N- Substituted Unsaturated Hydrocarbon Group Patents (Class 526/307.1)
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Patent number: 6627719Abstract: A cationic latex terpolymer prepared by polymerizing from about 1 to about 99.1 mole percent of one or more cationic monomers, from about 0.9 to about 5 mole percent of one or more hydroxyalkyl (meth)acrylates and from 0 to about 98.1 mole percent of one or more nonionic monomers is useful for dewatering sludge.Type: GrantFiled: January 31, 2001Date of Patent: September 30, 2003Assignee: Ondeo Nalco CompanyInventors: Wesley L. Whipple, Ananthasubramanian Sivakumar, Jitendra Shah
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Patent number: 6602928Abstract: A packing material for solid phase extraction, which is a particle having an exclusion limit molecular weight of 1×103 to 1.5×104 in gel permeation chromatography using a standard polystyrene as the sample. A column for solid phase extraction and a cartridge for solid phase extraction, a method of using the packing material; and a process for treating a sample using the column or cartridge are also disclosed.Type: GrantFiled: August 21, 2001Date of Patent: August 5, 2003Assignee: Showa Denko Kabushiki KaishaInventors: Ryuji Takahashi, Kuniko Igarashi, Hiroshi Suzuki
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Patent number: 6599999Abstract: The present invention relates to hair care compositions which contain a polymer which is prepared from N-vinyl acetamide (NVAM) monomer and the use of those hair care compositions to treat hair. The polymer may be a homopolymer of NVAM or an interpolymer of NVAM and at least one vinyl monomer. The polymer is present in amounts effective to provide the hair care compositions with hair fixative properties and/or hair conditioning properties.Type: GrantFiled: May 19, 1999Date of Patent: July 29, 2003Assignee: National Starch and Chemical Investment Holding CorporationInventors: Rama S. Chandran, Jean-Pierre Leblanc, Hideaki Hanazawa
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Patent number: 6596844Abstract: The present invention pertains to a method for forming poly-acrylic acid granules and granules formed therefrom wherein the granules are flowable, have an increased bulk density relative to the as polymerized polyacrylic acids, and a low amount of dust which is generally characterized herein as particles which pass through a 325 mesh screen. The granules formed by the method of the present invention can be used to prepare controlled release tablets, especially controlled release pharmaceutical tablets. The controlled release properties of the tablets formed from granules prepared according to the present invention are unexpectedly better than tablets prepared from granules formed by other known granulation methods.Type: GrantFiled: December 20, 2001Date of Patent: July 22, 2003Assignee: Noveon IP Holdings Corp.Inventors: Daniel James Adams, David William Weaver
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Patent number: 6590049Abstract: The present invention is directed to novel compounds that can serve as highly efficient initiators for controlled radical (co)polymerization processes including atom transfer radical (co)polymerization processes. These compounds include di-(trimethylolpropane)-tetra-(2-haloisobutyrate) compounds. The present invention also is directed to controlled radical (co)polymerization processes in which novel (co)polymers are prepared using the novel compounds, as well as to the novel (co)polymer products of the process.Type: GrantFiled: October 13, 2000Date of Patent: July 8, 2003Assignee: PPG Industries Ohio, Inc.Inventors: James B. O'Dwyer, Kevin C. Olson, Simion Coca, Brian E. Woodworth
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Publication number: 20030096933Abstract: In forming pressure sensitive adhesive microspheres by copolymerizing a non-ionic monomer of an alkyl acrylate or alkyl methacrylate ester of a non-tertiary alcohol and an acid monomer copolymerizable with said non-ionic monomer, an electrolyte is present during the polymerization to promote formation of solid rather than hollow microspheres.Type: ApplicationFiled: October 15, 2002Publication date: May 22, 2003Inventors: Jong-Shing Guo, Augustin T. Chen, Sharon D. Trembley
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Patent number: 6566473Abstract: A non-aqueous, heterogeneous polymerization process comprises heating a reaction mixture of about 5-70%, preferably 10-50%, by weight, of a vinyl amide monomer in an oil as solvent, and a water-soluble cosolvent, and a free radical initiator, optionally in the presence of a crosslinking agent and/or a surfactant, wherein the oil solvent is present in an amount sufficient to keep the resultant polymer in a stirrable state throughout the polymerization. The polymer reaction product is capable of forming a uniform emulsion or gel upon addition of water thereto.Type: GrantFiled: November 20, 2002Date of Patent: May 20, 2003Assignee: ISP Investments Inc.Inventors: Donald I. Prettypaul, Jenn S. Shih
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Patent number: 6555637Abstract: In anionic polymerization using an anionic polymerization initiator, a tertiary organoaluminum compound (A) having in the molecule thereof a chemical structure represented by a general formula: Al—O—Ar wherein Ar represents an aromatic ring, and at least one Lewis base (B) selected from the group consisting of a tertiary polyamine compound, are caused to be present in the polymerization system. In this way, the polar monomer can be polymerized with a high polymerization initiation efficiency and a high living polymerization property and at a high polymerization rate even if the used polymerization initiator is suitable for industrial use, and a relatively mild cooling condition or a temperature condition near room temperature is adopted as a polymerization temperature condition.Type: GrantFiled: August 15, 2000Date of Patent: April 29, 2003Assignee: Kuraray Co., Ltd.Inventors: Kenichi Hamada, Kazushige Ishiura, Masaji Kato, Sachie Yaginuma
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Patent number: 6552142Abstract: A description is given of a process for preparing aqueous copolymer dispersions by free-radical polymerization of ethylenically unsaturated monomers in an aqueous solution in which (a) from 10 to 90% by weight of at least one hydrophilic monomer A which has an N-vinyl group and whose polymerisation rate possesses a maximum at pH levels above 7, and (b) from 10 to 90% by weight of at least-one monoethylenically unsaturated hydrophobic monomer B whose polymerisation rate possesses a maximum at pH levels below 7, are copolymerised in the presence of a free-radical initiator system such that in the course of the polymerization the pH falls by from 2 to 5 units. The copolymer dispersions prepared in this way and the copolymers obtainable therefrom are suitable as auxiliaries for pharmaceutical, cosmetic or agrochemical formulations and for preparing paints, coating compositions, sizes, and adhesives.Type: GrantFiled: February 17, 2000Date of Patent: April 22, 2003Assignee: BASF AkeiengesellschaftInventors: Helmut Meffert, Maximilian Angel
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Patent number: 6538088Abstract: The present invention is directed to precipitation polymerization processes for the manufacture of essentially non-crosslinked polymers prepared from N-vinyl acetamide monomer which exhibit reduced levels of residual non-polymerizable contaminants, particularly residual acetamide, the processes including the steps of contacting the N-vinyl acetamide monomer with a polymerization medium containing a diluent selected from ethyl acetate and acetone and a free-radical initiator, under conditions effective to polymerize the N-vinyl acetamide monomer, thereby forming a precipitate of the polymer in the polymerization medium; and isolating the precipitated polymer from the polymerization medium.Type: GrantFiled: February 26, 1999Date of Patent: March 25, 2003Assignee: National Starch and Chemical Investment Holding CorporationInventors: Jean-Pierre Leblanc, Rama S. Chandran
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Patent number: 6531562Abstract: The present invention provides novel bicyclic photoresist monomers, and photoresist copolymer derived from the same. The bicyclic photoresist monomers of the present invention comprise both amine functional group and acid labile protecting group, and are represented by the formula: where m, n, R, V and B are those defined herein. The photoresist composition comprising the photoresist copolymer of the present invention has excellent etching resistance and heat resistance, and remarkably enhanced PED stability (post exposure delay stability).Type: GrantFiled: May 14, 2002Date of Patent: March 11, 2003Assignee: Hyundai Electronics Industries Co., Ltd.Inventors: Min Ho Jung, Jae Chang Jung, Geun Su Lee, Ki Ho Baik
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Patent number: 6525152Abstract: Copolymers useful in radiation-sensitive layers of printing plates have the units A, B and C wherein unit A is present in an amount of 5 to a maximum of 50 mol % and R1 and R4 are selected such that the homopolymer of A is alkali-soluble, B is present in an amount of 20-70 mol % and R2, R6 and R7 are selected such that the homopolymer of B has a high glass transition temperature, and C is present in an amount of 10-50 mol % and R3 and R5 are selected such that the homopolymer of C is water-soluble and that unit A is different from unit C.Type: GrantFiled: August 2, 2000Date of Patent: February 25, 2003Assignee: Kodak Polychrome Graphics LLCInventor: Mathias Jarek
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Publication number: 20030018152Abstract: Proposals are made for a process for preparing polymer solutions and/or polymer dispersions by free-radical addition polymerization and for the use of the polymers prepared, particularly as gas hydrate inhibitors.Type: ApplicationFiled: August 27, 2002Publication date: January 23, 2003Inventors: Maximilian Angel, Stefan Stein, Karin Neubecker
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Patent number: 6495645Abstract: An acrylamide derivative of the following general formula (I) is used to prepare a polymer or copolymer: wherein R1 represents a hydrogen atom, a straight-chain or branched alkyl group containing 1 to 4 carbon atoms or a C3-6 cycloalkyl group, R2 and R3 each independently represent an alkylene group containing 1 to 6 carbon atoms or R2 and R3 may be combined to form a ring, X represents a hydrogen atom, an amino group, a hydroxyl group, a halogen atom, a carboxyl group or a —COOR4 group wherein R4 represents a C1-6 straight-chain or branched alkyl, C3-6 cycloalkyl, phenyl, substituted phenyl, benzyl or substituted benzyl group, and Y represents an amino group, a halogen atom, a carboxyl group or a —COOR4 group wherein R4 represents a C1-6 straight-chain or branched alkyl, C3-6 cycloalkyl, phenyl, substituted phenyl, benzyl or substituted benzyl group.Type: GrantFiled: August 30, 2001Date of Patent: December 17, 2002Inventors: Teruo Okano, Takao Aoyagi
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Patent number: 6414080Abstract: Disclosed herein is an inverse emulsion polymer composition comprising a copolymer or copolymer salt of N,N,-dimethylacrylamide and 2-acrylamido-2-methylpropane sulfonic acid or acid salts thereof, having a Brookfield viscosity of less than 20,000 Cps at 23° C. and an active polymer concentration of about 25 to about 75 weight percent. The inverse emulsion polymer composition is in a hydrocarbon with a primary surfactant and optionally contains water.Type: GrantFiled: August 18, 1999Date of Patent: July 2, 2002Assignee: Calgon CorporationInventors: Randy J. Loeffler, Shih-Ruey T. Chen, Kevin W. Frederick, James E. Rak
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Publication number: 20020061996Abstract: The present invention relates to polymers of the general formula I: 1Type: ApplicationFiled: July 27, 2001Publication date: May 23, 2002Inventors: Richard Buchecker, Guy Marck, Andreas Schuster, Hubert Seiberle
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Patent number: 6369182Abstract: This invention is directed to a cationic terpolymer comprising (a) a first monomer unit selected from acrylamide and methacrylamide; (b) a second monomer unit selected from dimethylaminoethyl acrylate methyl chloride quaternary salt, 3-(acrylamido)propyltrimethylammonium chloride, 3-(methacrylamido)propyltrimethylammonium chloride, dimethylaminoethyl methacrylate methyl chloride quaternary salt, dimethylaminoethyl acrylate dimethylsulfate quaternary salt, dimethylaminoethyl methacrylate dimethylsulfate quaternary salt, diethylaminoethyl acrylate methyl chloride quaternary salt and diethylaminoethyl acrylate dimethylsulfate quaternary salt; and (c) a third monomer unit selected from benzyl methacrylate, 2,2,2-trifluoroethyl acrylate, acrylamide diacetone, N-phenylacrylamide, 2,2,3,3-tetrafluoropropyl acrylate and poly(propylene glycol)methacrylate. The terpolymer is useful for dewatering a variety of sludges.Type: GrantFiled: October 11, 1999Date of Patent: April 9, 2002Assignee: Nalco Chemical CompanyInventors: Wesley L. Whipple, Ananthasubramanian Sivakumar
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Patent number: 6369180Abstract: A process of making a homopolymer of vinyl caprolactam (VCL), and a copolymer with dimethylaminopropyl methacrylamide (DMAPMA), optionally including with one or more polymerizable monomers (X), in the composition range, by weight, VCL 99 to 30%, DMAPMA 1-70% and monomer X 0-30%, respectively, by suspension polymerization in an aqueous/alcoholic solvent medium, without requiring a protective colloid, which comprises charging vinyl caprolactam in an aqueous/alcoholic solvent mixture, wherein the weight ratio of alcohol to total monomers is ⅙ to 3, and if present, forming a solution of DMAPMA and optional monomers in water, feeding the solution into the VCL charge at a predetermined rate, periodically adding initiator to the reaction mixture, and polymerizing at about 40° to 130° C., and, if desired, neutralizing the product, to form a polymer product at about 5% to 40% solids, homogeneously dispersed in the solvent.Type: GrantFiled: August 18, 2000Date of Patent: April 9, 2002Assignee: ISP Investments Inc.Inventors: Jenn S. Shih, Donald I. Prettypaul, John Mc Kittrick, David E. Graham
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Patent number: 6359093Abstract: An amphipathic compound represented by any of the following Formulas: (R1 is a linear or branched, saturated hydrocarbon group having 6 to 48 carbon atoms, or a linear or branched, unsaturated hydrocarbon group containing 1 to 12 unsaturated double bond and having 6 to 48 carbon atoms; Y is NH, N—(CH2—CH═CH2), or O; Q is —CH2—C(R2)═CH2 or —R4—O—CO—C(R2)═CH2; and M is alkali metal, an ammonium group, or —(CH2CH2O)mH), a copolymer of the amphipatic compound with a copolymerizable ethylenically unsaturated compound and, a paper making additive containing a water soluble or dispersible high molecular compound as an active ingredient and processes for producing these high molecular compounds.Type: GrantFiled: February 16, 2000Date of Patent: March 19, 2002Assignee: Mitsui Chemicals, Inc.Inventors: Toshihiko Takaki, Masaru Tanabe, Shoko Oyanagi
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Patent number: 6342571Abstract: Polymerizable compositions comprising: (a) a mixture of thio(meth)acrylate functional monomers comprising, (a)(i) a first thio(meth)acrylate functional monomer, e.g., bis(thiomethacrylate)-1,2-ethylene, and (a)(ii) a second thio(meth)acrylate functional monomer, which is chain extended; (b) an aromatic monomer having at least two vinyl groups, e.g., divinyl benzene; (c) a polythiol monomer having at least two thiol groups, e.g., pentaerythritol tetrakis(3-mercaptopropionate); and (d) a comonomer selected from, (d)(i) an anhydride monomer having at least one ethylenically unsaturated group, e.g., methacrylic anhydride; (d) (ii) a monomer having at least three (meth)acryloyl groups, e.g., pentaerythritol tetrakis(acrylate); and (d)(iii) mixtures of monomers (d)(i) and (d)(ii). A polymerizate of the polymerizable composition has a refractive index of at least 1.57 and an Abbe number of at least 33.Type: GrantFiled: August 20, 1999Date of Patent: January 29, 2002Assignee: PPG Industries Ohio, Inc.Inventors: Robert A. Smith, Michael O. Okoroafor, Robert D. Herold, T. Edwin Freeman
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Patent number: 6329117Abstract: A composition for an anti-reflective coating or a light absorbing coating, which shows good light absorption for lights of 100-450 nm in wavelength, suffers neither footing nor intermixing, and has excellent storage stability and step coverage, and novel copolymers to be used therein.Type: GrantFiled: August 9, 1999Date of Patent: December 11, 2001Assignee: Clariant International, Ltd.Inventors: Munirathna Padmanaban, Wen-Bing Kang, Georg Pawlowski, Ken Kimura, Hatsuyuki Tanaka
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Patent number: 6271327Abstract: Water-soluble polymers whose characteristic structural elements comprise units of the formulae I and/or II where R1 is H, alkyl, cycloalkyl, aryl or aralkyl, R2 and R3 independently are as defined for R1 or are selected from substituted alkyl, substituted cycloalkyl, substituted aryl or substituted aralkyl, the substituents being selected from OH, O-alkyl, O-aryl, SH, S-alkyl, S-aryl, NH2, NH-alkyl, NH-aryl, N(alkyl)2, possibly in protinated form, N(Alkyl)3+3Z−, where Z is the radical of an inorganic or organic acid, COOH, COO-alkyl, CONH2, CONH-alkyl, CON(alkyl)2, CN and SO3H; and the indices x are each independently an integer from 1 to 20; and the acid addition salts of these polymers, (processes for whose preparation are also described), are used in cosmetic compositions.Type: GrantFiled: January 25, 1999Date of Patent: August 7, 2001Assignee: BASF AktiengesellschaftInventors: Manfred Niessner, Martin Rübenacker, Claudia Nilz, Peter Hössel
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Patent number: 6262012Abstract: A wet paint spray booth treating agent includes sepiolite alone or further accompanying cationic polymer or amphoteric metal compound. In a method of treating a wet paint spray booth, the sepiolite alone or further accompanying the cationic polymer or the amphoteric metal compound is added. The wet paint spray booth treating agent and a method of treating a wet paint spray booth improve the effect of reduction in tackiness and decrease the load of agents to prevent the corrosion of furnishings. The sepiolite is a fibrous mineral containing chain structures having lots of micropores so that the sepiolite can reduce the tackiness of the paint due to reaction with the particles of the paint in such a manner to adsorb the particles in the micropores thereof.Type: GrantFiled: December 20, 1999Date of Patent: July 17, 2001Assignees: Kurita Water Industries Ltd., Toyota Jidosha Kabushiki KaishaInventors: Keisuke Mizuno, Masahiro Horiuchi, Takao Mogami, Mitsuo Nakajima
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Patent number: 6177068Abstract: A cosmetically active oil-in-water (o/w) or water-in-oil (w/o) emulsion, for topical applications comprising (a) the reaction product of a non-aqueous, heterogeneous polymerization of a liquid reaction mixture containing between about 5 and about 70%, preferably 10-40%, by weight, of N-vinylamide monomer in an oil solvent, a free radical initiator, between about 0.1 and about 2.5% by weight of a crosslinking agent and optionally a surfactant, (b) water sufficient to form said emulsion, (c) a cosmetically active hair and/or skin treating chemical or chemical composition and optionally (d) a surfactant.Type: GrantFiled: December 2, 1998Date of Patent: January 23, 2001Assignee: ISP Investments Inc.Inventors: Jenn S. Shih, Jui-Chang Chuang, Krystyna Plochocka