Abstract: The present invention relates to a process for the preparation, of thermoprecipitating affinity polymers useful in the enhanced recovery of enzymes. The process comprises polymerising a monomer comprising a spacer and a co-monomer with a polymerisation initiator and a polymerisation accelerator at ambient temperature and pressure for a period ranging between 2 to 24 hours to obtain a polymer and then linking an inhibitor to pendant carboxyl groups of the spacers in the polymer to obtain an affinity polymer.
Type:
Grant
Filed:
March 6, 2000
Date of Patent:
July 16, 2002
Assignee:
Council of Scientific and Industrial Research
Abstract: The invention provides ion exchange and electrochemical methods and devices employing anion exchange polymers produced by substantially simultaneous quaternization and polymerization reactions. Anion selective polymers are produced in accordance with the invention by combining, an ethylenic tertiary amine monomer, an alkylating agent having a boiling point temperature of at least about 100° C., and a cross-linking agent in the presence of a polymerizing agent for a time and at a temperature sufficient to form the polymer. The alkylating agent and the cross-linking agent may be the same compound, a cross-linking alkylating agent. The polymers may be produced in the presence of solvents and/or in the presence of diluting monomers which are incorporated into the polymers.
Abstract: The invention relates to copolymers comprising a) 5-95% by weight of structural units which are derived from compounds of the formula 1
b) from 1 to 95% by weight of structural units which are derived from compounds of the formula 2
and
c1) from 1 to 95% by weight of structural units which are derived from compounds of the formula 3
or, alternatively, to c1),
c2) from 1 to 95% by weight of structural units which are derived from compounds of the formula 4
n which X is a cation. The copolymers according to the invention are suitable as a fluid loss additive for water-based drilling muds and for cement slurries in deep wells, for completion and clearing-out liquids and for water shut-off in production probes.
Type:
Grant
Filed:
June 8, 2000
Date of Patent:
May 28, 2002
Assignee:
Clariant GmbH
Inventors:
Reinhard J. Oswald, Roman Morschhäuser, Karl Heinz Heier, Aranka Tardi, Juergen Tonhauser, Christoph Kayser, Dan Patterson
Abstract: The present invention provides polyacrylamide hydrogels (especially polyacrylamide hydrogel arrays) made from prepolymers and polyacrylamide reactive polymers, as well as methods and compositions for preparing the polyacrylamide hydrogels or hydrogel arrays. The method advantageously provides greater control of polyacrylamide pore size and crosslink density, allowing, for instance, preparation of a polyacrylamide hydrogel appropriate for use with DNA. Furthermore, the methods and compositions can be employed in commercial processes.
Abstract: The present invention provides polyacrylamide hydrogels (especially polyacrylamide hydrogel arrays) made from prepolymers and polyacrylamide reactive polymers, as well as methods and compositions for preparing the polyacrylamide hydrogels or hydrogel arrays. The method advantageously provides greater control of polyacrylamide pore size and crosslink density, allowing, for instance, preparation of a polyacrylamide hydrogel appropriate for use with DNA. Furthermore, the methods and compositions can be employed in commercial processes.
Abstract: The present invention is directed to a copolymer containing a hydrophilic copolymerizable monomer and a plastisol obtained by the use of the copolymer, which exhibits reduced viscosity and longer pot-life.
Type:
Grant
Filed:
March 28, 2000
Date of Patent:
March 12, 2002
Assignee:
Roehm GmbH & Co KG
Inventors:
Klaus Schultes, Guenther Schmitt, Andreas Olschewski, Theodor Mager
Abstract: Resins comprising (meth)acrylic unsaturations are obtained by reacting functional groups of unsaturated monomers without solvents at temperatures above 150° C. and under controlled heat exchange, while maintaining intact their unsaturations, with functional groups of saturated and/or unsaturated polymers. The technologies and the work cycles used for conventional resins may also be used for these resin types.
Abstract: Disclosed herein is a moisture-absorbing and desorbing polymer, characterized in that, the said polymer is an organic high-molecular substance containing 1.0-8.0 meq/g of carboxyl group of a potassium type and having a cross-linking structure.
Abstract: The present invention can provide a water-absorbent or water-retention material comprising water-absorbent resin derived from monomer unit components comprising 40 to 99 wt. % of hydroxyl alkyl (meth)acrylate, 1 to 60 wt. % of (meth)acrylic acid and/or alkali metal salt thereof and 0.00001 to 3 wt. % of crosslinking agent; and a water-absorbent or water-retention material comprising water-swellable polymer which is obtained by further thermally crosslinking a particles of partially alkaline neutralized product of a copolymer of 20 to 99 mol % of acrylamide and 1 to 80 mol % of acrylic acid. The water-absorbent or water-retention material of the present invention is not readily subject to an influence of salts, and the absorbency does not deteriorate with respect to an aqueous solution containing a great amount of metallic ion of salts.
Abstract: Disclosed is a process for preparing temperature-responsive polymers that may be formed into a thermally-processable form which exhibits flushability properties when immersed in water such that the temperature-responsive polymer may be used in a disposable absorbent product to impart flushability properties to the product. The process prepares the temperature-responsive polymer in an aqueous solution using a chain transfer agent such as isopropanol.
Abstract: The present invention provides a novel class of polymer antiscalants which are polymers comprising a 1,2-dihydroxy-3-butene monomer unit and at least one monomer unit derived from the groups consisting of maleic acid, acrylic acid, acrylamide, methacrylic acid, itaconic acid, vinyl sulfonic acid, styrene sulfonic acid, N-tertbutylacrylamide, butoxymethylacrylamide, N,N-dimethylacrylamide, sodium acrylamidomethyl propane sulfonic acid, and salts thereof, with the proviso that said polymers do not contain the monomer unit —(CH2—CH═CH—CH2—O)—.
Type:
Grant
Filed:
November 9, 1999
Date of Patent:
May 15, 2001
Assignee:
Nalco Chemical Company
Inventors:
Prasad Yogendra Duggirala, John David Morris, Peter Edward Reed, Steven John Severtson
Abstract: What is described herein are conditioning/styling terpolymers of vinylpyrrolidone (VP), dimethylaminopropyl methacrylamide (DMAPMA) and C9-C24 alkyl dimethylaminopropyl methacrylic acid quaternized monomers (QDMAPMA), in a defined compositional range. Hair and skin care compositions which include these terpolymers exhibit advantageous low tackiness and high humidity resistance.
Type:
Grant
Filed:
May 7, 1999
Date of Patent:
March 27, 2001
Assignee:
ISP Investments Inc.
Inventors:
Janusz Jachowicz, Kou-Chang Liu, Roger L. Mc Mullen, Jr., Thomas Winkler
Abstract: A polymer of a low molecular weight having a very little odor is produced by emulsion-polymerizing a radical-polymerizable unsaturated monomer at a temperature of 115° C. or higher in the presence or absence of a chain transfer agent.