Abstract: The invention provides a coating composition for an optical element, such as an ophthalmic lens. The coating composition includes a relatively rigid multifunctional monomer and a relatively flexible difunctional monomer. The rigid multifunctional monomer and the flexible difunctional monomer are capable of co-reacting to form an abrasion resistant coating on the optical element. The invention also provides a method of forming an abrasion resistant coating on an optical element, such as an ophthalmic lens. The method includes the steps of coating the optical element with a relatively rigid multifunctional monomer and a relatively flexible difunctional monomer, and polymerising the coating to form an abrasion resistant coating on the optical element.

Abstract: The present invention comprises formulations comprising at least one pesticide and at least one co-polymer comprising (a) a N-vinylamid comonomer a) of formula (I) wherein R1 and R2 are independently of one another hydrogen or C1-C4 alkyl, preferably hydrogen or R1 and R2 represent together a —(CH2)x moiety, which forms together with the nitrogen and the carbonyl-moiety a 5-8 membered ring, and (b) at least one comonomer b) selected from the group consisting of vinylpyrridin, vinylpyrridin derivatives and N-vinlyimidazole in polymerized form, methods of combating harmful insects and/or phytopathogenic fungi, a method of controlling undesired vegetation and methods of improving the health of plants based on the afore-mentioned formulations.

Abstract: A single phase aqueous composition suitable for thermal inkjet printing comprises a mixture of curable materials including at least two curable oligomers; and one or more co-solvents for the curable materials.

Abstract: Provided herein are branched polymers synthesized from: at least one (A1) reactive monomer having a vinyl functional group, or (A2) a hybrid reactive monomer having (a) at least one vinyl functional group and (b) at least one reactive non-vinyl functional group; and at least one: (B1) branching agent having at least two N-vinyl formamide functional groups or (B2) a hybrid branching agent having (a) at least one N-vinyl formamide functional group, and (b) at least one vinyl functional group. The polymers exhibit branching behavior, which in some embodiments lends to lower viscosity, enhanced processability, and/or improved sprayability compared to a corresponding polymer of equal molecular weight synthesized without the second reactive moiety. Formulations with the invention's polymers also are presented.

Abstract: Low-dusting, granular compositions are provided that comprise at least 15% by weight crosslinked polyvinylpyrrolidone.

Abstract: Polymers are provided that are derived from at least (A) N-vinyl formamide, (B) one vinyl amide moiety or one acrylamide moiety, and (C) a reaction solvent. The polymers are random, block, or alternating polymers. A particular useful poly-mer comprises about 20% N-vinyl formamide, about 50% N-vinyl-?-caprolactam, about 30% N-vinyl-2-pyrrolidone, being synthesized in ethylene glycol. In preferred embodiments, polymers of the invention exhibit a cloud point temperature of 66° C. or more, inhibit the formation of gas hydrates, and/or inhibit corrosion. Especially preferred uses of the polymers are in oilfield operations as gas hydrate inhibitors and/or corrosion inhibitors.

Abstract: The invention relates to the use of vinyl phosphonic acid or a salt thereof for improving the biodegradability of mixed polymers, comprising 25 to 99.5% by weight of structural units of one or more monomers selected from the group made of compounds of formula (1) and formula (3), where R1 and R2 independently are hydrogen or C1-C4-alkyl, formula (4), where n is 3, 4, or 5, and formula (5), where X is OH or for NR3R4, and R3 and R4 independently are H or C1 to C4-alkyl, in that 0.5 to 25% by weight of vinyl phosphonic acid is polymerized into the mixed polymer.

Abstract: Process for the preparation of low-peroxide polymer comprising the treatment of the polymer with elemental metal in the presence of a liquid, polymer obtainable by this process, the use thereof, and also drugs comprising this polymer.

Abstract: Modified polyvinyllactams and their use.

Abstract: The present invention relates to amphoteric copolymers which comprise ethyl methacrylate, if appropriate a N-vinyllactam compound, at least one monoethylenically unsaturated carboxylic acid and at least one compound with ?,?-ethylenically unsaturated double bond and at least one cationogenic and/or cationic group in copolymerized form, to cosmetic and pharmaceutical compositions which comprise such copolymers, to preparation methods, and to the use of these copolymers.

Abstract: The present invention relates to a polymer comprising an N-vinyl amide monomer and a dual functional monomer. In the case where the dual functional monomer incorporates glycidyl methacrylate, a third polymerizable monomer is also included.

Abstract: The present invention provides a pressure-sensitive adhesive sheet having a pressure-sensitive adhesive layer which has both high corrosion resistance and adhesion reliability. The acrylic pressure-sensitive adhesive sheet of the present invention contains at least an acrylic pressure-sensitive adhesive layer containing as a main component an acrylic polymer formed from a composition containing a monomer mixture or a partially polymerized product thereof, in which the monomer mixture contains the following (m1), (m2) and (m3), or (m1), (m2), (m3) and (m4), and in which a content of each component (m1), (m2), (m3), and (m4) is 35 to 97.5% by mass, 2 to 40% by mass, 0.1 to 25% by mass, and 0 to 30% by mass, respectively: (m1) an alkyl(meth)acrylate monomer having an alkyl group with 1 to 12 carbon atoms, which is represented by Formula (1), [Chem.

Abstract: Compositions comprising a silyl-containing copolymer of a monomer system comprising: (A) a silyl-containing monomer having a structural formula (A) Wherein n=1-20, o=1-5 R=O or NH R?=H or CH3 R?=C1-C12 alkyl ?wherein m=1-20; (B) a neutral, hydrophilic, ethylenically unsaturated monomer; and (C) a cationic ethylenically unsaturated monomer are disclosed. Aqueous solutions of the silyl-containing copolymer form transparent coatings on substrates which have very high contact angles with aqueous solutions and receive aqueous ink with very low bleeding. Substrates coated with the copolymer, methods for printing images, and methods of forming a portion or all of an electronic feature, are also disclosed.

Abstract: The use of composite foils, comprising barrier layers based on polyvinyl alcohols, as packaging material for polymers susceptible to oxidation, processes for packaging said polymers, and packaging composed of said composite foils for packaging the polymers susceptible to oxidation.

Abstract: A structure that comprises a substrate; a cross-linked random free radical copolymer on the substrate; and a self-assembled patterned diblock copolymer film on the random copolymer; wherein the random copolymer is energy neutral with respect to each block of the diblock copolymer film. A method of making the structure is provided.

Abstract: The present invention relates to new anionic associative rheology modifiers, their manufacture and application.

Abstract: The present invention relates to a method of producing aqueous secondary dispersions of water-insoluble copolymers by free-radical solution polymerization of ethylenically unsaturated monomers M comprising: i) at least one hydrophobic, monoethylenically unsaturated monomer M1 with a solubility in water of not more than 30 g/l at 25° C. and 1 bar and ii) at least one hydrophilic, monoethylenically unsaturated, nonionic comonomer M2 with a solubility in water of at least 80 g/l at 25° C. and 1 bar, in an organic, water-miscible solvent or a mixture of water with an organic, water-miscible solvent as polymerization medium and subsequent replacement of the organic solvent by water in which, toward the end of the polymerization, some of the monomers M are added in the form of a monomer composition M? which comprises essentially only monomers M2 as monomers.

Abstract: The present invention is directed to the use of artificial polymers in the mimetization of enzymatic active sites and the carrying-out of catalysis using these artificial enzymes. Further, as used herein, an artificial enzyme refers more generally to a polymer-based scaffold for presenting specific chemically active atoms optimally for reactions, not just those that mimic natural enzymes. Various polymers can be used for this mimetization, including polyimides, polyurea, polyurethane, polyacrylic acid, and polylactic acid, as well as other polymers having properties and functionality that enable integration with natural and artificial amino acids, other molecules having nucleophilic and electrophilic groups (akin to the amine and carboxyl functionalities, respectively, of amino acids), as well as other molecules contributing unique chemical abilities not usually associated with the orthogonal functions inherent in most amino acids, i.e.

Abstract: The invention relates to a composition for processing and/or modifying surfaces, particularly hard surfaces or textile surfaces.

Abstract: The invention relates to preparations, in particular plant-protective preparations which contain a mixture of at least two different active plant-protective substances, wherein a) at least one active substance is selected from a conazole group (active substance 1) and b) another active-plant protective substance (active substance 2) whose water solubility at a temperature of 20° C. is less than 20 g/l., c) at least one type of copolymer CP consisting of M monomers comprising ?) at least one type of monoethylenically unsaturated monomer M1 comprising at least one sulphonic acid group and ?) at least one type of neutral monoethylenically unsaturated monomer M2, wherein the quantitative ratio between the active substance 1 and the other active plant-protective substance 2 ranges from 1:10 to 10:1.

Abstract: The present invention provides a reactive hydrophilic copolymer consisting essentially of units formed by ethylenically unsaturated hydrophilic monomers and units of formula (I) or (II) formed by ethylenically unsaturated monomers having alkoxy silane functional groups in a random order: wherein the copolymer has a molecular weight of at least 50,000, and wherein R1, R2 and R3 can be the same or different and are independently selected from H or C1-3 alkyl; R is C1-3 alkyl; X, Y and Z can be the same or different and are independently selected from R? or OR?, provided that at least one of X, Y and Z is OR?; R? is H or C1-3 alkyl; and the equivalent ratio of the units formed by ethylenically unsaturated hydrophilic monomers to the units of formula (I) or (II) is within the range of 5/1 to 200/1. The present invention also provides silicone hydrogel compositions comprising the reactive hydrophilic copolymer of the present invention and ocular articles made therefrom.

Abstract: The present invention relates to an acrylic pressure-sensitive adhesive composition comprising a copolymerization reaction product of a monomer mixture satisfying the following both conditions: (a) the monomer mixture includes a monomer m1 in an amount of 50% by mass or more based on whole monomer components constituting the monomer mixture, wherein the monomer m1 is an alkyl (meth)acrylate represented by the following formula (I): CH2?C(R1)COOR2??(I) wherein R1 represents a hydrogen atom or a methyl group, and R2 represents an alkyl group having from 1 to 20 carbon atoms; and (b) the monomer mixture includes a monomer m2 in an amount of 12% by mass or more based on the whole monomer components constituting the monomer mixture, or a monomer m2 and a monomer m3 in an amount in total of 12% by mass or more based on the whole monomer components constituting the monomer mixture, wherein the monomer m2 is an imidazole group-containing unsaturated monomer, and the monomer m3 is an amide group-containing unsatura

Abstract: The present invention relates to compositions comprising a polymeric substrate comprising at least one volume excluding polymer. In one embodiment, the present invention provides polymeric articles that are capable of acting as osmotic drivers. The articles are capable of maintaining a desired water balance by moving water in or out of a substrate to maintain cation concentration equilibrium between the substrate and its environment.

Abstract: This application is directed toward an improved method of synthesizing cationic siloxane prepolymers as well as a specific cationic siloxane prepolymer having improved compatibility with monofunctional siloxanyl methacrylate monomers and medical devices containing the cationic siloxane prepolymer.

Abstract: The present disclosure relates to Shape Memory Polymers (SMP's) comprising function groups that allow the polymers to be elastically deformed, utilized in the elastically deformed state, and subsequently returned to the original polymorphic shape.

Abstract: There is provided a polymer including a unit represented by Chemical Formula (1): wherein R represents -A1-SO2R1; R1w and R1x are each independently a halogen atom or a hydrogen atom; R1y is a CH3 group, a halogen atom or a hydrogen atom; A01 is a substituted or unsubstituted aromatic ring structure or a substituted or unsubstituted heterocyclic structure; A1 is a substituted or unsubstituted aliphatic hydrocarbon structure, a substituted or unsubstituted aromatic ring structure or a substituted or unsubstituted heterocyclic structure; R1 is OH, a halogen atom, ONa, OK or OR1a; R1a is a substituted or unsubstituted aliphatic hydrocarbon structure, a substituted or unsubstituted aromatic ring structure or a substituted or unsubstituted heterocyclic structure.

Abstract: A process for the production of a tinted polymer, which comprises co-polymerising a compound of the general formula I or a salt thereof with a polymerisable monomer containing a vinyl group, formula I being: in which R represents a hydrogen atom or an —SO3H group; A represents a direct bond, -alkylene-O—, or a -phenylene-NH— or -phenylene-NH-phenylene-NH— group in which the or each phenylene ring may be optionally substituted by one or more of the same or different groups selected from —SO3H, —(CH2)mSO3H, —SO2(CH2)mSO3H, —SO2NH(CH2)mSO3H, —SO2C1-2alkyl, —SO2C1-2haloalkyl, —SO2NHC1-2alkyl, —SO2NHC1-2haloakyl, —C1-2alkyl, or C1-2haloalkyl, in which m represents 1 or 2; R1 represents a hydrogen or halogen atom or a C1-4 alkyl group; and each of R2 and R3, which may be the same or different, represents a hydrogen atom or a C1-4 alkyl or alkoxy group; with the proviso that, if R1 represents a hydrogen or a C1-4alkyl group and simultaneously R represents a hydrogen atom, A must represent a -phenylene-NH— or -ph

Abstract: The present invention relates to novel polymeric microgels and to a method suitable for the preparation thereof. The novel microgels comprise cationic units.

Abstract: The present invention relates to polymeric compositions useful in the manufacture of biocompatible medical devices. More particularly, the present invention relates to certain monoethylenically unsaturated polycarbosiloxane monomers capable of polymerization to form polymeric compositions having desirable physical characteristics useful in the manufacture of ophthalmic devices.

Abstract: The present invention relates to a polymerizable water-soluble or alcohol-soluble ultraviolet absorber, which is represented by the following formula (I): wherein R1 is H or C1˜5 alkyl; R2 is H, Cl, Br or I; R3 is H or methyl; and m each is an integer in the range from 3 to 12. The above-mentioned compounds are suitable for copolymerizing with one or more monomers to form copolymers so that the UV-light resistance of the copolymer can be efficiently promoted. For example, the polymer made by copolymerizing the above-mentioned compound with acrylate monomers can be applied to the production of optical medical materials, especially contact lenses or intraocular lenses.

Abstract: The present invention is drawn to the use of blocked maleimide monomers for the preparation of latex particles, including those having active maleimide surface groups. In accordance with this, a method of forming latex particulates can comprise the steps of preparing a monomer emulsion including an aqueous phase and an organic monomer phase, wherein the organic monomer phase includes at least one blocked maleimide monomer; polymerizing the organic monomer phase to form blocked maleimide latex particulates dispersed in the aqueous phase; and unblocking the blocked maleimide latex particulates to form latex particulates with active maleimide groups at least on the surface of the latex particulates.

Abstract: The present invention is a powder of a vinylpyrrolidone polymer having a K value of smaller than 50, characterized in that a content of particles having a particle diameter of 106 ?m or smaller is 10% by mass or less and a content of particles having a particle diameter of greater than 1,000 ?m is 5% by mass or lower. A process for production of a powder of a vinylpyrrolidone polymer according to the present invention is characterized in that a vinylpyrrolidone polymer having a K value of smaller than 50 is formed into a solution having a concentration from 30% to 70% by mass, and the solution is dried by using a hot surface adhesion-type dryer, followed by pulverization so that a content of particles having a particle diameter of 106 ?m or smaller is 10% by mass or lower and a content of particles having a particle diameter of greater than 1,000 ?m is 5% by mass or lower.

Abstract: In one aspect, the invention relates to silicone prepolymer compositions comprising a silicone prepolymer and a solvent. A soluble silicone prepolymer can be provided having increased average silicon content, thereby attaining a desired oxygen permeability. A solvent can be provided with a desired balance between hydrophilicity and hydrophobicity by selection and modification of the solvent molecular structure, resulting in molded polymer films and articles that exhibit minimal or nonexistent eye irritation and exhibit highly transparent products. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.

Abstract: The invention relates to a hydrogel which is a copolymer formed from a polymerizable monomer mixture which contains a) 10-65 mol % of at least one hydrophobic vinyl monomer of the formula I in which R1 is hydrogen or methyl, p is an integer from 1 to 8, whose hydroxyl groups are present in protected form, b) 25-70 mol % of at least one silicone-containing (meth)acrylate, vinyl carbonate or vinyl carbamate monomer, c) 0-25 mol % of at least one hydrophilic vinyl monomer and d) 0-10 mol % of at least one crosslinker, based on the total amount of monomers a) to c), and where the hydroxyl groups of the segments formed by the monomers a) in the hydrogel are present in protected form or in free form. The hydrogel can be used to produce contact lenses or intraocular lenses.

Abstract: Biomedical devices such as contact lenses formed from a polymerization product of a mixture comprising (a) a hydrophilic polymer comprising one or more hydrophilic units and one or more thio carbonyl thio fragments of a reversible addition fragmentation chain transfer (“RAFT”) agent; and (b) one or more biomedical device-forming monomers are disclosed.

Abstract: There is provided a vinylpyrrolidone-based copolymer having as essential components N-vinylpyrrolidone and hydroxyl group-containing (meth)acrylate, which gives a favorable crosslinked coating film, and a method for production by which the copolymer is easily obtained. A vinylpyrrolidone-based copolymer of the present invention contains a constitutional unit derived from N-vinylpyrrolidone and a constitutional unit derived from hydroxyl group-containing (meth)acrylate at a specific ratio, in which a K value according to Fikentscher is 12 or more, water insoluble matter is 0.5% by mass (on the basis of solid content) or less, and each content of iron, nickel, chromium, sodium and calcium is 500 ppb (on the basis of mass: the same hereinafter) or less, or electrical conductivity of a 10% by mass-aqueous solution of the vinylpyrrolidone-based copolymer is 35 ?S/cm or less.

Abstract: Method of producing copolymers by free-radical polymerization of at least one water-soluble N-vinyllactam and at least one hydrophobic comonomer in an organic solvent in the presence of an initiator, where the polymerization is carried out under a gauge pressure such that evaporation of the components is avoided.

Abstract: This invention deals with a tissue protecting, spray-on film composition comprising an amphiphilic film-forming, segmented/block copolymer derived form at least one water-soluble monomer and at least another water-insoluble monomer, wherein the film can be formed from a water soluble organic solvent such as 2-propanol, acetone, and ethyl acetate. The film can contain a bioactive agent including those to have antimicrobial, anesthetic, anti-inflammatory, and wound-healing activities.

Abstract: Polymers are described comprising a) one or more of the recurring structural units of the formula (1) where R1 is hydrogen, methyl or ethyl and A is C1-C8 alkylene, and Q+ is H+, NH4+, Li+, Na+, K+, ½Ca++, ½ Mg++, ½ Zn++ or ? Al+++, and the neutralization degree of the structural units of formula (1) is 50 to 100 mol-%, and b) one or more of the recurring structural units of the formula (2) where R1 and A are R1 and A from formula (1) and X+ is [HNR5R6R7]+, where R5, R6 and R7 can independently from each other be hydrogen, a linear or branched alkyl group with 1 to 22 carbon atoms, a linear or branched, simple or polyunsaturated alkenylene group with 2 to 22 carbon atoms, a C6-C22-alkylamidopropyl group, a linear monohydroxyalkyl group with 2 to 10 carbon atoms or a linear or branched dihydroxyalkyl group with 3 to 10 carbon atoms, and wherein at least one of the groups R5, R6 and R7 is not hydrogen, with the proviso that the molar ratio of the structural units of formula (1), where Q+ is NH4+, Li+, N

Abstract: A novel optical film is provided that exhibits a wavelength dispersion (a reverse wavelength dispersion) such that the birefringence of the film decreases as the wavelength becomes shorter, at least in the visible light range. The optical film includes a layer formed of a resin (A) having a heteroaromatic group or a molecular structure represented by the following formula (1), (2) or (3): where in the formula (1), n is a natural number in the range of 1 to 4, and R1 and R2 each independently represent a hydrogen atom or a methyl group. The optical film exhibits a wavelength dispersion such that the birefringence of the film decreases as the wavelength becomes shorter, at least in the visible light range.

Abstract: Copolymers prepared in aqueous medium from macromonomers and one or more ethylenically unsaturated monomers are disclosed. The copolymers are useful for sound and vibration dampening applications.

Abstract: A latex copolymer composition comprising >5 wt % of polymerized units derived from a monomer X containing an unsaturated heterocycle, wherein the latex copolymer composition comprises ?1,000 ppm of residual monomer X is disclosed. Also disclosed are methods of making and using the latex copolymer compositions.

Abstract: The invention concerns the use as a thickening agent, in possibly pigmented aqueous formulations, such as coating formulations such as paints in the aqueous phase such as dispersion paints, varnishes, paper coatings, cosmetic formulations, detergent formulations, textile formulations and drilling muds, of a water-soluble acrylic copolymer consisting of at least one monomer with ethylenic unsaturation and a carboxylic function, at least one non-ionic monomer with ethylenic unsaturation, at least one oxyalkylated monomer with ethylenic unsaturation terminated by a hydrophobic branched and non-aromatic chain with 10 to 24 carbon atoms, and possibly at least one monomer with at least two ethylenic unsaturations. The invention also concerns the possibly pigmented aqueous formulations obtained.

Abstract: A polyvinylpyrrolidone powder composition including polyvinylpyrrolidone with a K value of not lower than 50 and not higher than 120, wherein a content of insoluble substances remaining on a membrane filter having a pore size of 1.2 ?m when a 2 wt % aqueous solution of the composition is filtered with the filter is not higher than 70 ppm; a polyvinylpyrrolidone powder composition including polyvinylpyrrolidone with a K value of not lower than 50 and not higher than 120, wherein a K value lowering ratio to be observed when the composition is heated at 80° C. in air for 14 days is not higher than 12%; and a polyvinylpyrrolidone powder composition including polyvinylpyrrolidone with a K value of not lower than 50 and not higher than 120, wherein a content of insoluble substances remaining on a membrane filter having a pore size of 1.

Abstract: The present invention relates to a copolymer with high cationic charge based on quaternized nitrogen-containing monomers, to cosmetic or pharmaceutical compositions which comprise at least one such copolymer, and to further uses of these copolymers.

Abstract: A process for preparing copolymers in solid form, where the copolymers are obtained by free-radical polymerization of a mixture of 30 to 80% by weight of N-vinyllactam, 10 to 50% by weight of vinyl acetate and 10 to 50% by weight of a polyether in the presence of at least one solvent, with the proviso that the total of i), ii) and iii) equals 100% by weight, which process comprises removing the solvent from the polymerization mixture with the aid of an extruder.

Abstract: A non-specific adsorption inhibitor includes a water-soluble polymer obtained by polymerizing a monomer unit that includes a monomer (A) that forms a polymer that has a lower critical solution temperature (LCST) of 80° C. or less in an aqueous solution under normal pressure when subjected to homopolymerization, and a monomer (B) that forms a polymer that does not have the LCST in an aqueous solution under normal pressure when subjected to homopolymerization.

Abstract: A polymeric composition consisting of water-soluble or water-swellable copolymers containing sulfo groups and nonionic polysaccharide derivatives, such as methylcellulose (MC), hydroxyethylcellulose (HEC), hydroxypropylcellulose (HPC), methylhydroxyethylcellulose (MHEC), methylhydroxypropylcellulose (MHPC) and welan gum or diutan gum, and the use thereof as an additive in aqueous construction systems based on hydraulic binders, such as cement, lime, gypsum or anhydrite, is described. The composition can also be used in water-based paint and coating systems. The composition according to the invention exhibits a synergistic improvement of the properties and, when used in relatively small amounts, constitutes highly effective water retention agents in such construction and paint systems, which also achieve outstanding air pore stability and tack.

Abstract: The present invention relates to a polymerizable polymer formed from an N-vinyl amide monomer and containing a polymerizable functionality. In one approach, a dual functional monomer may be employed. In the case where the dual functional monomer incorporates glycidyl methacrylate, a third polymerizable monomer is also included. In a second approach, a monomer with polymerizable functionality can be grafted onto a pre-existing, suitable N-vinyl amide co-polymeric material, yielding a co-polymer comprising a polymerizable functionality.

Abstract: The present invention relates to the use of cationic polymers obtainable by free-radical copolymerization of a) 60 to 99 mol % of at least one 1-vinylimidazole monomer, b) 1 to 40 mol % of at least one free-radically polymerizable quaternizable monomer b1) or methacrylic acid b2) and c) 0 to 30 mol % of at least one further free-radically copolymerizable monomer different from a) and b) in hair cosmetic preparations.