Abstract: A method of making carbon fiber material according to various embodiments of the present disclosure includes forming a polymer resin to have a polydispersity index (PDI) that is less than approximately 2.5. The method further includes spinning the polymer resin to create an acrylic fiber having an acrylic fiber length. The method further includes oxidizing the acrylic fiber while stretching the acrylic fiber to create an oxidized fiber that has an oxidized fiber length that is at least one of greater than or equal to approximately 100 percent (100%) of the acrylic fiber length. The method further includes carbonizing the oxidized fiber to create a carbon fiber.
Abstract: Disclosed is a layered body comprising a polymer comprising repeating units having the general structure —CH2—CHR1—COOR2— as defined herein, to a process for producing such a layered body, to a layered body produced by that process and to the use of a layered body for electrophysical measurements.
Type:
Grant
Filed:
July 23, 2018
Date of Patent:
May 14, 2024
Assignee:
HERAEUS DEUTSCHLAND GMBH & CO. KG
Inventors:
Christian Neumann, Armin Sautter, Tim Asmus
Abstract: [Object] To provide a method for efficiently producing a water-absorbing agent having excellent physical properties. [Solution] The method for producing a water-absorbing agent includes a drying step of drying a particulate crosslinked hydrogel polymer containing a drying aid. The drying aid is (a) a compound having a betaine structure and having a long-chain alkyl group having 8 or more carbon atoms, one quaternary nitrogen, and one acid group within a molecule thereof and/or (b) a compound having a long-chain alkyl group having 8 or more carbon atoms, one tertiary nitrogen, and one or more acid groups within a molecule thereof. An addition amount of the drying aid with respect to a gel solid content of the particulate crosslinked hydrogel polymer is 0.001% by mass to 0.5% by mass. In this production method, surface-crosslinking is performed on water-absorbent resin powder obtained through the drying step.
Type:
Grant
Filed:
June 20, 2017
Date of Patent:
November 7, 2023
Assignee:
NIPPON SHOKUBAI CO., LTD.
Inventors:
Ryota Wakabayashi, Mai Sato, Motohiro Imura, Tokio Shuto, Yoshihiro Shobo
Abstract: A disinfectant cleaning composition, the composition comprising: a nitrogen containing biocidal compound; a polymer comprising monomers of the following formulae: a) H2C?CR1-CO—NH—R2-N+R3R4R5X— wherein R1 represents hydrogen or C1-C4 alkyl; R2 represents linear or branched C1-C12 alkylene; R3, R4 and R5, independently of one another, each represent hydrogen, C1-C18 alkyl or phenyl; and X— represents an anion selected from the group consisting of halide, sulfate, alkylsulfate, hydroxide, phosphate, acetate and formate; b) 40-75% by weight of N-isopropylacrylamide, based on the water-soluble polymer; c) acrylic and/or methacrylic acid and/or salts thereof; and d) H2C?CR—CO—NH—CR?R?R??—SO3H, and salts thereof; wherein R, R? and R? independently represent hydrogen, C1-C4 alkyl or C1-C4 alkylene, and R?? independently represents C1-C4 alkyl or C1-C4 alkylene.
Abstract: The present disclosure relates to a cement additive composition including a polycarboxylic acid-based copolymer. When the cement additive composition of the present disclosure is used for cement formulation, it may improve fluidity of the composition even in a high water reducing ratio range of the particle and effectively prevent slump loss of the cement formulation, while improving initial dispersibility due to excellent water reducing performance.
Type:
Grant
Filed:
December 8, 2017
Date of Patent:
August 30, 2022
Inventors:
Chang Bum Ko, Dong Jo Ryu, Im Gyu Kim, Hyo Min Kim
Abstract: A laundry detergent composition comprising an anti-redeposition agent, a surfactant, and optionally a builder, wherein the anti-redeposition agent is a polymer comprising polymerized units of: (a) from 5 to 40 wt % of at least one nitrogen-containing ethylenically unsaturated monomer having at least one pKa value from 6 to 11.5, and (b) from 60 to 95 wt % of at least one ethylenically unsaturated carboxylic acid monomer.
Type:
Grant
Filed:
March 21, 2019
Date of Patent:
May 10, 2022
Assignees:
Rohm and Haas Company, Union Carbide Corporation
Inventors:
Robert Butterick, Eric Wasserman, Afua Sarpong Karikari
Abstract: A method of preparing a superabsorbent polymer sheet by polymerization of monomers in the presence of an encapsulated foaming agent and an inorganic foaming agent is provided. According to the method of preparing the superabsorbent polymer sheet of the present invention, a porous and flexible superabsorbent polymer sheet having an excellent initial absorption rate may be prepared.
Type:
Grant
Filed:
April 30, 2019
Date of Patent:
March 22, 2022
Inventors:
Kiyoul Yoon, Hyeon Choi, Gicheul Kim, Seongkyun Kang, Ju Eun Kim
Abstract: The invention relates to specific copolymers obtainable by co-polymerizing at least the following monomers: at least one bicyclic (meth)acrylate ester at least one lower-alkyl (meth)acrylate optionally, and preferably, at least one aromatic vinyl monomer; and optionally other ethylenically unsaturated monomers, whereby the copolymer has a weight averaged molecular weight of from 100,000 to 10,000,000 D, determined using GPC-MALS techniques for a solution in THF at 40° C., as well as to the way to synthesize such copolymers and the use of such polymers to modify the rheology of a liquid in which they are soluble.
Type:
Grant
Filed:
May 19, 2016
Date of Patent:
July 20, 2021
Assignee:
NOURYON CHEMICALS INTERNATIONAL B.V.
Inventors:
John Socrates Thomaides, John M. Morales, Qiwei He, Philip Nigel Threlfall-Holmes, Damien Christian Vadillo, Michael Timothy Philbin
Abstract: Novel methods and materials particularly useful for ophthalmic applications and to methods for making and using the same are disclosed herein. More particularly, relatively soft, optically transparent, foldable, high refractive index materials particularly suited for use in the production of intraocular lenses, contact lenses, and other ocular implants and to methods for manufacturing and implanting IOLs made therefrom are disclosed.
Abstract: A gradient copolymer comprises or consists of n polymer components. The n polymer components each independently represents an addition polymer of a monomer of the formula (I), and/or a mixture thereof, or the n polymer components each independently comprises or consists essential of one or more structural units represented by the formula (I-1), The symbol n represents an integer within the closed interval [5, ?]. The average side chain carbon number of the i-th polymer component as determined according to the nuclear magnetic resonance method is expressed as Xi, with the symbol i representing an arbitrary integer from 1 to n, the relationship X1<X2< . . . <Xn?1<Xn holds.
Type:
Grant
Filed:
June 27, 2017
Date of Patent:
June 8, 2021
Assignees:
CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
Inventors:
Yao Zhang, Qinghua Duan, Kecheng Wei, Yinong Liu, Hongwei Sun
Abstract: A superabsorbent polymer according to the present invention has excellent initial absorption properties, and thus it may be used in sanitary materials such as diapers, etc., thereby exhibiting excellent performances.
Type:
Grant
Filed:
January 5, 2017
Date of Patent:
June 1, 2021
Inventors:
Jun Kyu Kim, Hyung Ki Yoon, Dae Woo Nam, Bo Hyun Seong, Yeon Woo Hong, Seong Beom Heo, Seon Jung Jung, Ji Yoon Jeong, Tae Hwan Jang, Su Jin Kim
Abstract: A block copolymer for use as a dispersant for mineral binder compositions, containing an alkali activating agent. The block copolymer includes at least one first block A and at least one second block B, the first block A containing a monomeric unit M1 and the second block B containing a monomeric unit M2. A proportion of monomeric units M2, if any, in the first block A is less than 25 mol %, in particular less than or equal to 10 mol %, relative to all the monomeric units M1 in the first block A, and a proportion of monomeric units M1, if any, in the second block B is less than 25 mol %, in particular less than or equal to 10 mol %, relative to all the monomeric units M2 in the second block B.
Type:
Grant
Filed:
September 22, 2016
Date of Patent:
April 20, 2021
Assignee:
SIKA TECHNOLOGY AG
Inventors:
Jürg Weidmann, Lukas Frunz, Jörg Zimmermann, Patrick Juilland
Abstract: The invention relates to a specific copolymer obtainable by co-polymerizing at least the following monomers: —at least one bicyclic (meth)acrylate ester —at least one C8-C24-alkyl (meth)acrylate —optionally, and preferably, at least one aromatic vinyl monomer; and —optionally other ethylenically unsaturated monomers, whereby the copolymer has a weight averaged molecular weight from 400,000 to 50,000,000 Dalton, as well as to the way to synthesize them and the use of such polymers to modify the rheology of a liquid in which they are soluble.
Type:
Grant
Filed:
May 19, 2016
Date of Patent:
October 6, 2020
Assignee:
NOURYON CHEMICALS INTERNATIONAL B.V.
Inventors:
John Socrates Thomaides, John M. Morales, Qiwei He, Philip Nigel Threlfall-Holmes, Damien Christian Vadillo, Michael Timothy Philbin
Abstract: Disclosed are a polyacrylate (salt) and a polyacrylate (salt) water-absorbent resin containing a tracer which can be verified back to the manufacturing process of the water-absorbent resin when dealing with various problems with the water-absorbent resin which can occur from the manufacturing process of the water-resistant resin, during the use thereof by a consumer, up until the disposal thereof. The disclosed polyacrylate (salt) and the polyacrylate (salt) water-absorbent resin have a carbon stable isotope ratio (?13C) of at least ?20‰ when measured by accelerator mass spectrometry.
Abstract: A polyacrylic acid (salt), or a polyacrylic acid (salt)-based water-absorbing resin, contains a tracer for detecting various troubles in the water-absorbing resin during the period from the production of the water-absorbing resin to the use and discard thereof by a consumer. The polyacrylic acid (salt)-based water-absorbing resin has a stable carbon isotope ratio, as determined by accelerator mass spectrometry, of less than ?20‰ and a radioactive carbon content of 1.0×10?14 or more. The polyacrylic acid (salt)-based water-absorbing resin has: a CRC of 10 [g/g] or more; an AAP of 20 [g/g] or more; an Ext of 35 wt. % or less; a content of residual monomers of 1,000 ppm or less; a PSD in which the proportion of particles having a particle diameter of 150 ?m or larger but less than 850 ?m is 90 wt. % or more; and an FSR of 0.15 [g/g/s] or more.
Abstract: An object of the present invention is to provide (i) a water absorbent agent composition which has an excellent additional function (a deodorizing function in particular), which stably carries out the additional function even after being stored for a long term, and which is less stressful to skin when used as an absorbent article, (ii) a method for producing the water absorbent agent composition, and (iii) an absorbent core and an absorbent article. The water absorbent agent composition contains: a polycarboxylic acid (salt)-based water absorbent resin as a main component; a natural ingredient; and a temporal deterioration preventing agent. Further, a water absorbent agent composition is produced by simultaneously or separately mixing a natural ingredient and a temporal deterioration preventing agent with a water absorbent resin which is a crosslinked polymer of unsaturated monomers having carboxylic acid and/or a salt thereof.
Abstract: The disclosed process for continuously producing a water-absorbing resin comprising a plurality of joined continuous steps; a polymerization step of polymerizing an aqueous unsaturated monomer solution, a drying step of drying a particulated water-containing gel-like crosslinked polymer obtained in a finely crushing step during the polymerization or after the polymerization, a pulverizing step after the drying, a classification step after the drying, and a surface treatment step for the water-absorbing resin powder after the classification step. In the process, with some of the above steps kept running, the other steps are interrupted, and subsequently all the steps are restarted.
Abstract: Methods for forming an OLED device are described. An encapsulation structure having organic buffer layer and an interface layer disposed on the organic buffer layer sandwiched between barrier layers is deposited over an OLED structure. In one example, an OLED device includes a first barrier layer disposed on a region of a substrate having an OLED structure disposed thereon, a fluorinated buffer layer including a polymer material containing fluorine disposed on the first barrier layer, an interface layer including the polymer material on the fluorinated buffer layer, and a second barrier layer disposed on the interface layer.
Abstract: In a water-absorbent resin production apparatus for producing a water-absorbent resin by polymerizing a water-soluble ethylenically unsaturated monomer, a water-absorbent resin powder obtained by drying a water-absorbent resin composition with a dryer passes through a first powder flow path pipe, is discharged therefrom toward a classifier while a flow rate is regulated so as to a predetermined value by a powder flow rate regulating discharge member composed of a hopper and a rotary valve, and is classified by the classifier. In the water-absorbent resin production apparatus, a collector for collecting a powder aggregate composed of aggregated particles of the water-absorbent resin powder is disposed in the first powder flow path pipe. Accordingly, a water-absorbent resin in the form of a particulate powder from which the powder aggregate is removed can be produced at a high production efficiency.
Abstract: Novel methods and materials particularly useful for ophthalmic applications and to methods for making and using the same are disclosed herein. More particularly, relatively soft, optically transparent, foldable, high refractive index materials particularly suited for use in the production of intraocular lenses, contact lenses, and other ocular implants and to methods for manufacturing and implanting IOLs made therefrom are disclosed.
Abstract: Provided is a method for producing a polyacrylic acid (salt)-based water absorbent resin, which is a convenient production method for a water absorbent resin for an absorbent suitable for practical use, the water absorbent resin having a reduced amount of residual monomers.
Abstract: The present invention provides a method for producing, by adding an additive and/or gas bubbles to a monomer with high efficiency, a polyacrylic acid (salt)-based water-absorbing resin having high physical properties while high productivity is maintained. The step of preparing an aqueous monomer solution includes the steps of: preparing an aqueous solution; and adding a water-insoluble additive and/or gas bubbles. A retention time from when the water-insoluble additive and/or the gas bubbles is/are added to when polymerization starts is 1 second to 60 seconds.
Abstract: Plant oil-based compounds are provided which possess both low viscosity and high reactive functionality. These compounds are useful in coating and composite applications, as well as related methods. Exemplary compounds can be produced by transesterification of a plant oil triglyceride with a nucleophile reactant, such as a vinyl-functional alcohol, to yield reactive fatty acid-containing monomers.
Type:
Grant
Filed:
January 13, 2014
Date of Patent:
December 5, 2017
Assignee:
NDSU RESEARCH FOUNDATION
Inventors:
Bret Ja Chisholm, Harjyoti Kalita, Samim Alam, Andrey Chernykh
Abstract: A fluidizing composition in the form of a liquid or in the form of a powder including at least one superplasticizer chosen from polycarboxylate ethers, characterized in that it includes from 1 to 20 parts by weight of at least one aromatic hydrocarbon sulfonic acid or one of its salts chosen from alkali salts, alkaline-earth salts or one of their mixtures, for 100 parts by weight of the superplasticizer. A method for preparing such fluidizing composition, a dry mortar incorporating the fluidizing composition, as well as plasters prepared from the dry mortar are also described.
Type:
Grant
Filed:
November 7, 2014
Date of Patent:
November 28, 2017
Assignee:
KERNEOS
Inventors:
Pascal Boustingorry, Philippe Maitrasse, Jean-Noel Bousseau, Pascal Taquet, Jacques Estival
Abstract: An amphoteric betaine-type polycarboxylic acid water reducer and a preparation method therefor are provided in the present invention. An unsaturated betaine-type monomer A and an acrylic acid-type polyethylene glycol monomer B are placed in a reaction container, stirred until uniform and then an acrylic acid-type monomer C is added, the stirring is continued and water is added to make adjustments so as to make the total mass of the monomers account for 10%-20% of the total mass of the aqueous solution; and under the protection of an inert gas, the temperature is raised to 60° C.-100° C., an aqueous initiator solution is added, maintaining the temperature and reacting for 4-6 h, and after the reaction is completed, the solution is cooled to room temperature, and the pH value thereof is adjusted to 5-7 to prepare the amphoteric betaine-type polycarboxylic acid water reducer.
Abstract: The physical properties of a water-absorbing resin with low residual monomer content are improved or stabilized, without sacrifices in productivity, production cost, stability, etc. Provided is a water-absorbing resin with low residual monomer content and excellent whiteness, wherein a water-absorbing resin consumed in large quantities in disposable diapers, etc., is preferably a sustainable and renewable water-absorbing resin that does not require excessive purification of the acrylic acid, particularly acrylic acids derived from non-fossil sources, that is the starting material of the water-absorbing resin. Disclosed is a method of manufacturing a hydrophilic polyacrylic acid (salt) resin, which is a method of manufacturing a water-absorbing polyacrylic acid resin that comprises a step in which a monomer is prepared from acrylic acid, a step in which said monomer is polymerized, and a step in which the resulting hydrous gel is dried.
Abstract: The present invention relates to an absorbent suitable for use in a thin sanitary material/absorbent article having a high absorbent content and not prone to gel blocking, the absorbent having excellent liquid diffusibility (e.g. SFC) and minimal decrease in absorption ratio under pressure (e.g., AAP or PUP) even when a liquid permeation enhancer is added, and to a method for manufacturing the high-performance absorbent stably during actual production. The method is a method for manufacturing a polyacrylic acid (salt)-based absorbent, having a surface-crosslinking agent addition step for adding a solution of a surface-crosslinking agent, and a liquid permeation enhancer addition step for adding a liquid permeation enhancer, the liquid permeation enhancer addition step being performed after and/or at the same time as the surface-crosslinking agent addition step, the method characterized in that a surface crosslinking step for performing heat treatment in an atmosphere having a dew point of 45° C. to 100° C.
Abstract: Described herein are copolymers, and methods of making and utilizing such copolymers. Such copolymers have at least two blocks: a first block that has at least one unit that is hydrophilic at physiologic pH, and a second block that has hydrophobic groups. This second block further has at least one unit with a group that is anionic at about physiologic pH. The described copolymers are disruptive of a cellular membrane, including an extracellular membrane, an intracellular membrane, a vesicle, an organelle, an endosome, a liposome, or a red blood cell. Preferably, in certain instances, the copolymer disrupts the membrane and enters the intracellular environment. In specific examples, the copolymer is endosomolytic.
Type:
Grant
Filed:
May 13, 2009
Date of Patent:
October 25, 2016
Assignees:
University of Washington, PhaseRx, Inc.
Inventors:
Patrick S. Stayton, Allan S. Hoffman, Anthony J. Convertine, Danielle Benoit, Craig L. Duvall, Paul H. Johnson, Anna S. Gall
Abstract: Process for preparing polyacrylates, by the free-radical polymerization of monomer mixtures comprising at least 70% by weight of at least one acrylic and/or methacrylic ester in the presence of amino acids as regulator substances, and reaction solution comprising one or more solvents and one or more monomers, at least 50% by weight of the solvents being organic solvents, and at least 70% by weight of the monomers being acrylic and/or methacrylic esters, with at least one amino acid being present.
Abstract: The present invention provides a dispersant for a hydraulic composition containing N-methyldiethanolamine and a specific (meth)acrylic acid copolymer as a polycarboxylic acid copolymer dispersing agent to increase the fluidity of a hydraulic composition.
Type:
Grant
Filed:
March 14, 2012
Date of Patent:
May 31, 2016
Assignee:
KAO CORPORATION
Inventors:
Keiichiro Sagawa, Masaaki Shimoda, Koji Nagasawa
Abstract: In a composition aspect of the invention, a nanoparticle coating comprises repeating polyacrylic acid monomers covalently bound together in an aliphatic chain having a plurality of carboxylic acid functional groups and modified carboxylic acid functional groups extending therefrom. A first portion of the modified carboxylic acid functional groups are modified by a PEG oligomer having a terminal methoxy functional group and a second portion of the modified carboxylic acid functional groups are modified by a PEG oligomer having at least one terminal catechol group.
Type:
Grant
Filed:
February 21, 2013
Date of Patent:
April 12, 2016
Assignee:
The Florida State University Research Foundation, Inc.
Inventors:
Hedi Mattoussi, Goutam Palui, Hyon Bin Na
Abstract: A method for producing a water-absorbent resin includes a polymerization step of polymerizing a polymerizable component containing a water-soluble ethylenically unsaturated monomer dissolved in water using a water-soluble azo-type radical polymerization initiator to obtain a reaction system including a water-absorbent resin precursor, and a dehydration step of removing water from the reaction system by heating. In the dehydration step, a water-soluble radical polymerization initiator is added to the reaction system at any first dehydration stage when the residual water rate calculated by the formula (1) is 50% or more, and a reducing substance is added to the reaction system at any second dehydration stage when the residual water rate decreases from that at the first dehydration stage by 10% or more. According to this production method, a water-absorbent resin having satisfactory water-absorption capacity can be produced while suppressing the content of residual monomers.
Abstract: The present invention provides a crosslinked polyethylene sealing material sheet for a solar-cell module offering exceptional heat resistance, wherein the sealing material sheet is provided with high metal-adhesion performance. A sealing material sheet for a solar-cell module comprises a sealing material sheet composition for a solar-cell module containing a polyethylene resin in a concentration of 0.900 g/cm3 or less, glycidyl methacrylate (GMA), a radical polymerization initiator, and triallyl isocyanurate (TAIC), wherein the GMA content of the sealing material sheet is 0.15 to 3.0% by mass, the TAIC content of the sealing material sheet is 0.15 to 3.0% by mass, and the radical polymerization initiator content of the sealer is 0.01 to 2.5% by mass.
Abstract: A method for producing a water-absorbent resin by a reversed-phase suspension polymerization method, includes step 1 of dispersing a first aqueous solution containing a partially neutralized product (A) of a water-soluble ethylenically unsaturated monomer having acid groups in the molecule in a petroleum-type hydrocarbon dispersion medium in the presence of a dispersing agent, and then polymerizing the resulting dispersion to obtain a slurry containing primary particles of a polymer, and step 2 of adding a second aqueous solution containing a partially neutralized product (B) of a water-soluble ethylenically unsaturated monomer having acid groups in the molecule to the slurry obtained in step 1, and then polymerizing the mixture to obtain a slurry in which the primary particles are agglomerated. In the method, a molar neutralization degree X of the partially neutralized product (A) and a molar neutralization degree Y of the partially neutralized product (B) are defined.
Type:
Grant
Filed:
January 23, 2012
Date of Patent:
June 23, 2015
Assignee:
SUMITOMO SEIKA CHEMICALS CO., LTD.
Inventors:
Masayoshi Handa, Koji Ueda, Kimihiko Kondo
Abstract: Provided is a water absorbent resin having excellent liquid permeability, water absorbent speed, anti-impact stability, and weather resistance. Provided is a polyacrylic acid (salt)-based water absorbent resin powder in which the water absorption capacity without load (CRC) is 30 to 45 [g/g], the water absorption capacity under load (AAP 0.3) is 20 to 35 [g/g], the water absorption capacity under load (AAP 0.7) is 10 to 28 [g/g], and the weight average particle diameter (D50) is 300 to 500 ?m, characterized by including p-methoxyphenol; having a degradable soluble component (0.05% L-A (saline) for 2 hours/60° C., one hour extraction rinse/room temperature) of 40% by weight or less; and having a internal gas bubbles ratio of 0.1 to 2.5%, as specified by the following equation.
Abstract: Articles containing soil adsorbing polymers, and more particularly, articles, for example nonwovens, such as paper towels, wovens, and/or sponges and/or article-forming components thereof that comprise a durably bonded soil adsorbing polymer, article-forming components used to make such articles, and processes for making same are provided.
Type:
Application
Filed:
November 20, 2014
Publication date:
May 28, 2015
Inventors:
Robin Lynn McKIERNAN, Robert Joseph McCHAIN, Steven Daryl SMITH
Abstract: The present invention relates to a production method for efficiently obtaining an acrylic acid-based polymer having a narrow molecular mass distribution and a low molecular mass, without using a large amount of chain transfer agent. A method for continuously producing an acrylic acid-based polymer obtained by continuously polymerizing a monomer having acrylic acid as an essential component, characterized in that a liquid feed pump applies a mechanical load of 0.5 to 2.5 kJ/L to the liquid discharged from the outlet of a reactor. An acrylic acid-based polymer having fewer high-molecular-mass components, excellent dispersion and other properties, and a low molecular mass is thereby obtained.
Abstract: A process for producing water-absorbing polymer particles by polymerizing droplets of a monomer solution in a surrounding gas phase in a reaction chamber, wherein the monomer solution is metered into the reaction chamber via at least one bore, and the diameter is from 210 to 290 ?m per bore and the metering rate is from 0.9 to 5 kg/h per bore.
Type:
Grant
Filed:
August 29, 2013
Date of Patent:
May 12, 2015
Assignee:
BASF SE
Inventors:
Marco Krüger, Stefan Blei, Wilfried Heide, Matthias Weismantel, Uwe Stueven
Abstract: As associative thickener obtainable by free radical polymerization, the preparation thereof and the use thereof in paper coating slips are described. The associative thickener is formed from (a) acid monomers selected from ethylenically unsaturated C3- to C8-carboxylic acids, (b) associative monomers of the general formula H2C?CR1—COO-(EO)n—(PO)m—R2, in which R1 is hydrogen or methyl, n is a number of at least two, m is a number from zero to 50, EO is an ethylene oxide group, PO is a propylene oxide group and R2 is a C8-C30-alkyl group or a C8-C30-alkaryl group, and (c) nonionic, copolymerizable monomers differing from a) and b), the reaction product having been reacted, after the polymerization, with initiators forming nonionic radicals.
Type:
Grant
Filed:
February 1, 2011
Date of Patent:
May 5, 2015
Assignee:
BASF SE
Inventors:
Philipp Zacharias, Hermann Seyffer, Ilshat Gubaydullin, Harutyun Hanciogullari, Marc Bothe
Abstract: A process for the production of methacrylic acid or esters thereof by the base catalysed decarboxylation of at least one dicarboxylic acid selected from itaconic, citraconic or mesaconic acid or mixtures thereof in an aqueous reaction medium is described. The decarboxylation is carried out at a temperature in the range from 200° C. and up to 239° C. The methacrylic acid is isolated from the aqueous reaction medium by a purification process which does not include introducing an organic solvent to the aqueous reaction medium for solvent extraction of the methacrylic acid into an organic phase. A method of preparing polymers or copolymers of methacrylic acid or methacrylic acid esters is also described.
Type:
Application
Filed:
April 26, 2013
Publication date:
April 30, 2015
Inventors:
Graham Ronald Eastham, David William Johnson, Mark Waugh
Abstract: The invention provides an adhesive composition for conduction between electrical elements, comprising 25 to 46 parts by weight of nitrile-butadiene rubber with Mooney viscosity ranged from 50 to 75 (ML 1+4@100)° C., 25 to 45 parts by weight of acrylic oligomer, 16 to 32 parts by weight of thermoplastic resin, two organic peroxides having different one-minute half-life temperatures from each other, and a coupling agent. The thermoplastic resin is selected from the group consisting of phenoxy resin, poly(methyl)methacrylate copolymer, polystyrene copolymer and Novolak resin.
Abstract: A catalyst composition is provided. The composition comprises at least 30 percent by weight of a catalyst compound based on the total weight of solids in the catalyst composition; and a polymer prepared from ethylenically unsaturated monomers. The polymer either (i) has a backbone derived from substantially hydrophilic monomers and/or monomers containing groups that may be rendered substantially hydrophilic after polymerization, and a plurality of side chains along the backbone derived from substantially hydrophobic monomers, or (ii) has a backbone derived from substantially hydrophobic monomers and a plurality of side chains along the backbone derived from substantially hydrophilic monomers and/or monomers containing groups that may be rendered substantially hydrophilic after polymerization. The catalyst compound is contained within or encapsulated by the polymer. Methods of preparing the catalyst composition and curable compositions containing the catalyst composition are also provided.
Type:
Grant
Filed:
November 8, 2013
Date of Patent:
April 28, 2015
Assignee:
PPG Industries Ohio, Inc.
Inventors:
Scott Moravek, Davina Schwartzmiller, Steven V. Barancyk, David Fenn
Abstract: The purpose of the present invention is to provide a method for producing a water absorbent resin having improved physical properties, particularly, improved saline flow conductivity (SFC) and less amount of fine powder.
Type:
Grant
Filed:
November 16, 2012
Date of Patent:
April 21, 2015
Assignee:
Nippon Shokubai Co., Ltd.
Inventors:
Koji Tachi, Hironori Sato, Kazushi Torii, Hiroyuki Ikeuchi
Abstract: The application relates to the particulate water absorbing agent of the present invention composed primarily of a polyacrylic acid- or polyacrylate-based water absorbing resin and containing a chelating agent and a phosphorous compound. Accordingly, the particulate water absorbing agent composed primarily of a water absorbing resin achieves both excellent water absorbing properties and anti-coloring effect which would normally be incompatible. A particulate water absorbing agent for absorbent core is provided that is suitable for actual use.
Abstract: Processes for making water-absorbent cross-linked polymers, such as polyacrylic acids/polyacrylates, using supercritical medium; and water-absorbent polymers, e.g. particles thereof, obtained by such processes, where such particles may be porous.
Type:
Grant
Filed:
October 31, 2011
Date of Patent:
April 14, 2015
Assignee:
The Procter & Gamble Company
Inventors:
Thomas Tombuelt-Meyer, Axel Meyer, Torsten Lindner
Abstract: The present invention relates to a resin mixture for melt processing, comprising a first resin; and a second resin comprising an acrylate-based copolymer including silica particles and having a polydispersity index (PDI) of 1 to 2.5, a method for preparing a resin-molded article using the same, and a resin-molded article. Surface characteristics of the molded article can be improved and excellent scratch resistance can be obtained by using the resin composition. In addition, processing time can be reduced, productivity is increased, and manufacturing costs are lowered by omitting the additional surface coating step.
Type:
Grant
Filed:
October 14, 2011
Date of Patent:
April 7, 2015
Assignee:
LG Chem, Ltd.
Inventors:
Jin Young Ryu, Houng Sik Yoo, Hak Shin Kim, Eun Joo Choi, Young Jun Hong
Abstract: A process for the production of methacrylic acid by the base catalysed decarboxylation of at least one dicarboxylic acid selected from itaconic, citraconic or mesaconic acid or mixtures thereof is described. The decarboxylation is carried out at a temperature in the range from 100 to 199° C. A method of preparing polymers or copolymers of methacrylic acid or methacrylic acid esters is also described.
Type:
Application
Filed:
April 26, 2013
Publication date:
April 2, 2015
Inventors:
Graham Ronald Eastham, David William Johnson, Mark Waugh
Abstract: The present invention relates to methods of processing lignocellulosic material to obtain hemicellulose sugars, cellulose sugars, lignin, cellulose and other high-value products. Also provided are hemicellulose sugars, cellulose sugars, lignin, cellulose, and other high-value products.
Type:
Application
Filed:
May 3, 2013
Publication date:
March 26, 2015
Inventors:
Robert Jansen, Claire Gregoire, philip Travisano, Lee Madsen, Neta Matis, Yael Har-Tal, Shay Eliahu, James Alan Lawson, Noa Lapidot, Luke Burke, Aharon M. Eyal, Timothy Allen Bauer, Hagit Sade, Paul Mcwilliams, Ziv-Vladimir Belman, Bassem Hallac, Michael Zviely, Yelena Gershinksy, Adam Carden
Abstract: An absorbent core (28), for use in an absorbent article, comprising a core wrap (16, 16?) enclosing an absorbent material (60) comprising superabsorbent polymer particles. The core wrap comprises a top side (16) and a bottom side (16?), and the absorbent core comprises one or more area(s) (26) substantially free of absorbent material through which the top side of the core wrap is attached to the bottom side of the core wrap, so that when the absorbent material swells the core wrap forms one or more channel(s) (26?) along the area(s) (26) substantially free of absorbent material. The superabsorbent polymer particles have a time to reach an uptake of 20 g/g (T20) of less than 240 s as measured according to the K(t) test method.
Type:
Application
Filed:
August 19, 2014
Publication date:
March 19, 2015
Inventors:
Andrea PERI, Aniruddha CHATTERJEE, Peter DZIEZOK, Bruno Johannes EHRNSPERGER, Juliane KAMPHUS, Marion LUTSCHE
Abstract: The present invention provides a latex resin composition for rubber gloves without sulfur and a vulcanization accelerator and a method of manufacturing dip-formed article using the composition. The composition comprises a conjugated diene monomer; an ethylenically unsaturated nitrile monomer; an ethylenically unsaturated acid monomer; an ethylenically unsaturated monomer copolymerizable with the ethylenically unsaturated nitrile monomer and the ethylenically unsaturated acid monomer; and a reactive compound including two or more reactive groups. According to the manufacturing method, productivity is improved by omitting a long maturation process included in a traditional glove manufacturing process; not only an adverse effect caused by traditional sulfur and vulcanization accelerator is reduced but also rubber gloves with excellent physical properties can be provided.
Type:
Grant
Filed:
August 10, 2009
Date of Patent:
March 10, 2015
Assignee:
LG Chem, Ltd.
Inventors:
Byoung Yun Kim, Jung Su Han, Ho Yeul Choi, Seung Hun Yang, Jung Eun Kim, Chang Sun Han