Abstract: Copolymers comprising perfluoroalkyl groups, reproduction layers containing these copolymers and use thereof for waterless offset printing. The novel perfluoroalkyl group-containing copolymers are prepared from at least two different monomers, monomer (a) comprising acryloyl or methacryloyl groups and phenolic OH groups and monomer (b) comprising acryloyloxy, methacryloyloxy or vinyl groups and a perfluoroalkyl group. Monomer component (a) can, for example, be prepared from a hydroxybenzoic acid by esterification with a hydroxyalkyl-acrylate. The novel copolymers are, in particular, used as binders in radiation-sensitive reproduction layers which additionally contain at least one radiation-sensitive compound. Reproduction layers of this kind are used as radiation-sensitive coatings of support materials for printing plates used in waterless offset printing.

Abstract: This invention relates to polymeric additives useful for inhibition of the deposit of paraffins and improvement of the flow properties of crude oils and to compositions containing crude oils and such additives. The polymeric additive according to the invention consists of a polymer formed by units derived from one or more alkyl esters of unsaturated monocarboxylic acids, one or more unsaturated alpha, beta-dicarboxylic compounds in the form of diacids, low alkyl diesters or anhydrides and one or more monomers having ethylenic unsaturation of the general formula CH.sub.2 .dbd.CZ.sub.1 Z.sub.2, in which Z.sub.1 and Z.sub.2 are the same or different and represent hydrogen, a halogen, a saturated, unsaturated or aromatic hydrocarbon group or an ester or ether group. Compounds containing a crude oil and 5 to 4000 ppm and preferably 100 to 1500 ppm of the additive have much improved flow properties.

Abstract: Derivatives of diphenylhexafluoropropane having the formula: ##STR1## where R is an unsubstituted or substituted alkylene, an epoxy, a silyl or alkoxysilyl group; and where X and Y are hydrogen or halogen. The derivatives are useful in formulating polymer structures.

Abstract: An ionizing radiation sensitive resist consisting essentially of a polymer having a recurring unit represented by the following formula: ##STR1## wherein X is a hydrogen atom, a methyl group, or a halogen atom and R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5, which may be identical or different, are hydrogen atoms, halogen atoms, alkyl groups having 1 to 3 carbon atoms, alkoxy groups having 1 to 3 carbon atoms, haloalkyl groups having 1 to 3 carbon atoms or haloalkoxy groups having 1 to 3 carbon atoms, at least a part of the X groups present in said polymer being a halogen atom, at least a part of the Y.sup.1 and Y.sup.2 group present in said polymer being a halogen atom, and at least a part of the R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 groups present in said polymer being a haloalkyl or haloalkoxy group having 1 to 3 carbon atoms. Said ionizing radiation sensitive resist is suitable as a negative type resist.

Abstract: Peroxide-curable fluorocarbon elastomers having interpolymerized units derived from a cure site monomer containing bromine or iodine. The fluorocarbon elastomer gums are prepared by copolymerizing with the principal monomers normally used in preparing fluorocarbon elastomers, e.g. vinylidene fluoride, hexafluoropropene, and (optionally) tetrafluoroethylene, a small amount of a novel cure site monomer which is a vinyl ether in which at least one of the two vinylic (or double-bonded) carbon atoms thereof is bonded to at least one bromine or iodine atom, e.g. CF.sub.3 CH.sub.2 OCF.dbd.CFBr. The cured fluorocarbon elastomers of this invention have useful properties normally associated with fluorocarbon elastomers, such as acid resistance, thermal stability, and high tensile strength. These properties of shaped articles made from these fluorocarbon elastomers are not adversely affected upon exposure to high temperatures for extended periods.

Abstract: A homopolymer or copolymer which contains, as a monomer unit, at least one styrene of the formula ##STR1## in which R.sup.1, R.sup.2 and R.sup.3 independently of one another denote hydrogen, fluorine or partly or completely fluorinated alkyl or alkoxy andR.sup.4 and R.sup.5 independently of one another represent hydrogen or fluoride, the total number of fluorine atoms in the radicals R.sup.1 to R.sup.5 being at least 3 and the total number of carbon atoms in the radicals R.sup.1 to R.sup.3 being at most 8. The homo- or copolymers can be prepared by vinyl polymerization. They are useful as lenses or other components in an optical system where they have a refractive index n.sub.D of 1.42 to 1.55 with an Abbe number v.sub.D of 30 to 50.

Abstract: Alkyl methacrylate polymers which have one or more hydroxyhydrocarbyl end groups and a process for making them employing an anionic initiator followed by hydrolysis. The polyfunctional polymers are useful in automobile powder finishes and the monofunctional polymers are useful in polymer blends.

Abstract: A water soluble addition copolymer is formed by reaction admixing a monomer having a pendant vinyl group attached to at least one ring structure selected from the group consisting of nitrogen containing heterocyclic ring structures and aromatic ring structures and their mixtures, and a monomer selected from the group consisting of maleic anhydride, fumaronitrile, tetracyanoethylene, maleimide and their mixtures, where such addition copolymer can be used alone, as curable an insulating coating composition, or can be added to a resin, to form a curable resinous insulating coating composition.

Abstract: The method and production of macromolecular monomers from cationically polymerizable monomers and vinyl-substituted hydrocarbon halides is disclosed. These cationically polymerizable monomers may react in the presence of a catalyst with the hydrocarbon halide to produce a macromer retaining a polymerizable headgroup. This compound may be used in a variety of copolymerization processes with a variety of copolymerizable monomers to form graft copolymers.

Abstract: A novel contact lens having improved gas permeability is disclosed which is formed from copolymerizing a mixture comprising:(a) a group 1 monomer which is a styrene or substituted styrene monomer, and(b) a group 2 monomer which is a monomer of the general formula: ##STR1## wherein R is hydrogen, methyl, ethyl, and R' is an alkyl, or a monomer of the general formula: ##STR2## wherein n is 0 or 1, R is hydrogen, methyl or ethyl and R" is hydrogen when n is 0 and hydrogen or hydroxyl when n is 1.

Abstract: Polymers of compounds having the formula ##STR1## wherein n and m are, individually, 0 or 1, X is an anion, R.sup.1 is hydrogen, methyl or phenyl and R.sup.2, R.sup.3 and R.sup.4 are, individually, hydrogen, alkyl, aryl, alkaryl or aralkyl, and methods for their production, are disclosed.

Abstract: Organosulfur molecular weight regulators for emulsion polymerization systems, such as mercaptan compounds, are mixed and agitated with the aqueous emulsifier prior to use in emulsion polymerization systems. The modifying efficiency of the organosulfur molecular weight modifiers can be controlled by the degree of agitation. In many cases, adding the agitated mixture incrementally to the emulsion polymerization system further improves effectiveness of the modifier.

Abstract: Ar-halo-ar(t-alkyl)styrenes, e.g., 2-chloro-4-(t-butyl)styrene, polymerize to form materials having unusually high temperature resistance. Additionally, compositions of such monomers, unsaturated polyesters and free-radical generating catalysts cure at lower temperatures and in less time than similar compositions containing conventional styrene monomers.

Abstract: Biocompatible polymeric microspheres having an average diameter below about 3 microns and having density at least 15% greater or lesser than organic cells and having covalent binding sites are provided in accordance with this invention. The microspheres are obtained by copolymerizing a hydroxy or amine substituted acrylic monomer such as hydroxyethylmethacrylate with a light or dense comonomer such as a fluoromonomer. A lectin or antibody is bound to the hydroxy or amine site of the bead to provide cell specificity. When added to a cell suspension the marked bead will specifically label the cell membrane by binding to specific receptor sites thereon. The labelled membrane can then be separated by density gradient centrifugation.

Abstract: Polymers or copolymers of acid anhydride type norbornene derivatives and a method of preparing the same, said polymers or copolymers being formed with a reduced viscosity of 0.1 to 20 by ring-opening polymerization of acid anhydride type norbornene derivatives having at least one carboxylic anhydride group or a mixture of said norbornene derivatives and cycloolefins.