (b) one or more second crosslinking monomers comprising at least three trifluorovinyl groups and (c) one or more prepolymers comprising one or more trifluorovinyl groups are provided. Also provided are biomedical devices formed from such polymerization products.
    Type: Grant
    Filed: July 1, 2005
    Date of Patent: September 16, 2008
    Assignee: Bausch & Lomb Incorporated
    Inventors: Derek Schorzman, Joseph C. Salamone
  • Patent number: 7304115
    Abstract: Provided is a method of manufacturing a perhalogenated elastomer comprising using an onium compound to coagulate a latex comprising polymer particles, the polymer particles consisting essentially of interpolymerized units of one or more perhalogenated comonomer(s) and at least one cure site monomer, wherein the coagulation is performed essentially free of metal ions and metal salts. Also provided is an elastomeric composition comprising a curable perhalogenated elastomer comprising interpolymerized units derived from a nitrogen-containing cure site monomer and coagulated with an onium compound, wherein the elastomer is capable of curing without adding further components and wherein the composition is essentially free of metal ions and metal salts. Also provided are fluoropolymer articles and methods of making fluoropolymer compositions and articles.
    Type: Grant
    Filed: December 29, 2004
    Date of Patent: December 4, 2007
    Assignee: 3M Innovative Properties Company
    Inventors: Guy Van Gool, Alain Verschuere, Werner M. A. Grootaert
  • Patent number: 7300985
    Abstract: A fluoropolymer having pendant amidoxime groups, pendant amidrazone groups, or combinations thereof is provided. Also provided are methods of making such fluoropolymers, and compositions and articles containing such fluoropolymers.
    Type: Grant
    Filed: December 21, 2004
    Date of Patent: November 27, 2007
    Assignee: 3M Innovative Properties Company
    Inventors: Werner M. A. Grootaert, Klaus Hintzer, Kai Helmut Lochhaas, Franz Maerz
  • Patent number: 7271228
    Abstract: Ionic perfluorovinyl compounds and their uses as components of ionic conductors of the polymer type, of selective membranes or of catalysts. The compounds comprise at least one perfluorovinyl group and at least one group chosen from —O or one of the groups C?N, —C(C?N)2, —NSO2R or —C[SO2R]2 or a pentacyclic group comprising at least one N, C—C?N, CR, CCOR or CSO2R group. The compounds and/or their polymers are of use in the preparation of ionically conducting materials, electrolytes and selective membranes.
    Type: Grant
    Filed: January 12, 2005
    Date of Patent: September 18, 2007
    Assignees: ACEP Inc., Centre National de la Recherche Scientifique, Universite de Montreal
    Inventors: Michel Armand, Christophe Michot
  • Patent number: 7253241
    Abstract: In one aspect, the invention provides a water-based release coating composition comprising a mixture of (A.) from about 5 to about 100 wt % of a polymer comprising the reaction product of (a.) from 1 to about 15 wt % of a fluorinated monomer selected from the group consisting of monomers according to the general formula: RfX—OC(O)—C(R)?CH2, wherein Rf represents a perfluorinated aliphatic group having 3 or 4 carbon atoms, X is an organic divalent linking group, and R represents a hydrogen or methyl group, (b.) from about 40 to about 70 wt % of an alkyl (meth)acrylate, wherein the alkyl group contains from 16 to 22 carbon atoms, (c.) from about 3 to about 20 wt % of (meth)acrylic acid, (d.) from about 20 to about 40 wt % acrylonitrile, and (e.) from 0 to about 15 wt % of vinyl monomer, other than acrylonitrile, wherein the sum of (a.) through (e.) equals 100%; and (B.) from 0 to about 95 wt % of an extender polymer, wherein the sum of (A.) and (B.
    Type: Grant
    Filed: December 28, 2004
    Date of Patent: August 7, 2007
    Assignee: 3M Innovative Properties Company
    Inventors: James P. DiZio, David J. Kinning, George G. I. Moore
  • Patent number: 7247691
    Abstract: Fluoroalkyl amidoalkyl alcohols of the formula are disclosed and their corresponding (meth)acrylate esters. These fluoroalkyl amidoalkyl (meth)acrylate monomers can be copolymerized with a wide variety of conventional ethylenically unsaturated monomers. The resulting copolymers are useful as water, oil- and grease-proofing agents for paper, textiles and hard surfaces such as masonry and wood.
    Type: Grant
    Filed: October 25, 2004
    Date of Patent: July 24, 2007
    Assignee: Huntsman International LLC
    Inventor: Shobha Kantamneni