From Cycloaliphatic Monomer Patents (Class 526/308)
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Patent number: 7501222Abstract: A polymer including a monomer represented by the following Formula and a photoresist composition including the same are disclosed. The polymer and photoresist composition can improve the resolution and the process margin due to the low activation energy of the deprotection reaction of the alcohol ester group including saturated cyclic hydrocarbyl group, and also can produce fine photoresist patterns because they have a stable PEB(Post Exposure Baking) temperature sensitivity, and further, can improve the focus depth margin and the line edge roughness of the resist layer. In the above Formula, R* is a hydrogen or methyl group, R1 is saturated hydrocarbyl group of 1 to 5 carbon atoms, R is mono-cyclic or multi-cyclic homo or hetero saturated hydrocarbyl group of 3 to 50 carbon atoms, and n is an integer of at least 2.Type: GrantFiled: June 21, 2006Date of Patent: March 10, 2009Assignee: Dongjin Semichem Co., Ltd.Inventors: Jung-Youl Lee, Jae-Woo Lee, Jae-Hyun Kim
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Publication number: 20090061117Abstract: It is an object of the present invention to provide a sealant for a One prop Fill process which hardly causes a peeling phenomenon between the sealant and a substrate in production of liquid crystal display device since the sealant has excellent adhesion to the substrate, and which is most suitable for producing a liquid crystal display device having low color irregularity in liquid crystal display since the sealant does not cause liquid crystal contamination, and relates to a sealant for a One prop Fill process, in which in production of liquid crystal display device by a One prop Fill process, even a portion where light may be not directly irradiated can be adequately cured, a liquid crystal is not deteriorated by ultraviolet light to be irradiated in curing the sealant, and high display quality and high reliability of the liquid crystal display device can be realized, a vertically conducting material, and a liquid crystal display device obtained by using these.Type: ApplicationFiled: May 8, 2006Publication date: March 5, 2009Inventors: Yuichi Oyama, Hideyasu Nakajima, Takashi Watanabe, Takuya Yamamoto, Mitsuru Tanikawa
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Publication number: 20090035546Abstract: The present invention relates to polyethylene films, and to processes for making films. In particular the invention relates to solid state stretched films that may be monoaxially or biaxially oriented. The processes can tolerate high draw ratios and lower extrusion pressures and amperes while producing films having high tensile strength and modulus as well as low shrinkage. The polyethylene used to make the films has a density of from 0.940 to less than 0.960, a molecular weight distribution of greater than 10, a melt flow index ranging from 0.30 dg.min to 1.00 dg/min and a weight average molecular weight of 300,000 or less.Type: ApplicationFiled: July 30, 2007Publication date: February 5, 2009Applicant: FINA TECHNOLOGY, INC.Inventor: Michael McLeod
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Publication number: 20080299503Abstract: The formation of high-resolution resist patterns by liquid immersion lithography with various fluids is enabled by protecting a resist film from deterioration (such as bridging) during the immersion exposure in a fluid (such as water) and the fluid from deterioration and improving the stability of a resist film in the storage after exposure without increase in the number of treatment steps. A material for forming resist protection films which comprises an alkali-soluble polymer for forming a protective overcoat for a resist film, characterized in that the contact angle of the polymer to water is 90° or above. The polymer is preferably an acrylic polymer which comprises as the essential components constituent units derived from (meth) acrylic acid and constituent units derived from a specific acrylic ester.Type: ApplicationFiled: December 22, 2005Publication date: December 4, 2008Applicant: TOKYO OHKA KOGYO CO., LTD.Inventors: Keita Ishiduka, Kotaro Endo
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Patent number: 7452950Abstract: Photochromic monomers and methods for preparing these photochromic monomers, photochromic polymers based on these photochromic monomers and methods for preparing these photochromic polymers, as well as the use of these photochromic polymers in a polymer binder as a two-photon recording medium for an optical 3D memory and photoswitches of optical signals are disclosed. The materials exhibit thermally irreversible photochromic transformations and other properties enabling the use of the photochromic polymers in an optical two-photon read/write memory.Type: GrantFiled: September 26, 2005Date of Patent: November 18, 2008Assignees: Samsung Electronics Co., Ltd., Photochemistry Center of Russian Academy of SciencesInventors: Alexandr Alexandrovich Dunaev, Mikhail Vladimisovich Alfimov, Valery Alexandrovich Barachevsky, Valery Alexandrovidh Vasnev, Igor Victorovich Zavarzin, Sergey Nikolaevich Ivanov, Mukhammed Lastanbievich Keshtov, Ajexel Ivanovich Kovalev, Mikhall Mikhallovich Krayushkin, Yury Alexandrovich Pyankov, Alexandr Lyovich Rusanov, Yury Petrovich Strokach, Vladimir Nikolaevich Yarovenko
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Patent number: 7439315Abstract: A copolymer film having a decreased dielectric constant which is produced by supplying at least two organic monomers as raw materials, forming a film of a copolymer comprising a backbone based on said at least two monomers on a surface of a substrate, and heating the copolymer film at a temperature higher than a temperature at which the copolymer film is formed.Type: GrantFiled: July 22, 2005Date of Patent: October 21, 2008Assignee: NEC CorporationInventors: Nobutaka Kunimi, Jun Kawahara, Akinori Nakano, Keizo Kinoshita
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Publication number: 20080214756Abstract: A copolymer containing units represented by the defined formula (1) and cyclic olefin units; and a process for producing the copolymer, which comprises the step of copolymerizing a compound represented by the defined formula (3) with a cyclic olefin, the units represented by the formula (1) being polymerized units of the compound represented by the formula (3) such as isopropylidene diallylmalonate.Type: ApplicationFiled: February 23, 2008Publication date: September 4, 2008Applicants: Sumitomo Chemical Company, Limited, Tokyo Institute of TechnologyInventors: Kohtaro Osakada, Daisuke Takeuchi, Sehoon Park, Makoto Uemura, Masayuki Fujita
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Publication number: 20080214754Abstract: A polymer containing units represented by the defined formula (1); and a process for producing the polymer, which comprises the step of polymerizing a compound represented by the defined formula (3), the units represented by the formula (1) being polymerized units of the compound represented by the formula (3) such as 5,5-diallylbarbituric acid.Type: ApplicationFiled: December 18, 2007Publication date: September 4, 2008Applicants: SUMITOMO CHEMICAL COMPANY, LIMITED, TOKYO INSTITUTE OF TECHNOLOGYInventors: Kohtaro OSAKADA, Daisuke TAKEUCHI, Sehoon PARK, Makoto UEMURA, Masayuki FUJITA
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Publication number: 20080214755Abstract: A copolymer containing units represented by the defined formula (1) and olefin units; and a process for producing the copolymer, which comprises the step of copolymerizing a compound represented by the defined formula (3) with an olefin, the units represented by the formula (1) being polymerized units of the compound represented by the formula (3) such as 5,5-diallyl-2,2-dimethyl-1,3-dioxane.Type: ApplicationFiled: February 23, 2008Publication date: September 4, 2008Applicants: Sumitomo Chemical Company, Limited, Tokyo Institute of TechnologyInventors: Kohtaro Osakada, Daisuke Takeuchi, Sehoon Park, Makoto Uemura
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Publication number: 20080207862Abstract: A thin film formed from at least one polycyclic alicyclic compound selected from among compounds of the following formulas (1), (2) and (3) as a precursor.Type: ApplicationFiled: February 21, 2008Publication date: August 28, 2008Applicant: Idemitsu Kosan Co., Ltd.Inventors: Hirotoshi Ishii, Tatsuru Shirafuji, Shizuo Fujita, Kunihide Tachibana
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Patent number: 7393907Abstract: The present invention is a polar group-containing olefin copolymer having excellent adhesion properties to metals or polar resins and excellent compatibility therewith. A process for preparing the copolymer, a thermoplastic resin composition containing the copolymer, and uses thereof are also described. The polar group-containing olefin copolymer comprises a constituent unit derived from an ?-olefin of 2 to 20 carbon atoms, and a constituent unit derived from a straight-chain, branched or cyclic polar group-containing monomer having at the end a polar group such as a hydroxyl group or an epoxy group and/or a constituent unit derived from a macromonomer having at the end a polymer segment obtained by anionic polymerization, ring-opening polymerization or polycondensation.Type: GrantFiled: November 17, 2003Date of Patent: July 1, 2008Assignee: Mitsui Chemicals, Inc.Inventors: Junichi Imuta, Norio Kashiwa, Seiji Ota, Satoru Moriya, Tadahito Nobori, Kazumi Mizutani
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Patent number: 7385017Abstract: This invention relates to a silicone resin composition which exhibits high heat resistance, high transparency and high dimensional stability and thus can be suitably used for optical applications such as a lens, an optical disc, an optical fiber, a substrate for a plat panel display, a window material for an automobile, and the like.Type: GrantFiled: March 22, 2004Date of Patent: June 10, 2008Assignee: Nippon Steel Chemical Co., Ltd.Inventors: Takashi Saito, Masayoshi Isozaki, Hideki Andoh
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Patent number: 7381782Abstract: The present invention provides a polymerizable composition and a resin formed object capable of providing a crosslinked cycloolefin resin formed object and a crosslinked cycloolefin resin composite excellent in heat resistance, more specifically, a polymerizable composition comprising a cycloolefin mixture containing 0.1 to 50 % by mole of a cycloolefin having, as a substituent group, a monovalent group including an aliphatic carbon-carbon unsaturated bond, a metathesis polymerization catalyst, and a radical generating agent; and formed objects produced by using a polymerizable composition described above which preferably further comprises a chain transfer agent and making the cycloolefin mixture undergo at least ring-opening polymenzation.Type: GrantFiled: August 13, 2004Date of Patent: June 3, 2008Assignee: Zeon CorporationInventors: Tomoo Sugawara, Hirotoshi Tanimoto
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Patent number: 7344820Abstract: The present invention relates to a chemically amplified polymer having a pendent group with dicyclohexyl bonded thereto, a process for the preparation thereof, and a resist composition comprising it, and more particularly, to a novel (meth)acrylic or norbornene carboxylate compound with dicyclohexyl bonded thereto, a process for the preparation thereof, a chemically amplified polymer synthesized therewith, and a positive photoresist composition for ArF comprising said polymer, with high resolution and excellent etching resistance.Type: GrantFiled: November 19, 2002Date of Patent: March 18, 2008Assignee: DongJin Semichem Co., Ltd.Inventors: Eun-Kyung Son, Jae-Hyun Kang, Deog-Bae Kim, Jae-Hyun Kim
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Patent number: 7312292Abstract: A polymer comprising polycyclic repeating units having recurring ion conducting groups and optional crosslinkable groups is disclosed. The present invention provides the capability of tailoring polymers to impart unique properties to membranes fabricated from the polymers. Membranes comprising the polymers and methods for preparing the membranes and their use in ion conducting membranes, particularly in fuel cells, are also provided.Type: GrantFiled: June 4, 2004Date of Patent: December 25, 2007Assignee: Promerus LLCInventors: Ravi Ravikiran, Xiaoming Wu, Larry F. Rhodes, Robert A. Shick, Hiroko Nakano, Hirotaka Nonaka, Huabin Wang, Saikumar Jayaraman, Robert John Duff, John-Henry Lipian
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Patent number: 7297751Abstract: The invention relates to photochromic monomers based on benzothiophenes and a method for preparing them, and to photochromic polymers-polyazomethines that are reversibly photocontrollable due to the introduction of photochromic fragments from the class of dihetarylethenes into their structure. The invention provides photochromic photocontrollable polymers for the creation of new information technologies.Type: GrantFiled: October 27, 2005Date of Patent: November 20, 2007Assignees: Samsung Electronics Co., Ltd., Photochemistry Center of Russian Academy of SciencesInventors: Mikhail Vladimirovich Alfimov, Valery Alexandrovich Barachevsky, Valery Alexandrovich Vasnev, Alexander Alexandrovich Dunaev, Igor Viktorovich Zavarzin, Sergei Nikolaevich Ivanov, Muhammed Lastanbievich Keshtov, Mikhail Mikhailovich Krayushkin, Yury Aleksandrovich Pyankov, Stanislav Leonidovich Semenov, Yury Petrovich Strokach, Vladimir Nikolaevich Yarovenko
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Patent number: 7291686Abstract: Process for the preparation of a polymeric network, in which (i) one or more polymers are made available which can be crosslinked with one another intramolecularly or intermolecularly or intra- and intermolecularly by covalent or non-covalent bonding, (ii) the conformation of at least one of the polymers is adapted to at least one template compound with obtainment of at least one preferred conformation of the at least one polymer, (iii) at least one of the preferred conformations obtained according to (ii) is fixed by crosslinkage.Type: GrantFiled: November 26, 1999Date of Patent: November 6, 2007Assignee: Dr. Gottschall Instruction Gesellschaft fur Technische Chromatographie mbHInventor: Klaus Gottschall
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Patent number: 7276568Abstract: A copolymer of a strait chain ?-olefin and a vinyl compound (I) represented by the general formula CH2?CH—R, wherein R is a hydrocarbon group, the steric parameter Es of the substituent R is ?1.64 or less and the steric parameter B1 of the substituent R is 1.53 or more, an adhesive containing the same as an effective ingredient, and an laminate containing the adhesive.Type: GrantFiled: July 18, 2006Date of Patent: October 2, 2007Assignee: Sumitomo Chemical Company, LimitedInventors: Nobuo Oi, Akihiro Kondo, Toshiki Mori
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Patent number: 7273915Abstract: A crosslinkable resin composition is provided which can be a forming material having excellent adhesion to metals and excellent heat resistance. The crosslinkable resin composition comprises; a cycloolefin resin (A) obtained through metathesis polymerization of a cycloolefin monomer in the presence of a compound having two or more vinyl groups in the molecule, and a radical generating agent (B). A crosslinked resin molded product is obtained by crosslinking such a crosslinkable resin composition through heating.Type: GrantFiled: August 13, 2004Date of Patent: September 25, 2007Assignee: Zeon CorporationInventor: Tomoo Sugawara
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Patent number: 7262250Abstract: The present invention relates to the prevention of scorching before crosslinking of a thermoplastic and/or elastomeric composition with peroxides or azo compounds. This is achieved by using a family of specific nitroxides as additive.Type: GrantFiled: April 29, 2005Date of Patent: August 28, 2007Assignee: Arkema FranceInventors: Fabien Debaud, Alfredo Defrancisci, Olivier Guerret, Jacques Kervennal
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Patent number: 7232874Abstract: The interlayer insulating film of this invention is composed of a polymer in which a first monomer having four substituted acetylenyl groups and polymerizable in the three-dimensional direction and a second monomer having two substituted cyclopentanonyl groups and polymerizable in the two-dimensional direction are three-dimensionally polymerized.Type: GrantFiled: July 21, 2003Date of Patent: June 19, 2007Assignee: Matsushita Electric Industrial Co., Ltd.Inventor: Nobuo Aoi
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Patent number: 7230059Abstract: A process for producing an olefin-based copolymer, which comprises copolymerizing at least one olefin selected from the group consisting of ethylene and straight chain ?-olefins, and a vinyl compound (I) and a polyene (II) described below: Vinyl compound (I); a vinyl compound represented by the general formula CH2?CH—R, wherein the substituent R is a saturated hydrocarbon group and steric parameters Es and B1 of the substituent R are respectively ?1.64 or less and 1.53 or more; and Polyene (II); a compound having two or more of ethylene bonds and at least one combination of two ethylene bonds in which those are bonded to each other through at least three carbon atoms.Type: GrantFiled: December 18, 2003Date of Patent: June 12, 2007Assignee: Sumitomo Chemical Company, LimitedInventors: Nobuo Oi, Hitoshi Tsukui
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Patent number: 7214751Abstract: The invention relates to a method of preparing a composition of living polymers comprising a non-photoinitiated radical polymerization step using a composition consisting of: at least one ethylenically unsaturated monomer, preferably a methacrylic monomer, at least one disulphide compound having formula (II), i.e. Z1—C(?S)—S—S—C(?S)—Z2; and at least one thermally-activate free radical source which is different from the formula (II) compound.Type: GrantFiled: August 14, 2002Date of Patent: May 8, 2007Assignee: Rhodia ChimieInventor: Jean-Marie Catala
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High-softening-point copolymer, process for producing the same, and product of hydrogenation thereof
Patent number: 7196143Abstract: Provided are a high melting point copolymer prepared by heat-polymerizing cyclopentadiene and/or dicyclopentadiene and a vinyl-substituted aromatic compound, wherein a use amount of a solvent in heat polymerization is 0.1 time or more and less than 0.5 time based on the mass of the whole monomers, and the copolymer has a softening point falling in a range of 100 to 135° C., and a hydrogenated copolymer obtained by hydrogenating the above high melting point copolymer. The hydrogenated copolymer of the present invention is suitably used as an adhesion-providing resin having a high softening point for a hot melt adhesive.Type: GrantFiled: June 26, 2002Date of Patent: March 27, 2007Assignee: Idemitsu Kosan Co., Ltd.Inventor: Toyozo Fujioka -
Patent number: 7193003Abstract: A copolymer of a strait chain ?-olefin and a vinyl compound (I) represented by the general formula CH2?CH—R, wherein R is a hydrocarbon group, the steric parameter Es of the substituent R is ?1.64 or less and the steric parameter B1 of the substituent R is 1.53 or more, an adhesive containing the same as an effective ingredient, and an laminate containing the adhesive.Type: GrantFiled: December 21, 2001Date of Patent: March 20, 2007Assignee: Sumitomo Chemical Company, LimitedInventors: Nobuo Oi, Akihiro Kondo, Toshiki Mori
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Patent number: 7173096Abstract: Chemically crosslinked polycyclooctene having excellent shape recovery properties and a method for its synthesis via ring-opening methathesis polymerization of cyclooctene using the dihydroimidazolylidene-modified Grubbs catalyst are disclosed. The polycyclooctene products, following curing with dicumyl peroxide can be shaped, the shape memorized, a new shape imparted with the original shape being recoverable by suitable temperature adjustment. The dependence of shape memory characteristics on degree of crosslinking was established. In addition to polycyclooctene, blends thereof with other materials such as SBR, EVA, polyurethane rubbers, and inorganic fillers can be utilized to provide chemically crosslinked products having excellent and tailored shape memory properties.Type: GrantFiled: October 10, 2003Date of Patent: February 6, 2007Assignee: University of ConnecticutInventors: Patrick T. Mather, Changdeng Liu, Seung B. Chun, E. Bryan Coughlin
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Patent number: 7153918Abstract: Disclosed are random copolymers derived from ethylene and at least two different alkyl acrylate comonomers, with or without an acid cure site-containing comonomer. In particular, disclosed are copolymers derived from copolymerization of (a) from 10 to 50 weight % of ethylene; (b) from 5 to 55 weight % of a first alkyl acrylate; (b) from 15 to 80 weight % of a second alkyl acrylate; and (d) from 0 to 7 weight % of a monoalkyl ester of 1,4-butene-dioic acid. Such copolymers exhibit lower glass transition temperatures (Tg) relative to previous ethylene copolymers comprising a single alkyl acrylate comonomer and maintain the good heat and fluid resistance when employed to produce cured elastomeric compositions as well as the improved low temperature properties. This invention also provides compounded compositions comprising these copolymers, and cured compositions (i.e.Type: GrantFiled: July 15, 2004Date of Patent: December 26, 2006Assignee: E. I. du Pont de Nemours and CompanyInventors: Yun-Tai Wu, Mark Aaron Stewart, David John Mitchell, Edward McBride
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Patent number: 7148303Abstract: The present invention relates to an elastomeric polymer having repeating units derived from at least one isomonoolefin monomer, at least one multiolefin monomer, at least one diisoalkenylbenzene monomer, and optionally further copolymerizable monomers, wherein the polymer has a Mooney viscosity (ML 1+8@125° C. according to ASTM D1646) of less than 40 units and a Shore A hardness higher than 65 points @ 23° C. (according to ASTM D2240) as well as a curable composition containing the elastomeric polymer and a shaped article manufactured from the curable composition.Type: GrantFiled: February 16, 2005Date of Patent: December 12, 2006Assignee: Lanxess Inc.Inventors: Adam Gronowski, Akhtar Osman
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Patent number: 7125943Abstract: A fluorine-containing compound represented by the formula 1, where R1 is a methyl group or trifluoromethyl group, each of R2 and R3 is independently a hydrogen atom or a group containing (a) a hydrocarbon group having a straight-chain, branched or ring form and having a carbon atom number of 1–25 or (b) an aromatic hydrocarbon group, each of the hydrogen group and the aromatic hydrocarbon group independently optionally containing at least one of a fluorine atom, an oxygen atom and a carbonyl bond, l is an integer of from 0 to 2, each of m and n is independently an integer of 1–5 to satisfy an expression of m+n?6, and when at least one of R1, R2 and R3 is present in a plural number, the at least one of R1, R2 and R3 may be identical with or different from each other.Type: GrantFiled: August 6, 2003Date of Patent: October 24, 2006Assignee: Central Glass Company, LimitedInventors: Shinichi Sumida, Haruhiko Komoriya, Kazuhiko Maeda
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Patent number: 7105617Abstract: This invention relates to the synthesis of Mqn-containing monomeric compounds, comprising a polymerizable moiety, an Mqn-moiety, and an optional chemical spacer therebetween, wherein q, in each instance, comprises an 8-hydroxyquinoline residue, M is a metal such as Mg, Zn, Al, Ga, or In, and n is 2 or 3 as the valence of the metal requires. For example, the polymerization of Znq2- or Alq3-containing monomers, in the presence or absence of a co-monomer, provided a Znq2- or Alq3-containing polymer, which retained the optical properties of Znq2 or Alq3 in solution, respectively. The Mqn-containing polymers may be used in, among other things, the fabrication of light-emitting diodes (LEDs).Type: GrantFiled: February 6, 2004Date of Patent: September 12, 2006Assignee: Georgia Tech Research CorporationInventors: Marcus Weck, Amy Meyers
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Patent number: 7105269Abstract: 1. A copolymer having recurring units of the following formulas (1), (2), and (3), wherein R1, R4, R5, and R6 are a hydrogen atom or a methyl group, R2, R3, and R7 represent a monovalent organic group, k is 1 or 2, 1 is 0–4, n is 1–3, m is 0–3, R8 is a substituted methyl group, 1-substituted ethyl group, 1-branched alkyl group, triorganosilyl group, triorganogermyl group, alkoxycarbonyl group, acyl group, or cyclic acid-dissociable group, with two or more R8 groups being the same or different, q is 1–3, and p is 0–3, the copolymer having a GPC average molecular weight of 3,000–100,000. The composition is useful as a polymer component for a radiation-sensitive resin composition suitable as a chemically-amplified resist.Type: GrantFiled: December 18, 2002Date of Patent: September 12, 2006Assignee: JSR CorporationInventors: Tomoki Nagai, Daisuke Shimizu, Tsutomu Shimokawa, Fumihisa Miyajima, Masaaki Miyaji
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Patent number: 7087691Abstract: Embodiments in accordance with the present invention encompass photo-imageable compositions that include polymers of acrylate-type monomers and norbornene-type monomers. In some embodiments a catalyst system comprising a cationic or a neutral Pd(II) dimer component having the formula (Allyl)Pd(P(R21)3) or (L?)[(L)Pd(R)(X)]2, respectively is employed to effect polymerization. In other embodiments a free radical or living free radical catalyst is employed to effect polymerization. At least one of the acrylate-type monomers and norbornene-type monomers of the polymer embodiments of the present invention encompass an acid labile moiety. Some polymer embodiments of the present invention include more than one type of acrylate-type monomer and norbornene-type monomer. Embodiments of the present invention include forming a patterned layer on a substrate and some embodiments include transferring the patterned structure to a material layer first formed on the substrate.Type: GrantFiled: July 7, 2003Date of Patent: August 8, 2006Assignees: Promerus LLC, Penn State Research FoundationInventors: Larry F. Rhodes, Larry Seger, Ayusman Sen, April Hennis Marchetti
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Patent number: 7037974Abstract: A poly(?-olefin) copolymer obtained from the polymerization of at least one ?-olefin having from 2 to about 20 carbon atoms and at least one bulky olefin, the process comprising polymerizing the monomers in the presence of hydrogen and a catalytically effective amount of a catalyst comprising the product obtained by combining a metallocene procatalyst with a cocatalyst; lubricant compositions comprising such poly(?-olefin) copolymer; and a method for improving the viscosity index of a lubricant composition using such poly(?-olefin) copolymer.Type: GrantFiled: February 4, 2004Date of Patent: May 2, 2006Assignee: Uniroyal Chemical Company, Inc.Inventors: Anthony DiMaio, Thomas P. Matan
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Patent number: 7022789Abstract: The present invention relates to telechelic polymers having crosslinkable end groups of the formula and methods for preparing the same wherein n is an integer; is an alkadienyl group; Y is an alkyl group; and Z is crosslinkable end group. In general, the inventive synthesis involves reacting a functionalized chain transfer agent having crosslinkable ends with a cycloalkene in the presence of a ruthenium or osmium catalyst of the formula wherein: M is ruthenium or osmium; X and X1 are independently any anionic ligand; L and L1 are any neutral electron donor ligand; R and R1 are each hydrogen or a substituted or unsubstituted substituent wherein the substituent is selected from the group consisting of C1–C20 alkyl, C2–C20 alkenyl, C2–C20 alkynyl, aryl, C1–C20 carboxylate, C1–C20 alkoxy, C1–C20 alkenyloxy, C2–C20 alkynyloxy, aryloxy, C2–C20 alkoxycarbonyl, C1–C20 alkylthio, C1–C20 alkylsulfonyl and C1–C20 alkylsulfinyl.Type: GrantFiled: February 22, 2005Date of Patent: April 4, 2006Assignee: California Institute of TechnologyInventors: Bob R. Maughon, Takeharu Morita, Robert H. Grubbs
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Patent number: 6995228Abstract: A cyclic conjugated diene copolymer comprising a main chain comprised of (A) cyclic conjugated diene monomer units, (B) monomer units obtained from vinyl aromatic monomers each having a hydrogen atom at the ?-position thereof, and optionally (C) monomer units obtained from commoners which are other than the monomers used for obtaining the monomer units A and B and which are copolymerizable with at least one of the monomers used for obtaining the monomer units A and B, wherein all monomer units A and the monomer units B together form one or more polymer chains each having an A/B random sequence, wherein the one or more polymer chains each having an A/B random sequence contain at least one polymer chain having a number average molecular weight of from 20,000 to 500,000 and contain no polymer chain having a number average molecular weight of more than 500,000. A process for producing the above-mentioned cyclic conjugated diene copolymer by living anionic polymerization.Type: GrantFiled: August 16, 2002Date of Patent: February 7, 2006Assignee: Asahi Kasei Kabushiki KaishaInventors: Junichi Shishido, Kenichi Sanechika
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Patent number: 6987156Abstract: A film and method for fastening cargo during transportation wherein the film has a percentage strain change 100 hours after applying a load of 3.5 MPa at a temperature of 23° C. of not more than 2.0%, and a percentage strain change 100 hours after applying a load of 0.5 MPa at a temperature of 55° C. of not more than 2.5%. Moreover, it is preferable for the elastic modulus at a temperature of 23° C. to be not more than 60 MPa, and the elastic modulus at a temperature of 55° C. to be not more than 20 MPa. Such a film can be formed from substantially random interpolymer(s) each comprising 1 to 99 mol % of polymer units derived from an aromatic vinyl or vinylidene monomer and/or a hindered aliphatic or cycloaliphatic vinyl or vinylidene monomer, and 1 to 99 mol % of polymer units derived from at least one ?-olefin having 2 to 20 carbon atoms.Type: GrantFiled: June 24, 2003Date of Patent: January 17, 2006Assignee: Mitsui Chemicals, Inc.Inventors: Masashi Arimoto, Tomohiko Kimura, Saburou Takeyama
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Patent number: 6984704Abstract: To provide a fluoropolymer which has a high concentration of functional groups to provide adequate characteristics of the functional groups and which brings about no decrease of Tg. A fluoropolymer having monomer units formed by cyclopolymerization of a functional group-containing fluorinated diene represented by the formula (1): CFR1?CR2-Q-CR3?CHR4??(1) wherein each of R1 to R4 which are independent of one another, represents a hydrogen atom, a fluorine atom, an alkyl group having at most 8 carbon atoms, or an alicyclic hydrocarbon group, and at least one of them is an alicyclic hydrocarbon group, provided that hydrogen atoms in the alkyl group or the alicyclic hydrocarbon group may be substituted by a fluorine atom, an alkyl group or a fluoroalkyl group; and Q represents a bivalent organic group having a blocked acidic group capable of developing an acidic group by an acid or a group capable of being converted into such a blocked acidic group.Type: GrantFiled: February 17, 2005Date of Patent: January 10, 2006Assignee: Asahi Glass Company, LimitedInventors: Shun-ichi Kodama, Isamu Kaneko, Osamu Yokokoji, Shinji Okada, Yoko Takebe, Yasuhide Kawaguchi
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Patent number: 6965003Abstract: A block copolymer comprising a polymer block [A] and a polymer block [B]. The polymer block [A] contains mainly a repeating unit having an alicyclic structure, and the polymer block [B] contains the repeating unit having an alicyclic structure and a repeating unit derived from a diene based monomer and/or a vinyl based monomer. In any block, the carbon-carbon unsaturated bonds are hydrogenated. The block copolymer is molded into optical disks, optical waveguides, films, sheets, containers, and optical lenses.Type: GrantFiled: August 6, 2001Date of Patent: November 15, 2005Assignee: Zeon CorporationInventors: Atsushi Sone, Tsutomu Nagamune, Masakazu Hashimoto, Toru Murata
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Patent number: 6946523Abstract: In accordance with the present invention, there are provided novel heterobifunctional monomers and users for the same. Invention compounds have many of the properties required by the microelectronics industry, such as, for example, hydrophobicity, high Tg values, low dielectric constant, ionic purity, low coefficient of thermal expansion (CTE), and the like. These properties result in a thermoset that is particularly well suited to high performance applications where typical operating temperatures are often significantly higher than those at which prior art materials were suitable. Invention compounds are particularly ideal for use in the manufacture of electronic components, such as, for example, printed circuit boards, and the like.Type: GrantFiled: July 1, 2003Date of Patent: September 20, 2005Assignee: Henkel CorporationInventors: Stephen M. Dershem, Kevin J. Forrestal, Puwei Liu
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Patent number: 6930157Abstract: A catalyst composition for preparing olefin polymers. The catalyst composition includes a metallocene compound and an activating cocatalyst. In the metallocene compound, two cyclopentadienyl groups are bridged by X (carbon, silicon, germanium or tin) in a ring structure. The bite angle ? formed by the two cyclopentadienyl rings and X is equal to or greater than 100 degrees. The obtained olefin polymer has high cycloolefin conversion and a high glass transition temperature. In addition, the catalyst composition can still maintain relatively high activity at high temperature reaction conditions.Type: GrantFiled: June 12, 2003Date of Patent: August 16, 2005Assignee: Industrial Technology Research InstituteInventors: Jing-Cherng Tsai, Ming-Yuan Wu, Tung-Ying Hsieh, Yuh-Yuan Wei, Chao-Ying Yu
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Patent number: 6914112Abstract: An ethylene-based copolymer is useful as a modifier for resins, e.g., polypropylene, and can be used in an ethylene/?-olefin copolymer composition containing the same ethylene-based copolymer. The inventive copolymer is characterize by: (a-1) having temperature (Tm) at the maximum peak in the endothermic curve, measured by a differential scanning calorimeter (DSC), of 40 to 90° C., (a-2) containing the component soluble in decane at normal temperature at 1 to 70% b weight, and (a-3) containing the component soluble in decane at normal temperature which comprises (i) a recurring unit derived from ethylene and (ii) a recurring unit derived from an ?-olefin of 4 or more carbon atoms, and in which a content of (i) the recurring unit derived from ethylene is 50 to 75% by mole.Type: GrantFiled: May 15, 2001Date of Patent: July 5, 2005Assignee: Mitsui Chemical, Inc.Inventors: Ryoji Mori, Kouichi Kizu, Keiji Okada, Kazuyuki Takimoto
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Patent number: 6914109Abstract: The invention relates to a process for the preparation of 15-pentadecanolide by hydrogenating 15-pentadecenolide and to its use.Type: GrantFiled: March 18, 2002Date of Patent: July 5, 2005Assignee: Symrise GmbH & Co. KGInventors: Walter Kuhn, Oskar Koch, Hans-Ulrich Funk, Gerhard Senft
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Patent number: 6911507Abstract: A cyclic olefin having a specific polar group is polymerized by addition polymerization in a hydrocarbon solvent, using a polymerization catalyst component containing (i) a specific transition metal compound, (ii) a Lewis acid compound and (iii) an alkyl aluminoxane, or the cyclic olefin is polymerized by addition polymerization in the hydrocarbon solvent, using the polymerization catalyst component, by further adding at least one aromatic vinyl compound and at least one cyclic nonconjugated polyene compound, or either one of them as a molecular weight modifier, thereby obtaining a cyclic olefinic addition polymer.Type: GrantFiled: January 23, 2001Date of Patent: June 28, 2005Assignee: JSR CorporationInventors: Kenzo Ohkita, Noboru Oshima, Takashi Imamura, Takashi Tsubouchi
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Patent number: 6903171Abstract: Methods for the addition polymerization of cycloolefins using a cationic Group 10 metal complex and a weakly coordinating anion of the formula: [(R?)zM(L?)x(L?)y]b[WCA]d wherein [(R?)zM(L?)x(L?)y] is a cation complex where M represents a Group 10 transition metal; R? represents an anionic hydrocarbyl containing ligand; L? represents a Group 15 neutral electron donor ligand; L? represents a labile neutral electron donor ligand; x is 1 or 2; and y is 0, 1, 2, or 3; and z is 0 or 1, wherein the sum of x, y, and z is 4; and [WCA] represents a weakly coordinating counteranion complex; and b and d are numbers representing the number of times the cation complex and weakly coordinating counteranion complex are taken to balance the electronic charge on the overall catalyst complex.Type: GrantFiled: October 15, 2002Date of Patent: June 7, 2005Assignee: Promerus, LLCInventors: Larry Funderburk Rhodes, Andrew Bell, Ramakrishna Ravikiran, John C. Fondran, Saikumar Jayaraman, Brian Leslie Goodall, Richard A. Mimna, John-Henry Lipian
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Patent number: 6897272Abstract: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc.Type: GrantFiled: August 23, 2000Date of Patent: May 24, 2005Assignee: E.I. Du Pont de Nemours and CompanyInventors: Maurice S. Brookhart, Lynda Kaye Johnson, Samuel David Arthur, Stephan James McLain
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Patent number: 6891007Abstract: This invention relates to a process for polymerizing polar substituted norbornenes and/or cycloalkenes, optionally, in the presence of another unsaturated compound. The method is characterized in that the polymerization is carried out in the presence of one or more tungsten carbine complexes.Type: GrantFiled: March 19, 2001Date of Patent: May 10, 2005Assignee: Bayer AktiengesellschaftInventors: Karl-Heinz Alexsander Ostoja Starzewski, Karin Weiss, Martin Olaf Thüring
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Patent number: 6878501Abstract: Polymers comprising recurring units of cycloolefin having fluorinated alkyl introduced therein are novel and have transparency and alkali solubility. Using the polymers, resist compositions featuring low absorption of F2 excimer laser light are obtained.Type: GrantFiled: April 26, 2001Date of Patent: April 12, 2005Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Jun Hatakeyama, Jun Watanabe, Yuji Harada
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Patent number: 6867274Abstract: The present invention relates to telechelic polymers having crosslinkable end groups of the formula and methods for preparing the same wherein n is an integer; is an alkadienyl group; Y is an alkyl group; and Z is crosslinkable end group. In general, the inventive synthesis involves reacting a functionalized chain transfer agent having crosslinkable ends with a cycloalkene in the presence of a ruthenium or osmium catalyst of the formula wherein: M is ruthenium or osmium; X and X1 are independently any anionic ligand; L and L1 are any neutral electron donor ligand; R and R1 are each hydrogen or a substituted or unsubstituted substituent wherein the substituent is selected from the group consisting of C1-C20 alkyl, C2-C20 alkenyl, C1-C20 alkynyl, aryl, C1-C20 carboxylate, C1-C20 alkoxy, C2-C20 alkenyloxy, C2-C20 alkynyloxy, aryloxy, C2-C20 alkoxycarbonyl, C1-C20 alkylthio, C1-C20 alkylsulfonyl and C1-C20 alkylsulfinyl.Type: GrantFiled: May 21, 2002Date of Patent: March 15, 2005Assignee: California Institute of TechnologyInventors: Bob R. Maughon, Takeharu Morita, Robert H. Grubbs
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Patent number: 6864325Abstract: The invention relates to metathesis polymers wherein an aromatic group that has UV-light absorbing properties is attached with a bridge group to the polymer. Also disclosed is a polymerizable composition comprising a catalytically effective amount of a penta- or hexavalent ruthenium or osmium carbene catalyst, the process for preparing the metathesis polymer by applying the reaction conditions of Ring Opening Metathesis Polymerization (=ROMP) to the polymerizable composition; and various technical applications of the metathesis polymers.Type: GrantFiled: February 13, 2001Date of Patent: March 8, 2005Assignee: Ciba Specialty Chemicals CorporationInventors: Alessandro Zedda, Dario Lazzari, Massimiliano Sala, Michela Bonora, Manuele Vitali, Paul Adriaan Van Der Schaaf
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Patent number: 6858676Abstract: The present invention relates to an olefin derived copolymer and a thermoplastic resin composition using the olefin derived copolymer satisfying the following (1) and (2): (1) tensile strength at break measured based on JIS K6251 is 2.0 or less MPa; and (2) tensile elongation at break EB (%) of a resin composition obtained satisfies the following relational expression (expression 1) and (expression 2), when blended with a polypropylene derived resin that has 20 degree C. xylene soluble component of not more than 20 wt %. R[3/5]?R[2/6]?0.15??(expression 1) S[2/6]??800??(expression 2) (R[3/5] and R[2/6] are obtained by the following methods: a curve is obtained by plotting tensile elongation at break EB (%) (based on JIS K6251) of resin composition taken as vertical axis, and weight part rate Pa of a content of an olefin derived copolymer contained in a resin composition taken as horizontal axis; a multiple regression curve in section regions of Pa=0.30-0.50 and Pa=0.20-0.Type: GrantFiled: July 21, 1999Date of Patent: February 22, 2005Assignee: Sumitomo Chemical Company, Ltd.Inventors: Hirofumi Johoji, Hidetake Hozumi, Atsuko Ogawa, Tadaaki Nishiyama