Contains Oxygen Atom Other Than In Amide Form Bonded To A Carbon Atom Patents (Class 526/304)
  • Patent number: 6077527
    Abstract: Pressure sensitive adhesive compositions for use in transdermal drug delivery systems comprising an adhesive composition which is tolerant to plasticization by cutaneous penetration enhancers contained in the transdermal drug formulation are disclosed. Specifically, the pressure sensitive adhesive composition of the present invention comprises an acrylic copolymer prepared from (i) at least 40% by weight of th total monomer composition of alkyl acrylate monomers with a Tg of -90 to 0.degree. C., (ii) 0-15% by weight of the total monomer composition of monomers with a Tg of 0 to 250.degree. C., and (iii) 10-60% by weight of the total monomer composition of substituted acrylamides or methacrylamides having the structural formula: ##STR1## wherein R.sub.1 is H or CH.sub.3,R.sub.2 is H or CH.sub.3, andR.sub.3 is (a) CH.sub.3,(b) C(CH.sub.3).sub.2 --(CH.sub.2).sub.n --CH.sub.3 where n is 0 through 17, or(c) substituents of the formula: ##STR2## where m is 0 through 10, and optionally(iv) at least 0.
    Type: Grant
    Filed: October 28, 1997
    Date of Patent: June 20, 2000
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Hock S. Tan, Ingrid Zhang, Susan Lydzinski, Peter L. Merkel, Paul Foreman, Smita Shah, Rama S. Chandran
  • Patent number: 6075108
    Abstract: Carbamate-functional allyl monomers and methods for making them are disclosed. The monomers, which are easy to prepare, readily polymerize with common ethylenic monomers to give low-molecular-weight resins without the need for solvents or chain-transfer agents. Coatings made from the resins should have good durability, good acid etch resistance, good mar resistance, high gloss, and high DOI.
    Type: Grant
    Filed: October 6, 1998
    Date of Patent: June 13, 2000
    Assignee: Arco Chemical Technology, L.P.
    Inventor: Shao Hua Guo
  • Patent number: 6069216
    Abstract: A cationic group-containing copolymer is provided which possesses excellent thixotropy and exhibits high adsorbability to the skin, hair, etc. and, when incorporated as a thickener in cosmetic articles, manifests a very satisfactory tactile sensation. The cationic group-containing copolymer is characterized in that the viscosity at 25.degree. C. of the aqueous solution prepared by incorporating the copolymer in deionized water at a concentration of 0.5 wt. % is in the range of 0.3-20 Pa.multidot.sec. at a shear rate of 1 sec.sup.-1 and in the range of 0.01-5 Pa.multidot.sec. at a shear rate of 10 sec.sup.-1 and the viscosity at a shear rate of 1 sec.sup.-1 is higher than the viscosity at a shear rate of 10 sec.sup.-1.
    Type: Grant
    Filed: June 3, 1998
    Date of Patent: May 30, 2000
    Assignee: Kao Corporation
    Inventors: Masaki Iwasaki, Tadanori Yoshimura, Takashi Matsuo, Koji Yui
  • Patent number: 6063961
    Abstract: A process for preparing cocondensates of aspartic acid and amines by heating aspartic acid and amines in the presence of acidic catalysts comprises supplying the feed region of the extruder with particulate aspartic acid and a downstream metering zone with at least one amine and at least one acidic catalyst, condensing the resulting mixture to such an extent by heating that the downstream end of the extruder discharges a precondensate which contains at least 20-95% by weight of the starting aspartic acid in condensed form, and then completing the condensation of the precondensate. The cocondensates are useful as incrustation inhibitors in detergents.
    Type: Grant
    Filed: December 10, 1998
    Date of Patent: May 16, 2000
    Assignee: BASF Aktiengesellschaft
    Inventor: Matthias Kroner
  • Patent number: 6057412
    Abstract: An amphipathic compound represented by any of the following Formulas: ##STR1## (R.sub.1 is a linear or branched, saturated hydrocarbon group having 6 to 48 carbon atoms, or a linear or branched, unsaturated hydrocarbon group containing 1 to 12 unsaturated double bond and having 6 to 48 carbon atoms; Y is NH, N--(CH.sub.2 --CH.dbd.CH.sub.2), or O; Q is --CH.sub.2 --C(R.sub.2).dbd.CH.sub.2 or --R.sub.4 --O--CO--C(R.sub.2).dbd.CH.sub.2 ; and M is alkali metal, an ammonium group, or --(CH.sub.2 CH.sub.2 O).sub.m H), a copolymer of the amphipatic compound with a copolymerizable ethylenically unsaturated compound and, a paper making additive containing a water soluble or dispersible high molecular compound as an active ingredient and processes for producing these high molecular compounds.
    Type: Grant
    Filed: July 17, 1998
    Date of Patent: May 2, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Toshihiko Takaki, Masaru Tanabe, Hiroshi Itoh, Masayuki Yanagi, Shoko Oyanagi, Hiroyoshi Watanabe
  • Patent number: 6048587
    Abstract: Radiation-curable resins as well as thermal and electron-beam-curable resins are provided comprising a polymeric backbone having acrylate or vinyl ether substituents and an ionically bonded neutralizing agent such as an aminoacrylate. These resins are hydrophilic and water-dispersible before curing, but resistant to most solvents including water after curing while preserving a hard, strong, adhesive character which makes them suitable for use as coatings and fabrication of three-dimensional structures in a wide variety of applications.
    Type: Grant
    Filed: October 1, 1998
    Date of Patent: April 11, 2000
    Assignee: Ricon Resins, Inc.
    Inventor: Tanya Estrin
  • Patent number: 6043328
    Abstract: The present invention describes a polysiloxane-polyol macromer which is uninterrupted or interrupted by a bivalent structural element and furthermore carries at least one polymerizable segment on a polyol segment; a polymer comprising a polymerization product of at least one macromer according to the invention and, if appropriate, of at least one vinylic comonomer; intermediates; processes for the preparation of a macromer and a polymerization product; moldings, contact lenses, corneal implants or biomedical articles of a polymerization product; and furthermore the use of a macromer according to the invention or of a polymer prepared therefrom for coating a substrate.
    Type: Grant
    Filed: November 17, 1997
    Date of Patent: March 28, 2000
    Assignee: Novartis AG
    Inventors: Angelika Domschke, Dieter Lohmann, Jens Hopken
  • Patent number: 6005040
    Abstract: Methods for dispersing and binding ceramic materials in aqueous media are disclosed. The methods utilize water-soluble polymers having pendant derivatized amide, ester or ether functionalities for dispersing and binding various classes of ceramic materials.
    Type: Grant
    Filed: November 5, 1998
    Date of Patent: December 21, 1999
    Assignee: Nalco Chemical Company
    Inventors: Christopher P. Howland, Kevin J. Moeggenborg, John D. Morris, Peter E. Reed, Jiansheng Tang, Jin-Shan Wang
  • Patent number: 5962577
    Abstract: An aqueous resin composition for coating a metal, which can form a coating film having excellent water resistance and also having high hardness and excellent workability even after being subjected to a pressurized steam treatment is provided. The aqueous resin composition comprises (A) an aqueous copolymer obtained by neutralizing with a base carboxyl groups in a copolymer which is obtained by copolymerizing (a) a macromonomer which is a copolymer of N-alkoxymethyl (meth)acrylamide monomer units and other .alpha.,.beta.-ethylenically unsaturated monomer units, having a radically polymerizable group at one end thereof, (b) .alpha.,.beta.-ethylenically unsaturated carboxylic acid, (c) hydroxyalkyl (meth)acrylate, and (d) other .alpha.,.beta.-ethylenically unsaturated monomers, in specific proportions, and (B) an amino resin.
    Type: Grant
    Filed: March 17, 1997
    Date of Patent: October 5, 1999
    Assignee: Toagosei Co., Ltd.
    Inventors: Yoshio Mori, Shiro Kojima
  • Patent number: 5959122
    Abstract: A process for making derivatized polymers of maleic anhydride containing maleamic acid and its corresponding cyclic imide repeat units, in alcohol solution, at a temperature of about 60-160.degree. C., during a reaction period of about 1-25 hours. The product is a polymer having a predetermined ratio of the above repeat units.
    Type: Grant
    Filed: June 24, 1998
    Date of Patent: September 28, 1999
    Assignee: ISP Investments Inc.
    Inventors: Herbert W. Ulmer, John A. Katirgis, Timothy Gillece
  • Patent number: 5945457
    Abstract: A hemocompatible composition comprising a polymer containing at least one pharmacologic material chemically bonded to a polymer backbone. Such compositions may be obtained by reacting a pharmacologic material with a compound containing a polymerizable group (e.g., an acyl halide) and thereafter either copolymerizing the acylated material with one or more copolymerizable monomers or first irradiating a backbone polymer and thereafter grafting the acylated pharmacologic material onto the irradiated polymer. The resulting products are hemocompatible and may be used in the manufacture of medical devices which come in contact with blood or other bodily fluids. The advantage of chemically bonded pharmacologic materials is that they are not leached out and retain their pharmaceutical effectiveness for a long period of time. The compositions may contain one or more additional pharmacologic materials which are physically admixed with polymers containing bonded pharmacologic materials.
    Type: Grant
    Filed: October 1, 1997
    Date of Patent: August 31, 1999
    Assignee: A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Science
    Inventors: Nicolai A. Plate, Lev I. Valuev, Lubov D. Uzhinova, Vladimir A. Sinani
  • Patent number: 5932674
    Abstract: The invention relates to a novel process for the production of mouldings, in particular contact lenses, in which a soluble prepolymer comprising units containing a crosslinkable group and at least one unit containing a modifier is crosslinked in solution, and to mouldings, in particular contact lenses, obtainable by this process. The present invention likewise relates to novel prepolymers which can be employed in the novel process, in particular derivatives of a polyvinyl alcohol having a molecular weight of at least about 2000 which comprises from about 0.
    Type: Grant
    Filed: July 30, 1997
    Date of Patent: August 3, 1999
    Assignee: Novartis AG
    Inventor: Beat Muller
  • Patent number: 5921779
    Abstract: A formulation for use as a dental adhesive in the treatment of the hard tooth substance, to provide enhanced bonding between dental restoration material and the enamel and dentine of the tooth. The formulation contains glycerol di(meth)acrylate, volatile solvent, photo-initiator and, optionally, usual additives and fillers.
    Type: Grant
    Filed: November 13, 1996
    Date of Patent: July 13, 1999
    Assignee: Heraeus Kulzer GmbH & Co. KG
    Inventors: Wolfgang Podszun, Werner Finger, Ludger Heiliger
  • Patent number: 5905127
    Abstract: Mesogens are provided based on substituted unsaturated carboxylic acids such as acrylic and methacrylic acid. Substitution of a variety of hydrophobic tails onto the carboxylic acid or acid derivative via the vinyl carbon proximal to the carbonyl of the carboxylic acid results in mesogens that are capable of forming thermotropic and single-phase lyotropic mesophases over a broad range of compositions. The mesophases can be polymerized to lock in the ordered phases.
    Type: Grant
    Filed: April 8, 1997
    Date of Patent: May 18, 1999
    Assignee: The University of Southern Mississippi
    Inventors: Robert Y Lochhead, Lon J Mathias
  • Patent number: 5886116
    Abstract: A novel ethylenically-unsaturated 1,3-diketoamide functional compound, polymers comprised thereof, and latex formulations containing polymeric ingredients having 1,3-diketoamide functional pendant moieties are disclosed. The 1,3-diketoamide functional pendant moieties have excellent hydrolytic stability.
    Type: Grant
    Filed: May 28, 1997
    Date of Patent: March 23, 1999
    Assignee: S.C. Johnson Commercial Markets, Inc.
    Inventor: David L. Trumbo
  • Patent number: 5886121
    Abstract: This invention covers the use of cross-linkable redispersible dispersion powders based on vinyl ester copolymers or (meth)acrylic acid ester copolymers as binders for the dry binding of fiber materials.
    Type: Grant
    Filed: April 7, 1997
    Date of Patent: March 23, 1999
    Assignee: Wecker-Chemie GmbH
    Inventors: Johannes Kinkel, Gerhard Brink, Walter Ernet, Joachim Schulze, Konrad Wierer
  • Patent number: 5880237
    Abstract: Methods for dispersing and binding ceramic materials in aqueous media are disclosed. The methods utilize water-soluble polymers having pendant derivatized amide, ester or ether functionalities for dispersing and binding various classes of ceramic materials.
    Type: Grant
    Filed: December 4, 1997
    Date of Patent: March 9, 1999
    Assignee: Nalco Chemical Company
    Inventors: Christopher P. Howland, Kevin J. Moeggenborg, John D. Morris, Peter E. Reed, Jiansheng Tang, Jin-Shan Wang
  • Patent number: 5880236
    Abstract: Water-thickening copolymers are obtainable by copolymerization of(A) one or more monomers of the formula IR.sup.1 HC.dbd.CR.sup.2 R.sup.3 IwhereR.sup.1 and R.sup.2 can be identical or different and each is H or C.sub.1 -C.sub.5 -alkyl, andR.sup.3 is ##STR1## where R.sup.1 and R.sup.2 can be identical or different and each is H or C.sub.1 -C.sub.5 -alkyl,R.sup.4 is H or C.sub.1 -C.sub.5 -alkyl,R.sup.5 is C.sub.1 -C.sub.4 -alkylene,R.sup.6 and R.sup.7 can be identical or different and each is H or C.sub.1 -C.sub.3 -alkyl, andM is hydrogen or an alkali metal, 1/2 alkaline earth metal or ammonium ion, and(B) one or more monomers of the formula IIa or IIb ##STR2## where R.sup.1 and R.sup.2 can be identical or different and each is H or C.sub.1 -C.sub.5 -alkyl,R.sup.4 is H or C.sub.1 -C.sub.5 -alkyl,X is --COOM where M is hydrogen or alkali metal, 1/2 alkaline earth metal or ammonium ion,Y is ##STR3## where R.sup.8 is C.sub.6 -C.sub.30 -alkyl, alkylaryl or aryl and R.sup.9 is H, C.sub.1 -C.sub.
    Type: Grant
    Filed: April 13, 1993
    Date of Patent: March 9, 1999
    Inventors: Gerd Konrad, Heinrich Hartmann
  • Patent number: 5856418
    Abstract: A water-soluble monomer is shown by general formula (1) below. This monomer, for example, can be obtained by reacting asparagic acid and maleic anhydride in an aqueous basic solution under cooled conditions. A water-soluble polymer has a structural unit of general formula (2) below and a weight-average molecular weight of about 800 to about 8,000,000, and is, for example, produced by polymerizing a monomer including the water-soluble monomer of general formula (1). The water-soluble polymer has excellent chelating and dispersing actions and therefore can favorably be used for various purposes, such as, detergent compositions, inorganic-pigment dispersants, fiber-treating agents, water-treating agents, wood pulp-bleaching assistants.
    Type: Grant
    Filed: April 9, 1997
    Date of Patent: January 5, 1999
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Yoshihiro Maeda, Shigeru Yamaguchi
  • Patent number: 5849270
    Abstract: The adhesion of resin material to the solid substance of the tooth and to metals and metal alloys, for example, dental alloys, can be improved with a photo-polymerizable formulation containing hydroxyalkyl(meth)acrylates, urethanedi(meth)acrylates and, if applicable, esters of aromatic polycarboxylic acids possessing methacryloyloxy groups.
    Type: Grant
    Filed: January 22, 1997
    Date of Patent: December 15, 1998
    Assignee: Heraeus Kulzer GmbH
    Inventors: Wolfgang Podszun, Werner Finger
  • Patent number: 5840877
    Abstract: Electrophoresis gels of enhanced selectivity are produced by adding a preformed polymer to a polymerization solution containing at least one monomer and at least one cross-linker. The polymer must be of such a chemical composition and molecular weight that its presence during free-radical polymerization results in a new topology of gel polymers, so that under the influence of an electric field, such as during electrophoresis, the passage of long DNA molecules through the gel is retarded proportionally more than the passage of the short ones. The polymer needs to be added at specific ratio to the monomer and the cross-linker, and the enhanced selectivity is achievable only within a certain range of ratios of polymer(s), monomer(s) and cross linker(s). That range is dependent on all three essential gel components, the polymer, the monomer and the cross-linker.
    Type: Grant
    Filed: September 5, 1996
    Date of Patent: November 24, 1998
    Assignee: Guest Elchrom Scientific
    Inventor: Branko Kozulic
  • Patent number: 5821312
    Abstract: The present invention includes polymerizable monomers comprising an acid-functionalized glycoside moiety. The monomer can have a polymerizable functional group, such as an olefinic bond, to which the acid-functionalized glycoside moiety is attached by a spacer group, for example, an alkylene group, or an alkylene group wherein one or more carbon atoms are substituted by heteroatoms, such as oxygen, nitrogen or sulfur atoms. The present invention also includes polymers comprising pendant acid-functionalized glycoside moieties. The present invention also provides a method for treating a microbial infection in a mammal by administering to the mammal a therapeutically effective amount of a polymer comprising one or more acid-functionalized glycoside moieties.
    Type: Grant
    Filed: June 25, 1997
    Date of Patent: October 13, 1998
    Assignee: GelTex Pharmaceuticals, Inc.
    Inventors: W. Harry Mandeville, III, Venkata R. Garigapati
  • Patent number: 5817727
    Abstract: The present invention pertains to a film for detecting chemical substances comprising a homopolymer or a copolymer having recurring units represented by the following formula (I): ##STR1## wherein X is --H, --F, --Cl, --Br, --CH.sub.3, --CF.sub.3, --CN or --CH.sub.2 CH.sub.3 ; and R.sup.1 is --R.sup.2 or --Z--R.sup.2 ;wherein Z is --O--, --S--, --NH--, --NR.sup.2' --, --(C.dbd.Y)--, --(C.dbd.Y)--Y--, --Y--(C.dbd.Y)--, --(SO.sub.2)--, --Y'--(SO.sub.2)--, --(SO.sub.2)--Y'--, --Y'--(SO.sub.2)--Y'--, --NH--(C.dbd.O)--, --(C.dbd.O)--NH--, --(C.dbd.O)--NR.sup.2' --, --Y'--(C.dbd.Y)--Y'-- or --O--(C.dbd.O)--(CH.sub.2).sub.n --(C.dbd.O)--O--;wherein Y is independently O or S, and Y' is independently O or NH, and n is an integer of 0 to 20;and wherein R.sup.2 and R.sup.2' represent independently a hydrogen atom, a linear alkyl group, a branched alkyl group, a cycloalkyl group, an unsaturated hydrocarbon group, an aryl group, a saturated or unsaturated hetero ring or derivatives thereof, provided that R.sup.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: October 6, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Werner Prass, Thomas Stehlin, Yuan Liu, Shizuo Ogura, Tetsu Yamamoto, Akihiko Tokida, Kenji Motosugi
  • Patent number: 5780566
    Abstract: Novel polymers may be used in resist formulations for the fabrication of printing plates and circuit boards and, in particular, for the fabrication of integrated circuits. No autocatalytic decomposition of the compounds occurs and the resist film obtained therewith has good adhesive properties.
    Type: Grant
    Filed: October 26, 1995
    Date of Patent: July 14, 1998
    Assignee: Olin Microelectronic Chemicals, Inc.
    Inventor: Carl-Lorenz Mertesdorf
  • Patent number: 5747635
    Abstract: Modified polyaspartic acids useful as detergent and cleaner additives, as water treatment agents and as scale inhibitors in the evaporation of sugar juice are obtainable by polycondensation of(a) from 1 to 99.9 mol % of aspartic acid with(b) from 99 to 0.1 mol % of fatty acids, polybasic carboxylic acids, anhydrides of polybasic carboxylic acids, polybasic hydroxycarboxylic acids, monobasic polyhydroxycarboxylic acids, alcohols, amines, alkoxylated alcohols and amines, amino sugars, carbohydrates, sugarcarboxylic acids and/or non-proteinogenic aminocarboxylic acidsor by polymerizing monoethylenically unsaturated monomers in the presence of polyaspartic acids in the manner of a free-radically initiated graft polymerization.
    Type: Grant
    Filed: January 3, 1995
    Date of Patent: May 5, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Heinrich Hartmann, Dieter Boeckh, Angelika Funhoff, Richard Baur, Alexander Kud, Volker Schwendemann, Birgit Potthoff-Karl, Karl-Heinz Buechner
  • Patent number: 5726267
    Abstract: Methods for dispersing and binding ceramic materials in aqueous media are disclosed. The methods utilize water-soluble polymers having pendant derivatized amide, ester or ether functionalities for dispersing and binding various classes of ceramic materials.
    Type: Grant
    Filed: January 31, 1997
    Date of Patent: March 10, 1998
    Assignee: Nalco Chemical Company
    Inventors: Christopher P. Howland, Kevin J. Moeggenborg, John D. Morris, Peter E. Reed, Jiansheng Tang, Jin-shan Wang
  • Patent number: 5716981
    Abstract: The present invention provides compositions comprising an anti-angiogenic factor, and a polymeric carrier. Representative examples of anti-angiogenic factors include Anti-Invasive Factor, Retinoic acids and derivatives thereof, and paclitaxel. Also provided are methods for embolizing blood vessels, and eliminating biliary, urethral, esophageal, and tracheal/bronchial obstructions.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: February 10, 1998
    Assignee: Angiogenesis Technologies, Inc.
    Inventors: William L. Hunter, Lindsay S. Machan, A. Larry Arsenault
  • Patent number: 5717049
    Abstract: Novel biocompatible, high strength hydrogels useful in intraocular lenses are provided which are optically transparent, have high refractive indices and possess long term stability. The hydrogels are prepared from cross-linked copolymers of N-benzyl-N-methylacrylamide.
    Type: Grant
    Filed: March 25, 1996
    Date of Patent: February 10, 1998
    Assignee: Pharmacia Iovision, Inc.
    Inventors: Xiugao Liao, Yading Wang, Stephen Q. Zhou
  • Patent number: 5717046
    Abstract: The present invention relates to retention aids for papermaking, in particular which comprise cationic multiarmed star-like polymers of formula (I):(D).sub.y --(A).brket open-st.B--(CH.sub.2).sub.n --(E).sub.p --(F).sub.q .brket close-st..sub.x (I)as an effective component to improve the retention of fines fraction by structural characteristics of multiarmed polymer chains connected with one starting point on the compound. In formula (I), A is ##STR1## B is --O-- or --COO--; D is --OH; E is ##STR2## F is ##STR3## wherein, R.sup.1 --R.sup.11 are independently hydrogen or alkyl; R.sub.a --R.sub.d are independently hydrogen or alkyl; X.sup.- is ##STR4## x is an integer selected from 3 to 24; y is an integer selected from 0 to 21; n is an integer selected from 3 to 6; p is an integer selected from 300 to 4000; and q is an integer selected from 0 to 1000.
    Type: Grant
    Filed: January 19, 1996
    Date of Patent: February 10, 1998
    Assignee: Korea Research Institute of Chemical Technology
    Inventors: Jong Ho Shin, Sin Ho Han, Say Kyoun Ow
  • Patent number: 5702642
    Abstract: The polymeric compound of this invention is represented by the following general formula (I): ##STR1## wherein A represents a hydrogen atom or ##STR2## B represents a hydrogen atom or ##STR3## each of X.sub.1 and X.sub.2 represents independently a hydrogen atom or a methyl group, each of m and n represents independently an integer of 0 to 14, each of p and q represents independently 0 or 1, and each of Y1 , Y.sub.2, Y.sub.3, and Y.sub.4 represents independently a hydrogen atom or a fluorine atom, with the proviso that both A and B are not hydrogen atoms, p is 0 when m is 0, and q is 0 when n is 0.
    Type: Grant
    Filed: February 11, 1997
    Date of Patent: December 30, 1997
    Assignees: Sharp Kabushiki Kaisha, Kanto Kagaku Kabushiki Kaisha
    Inventors: Nobuaki Yamada, Shuichi Kozaki, Hoyo Mizobe, Masahiko Yoshida, Kenji Suzuki
  • Patent number: 5700873
    Abstract: A method is provided for the production of a water-soluble or water-dispersible copolymer. The copolymer is comprised of a water-soluble base monomer and/or a water-soluble or water-dispersible macromer. The disclosed method involves a two step polymerization procedure wherein in a first step a minor portion of the reactants are polymerized to conversion under conditions which result in the formation of a low molecular weight product, and in a second step the remaining portion of the reactants are polymerized to conversion in the presence of the reaction product of the first step under conditions which result in the production of a higher molecular weight product.
    Type: Grant
    Filed: December 14, 1995
    Date of Patent: December 23, 1997
    Assignee: Adhesives Research, Inc.
    Inventors: Michael J. Zajaczkowski, Barbara A. Stutzman
  • Patent number: 5693320
    Abstract: Novel acetylsalicylic acid derivatives having general formula (I) are provided, in which R.sup.1 is hydrogen or methyl; R.sup.2 is --O-- or --NH--; and W is hydroxy, halogen, lower alkoxy, lower alkenyloxy, lower alkynyloxy, cycloalkyloxy, aryloxy, aralkyloxy, acyloxy, or --N(R.sup.3)(R.sup.4) wherein the lower alkoxy, the lower alkenyloxy, the lower alkynyloxy, the cycloalkyloxy, the aryloxy, the aralkyloxy, and the acyloxy are optionally substituted with hydroxy, carboxyl, lower alkoxy, lower alkyl, halogen, nitro, and amino. The invention also pertains to a polymer made from such derivatives and a medical equipment containing the polymer. The polymer is useful in the prevention of platelet aggregation thereon.
    Type: Grant
    Filed: March 12, 1996
    Date of Patent: December 2, 1997
    Assignee: Ube Industries, Ltd.
    Inventors: Masamune Sakai, Hiroyuki Ikeda, Noriaki Kaneko, Yutaka Tamura
  • Patent number: 5684104
    Abstract: Method for avoiding network defects due to unwanted secondary reactions during the polymerization in water-swellable hydrophilic polymers which contain polymers prepared by free radical (co)polymerization of one or more hydrophilic monomers of the formula I ##STR1## wherein R.sup.1 is hydrogen, methyl or ethyl,R.sup.2 is the group --COOR.sup.4, the sulphonyl group, the phosphonyl group, the phosphonyl group-esterified by (C.sub.1 -C.sub.4)-alkanol or a group of the formula ##STR2## R.sup.3 is hydrogen, methyl, ethyl or the carboxyl group, R.sup.4 is hydrogen, amino or hydroxy-(C.sub.1 -C.sub.4)-alkyl andR.sup.5 is the sulphonyl group, the phosphonyl group or the carboxyl group, or grafting (co)polymerization of one or more hydrophilic monomers of the formula I onto a grafting base, using a free radical initiator which forms three or more free radical sites per molecule.
    Type: Grant
    Filed: July 18, 1996
    Date of Patent: November 4, 1997
    Assignee: Cassella
    Inventors: Rudiger Funk, Fritz Engelhardt, Ulrich Riegel, Michael Wessling
  • Patent number: 5665844
    Abstract: The present invention pertains to a film for detecting chemical substances comprising a homopolymer or a copolymer having recurring units represented by the following formula (I): ##STR1## wherein X is --H, --F, --Cl, --Br, --CH.sub.3, --CF.sub.3, --CN or --CH.sub.2 CH.sub.3 ; and R.sup.1 is --R.sup.2 or --Z--R.sup.2 ;wherein Z is --O--, --S--, --NH--, --NR.sup.2' --, --(C.dbd.Y)--, --(C.dbd.Y)--Y--, --Y--(C.dbd.Y)--, --(SO.sub.2)--, --Y'--(SO.sub.2)--, --(SO.sub.2)--Y'--, --Y'--(SO.sub.2)--Y'--, --NH--(C.dbd.O)--, --(C.dbd.O)--NH--, --(C.dbd.O)--NR.sup.2' --, --Y'--(C.dbd.Y)--Y'-- or --O--(C.dbd.O)--(CH.sub.2).sub.n --(C.dbd.O)--O--;wherein Y is independently O or S, and Y' is independently O or NH, and n is an integer of 0 to 20;and wherein R.sup.2 and R.sup.2' represent independently a hydrogen atom, a linear alkyl group, a branched alkyl group, a cycloalkyl group, an unsaturated hydrocarbon group, an aryl group, a saturated or unsaturated hetero ring or derivatives thereof, provided that R.sup.
    Type: Grant
    Filed: November 15, 1993
    Date of Patent: September 9, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Werner Prass, Thomas Stehlin, Yuan Liu, Shizuo Ogura, Tetsu Yamamoto, Akihiko Tokida, Kenji Motosugi
  • Patent number: 5663261
    Abstract: A film-forming resin which is a copolymer of (meth)acrylamide and (meth)acrylate monomers is disclosed. The film-forming resin can sustain a hair style over a prolonged period of time, even under high humidity, when used in a hair care product. Further, it is excellent in shampoo-washability and set-retaining power.
    Type: Grant
    Filed: January 3, 1996
    Date of Patent: September 2, 1997
    Assignee: Kao Corporation
    Inventors: Naomi Hori, Takashi Oda, Takako Taya, Katsumi Mita
  • Patent number: 5652296
    Abstract: A water-based adhesive comprising water-soluble polymers having carboxy groups and quaternary ammonium groups wherein the polymers can be derived by copolymerizing one or more unsaturated aliphatic carboxylic acid monomers, such as acrylic acid and/or methacrylic acid, and alkylaminoalkyl(meth)acrylate or alkylaminoalkyl(meth)acrylamide, such as dimethylaminoethyl methacrylate or dimethylaminopropylmethacrylamide and the water-based adhesive is a viscous liquid that is colorless, relatively odorless, and free of organic solvents.
    Type: Grant
    Filed: March 15, 1996
    Date of Patent: July 29, 1997
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Neil A. Randen
  • Patent number: 5644010
    Abstract: A curable liquid resin which can give a coating composition capable of forming a film, the curable liquid resin being a copolymer obtained from(A) a monomer of the formula (1) or (2),CH.sub.2 .dbd.C(R.sup.1)COO--R.sup.2 (1)CH.sub.2 .dbd.C(R.sup.3)COO(C.sub.n H.sub.2n O).sub.m--R.sup.4(2)and(B) at least one monomer selected from the group consisting of(B1) a monomer prepared by reacting an ethylenically unsaturated epoxide (a) with a fatty acid (b) of the formula (3)R.sup.5 COOH (3)(B2) a monomer of the formula (4),CH.sub.2 .dbd.C(R.sup.6)CONR.sup.7 R.sup.8 (4)and(B3) a monomer whose molecule has at least two ethylenically unsaturated double bonds.
    Type: Grant
    Filed: July 18, 1995
    Date of Patent: July 1, 1997
    Assignee: Toyo Ink Manufacturing Co., Ltd.
    Inventors: Toru Kurihashi, Miki Kawashima, Takeo Yamaguchi
  • Patent number: 5641846
    Abstract: Side-group polymers whose permanently shape-anisotropic side groups carry lateral substituents are particularly suitable, owing to their excellent properties, for optical components which can be employed, in particular, in optical data storage and transfer.
    Type: Grant
    Filed: September 22, 1995
    Date of Patent: June 24, 1997
    Assignee: Bayer Aktiengesellschaft
    Inventors: Thomas Bieringer, Uwe Gessner, Dietrich Haarer, Joachim Rubner, Roland Wuttke, Uwe Claussen, Ralf Ruhmann, Horst Berneth, Sergei Kostromin, Ralf Neigl
  • Patent number: 5637640
    Abstract: It has been determined that rubbery terpolymers of a conjugated diolefin monomer, a vinyl aromatic monomer, and N-(isobutoxymethyl) acrylamide (IBMA) tan be used to modify asphalt cement to greatly enhance the resistance to shoving, rutting, and low temperature cracking of asphalt concretes made therewith. These rubbery polymers have a Mooney viscosity which is within the range of about 35 to about 80. It has further been determined that these rubbery terpolymers are compatible with virtually all types of asphalt. It is particularly preferred for the rubbery polymers of this invention to also contain repeat units which are derived from hydroxypropyl methacrylate (HPMA).
    Type: Grant
    Filed: March 25, 1996
    Date of Patent: June 10, 1997
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Gerald O. Schulz, Daniel F. Klemmensen
  • Patent number: 5635574
    Abstract: A method for the production of a microsphere without use of a dispersion stabilizer is disclosed which permits the microsphere to be produced in the form of discrete particles readily treatable for purification. The method which produces this microsphere comprises the steps of dissolving in an organic solvent such as an alcohol a monomer mixture including an ethylenically unsaturated amide and 10 to 70% by weight, based on 100% by weight of said monomer mixture, of a cross-linking agent thereby preparing a mixed solution, keeping said mixed solution at a temperature in the range of from 30.degree. to 95.degree. C., and adding thereto at least one initiator selected from the group consisting of peroxide type initiators and azo type initiators in an amount such as to be contained therein at a final concentration in the range of from 1.times.10.sup.-5 to 8.times.10.sup.-2 mol/liter thereby inducing polymerization of said monomer mixture.
    Type: Grant
    Filed: March 15, 1996
    Date of Patent: June 3, 1997
    Assignee: Fujimoro Kogyo Co., Ltd.
    Inventors: Juuro Aoyagi, Toyoaki Suzuki, Reiko Kato, Masanori Nagata
  • Patent number: 5633310
    Abstract: Novel water-soluble linear copolymers of vinylacetate with monomeric addition products of amines, amino acids, amino groups containing aromatic sulfonic acids, amino alcohols of maleic anthydride. The copolymers are useful as fluidizers in water containing solid matter suspensions.
    Type: Grant
    Filed: December 28, 1993
    Date of Patent: May 27, 1997
    Assignee: Sika AG, vorm. Kaspar Winkler & Co.
    Inventors: Ueli Sulser, Anna Huber, J urg Widmer
  • Patent number: 5623015
    Abstract: A latex binder composition which is the reaction product of a conjugated diene monomer and a vinyl-substituted aromatic monomer along with minor amounts of other comonomers including acrylamide or a derivative thereof, methacrylic acid, N-methylolacrylamide, and optional unsaturated carboxylic acids, has an average particle size of less than 1,500 .ANG.. The latex binder which has good stability can be used on nonwoven cellulosic based substrates to impart high wet tensile strength thereto.
    Type: Grant
    Filed: April 4, 1996
    Date of Patent: April 22, 1997
    Assignee: GenCorp Inc.
    Inventors: David F. Diehl, Peter C. Hayes
  • Patent number: 5621058
    Abstract: The present invention provides hydrophilic crosslinked polymer fine particles made of a copolymer composed of:2-50% by weight of (a) a monoethylenic monomer having a polyoxyalkylene or polyvinylpyrrolidone chain,20-97% by weight of (b) a (meth)acrylamide type monoethylenic monomer,1-30% by weight of (c) a crosslinkable unsaturated monomer having at least one N-methylol or N-alkoxymethyl group and a polymerizable double bond, and0-50% by weight of (d) other monoethylenic monomer.Said polymer fine particles are superior in polymerization stability as well as in dispersion stability during storage, undergoes no adverse effect by dispersion stabilizer owing to no use of said stabilizer, and are suitably used for formation of a hydrophilic film.
    Type: Grant
    Filed: October 24, 1995
    Date of Patent: April 15, 1997
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Masahiro Kondo, Hiromi Harakawa, Hiroshi Inoue
  • Patent number: 5618898
    Abstract: A process for producing a polymer of excellent weatherability, which comprises reacting a polymer having a thioether bond, with a peroxide to oxidize the sulfur atom in the bond to convert it into a sulfone.
    Type: Grant
    Filed: October 5, 1994
    Date of Patent: April 8, 1997
    Assignees: Toagosei Chemical Industry Co., Ltd., Toyota Jidosha Kabushiki Kaisha, Toyota Technological Institute
    Inventors: Mitsuru Nagasawa, Kazuyuki Kuwano, Takeshi Kawakami, Mamoru Sugiura, Hiroshi Hibino, Shiro Kojima, Kishiro Azuma
  • Patent number: 5612388
    Abstract: A polyfunctional cationic monomer produced by reacting a tertiary amine having a polymerizable vinyl group with a compound having two or more oxirane groups. The polyfunctional cationic monomer of the present invention shows a very high curing rate and a high reaction suitability as a radiation cure coating to be applied onto the surface of a molded article made of plastics, wood, metals, etc. or the surface of a sheet such as a paper, a film, a metal plate, a knitted web, etc.
    Type: Grant
    Filed: September 15, 1995
    Date of Patent: March 18, 1997
    Assignee: Nitto Chemical Industry Co., Ltd.
    Inventors: Tadashi Irizawa, Masahiko Morooka, Masahiko Miyanoki
  • Patent number: 5610255
    Abstract: Polysuccinimide and polyaspartic acid are prepared by polymerizing maleic anhydride, ammonia and water or maleic acid derivatives or fumaric acid derivatives in bulk or dissolved in solvents in a continuous kneading reactor. The polysuccinimide formed can be converted into polyaspartic acid and polyaspartate salts by hydrolysis.
    Type: Grant
    Filed: August 18, 1995
    Date of Patent: March 11, 1997
    Assignee: Bayer AG
    Inventors: Torsten Groth, Winfried Joentgen, Nikolaus M uller, Ulrich Liesenfelder
  • Patent number: 5604291
    Abstract: Phosphonic telomer intermediates for preparing the telomers of U.S. Pat. No. 5,376,731 may be produced by an aqueous process comprising (a) reacting hypophosphorous acid with a carbonyl compound which is preferably an aldehyde, a ketone or an imine, and (b) reacting the product of (a) with an olefinic reactant or reactants in the presence of a suitable initiator especially a free radical initiator. The telomer intermediates are themselves useful as scale inhibitors in aqueous systems.
    Type: Grant
    Filed: September 16, 1994
    Date of Patent: February 18, 1997
    Assignee: FMC Corporation (UK) Limited
    Inventors: Elizabeth A. Kerr, Jan Rideout
  • Patent number: 5594083
    Abstract: Water-swellable hydrophilic polymers which contain polymers prepared by free radical (co)polymerization of one or more hydrophilic monomers of the formula I ##STR1## wherein R.sup.1 is hydrogen, methyl or ethyl,R.sup.2 is the group --COOR.sup.4, the sulphonyl group, the phosphonyl group, the phosphonyl group esterified by (C.sub.1 -C.sub.4)-alkanol or a group of the formula ##STR2## R.sup.3 is hydrogen, methyl, ethyl or the carboxyl group, R.sup.4 is hydrogen, amino or hydroxy-(C.sub.1 -C.sub.4)-alkyl andR.sup.5 is the sulphonyl group, the phosphonyl group or the carboxyl group, or grafting (co)polymerization of one or more hydrophilic monomers of the formula I onto a grafting base, using a free radical initiator which forms three or more free radical sites per molecule.
    Type: Grant
    Filed: March 22, 1995
    Date of Patent: January 14, 1997
    Assignee: Cassella Aktiengesellschaft
    Inventors: R udiger Funk, Fritz Engelhardt, Ulrich Riegel, Michael Wessling
  • Patent number: 5594085
    Abstract: Urea and urethane-containing monomers for contact lens materials are disclosed.
    Type: Grant
    Filed: May 16, 1995
    Date of Patent: January 14, 1997
    Assignee: Bausch & Lomb Incorporated
    Inventor: Yu-Chin Lai
  • Patent number: RE36625
    Abstract: The invention is concerned with linear and cyclic polymers or oligomers having a photoreactive ethene group. The polymers are of the formula ##STR1## wherein M.sub.a, M.sub.b, M.sub.c are monomer units for homo- or copolymers;x, y, z are mole fractions of the copolymers, whereby in each case 0<x.ltoreq.1; 0.ltoreq.y.ltoreq.1 and 0.ltoreq.z<1;S.sub.a, S.sub.b are spacer units;Z.sub.a, Z.sub.b are molecular units which can undergo photochemical isomerization/dimerization;n is a magnitude of 4-100 000 andm is 0 or 1,The compounds are used as an orienting layer for liquid cyrstals.
    Type: Grant
    Filed: July 21, 1998
    Date of Patent: March 21, 2000
    Assignee: Rolic AG
    Inventors: Rolf-Peter Herr, Stephen Kelly, Martin Schadt, Klauss Schmitt, Andreas Schuster