Contains Atoms Other Than Carbon And Hydrogen Patents (Class 526/309)
  • Patent number: 7649065
    Abstract: To provide a novel fluoroadamantane derivative, a novel polymerizable fluoroadamantane derivative and a novel fluoropolymer, and processes for production thereof. To provide the following compound (3), the following compound (4), a polymer obtained by polymerizing the compound (4) and processes for production thereof: provided that Q represents —CHF— or —CF2— (provided that six Qs may be the same or different), Z represents —H, —F or —CH2OH (provided that three Zs may be the same or different), W represents —H or a C1-10 hydrocarbon group, R represents —H, —F, —CH3 or —CF3, and J represents —H, —F, —CHWOH or —CHWOCOCR?CH2 (provided that three Js may be the same or different).
    Type: Grant
    Filed: October 25, 2006
    Date of Patent: January 19, 2010
    Assignee: Asahi Glass Company, Limited
    Inventors: Shu-zhong Wang, Koichi Murata, Kazuya Oharu, Yoshitomi Morizawa, Osamu Yokokoji, Naoko Shirota
  • Publication number: 20090297979
    Abstract: The present invention provides; a polymer suitable as a base resin for a positive resist composition, in particular a chemically amplified positive resist composition, having a higher resolution, a larger exposure allowance, a smaller sparse-dense size difference, a better process applicability, a better pattern configuration after exposure, and in addition, a further excellent etching resistance, than a conventional positive resist; a positive resist composition using the same; a patterning process; and a novel polymerizable compound to obtain a polymer like this. The present invention was accomplished by a polymer whose hydrogen atom of at least a carboxyl group is substituted by an acid labile group represented by the following general formula (2), a positive resist composition using the same, a patterning process, and a novel polymerizable compound to obtain a polymer like this.
    Type: Application
    Filed: May 18, 2009
    Publication date: December 3, 2009
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Jun Hatakeyama, Takeru Watanabe, Seiichiro Tachibana
  • Patent number: 7604918
    Abstract: A photosensitive polymer for a photoresist and a photoresist composition having the same are provided. The photosensitive polymer for a photoresist includes the repeating unit represented by the formula below: wherein R1 is a C1-C20 hydrocarbon group or a C1-C20 hetero hydrocarbon group including at least one hetero atom selected from the group consisting of nitrogen, fluorine and sulfur.
    Type: Grant
    Filed: January 22, 2007
    Date of Patent: October 20, 2009
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Sang-jun Choi, Han-ku Cho
  • Patent number: 7595354
    Abstract: A composition comprising (A) at least one fluorinated vinylcyclopropane according to Formula (I) wherein R1 is H or —CO—O—(CH2CH2)p—R7; R2 is H or forms together with R6 a —CH2—C(R9)(R10)—CH2— residue; R3 is H; R4 is H or forms together with R5—CH2—C(R9)(R10)—CH2— residue; R5 is H, —CO—O—R8, —CO—O—(CH2CH2)p—R7 or forms together with R4—CH2—C(R9)(R10)—CH2— residue; R6 is H, —CO—O—R8, —CO—O—(CH2CH2)p—R7 or forms together with R2 a —CH2—C(R9)(R10)—CH2— residue; R7 is perfluorinated C2-C20 aliphatic or alicyclic group; R8 is H, phenyl, benzyl, or a linear or branched C1-C12 aliphatic or alicyclic group; R9 is a H, benzoyl, acetyl or a C1-C5-alkyl group; R10H or a —CO—O—R8; p is 1, 2, 3, or 4, provided that the compound of Formula (I) comprises at least one —CO—O—(CH2CH2)p—R7 residue; (B) at least one non-fluorinated vinylcyclopropane derivative; (C) a bisphenol-A-ether di(meth)acrylate according to Formula (II) wherein R18 is H or CH3, R19 is CH3 or CF3, Y is a C2-C5-alkylen residue which can be substitu
    Type: Grant
    Filed: January 24, 2006
    Date of Patent: September 29, 2009
    Assignee: Ivoclar Vivadent AG
    Inventors: Norbert Moszner, Urs Karl Fischer, Volker M Rheinberger, Giancarlo Galli, Marina Ragnoli, Emo Chiellini
  • Patent number: 7585901
    Abstract: Bicyclic cyclopropane derivatives of the general Formula (I) in which n+m is 0 to 8; r is 1 to 4; R1 is absent or is a C1-C20 alkylene radical which can be interrupted by O or S, a cycloaliphatic C4-C12 radical, a bicyclic C4-C12 radical, a C6-C14 arylene or C7-C20 alkylenearylene radical; R2 is for r=1 a C1-C20 alkyl radical which can be interrupted by O or S, a cycloaliphatic C4-C12 radical, a bicyclic C4-C12 radical, a C6-C14 aryl or a C7-C20 alkylaryl radical; is for r>1 an r-times substituted aliphatic C1 to C20 radical which can be interrupted by O or S, a cycloaliphatic C4-C12 radical, an aromatic C6-C14 radical or aliphatic-aromatic C7-C20 radical; X is absent or is —CO—O—, —CO—NH— or —O—CO—NH—, and Y is CH2, O or S which is suitable in particular for the preparation of dental materials.
    Type: Grant
    Filed: May 23, 2007
    Date of Patent: September 8, 2009
    Assignee: Ivoclar Vivadent AG
    Inventors: Norbert Moszner, Armin de Meijere, Frank Zeuner, Urs Karl Fischer
  • Patent number: 7582684
    Abstract: Ion exchange resins are described that are hydrophilic, crosslinked (meth)acrylic copolymers. The ion exchange resins are macroporous, have a surface area of at least 50 m2/g, and an average particle size of at least 20 micrometers. Additionally, chromatographic columns containing the ion exchange resins, composite materials containing the ion exchange resin, filtration elements containing the ion exchange resin, methods of preparing the ion exchange resins, and methods of separating or purifying negatively or positively charged materials with the ion exchange resins are described.
    Type: Grant
    Filed: February 17, 2005
    Date of Patent: September 1, 2009
    Assignee: 3M Innovative Properties Company
    Inventors: Jerald K. Rasmussen, James I. Hembre
  • Publication number: 20090209715
    Abstract: A process for producing a polymer, characterized by comprising the following step (A) and step (B). (A) A step in which a polymer having repeating units represented by the general formula (1): —Ar1— (wherein Ar1 represents an arylene, divalent heterocyclic, or divalent aromatic amine group having at least one C—H bond on the aromatic ring) is used as a raw material and one or more of the C—H bond(s) on the aromatic ring are converted to thereby produce a polymer having repeating units which have one or more characteristic groups X and are represented by the general formula (2): (wherein X represents a characteristic group; Ar2 represents an arylene group, heterocyclic group, or aromatic amine group which each has a valence of n+2 and in each of which n of the C—H bonds on the aromatic ring of Ar1 have been converted into a C—X bond; and n is an integer of 1-4) (hereinafter, this polymer is referred to as polymer having the characteristic group (X)).
    Type: Application
    Filed: June 9, 2006
    Publication date: August 20, 2009
    Applicant: Sumitomo Chemical Company, Limited
    Inventors: Kazuei Ohuchi, Daisuke Fukushima, Hideyuki Higashimura
  • Patent number: 7553906
    Abstract: An organic polyisocyanate with at least one unsaturated functional group is capable of copolymerizing when exposed to actinic radiation. The polyisocyanate comprises structural units with the formula (1): wherein: X is an electron-attracting group; R1, and R2 are hydrogen atoms, a saturated or unsaturated aliphatic or cycloaliphatic radical, or an aromatic or araliphatic radical; and n is an integer from 0 to 5. A process for producing this polyisocyanate is also disclosed.
    Type: Grant
    Filed: December 17, 2003
    Date of Patent: June 30, 2009
    Assignee: Bayer MaterialScience AG
    Inventors: Jan Weikard, Christoph Gürtler, Wolfgang Fischer, Diethelm Rappen, Michael Schelhaas
  • Patent number: 7547753
    Abstract: The invention relates to copolymers made from monoethylenically unsaturated monomers with acid groups and a further hydrophobic monomer component for the prevention of inorganic and organic deposits in water supply systems. The invention further relates to a method for production of the above.
    Type: Grant
    Filed: June 14, 2003
    Date of Patent: June 16, 2009
    Assignee: Ashland Licensing and Intellectual Property LLC
    Inventors: Joerg Issberner, Rainer Poeschmann, Christian Flocken
  • Publication number: 20090110995
    Abstract: The present invention provides a novel polymer having oxocarbon groups which is particularly useful in battery and fuel cell applications.
    Type: Application
    Filed: October 29, 2007
    Publication date: April 30, 2009
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Lanny S. LIEBESKIND, Ken Yoshimura
  • Publication number: 20090110994
    Abstract: The present invention provides a novel polymer composed of polyarylene in the main chain and having oxocarbon groups which is particularly useful in battery and fuel cell applications.
    Type: Application
    Filed: October 29, 2007
    Publication date: April 30, 2009
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Ken Yoshimura, Lanny S. Liebeskind
  • Patent number: 7521172
    Abstract: Disclosed is a topcoat composition comprising a polymer having a dissolution rate of at least 1500 ?/second in an aqueous alkaline developer, and at least one solvent. The topcoat composition can be used to coat a photoresist layer on a material layer on a substrate, for example, a semiconductor chip. Also disclosed is a method of forming a pattern in the material layer of the coated substrate.
    Type: Grant
    Filed: April 28, 2006
    Date of Patent: April 21, 2009
    Assignee: International Business Machines Corporation
    Inventors: Robert Allen David, Phillip Joe Brock, Sean David Burns, Dario Leonardo Goldfarb, David Medeiros, Dirk Pfeiffer, Matt Pinnow, Ratnam Sooriyakumaran, Linda Karin Sundberg
  • Patent number: 7514515
    Abstract: A process for preparing a pressure-sensitive polyacrylate adhesive, characterized in that a polyacrylate composition including the atomic sequence C—S—C is admixed with at least one metal compound of type (L)yM where M=metal atom or metal ion L=counterion or ligand y=0 to 6.
    Type: Grant
    Filed: July 16, 2003
    Date of Patent: April 7, 2009
    Assignee: tesa AG
    Inventors: Marc Husemann, Stephan Zollner
  • Patent number: 7501222
    Abstract: A polymer including a monomer represented by the following Formula and a photoresist composition including the same are disclosed. The polymer and photoresist composition can improve the resolution and the process margin due to the low activation energy of the deprotection reaction of the alcohol ester group including saturated cyclic hydrocarbyl group, and also can produce fine photoresist patterns because they have a stable PEB(Post Exposure Baking) temperature sensitivity, and further, can improve the focus depth margin and the line edge roughness of the resist layer. In the above Formula, R* is a hydrogen or methyl group, R1 is saturated hydrocarbyl group of 1 to 5 carbon atoms, R is mono-cyclic or multi-cyclic homo or hetero saturated hydrocarbyl group of 3 to 50 carbon atoms, and n is an integer of at least 2.
    Type: Grant
    Filed: June 21, 2006
    Date of Patent: March 10, 2009
    Assignee: Dongjin Semichem Co., Ltd.
    Inventors: Jung-Youl Lee, Jae-Woo Lee, Jae-Hyun Kim
  • Publication number: 20090062475
    Abstract: In a process for producing a functionalized polyalkenamer, at least one monomer comprising a monocyclic olefin having at least one pendant alkyl group bonded thereto, wherein the pendant alkyl group has at least two carbon atoms and is substituted with a polar moiety spaced by at least one carbon atom from the monocyclic olefin, is contacted with a polymerization catalyst under conditions effective to effect ring opening polymerization of the monocyclic olefin and produce the functionalized polyalkenamer.
    Type: Application
    Filed: September 2, 2008
    Publication date: March 5, 2009
    Inventors: Lisa Saunders Baugh, Enock Berluche, Karla Schall Colle
  • Publication number: 20090048409
    Abstract: It is intended to in a liquid-immersion exposure process, simultaneously prevent any degeneration, represented by bridge, etc., of resist film during the liquid-immersion exposure using water and other various liquid-immersion exposure liquids and any degeneration of liquid-immersion exposure liquids per se, and to without increasing of the number of treatment steps, realize enhancing of the post-exposure storage stability of resist film, and to enable forming of a resist pattern of high resolution through liquid-immersion exposure.
    Type: Application
    Filed: December 22, 2005
    Publication date: February 19, 2009
    Applicant: TOKYO OHKA KOGYO CO., LTD
    Inventors: Kotaro Endo, Keita Ishiduka, Tomoyuki Hirano, Ichiro Taninaka, Takahiko Tsukuda
  • Patent number: 7452952
    Abstract: A method of applying coating composition is described in which the coating composition comprises a multi-stage emulsion polymer that is both radiation curable, removable and includes chemically reactive functional groups in the coating that react with one or more conventional chemical stripping agents, effecting the removal of the coating from a substrate. The UV curable and removable composition is included within one or more layers applied on top of a substrate or on top of a base coat that itself is disposed on top of a substrate.
    Type: Grant
    Filed: December 4, 2006
    Date of Patent: November 18, 2008
    Assignee: Rohm and Haas Company
    Inventors: Alan Wayne Kohr, Theodore Tysak
  • Publication number: 20080257493
    Abstract: The invention is based on the discovery that certain well-defined compounds derived from pentacyclopentadecane dimethanol are useful components in adhesive formulations. In particular, the invention compounds described herein provide high Tg values and low shrinkage. Compounds of the invention are useful as adhesives for use in the semiconductor packaging industry.
    Type: Application
    Filed: April 9, 2008
    Publication date: October 23, 2008
    Inventor: Stephen M. Dershem
  • Patent number: 7429627
    Abstract: A substituted (meth)acrylic copolymer leveling agent is useful in producing a ferroelectric polymer film that is especially suitable for use in a data processing device. Also disclosed is a a casting composition which includes the leveling agent, a film stack, and a data processing device comprising a ferroelectric film produced using the leveling agent.
    Type: Grant
    Filed: March 8, 2004
    Date of Patent: September 30, 2008
    Assignee: Rohm and Haas Electronic Materials LLC
    Inventors: Charles R. Szmanda, Kathleen B. Spear-Alfonso, Lujia Bu
  • Patent number: 7402631
    Abstract: An acrylic rubber, comprising an alkoxyalkyl(meth)acrylate monomer unit in an amount of 70.1 to 99.8 wt %, a methacrylonitrile monomer unit in an amount of 0.1 to 9.9 wt % and a butenedionic acid monoester monomer unit in an amount of 0.1 to 20 wt %; and a cross-linkable acrylic rubber composition made by containing the acrylic rubber and a cross-linking agent. According to the invention, it is possible to provide a cross-linkable acrylic rubber composition having excellent scorch stability and an acrylic rubber cross-linked product, which can be obtained by cross-linking the cross-linkable acrylic rubber composition, having excellent heat resistance, cold resistance and fuel oil resistance.
    Type: Grant
    Filed: February 24, 2005
    Date of Patent: July 22, 2008
    Assignee: Zeon Corporation
    Inventors: Isao Kubota, Nobukazu Kaihatsu
  • Patent number: 7396891
    Abstract: Aqueous coating compositions containing (1) a first polymer containing reactive functional groups with a selected level of carboxylic acid functionality and (2) a polyfunctional crosslinker agent containing functional groups that are reactive with appropriate functional groups of the first polymer, are disclosed. The two-component polymer compositions provide a combination of durability and ready removability of the final coating after curing. Two-component polymer compositions based on the first polymer containing hydroxyl functionality in addition to carboxylic acid functionality and use of a polyisocyanate as the polyfunctional crosslinker agent are especially useful as floor polish compositions.
    Type: Grant
    Filed: February 3, 2005
    Date of Patent: July 8, 2008
    Assignee: Rohm and Haas Company
    Inventors: Richard Thomas Gray, Alan Wayne Kohr, Dennis Michael Sharpe, Theodore Tysak
  • Publication number: 20080142454
    Abstract: Azidoaryl-substituted cyclooctene monomers and synthesized and used in the preparation of various copolymers. Among these copolymers are those prepared from ring-opening metathesis polymerization of cyclooctene, polyethylene glycol-substituted cyclooctene, and azidoaryl-substituted cyclooctene. These copolymers are useful in the formation of crosslinked films that reduce fouling of water purification membranes.
    Type: Application
    Filed: September 7, 2007
    Publication date: June 19, 2008
    Inventors: Todd Shannon Emrick, Kurt Breitenkamp, Ravindra Revanur, Benny D. Freeman, Bryan McCloskey
  • Patent number: 7385017
    Abstract: This invention relates to a silicone resin composition which exhibits high heat resistance, high transparency and high dimensional stability and thus can be suitably used for optical applications such as a lens, an optical disc, an optical fiber, a substrate for a plat panel display, a window material for an automobile, and the like.
    Type: Grant
    Filed: March 22, 2004
    Date of Patent: June 10, 2008
    Assignee: Nippon Steel Chemical Co., Ltd.
    Inventors: Takashi Saito, Masayoshi Isozaki, Hideki Andoh
  • Patent number: 7371505
    Abstract: A positive working photosensitive composition which is useful in the manufacturing step of a semiconductor such as IC, the manufacture of a circuit board such as liquid crystals and thermal heads, and other fabrication steps and has an excellent resolution and line edge roughness, and a method for forming a pattern using the same, are provided, which are a photosensitive composition containing (A) a resin having a repeating unit having a specific group, whose solubility in an alkaline developer increases by the action of an acid, and a method for forming a pattern using the same.
    Type: Grant
    Filed: June 28, 2005
    Date of Patent: May 13, 2008
    Assignee: FUJIFILM Corporation
    Inventor: Kunihiko Kodama
  • Patent number: 7307129
    Abstract: A method of preparing a latex that includes pigments copolymerized with a crystalline polymer includes: dispersing a pigment and a dispersing agent in water having an ultra-high purity to obtain a pigment dispersion; dissolving a crystalline monomer in a basic monomer mixture to obtain an organic phase; dissolving while heating the dispersing agent in water having an ultra-high purity, and then mixing the solution with the pigment dispersion to obtain an aqueous phase; mixing and agitating the organic phase and the aqueous phase to obtain a homogenized solution; agitating and heating the homogenized solution; adding a polymerization initiator to the homogenized solution to be reacted; and cooling the reaction solution to room temperature.
    Type: Grant
    Filed: January 19, 2005
    Date of Patent: December 11, 2007
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Jun-young Lee, Sang-woo Kim, Kyung-yol Yon
  • Patent number: 7285598
    Abstract: A polymer consisting mainly of structural units represented by the general formula (1), wherein the total molar amount of terminal aldehyde groups and acetal groups is 0.6 mol % or smaller based on the total molar amount of the structural units represented by the general formula (1). —[—(—CHR1—)n—CX1R2—CX2R3-]— (1) (In the formula, n is an integer of 2 to 10; X1 and X2 each represents —H, —OH, or a functional group capable of being converted into —OH, provided that at least one of X1 and X2 is hydroxy or a functional group capable of being converted into hydroxy; and R1, R2, and R3 each represents —H or C1-5 alkyl, aryl, aralkyl, or heteroaryl and the two or more R1's may be different).
    Type: Grant
    Filed: February 23, 2004
    Date of Patent: October 23, 2007
    Assignee: Kuraray Co., Ltd.
    Inventors: Kikuo Arimoto, Nobuhiro Moriguchi, Hiroyuki Ohgi, Yukiatsu Komiya
  • Patent number: 7279539
    Abstract: A polymer, which contains a structural unit having a carboxyl group represented by the following formula (1) at a side chain of the structural unit, wherein node position is formed, when the polymer is dissolved in an alkali aqueous solution having a pH of 10 or more and kept at 25° C. for 60 days: wherein R1 represents a hydrogen atom or a methyl group; R2 represents an (n+1)-valent organic linking group containing an ester group represented by —O(C?O)—; A represents an oxygen atom or NR3—; R3 represents a hydrogen atom, or an monovalent hydrocarbon group having from 1 to 10 carbon atoms; and n indicates an integer of from 1 to 5.
    Type: Grant
    Filed: June 29, 2006
    Date of Patent: October 9, 2007
    Assignee: Fujifilm Corporation
    Inventors: Atsushi Sugasaki, Kazuto Kunita
  • Patent number: 7232874
    Abstract: The interlayer insulating film of this invention is composed of a polymer in which a first monomer having four substituted acetylenyl groups and polymerizable in the three-dimensional direction and a second monomer having two substituted cyclopentanonyl groups and polymerizable in the two-dimensional direction are three-dimensionally polymerized.
    Type: Grant
    Filed: July 21, 2003
    Date of Patent: June 19, 2007
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventor: Nobuo Aoi
  • Patent number: 7230060
    Abstract: A coating composition is described comprising a multi-stage emulsion polymer that is both radiation curable, removable and includes chemically reactive functional groups in the coating that react with one or more conventional chemical stripping agents, effecting the removal of the coating from a substrate. The UV curable and removable composition is included within one or more layers applied on top of a substrate or on top of a base coat that itself is disposed on top of a substrate.
    Type: Grant
    Filed: December 4, 2003
    Date of Patent: June 12, 2007
    Assignee: Rohm and Haas Company
    Inventors: Alan Wayne Kohr, Theodore Tysak
  • Patent number: 7115690
    Abstract: There is provided a fluorine-containing copolymer having an aliphatic monocyclic structure in the polymer trunk chain which has a number average molecular weight of from 500 to 1,000,000 and is represented by the formula (Ma): -(M1)-(M2a)-(N)—??(Ma) in which the structural unit M1 is a structural unit derived from an ethylenic monomer having 2 or 3 carbon atoms and at least one fluorine atom, the structural unit M2a is at least one structural unit which introduces an aliphatic monocyclic structure in the polymer trunk chain and is represented by the formula (a): wherein R1 is at least one hydrocarbon group selected from the group consisting of a divalent hydrocarbon group having 1 to 8 carbon atoms and constituting a ring which may be further substituted with a hydrocarbon group or a fluorine-containing alkyl group and a divalent hydrocarbon group having ether bond which has the sum of carbon atoms and oxygen atoms of 2 to 8, constitutes a ring and may be further substituted with a hydrocarbon group o
    Type: Grant
    Filed: April 2, 2004
    Date of Patent: October 3, 2006
    Assignee: Daikin Industries, Ltd.
    Inventors: Takayuki Araki, Takuji Ishikawa, Meiten Koh
  • Patent number: 7109280
    Abstract: The present invention relates to block copolymers for applications in medicine and biotechnology and synthesis thereof. Block copolymers comprise polyvalent N-Acetyl Glucosamine (NAG) which bind more efficiently to lysozyme than NAG itself. The effective inhibition is possible even at very low ligand concentrations than reported earlier. The block copolymers could be used for prevention and treatment of bacterial and viral infections. Moreover these polymers can be stimuli sensitive and be used for the recovery of biomolecules. The methodology of preparation of block copolymers reported here can be extended to other polymers and ligands such as sialic acid and used for preventing influenza and/or rotavirus infections. It also provides a method for preparation of block copolymers wherein polymers comprising sequences of specific ligands are essential.
    Type: Grant
    Filed: October 29, 2003
    Date of Patent: September 19, 2006
    Assignee: Council of Scientific and Industrial Research
    Inventors: Mohan Gopalkrishna Kulkarni, Jayant Jagannath Khandare
  • Patent number: 7105602
    Abstract: The present invention provides a processing aid for thermoplastic resin having a weight average molecular weight of 10,000 to 300,000, which is obtained by polymerizing an alkyl (meth)acrylate, or an alkyl (meth)acrylate and another vinyl monomer copolymerizable therewith, in the presence of a mercaptan having an alkyl ester group with C4-20 alkyl group as a chain transfer agent, and/or an organic peroxide having a tertiary-butyl peroxy group as a polymerization initiator.
    Type: Grant
    Filed: April 14, 2000
    Date of Patent: September 12, 2006
    Assignee: Kaneka Corporation
    Inventors: Takenobu Sunagawa, Riichi Nishimura, Toshiyuki Mori, Akira Takaki
  • Patent number: 7098253
    Abstract: Ion exchange resins are described that are hydrophilic, crosslinked (meth)acrylic copolymers. The ion exchange resins are macroporous, have a surface area of at least 50 m2/g, and an average particle size of at least 20 micrometers. Additionally, chromatographic columns containing the ion exchange resins, composite materials containing the ion exchange resin, filtration elements containing the ion exchange resin, methods of preparing the ion exchange resins, and methods of separating or purifying negatively or positively charged materials with the ion exchange resins are described.
    Type: Grant
    Filed: May 20, 2004
    Date of Patent: August 29, 2006
    Assignee: 3M Innovative Properties Company
    Inventors: Jerald K. Rasmussen, James I. Hembre
  • Patent number: 7087691
    Abstract: Embodiments in accordance with the present invention encompass photo-imageable compositions that include polymers of acrylate-type monomers and norbornene-type monomers. In some embodiments a catalyst system comprising a cationic or a neutral Pd(II) dimer component having the formula (Allyl)Pd(P(R21)3) or (L?)[(L)Pd(R)(X)]2, respectively is employed to effect polymerization. In other embodiments a free radical or living free radical catalyst is employed to effect polymerization. At least one of the acrylate-type monomers and norbornene-type monomers of the polymer embodiments of the present invention encompass an acid labile moiety. Some polymer embodiments of the present invention include more than one type of acrylate-type monomer and norbornene-type monomer. Embodiments of the present invention include forming a patterned layer on a substrate and some embodiments include transferring the patterned structure to a material layer first formed on the substrate.
    Type: Grant
    Filed: July 7, 2003
    Date of Patent: August 8, 2006
    Assignees: Promerus LLC, Penn State Research Foundation
    Inventors: Larry F. Rhodes, Larry Seger, Ayusman Sen, April Hennis Marchetti
  • Patent number: 7034171
    Abstract: This invention relates to the reversible protection of hydroxy-silane functional groups by acid cleavable protecting groups. The development of reversible protecting groups greatly enhances the current utility of silanes while introducing further novel applications. For instance, reversibly protected silanes are of particular value in applications where room temperature cure and/or adhesion is of value, such as coatings, high resolution imaging, caulks, adhesives, sealents, gaskets, and silicones. Reversibly protected silanes can also be beneficially used in reticulating agents, and in sizing agents, tires, and release coatings. The incorporation of reversibly protected silanes into coating resins is of particular value. The reversibly protected silane can be incorporated into the coating resin by polymerizing a monomer containing the reversibly protected silane into the resin or by post-addition into the coating formulation.
    Type: Grant
    Filed: November 3, 2003
    Date of Patent: April 25, 2006
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Daniel Edward Bowen, III, Eric Sean Castner
  • Patent number: 7029618
    Abstract: The present invention relates compositions containing acetoacetylated polyvinyl polymers obtained from polyvinyl polymers, such as polyvinyl butyrals. These coating compositions are especially suitable for use as wash primers in automotive OEM and refinish coating applications.
    Type: Grant
    Filed: March 4, 2005
    Date of Patent: April 18, 2006
    Assignee: E.I. duPont de Nemours and Company
    Inventors: Lorenzo Fred Pelosi, Patricia Mary Ellen Sormani
  • Patent number: 6946523
    Abstract: In accordance with the present invention, there are provided novel heterobifunctional monomers and users for the same. Invention compounds have many of the properties required by the microelectronics industry, such as, for example, hydrophobicity, high Tg values, low dielectric constant, ionic purity, low coefficient of thermal expansion (CTE), and the like. These properties result in a thermoset that is particularly well suited to high performance applications where typical operating temperatures are often significantly higher than those at which prior art materials were suitable. Invention compounds are particularly ideal for use in the manufacture of electronic components, such as, for example, printed circuit boards, and the like.
    Type: Grant
    Filed: July 1, 2003
    Date of Patent: September 20, 2005
    Assignee: Henkel Corporation
    Inventors: Stephen M. Dershem, Kevin J. Forrestal, Puwei Liu
  • Patent number: 6919416
    Abstract: The present invention relates compositions containing acetoacetylated polyvinyl polymers obtained from polyvinyl polymers, such as polyvinyl butyrals. These coating compositions are especially suitable for use as wash primers in automotive OEM and refinish coating applications.
    Type: Grant
    Filed: February 9, 2004
    Date of Patent: July 19, 2005
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Lorenzo Fred Pelosi, Patricia Mary Ellen Sormani
  • Patent number: 6903171
    Abstract: Methods for the addition polymerization of cycloolefins using a cationic Group 10 metal complex and a weakly coordinating anion of the formula: [(R?)zM(L?)x(L?)y]b[WCA]d wherein [(R?)zM(L?)x(L?)y] is a cation complex where M represents a Group 10 transition metal; R? represents an anionic hydrocarbyl containing ligand; L? represents a Group 15 neutral electron donor ligand; L? represents a labile neutral electron donor ligand; x is 1 or 2; and y is 0, 1, 2, or 3; and z is 0 or 1, wherein the sum of x, y, and z is 4; and [WCA] represents a weakly coordinating counteranion complex; and b and d are numbers representing the number of times the cation complex and weakly coordinating counteranion complex are taken to balance the electronic charge on the overall catalyst complex.
    Type: Grant
    Filed: October 15, 2002
    Date of Patent: June 7, 2005
    Assignee: Promerus, LLC
    Inventors: Larry Funderburk Rhodes, Andrew Bell, Ramakrishna Ravikiran, John C. Fondran, Saikumar Jayaraman, Brian Leslie Goodall, Richard A. Mimna, John-Henry Lipian
  • Patent number: 6891007
    Abstract: This invention relates to a process for polymerizing polar substituted norbornenes and/or cycloalkenes, optionally, in the presence of another unsaturated compound. The method is characterized in that the polymerization is carried out in the presence of one or more tungsten carbine complexes.
    Type: Grant
    Filed: March 19, 2001
    Date of Patent: May 10, 2005
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl-Heinz Alexsander Ostoja Starzewski, Karin Weiss, Martin Olaf Thüring
  • Patent number: 6875834
    Abstract: Aqueous coating compositions containing (1) a first polymer containing reactive functional groups with a selected level of carboxylic acid functionality and (2) a polyfunctional crosslinker agent containing functional groups that are reactive with appropriate functional groups of the first polymer, are disclosed. The two-component polymer compositions provide a combination of durability and ready removability of the final coating after curing. Two-component polymer compositions based on the first polymer containing hydroxyl functionality in addition to carboxylic acid functionality and use of a polyisocyanate as the polyfunctional crosslinker agent are especially useful as floor polish compositions.
    Type: Grant
    Filed: January 16, 2002
    Date of Patent: April 5, 2005
    Assignee: Rohm and Haas Company
    Inventors: Richard Thomas Gray, Alan Wayne Kohr, Dennis Michael Sharpe, Theodore Tysak
  • Patent number: 6849375
    Abstract: Photoresist monomers of following Formula 1, photoresist polymers thereof, and photoresist compositions containing the same. The photoresist polymers include a repeating unit comprising the photoresist monomer of Formula 1 as a comonomer and the photoresist compositions containing the same have excellent etching resistance, heat resistance and adhesiveness to a wafer, and are developable in aqueous tetramethylammonium hydroxide (TMAH) solutions. In addition, the photoresist compositions have a low light absorbance at 157 nm wavelength, and thus are suitable for a photolithography process using ultraviolet light sources such as VUV (157 nm) in fabricating a minute circuit for a high integration semiconductor device. wherein Y1, Y2, Y3, Y4, Y5, Y6, Z1, Z2 and m are defined in the specification.
    Type: Grant
    Filed: February 21, 2002
    Date of Patent: February 1, 2005
    Assignee: Hynix Semiconductor Inc.
    Inventors: Geun Su Lee, Jae Chang Jung, Ki Soo Shin
  • Publication number: 20040242825
    Abstract: A cyclic conjugated diene copolymer comprising a main chain comprised of (A) cyclic conjugated diene monomer units, (B) monomer units obtained from vinyl aromatic monomers each having a hydrogen atom at the &agr;-position thereof, and optionally (C) monomer units obtained from commoners which are other than the monomers used for obtaining the monomer units A and B and which are copolymerizable with at least one of the monomers used for obtaining the monomer units A and B, wherein all monomer units A and the monomer units B together form one or more polymer chains each having an A/B random sequence, wherein the one or more polymer chains each having an A/B random sequence contain at least one polymer chain having a number average molecular weight of from 20,000 to 500,000 and contain no polymer chain having a number average molecular weight of more than 500,000. A process for producing the above-mentioned cyclic conjugated diene copolymer by living anionic polymerization.
    Type: Application
    Filed: February 13, 2004
    Publication date: December 2, 2004
    Inventors: Junichi Shishido, Kenichi Sanechika
  • Patent number: 6806325
    Abstract: Ruthenium and osmium carbene compounds that are stable in the presence of a variety of functional groups and can be used to catalyze olefin metathesis reactions on unstrained cyclic and acyclic olefins are disclosed. Also disclosed are methods of making the carbene compounds. The carbene compounds are of the formula where M is Os or Ru; R1 is hydrogen; R is selected from the group consisting of hydrogen, substituted or unsubstituted alkyl, and substituted or unsubstituted aryl; X and X1 are independently selected from any anionic ligand; and L and L1 are independently selected from any neutral electron donor. The ruthenium and osmium carbene compounds of the present invention may be synthesized using diazo compounds, by neutral electron donor ligand exchange, by cross metathesis, using acetylene, using cumulated olefins, and in a one-pot method using diazo compounds and neutral electron donors.
    Type: Grant
    Filed: December 19, 2002
    Date of Patent: October 19, 2004
    Assignee: California Institute of Technology
    Inventors: Robert H. Grubbs, Peter Schwab, Sonbinh T. Nguyen
  • Publication number: 20040157039
    Abstract: An insulating material comprising a cycloolefin polymer, specifically, an interlayer insulating material for a high-density assembly board having interlayer-connecting via holes at most 200 &mgr;m in diameter, comprising a cycloolefin polymer containing at least 50 mol % of a repeating unit derived from a cycloolefin monomer; a dry film formed from a curable resin composition comprising a polymer having a number average molecular weight within a range of 1,000 to 1,000,000 as measured by gel permeation chromatography, and a hardener; and a resin-attached metal foil obtained by forming a film of a cycloolefin polymer on one side of a metal foil. Laminates, multi-layer laminates and build-up multi-layer laminates making use of these materials, and production processes thereof.
    Type: Application
    Filed: February 4, 2004
    Publication date: August 12, 2004
    Inventors: Yasuo Tsunogae, Yasuhiro Wakizaka, Junji Kodemura, Tohru Hosaka
  • Patent number: 6773767
    Abstract: To provide a liquid crystal display unit without occurrence of abnormal orientation of liquid crystal molecules and deterioration of the image quality and a method for manufacturing the same. Above and below a TFT, light shielding films are disposed and further the ruggedness generated by stacking a plurality of light shielding films is smoothed using a transparent resin not absorbing light with a wavelength of not smaller than 300 nm. As this transparent resin, acrylic resins are used. As a result, according to the present invention, no abnormal orientation of liquid crystal molecules occurs and a problem of reverse twist, reverse tilt or the like is less probable to take place. Since the smoothening film absorbs no light of not smaller than 300 nm, neither denaturalization nor coloration nor bubbles occur in the smoothening film even under irradiating environments of intense light of a projector or the like.
    Type: Grant
    Filed: March 7, 2001
    Date of Patent: August 10, 2004
    Assignee: NEC Corporation
    Inventors: Hiroyuki Sekine, Fujio Okumura, Shigeyuki Iwasa
  • Patent number: 6765078
    Abstract: A process for preparing polyacrylates, characterized in that the monomer mixture for preparing the polyacrylates is composed of at least 70% by weight of at least one acrylic monomer of the general formula where R1 is H or CH3 and R2 is H or an alkyl chain having 1-20 carbon atoms, the monomers are polymerized in the presence of at least one free-radical initiator by free-radical polymerization with at least one thioester as polymerization regulator, the average molecular weight of the polyacrylates is in the range from 250,000 g/mol to 1,000,000 g/mol, and the molecular weight distribution of the polyacrylates, Mw/Mn, is <4.
    Type: Grant
    Filed: May 10, 2002
    Date of Patent: July 20, 2004
    Assignee: tesa AG
    Inventors: Marc Husemann, Stephan Zöllner, Martin Losch
  • Patent number: 6765077
    Abstract: A negative-chargeability control resin containing a specific vinyl copolymer imparts stable chargeability to toner. The vinyl copolymer is obtainable by copolymerizing a monomer composition which contains at least i) a vinyl monomer (A) as exemplified by N-acryloylmorpholine, N-isopropylacrylamide, N-methylmethacrylamide, N-butoxymethylacrylamide or N-t-butylacrylamide, or a vinyl monomer (B) as exemplified by vinyl butyrate, vinyl 2-ethylhexanoate, vinyl benzoate, vinyl monochloroacetate pivarate, and ii) a vinyl monomer (C) having as a functional group a carboxyl group or a carboxyl group made into salt structure.
    Type: Grant
    Filed: March 10, 2003
    Date of Patent: July 20, 2004
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tatsurou Yoshida, Eri Komatsumoto
  • Patent number: 6713154
    Abstract: An insulating material comprising a cycloolefin polymer, specifically, an interlayer insulating material for a high-density assembly board having interlayer-connecting via holes at most 200 &mgr;m in diameter, comprising a cycloolefin polymer containing at least 50 mol % of a repeating unit derived from a cycloolefin monomer; a dry film formed from a curable resin composition comprising a polymer having a number average molecular weight within a range of 1,000 to 1,000,000 as measured by gel permeation chromatography, and a hardener; and a resin-attached metal foil obtained by forming a film of a cycloolefin polymer on one side of a metal foil. Laminates, multi-layer laminates and build-up multi-layer laminates making use of these materials, and production processes thereof.
    Type: Grant
    Filed: December 6, 1999
    Date of Patent: March 30, 2004
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Yasuo Tsunogae, Yasuhiro Wakizaka, Junji Kodemura, Tohru Hosaka
  • Publication number: 20040038150
    Abstract: Provided are new resins that comprise carbocyclic aryl units with hetero substitution units and photoresists that contain such resins. Particularly preferred photoresists of the invention comprise a deblocking resin that contains hydroxy naphthyl units and can be effectively imaged with sub-200 nm radiation such as 193 nm radiation.
    Type: Application
    Filed: May 30, 2003
    Publication date: February 26, 2004
    Applicant: Shipley Company, L.L.C.
    Inventors: Young C. Bae, George G. Barclay