Carboxylic Acid Contains Ester Group Patents (Class 526/318)
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Patent number: 12189429Abstract: A display device includes: a display panel; a driver IC positioned on the display panel; a supporting member positioned under the display panel; and a lower adhesive layer positioned between the display panel and the supporting member. A storage modulus of the lower adhesive layer is about 0.020 MPa to about 0.030 MPa at about 1 Hz and about 140° C.Type: GrantFiled: July 12, 2022Date of Patent: January 7, 2025Assignee: SAMSUNG DISPLAY CO., LTD.Inventors: Ju Hee Song, Sang Jae Kim, Dong-Hee Lee
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Patent number: 12024586Abstract: Described are polymerizable materials (e.g., compounds, prepolymers, and compositions thereof) useful in curable compositions such as anaerobically curable compositions, the compositions including adhesives, sealants, paints, coatings, and the like, as well as methods of making the polymerizable materials and using the polymerizable materials and curable compositions.Type: GrantFiled: April 5, 2021Date of Patent: July 2, 2024Inventors: Kevin G. Rosenberg, Gerhardt P. Werber
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Patent number: 11884760Abstract: A production method for a branched conjugated diene-based polymer, comprising: a polymerizing step of obtaining a conjugated diene-based polymer having an active end by polymerizing or copolymerizing a conjugated diene compound, or a conjugated diene compound and an aromatic vinyl compound with an alkali metal compound or an alkaline earth metal compound used as a polymerization initiator; and a branching step of introducing a branch structure by reacting a styrene derivative as a branching agent with the active end of the conjugated diene-based polymer.Type: GrantFiled: December 9, 2020Date of Patent: January 30, 2024Assignee: Asahi Kasei Kabushiki KaishaInventors: Shinichi Sekikawa, Kenta Hisamura, Syogo Sumitani, Yoshifumi Araki
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Patent number: 11834590Abstract: Adhesive compositions comprising an aqueous dispersion of an acrylic polymer are disclosed, with such compositions having particular applicability in additive manufacturing processes, such as three-dimensional (3D) printing, including Fused Filament Fabrication (FFF). In particular, the compositions address drawbacks associated with an improper degree of adhesion between a thermoplastic build material and build plate, which decrease the quality of printed objects. In representative aqueous dispersions, the solids content of at least about 5 wt. % and also most about 95 wt. % of the acrylic polymer is solubilized, with the balance of this polymer comprising dispersed solid particles.Type: GrantFiled: December 21, 2018Date of Patent: December 5, 2023Assignee: STRATASYS, INC.Inventors: Wilhelmus Frederikus Zoetelief, Patrick Gerardus Duis, Adrianus Antonius Johannes Van Geel, Danielle Glasbergen-Benning, Rudolfus Antonius Theodorus Maria Van Benthem, Robbert Van Sluijs
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Patent number: 11708439Abstract: The present invention is a modified resin for a molded article obtained by modifying an ethylene/unsaturated carboxylic acid copolymer with guanidine carbonate, wherein a melt flow rate of the ethylene/unsaturated carboxylic acid copolymer is 20 (g/10 minutes) or more and 600 (g/10 minutes) or less.Type: GrantFiled: February 12, 2019Date of Patent: July 25, 2023Assignee: DOW-MITSUI POLYCHEMICALS CO., LTD.Inventor: Takahiro Shimizu
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Patent number: 11701447Abstract: A composition including a solution at least one acrylic adhesive and particles of a cross-linked polymer having a carboxylate-group density between 2.0 and 12.0 meq/g and an average pore size between 0.005 and 1.0 ?m, usable in particular for creating an adhesive matrix suitable for any device, for example for medical aims such as a patch, a film, a strip or a dressing, preferably a dressing, or suitable for any device of the functional textile type such as a sports item.Type: GrantFiled: February 20, 2019Date of Patent: July 18, 2023Assignee: URGO RECHERCHE INNOVATION ET DEVELOPPEMENTInventors: Anne-Sophie Danérol, Christelle Guillamaud, Jean-Marc Pernot
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Patent number: 10703859Abstract: A composition for use in 3D printing includes an unsaturated polyester resin including an ethylenically unsaturated monomer, a first diol monomer and a second diol monomer.Type: GrantFiled: May 17, 2018Date of Patent: July 7, 2020Assignee: XEROX CORPORATIONInventors: Shivanthi E. Sriskandha, Valerie M. Farrugia, Guerino G. Sacripante, Edward G. Zwartz
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Patent number: 10366843Abstract: A structural capacitor and method for manufacturing the structural capacitor. A first layer of nonconductive fiber glass may be formed into a desired shape of the structural capacitor, and then a conductive layer made of carbon fiber pre-impregnated material may be placed on the fiber glass layer. A dielectric layer of parylene may then be coated onto the conductive layer using a conformal vapor deposition process. More conductive and dielectric layers may be added in alternating succession until desired structural and/or electrical properties are achieved. A final layer of fiber glass may then be applied and the resulting structural capacitor may be cured.Type: GrantFiled: January 26, 2018Date of Patent: July 30, 2019Assignee: Honeywell Federal Manufacturing & Technologies, LLCInventors: Steven Todd LaPlant, Daniel John Salzman
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Patent number: 10323119Abstract: The invention provides poiyfunctionai bio-based methacrylate oligomers, which are synthesized via the ring-opening reaction between at least one ethyienicaliy unsaturated acid selected from methacrylic acid, acrylic acid, and crotonic acid, and a poiyfunctionai bio-based epoxy resin, such as epoxidized sucrose soyate. The extent of reaction may be varied to generate a family of methacrylate oligomers with differing degrees of methacryiation. These methacrylate oligomers can optionally be mixed with a reactive diluent, such as styrene, and cured using, for example, a thermally-activated free radical initiator to form a thermoset polymer with high modulus. The thermosets can be used to form composites, adhesives, coatings, and dental restorative materials. Methods of making the methacrylate oligomers are disclosed as are coating compositions and coated objects, such as dental restorative materials, using the methacrylate oligomers.Type: GrantFiled: November 7, 2014Date of Patent: June 18, 2019Assignee: NDSU RESEARCH FOUNDATIONInventors: Dean C. Webster, Lindsey Bultema, Jingling Yan
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Patent number: 10077385Abstract: A resin composition has a high glass transition temperature and is highly adhesive to a member made of metal, ceramics, or the like. The resin composition includes a thermosetting base resin, a thermoplastic resin powder, a curing agent, and an inorganic filler, a cured resin product formed by curing the resin composition, and an electrical member.Type: GrantFiled: January 20, 2017Date of Patent: September 18, 2018Assignee: Fuji Electric Co., Ltd.Inventors: Kotomi Suzuki, Yuji Ichimura, Yuko Nakamata
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Patent number: 9580381Abstract: An amine which can be used in epoxy resin compositions that cure at room temperature. The amine dilutes the composition highly effectively, allows rapid, trouble-free curing, even in cold and damp conditions, and reduces brittleness. The amine is particularly suitable as a constituent of a curing agent for low-emission epoxy resin compositions that cure at room temperature, in particular for floor coverings.Type: GrantFiled: December 20, 2013Date of Patent: February 28, 2017Assignee: SIKA TECHNOLOGY AGInventors: Edis Kasemi, Andreas Kramer, Ursula Stadelmann, Urs Burckhardt
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Patent number: 9539065Abstract: The present invention provides assemblies, kits, and methods including a compressible material. Optionally, a hardenable dental composition (e.g., an adhesive or primer) is in contact with the compressible material for bonding a dental article (e.g., an orthodontic appliance) to a tooth structure. Removal of excess hardenable and/or hardened dental composition, if desired, can be facilitated for embodiments in which the hardenable dental composition is an unfilled or a lightly filled composition.Type: GrantFiled: April 23, 2009Date of Patent: January 10, 2017Assignee: 3M Innovative Properties CompanyInventor: David K. Cinader, Jr.
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Patent number: 9163103Abstract: Water-soluble, hydrophobically associating copolymers which comprise new types of hydrophobically associating monomers. The monomers comprise an ethylenically unsaturated group and a polyether group with block structure comprising a hydrophilic polyalkylene oxide block which consists essentially of ethylene oxide groups, and a terminal, hydrophobic polyalkylene oxide block which consists of alkylene oxides with at least 4, preferably at least 5 carbon atoms.Type: GrantFiled: July 3, 2014Date of Patent: October 20, 2015Assignee: BASF SEInventors: Roland Reichenbach-Klinke, Thomas Pfeuffer, Kati Schmidt, Thomas Ostrowski, Reinhold J. Leyrer, Yulia Fogel, Stefan Friedrich, Peter Gaeberlein, Andrea Orleans, Manfred Schuhbeck, Marcus Guzmann, Marcus Rösch, Bjorn Langlotz
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Patent number: 9023948Abstract: It is an object of the invention to provide a chloroprene rubber-based polymer latex that has a good balance between initial adhesion and storage stability and is suitable for one-component aqueous adhesive applications. The invention relates to a chloroprene rubber-based polymer latex composition containing a mixture of a chloroprene rubber-based polymer latex and a latex of an acrylic or styrene-acrylic resin-based polymer obtained by copolymerization of a specific carboxyl group-containing unsaturated monomer, in which the specific carboxyl group is neutralized with an alkali.Type: GrantFiled: March 15, 2013Date of Patent: May 5, 2015Assignee: Showa Denko K.K.Inventor: Tetsuya Ohnishi
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Patent number: 9023116Abstract: As associative thickener obtainable by free radical polymerization, the preparation thereof and the use thereof in paper coating slips are described. The associative thickener is formed from (a) acid monomers selected from ethylenically unsaturated C3- to C8-carboxylic acids, (b) associative monomers of the general formula H2C?CR1—COO-(EO)n—(PO)m—R2, in which R1 is hydrogen or methyl, n is a number of at least two, m is a number from zero to 50, EO is an ethylene oxide group, PO is a propylene oxide group and R2 is a C8-C30-alkyl group or a C8-C30-alkaryl group, and (c) nonionic, copolymerizable monomers differing from a) and b), the reaction product having been reacted, after the polymerization, with initiators forming nonionic radicals.Type: GrantFiled: February 1, 2011Date of Patent: May 5, 2015Assignee: BASF SEInventors: Philipp Zacharias, Hermann Seyffer, Ilshat Gubaydullin, Harutyun Hanciogullari, Marc Bothe
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Patent number: 9000112Abstract: The present invention relates to a resin mixture for melt processing, comprising a first resin; and a second resin comprising an acrylate-based copolymer including silica particles and having a polydispersity index (PDI) of 1 to 2.5, a method for preparing a resin-molded article using the same, and a resin-molded article. Surface characteristics of the molded article can be improved and excellent scratch resistance can be obtained by using the resin composition. In addition, processing time can be reduced, productivity is increased, and manufacturing costs are lowered by omitting the additional surface coating step.Type: GrantFiled: October 14, 2011Date of Patent: April 7, 2015Assignee: LG Chem, Ltd.Inventors: Jin Young Ryu, Houng Sik Yoo, Hak Shin Kim, Eun Joo Choi, Young Jun Hong
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Patent number: 8940825Abstract: There are provided a sealing composition for a hard disk drive (HDD) motor and a HDD motor fabricated using the same. The sealing composition includes: 45 to 65 parts by weight of urethane methacrylate; 35 to 50 parts by weight of methacrylate; and 2 to 4 parts by weight of acrylic acid. A sealing composition having a new composition is used as a sealing material of a flexible printed circuit (FPC) adhering part of the HDD motor, whereby a haze phenomenon due to air leak and outgas at the FPC adhering part may be improved and reliability of a HDD motor may be enhanced due to a reduction in generation of the outgas of the adhering part.Type: GrantFiled: February 29, 2012Date of Patent: January 27, 2015Assignee: Samsung Electro-Mechanics Co., Ltd.Inventors: Kun Kim, Hyung Kyu Kim
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Patent number: 8916663Abstract: The present invention relates to a method for producing a high-molecular-weight copolymer of polar group-containing allyl monomers including monomer units represented by formulae (3) and (4) (in the formulae, R1 represents a hydrogen atom (H) or hydrocarbon group having 1 to 6 carbon atoms; R2 represents —OH, —OCOR3 (R3 represents hydrocarbon group having 1 to 5 carbon atoms), —N(R4)2 (R4 represents a hydrogen atom or hydrocarbon group having 1 to 5 carbon atoms); and n and m are a value representing the molar ratio of each of the monomer units), which has few branches and unsaturated group at the molecular end, by copolymerizing olefin and a polar group-containing allyl compound using a metal complex of group 10 elements in the periodic system represented by formula (I) as a catalyst.Type: GrantFiled: August 26, 2010Date of Patent: December 23, 2014Assignees: The University of Tokyo, Showa Denko K.K.Inventors: Kyoko Nozaki, Shingo Ito, Yoshikuni Okumura, Junichi Kuroda
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Patent number: 8900792Abstract: A compound has formula (I): Q-O-(A)-Z?G+??(I) wherein Q is a halogenated or non-halogenated, C2-30 olefin-containing group, A is a fluorine-substituted C1-30 alkylene group, a fluorine-substituted C3-30 cycloalkylene group, a fluorine-substituted C6-30 arylene group, or a fluorine-substituted C7-30 alkylene-arylene group, Z is an anionic group comprising sulfonate, sulfonamide, or sulfonimide, and G+ has formula (II): wherein X is S or I, each R0 is halogenated or non-halogenated and is independently C1-30 alkyl group; a polycyclic or monocyclic C3-30 cycloalkyl group; a polycyclic or monocyclic C4-30 aryl group; or a combination of these, wherein when X is S, one of the R0 groups is optionally attached to one adjacent R0 group by a single bond, and a is 2 or 3, wherein when X is I, a is 2, or when X is S, a is 3. A copolymer, a photoresist, a coated substrate and method of patterning are disclosed.Type: GrantFiled: December 29, 2011Date of Patent: December 2, 2014Assignees: Rohm and Haas Electronic Materials LLC, Dow Global Technologies LLCInventors: James W. Thackeray, Suzanne M. Coley, Vipul Jain, Owendi Ongayi, James F. Cameron, Paul J. Labeaume, Ahmad E. Madkour
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Patent number: 8883948Abstract: Optimized methods to achieve extensive dark curing from a three-component visible light-initiated system though controlled radical polymerization and compositions useful in these optimized methods are provided. These compositions and methods are particularly suited for use in certain dental applications.Type: GrantFiled: July 1, 2009Date of Patent: November 11, 2014Assignee: The Regents of the University of ColoradoInventors: Jeffrey W. Stansbury, Dongkwan Kim
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Patent number: 8829133Abstract: To provide an ABA triblock copolymer containing: an A-block having, in a constitutional unit thereof, a monomer represented by the following general formula (1) or a monomer represented by the following general formula (2); and a B-block having, in a constitutional unit thereof, a hydrophilic monomer having a radical polymerizable unsaturated bond, where R1 is a hydrogen atom or a methyl group; R2 is a C5-C18 alkylene group; M is a hydrogen atom or a monovalent metal atom; and X1 is —NH— or an oxygen atom in the general formula (1), and where R11 is a hydrogen atom or a methyl group; R12 is a C5-C18 alkylene group; R13 and R14 are each independently a hydrogen atom, a methyl group, or an ethyl group; and X11 is —NH— or an oxygen atom in the general formula (2).Type: GrantFiled: April 22, 2013Date of Patent: September 9, 2014Assignees: Ricoh Company, Ltd., University of HyogoInventors: Yuuma Usui, Shin-ichi Yusa
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Patent number: 8809476Abstract: A polymer includes a repeating unit shown by a following general formula (1). R1 represents a hydrogen atom, a methyl group, a fluorine atom, or a trifluoromethyl group. R2 represents a substituted or unsubstituted aryl group having 6 to 22 carbon atoms. Y represents a carbon atom. X represents an atomic group that forms an alicyclic hydrocarbon group together with Y.Type: GrantFiled: October 24, 2012Date of Patent: August 19, 2014Assignee: JSR CorporationInventors: Ken Maruyama, Toshiyuki Kai
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Patent number: 8791288Abstract: An acid-labile ester monomer of spirocyclic structure has formula (1) wherein Z is a monovalent group having a polymerizable double bond, X is a divalent group which forms a cyclopentane, cyclohexane or norbornane ring, R2 is H or monovalent hydrocarbon, R3 and R4 are H or monovalent hydrocarbon, or R3 and R4, taken together, stand for a divalent group which forms a cyclopentane or cyclohexane ring, and n is 1 or 2. A polymer obtained from the acid-labile ester monomer has so high reactivity in acid-catalyzed elimination reaction that the polymer may be used to formulate a resist composition having high resolution.Type: GrantFiled: May 25, 2010Date of Patent: July 29, 2014Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Takeshi Kinsho, Tomohiro Kobayashi, Masayoshi Sagehashi, Takeru Watanabe, Koji Hasegawa, Seiichiro Tachibana
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Patent number: 8753793Abstract: Disclosed is a method for producing a resin solution for photoresists, which includes the steps of heating and thereby aging a solution at 30° C. to 90° C. for 30 minutes or longer, the solution containing, in a solvent, a photoresist resin capable of being alkali-soluble by the action of an acid; and filtering the aged solution through a filter medium having a pore size of 1 ?m or less. The method gives a photoresist composition having good filterability which enables uniform patterning. The method also gives a resin solution for photoresists which is stable over a long time, namely, a resin solution for photoresists which maintains good filterability even after long-term storage.Type: GrantFiled: January 15, 2009Date of Patent: June 17, 2014Assignee: Daicel Chemical Industries, Ltd.Inventors: Akira Eguchi, Masamichi Nishimura
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Patent number: 8729202Abstract: The present invention provides a biocompatible polymer composition for use in biomedical applications comprising a base molecule, a linker molecule and at least one initiator compound, said base molecule having at least two differing functionalities, and said linker molecule having a functionality reactive with at least one functionality of said base molecule, the first of said at least two functionalities of said base molecule enabling a first curing stage of said polymer composition by reaction with said linker molecule, and the second and any further functionality of said base molecule enabling second and further curing stages of said polymer composition, said first, second and any further curing stages being capable of activation simultaneously or independently of each other as required.Type: GrantFiled: March 3, 2005Date of Patent: May 20, 2014Assignee: Polynovo Biomaterials Pty LimitedInventors: Roshan Tyrrel Anton Mayadunne, Raju Adhikari, Pathiraja Arachchillage Gunatillake
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Patent number: 8710168Abstract: The present invention is a polymer having structural units, units of formula I, units of formula II and units of either formula IIIa or formula IIIb: The polymer improves the low-temperature properties of fuel oils from petroleum sources and especially from vegetable or animal sources.Type: GrantFiled: December 17, 2010Date of Patent: April 29, 2014Assignee: Infineum International LimitedInventors: Carl Waterson, Christopher J. Booth
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Patent number: 8637623Abstract: Disclosed is a monomer having an electron-withdrawing substituent and a lactone skeleton, represented by Formula (1), wherein Ra represents, e.g., hydrogen or an alkyl group having 1 to 6 carbons; R1 represents, e.g., a halogen or an alkyl or haloalkyl group having 1 to 6 carbons; “A” represents an alkylene group having 1 to 6 carbons, oxygen, sulfur, or is nonbonding; “m” denotes an integer of 0 to 8; Xs each represent an electron-withdrawing substituent; “n” denotes an integer of 1 to 9; and Y represents a bivalent organic group having 1 to 6 carbons. The monomer is useful as a monomer component typically for a highly functional polymer, because, when the monomer is applied to a resist resin, the resin is stable and resistant to chemicals, is highly soluble in organic solvents, and has improved hydrolyzability and/or solubility in water after hydrolysis.Type: GrantFiled: February 3, 2009Date of Patent: January 28, 2014Assignee: Daicel Chemical Industries, Ltd.Inventors: Hiroshi Koyama, Kyuhei Kitao, Akira Eguchi
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Patent number: 8614046Abstract: A salt represented by the formula (I-Pa): wherein Xpa represents a single bond or a C1-C4 alkylene group, Rpa represents a single bond, a C4-C36 divalent alicyclic hydrocarbon group or a C6-C36 divalent aromatic hydrocarbon group, and one or more methylene groups in the divalent alicyclic hydrocarbon group can be replaced by —O— or —CO—, Ypa represents a polymerizable group, and Zpa+ represents an organic cation.Type: GrantFiled: July 9, 2010Date of Patent: December 24, 2013Assignee: Sumitomo Chemical Company, LimitedInventors: Koji Ichikawa, Masako Sugihara, Yuko Yamashita
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Patent number: 8574292Abstract: Disclosed are soft, high refractive index, acrylic device materials. The materials contain a functionalized alkylphenol ethoxylate to reduce glistenings.Type: GrantFiled: October 1, 2008Date of Patent: November 5, 2013Assignee: Novartis AGInventors: Water R. Laredo, Douglas C. Schlueter
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Publication number: 20130281594Abstract: The present invention relates to a process for producing water-absorbent polymer particles by polymerizing droplets of a monomer solution in a surrounding heated gas phase and flowing the gas cocurrent through the polymerization chamber, wherein the temperature of the gas leaving the polymerization chamber is 130° C. or less, the gas velocity inside the polymerization chamber is at least 0.5 m/s, and the droplets are generated by using a droplet plate having a multitude of bores.Type: ApplicationFiled: April 25, 2013Publication date: October 24, 2013Inventors: Rainer Dobrawa, Thomas Daniel, Uwe Stueven, Marco Krüger, Francisco Javier Lopez Villanueva, Norbert Herfert, Michael A. Mitchell
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Patent number: 8551615Abstract: Disclosed is a pressure-sensitive adhesive composition which contains an acrylic polymer and a crosslinking agent. The acrylic polymer has a weight-average molecular weight of 40×104 to 160×104 and contains at least an alkoxyalkyl acrylate (Component A) and an acrylic monomer having a crosslinkable functional group (Component B). The monomer components constituting the acrylic polymer contain 45 to 99.5 parts by weight of Component A and 0.5 to 4.5 parts by weight of Component B to 100 parts by weight of total monomer components constituting the acrylic polymer, and the monomer components constituting the acrylic polymer contain substantially no carboxyl-containing monomers. This relates to improvements to provide pressure-sensitive adhesive compositions that show excellent coatability, transparency, adhesion (typically low-temperature adhesion), and resistance to blistering/separation and concurrently have anticorrosive properties.Type: GrantFiled: September 3, 2008Date of Patent: October 8, 2013Assignee: Nitto Denko CorporationInventors: Hiroaki Kishioka, Ryuuichi Kabutoya
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Patent number: 8552134Abstract: A method of producing a water-absorbent resin of the present invention reduces amounts of a residual cross-linking agent and a residual surfactant, achieves high productivity, and improves physical properties of the resultant water-absorbent, such as absorption capacity, extractable polymer content, powder friction, and gel crushability. The method includes the steps of: polymerizing an aqueous monomer solution containing as a major component an acrylic acid monomer in the presence of a cross-linking agent; and drying the resultant polymer by heating, in which the cross-linking agent is a multifunctional (meth)acrylate cross-linking agent having polyethylene glycol structural units including a total of 6 to 200 ethylene oxide repeating units, and the aqueous monomer solution includes a mono(meth)acrylate compound having polyethylene glycol structural units in an amount of 0.1 to 30% by weight relative to an amount of the multifunctional (meth)acrylate cross-linking agent.Type: GrantFiled: March 29, 2007Date of Patent: October 8, 2013Assignee: Nippon Shokubai Co., Ltd.Inventors: Hirotama Fujimaru, Eri Goto, Kunihiko Ishizaki, Atsushi Motoyama
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Patent number: 8501033Abstract: The invention relates to a liquid radiation curable resin capable of curing into a solid upon irradiation comprising: (A) from about 0 to about 12 wt % of a cycloaliphatic epoxide having a linking ester group; (B) from about 30 to about 65 wt % of one or more epoxy functional components other than A; (C) from about 10 to about 30 wt % of one or more oxetanes; (D) from, about 1 to about 10 wt % of one or more polyols; (E) from about 2 to about 20 wt % of one or more radically curable (meth)acrylate components; (F) from about 2 to about 12 wt % of one or more impact modifiers; (G) from about 0.1 to about 8 wt % of one or more free radical photoinitiators; and (H) from about 0.1 to about 8 wt % of one or more cationic photoinitiators; wherein the liquid radiation curable resin has a viscosity at 30° C. of from about 600 cps to about 1300 cps.Type: GrantFiled: March 12, 2010Date of Patent: August 6, 2013Assignee: DSM IP Assets B.V.Inventors: John Southwell, Brett A. Register, Satyendra Kumar Sarmah, Paulus Antonius Maria Steeman, Beert Jacobus Keestra, Marcus Matheus Driessen
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Patent number: 8492513Abstract: The present invention provides a method for producing a silicone hydrogel having a high water content. The method comprises the following steps: (a) polymerizing a monomer mixture to form the silicone hydrogel, wherein the monomer mixture comprises at least one silicon-containing monomer and at least one ionic monomer; and (b) placing the silicone hydrogel in an alkaline solution for at least 20 minutes, wherein the alkaline solution has a pH not less than 7.5 and the ionic monomer is present in an amount not less than 0.7 wt % based on the total dry weight of the silicone hydrogel.Type: GrantFiled: October 14, 2011Date of Patent: July 23, 2013Assignee: Far Eastern New Century CorporationInventors: Chih-Ta Lee, Ching-Ping Huang, Yi-Hsuan Chang, Ken-Yuan Chang
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Patent number: 8481631Abstract: The invention relates to a process for the preparation of an aqueous dispersion of polymer particles in an aqueous medium employing a living macroinitiator requiring a reinitiation temperature of less than 100° C. Application of the particles obtained in the field of surface coatings.Type: GrantFiled: May 19, 2009Date of Patent: July 9, 2013Assignees: Arkema France, Centre de la Recherche Scientifique, Universite Pierre et Marie Curie (Paris 6)Inventors: Charlotte Dire, Bernadette Charleux, Stéphanie Magnet, Laurence Couvreur
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Patent number: 8476386Abstract: The present invention provides a branched, a dendritic, or a hyperbranched poly(amino ester) having a polymer backbone comprising a plurality of branches, wherein the polymer backbone has at least one secondary and at least one tertiary amine linkage. Branched poly(amino ester)s are prepared via a Michael addition reaction of a tris(acrylate ester)monomer with a diamine monomer. In one aspect, the diamine monomer has a primary amino group and a secondary amino group. The poly(amino ester) compounds can be end-capped by reacting with a suitable agent. The present invention also provides applications including, but are not limited to, the delivery of bioactive agents, such as drugs, DNA or RNA; or biocompatible imaging.Type: GrantFiled: March 8, 2012Date of Patent: July 2, 2013Assignee: Agency for Science, Technology and ResearchInventors: Ye Liu, Decheng Wu, Chaobin He
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Patent number: 8476391Abstract: The invention relates to a method for producing anionic water-in-water polymer dispersions containing at least one finely dispersed, water-soluble and/or water-swellable polymer A and a continuous aqueous phase. This phase has a partial quantity of at least one polymeric dispersing agent B in which monomers dispersed in this aqueous phase are subjected to a radical polymerization, and after the polymerization is completed, the reaction mixture is subsequently diluted with the remaining amount of dispersing agent B. The invention also relates to the polymer dispersions obtained according to the method and to their use, particularly in the paper industry.Type: GrantFiled: March 7, 2005Date of Patent: July 2, 2013Assignee: Ashland Licensing and Intellectual Property LLCInventors: Susanne Bellmann, Norbert Steiner, Michael Busch, Dev Steuck, Johann Schulte, Wolfgang Woebel
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Patent number: 8461277Abstract: An additive composition for imparting caustic removability to a hot melt adhesive comprises a low molecular weight ?,? ethylenically unsaturated anhydride-containing or acid-containing polymer. The polymer is selected from the group consisting of a low molecular weight carboxylic anhydride homo-polymer or the at least partial ester thereof, a low molecular weight carboxylic anhydride copolymer or the at least partial ester thereof, a low molecular weight carboxylic anhydride polyolefin, a low molecular weight carboxylic anhydride vinyl aromatic copolymer, and a low molecular weight carboxylic anhydride grafted copolymer, or the combination or mixtures thereof. A caustic removable hot melt adhesive composition comprises a hot melt adhesive additive and a conventional hot melt adhesive resin. A caustic removable adhesive label comprises a substrate and a caustic removable hot melt adhesive composition which includes an additive composition.Type: GrantFiled: April 5, 2010Date of Patent: June 11, 2013Assignee: Cray Valley USA, LLCInventors: William R. Dougherty, Alan J. Pape, Nestor P. Hansen, W. Paul Boggs, Charles C. Mateer
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Patent number: 8450380Abstract: The invention pertains to a new method for formulating pharmaceutical active ingredients in such a way as to protect them when ingested orally, and to allow for the controlling of the release of the active ingredient in the intestine. It relies upon the use of thickening acrylic emulsions with a pH greater than 5, containing hydrophobic groups, in order to encapsulate the pharmaceutical active ingredients for the purpose of encouraging their passage through the gastrointestinal barrier, while controlling the release kinetics of said active ingredients.Type: GrantFiled: January 30, 2008Date of Patent: May 28, 2013Assignee: Coatex S.A.S.Inventors: Olivier Guerret, Jean-Marc Suau
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Patent number: 8445776Abstract: A solar cell module comprising a solar cell layer and a sheet comprising at least one layer of a sodium ionomer composition, wherein the sodium ionomer composition consists essentially of a sodium ionomer that is an ionic, neutralized derivative of a precursor ?-olefin carboxylic acid copolymer, wherein about 10% to about 35% of the total content of the carboxylic acid groups present in the precursor ?-olefin carboxylic acid copolymer have been neutralized with sodium ions, and wherein the precursor ?-olefin carboxylic acid copolymer comprises (i) copolymerized units of an ?-olefin having 2 to 10 carbons and (ii) about 20 to about 25 wt %, based on the total weight of the ?-olefin carboxylic acid copolymer, of copolymerized units of an ?,?-ethylenically unsaturated carboxylic acid having 3 to 8.Type: GrantFiled: June 1, 2009Date of Patent: May 21, 2013Assignee: E I du Pont de Nemours and CompanyInventors: Richard Allen Hayes, Rebecca L. Smith, Kristof Proost, Steven C. Pesek, Charles Anthony Smith
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Patent number: 8420214Abstract: A pre-adhesive composition is described comprising an acid-functional (meth)acrylate copolymer and an aziridine crosslinking agent, which when crosslinked provides a pressure-sensitive adhesive and pressure-sensitive adhesive articles.Type: GrantFiled: June 9, 2009Date of Patent: April 16, 2013Assignee: 3M Innovative Properties CompanyInventors: Maureen A. Kavanagh, Belma Erdogan-Haug, Timothy D. Filiatrault, Shaun D. McCracken, Kumars Sakizadeh
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Patent number: 8394504Abstract: Disclosed is an optical planar thermoplastic resin composition including a lactone ring-containing polymer as a main component thereof, or including a lactone ring-containing polymer and at least one other thermoplastic resin. The optical planar thermoplastic resin composition of the present invention has high transparency, high heat resistance, and high optical isotropy, and therefore, can sufficiently exhibit characteristics according to various optical applications.Type: GrantFiled: August 31, 2005Date of Patent: March 12, 2013Assignee: Nippon Shokubai Co., Ltd.Inventors: Shoji Ito, Ken-ichi Ueda, Nobuhisa Noda, Shigeru Oka, Shigeo Otome, Hiroko Izumi
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Use of copolymers with a composition gradient as stabilizers in emulsion free-radical polymerization
Patent number: 8389637Abstract: The present invention describes the use of copolymers with a composition gradient as sole stabilizer in emulsion free-radical polymerization. The copolymers of the invention are prepared via controlled free-radical polymerization and comprise at least one hydrophilic monomer such as acrylic acid and at least one hydrophobic monomer such as styrene.Type: GrantFiled: December 22, 2005Date of Patent: March 5, 2013Assignee: Arkema FranceInventors: Stephanie Magnet, Olivier Guerret, Catherine Lefay, Bernadette Charleux -
Patent number: 8378003Abstract: Provided are substantially flat membranes that include a block or graft co-polymer and a water transport protein, such as Aquaporin-Z, or a synthetic mimic of such proteins. Also provided are methods of removing contaminants from a liquid, by contacting the liquid with a substantially flat membrane that includes a block or graft co-polymer and a water transport protein or synthetic mimic thereof. Also provided are methods of making such membranes. Further provided are compositions that include at least one active ingredient and vesicles surrounding the active ingredient, where the vesicles include a block or graft copolymer and a water transport protein or synthetic mimic surrounding the active ingredient. Also provided are methods that include administering such compositions to patients.Type: GrantFiled: December 4, 2008Date of Patent: February 19, 2013Assignee: The Board of Trustees of the University of IllinoisInventors: Kumar Manish, Clark Mark, Zilles L. Julie, Mariusz Grzelakowski, Rainer Nehring, WolfGang Meier
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Patent number: 8367777Abstract: A linear, block copolymer, which is useful in cosmetics and improves the styling power and hold of hair laquer, adhesion of nail varnish and hold/adhesion of makeup, includes at least two blocks having different glass transition temperatures, Tg; where at least one of said blocks has a glass transition temperature of 20° C. to ?100° C., and wherein the at least one block having a Tg of 20° C. to ?100° C. is a copolymer B having a first monomer wherein the Tg of the corresponding homopolymer is in the range from more than 20° C. to 200° C., and a second monomer wherein the Tg of the corresponding homopolymer is in the range from 20° C. to ?100° C.Type: GrantFiled: November 27, 2002Date of Patent: February 5, 2013Assignee: L'OrealInventors: Nathalie Mougin, Bertrand Lion
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Patent number: 8349980Abstract: A polyol having a substituent of formula (I) attached via a carbon-carbon single bond to a saturated carbon atom in a fatty acid hydrocarbyl group; wherein R1 and R2 are esterified residues of aliphatic or cycloaliphatic diols; and from 0 to 15 wt % of esterified residues of at least one C4-C12 anhydride, C4-C12 diacid or C4-C12 lactone, not including units of formula (I) attached to a fatty acid hydrocarbyl group.Type: GrantFiled: February 23, 2010Date of Patent: January 8, 2013Assignee: Rohm and Haas CompanyInventor: Joseph James Zupancic
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Patent number: 8350081Abstract: The invention relates to processes for production of methacrylic acid and to processes for production of methyl methacrylate.Type: GrantFiled: February 25, 2008Date of Patent: January 8, 2013Assignee: Evonik Roehm GmbHInventor: Torsten Balduf
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Patent number: 8344083Abstract: The present invention relates to a transparent resin composition which comprises (a) a (meth)acrylate based unit comprising one or more (meth)acrylate based derivatives; (b) an aromatic based unit having a chain having the hydroxy group containing portion and an aromatic moiety and (c) a styrene-based unit comprising one or more styrene-based derivatives, and an optical film that is formed by using the same.Type: GrantFiled: May 4, 2009Date of Patent: January 1, 2013Assignee: LG Chem, Ltd.Inventors: Jun-Geun Um, Min-Hee Lee, Nam-Jeong Lee, Jong-Hun Lee, Dong-Ryul Kim, Sae-Han Cho
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Patent number: 8337824Abstract: The present invention is directed to compositions of a linear polyol and a salt of a crosslinked cation exchange polymer comprising a fluoro group and an acid group. These compositions are useful to bind potassium in the gastrointestinal tract.Type: GrantFiled: August 22, 2009Date of Patent: December 25, 2012Assignee: Relypsa, Inc.Inventors: Detlef Albrecht, Michael Burdick, Han-Ting Chang, Dominique Charmot, Ramakrishnan Chidambaram, Eric Connor, Sherin Halfon, I-Zu Huang, Mingjun Liu, Jonathan Mills, Werner Strüver
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Patent number: RE45500Abstract: Methods of making a coating on a medical device are disclosed, including associating a composition with at least a portion of the device to form a layer. In some embodiments, a composition may include a copolymer prepared from a room temperature melt of a plurality of monomer units that comprises a first monomer unit and a second monomer unit, wherein the second monomer unit has a glass transition temperature that is at least about 30 degrees Centigrade higher than the glass transition temperature of the first monomer unit, with a glass transition temperature of a monomer unit being defined as a glass transition temperature of a homopolymer of that monomer unit.Type: GrantFiled: February 2, 2012Date of Patent: April 28, 2015Assignee: BioInteractions Ltd.Inventors: Ajay K. Luthra, Shivpal S. Sandhu