From Monomer Containing A Silicon Atom Patents (Class 526/279)
  • Patent number: 7968174
    Abstract: A decorative material having a pattern on a surface thereof and exhibiting a difference in gloss according to the pattern which is visually recognized as a concave portion, the decorative material further exhibiting not only a good surface strength such as abrasion resistance but also good marring resistance and oil resistance. The decorative material includes at least a substrate, a low-gloss pattern ink layer formed on part of the substrate, and a surface protective layer which is present on and contacted with the low-gloss pattern ink layer so as to cover a whole surface including both a region where the low-gloss pattern ink layer is formed and a region where no low-gloss pattern ink layer is formed.
    Type: Grant
    Filed: September 29, 2005
    Date of Patent: June 28, 2011
    Assignee: Dai Nippon Printing Co., Ltd.
    Inventors: Toshitake Kobayashi, Eiichiro Yokochi
  • Publication number: 20110146206
    Abstract: This application is directed toward an improved method of synthesizing cationic siloxane prepolymers as well as a specific cationic siloxane prepolymer having improved compatibility with monofunctional siloxanyl methacrylate monomers and medical devices containing the cationic siloxane prepolymer.
    Type: Application
    Filed: March 3, 2011
    Publication date: June 23, 2011
    Inventors: Jason K. Stanbro, Ivan M. Nunez, Jay F. Kunzler, Derek A. Schorzman
  • Patent number: 7964684
    Abstract: An antireflection film forming composition, includes: a polymerized product of Compound (I) having m number of RSi(O0.5)3 units, in which m stands for an integer of from 8 to 16, and Rs each independently represents a non-hydrolyzable group, with the proviso that at least two of Rs each represents a vinyl- or ethynyl-containing group, wherein each of the RSi(O0.5)3 units is linked to another RSi(O0.5)3 unit while having an oxygen atom in common and constitutes a cage structure, and wherein, of solids contained in the composition, the polymerized product obtained by a polymerization reaction of Compound (I) amounts to 60 mass % or greater and Compound (I) amounts to 15 mass % or less.
    Type: Grant
    Filed: March 3, 2008
    Date of Patent: June 21, 2011
    Assignee: FUJIFILM Corporation
    Inventors: Kensuke Morita, Makoto Muramatsu, Kouji Tonohara
  • Patent number: 7959989
    Abstract: The present invention relates to a novel cyclic olefin compound, a polymer including the cyclic olefin compound, a liquid crystal alignment film including the polymer, and a liquid crystal display device including the liquid crystal alignment film. Since the polymer includes the cyclic olefin compound as a main chain, the thermal stability is excellent and the photoreactive speed is high. Accordingly, the production time can be reduced, the production cost can be reduced, and the anchoring force of the liquid crystal can be increased because the alignment property is stabilized due to the curing.
    Type: Grant
    Filed: March 6, 2008
    Date of Patent: June 14, 2011
    Assignee: LG Chem, Ltd.
    Inventors: Heon Kim, Sung-Ho Chun, Hee-Jin Lee, Dmitry Kravchuk, Kyung-Jun Kim, Sang-Kook Kim, Sung-Joon Oh, Hye-Ran Seong, Byung-Hyun Lee, Hye-Won Jeong, Jung-Ho Jo, Yun-Jeong Lee, Dong-Hyun Oh
  • Patent number: 7960475
    Abstract: A powder coating composition of the present invention includes, as essential components, an epoxy group-containing vinyl copolymer (A) with a glass transition temperature of 40° C. or higher, an epoxy group-containing vinyl copolymer (B) that contains organosiloxane side chains and has a glass transition temperature of 0° C. or lower, and a polyvalent carboxylic acid (C), and is able to form a coating film with excellent external appearance and scratch resistance.
    Type: Grant
    Filed: March 9, 2005
    Date of Patent: June 14, 2011
    Assignee: DIC Corporation
    Inventors: Naoyuki Seike, Koichi Yamaguchi, Yutaka Furuya, Tetsuro Agawa
  • Publication number: 20110135850
    Abstract: The present disclosure provides for new photoalignment (co)polymer materials which demonstrate improved adhesion to a substrate. The (co)polymeric structure includes at least one photochemically active chromophore and at least one adhesion promoter group. Articles of manufacture, optical elements, ophthalmic elements and liquid crystal cells which include at least one photoalignment layer made from the photoalignment (co)polymer materials and methods for formation are also disclosed.
    Type: Application
    Filed: December 3, 2010
    Publication date: June 9, 2011
    Applicant: TRANSITIONS OPTICAL, INC.
    Inventors: Gobinda Saha, Anil Kumar
  • Patent number: 7951897
    Abstract: This application is directed toward an improved method of synthesizing cationic siloxane prepolymers as well as a specific cationic siloxane prepolymer having improved compatibility with monofunctional siloxanyl methacrylate monomers and medical devices containing the cationic siloxane prepolymer.
    Type: Grant
    Filed: January 24, 2008
    Date of Patent: May 31, 2011
    Assignee: Bausch & Lomb Incorporated
    Inventors: Jason K. Stanbro, Ivan M. Nunez, Jay F. Kunzler, Derek A. Schorzman
  • Publication number: 20110123478
    Abstract: The present invention relates to silyl ester copolymers useful as binders in antifouling coating compositions and antifouling coating compositions comprising the silyl ester copolymers. The silyl ester copolymers comprise repeating units of monomers A, B and optionally C. A is one or more monomers selected from the group consisting of triorganosilyl esters of polymerisable ethylenically unsaturated carboxylic acids. B is one or more monomers selected from the group consisting of lactone modified hydroxyalkyl (meth)acrylates, and C is one or more monomers selected from the group consisting of polymerisable ethylenically unsaturated compounds.
    Type: Application
    Filed: June 10, 2009
    Publication date: May 26, 2011
    Applicant: JOTUN A/S
    Inventor: Marit Dahling
  • Publication number: 20110118372
    Abstract: Acrylic copolymers that include the controlled placement of functional groups within the polymer structure are provided. The copolymers contain a reactive segment and a non-reactive segment and are manufactured via a controlled radical polymerization process. The copolymers are useful in the manufacture of adhesives and elastomers.
    Type: Application
    Filed: March 20, 2009
    Publication date: May 19, 2011
    Applicant: AVERY DENNISON CORPORATION
    Inventors: Christopher L. Lester, Brandon S. Miller, Michael J. Zajaczowski, William L. Bottorf, Kyle R. Heimbach
  • Publication number: 20110118413
    Abstract: A silicon-containing polymer represented by the following average unit formula: (O2/2SiR1-R2-C6H4-R2-SiR1O2/2)x [R3 SiO(4-a)/2]y(R4O1/2)z (wherein R1 designates identical or different, substituted or unsubstituted monovalent hydrocarbon groups; R2 designates identical or different, substituted or unsubstituted alkylene groups; R3 designates substituted or unsubstituted monovalent hydrocarbon groups; R4 designates alkyl groups or hydrogen atoms; ‘a’ is a positive number that satisfies the following condition: 0=a=3; and ‘x’, ‘y’, and ‘z’ are positive numbers that satisfy the following conditions: 0<x<0.1; 0<y<1; 0=z<0.1; and (x+y+z)=1); and a curable polymer composition comprising: (A) the aforementioned silicon-containing polymer; (B) an organosilicon compound that contains in one molecule at least two silicon-bonded hydrogen atoms; and (C) a hydrosilylation catalyst.
    Type: Application
    Filed: April 6, 2009
    Publication date: May 19, 2011
    Inventors: Yoshitsugu Morita, Yoshinori Taniguchi, Hiroshi Ueki
  • Publication number: 20110118415
    Abstract: A polymer composition, including: a first copolymer, including a first monomer unit derived from a monomer of Formula A: (R1SiO1.5)x(R2SiO1.5)y??Formula A wherein R1 is a polymerizable functional group, R2 is a non-polymerizable group, x is a positive integer, and y is a positive integer, provided that x+y=2n, wherein n is an integer greater than or equal to 3; a second monomer unit copolymerizable with the first monomer unit; and a second polymer having no monomer units derived from a monomer of Formula A; wherein the content of the monomer unit of Formula A is 4 wt % or less, based on the total weight of the polymer components of the polymer composition.
    Type: Application
    Filed: November 16, 2010
    Publication date: May 19, 2011
    Applicant: THE UNIVERSITY OF MASSACHUSETTS
    Inventors: E. Bryan Coughlin, Yoshinobu Nozue, Shuichiro Seno
  • Patent number: 7939579
    Abstract: Hydrogels, methods of preparing hydrogels, and ophthalmic lenses comprising hydrogels are described. Fully hydrated embodiments of the hydrogels have relatively high water content and oxygen permeability, along with relatively low modulus of elasticity. Embodiments of the hydrogels in substantially dehydrated condition are adapted to lathe cutting at or above room temperature. Embodiments of contact lenses made with the silicone hydrogels have low on-eye water loss.
    Type: Grant
    Filed: July 9, 2008
    Date of Patent: May 10, 2011
    Assignee: Contamac Limited
    Inventors: Tristan Tapper, Richard Young
  • Patent number: 7939687
    Abstract: A nanocomposite material including organic-inorganic polymeric interpenetrating networks having a low or no-shrinkage characteristic and a method for making the composite, as defined herein.
    Type: Grant
    Filed: November 9, 2009
    Date of Patent: May 10, 2011
    Assignee: Corning Incorporated
    Inventor: Nikita Sergeevich Shelekhov
  • Patent number: 7934830
    Abstract: Silicone hydrogels formed from a hydrated polymerization product of a monomer mixture comprising (a) a major amount of a non-silicone-containing hydrophilic monomer; and (b) a minor amount of a silicone-containing monomer, wherein the hydrogel has a water content of greater than 50 weight percent are disclosed.
    Type: Grant
    Filed: November 10, 2008
    Date of Patent: May 3, 2011
    Assignee: Bausch & Lomb Incorporated
    Inventors: Richard I. Blackwell, Jay F. Kunzler, Amy Jasek
  • Patent number: 7935884
    Abstract: An encapsulant layer for a photovoltaic module enabling recovering and recycling or reusing of reutilizeable resources such as a transparent front face substrate and photovoltaic cell and the like among constituents of a photovoltaic module, and a method for manufacturing a regenerated photovoltaic cell and a regenerated transparent front face substrate. The photovoltaic module is formed by laminating: a transparent front face substrate; a photovoltaic cell carrying a wiring electrode and a takeoff electrode, and an encapsulant layer is placed on at least one surface; and a rear face protecting sheet. The encapsulant layer is a separable layer formed mainly of a thermoplastic resin, and an output maintenance factor of photoelectronic power of the photovoltaic module using the encapsulant layer is in a range of 80% to 100%.
    Type: Grant
    Filed: September 9, 2004
    Date of Patent: May 3, 2011
    Assignee: Dai Nippon Printing Co., Ltd.
    Inventors: Kasumi Oi, Takaki Miyachi, Isao Inoue, Koujiro Ohkawa, Hiroki Nakagawa
  • Publication number: 20110095270
    Abstract: There is provided an electroactive material having Formula I wherein: Q is the same or different at each occurrence and can be O, S, Se, Te, NR, SO, SO2, or SiR3; R is the same or different at each occurrence and can be hydrogen, alkyl, aryl, alkenyl, or alkynyl; R1 through R8 are the same or different and can be hydrogen, alkyl, aryl, halogen, hydroxyl, aryloxy, alkoxy, alkenyl, alkynyl, amino, alkylthio, phosphino, silyl, —COR, —COOR, —PO3R2, —OPO3R2, or CN.
    Type: Application
    Filed: December 17, 2008
    Publication date: April 28, 2011
    Inventor: HONG MENG
  • Patent number: 7931954
    Abstract: There is provided a decorative material comprising at least a substrate, a low-luster pattern ink layer partially formed on the substrate, and a surface protective layer which is present on and contacted with the low-luster pattern ink layer so as to cover a whole surface including both a region where the low-luster pattern ink layer is formed and a region where no low-luster pattern ink layer is formed, wherein the surface protective layer is formed by crosslinking and curing an ionizing radiation-curable resin composition, and provided therein with a low-gloss region which is located in a portion just above the low-luster pattern ink layer and in the vicinity of the portion and visually recognized as a concave portion. The decorative material is provided on a surface thereof with a pattern, and exhibits a difference in gloss according to the pattern which is visually recognized as a concave portion, thereby imparting a good convexo-concave feeling to a surface thereof.
    Type: Grant
    Filed: September 30, 2004
    Date of Patent: April 26, 2011
    Assignee: Dai Nippon Printing Co., Ltd.
    Inventors: Toshitake Kobayashi, Kazuhiro Abe, Kenichi Tachihara, Eiichiro Yokochi
  • Patent number: 7932097
    Abstract: A method of manufacturing an analytical sample by a secondary ion mass spectrometry method is provided, which comprises a step of forming a separation layer over a substrate, a step of forming one of a thin film and a thin-film stack body to be analyzed over the separation layer, a step of forming an opening portion in one of the thin film and the thin-film stack body, a step of attaching a supporting body to one of a surface of the thin film and a surface of a top layer of the thin-film stack body, and a step of separating one of the thin film and the thin-film stack body from the substrate.
    Type: Grant
    Filed: October 20, 2010
    Date of Patent: April 26, 2011
    Assignee: Semiconductor Energy Laboratory Co., Ltd.
    Inventor: Satoshi Toriumi
  • Publication number: 20110089385
    Abstract: The composition for optical materials includes a polymer obtained from silsesquioxanes which are represented by average composition formula (1): (R1SiO1.5)x(R2SiO1.5)y (wherein R1 is a polymerizable group, R2 is a non-polymerizable group, x is a number of 2.0 to 14.0, y is a number of 2.0 to 14.0, provided that x+y=8.0 to 16.0, and R1 groups and R2 groups may be the same or different) and include at least one cage silsesquioxane compound. This composition is suitable for use as the antireflective film in optical devices, has less film shrinkage in the curing step, has good coated surface state and excellent moisture resistance and adhesion, has small changes in the refractive index under high temperature conditions, and is capable of forming a low-refractive-index film.
    Type: Application
    Filed: October 14, 2010
    Publication date: April 21, 2011
    Applicant: FUJIFILM Corporation
    Inventors: Kenji Wada, Kyohei Arayama, Akiyoshi Goto
  • Publication number: 20110090568
    Abstract: The present invantion provides a resin particle having many recesses on the surface thereof, which has solvent resistance and heat resistance. More specifically, the present invantion provides a resin particle having many recesses on the surface thereof which is obtained by using a seed particle, wherein a seed particle component in the resin particle has a crosslinked structure.
    Type: Application
    Filed: May 11, 2009
    Publication date: April 21, 2011
    Applicant: SUMITOMO SEIKA CHEMICALS CO., LTD.
    Inventors: Shigeki Hamamoto, Hirotsugu Kawata, Kiyoshi Yamaguchi, Masayoshi Okubo
  • Patent number: 7928179
    Abstract: A photoreactive group-containing siloxane compound is obtained by subjecting a system comprising (a) a photoreactive group-containing alkoxysilane and (b) a hydrolyzable group end-capped dimethylsiloxane to hydrolytic condensation in the presence of a basic catalyst and with an amount of water greater than the amount necessary for hydrolytic condensation of all alkoxy groups. It forms on a substrate a coating having mar resistance, crack resistance, anti-staining effect, and marker ink wipe-off ability.
    Type: Grant
    Filed: April 17, 2007
    Date of Patent: April 19, 2011
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Yuji Yoshikawa, Masaaki Yamaya
  • Patent number: 7928171
    Abstract: A polymer material useful for manufacturing an intraocular lens (IOL) suitable for insertion through an IOL inserter barrel having an inner diameter of less than 3 mm is provided. Specifically, acrylic-silicone hybrids having a tensile strength of approximately 100 psi to 400 psi and a percent elongation at break of between 50% and 400% are disclosed.
    Type: Grant
    Filed: December 29, 2004
    Date of Patent: April 19, 2011
    Assignee: Abbott Medical Optics Inc.
    Inventors: Harish C. Makker, Michael D. Lowery, Can B. Hu
  • Patent number: 7928175
    Abstract: An object of the present invention is to provide an antifouling paint composition which shows an excellent antifouling effect in seawater for a long period of time, and has excellent adhesion and recoating properties to a substrate. The present invention relates to an antifouling pain composition comprising a copolymer which is obtained by polymerizing a monomer mixture comprising silicon-containing polymerizable monomer (a) having two (meth)acryl end groups, and which contains bivalent metal atom. The copolymer is also obtained by polymerizing a monomer mixture comprising silicon-containing polymerizable monomer (b) having one (meth)acryl end group, and metal atom containing polymerizable monomer (c,) having two unsaturated groups and metal atom selected from Mg, Zn, and Cu.
    Type: Grant
    Filed: March 12, 2004
    Date of Patent: April 19, 2011
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Mitsunori Sugihara, Yukihiro Ikegami, Kazuhiko Hotta, Kunio Iwase, Junichi Nakamura
  • Publication number: 20110082250
    Abstract: The invention relates to silane of formula (Ia), wherein the radicals and indices have the following meaning: R is an alkylene, arylene or alkylenearylene group that can be interrupted by one or more oxygen or sulfur atoms or carboxyl or amino groups or can carry said atoms/groups on their ends opposite the silicon atom; R1 is a Z?-substituted alkylene, arylene or alkylenearylene group, which can be interrupted by one or more oxygen or sulfur atoms or carboxyl or amino groups or can carry said atoms/groups on one of their ends; R? is an alkyl, alkanyl, aryl, alkylaryl or arylalkyl group; B and B? can be identical or different, both radicals can have the meaning of a straight-chained or branched organic group with at least one C?C double bond and at least 2 carbon atoms; B? can mean instead thereof but also —R2aSi(OR3)4-a or —R2aR?bSi(OR3)4-a-b, wherein R2 is an alkylene group and R? has the meaning defined above; X represents a group that can enter into a hydrolytic while forming Si—O—Si bridges; Z? means —NH
    Type: Application
    Filed: October 1, 2010
    Publication date: April 7, 2011
    Applicant: Fraunhofer-Gesellschaft zur Foerderung der angewandten Forschung e. V.
    Inventor: Herbert Wolter
  • Publication number: 20110082251
    Abstract: A conjugated diene polymer is provided that comprises a conjugated diene-based constituent unit and a constituent unit of formula (I) below, at least one terminus of the polymer being modified by a compound of formula (II): X1, X2, and X3 independently denote a group of formula (Ia) below, a hydroxy group, a hydrocarbyl group, or a substituted hydrocarbyl group, and at least one of X1, X2, and X3 is a group of formula (Ia) below or a hydroxy group.
    Type: Application
    Filed: December 9, 2010
    Publication date: April 7, 2011
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventor: Mayumi Oshima
  • Patent number: 7915362
    Abstract: Provided is a heat-curable silicone composition containing: (A) an organopolysiloxane having at least one structure represented by the following general formula (2) within each molecule: wherein m represents an integer of 0, 1 or 2, R1 represents a hydrogen atom, a phenyl group or a halogenated phenyl group, R2 represents a hydrogen atom or a methyl group, R3 represents an identical or different monovalent organic group having 1 to 10 carbon atoms, and R4 represents an identical or different bivalent organic group having 1 to 10 carbon atoms; and (B) a quantity of an organic peroxide that is effective as a curing catalyst. The heat-curable silicon composition yields a cured product having excellent transparency and minimal discoloration over time. Also provided is a light emitting diode element having a material composed of the cured product.
    Type: Grant
    Filed: September 21, 2007
    Date of Patent: March 29, 2011
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventor: Toshiyuki Ozai
  • Publication number: 20110065864
    Abstract: The present invention relates to a process for crosslinking polymers containing chromophoric groups, by thermal Huisgen reaction, on heat-polymerizable chromophoric polymers bearing at least one azide function and/or one alkyne function and on crosslinked polymerized materials with good orientation stability of the chromophores.
    Type: Application
    Filed: April 17, 2009
    Publication date: March 17, 2011
    Applicant: Centre National de la Recherche Scientifique (CNRS)
    Inventors: Fabrice Odobel, Annabelle Jenny Scarpaci, Errol Blart, Laurent Fontaine
  • Patent number: 7906593
    Abstract: This invention relates to a precipitated silica reinforced conjugated diene-based elastomer composition containing an alkoxysilane coupled, in-chain functionalized, conjugated diene-based elastomer and to a tire having at least one component thereof. Said in-chain functionalized conjugated diene-based elastomer is a conjugated diene-based elastomer which contains a plurality of at least one of in-chain p- and m-(2-pyrrolidinoethyl) styrene (PES) and m-(2-pyrrolidino-1-methylethyl) alpha-methylstyrene (PAMS) groups.
    Type: Grant
    Filed: April 20, 2005
    Date of Patent: March 15, 2011
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Adel Farhan Halasa, Wen-Liang Hsu, Kenneth Allen Bates, David Andrew Benko, Shingo Futamura, Kuo-Chih Hua
  • Publication number: 20110052909
    Abstract: Device for thermohydraulic applications wherein at least one portion of one surface destined for contact with water is coated with a film comprising at least one layer of a material applied by means of plasma phase polymerization of one or more monomers containing silicone. The relative method for obtaining the device comprises the following phases: to precondition a device for thermohydraulic applications within a vacuum chamber; to bring the vacuum chamber to pressure conditions between 0.01 and 100 Pa; to introduce a first gaseous mixture comprising at least a monomer containing silicone into said chamber; to bring said monomer containing silicone to the plasma state by means of an electromagnetic wave; to maintain the ionization conditions for a period of time sufficient to permit the deposit of a layer of a polymer containing said monomer on at least a portion of a surface of said device.
    Type: Application
    Filed: April 23, 2009
    Publication date: March 3, 2011
    Applicant: MOMA S.R.L.
    Inventor: Roberto Canton
  • Patent number: 7897654
    Abstract: In one aspect, the invention relates to silicone prepolymer compositions comprising a silicone prepolymer and a solvent. A soluble silicone prepolymer can be provided having increased average silicon content, thereby attaining a desired oxygen permeability. A solvent can be provided with a desired balance between hydrophilicity and hydrophobicity by selection and modification of the solvent molecular structure, resulting in molded polymer films and articles that exhibit minimal or nonexistent eye irritation and exhibit highly transparent products. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.
    Type: Grant
    Filed: April 1, 2008
    Date of Patent: March 1, 2011
    Assignees: Johnson & Johnson Vision Care Inc., Toray Industries Inc.
    Inventors: Kazuhiko Fujisawa, Mitsuru Yokota, Masataka Nakamura
  • Publication number: 20110046310
    Abstract: The present invention provides an organopolysilmethylene represented by the following general formula (1): wherein R1 is, independently of each other, a group selected from the group consisting of an unsubstituted or substituted monovalent hydrocarbon group having 1 to 10 carbon atoms, an alkoxy group, a hydroxy group, R3SiCH2— and R3SiO—, wherein R is, independently of each other, a group selected from the group consisting of an unsubstituted or substituted monovalent hydrocarbon group having 1 to 10 carbon atoms, an alkoxy group, and a hydroxy group, m is an integer of 1 to 100, and n is an integer of 1 to 100, and wherein at least two out of R1's and R's are an alkenyl group.
    Type: Application
    Filed: August 23, 2010
    Publication date: February 24, 2011
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Tsutomu KASHIWAGI, Toshio Shiobara
  • Publication number: 20110046332
    Abstract: The invention relates to a hydrogel which is a copolymer formed from a polymerizable monomer mixture which contains a) 10-65 mol % of at least one hydrophobic vinyl monomer of the formula I in which R1 is hydrogen or methyl, p is an integer from 1 to 8, whose hydroxyl groups are present in protected form, b) 25-70 mol % of at least one silicone-containing (meth)acrylate, vinyl carbonate or vinyl carbamate monomer, c) 0-25 mol % of at least one hydrophilic vinyl monomer and d) 0-10 mol % of at least one crosslinker, based on the total amount of monomers a) to c), and where the hydroxyl groups of the segments formed by the monomers a) in the hydrogel are present in protected form or in free form. The hydrogel can be used to produce contact lenses or intraocular lenses.
    Type: Application
    Filed: April 23, 2009
    Publication date: February 24, 2011
    Applicant: Evonik Roehm GmbH
    Inventors: Christine Maria Breiner, Marianne Omeis
  • Publication number: 20110045030
    Abstract: The present invention pertains to crosslinkable and crosslinked polyisobutylene-based polymers, to compositions that contain such polymers, and to medical devices that are formed using such polymers. According to one aspect, the present invention pertains to crosslinkable and crosslinked compositions that comprise a copolymer that comprises a polyisobutylene segment and two or more reactive groups. According to another aspect, the present invention pertains to medical devices that contain such compositions. According to another aspect, the present invention pertains to methods of making medical devices using such compositions.
    Type: Application
    Filed: August 20, 2010
    Publication date: February 24, 2011
    Applicant: CARDIAC PACEMAKERS, INC.
    Inventors: Shrojalkumar Desai, Mark Boden
  • Publication number: 20110046331
    Abstract: The invention provides a polymerizable composition which comprises: a) acrylates and/or methacrylates, b) 0.05% to 70% by weight of SiO2 particles having an average particle size of 1 to 30 nm which have polymerizable groups of the methacryloyl, acryloyl, styryl, itaconyl, crotonyl, vinyl, allyl and/or alkenyl type on the surface and are present in dispersion in the acrylates and/or methacrylates, at least 50% of the SiO2 particles consisting of individual, unaggregated or unagglomerated primary particles, c) not more than 2% by weight of crosslinker molecules.
    Type: Application
    Filed: April 20, 2009
    Publication date: February 24, 2011
    Applicant: NANORESINS AG
    Inventors: Klaus Langerbeins, Uwe Dietrich Kühner, Werner Siol
  • Patent number: 7888415
    Abstract: A method of polymerizing poly(cyclic)olefin monomers encompassing (a) combining a monomer composition containing the poly(cyclic)olefin monomers, a non-olefinic chain transfer agent and an activator compound to faun a mixture; (b) heating the mixture; and (c) adding a polymerization catalyst containing Ni and/or Pd. The non-olefinic chain transfer agent includes one or more compounds selected from H2, alkylsilanes, alkylalkoxysilanes, alkylgermanes, alkylalkoxygermanes, alkylstannanes, and alkylalkoxystannanes. The activator is characterized as having an active hydrogen with a pKa of at least 5. The resulting poly(cyclic)olefin polymers can be used in photoresist compositions.
    Type: Grant
    Filed: February 4, 2010
    Date of Patent: February 15, 2011
    Assignee: Promerus LLC
    Inventors: Larry F. Rhodes, Dennis A. Barnes, Andrew Bell, Brian K. Bennett, Chun Chang, John Henry Lipian, Xiaoming Wu
  • Publication number: 20110028666
    Abstract: The present invention relates to a process and to an apparatus for continuous living polymerization of cationically polymerizable monomers, in which at least three feedstocks are mixed in one or more mixers with microstructures and then polymerized in at least one reaction zone.
    Type: Application
    Filed: April 30, 2009
    Publication date: February 3, 2011
    Applicant: BASF SE
    Inventors: Wolfgang Mattmann, Wolfgang Loth, Phillip Hanefeld, Elke Guetlich-hauk, Thomas Wettling, Andreas Daiss
  • Publication number: 20110021702
    Abstract: Nanoparticles of functionalised, cross-linked vinyl polymer, usable as reinforcing filler in a polymeric matrix. The vinyl polymer is a copolymer of at least the following monomers, which are all copolymerisable by free-radical polymerisation: a non-aromatic vinyl monomer “A”; a monomer “B” bearing a function Z of formula ?Si—X, where X represents a hydroxyl or hydrolysable group; and a cross-linking monomer “C” which is at least bifunctional from the point of view of the polymerisation. The vinyl polymer is preferably a polymethacrylate, in particular a copolymer of methyl methacrylate (monomer A), trimethoxysilylpropyl methacrylate (monomer B) and ethylene glycol dimethacrylate (monomer C), being in the form of nanobeads the diameter of which is of between 10 and 100 nm.
    Type: Application
    Filed: June 29, 2007
    Publication date: January 27, 2011
    Applicant: MICHELIN RECHERCHE ET TECHNIQUE S.A.
    Inventors: Sylvie Gandon-Pain, Alain Hut
  • Publication number: 20110021730
    Abstract: Disclosed herein is a surface functionalized poly(dimethylsiloxane) (PDMS) and methods for making the same. The surface functionalized poly(dimethylsiloxane) (PDMS) disclosed herein is applicable in the general field of microfluidics, bioMEMS (bio-microelectromechanical systems), soft lithography and other related biotechnology fields.
    Type: Application
    Filed: August 29, 2008
    Publication date: January 27, 2011
    Inventor: Hongwei Ma
  • Patent number: 7875687
    Abstract: A hydrogel that is the hydrated polymerization product of a monomer mixture that includes a hydrophilic monomer and a polysiloxane-containing monomer. The resulting hydrogel has an oxygen permeability of at least about 120 Barrers, a water content of at least about 20 weight percent, and a modulus from 40 to 57 g/mm2.
    Type: Grant
    Filed: August 1, 2007
    Date of Patent: January 25, 2011
    Assignee: Bausch & Lomb Incorporated
    Inventors: Jay F. Kunzler, David E. Seelye
  • Patent number: 7875686
    Abstract: Polymeric compositions for semiconductor applications comprising 10 to 99 wt. % of norbornene-type cycloolefin monomers represented by one or more of Formula I(a), I(b), and optionally I(c) and/or I(d), 0.0005 to 0.5 wt. % of an addition polymerization procatalyst, and optionally: up to 0.5 wt. % of a cocatalyst, up to 59 wt. % of a crosslinking monomer, up to 50 wt. % of a viscosifier, up to 20 wt. % of a thixotropic additive(s), up to 80 wt. % of a filler, up to 10 wt. % of an antioxidant, and up to 0.6 wt. % of an antioxidant synergist, the total of the components of the formulation adding up to 100%. Such formulations are mass polymerized, or cured, to form polymeric compositions that have properties desirable for a variety of specific electronic, microelectronic, optoelectronic and micro-optoelectronic applications such as die attach adhesives, underfill materials, prepreg binders, encapsulants, protective layers, and other related applications.
    Type: Grant
    Filed: August 16, 2005
    Date of Patent: January 25, 2011
    Assignee: Promerus LLC
    Inventors: Ramakrisha Ravikiran, Hendra Ng, Rajesh Raja Puthenkovilakom, Linda Zhang, Dino Amoroso, Brian Knapp, Andrew Bell, Larry F. Rhodes
  • Publication number: 20110015337
    Abstract: An organopolysiloxane having a main chain composed of the following repeating units (I), 2 to 199 side chain units (II) and 1 to 50 crosslinkage units (III) per 100 SiO units in the main chain, provided that the organopolysiloxane has at least 2, on average, crosslinkage units (III):
    Type: Application
    Filed: September 30, 2010
    Publication date: January 20, 2011
    Inventors: Koji SAKUTA, Kiyomi Tachibana
  • Publication number: 20110009587
    Abstract: The present invention relates to polymeric compositions useful in the manufacture of biocompatible medical devices. More particularly, the present invention relates to certain monoethylenically unsaturated polycarbosiloxane monomers capable of polymerization to form polymeric compositions having desirable physical characteristics useful in the manufacture of ophthalmic devices.
    Type: Application
    Filed: July 9, 2009
    Publication date: January 13, 2011
    Inventors: Alok Kumar Awasthi, Jason K. Stanbro, Jay F. Kunzler, Jeffrey G. Linhardt
  • Publication number: 20110009588
    Abstract: A coupled copolymer is provided. The coupled copolymer is coupled by reacting a silane coupling agent with a copolymer, where the copolymer is polymerized by a conjugated diene monomer and a vinyl aromatics monomer, and the silane coupling agent has an alkenyl group and a alkoxy group, and has a chemical Formula (I) as follows: where R1 and R4 are alkyl groups; R3 is a group having an alkenyl group; R5 is one of an alkyl and an alkenyl groups; q is one of “1” and “0”; when q=0, then k=j=0, 1?n?3, 0?m?2, m+n=3, and R2 is alkoxy group; and when q=1, then k+j=3, R2 is —(CH2)r, r=1-6 and m+n=3.
    Type: Application
    Filed: April 6, 2010
    Publication date: January 13, 2011
    Applicant: TSRC CORPORATION
    Inventors: Chi-Chen Hsieh, Chih-Kuang Tsai, Yen-Hsian Li, Ming-Cheng Chiu
  • Patent number: 7868112
    Abstract: A polymer containing: a constitutional unit A that is derived from fluorosilsesquioxane having one addition polymerizable functional group in a molecule; a constitutional unit B that is derived from organopolysiloxane having an addition polymerizable functional group; and a constitutional unit C that is derived from an addition polymerizable monomer and has a group having a polymerizable unsaturated bond on a side chain, and optionally containing a constitutional unit D that is derived from an addition polymerizable monomer other than the fluorosilsesquioxane having one addition polymerizable functional group in a molecule, the organopolysiloxane having an addition polymerizable functional group and the addition polymerizable monomer having a functional group capable of introducing a group having a polymerizable unsaturated bond.
    Type: Grant
    Filed: December 17, 2007
    Date of Patent: January 11, 2011
    Assignee: Chisso Corporation
    Inventors: Hisao Oikawa, Koji Ohguma, Kenya Ito, Minoru Nakayama, Shin Koga, Mikio Yamahiro, Hiroyuki Sato
  • Publication number: 20110003957
    Abstract: A compound capable of satisfying both high refractive index and high light resistance, and a photocurable composition containing it, are provided. Further, an optical element having good light resistance against blue laser light, and an optical head device using it, are provided. A polymerizable compound represented by SiA1A2A3A4 wherein silicon and four cyclic groups are bonded directly or via oxygen. each of A1, A2, A3 and A4 which are independent of one another, is —(O)m—X; and each of four m's which are independent of one another, is 0 or 1. X is preferably a phenyl group. From 0 to 3 hydrogen atoms in the phenyl group are substituted by a polymerizable substituent represented by CH2?CR—COO—Y—, and some or all of remaining hydrogen atoms in the phenyl group may be substituted by a methyl group or a fluorine atom.
    Type: Application
    Filed: September 17, 2010
    Publication date: January 6, 2011
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Hiroyuki ARISHIMA, Hiroki HOTAKA
  • Patent number: 7863396
    Abstract: The present invention provides a silicon compound represented by Formula (1) and a polymer obtained by using the same, and this makes it possible not only to obtain an organic-inorganic composite material having a distinct structure but also to control the structure of the above polymer as a molecular aggregate. wherein R1 is a group independently selected from hydrogen, alkyl having a carbon atom number of 1 to 40, substituted or non-substituted aryl and substituted or non-substituted arylalkyl; in this alkyl having a carbon atom number of 1 to 40, optional hydrogens may be substituted with fluorine, and optional —CH2— may be substituted with —O—, —CH?CH—, cycloalkylene or cycloalkenylene; in alkylene in this arylalkyl, optional hydrogens may be substituted with fluorine, and optional —CH2— may be substituted with —O— or —CH?CH—; and A1 is a group having an ?-haloester group.
    Type: Grant
    Filed: March 5, 2004
    Date of Patent: January 4, 2011
    Assignee: Chisso Corporation
    Inventors: Mikio Yamahiro, Hisao Oikawa, Kenya Ito, Yasuhiro Yamamoto, Masami Tanaka, Nobumasa Ootake, Kenichi Watanabe, Kohji Ohno, Yoshinobu Tsujii, Takeshi Fukuda
  • Publication number: 20100331490
    Abstract: The present invention relates to a polyolefin composition comprising an olefin homo- or copolymer (A) in an amount of 90 wt. % or more, and an olefin homo- or copolymer (B) comprising hydrolysable silicon-containing groups, wherein olefin homo- or copolymer (B) is present in the composition in an amount of from 0.01 to 2 wt. %.
    Type: Application
    Filed: November 7, 2007
    Publication date: December 30, 2010
    Applicant: BOREALIS TECHNOLOGY OY
    Inventors: Markus Gahleitner, Tung Pham, Johannes Wolfschwenger, Doris Machl
  • Publication number: 20100323570
    Abstract: A copolymer comprises the reaction product of (a) (meth)acrylate functionalized nanoparticles, (b) vinyl monomer, and (c) silicone macromer. The (meth)acrylate functionalize nanoparticles are selected from the group consisting of silica nanoparticles, zirconia nanoparticles, titania nanoparticles, and combinations thereof.
    Type: Application
    Filed: December 19, 2008
    Publication date: December 23, 2010
    Inventors: Ramesh C. Kumar, Taun L. McKenzie, Ying-Yuh Lu
  • Publication number: 20100324246
    Abstract: Provided are a resin for an optical component, which has heat resistance, does not suffer from yellowing because of its stability against heat, and is excellent in transparency and workability; a raw material composition used for the resin for an optical component; and an optical component. Specifically, provided is a resin for an optical component containing a (meth)acrylate compound unit (A1), in which a hydrocarbon group containing an adamantane structure is ester-bonded, and a (meth)acrylate compound unit (B1) having a polyfunctional group, which is other than the unit (A1). Also, provided is a raw material composition used for a resin for an optical component, which contains a (meth)acrylate compound (A2) in which a hydrocarbon group containing an adamantane structure is ester-bonded, and a (meth)acrylate compound (B2) having a polyfunctional group, which is other than the compound (A2). Further, provided is an optical component which is obtained by polymerizing and molding the raw material composition.
    Type: Application
    Filed: June 30, 2008
    Publication date: December 23, 2010
    Applicant: IDEMITSU KOSAN CO., LTD.
    Inventors: Yutaka Obata, Takeshi Iwasaki, Tomoaki Takebe
  • Publication number: 20100317817
    Abstract: Biomedical devices such as contact lenses formed from a polymerization product of a mixture comprising (a) a random copolymer comprising hydrophilic units and hydrophobic units, wherein the random copolymer has at least one thio carbonyl thio fragment of a reversible addition fragmentation chain transfer (“RAFT”) agent are disclosed.
    Type: Application
    Filed: June 16, 2009
    Publication date: December 16, 2010
    Applicant: Bausch & Lomb Incorporated
    Inventors: Jeffrey G. Linhardt, Joseph A. McGee, Ivan M. Nunez