Oxygen Atom Is Part Of Ester Group Derived From Unsaturated Carboxylic Acid Patents (Class 526/307.7)
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Patent number: 12252622Abstract: An aqueous dispersion of resin particles comprising a dispersing group covalently bonded to the resin and at least one repeating unit of formula I, II and/or III and which is obtainable by contacting a compound A comprising at least 2 functional groups selected from the group of functional groups —X—C(?O)—CHR1-C(?O)—R2, —X—C(?O)—C?C—R2; or —X—C(?O)—CR1?CR2-NR11R12, with a compound B comprising at least two —NH2, —NH3+ or —N?C?O, wherein X, R1, R2, R3, R11 and R12 have the same meaning as that defined in the claims and wherein compound A and/or B comprise a dispersing group. The invention also includes a method of producing the aqueous dispersion and further relates to an aqueous inkjet ink comprising the resin particles.Type: GrantFiled: September 23, 2019Date of Patent: March 18, 2025Assignee: Agfa-Gevaert NVInventors: Tim Desmet, Johan Loccufier, Hubertus Van Aert, Ellen Bertels
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Patent number: 11248147Abstract: The invention relates to a wash-off label structure and an adhesive layer comprising a pressure sensitive hot melt adhesive layer sensitive to the washing conditions. According to an embodiment the adhesive layer comprises an acrylate composition curable with ultraviolet radiation and at least one modifier selected from a tackifier, a plasticizer and a filler, and wherein the peel adhesion from the labelled surface at 50-80° C. in alkaline aqueous solution of at least 30% less than the peel adhesion at room temperature of 23° C.±2° C. and relative humidity of 50%±5%. The invention further relates to a use of the label for recyclable or reusable packages, and a combination of a package and a wash-off label.Type: GrantFiled: June 24, 2014Date of Patent: February 15, 2022Assignee: UPM RAFLATAC OYInventors: Tom Saxberg, Sami Kivinen
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Patent number: 11034787Abstract: Acrylic copolymers that include the controlled placement of functional groups within the polymer structure are provided. The copolymers contain a reactive segment and a non-reactive segment and are manufactured via a controlled radical polymerization process. The copolymers are useful in the manufacture of adhesives and elastomers.Type: GrantFiled: March 20, 2009Date of Patent: June 15, 2021Assignee: Avery Dennison CorporationInventors: Christopher L. Lester, Brandon S. Miller, Michael J. Zajaczowski, William L. Bottorf, Kyle R. Heimbach
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Patent number: 10240068Abstract: An adhesive film of the present invention comprises a (meth)acrylate-based copolymer and a cross-linking agent, and a gel fraction thereof is approximately 50-95%, and a ratio of change G? in storage modulus thereof, represented by the following formula 1, is 20% or less. G?=(G7?G1)/G1×100??[Formula 1] (In formula 1, G1 is a storage modulus at 25° C. when the adhesive film is matured at 23° C. and a relative humidity (RH) of 55% for one day, and G7 represents a storage modulus at 25° C. when the adhesive film is matured at 23° C. and an RH of 55% for seven days.Type: GrantFiled: June 29, 2015Date of Patent: March 26, 2019Assignee: Samsung SDI Co., Ltd.Inventors: Irina Nam, Young Jong Kim, Hwan Sung Cheon, In Cheon Han
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Patent number: 9761403Abstract: A heat spreader for high volume manufacturing of a heat source, having a heat spreader composition which comprises a heat spreader material, an adhesive thereon, and a release material. The adhesive and release material are selected to prevent delamination of the heat spreader material when the release material is removed during the high volume manufacturing process of heat sources.Type: GrantFiled: June 4, 2012Date of Patent: September 12, 2017Assignee: Advanced Energy Technologies LLCInventors: Julian Norley, Martin David Smalc, Joseph Paul Capp, Timothy Clovesko
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Patent number: 9725622Abstract: An adhesive tape has a preferably textile carrier and of a pressure-sensitive adhesive which is applied on at least one side of the carrier and is in the form of a dried polymer dispersion. The polymer being synthesized from (a) 5% to 25% by weight, preferably 10% to 22% by weight, of ethylene, (b) 30% to 69% by weight, preferably 40% to 60% by weight, of alkylacrylic ester having C4 to C12 alkyl radicals, (c) 20% to 55% by weight, preferably 28% to 38% by weight, of vinyl acetate, (d) 0% to 10% by weight of other ethylenically unsaturated compounds, and the pressure-sensitive adhesive comprising between 15 and 100 parts by weight of a tackifier (based on the mass of the dried polymer dispersion).Type: GrantFiled: April 27, 2012Date of Patent: August 8, 2017Assignee: tesa SEInventors: Brigitte Korthals, Nicolai Böhm, Dennis Seitzer
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Patent number: 9249344Abstract: The present invention relates to a pressure sensitive adhesive composition comprising a copolymer having cross-linkable epoxy groups as well as a solvent. The copolymer is made up of one or more first, second and third monomers, wherein the first monomer possesses an epoxy group and third monomer has a bulky side chain. Surprisingly, the third monomer provides for stability without affecting the ability of the copolymer to form cross-links. The invention also relates to a method of preparing the pressure sensitive adhesive composition and to a method of its use.Type: GrantFiled: February 27, 2006Date of Patent: February 2, 2016Assignee: Henkel AG & Co. KGaAInventors: Kerstin Ursula Van Wijkschmitz, Martijn Johannes Verhagen, Martinus Rutgers, Evert Smit, Gerrit Hendrik Brunsveld
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Patent number: 9188722Abstract: The present invention aims at providing an antistatic pressure-sensitive adhesive optical film exhibiting excellent antistatic effect, optical properties, and water resistance and having excellent adhesion between the antistatic layer and the pressure-sensitive adhesive layer. An antistatic pressure-sensitive adhesive optical film, the optical film having an antistatic layer laminated on at least one side of the optical film, and a pressure-sensitive adhesive layer further laminated on the antistatic layer, wherein the antistatic layer comprises a conductive polymer and a sulfonic acid compound as raw material components, and the pressure-sensitive adhesive layer is formed of an acryl-based pressure-sensitive adhesive containing nitrogen.Type: GrantFiled: October 12, 2005Date of Patent: November 17, 2015Assignee: Nitto Denko CorporationInventors: Shinichi Inoue, Masayuki Satake, Toshitsugu Hosokawa, Akiko Ogasawara
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Patent number: 9056061Abstract: A transdermal nicotine salt delivery system to an individual. The system has a high nicotine salt loading to effect therapeutic flux rate. Acrylate polymeric drug reservoir with the high nicotine salt dissolved therein provides desirable adhesive characteristics and effective transdermal therapeutic properties.Type: GrantFiled: September 22, 2006Date of Patent: June 16, 2015Assignee: ALZA CorporationInventors: Robert M. Gale, Jay Audett, Rama V. Padmanabhan, Michel J. N. Cormier, Allison Luciano, Eric N. Silverberg, Paul B. Foreman
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Patent number: 9029471Abstract: Various fluoropolymers have been proposed for imparting oil and water repellency to leather. Commonly, these fluoropolymers are amphiphilic; i.e., they are made from at least one monomer which is hydrophobic and at least one monomer which is hydrophilic. The present invention identifies and remedies disadvantages associated with the ability of amphiphilic fluoropolymers to impart oil and water repellency to leather. Contrary to conventional thinking, it has now been discovered that the incorporation of hydrophilic groups in a fluoropolymer undesirably reduces its ability to impart water resistance to leather. Correspondingly, it has also been discovered that a fluoropolymer incorporating fewer or no hydrophilic groups imparts superior oil and water repellency to leather when compared to fluoropolymers incorporating more hydrophilic groups. Therefore, this invention provides fluoropolymers which incorporate reduced levels of hydrophilic groups.Type: GrantFiled: September 30, 2008Date of Patent: May 12, 2015Assignee: E I du Pont du Nemours and CompanyInventors: Romain Severac, Agnes Ibos, Lamia Heuze, Renaud Laloux-Walther
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Patent number: 9023966Abstract: The present invention relates compositions and methods for enhanced oil recovery. The method is directed to employing a water-soluble The present invention relates compositions and methods for enhanced oil recovery (EOR). The method is directed to employing a water-soluble functional polymeric surfactant (FPS), with a medium IFT value, preferably ranged from about 0.1 to about 15 dyne/cm between water phase containing polymeric surfactant and hydrocarbon phase, for recovery of hydrocarbons from subterranean formations. The FPS solution demonstrates a strong interaction with oil and the great potential to increase both volumetric sweep efficiency and microscopic displacement efficiency in EOR.Type: GrantFiled: April 23, 2009Date of Patent: May 5, 2015Inventors: Rui Zhang, Yongchun Tang
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Publication number: 20150119541Abstract: A process for the production of methacrylic acid or esters thereof by the base catalysed decarboxylation of at least one dicarboxylic acid selected from itaconic, citraconic or mesaconic acid or mixtures thereof in an aqueous reaction medium is described. The decarboxylation is carried out at a temperature in the range from 200° C. and up to 239° C. The methacrylic acid is isolated from the aqueous reaction medium by a purification process which does not include introducing an organic solvent to the aqueous reaction medium for solvent extraction of the methacrylic acid into an organic phase. A method of preparing polymers or copolymers of methacrylic acid or methacrylic acid esters is also described.Type: ApplicationFiled: April 26, 2013Publication date: April 30, 2015Inventors: Graham Ronald Eastham, David William Johnson, Mark Waugh
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Publication number: 20150094438Abstract: A process for the production of methacrylic acid by the base catalysed decarboxylation of at least one dicarboxylic acid selected from itaconic, citraconic or mesaconic acid or mixtures thereof is described. The decarboxylation is carried out at a temperature in the range from 100 to 199° C. A method of preparing polymers or copolymers of methacrylic acid or methacrylic acid esters is also described.Type: ApplicationFiled: April 26, 2013Publication date: April 2, 2015Inventors: Graham Ronald Eastham, David William Johnson, Mark Waugh
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Patent number: 8921478Abstract: A method of inhibiting hydrates in a fluid comprising water and gas comprising adding to the fluid an effective hydrate-inhibiting amount of a composition comprising one or more copolymers of N-alkyl(alkyl)acrylamide monomers and one or more cationic monomers selected from acid and alkyl chloride quaternary salts of N,N-dialkylaminoalkyl(meth)acrylates and N,N-dialkylaminoalkyl(meth)acrylamides.Type: GrantFiled: October 17, 2008Date of Patent: December 30, 2014Assignee: Nalco CompanyInventors: Peter G. Conrad, Erick J. Acosta, Kevin P. McNamee, Brian M. Bennett, Olga E. S. Lindeman, Joseph R. Carlise
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Patent number: 8911928Abstract: A resist composition including a base component (A) that exhibits changed solubility in a developing solution under action of acid and an acid generator component (B) that generates acid upon exposure, wherein the base component (A) contains a resin component (A1) including a structural unit (a0) represented by general formula (a0-1) shown below and a structural unit (a1)) containing an acid decomposable group that exhibits increased polarity under action of acid, and the amount of the structural unit (a0) is less than 50 mol %, wherein R represents a hydrogen atom, an alkyl group of 1 to 5 carbon atoms or a halogenated alkyl group of 1 to 5 carbon atoms; R1 represents a divalent linking group; R2 represents a —SO2— containing cyclic group; and v represents 0 or 1.Type: GrantFiled: May 22, 2012Date of Patent: December 16, 2014Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Tomoyuki Hirano, Daiju Shiono, Daichi Takaki, Junichi Tsuchiya
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Publication number: 20140309391Abstract: The acrylic copolymer according to the present invention has a specific repeating unit and includes, in a chain, a methacrylate unit, a glutaric anhydride unit, or a mixture thereof in the amount of 0 to 1 ppm.Type: ApplicationFiled: November 8, 2012Publication date: October 16, 2014Applicant: Cheil Industries Inc.Inventors: In Sik Jeon, Beom Jun Joo, Im Hyuck Bae
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Patent number: 8859699Abstract: A non-specific adsorption inhibitor includes a water-soluble polymer obtained by polymerizing a monomer unit that includes a monomer (A) that forms a polymer that has a lower critical solution temperature (LCST) of 80° C. or less in an aqueous solution under normal pressure when subjected to homopolymerization, and a monomer (B) that forms a polymer that does not have the LCST in an aqueous solution under normal pressure when subjected to homopolymerization.Type: GrantFiled: May 19, 2008Date of Patent: October 14, 2014Assignee: JSR CorporationInventors: Kouji Tamori, Eiji Takamoto, Toshihiro Ogawa
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Patent number: 8829133Abstract: To provide an ABA triblock copolymer containing: an A-block having, in a constitutional unit thereof, a monomer represented by the following general formula (1) or a monomer represented by the following general formula (2); and a B-block having, in a constitutional unit thereof, a hydrophilic monomer having a radical polymerizable unsaturated bond, where R1 is a hydrogen atom or a methyl group; R2 is a C5-C18 alkylene group; M is a hydrogen atom or a monovalent metal atom; and X1 is —NH— or an oxygen atom in the general formula (1), and where R11 is a hydrogen atom or a methyl group; R12 is a C5-C18 alkylene group; R13 and R14 are each independently a hydrogen atom, a methyl group, or an ethyl group; and X11 is —NH— or an oxygen atom in the general formula (2).Type: GrantFiled: April 22, 2013Date of Patent: September 9, 2014Assignees: Ricoh Company, Ltd., University of HyogoInventors: Yuuma Usui, Shin-ichi Yusa
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Patent number: 8815972Abstract: The present invention relates to ionic silicone hydrogel polymers displaying improved thermal stability. More specifically, the present invention relates to a polymer formed from reactive components comprising at least one silicone component and at least one ionic component comprising at least one anionic group. The polymers of the present invention display good thermal stability and desirable protein uptake.Type: GrantFiled: May 21, 2013Date of Patent: August 26, 2014Assignee: Johnson & Johnson Vision Care, Inc.Inventors: Osman Rathore, Zohra Fadli, Mark Lada, James D. Ford, Azaam Alli, Yongcheng Li
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Patent number: 8778595Abstract: A resist composition containing a base component (A) which generates acid upon exposure, and exhibits changed solubility in a developing solution under the action of acid, wherein the base component (A) contains a polymeric compound (A1) having a structural unit (a5) represented by general formula (a5-0) shown below and a structural unit (a6) that generates acid upon exposure. In the formula, R represents a hydrogen atom, an alkyl group of 1 to 5 carbon atoms or a halogenated alkyl group of 1 to 5 carbon atoms, R1 represents a sulfur atom or an oxygen atom, R2 represents a single bond or a divalent linking group, and Y represents a hydrocarbon group in which a carbon atom or a hydrogen atom may be substituted with a substituent.Type: GrantFiled: November 16, 2012Date of Patent: July 15, 2014Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Daichi Takaki, Daiju Shiono, Yoshiyuki Utsumi, Jun Iwashita
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Patent number: 8765358Abstract: A water-soluble resin composition for forming fine patterns comprising water-soluble polymer represented by Chemical Formula 1 as below and the first water-soluble solvent, is coated and heated on a photoresist layer having at least one contact hole to reduce a size of the at least one contact hole. (In Chemical Formula 1, each of R1, R2, R3 and R5 independently represents an alkyl group of C1-30 or an cyclo alkyl group of C3-30 which respectively have one selected from the group consisting of hydrogen, an ether group, an ester group, a carbonyl group, an acetal, an epoxy group, a nitril group, an amine group, and an aldehyde group; each of R4, R6, R7 and R8 independently represents hydrogen or a methyl group; n represents an integer of 0 to 5; a represents a real number of 0.05 to 0.5; each of b, c and d respectively represents a real number of 0 to 0.7; and a+b+c+d=1).Type: GrantFiled: June 29, 2011Date of Patent: July 1, 2014Assignee: Korea Kumho Petrochemical Co., Ltd.Inventors: Sang Wook Park, So Jung Park, Dong-Chul Seo
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Patent number: 8691924Abstract: The present invention provides an optical-use pressure-sensitive adhesive sheet, which includes a pressure-sensitive adhesive layer containing a polymer formed of one or more monomer ingredients containing, as an indispensable monomer ingredient, a monomer of which homopolymer has a glass transition temperature of not lower than ?10° C., said sheet having a moisture content of at least 0.65% by weight after stored in an environment at 60° C. and 95% RH for 120 hours. The pressure-sensitive adhesive layer is preferably an acrylic pressure-sensitive adhesive layer.Type: GrantFiled: November 8, 2010Date of Patent: April 8, 2014Assignee: Nitto Denko CorporationInventors: Shou Takarada, Takahiro Nonaka, Hiroaki Kishioka, Hiroaki Fumoto, Tomohide Banba, Masayuki Okamoto, Masahito Niwa
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Patent number: 8685620Abstract: A resist composition including a base component (A) which exhibits changed solubility in a developing solution under action of acid and an acid-generator component (B) which generates acid upon exposure, the base component (A) containing a polymeric compound (A1) having a structural unit (a5) represented by general formula (a5-0) shown below (R1 represents a sulfur atom or an oxygen atom; R2 represents a single bond or a divalent linking group; and Y represents an aromatic hydrocarbon group or an aliphatic hydrocarbon group having a polycyclic group, provided that the aromatic hydrocarbon group or the aliphatic hydrocarbon may have a carbon atom or a hydrogen atom thereof substituted with a substituent.Type: GrantFiled: November 6, 2012Date of Patent: April 1, 2014Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Daichi Takaki, Daiju Shiono, Yoshiyuki Utsumi, Takaaki Kaiho
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Patent number: 8628847Abstract: An adhesive binder, an adhesive composition including the same, an optical member, and associated methods, the adhesive binder including a (meth)acrylic copolymer having urethane, hydroxyl, aromatic, and vinyl groups in side chains thereof.Type: GrantFiled: December 28, 2010Date of Patent: January 14, 2014Assignee: Cheil Industries, Inc.Inventors: Kyoung Jin Ha, Kil Sung Lee, Mi Sun Kim, Irina Nam, Chang Min Lee
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Patent number: 8568875Abstract: Copolymers which are composed of at least 4 monomers, including (meth)acrylate compounds containing perfluoroalkyl groups, are suitable for the treatment of fiber materials. The copolymers are usually used here in the form of aqueous dispersions. The fiber materials are in particular fabrics, for example made of polyolefin. Treatment with the copolymers imparts to them oil- and water-repellent properties and also repellent properties toward low molecular weight alcohols.Type: GrantFiled: December 11, 2012Date of Patent: October 29, 2013Assignee: Huntsman Textile Effects (Germany) GmbHInventors: Rolf Moors, Wilhelm Artner, Isabella Rettenbacher, Edeltraud Schidek
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Patent number: 8569435Abstract: Biocompatible polymers are manufactured to include an amino acid mimetic monomer and one or more hydrophobic acrylate monomers. The amino acid mimetic monomers are selected to mimic the side chain of the amino acids asparagine or glutamine. The amino acid mimetic monomer can be a methacryloyl or acryloyl derivative of 2-hydroxyacetamide, 3-hydroxypropionamide, alaninamide, lactamide, or glycinamide. These amide functional groups offer the advantage of moderate hydrophilicity with little chemical reactivity. The amino acid mimetic monomer can be copolymerized with one or more hydrophobic acrylate monomers to obtain desired coating properties.Type: GrantFiled: March 10, 2011Date of Patent: October 29, 2013Assignee: Abbott LaboratoriesInventor: Stephen Pacetti
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Publication number: 20130274431Abstract: Disclosed herein is a methacrylic resin prepared using a mercaptan and a lactam as an initiation system. The methacrylic resin includes an alkyl(meth)acrylate unit and a (meth)acrylamide unit, and has a weight average molecular weight of about 50,000 g/mol to about 500,000 g/mol and a glass transition temperature of about 125° C. to about 145° C.Type: ApplicationFiled: June 17, 2013Publication date: October 17, 2013Inventors: Kwang Won SEO, Byeong Do LEE, Jae Keun HONG, Joong In KIM
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Patent number: 8552126Abstract: The present invention relates to an aqueous polymer dispersion whose dispersed addition polymer P comprises, copolymerized in free-radically polymerized form, at least one polar monomer having a water solubility of greater than 50 g/liter (measured at 20° C.), and obtainable by free-radically initiated aqueous emulsion polymerization, the polar monomer being metered to the reaction mixture during the polymerization process at a variable, i.e., nonconstant rate, for example in the sense of a rate gradient. The present invention further relates to processes for preparing these aqueous polymer dispersions, to their use as binders and/or in coatings, and also to coatings comprising the polymer dispersion of the invention.Type: GrantFiled: February 17, 2012Date of Patent: October 8, 2013Assignee: BASF SEInventors: Ekkehard Jahns, Sebastian Roller
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Patent number: 8552132Abstract: The present invention provides rheology modifiers, which are water-soluble polymers having a weight average molecular weight (Mw) of at least 1,000,000 g/mol and an intrinsic viscosity of at least 2.5 dl/g, both as determined by size exclusion chromatography, and wherein the water-soluble polymers are in the form of solid particles. It also provides mixtures of rheology modifiers comprising a first rheology modifier, which is a water-soluble polymer having a weight average molecular weight (Mw) of at least 1,000,000 g/mol and an intrinsic viscosity of at least 2.5 dl/g, both as determined by size exclusion chromatography, and a second rheology modifier, which has a weight average molecular weight of from 2,000 g/mol to 800,000 g/mol. It also provides coating composition containing the rheology modifiers, respectively, mixtures of rheology modifiers, a process for their preparation, a process for coating a substrate using these coating compositions and substrates coated with these coating compositions.Type: GrantFiled: September 4, 2006Date of Patent: October 8, 2013Assignee: BASF SEInventors: Tamal Ghosh, Malcolm Skinner, Tiina Luttikhedde, Céline Hossenlopp, Laurent Brauge
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Publication number: 20130251991Abstract: There is provided a pressure sensitive adhesive displaying sufficient adhesive force to the surface of PMMA under a wide range of temperatures including ambient, low, and high temperatures, and also an adhesive tape having an adhesive layer including the pressure sensitive adhesive. There is provided a pressure sensitive adhesive comprising a polymer obtained by polymerizing 100 mass parts of a monomer mixture comprising: a monomer component 1 comprising an acrylate mixture selected from an aliphatic alkyl(meth)acrylate having a carbon number of 4-6 and an aliphatic alkyl(meth)acrylate having a carbon number of 7-12; a monomer component 2 comprising an amide group-containing vinyl monomer; a monomer component 3 comprising an ester of a non-tertial aromatic alcohol and (meth)acrylic acid, or an ester of a non-tertial alicyclic alcohol and (meth)acrylic acid; and a monomer component 4 comprising (meth)acrylic acid.Type: ApplicationFiled: December 1, 2011Publication date: September 26, 2013Applicant: 3M Innovative Properties CompanyInventors: Aizoh Sakurai, Kosuke Sugawa
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Publication number: 20130144023Abstract: The present invention relates to an acrylic copolymer having high heat resistance and high strength, and an optical film comprising the same, and more particularly, to an acrylic copolymer for optical films in which alkyl (meth)acrylate monomers; (meth)acrylate monomers comprising aromatic rings and/or aliphatic rings; and (meth)acrylamide monomers are included and polymerized. An acrylic copolymer according to the present invention is excellent in heat resistance while maintaining transparency. Further, an optical film comprising a compound resin including the acrylic copolymer has superior transparency and heat resistance and is excellent in formability, adhesion, retardation properties, and durability.Type: ApplicationFiled: June 8, 2011Publication date: June 6, 2013Applicant: LG CHEM, LTDInventors: Su-Kyung Kim, Da-Eun Sung, Chang-Hun Han, Byung-Il Kang, Jae-Bum Seo, Eun-Jung Choi, Byoung-Kue Chun, Yu-Taek Sung
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Publication number: 20130122288Abstract: Disclosed is a pressure-sensitive adhesive composition capable of forming a pressure-sensitive adhesive layer having satisfactory tackiness at room temperature and superior reworkability at a low temperature. The pressure-sensitive adhesive composition includes an acrylic polymer formed from a monomer component through polymerization, or a partial polymer of the monomer component. The monomer component includes a (meth)acrylic alkyl ester whose alkyl moiety being a linear or branched-chain alkyl group having 10 to 13 carbon atoms and includes substantially no carboxyl-containing monomer.Type: ApplicationFiled: November 9, 2012Publication date: May 16, 2013Applicant: NITTO DENKO CORPORATIONInventor: Nitto Denko Corporation
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Patent number: 8440760Abstract: Disclosed herein is a methacrylic copolymer which is a polymer of a monomer mixture comprising about 20 to about 99.9% by weight of a C6-20 aromatic methacrylate, an aliphatic methacrylate, or a combination thereof, and about 0.1 to about 80% by weight of a mono-functional unsaturated monomer. The methacrylic copolymer can have a high refractive index of about 1.495 to about 1.59, and thus when it is blended with polycarbonate resin, it is possible to obtain a methacrylic resin composition having improved compatibility without any other compatibilizer.Type: GrantFiled: April 12, 2010Date of Patent: May 14, 2013Assignee: Cheil Industries Inc.Inventors: Il Jin Kim, Kee Hae Kwon, Hyung Rang Moon
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Patent number: 8431624Abstract: The invention provides a class of actinically-crosslinkable silicone-containing prepolymers which comprise (1) ethylenically-unsaturated groups and (2) UV-absorbing polymeric units, latent UV-absorbing polymeric units, and/or dual photo-functional polymeric units. The prepolymer of the invention can be used to prepare silicone hydrogel contact lenses capable of absorbing UV/visible radiation. The present invention is also related to silicone hydrogel contact lenses made from a prepolymer of the invention and methods for making the contact lenses in a cost-effective way and with high consistency and high fidelity to the original lens design.Type: GrantFiled: September 13, 2010Date of Patent: April 30, 2013Assignee: Novartis AGInventors: Angelika Maria Domschke, Troy Vernon Holland, Richard Charles Turek
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Publication number: 20130090269Abstract: The present invention relates to a dendritic comb-shaped polymer thickening agent and preparation and application thereof; it is a copolymer obtained by copolymerization of monomer (A) and monomer (B). Monomer (A) is one or more water-soluble unsaturated monomers with olefin chain, and monomer (B) is at least one monomer with the following general structure: wherein R1, R2 is selected from H or C1˜C12 alkyl group, respectively; R3, R4, R5 is selected from H or C1˜C8 alkyl group, C1˜C8 alkylaryl group, C1˜C8 alkyl ether or C1˜C8 alkyl ester group, respectively; A? is selected from COO? or OH. The content of the monomer (A) is 70˜99.99% of the total mass of the monomer (A) and the monomer (B), and the content of monomer (B) is 0.01˜30% of the total mass of the monomer (A) and the monomer (B). The viscosity of the polymer solution with the present polymer is 30% higher than that with common polyacrylamide and it is used in polymer flooding for oil reservoir with permeability lower than 400 mD in oilfields.Type: ApplicationFiled: June 11, 2010Publication date: April 11, 2013Applicant: Petrochina Company LimitedInventors: Jianhui Luo, Huaijiang Zhu, Fengluan Bai, Pingmei Wang, Bin Ding, Jingbo Yang, Qiang Liu, Yuzhang Liu
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Patent number: 8349976Abstract: Copolymers which are composed of at least 4 monomers, including (meth)acrylate compounds containing perfluoroalkyl groups, are suitable for the treatment of fiber materials. The copolymers are usually used here in the form of aqueous dispersions. The fiber materials are in particular fabrics, for example made of polyolefin. Treatment with the copolymers imparts to them oil- and water-repellent properties and also repellent properties toward low molecular weight alcohols.Type: GrantFiled: May 14, 2008Date of Patent: January 8, 2013Assignee: Huntsman Textile Effects (Germany) GmbHInventors: Rolf Moors, Wilhelm Artner, Isabella Rettenbacher, Edeltraud Schidek
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Patent number: 8334350Abstract: The present invention relates to an aqueous polymer dispersion whose dispersed addition polymer P comprises, copolymerized in free-radically polymerized form, at least one polar monomer having a water solubility of greater than 50 g/liter (measured at 20° C.), and obtainable by free-radically initiated aqueous emulsion polymerization, the polar monomer being metered to the reaction mixture during the polymerization process at a variable, i.e., nonconstant rate, for example in the sense of a rate gradient. The present invention further relates to processes for preparing these aqueous polymer dispersions, to their use as binders and/or in coatings, and also to coatings comprising the polymer dispersion of the invention.Type: GrantFiled: December 16, 2008Date of Patent: December 18, 2012Assignee: BASF SEInventors: Ekkehard Jahns, Sebastian Roller
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Patent number: 8241462Abstract: To provide a papermaking internal sizing agent capable of efficiently imparting sizing performance even in neutral papermaking which uses calcium carbonate as filler, and uses no aluminum sulfate or uses a small amount of aluminum sulfate, and also provide a paper or a paperboard obtained by using the papermaking internal sizing agent. The papermaking internal sizing agent comprises as an effective ingredient an amphoteric copolymer having hydrophobic groups and cationic groups, at least a part of the cationic groups being quaternized. Preferably, the amphoteric copolymer is obtained by polymerizing monomer ingredients that it essentially contain a hydrophobic monomer (A), a cationic monomer (B), and an anionic monomer (C) and that an anion equivalent of the monomer (C) is 0.1 to 90% of a cation equivalent of the monomer (B), in which a rate of quaternizing of the cationic groups is not less than 40% by mole. The paper or the paperboard contains the above papermaking internal sizing agent.Type: GrantFiled: March 6, 2008Date of Patent: August 14, 2012Assignees: Harima Chemicals, Inc., Nippon Paper Industries Co., Ltd.Inventors: Kazunari Sakai, Takahiro Fujiwara, Kazushige Inaoka, Takashi Yamaguchi, Masaki Ito, Yasunobu Ooka
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Publication number: 20120141408Abstract: An ophthalmic device is disclosed that is a polymerization product of a monomeric mixture comprising (a) a major amount of a non-silicone-containing hydrophilic monomer; (b) a hydrophobic monomer; and (c) a crosslinking agent, wherein the ophthalmic device has an equilibrium water content of at least about 70 weight percent and further wherein the ophthalmic device has an evaporative dehydration barrier layer on the surface thereof. A method for the mitigation of evaporative corneal dehydration employing the high water content ophthalmic device is also disclosed.Type: ApplicationFiled: February 10, 2012Publication date: June 7, 2012Inventors: Richard I. Blackwell, Joseph C. Salamone, Jay F. Kunzler
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Publication number: 20120100358Abstract: The invention relates to a method for preparing molecular imprint polymers (MIP) by radical polymerisation that uses at least one primer including at least two chemical functions capable of forming reactive radicals, thereby providing a locally high radical concentration for priming the polymerisation on or about the imprint entity or molecule. The invention also relates to molecular imprint polymers (MIP) that can be obtained by the method of the invention, and to the use thereof in the production of biomimetic biosensors, biomimetic biochips, chemical sensors, specific adsorption separation devices, as a coating, particularly for releasing active ingredients.Type: ApplicationFiled: September 1, 2009Publication date: April 26, 2012Applicant: Universite De Technologie De Compiegne - UTCInventors: Karsten Haupt, Arnaud Cutivet, Jeanne Bernadette Tse Sum Bui, Pinar Cakir
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Patent number: 8119110Abstract: Disclosed herein are a cosmetic composition comprising a cosmetically acceptable organic liquid medium, at least one non-volatile silicone oil and at least one film-forming block ethylenic polymer and use of the composition for making up keratin materials, such as the skin.Type: GrantFiled: September 27, 2004Date of Patent: February 21, 2012Assignee: L'Oreal S.A.Inventors: Xavier Blin, Véronique Ferrari
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Patent number: 8114936Abstract: The invention relates to polymers useful as a papermaking additives. The invention also relates to methods for making and using such additives.Type: GrantFiled: April 6, 2011Date of Patent: February 14, 2012Inventors: Lucyna Pawlowska, Robert Proverb
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Patent number: 8071705Abstract: Biocompatible polymers are manufactured to include an amino acid mimetic monomer and one or more hydrophobic acrylate monomers. The amino acid mimetic monomers are selected to mimic the side chain of the amino acids asparagine or glutamine. The amino acid mimetic monomer can be a methacryloyl or acryloyl derivative of 2-hydroxyacetamide, 3-hydroxypropionamide, alaninamide, lactamide, or glycinamide. These amide functional groups offer the advantage of moderate hydrophilicity with little chemical reactivity. The amino acid mimetic monomer can be copolymerized with one or more hydrophobic acrylate monomers to obtain desired coating properties.Type: GrantFiled: March 10, 2011Date of Patent: December 6, 2011Assignee: Abbott LaboratoriesInventor: Stephen Pacetti
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Publication number: 20110269904Abstract: Of the many embodiments presented herein, one is a subterranean treatment fluid comprising: an aqueous fluid; and a water-soluble degradable synthetic vinyl polymer having a labile link in its backbone. Also provided in one instance is a water-soluble degradable synthetic vinyl polymer with labile group in its backbone made by a redox polymerization, the redox polymerization reaction comprising these reactants: a macroinitiator that comprises a labile link, an oxidizing metal ion, and a vinyl monomer.Type: ApplicationFiled: April 30, 2010Publication date: November 3, 2011Inventors: Alexander Bismarck, Emilia M. Kot, Rajesh K. Saini
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Patent number: 8048975Abstract: Biocompatible polymers are manufactured to include an amino acid mimetic monomer and one or more hydrophobic acrylate monomers. The amino acid mimetic monomers are selected to mimic the side chain of the amino acids asparagine or glutamine. The amino acid mimetic monomer can be a methacryloyl or acryloyl derivative of 2-hydroxyacetamide, 3-hydroxypropionamide, alaninamide, lactamide, or glycinamide. These amide functional groups offer the advantage of moderate hydrophilicity with little chemical reactivity. The amino acid mimetic monomer can be copolymerized with one or more hydrophobic acrylate monomers to obtain desired coating properties.Type: GrantFiled: March 10, 2011Date of Patent: November 1, 2011Assignee: Abbott LaboratoriesInventor: Stephen Pacetti
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Publication number: 20110263806Abstract: The invention relates to a copolymer for producing molded compounds or cast glass for the production of molded bodies having increased dimensional stability under heat, obtainable from the copolymerization of A) one or more ethylenically unsaturated ester compounds of the formula (I), where R1 is hydrogen or methyl and R2 a linear or branched alkyl group with 1 to 8 carbon atoms, B) one or more ethylenically unsaturated ester compounds of the formula (II), where R3 is hydrogen or methyl and R4 a cyclic group with 8 to 30 carbon atoms, C) one or more ethylenically unsaturated ester compounds of the formula (III), where R5 is hydrogen or methyl and R6 and R7, independently of each other, are hydrogen or a linear or branched group with 1 to 40 carbon atoms.Type: ApplicationFiled: October 15, 2009Publication date: October 27, 2011Applicant: Evonik Roehm GmbHInventors: Gerald Dietrich, Ruediger Carloff, Wilhelm Karnbrock, Joachim Knebel, Zhong Shen, Chiew-Chiang Haw
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Patent number: 8044156Abstract: Disclosed are multi-purpose polymers that are the polymerization product of a monomer mixture comprising at least one amino-substituted vinyl monomer; at least one nonionic vinyl monomer; at least one associative vinyl monomer; at least one semihydrophobic vinyl surfactant monomer; and, optionally, comprising one or more hydroxy-substituted nonionic vinyl monomer, crosslinking monomer, chain transfer agent or polymeric stabilizer. These vinyl addition polymers have a combination of substituents, including amino substituents that provide cationic properties at low pH, hydrophobic substituents, hydrophobically modified polyoxyalkylene substituents, and hydrophilic polyoxyalkylene substituents. The polymers provide surprisingly beneficial rheological properties in acidic aqueous compositions, and are compatible with cationic materials. The multi-purpose polymers are useful in a variety of products for personal care, health care, household care, institutional and industrial care, and industrial applications.Type: GrantFiled: May 22, 2008Date of Patent: October 25, 2011Assignee: Lubrizol Advanced Materials, Inc.Inventors: Krishnan Tamareselvy, Thomas A. Barker, James E. Mullee, Charles T. Greenslade, Julie F. Schmucker-Castner, Deborah S. Filla
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Patent number: 8039568Abstract: The present invention relates to copolymers which comprise ethyl methacrylate, at least one ?,?-ethylenically unsaturated amide group-containing compound and at least one monoethylenically unsaturated carboxylic acid in copolymerized form, to cosmetic and pharmaceutical compositions which comprise at least one such copolymer, and to the use of these copolymers.Type: GrantFiled: October 19, 2005Date of Patent: October 18, 2011Assignee: BASF SEInventors: Son Nguyen-Kim, Gabi Winter, Matthias Laubender
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Patent number: 8034888Abstract: The present invention relates to amphoteric copolymers which comprise ethyl methacrylate, if appropriate a N-vinyllactam compound, at least one monoethylenically unsaturated carboxylic acid and at least one compound with ?,?-ethylenically unsaturated double bond and at least one cationogenic and/or cationic group in copolymerized form, to cosmetic and pharmaceutical compositions which comprise such copolymers, to preparation methods, and to the use of these copolymers.Type: GrantFiled: October 19, 2005Date of Patent: October 11, 2011Assignee: BASF SEInventors: Son Nguyen-Kim, Gabi Winter, Matthias Laubender
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Publication number: 20110166308Abstract: The present invention provides polymers resulting from polymerization of at least one reactive vinyl monomer moiety and a multifunctional N-vinylformamide crosslinking moiety; polymers resulting from polymerization of at least one reactive vinyl monomer moiety and a hybrid N-vinylformamide crosslinking moiety having at least one N-vinylformamide functionality and at least one other reactive vinyl functionality; polymers resulting from polymerization of at least one hybrid reactive N-vinylformamide monomer moiety having one N-vinylformamide functionality and at least one other reactive non-vinyl functionality and a multifunctional N-vinylformamide crosslinking moiety; and polymers resulting from polymerization of at least one hybrid reactive N-vinylformamide monomer moiety having one N-vinylformamide functionality and at least one other reactive non-vinyl functionality and a hybrid N-vinylformamide crosslinking moiety having at least one N-vinylformamide functionality and at least one other reactive vinyl funcType: ApplicationFiled: January 5, 2011Publication date: July 7, 2011Inventors: Osama M. Musa, Ilya Makarovsky, Lei Cuiyue