Abstract: A preparation method of a molecularly imprinted polymer (MIP) for separation and concentration of 4-methylsterane compounds is provided. A template molecule, a functional monomer, a porogen, an initiator and a cross-linking agent are mixed and subjected to polymerization to prepare a polymer with the template molecule, which is then treated to remove the template molecule, so as to give the desired MIP. The template molecule is ?-sitosterol or deoxycholic acid. The obtained molecularly imprinted polymer has multiple stable hole structures and binding sites inside, and has memory and recognition functions for the 4-methylsterane compounds, exhibiting excellent specific adsorption performance. The MIP can contribute to the accurate identification of correlation between depositional environment and maturity of crude oils or source rocks. A molecularly imprinted polymer prepared by such method, a chromatographic column and an application thereof are also provided.

Abstract: An aqueous composition includes water and a cationic polymeric resin having at least one reactive aldehyde group and formed from the reaction of glyoxal and a polymer. The polymer comprises at least one acrylamide repeating unit and at least one cationic repeating unit wherein a number of reactive aldehyde equivalents divided by a number of equivalents of residual glyoxal based on the total weight of the polymer is greater than about 1.2, wherein prior to reaction the polymer has greater than about 50 mole % acrylamide repeat units and from about 2 to about 30 mole % cationic repeating units, wherein greater than about 5 mole % of the acrylamide repeating units are converted to reactive aldehyde groups in the cationic polymer resin; and wherein the composition exhibits a viscosity gain of less than about 200%.

Abstract: The present invention relates to novel compounds, particularly to compounds comprising a photoactive unit, said novel compounds being particularly suitable for compositions and ophthalmic devices as well as to compositions and ophthalmic devices comprising such compounds.

Abstract: A peptide-crosslinked protein-imprinted polymer, preparation method, and application thereof. One method comprises: 1) dissolving a main monomer, functional monomers, a peptide crosslinking agent, and a template protein in an aqueous solution to obtain a mixed solution; 2) adding an initiator or initiator system to the mixed solution to initiate the polymerization when the peptide crosslinking agent exists in a helix conformation to obtain a polymer; 3) eluting the template protein when the peptide chain exists in a coil conformation to obtain a peptide-crosslinked protein-imprinted polymer. The peptide crosslinking agent is a peptide with a polymerizable double bond at its both ends, and being capable of undergoing helix-coil transition. The polypeptide crosslinking agent is a polypeptide having an amino acid sequence which has a polymerizable double bond at its both ends, being capable of undergoing a helix-coil conformational transformation.

Abstract: The present invention provides a carboxyl group-containing copolymer having a better calcium ion trapping ability and a better carbon black dispersing ability than any conventional carboxyl group-containing copolymers. The present invention relates to a carboxyl group-containing copolymer including a structural unit (a) derived from an unsaturated monocarboxylic acid monomer (A), a structural unit (b) derived from an unsaturated dicarboxylic acid monomer (B), and a structural unit (c) derived from a cationic monomer (C).

Abstract: A process is disclosed for making paper having improved filler retention and opacity. The process includes the step of adding Additive A and Additive B to a slurry in a wet end of a paper machine wherein the slurry comprises pulp and a filler. Additive A is a wet strength agent. Additive B is an anionic polymer having a charge density from about ?3000 to about ?7000 ueq/g on a dry basis when measured in a buffer having a pH of about 6. Additive B also has a weight average molecular weight of from about 150,000 to about 1,000,000, Daltons.

Abstract: Provided is a method that is for producing acrylamide, continuously produces acrylamide from acrylonitrile using a biocatalyst, and is characterized in that a continuous reaction is started by means of introducing acrylamide into a reaction vessel and then causing acrylonitrile to contact a biocatalyst. The method for producing acrylamide has superior operability and a low cost, and is capable of continuously extracting an aqueous solution of acrylamide at a target concentration in a short period of time after starting the continuous reaction.

Abstract: This invention relates to a water-soluble polymer in bead or powder form, characterized in that it has a Brookfield viscosity greater than 100 cps, and in that it is obtained by inverse suspension or inverse emulsion polymerization, in the presence of a transfer agent, of monomers where less than 20 mol % is made up of a hydroxyalkyl monomer with formula H2C?CR1R2, R1 being a hydrogen atom or a methyl group and R2 being a hydrocarbon group containing at least one OH pendant group or at least one epoxide group and optionally at least one N or O heteroatom in the hydrocarbon chains; R2 being different from the C(?O)—OH group.

Abstract: The invention provides an infiltrant for dental application that comprises crosslinking monomers. In accordance with the invention the infiltrant has a penetration coefficient PC>50 cm/s, and the crosslinking monomers, based on the total mass of monomers, comprise at least 5% by weight of crosslinking monomers having at least three polymerizable groups and not more than 95% by weight of crosslinking monomers having two polymerizable groups.

Abstract: A composition for treating an aqueous fluid includes an ionic polyacrylamide and a silicon polyether. The composition can be an oil-in-water emulsion or a water-in-oil emulsion. The ionic polyacrylamide can be an anionic polyacrylamide or a cationic polyacrylamide. The composition can be employed, for example, as a friction reducing additive for water based fracturing fluid, or a drilling mud additive.

Abstract: Cationic acrylamide copolymers have been designed and synthesized for highly efficient delivery of nucleic acids to cells in biological systems, specifically for in vitro cell transfection research.

Abstract: The present invention provides an alignment layer including a backbone including a polyolefin-based compound, and a plurality of side chains including a vertical functional group and a reactive mesogen (RM) and connected to the backbone, the backbone and the plurality of side chains include a compound represented by the following Chemical Formula 1, and a liquid crystal display including the alignment layer. According to the present invention, the alignment layer may have improved mechanical properties and afterimage by including a polyolefin-based compound as a backbone. Wherein X, Y, Z, Ak, Ar, Ra, and a, b, c, d and e are defined as in the specification.

Abstract: The current invention provides a method to form a stable blend of polyacrylamide water-in-oil emulsion and breaker surfactants such as silicon polyether copolymer and linear or branched alcohol ethoxylate surfactants. The composition can be employed, for example, as a friction reducing additive for water based fracturing fluid, or a drilling mud additive.

Abstract: The present invention relates to a personal care composition with a synthetic random copolymer having a net positive charge, a detersive surfactant; and an aqueous carrier.

Abstract: The invention pertains to a technique for suppressing a decrease in nitrile hydratase activity and improving the productivity of the amide compound in the course of producing an amide compound from a nitrile compound using a biocatalyst. Specifically, the invention pertains to a method for producing the corresponding amide compound from a nitrile compound in the presence of a biocatalyst having nitrile hydratase activity, wherein the method for producing an amide compound using a nitrile compound is characterized in that the zinc concentration of the nitrile compound is 0.4 ppm or less.

Abstract: The present invention relates to an acrylamide-based mesoporous polymer and its preparation method, where the acrylamide-based mesoporous polymer is fabricated by a simple preparation method to have uniform minute pores controllable in pore size and thereby applicable to a wide variety of fields. The acrylamide-based mesoporous polymer includes at least one of a defined repeating unit and contains a plurality of pores having a diameter of 2.0 to 10.0 nm in the solid state.

Abstract: An improved, cost effective process for the preparation of Lacosamide is disclosed. A novel intermediate of formula (IV) and a process for preparation of the novel intermediate is also disclosed. wherein, X is halogen.

Abstract: The present invention relates to a method for the preparation of a controlled release system and especially to a method for entrapment of compounds in polymer carriers for controlled release of active ingredients, preferably bioactive ingredients, such as drugs. This method results in a system for controlled release of active ingredients and especially for controlled drug delivery. In accordance with the present invention, the term “controlled release” encompasses all kinds of controlled release, including slow release, sustained and delayed release. Particularly, the present invention results in active ingredients, entrapped in or otherwise incorporated in or coupled to polymer carriers or polymeric devices, such as micelles, nanoparticles, microspheres and other types of polymer devices for controlled release; the active ingredients are covalently bonded to the polymer carriers or polymeric devices.

Abstract: Disclosed are derivatives of (tetrahydropyranyl)methyl acrylamide and polymers derived therefrom, as well as methods of making such compounds and polymers. Adhesives, coatings, and plastics which include such polymers are also described.

Abstract: A water-soluble copolymer comprising, by mass relative to the total mass of the copolymer: 1 to 40% of at least one cationic monomer; 59.99 to 98% of at least one nonionic monomer; 0.01 to 10% of at least one monomer of formula (I); in which: R1 is a hydrogen atom or a methyl radical; Z is a divalent group —C(?O)—O—, or —C(?O)—NH—; n is an integer between 2 and 200; R2 is a hydrogen atom or a carbon-containing radical which is saturated or unsaturated, optionally aromatic, linear, branched or cyclic, comprising 1 to 30 carbon atoms, and from 0 to 4 heteroatoms chosen from the group comprising O, N and S; the copolymer having a cationic charge density between 0.05 and 3 meq/g.

Abstract: Articles containing soil adsorbing polymers, and more particularly, articles, for example nonwovens, such as paper towels, wovens, and/or sponges and/or article-forming components thereof that comprise a durably bonded soil adsorbing polymer, article-forming components used to make such articles, and processes for making same are provided.

Abstract: The present invention relates compositions and methods for enhanced oil recovery. The method is directed to employing a water-soluble The present invention relates compositions and methods for enhanced oil recovery (EOR). The method is directed to employing a water-soluble functional polymeric surfactant (FPS), with a medium IFT value, preferably ranged from about 0.1 to about 15 dyne/cm between water phase containing polymeric surfactant and hydrocarbon phase, for recovery of hydrocarbons from subterranean formations. The FPS solution demonstrates a strong interaction with oil and the great potential to increase both volumetric sweep efficiency and microscopic displacement efficiency in EOR.

Abstract: The invention relates to a biocompatible, non-biodegradable, and non-toxic polymer of formula (I), comprising of three monomeric units, selected from 1-Vinylpyrrolidne (VP), N-Isopropylactylamide (NIPAM), and ester of Maleic anhydride and Polyethylene glycol (MPEG), cross-linked with a bi-functional vinyl derivative, of high purity and substantially free of respective toxic monomeric contaminants, and a process for preparation thereof. The invention further relates to nanoparticulate pharmaceutical compositions of poorly water-soluble drugs or compounds comprising the polymer of the invention, which are safe, less-toxic and convenient for bedside administration to patients in need thereof. Furthermore, the invention relates to a highly selective method for preparation of nanoparticulate pharmaceutical compositions of poorly water-soluble drugs or compounds.

Abstract: A method of inhibiting hydrates in a fluid comprising water and gas comprising adding to the fluid an effective hydrate-inhibiting amount of a composition comprising one or more copolymers of N-alkyl(alkyl)acrylamide monomers and one or more cationic monomers selected from acid and alkyl chloride quaternary salts of N,N-dialkylaminoalkyl(meth)acrylates and N,N-dialkylaminoalkyl(meth)acrylamides.

Abstract: The present invention provides membrane lytic poly(amido amine) polymers, polyconjugates, compositions and methods for the delivery of oligonucleotides for therapeutic purposes.

Abstract: The invention relates to a process for preparing polymers from monomers and/or oligomers by adding a liquid comprising the monomers and/or oligomers dropwise to a continuous liquid phase in a reactor, the continuous liquid phase being immiscible with the liquid comprising the monomers and/or oligomers, and the monomers and/or oligomers reacting in the continuous liquid phase to give the polymer. The liquid comprising the monomers and/or oligomers is shaped to droplets outside the continuous liquid phase, which are subsequently introduced into the continuous liquid phase. The invention further relates to a reactor for performing the process, comprising a tube through which a continuous liquid phase flows, and means of generating droplets, the means of generating droplets being arranged such that the droplets are generated outside the continuous liquid phase and then introduced into the continuous liquid phase.

Abstract: A polymer formed by controlled radical polymerization includes groups that can be modified after controlled radical polymerization to form a radical. The polymer can be the reaction product of a controlled radical polymerization of radically polymerizable monomers, wherein at least one of the radically polymerizable monomers includes at least one group that can be modified after the controlled radical polymerization to form a radical.

Abstract: A non-specific adsorption inhibitor includes a water-soluble polymer obtained by polymerizing a monomer unit that includes a monomer (A) that forms a polymer that has a lower critical solution temperature (LCST) of 80° C. or less in an aqueous solution under normal pressure when subjected to homopolymerization, and a monomer (B) that forms a polymer that does not have the LCST in an aqueous solution under normal pressure when subjected to homopolymerization.

Abstract: The object of the present invention is to provide a silicone-based copolymer which has excellent long-term antifouling property even in a dry-wet alternate portion of a ship and the like or a portion thereof near the surface of water, is excellent also in mechanical strength and recoatability and exhibits high antifouling performance even if an antifouling agent is not added, and an antifouling coating composition containing the copolymer.

Abstract: The invention relates to polymeric latexes that can be used in adhesive compositions, which provide improved bonding of rubber articles to rubber reinforcing articles. The adhesive composition includes a single or a blend of polymeric latexes comprising a conjugated aliphatic monomer, a vinylaromatic monomer, a vinylpyridine monomer, and a nitrogen-containing monomer comprising a reactive N-methylol- or N-alkoxy-functionality. Use of the monomer comprising a nitrogen-containing monomer comprising a reactive N-methylol- or N-alkoxy-functionality allows for reduced amounts of the vinylpyridine monomer in the latex, and enhances the bonding properties of the adhesive composition. Use of the adhesive composition provides economic and chemical advantages for the preparation of reinforced rubberized articles.

Abstract: A composition including an actinic radiation or thermally curable polyorganosiloxane ionomer having one or more reactive groups, for example, vinyl, acrylate, epoxy groups.

Abstract: To provide an ABA triblock copolymer containing: an A-block having, in a constitutional unit thereof, a monomer represented by the following general formula (1) or a monomer represented by the following general formula (2); and a B-block having, in a constitutional unit thereof, a hydrophilic monomer having a radical polymerizable unsaturated bond, where R1 is a hydrogen atom or a methyl group; R2 is a C5-C18 alkylene group; M is a hydrogen atom or a monovalent metal atom; and X1 is —NH— or an oxygen atom in the general formula (1), and where R11 is a hydrogen atom or a methyl group; R12 is a C5-C18 alkylene group; R13 and R14 are each independently a hydrogen atom, a methyl group, or an ethyl group; and X11 is —NH— or an oxygen atom in the general formula (2).

Abstract: The present disclosure relates to compositions comprising a copolymer that includes a first monomer and a second monomer that is different from the first monomer, wherein both the first and second monomer are selected from the group consisting of 3-sulfopropyl acrylate potassium salt, sodium acrylate, N-(tris(hydroxyl methyl)methyl)acrylamide, and 2-acrylamideo-2-methyl-1-propane sulfonic acid. The present disclosure further relates to methods for preparing the copolymer compositions and shaped articles comprising the copolymers.

Abstract: The present invention provides a method for preparing a water soluble polymer, which comprises: a first step of polymerizing: (a) 60 to 99.5 mol % of at least one selected from acrylamide and methacrylamide, (b) 0.5 to 20 mol % of at least one selected from ?,?-unsaturated monocarboxylic acid, ?,?-unsaturated dicarboxylic acid and salts thereof, and (c) 1 to 20 mol % of at least one selected from a water soluble cationic monomer and a salt thereof, (d) 0.01 to 1 mol % of a chain transfer agent, and (e) 0.005 to 5 mol % of a crosslinkable monomer, in the presence of a persulfate-based catalyst to obtain a prepolymer; and a second step of further adding the persulfate-based catalyst to the prepolymer obtained in the first step and the residual monomer, followed by the polymerization and termination of the polymerization.

Abstract: A microdroplet or microparticle with Janus or core-shell internal morphology, which is obtained under the control of phase separation of high-concentration NIPAAm formed at 25° C. or more in a microfluidic device, is provided. The microdroplet or microparticle shows an anisotropic volume change according to a change in temperature, and can also serve as a fat-soluble/water-soluble carrier, and thus can be used as a new material for medical supplies in the field of various applications in the future.

Abstract: The invention provides a method and apparatus for continuously feeding wet gel polymers into a drying step of a dry polymer synthesis operation. A number of pistons are arranged having inner chambers through which monomers and other reagents are fed and polymerized into wet gel polymers. Each piston operates according to a coordinated schedule so that as one piston finishes extruding polymer into the drying step, a second piston has completed polymerizing more polymer and continues to feed more polymer without interruption. The then finished is re-fed more reagents so as to be ready again when needed next. As a result, cost effective continuous feeding can be achieved without the contamination and impurity problems that have plagued previous attempts to accomplish this.

Abstract: A finish for cellulosic fibrous substrates containing tertiary amine-containing polymers for providing durable control of body odors and the cellulosic materials treated with the finish, which materials exhibit little or no discoloration and little or no degradation of physical strength as a result of the treatment.

Abstract: A polymer composite composition wherein at least one of the constituents is a silicone ionomer and the other constituent is polymer.

Abstract: A water-soluble resin composition for forming fine patterns comprising water-soluble polymer represented by Chemical Formula 1 as below and the first water-soluble solvent, is coated and heated on a photoresist layer having at least one contact hole to reduce a size of the at least one contact hole. (In Chemical Formula 1, each of R1, R2, R3 and R5 independently represents an alkyl group of C1-30 or an cyclo alkyl group of C3-30 which respectively have one selected from the group consisting of hydrogen, an ether group, an ester group, a carbonyl group, an acetal, an epoxy group, a nitril group, an amine group, and an aldehyde group; each of R4, R6, R7 and R8 independently represents hydrogen or a methyl group; n represents an integer of 0 to 5; a represents a real number of 0.05 to 0.5; each of b, c and d respectively represents a real number of 0 to 0.7; and a+b+c+d=1).

Abstract: The invention relates to a process for the production of paper, card and board, including the steps of draining a filler-containing paper stock, having a certain fibrous concentration and containing at least one water-soluble amphoteric copolymer, with sheet formation in a wire section, then pressing the paper in a press section, diluting the paper stock to a fibrous concentration in the range from 5 to 15 g/l, draining the diluted paper stock to form a sheet, and then pressing the sheet in the press section to a solids content G(x) wt % or greater, such that G(x) computes according to: G(x)=48+(x?15)·0.4, where x is the numerical value of a filler content of the dry paper, card or board (in wt %), and G(x) is a numerical value of the minimal solids content (in wt %) to which the sheet is pressed.

Abstract: The present invention relates to the manufacture of bioresourced polymer-grade acrylic acid from glycerol. The polymer grade acrylic acid produced has limited content of certain impurities harmful to polymerization processes, such as, total aldehydes, protoanemonin, maleic anhydride and nonphenolic polymerization inhibitors. The invention also relates to the use of the bioresourced acrylic acid obtained for manufacture of superabsorbents or for manufacture of polymers or copolymers using amide or ester derivatives of the bioresourced acrylic acid.

Abstract: The present invention is directed to the use of hydrophilic terpolymers in hard surface cleaners which provide easier cleaning for surface soils such as hard water stains, soap scum, limescale, mud, food, toilet stains, oil, grease, particulates and the like as well as anti-fog effects on hard surfaces such as glass, mirrors, ceramic and plastic by causing water droplets to coalesce into a film.

Abstract: The invention relates to a process for producing water-absorbing polymer particles with improved permeability, comprising the steps of polymerization, drying, grinding, classification and thermal surface postcrosslinking, with pneumatic conveying between grinding and classification.

Abstract: Copolymers of acrylamide or methacrylamide, suitably modified with appropriate percentages of units deriving from comonomers of a hydrophobic nature and comonomers containing a positively charged ionic group, which are capable of effectively reducing the water permeability of a porous medium.

Abstract: The present invention relates to an N-(1-hydroxyethyl)carboxamide compound represented by formula (1) (in the formula, RA and RB represent independently from each other a hydrogen atom or an alkyl group having 1 to 4 carbon atoms except for a case where RA and RB represent a hydrogen atom at the same time) and a method for producing the same; a method for producing an N-(1-alkoxyethyl)carboxamide compound; a method for producing an N-vinyl carboxylic acid amide compound; and a method for producing an N-vinyl carboxylic acid amide (co)polymer. An N-(1-alkoxyethyl)carboxamide compound can be obtained by reacting N-(1-hydroxyethyl)carboxamide compound with alcohol in the presence of an acid catalyst, and an N-vinyl carboxylic acid amide compound, which is a monomer of the N-vinyl carboxylic acid amide (co)polymer, can be obtained by thermally decomposing or catalytically decomposing the N-(1-alkoxyethyl)carboxamide compound.

Abstract: A resist composition including a base component (A) which exhibits changed solubility in a developing solution under action of acid and an acid-generator component (B) which generates acid upon exposure, the base component (A) containing a polymeric compound (A1) having a structural unit (a5) represented by general formula (a5-0) shown below (R1 represents a sulfur atom or an oxygen atom; R2 represents a single bond or a divalent linking group; and Y represents an aromatic hydrocarbon group or an aliphatic hydrocarbon group having a polycyclic group, provided that the aromatic hydrocarbon group or the aliphatic hydrocarbon may have a carbon atom or a hydrogen atom thereof substituted with a substituent.

Abstract: The invention pertains to the field of membrane protein immobilization onto supports. It relates to a product comprising a support and at least one membrane protein attached to the surface thereof, characterized in that said membrane protein is attached to said support using an amphiphilic molecule with which said membrane protein is complexed. It also relates to a process for preparing such product, as well as to various applications in the fields of diagnosis, drug design and biotechnologies. It further relates to a kit, together with a functionalized amphiphilic molecule, for preparing a product according to the invention comprising a support and an amphiphilic molecule, wherein the amphiphilic molecule and the support interact through a hydrophobic bond, an ionic bond, a specific bond or a covalent bond.

Abstract: Biocompatible polymers are manufactured to include an ammo acid mimetic monomer and one or more hydrophobic acrylate monomers. The amino acid mimetic monomers are selected to mimic the side chain of the amino acids asparagine or glutamine. The amino acid mimetic monomer can be a methacryloyl or acryloyl derivative of 2-hydroxyacetamide, 3-hydroxypropionamide, alaninamide, lactamide, or glycinamide. These amide functional groups offer the advantage of moderate hydrophilicity with little chemical reactivity. The amino acid mimetic monomer can be copolymerized with one or more hydrophobic acrylate monomers to obtain desired coating properties.

Abstract: In one aspect, the invention relates to silicone prepolymer compositions comprising a silicone prepolymer and a solvent. A soluble silicone prepolymer can be provided having increased average silicon content, thereby attaining a desired oxygen permeability. A solvent can be provided with a desired balance between hydrophilicity and hydrophobicity by selection and modification of the solvent molecular structure, resulting in molded polymer films and articles that exhibit minimal or nonexistent eye irritation and exhibit highly transparent products. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.

Abstract: An improved polymerization and process method allows the production of special nitrile rubbers which are characterized by a specific anion content and an excellent storage stability and allow a particularly good vulcanization rate and moreover result in vulcanized materials that have advantageous properties, especially with regard to the contact with metal components of molded parts based on said vulcanized materials.