Lactam Monomer Patents (Class 526/264)
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Patent number: 5395905Abstract: The present invention provides water-soluble poylmers containing, as polymerized units: (a) from about 3 to about 95 percent by weight of one or more cyclohexene anhydrides or the alkali metal or ammonium salts thereof. The present further provides aqueous polymerization processes for making the polymers. The water-soluble polymers are useful as water-treatment additives for boiler waters and cooling towers and as detergent additives acting as builders, anti-filming agents, dispersants, sequestering agents and encrustation inhibitors.Type: GrantFiled: January 12, 1993Date of Patent: March 7, 1995Assignee: Rohm and Haas CompanyInventors: Marianne P. Creamer, Thomas F. McCallum, III, Graham Swift, Barry Weinstein
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Patent number: 5393854Abstract: What is provided herein is a colorless, purified polymerizable composition useful for the production of crosslinked polyvinylpyrrolidone. The polymerizable composition includes about 74-96% by weight vinylpyrrolidone monomer and 4-26% by weight of the isomeric compound 1-vinyl-3(E)-ethylidene pyrrolidone as crosslinker. The polymerizable composition is used to make crosslinked polyvinylpyrrolidone rapidly upon heating the composition at about 80.degree.-120.degree. C. in the absence of base.Type: GrantFiled: April 28, 1994Date of Patent: February 28, 1995Assignee: ISP Investments Inc.Inventors: Susan Y. Tseng, Philip F. Wolf
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Patent number: 5393825Abstract: This invention relates to a continuous film, coating, membrane or extruded filament of a crosslinked vinyl lactam polymer having excellent substrate adhesion, a glass transition temperature (Tg) above 150.degree. C. and water repellent properties. The invention also relates to the method of preparing and using filaments, coatings and membranes of said crosslinked polymeric product.Type: GrantFiled: May 13, 1994Date of Patent: February 28, 1995Assignee: ISP Investments Inc.Inventors: Susan Y. Tseng, Philip F. Wolf, William J. Burlant
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Patent number: 5391667Abstract: Crosslinked copolymers of N-vinylpyrrolidone and other n-vinyl-lactam monomers and ethylenically unsaturated monomer having at least one amine or amine-displaceable functionality are utilized for oligomer synthesis. The oligomer of interest is connected to the polymer via a connection to an amine function. A spacer can be included between the amine function and the polymeric backbone.Type: GrantFiled: March 4, 1993Date of Patent: February 21, 1995Assignee: Isis PharmaceuticalsInventor: Douglas J. Dellinger
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Patent number: 5391668Abstract: What is provided herein is a colorless, purified polymerizable composition useful for the production of crosslinked polyvinylpyrrolidone. The polymerizable composition includes about 74-96% by weight vinylpyrrolidone monomer and 4-26% by weight of the isomeric compound 1-vinyl-3(E)-ethylidene pyrrolidone as crosslinker. The polymerizable composition is used to make crosslinked polyvinylpyrrolidone rapidly upon heating the composition at about 80.degree.-120.degree. C. in the absence of base.Type: GrantFiled: May 6, 1993Date of Patent: February 21, 1995Assignee: ISP Investments Inc.Inventors: Susan Y. Tseng, Philip F. Wolf
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Patent number: 5378765Abstract: A polymer useful for preparing shaped articles comprises essentially repeat units of the formula I ##STR1## where R.sup.1 and R.sup.2 are each hydrogen or methyl, andR.sup.3 is C.sub.6 -C.sub.14 -aryl, which may be monosubstituted, disubstituted or trisubstituted by radicals selected from the group consisting of C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy and halogen,and is obtainable by reacting a polymer based on C.sub.1 -C.sub.20 -alkyl esters of metharcylic acid or of arcylic acid or mixtures of such esters with an aromatic amine of the general formula IIR.sup.3 NH.sub.2 IIin the presence of an amine having a pK.sub.b value .ltoreq.9.Type: GrantFiled: November 12, 1993Date of Patent: January 3, 1995Assignee: BASF AktiengesellschaftInventors: Siegmund Besecke, Andreas Deckers, Harald Lauke
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Patent number: 5374662Abstract: Novel fumarate- and fumaramide-containing monomers are disclosed which are especially useful in the preparation of biocompatible devices, especially contact lenses.Type: GrantFiled: March 15, 1993Date of Patent: December 20, 1994Assignee: Bausch & Lomb IncorporatedInventors: Yu-Chin Lai, Ronald E. Bambury
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Patent number: 5374698Abstract: The invention relates to pressure-sensitive adhesive (PSA) structured bead, which has a distinct morphology, which is comprised of a copolymer which is characterized as a two-phase system wherein more rigid, thermoplastic segments (hydrophilic segments formed from the polymerization of water soluble monomer in the water-in-oil emulsion particles) provide discrete reinforcing micro-domains within a predominating continuous matrix formed by rubbery, viscoelastic polymer segments (formed from the polymerization of the ester and the polar monomer). The invention also relates to a method of making the beads via a polymerization of a water-in-oil emulsion in a water suspension.Type: GrantFiled: November 25, 1992Date of Patent: December 20, 1994Assignee: Minnesota Mining and Manufacturing CompanyInventors: Chung I. Young, Ying-Yuh Lu
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Patent number: 5373074Abstract: A free radical solution process for making PVP polymers having a molecular weight corresponding to a K-value of about 30-150, a narrow molecular weight distribution represented by a polydispersity of about 3 to 6, and a residual VP monomer level of less than 0.1%, which comprises:(a) precharging a reaction mixture of vinylpyrrolidone monomer and water in a solids contents w/w VP/H.sub.2 O of about 5-50%, and a dual free radical initiator system which comprises both low and high decomposition temperature free radical initiators whose 10-hour half-life temperature decomposition constants differ from each other by more than 5.degree. C., the low and high temperature initiators being present, respectively, in an amount of about 0.05-0.5%, and about 0.1-0.Type: GrantFiled: February 12, 1993Date of Patent: December 13, 1994Assignee: ISP Investments Inc.Inventors: Chi-San Wu, James F. Curry, James P. Cullen
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Patent number: 5362698Abstract: This invention relates to a process for preparing an improved polymerization free radical initiator delivery system for the polymerization of a monomer containing olefinic unsaturation which comprises uniformly dispersing a water insoluble free radical initiator, an excess amount of the polymeric product of the reaction and between about 1.0 and about 100 wt. % of a surfactant based on initiator in water to form an aqueous mixture containing between about 5 and about 40 wt. % solids; subjecting the dispersion to treatment at a temperature of between about -25.degree. C. and about 0.degree. C. under from about 50 to about 400 milli Tort vacuum for a period of from about 5 to about 24 hours to remove water and to form uniform coprecipitated initiator/polymer microparticles having an average particle diameter of between about 0.Type: GrantFiled: April 8, 1993Date of Patent: November 8, 1994Assignee: ISP Investments Inc.Inventors: Kolazi S. Narayanan, Waldo De Thomas
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Patent number: 5362796Abstract: This invention relates to a moldable crosslinked vinyl lactam polymer composition and to a transparent, formed gel product obtained therefrom having desired flexibility coupled with high mechanical strength and dimensional and thermal stability. The invention also relates to the method of preparing said molded gel products.Type: GrantFiled: August 9, 1993Date of Patent: November 8, 1994Assignee: ISP Investments Inc.Inventors: Susan Y. Tseng, Philip F. Wolf
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Patent number: 5362830Abstract: Crosslinkable copolymers of (a) 80-99% by wt. vinylpyrrolidone (VP) and 1-20% by wt. of a tertiary-amine-containing polymerizable monomer, e.g. vinylimidazole (VI) or 4-vinylpyridine (VPy), and (b) 80-99% by wt. VP and 1-20% by wt. of an epoxide-containing polymerizable monomer, e.g. allyl glycidyl ether (AGE) or glycidyl acrylate (GA), are reacted in solution, e.g. water, alcohol, or mixtures thereof, at a predetermined temperature, e.g. 50.degree.-70.degree. C., in a wt. ratio (solids basis) of (a):(b) of about 2:1 to 1:2, preferably about 1:1, in a solution concentration of about 10-30% of each, to provide a crosslinked PVP product, in gel form, suitable for use as an electrolead on a conductive foilbacking, or for bandages and wound dressings, and as a controlled release media for pharmaceuticals.Type: GrantFiled: September 15, 1993Date of Patent: November 8, 1994Assignee: ISP Investments Inc.Inventors: Jui-Chang Chuang, Jenn S. Shih, Robert B. Login
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Patent number: 5360883Abstract: What is provided herein is a process for obtaining a polymerizable reaction solution which includes 5-30% by weight of a crosslinker which is the isomeric compound 1-vinyl-3(E)-ethylidene pyrrolidone and 50-80% by weight of a monomer which is vinylpyrrolidone. The polymerizable solution can be used to make crosslinked polyvinylpyrrolidone rapidly upon heating the solution at about 80.degree.-120.degree. C. in the absence of base.Type: GrantFiled: March 30, 1993Date of Patent: November 1, 1994Assignee: ISP Investments Inc.Inventors: Susan Y. Tseng, Philip F. Wolf
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Patent number: 5359021Abstract: New high refractive index polymeric compositions and foldable intraocular lenses made from such compositions are disclosed. In one embodiment, the present compositions comprise a copolymer including a major amount of a first constituent derived from a first monomeric component the homopolymers of which have a refractive index of at least about 1.50, a minor amount of a second constituent derived from a second monomeric component other than the first monomeric component the homopolymers of which have a glass transition temperature of less than about 30.degree. C., preferably less than about 22.degree. C., and a third constituent derived from a crosslinking monomeric component in an amount effective to facilitate returning a deformed intraocular lens made of the composition to its original shape.Type: GrantFiled: September 16, 1993Date of Patent: October 25, 1994Assignee: Allergan, Inc.Inventors: Joseph I. Weinschenk, III, F. Richard Christ
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Patent number: 5354823Abstract: This invention relates to a continuous film, coating, membrane or extruded filament of a crosslinked vinyl lactam polymer having excellent substrate adhesion, a glass transition temperature (Tg) above 150.degree. C. and water repellent properties. The invention also relates to the method of preparing and using filaments, coatings and membranes of said crosslinked polymeric product.Type: GrantFiled: August 9, 1993Date of Patent: October 11, 1994Assignee: ISP Investments Inc.Inventors: Susan Y. Tseng, Philip F. Wolf, William J. Burlant
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Patent number: 5346976Abstract: Copolymers useful as contact lens materials are the polymerization product of a mixture comprising:(a) an itaconate;(b) a compound represented by formula (I): ##STR1## wherein: each A is independently an activated unsaturated radical;each R is independently selected from the group consisting of a C.sub.1 -C.sub.12 monovalent hydrocarbon radical, a C.sub.1 -C.sub.12 monovalent hydrocarbon radical containing ether linkages, a halogen-substituted C.sub.1 -C.sub.12 monovalent hydrocarbon radical, and a halogen-substituted C.sub.1 -C.sub.12 monovalent hydrocarbon radical containing ether linkages;each R' is independently a C.sub.1 -C.sub.22 divalent hydrocarbon radical; andn averages about 15 to about 50;(c) an ethylenically unsaturated organosiloxane monomer; and(d) a hydrophilic monomer.Type: GrantFiled: March 29, 1993Date of Patent: September 13, 1994Assignee: Polymer Technology CorporationInventors: Edward J. Ellis, Alfred P. Olson, James A. Bonafini, Jr.
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Patent number: 5338814Abstract: A process for making polyvinylpyrrolidone (PVP) K-90 having a polydispersity of less than 6, preferably less than 5, and most preferably, less than 4, which comprises polymerizing vinylpyrrolidone monomer by free radical solution polymerization, in water, in the presence of polyethylene glycol (PEG) having a molecular weight of about 300 as a chain transfer agent. The product is an aqueous solution of 15-25% PVP K-90, preferably 20%, 15-30% PEG, preferably 25%, and 45-70% water, preferably 55%, by weight of the solution.Type: GrantFiled: April 21, 1993Date of Patent: August 16, 1994Assignee: ISP Investments Inc.Inventors: Chi-San Wu, James F. Curry, James P. Cullen
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Patent number: 5331073Abstract: New high refractive index polymeric compositions and foldable intraocular lenses made from such compositions are disclosed. In one embodiment, the present compositions comprise a copolymer including a major amount of a first constituent derived from a first monomeric component the homopolymers of which have a refractive index of at least about 1.50, a minor amount of a second constituent derived from a second monomeric component other than the first monomeric component the homopolymers of which have a glass transition temperature of less than about 300.degree. C., preferably less than about 220.degree. C., and a third constituent derived from a crosslinking monomeric component in an amount effective to facilitate returning a deformed intraocular lens made of the composition to its original shape.Type: GrantFiled: November 9, 1992Date of Patent: July 19, 1994Assignee: Allergan, Inc.Inventors: Joseph I. Weinschenk, III, F. Richard Christ
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Patent number: 5321110Abstract: What is provided herein are cationic polymer compositions comprising a cationic polymer of strongly swellable, moderately crosslinked vinyl lactam, e.g. vinylpyrrolidone, and a quaternized amino alkyl acrylamido or acrylate, e.g. quaternized dimethylaminopropyl methacrylamide or dimethylaminoethyl methacrylate, optionally including a polymerizable carboxylic acid, e.g. acrylic acid or methacrylic acid, which includes about 0.1-0.8% of a crosslinking agent therein. These polymer compositions, in a concentration of 1-10% by weight in aqueous and non-aqueous medium, provide effective thickener action while imparting cationic characteristics to the resulting solution.Type: GrantFiled: June 29, 1992Date of Patent: June 14, 1994Assignee: ISP Investments Inc.Inventor: Jenn S. Shih
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Patent number: 5319041Abstract: This invention relates to an improved process for producing a clear solution of vinylpyrrolidone (VP) and vinyl acetate (VA) monomers which comprises, in an anhydrous system,(a) reacting a C.sub.2 to C.sub.3 alcoholic solution containing said VA monomer and between about 60 and about 80 wt. % portion of total VP monomer in the presence of between about 0.05 and about 0.3 wt. % of a free radical initiator selected from the group consisting of tertamylperoxy pivalate and 2,2-azobis(2-methylbutyronitrile) or a mixture thereof for a period of from about 5 to about 10 hours, at a temperature between about 60.degree. and about 110.degree. C.;(b) gradually adding the remaining VP monomer in C.sub.2 to C.sub.3 alcohol solution at reaction temperature after the addition of the VA monomer is complete;(c) raising the temperature of the resulting reaction mixture to between about 110.degree. and about 150.degree. C.;(d) continuing the polymerization reaction at said higher temperature in the presence of from about 0.Type: GrantFiled: March 26, 1993Date of Patent: June 7, 1994Assignee: ISP Investments Inc.Inventors: Yuanzhen Zhong, Hemant Parikh, Paul D. Taylor, Terry E. Smith
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Patent number: 5306795Abstract: What is provided herein is a process for making homopolymers of polyvinylpyrrolidone polymer in the form of fine powders at a polymer solids level of at least about 17%, preferably 30% or more, and in a yield of at least about 95%, which comprises precharging a reactor with a predetermined amount of a solvent selected from a C.sub.3 -C.sub.20 alkane, preferably heptane, or a C.sub.3 -C.sub.20 cycloalkane, preferably cyclohexane, and a free radical polymerization initiator, and feeding vinylpyrrolidone monomer into the precharged reactor at a selected rate, preferably about 0.1 to 1.8 g vinylpyrrolidone/min/1000 g of solvent, and most preferably, about 1 g/min/1000 g of cyclohexane and 0.5 g/min/1000 g of heptane, which rates preclude build-up of monomer during the polymerization, and for a feed period which provides the desired level of polymer solids in the reaction product, preferably at least about 200 minutes.Type: GrantFiled: January 31, 1991Date of Patent: April 26, 1994Assignee: ISP Investments Inc.Inventors: Jenn S. Shih, Terry E. Smith
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Patent number: 5302677Abstract: The invention relates to alkenylaminoalkane-1,1-diphosphonic acid derivatives of the formula I ##STR1## in which R.sup.1 to R.sup.5, a, b, and Z have the meaning given in the description and to processes for their preparation. The invention furthermore relates to copolymers comprising 0.1-50 mol %, preferably 1-15 mol %, of at least one alkenylaminoalkane-1,1-diphosphonate unit of the formula I and 99.9-50 mol %, preferably 99-85 mol %, of at least one carboxylic acid unit of the formula IIR.sup.6 R.sup.7 C=CR.sup.8 Y (II)in which R.sup.6, R.sup.7, R.sup.8 and Y have the meaning given in the description and to processes for their preparation. These copolymers are used as scale inhibitors, as alkaline earth metal and heavy metal complexing agents and/or sequestering agents and as builders or co-builders in detergents.Type: GrantFiled: March 26, 1993Date of Patent: April 12, 1994Assignee: Hoechst AktiengesellschaftInventors: Matthias Krull, Christoph Naumann, Herrmann Hoffmann
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Patent number: 5300606Abstract: A liquid absorption agent for water or organic solvents comprising, as a main component, a crosslinked N-vinylcarboxylic acid amide resin comprising the backbone chain of a homopolymer or copolymer comprising repeating units of the formula shown below crosslinked with a crosslinking agent: ##STR1## wherein R.sup.1, R.sup.2, and R.sup.3 independently represent a hydrogen atom or methyl;X represents a group --COOY, wherein Y represents a hydrogen atom, an alkali metal, C.sub.1 -C.sub.6 alkyl, or lower alkyl substituted with hydroxyl, dialkylamino or quaternary ammonium group; a group --CONHZ, wherein Z represents a hydrogen atom or lower alkyl substituted with a dialkylamino group, quaternary ammonium group, sulfonic acid or an alkali metal salt thereof; cyano, 2-ketopyrrolidinyl, lower alkoxy, lower acyl, lower acyloxy or lower alkyl substituted with sulfonic acid or an alkali metal salt thereof, with a proviso that when R.sup.Type: GrantFiled: March 11, 1993Date of Patent: April 5, 1994Assignee: Showa Denko K.K.Inventors: Toshiyuki Aizawa, Hitoshi Nakamura, Yoshikazu Hosoda
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Patent number: 5292844Abstract: The present invention relates to a method of suspension polymerization of a pressure-sensitive acrylate copolymer bead having a glass transition temperature of 0.degree. C. or less which are storage stable in addition to being extrudable at temperature below about 340.degree. F. (171.degree. C.). The method comprises making a monomer-containing premix comprising (i) about 70 to about 98 parts by weight of an acrylic acid ester monomer of non-tertiary alcohol, the alcohol having from 1 to 14 carbon atoms, with the average number of carbon atoms being about 4 to about 12, (ii) about 1 to about 10 parts of a polar monomer copolymerizable with the acrylic acid ester, and (iii) about 1 to about 40 parts vinyl acetate monomer, wherein (i), (ii), and (iii) comprise 100 parts of the monomer-containing premix, (iv) about 0.01 to about 0 5 part by weight chain transfer agent, and (v) about 0.05 to about 1.Type: GrantFiled: June 10, 1993Date of Patent: March 8, 1994Assignee: Minnesota Mining and Manufacturing CompanyInventors: Chung I. Young, Stephen E. Krampe
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Patent number: 5288827Abstract: A new polymer, the feed monomers and molar percents of which, exclusive of a polymerization initiator and crosslinker, are:A.(I) 42 mole % to 58 mole % of a siloxy silane of formula I,(II) 42 mole % to 58 mole % of an unsubstituted alkyl (meth)acrylate of formula II,(III) 0 to 5 mole % of a Group A monomer, and(IV) 0 to 16 mole % of an additional vinylic copolymerizable monomer;B.(I) 42 mole % to 58 mole % of a siloxy silane of formula I,(II) 21 mole % up to less than 42 mole % of an unsubstituted alkyl (meth)acrylate of formula II,(III) 0 to 5 mole % of a Group A monomer, and(IV) 0 to 29 mole % of an additional vinylic copolymerizable monomer, orC.Type: GrantFiled: February 17, 1993Date of Patent: February 22, 1994Assignee: Ciba-Geigy CorporationInventors: Xiaoling Li, Bret Berner
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Patent number: 5286826Abstract: A process for making highly crosslinked polyvinylpyrrolidone (PVP) polymer which has a low swell volume and is white in appearance comprising:(a) heating a reaction mixture comprising vinylpyrrolidone (VP) monomer at a VP concentration of about 70-95%, preferably 75-85%, by weight, in an aqueous basic solution containing about a 0.3-1.5%, preferably a 0.4-0.8% basic content, at a reaction temperature of about 130.degree.-170.degree. C., preferably 135.degree.-145.degree. C., and under an inert gas atmosphere, for a period of time sufficient to generate a crosslinker in situ,(b) diluting the basic reaction solution with water to reduce the VP concentration to about 5-30%, preferably 15-25%, and(c) polymerizing the diluted reaction solution at a polymerization temperature of about 100.degree. C. to provide a crosslinked PVP polymer having a swell volume of <45 ml/10 g.Type: GrantFiled: March 5, 1993Date of Patent: February 15, 1994Assignee: ISP Investments Inc.Inventors: Jenn S. Shih, Susan Y. Tseng
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Patent number: 5283305Abstract: Crosslinkable copolymers of (a) 80-99% by wt. vinylpyrrolidone (VP) and 1-20% by wt. of a tertiary-amine-containing polymerizable monomer, e.g. vinylimidazole (VI) or 4-vinylpyridine (VPy), and (b) 80-99% by wt. VP and 1-20% by wt. of an epoxide-containing polymerizable monomer, e.g. allyl glycidyl ether (AGE) or glycidyl acrylate (GA), are reacted in solution, e.g. water, alcohol, or mixtures thereof, at a predetermined temperature, e.g. 50.degree.-70.degree. C., in a wt. ratio (solids basis) of (a):(b) of about 2:1 to 1:2, preferably about 1:1, in a solution concentration of about 10-30% of each, to provide a crosslinked PVP product, in gel form, suitable for use as an electrolead on a conductive foilbacking, or for bandages and wound dressings, and as a controlled release media for pharmaceuticals.Type: GrantFiled: October 26, 1992Date of Patent: February 1, 1994Assignee: ISP Investments Inc.Inventors: Jui-Chang Chuang, Jenn S. Shih, Robert B. Login
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Patent number: 5275811Abstract: What is provided herein is an improved hair spray resin composition including a terpolymer consisting essentially of a vinyl ester, preferably vinyl acetate, a water-insoluble or water-miscible alkyl maleate half-ester, preferably mono-N-butyl maleate and an N-substituted acrylamide, preferably N-t-butyl acrylamide, N-t-octyl acrylamide or N-[1-(2-pyrrolidonyl)ethyl]acrylamide, in the molar ratio of 1:0.6-0.8:0.08-0.12, respectively, and having a relative viscosity of about 1.2-2.0.Type: GrantFiled: November 2, 1992Date of Patent: January 4, 1994Assignee: ISP Investments Inc.Inventors: Jui-Chang Chuang, Edward W. Walls, Jr.
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Patent number: 5268117Abstract: This invention relates to a glycol based anti-icing fluid containing between about 0.05 and about 5.0 wt. % of 0.2 to 1.0% crosslinked poly(N-vinyl pyrrolidone).Type: GrantFiled: April 26, 1993Date of Patent: December 7, 1993Assignee: ISP Investments Inc.Inventors: Frank Fusiak, Ki-Ho Chung, Thomas C. Bohrer
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Patent number: 5268437Abstract: This invention relates to high temperature aqueous processes for the polymerization of monoethylenically unsaturated carboxylic monomers to produce low molecular weight, water-soluble polymer products useful as detergent additives, scale inhibitors, dispersants and crystal growth modifiers. Suitable monomers include acrylic acid, methacrylic acid, maleic acid, maleic anhydride, crotonic acid, and itaconic acid. The reactions are run at temperatures ranging from about 130.degree. C. to 240.degree. C., preferably from about 140.degree. C. to about 230.degree. C. The process can be continuous, semi-continuous, or batch.Type: GrantFiled: January 22, 1992Date of Patent: December 7, 1993Assignee: Rohm and Haas CompanyInventors: Norman L. Holy, Newman M. Bortnick, Graham Swift, Kathleen A. Hughes
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Patent number: 5262171Abstract: A pharmaceutical tablet is provided herein having an effective dissolution rate. The tablet contains a pharmaceutically-active ingredient and a substantially linear, i.e. non-crosslinked K-30 to K-120 PVP as a binding agent. The PVP used herein is made by an initiated polymerization process in which vinyl pyrrolidone monomer is polymerized in the presence of an initiator which produces a linear PVP polymerization, i.e. is a poor hydrogen abstractor of PVP polymer backbones, which would produce a disadvantageous crosslinked PVP product. Suitable initiators include low energy peroxyester free radical initiators, such as t-amylperoxy pivalate, an azo initiator, or a redox initiator which can perform at low temperatures.Preferably the residual initiator level in the PVP is reduced to less than 500 ppm, thereby further precluding the possibility of crosslinking of the PVP polymer during the shelf-life of the tablet.Type: GrantFiled: November 25, 1991Date of Patent: November 16, 1993Assignee: ISP Investments Inc.Inventors: Robert B. Login, Mohammed Tazi, Jui-Chang Chuang, Rama K. Haldar, Dinesh Jaiswal, Chi-San Wu
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Patent number: 5260391Abstract: A unique tetrapolymer and an additive package for reducing water loss from cement comprising a tetrapolymer, base, and electrolyte, at least one surfactant, and water is disclosed. A process for producing cement slurries with improved water loss properties, as well as an improved method for cementing gas and oil wells is also disclosed.Type: GrantFiled: March 15, 1991Date of Patent: November 9, 1993Inventor: Michael Stephens
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Controlled release tablets including strongly swellable, moderately crosslinked polyvinylpyrrolidone
Patent number: 5252611Abstract: What is described herein is a controlled release, drug-delivery composition which comprises a strongly swellable, moderately crosslinked polyvinylpyrrolidone polymer in the form of fine white powders having a defined aqueous gel volume and Brookfield viscosity which is prepared by precipitation polymerization in the presence of a prescribed amount of crosslinking agent, and an effective amount of a pharmaceutical medicament.Type: GrantFiled: July 20, 1992Date of Patent: October 12, 1993Assignee: ISP Investments Inc.Inventors: Jenn S. Shih, Jui-Chang Chuang, Rama K. Haldar -
Patent number: 5250642Abstract: A composition of a superabsorbent polymer and a process for using the polymer to absorb an aqueous electrolyte solution are disclosed.Type: GrantFiled: May 20, 1992Date of Patent: October 5, 1993Assignee: Phillips Petroleum CompanyInventors: Iqbal Ahmed, Henry L. Hsieh
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Patent number: 5244988Abstract: Copolymers of aliphatic monoethylenically unsaturated dicarboxylic acids and unsaturated monomers have been formed by gradually and simultaneously adding monomers and initiator, in the presence of a metal salt activator, to a reaction vessel initially containing water at a temperature suitable for polymerization. These copolymers have consistent compositions and superior properties as antiscalants, dispersants and incrustation inhibitors.Type: GrantFiled: March 30, 1990Date of Patent: September 14, 1993Assignee: Rohm and Haas CompanyInventors: Kathleen A. Hughes, Graham Swift
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Patent number: 5242985Abstract: What is described herein is a PVP-I.sub.2 composition comprising strongly swellable, lightly crosslinked PVP complex to iodine, wherein said composition is capable of releasing free iodine slowly with time in the presence of water. Preferably the complex has about 10-15% by weight available iodine and about 4-8 weight % iodide, and is a free-flowing, fine, lightly yellow powder.Type: GrantFiled: June 17, 1992Date of Patent: September 7, 1993Assignee: ISP Investments Inc.Inventors: Jenn S. Shih, John J. Merianos
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Patent number: 5236993Abstract: A method of crosslinking polyvinylpyrrolidone (PVP) at a predetermined pH which comprises (a) providing a tertiary amino-functional PVP as a starting material, (b) condensing said starting material with a predetermined amount of epichlorohydrin to form an epichlorohydrin-functional PVP copolymer, and, if less than an equivalent of epichlorohydrin in use, unreacted starting material, (c) acidifying the resultant copolymer to form a solution of a storage stable glycidyl quat intermediate, and (d) increasing the pH of the solution to above 7 to convert the glycidyl quat into a glycidyl epoxide, and (e) crosslinking the glycidyl epoxide with free amine group on the copolymer or as added amine functional PVP copolymer to form a crosslinked PVP polymer.Type: GrantFiled: September 16, 1992Date of Patent: August 17, 1993Assignee: ISP Investments Inc.Inventors: Robert B. Login, Jenn S. Shih, Jui-Chang Chuang
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Patent number: 5212213Abstract: This invention relates to novel radiation-curable, rosin-based resins and the process for preparing them. In particular, the invention relates to unsaturated polyester resins containing fully fumarated rosin and/or fully maleated rosin which have softening points of at least 80.degree. C. and are capable of being flaked into solid chips; a property that make the resins useful in formulating vehicles for lithographic printing inks and other coating applications.Type: GrantFiled: May 20, 1992Date of Patent: May 18, 1993Assignee: Westvaco CorporationInventor: G. Frederick Hutter
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Patent number: 5209924Abstract: A novel topical medicinal composition is described which comprises a copolymer which has both pendant fluorochemical groups and pendant polysiloxane grafts.Type: GrantFiled: September 9, 1991Date of Patent: May 11, 1993Assignee: Minnesota Mining and Manufacturing CompanyInventors: James E. Garbe, Steven S. Kantner, Kanta Kumar, Smarajit Mitra
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Patent number: 5206322Abstract: Crosslinkable, functional polymers of vinylpyrrolidone and aminoalkyl acrylamides are provided herein. Such polymers are readily crosslinked with a crosslinking agent, e.g. a multi-aldehyde, such as a di-, tri- or tetra- aldehyde, preferably, glutaric dialdehyde, to form an aqueous gel of predetermined viscosity suitable for making hydrogels, adhesives and coatings.Type: GrantFiled: May 26, 1992Date of Patent: April 27, 1993Assignee: ISP Investments Inc.Inventors: Robert B. Login, Jenn S. Shih, Jui-Chang Chuang
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Patent number: 5196495Abstract: A hair spray fixative resin comprises a vinyl acetate/alkyl maleate half ester/N-substituted acrylamide terpolymer in a molar ratio of about 1.0 to 0.6-0.8 to 0.08-0.12, which is preferably produced by a suspension or solution polymerization process. Utilizing N-substituted acrylamides in place of isoborneol methacrylates in the terpolymer provides superior holding power over conventional hair fixative resins, at lower cost.Type: GrantFiled: January 25, 1991Date of Patent: March 23, 1993Assignee: ISP Investments Inc.Inventors: Jui-Chang Chuang, Edward W. Walls, Jr., Stephen C. Johnson
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Patent number: 5196491Abstract: This invention relates to a process for the living cationic polymerization of vinylic unsaturated compounds containing electron donating substituents resulting in polymers of narrow molecular weight distribution.Type: GrantFiled: November 25, 1988Date of Patent: March 23, 1993Assignee: E. I. Du Pont de Nemours and CompanyInventors: Chang Cho, Ben-Ami Feit, Owen W. Webster
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Patent number: 5194546Abstract: What is provided herein are copolymers of a vinyl lactam and a hydroxy or amino alkene monomers, which contain a hydroxy or amino functionality therein. These copolymers are prepared by reaction between a vinyl lactam, e.g. vinylpyrrolidone (VP) or vinyl caprolactam (VCL), a functional polymerizable monomer, e.g. .omega.-amino-1-alkene (AA) or .omega.-hydroxy-1-alkene (HA), in water solution in the presence of a free radical initiator under predetermined reaction conditions.Type: GrantFiled: May 6, 1992Date of Patent: March 16, 1993Assignee: ISP Investments Inc.Inventors: Robert B. Login, Jenn S. Shih, Jui-Chang Chuang
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Patent number: 5191043Abstract: What is described herein is a precipitation polymerization process in a reaction mixture of a vinyl lactam, e.g. vinyl pyrrolidone or vinyl caprolactam, and a polymerizable carboxylic acid, e.g. acrylic acid or methacylic acid, in the presence of a polymerization initiator, in a cosolvent mixture of an aliphatic hydrocarbon solvent, particularly, a C.sub.3 -C.sub.10 saturated hydrocarbon, which is branched or unbranched, cyclic or acylic, and preferably, is heptane or cyclohexane and a secondary alochol, preferably isopropanol. The copolymers obtained thereby have an advantageous low molecular weight of less than 20,000.Type: GrantFiled: March 16, 1992Date of Patent: March 2, 1993Assignee: ISP Investments Inc.Inventor: Jenn S. Shih
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Patent number: 5185170Abstract: Ganex.RTM. copolymers in the physical form of flakes or powders is provided herein by a novel process, and used in a personal care composition.Type: GrantFiled: July 10, 1992Date of Patent: February 9, 1993Assignee: ISP Investments Inc.Inventor: Stephen L. Kopolow
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Patent number: 5185418Abstract: A hydrolyzable silyl group-containing azo compound is represented by the following general formula (I): ##STR1## wherein A represents a group originating from an azo compound having one or more active hydrogen groups;R.sup.1 represents a monovalent organic group;R.sup.2 represents a divalent organic group;X represents a hydrolyzable group;Y represents --O--, --S--, ##STR2## m is an integer of 1 to 3; and n is an integer of 1 or 2;and process for producing the same is disclosed. The hydrolyzable silyl group-containing azo compound is used to prepare a hydrolyzable silyl group-containing vinyl polymer produced by polymerizing vinyl monomer as a radical polymerization initiator.Type: GrantFiled: April 3, 1992Date of Patent: February 9, 1993Assignee: Kanegafuchi Kagaku Kogyo Kabushiki KaishaInventors: Hisao Furukawa, Katsuhiko Isayama, Yasushi Kato
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Patent number: 5179184Abstract: The present invention relates to polymerizable cyclic urea derivatives which can be thermally split to give rise to an isocyanate group; and to a polymer having cyclic urea pendant groups, which can be cured by heating without any additional curing agent such as an isocyanate blocked with a volatile lower molecular weight material, so that volatile material is not released in a thermal curing process.Type: GrantFiled: April 10, 1991Date of Patent: January 12, 1993Assignee: Nippon Paint Co., Ltd.Inventors: Noriyuki Tsuboniwa, Satoshi Urano, Hirotoshi Umemoto, Noriyuki Sakamoto, Kenshiro Tobinaga, Yasuyuki Tsuchiya
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Patent number: 5177165Abstract: A new class of polymerizable surfactants, useful for modifying the surfaces of polymeric objects, which are described by the formula:DC[A.sub.x B.sub.y ]wherein A is at least one ethylenically unsaturated hydrophilic monomer, B is at least one ethylenically unsaturated hydrophobic monomer, C is a functional chain transfer agent, D is an ethylenically unsaturated end group, y is within the range from about 0.1 to about 0.9, and x+y=1. Also disclosed are random copolymer precursors of such polymerizable surfactants.Type: GrantFiled: December 11, 1991Date of Patent: January 5, 1993Assignee: Bausch & Lomb IncorporatedInventors: Paul L. Valint, Jr., Joseph A. McGee
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Patent number: 5171807Abstract: Ganex.RTM. copolymers in the physical form of flakes or powders is provided herein by a novel process, and used in a personal care composition.Type: GrantFiled: August 26, 1991Date of Patent: December 15, 1992Assignee: ISP Investments Inc.Inventor: Stephen L. Kopolow
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Patent number: 5171808Abstract: Novel compositions comprising anionic and/or amphoteric organic polymeric microparticles are disclosed, along with a method for their production. The products are useful in flocculating a wide variety of dispersions of suspended solids and in paper-making.Type: GrantFiled: July 22, 1991Date of Patent: December 15, 1992Assignee: American Cyanamid CompanyInventors: Roderick G. Ryles, Dan S. Honig, Elieth W. Harris, Roger E. Neff