With Hydrocarbon Monomer Patents (Class 526/318.6)
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Publication number: 20100096072Abstract: A support material feedstock comprising a first copolymer and a polymeric impact modifier, where the first copolymer includes a first monomer unit comprising a carboxyl group and a second monomer unit comprising a phenyl group.Type: ApplicationFiled: July 24, 2009Publication date: April 22, 2010Applicant: STRATASYS, INC.Inventors: Paul E. Hopkins, William R. Priedeman, JR., Jeffrey F. Bye
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Patent number: 7691260Abstract: The present invention provides method for recovering fossil-based materials from oil sources using multifunctional, multipolymeric continuous composition spectrum surfactant mixtures. The invention also provides methods for reducing the loss of volatile organic compounds (VOCs) from oil storage containers using multifunctional, multipolymer surfactants. The multifunctional, multipolymer surfactants are characterized by a hydrophobic part and a hydrophilic part. The hydrophobic part of the polymer surfactants includes functionalities that impart a polarity of greater than 0 Debye to the hydrophobic part. The polymer surfactants are further characterized by molecular weights that are above their entanglement weights. The result is polymer surfactants and their continuous composition surfactant-thickener mixtures with demulsifying characteristics.Type: GrantFiled: February 9, 2007Date of Patent: April 6, 2010Assignee: Nanochemical Oil CompanyInventor: Gerard Caneba
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Patent number: 7683128Abstract: The present invention provides an ionomer composition for a golf ball providing a golf ball which is excellent in abrasion-resistance, durability and resilience, and a golf ball using the same. An ionomer composition for a golf ball of the present invention comprises a binary copolymer obtained by copolymerizing an olefin monomer having 2 to 8 carbon atoms with an unsaturated monomer having an acid functional group and/or a ternary copolymer obtained by copolymerizing an olefin monomer having 2 to 8 carbon atoms, an unsaturated monomer having an acid functional group and an unsaturated carboxylic acid ester, wherein a functional group is introduced in both terminals of the copolymers.Type: GrantFiled: January 9, 2007Date of Patent: March 23, 2010Assignee: SRI Sports LimitedInventors: Toshiyuki Tarao, Takashi Sasaki, Satoko Okabe
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Patent number: 7666963Abstract: Hybrid copolymers for use as anti-scalant and dispersant. The polymers are useful in compositions used in aqueous systems. The polymers include at least one synthetic monomeric constituent that is chain terminated by a naturally occurring hydroxyl containing moiety. A process for preparing these hybrid copolymers is also provided.Type: GrantFiled: July 18, 2006Date of Patent: February 23, 2010Assignee: Akzo Nobel N.V.Inventors: Klin A. Rodrigues, Darin K. Griffith
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Publication number: 20100041840Abstract: The present invention relates to a method for preparing an unsaturated ethylene-diene copolymer by high pressure radical-initiated polymerisation, said method providing an improved conversion of added diene into pendant vinyl groups.Type: ApplicationFiled: November 6, 2007Publication date: February 18, 2010Inventors: Kenneth Johansson, Peter Rydin, Annika Smedberg
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Publication number: 20090324836Abstract: The present invention provides an industrially advantageous method for producing an unsaturated carboxylic acid-modified vinyl alcohol polymer, and a gas barrier film obtained by using the same.Type: ApplicationFiled: May 31, 2007Publication date: December 31, 2009Applicant: TOHCELLO CO., LTD.Inventors: Kou Tsurugi, Yoshihisa Inoue, Isao Hara, Hiroyoshi Watanabe, Tomoyoshi Hakamata, Akira Nomoto, Osamu Nakamura
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Publication number: 20090318647Abstract: This invention relates to a process to functionalize propylene co-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene a co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(?0.94 (mol % ethylene incorporated)+100), when 10 to 60 mol % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mol % ethylene is present in the co-oligomer, and 3) X=(1.83*(mol % ethylene incorporated)?83), when 70 to 90 mol % ethylene is present in the co-oligomer.Type: ApplicationFiled: June 19, 2009Publication date: December 24, 2009Inventors: John R. Hagadorn, Matthew W. Holtcamp, Andrew G. Narvaez, JR., Donna J. Crowther, Patrick Brant
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Publication number: 20090270551Abstract: There is disclosed a polymer (Polymer P) which is obtained and/or is obtainable from a monomer composition comprising (a) from about 5% to about 95% by weight of at least one C2-12alkyl acrylate; (b) from about 2.5% to about 60% by weight of at least one polymer precursor selected from the group consisting of: C1-30 alkyl(meth)acrylates, C2-30 vinyl aromatic compounds, C2-30 vinyl halides, C2-30 vinyl nitriles, C2-30 vinyl esters of carboxylic acids and mixtures thereof; with the provisos that (i) the homopolymers of each of said polymer precursor(s) have a Tg above about ?25° C.; and (ii) each of said polymer precursor(s) comprises other than a functional group selected from the group consisting of: hydroxy, carboxy, acid anhydride, nitro, epoxy and amino; (c) from about 0.Type: ApplicationFiled: September 7, 2006Publication date: October 29, 2009Inventors: Olivier Dupont, Singa Tobing, Hui Liu
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Patent number: 7605211Abstract: The present invention provides a golf ball with excellent abrasion-resistance, durability and resilience having an ionomer resin cover therein. The ionomer composition for the golf ball of the invention comprises a reaction product obtained by reacting a telechelic copolymer having functional groups introduced in both terminals of a binary copolymer formed by copolymerizing an olefin monomer having 2 to 8 carbon atoms and an unsaturated carboxylic acid having 2 to 18 carbon atoms, and/or a ternary copolymer formed by copolymerizing an olefin monomer having 2 to 8 carbon atoms, an unsaturated carboxylic acid having 2 to 18 carbon atoms and an unsaturated carboxylic acid ester with a hydroxyl group-containing compound or an isocyanate group-containing compound, wherein at least 10 mole % of a carboxylic group in said reaction product is neutralized with an inorganic metal.Type: GrantFiled: January 9, 2007Date of Patent: October 20, 2009Assignee: SRI Sports LimitedInventors: Satoko Okabe, Takashi Sasaki, Toshiyuki Tarao
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Publication number: 20090239050Abstract: A methacrylic resin comprising 80 to 98.5 wt % of methyl methacrylate monomer unit and 1.5 to 20 wt % of at least one different vinyl monomer unit copolymerizable with methyl methacrylate, characterized in that the methacrylic resin has a weight average molecular weight measured by gel permeation chromatography (GPC) of 60,000 to 230,000 and comprises 7 to 30% of a component having a weight average molecular weight of ? or less of a peak weight average molecular weight (Mp) obtained from a GPC elution curve based on the methacrylic resin component.Type: ApplicationFiled: November 17, 2006Publication date: September 24, 2009Applicant: Asahi Kasei Chemicals CorporationInventors: Naoki Azuma, Kohei Okumura, Kazunori Kozawa
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Publication number: 20090221729Abstract: This invention provides a water-soluble macromonomer having terminal unsaturation obtained by polymerization of monomers in the presence of inclusion complex of chain transfer agent in aqueous system. Hydrophobic chain transfer agent AMSD forms an inclusion complex with methylated cyclodextrin. The complexation enhances its solubility in water and enables the polymerization of water-soluble monomers in aqueous medium. After polymerization cyclodextrin is removed and the macromer with terminal unsaturation obtained can be used further for copolymerization with any vinyl monomer.Type: ApplicationFiled: March 28, 2007Publication date: September 3, 2009Applicant: COUNCIL OF SCIENTIFIC AND INDUSTRIAL RESEARCHInventors: Mohan Gopalkrishna Kulkarni, Prerana Maruti Patil
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Publication number: 20090186231Abstract: A method of coating surfaces of plastic or metal, which comprises treating the plastic or metal surface in question with an aqueous dispersion comprising (A) at least one ethylene copolymer having a molecular weight Mn in the range from 2000 to 20 000 g/mol, selected from ethylene copolymers comprising as comonomers in copolymerized form (a) 15.5% to 19.9% by weight of at least one ethylenically unsaturated C3-C10 carboxylic acid and (b) 80.1% to 84.5% by weight of ethylene, (B) at least one base, in one step and subsequently providing in at least one further step the metal or plastic surface in question with at least one further coat.Type: ApplicationFiled: May 22, 2007Publication date: July 23, 2009Applicant: BASF SEInventors: Heike Pfistner, Andreas Fechtenkotter, Frank-Olaf Mähling, Helmut Witteler, Frank Dietsche, Stefan Fassbender, Claudia Simon
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Publication number: 20090076233Abstract: A novel hybrid polymer has a structure in which a polyolefin segment and a polar polymer segment are connected not via a bonding group containing a heteroatom. A method of the invention produces the hybrid polymer with industrial advantages. The hybrid polymer includes a polyolefin segment (A) and a polar polymer segment (B), the polar polymer segment being obtained by radical polymerization of a radically polymerizable monomer.Type: ApplicationFiled: February 21, 2006Publication date: March 19, 2009Applicant: MITSUI CHEMICALS, INC.Inventors: Hideyuki Kaneko, Shinichi Kojoh, Nobuo Kawahara, Shingo Matsuo, Tomoaki Matsugi, Norio Kashiwa
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Publication number: 20090040618Abstract: An object of the present invention is to provide a light diffuser plate (1) which can illuminate the front side more brightly when incorporated in a surface light source (3) constituting a transmissive image display (2). The light diffuser plate of the present invention comprises a transparent resin and a light diffuser dispersed in the transparent resin, wherein the transparent resin is a transparent resin which has a light transmittance [T600] at a wavelength of 600 nm of 85% or more measured with respect to a thickness of a 2 mm thick plate-shaped specimen, and a ratio [T365/T600] of a light transmittance [T365] at a wavelength of 365 nm to the light transmittance [T600] is 0.90 to 0.99. The transparent resin is polystyrene or the like, an average particle diameter of the light diffuser is from 0.5 to 5 ?m, an absolute value [|?n|] of a difference in a refractive index between the light diffuser and the transparent resin is 0.05 or more, an amount of the light diffuser is from 0.Type: ApplicationFiled: August 7, 2008Publication date: February 12, 2009Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventor: Hironobu Iyama
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Publication number: 20090005529Abstract: A s,s?-bis-(?,??-disubstituted-??-acetic acid)-trithiocarbonate and derivatives thereof can be used as an initiator, chain transfer agent, or terminator for polymerization of monomers such as free radical polymerizable monomers. Homopolymers, copolymers, and the like as well as block copolymers can be made utilizing the trithio carbonate compound such as in a living free radical polymerization as well as to form telechelic polymers.Type: ApplicationFiled: October 9, 2007Publication date: January 1, 2009Inventor: John T. Lai
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Publication number: 20080275203Abstract: The present invention relates to resin compositions for radical curing comprising a component (I) containing reactive carbon-carbon unsaturations and a component (II) containing XH-groups, with X not being C or O, which resin compositions (a) are substantially free of photoinitiators; (b.) have an average number of reactive carbon-carbon unsaturations of component (I) higher than 2; (c) have an average number of XH-groups of component (II) equal to or higher than 2, with at least one of the XH-groups of the XH-component being a thiol group, and; (d) whereby at least one of the average numbers of (b) and (c) is higher than 2; (e) and at most 5 mol % of the reactive unsaturations is capable of undergoing homopolymerisation; (f) respectively is present in the form of a mono-ene functional alkylene; and (g) the molar ratio of the XH-groups and of the reactive unsaturations is in the range of from 4:1 to 1:4; with the proviso that the RU component is not tris-(norborn-5-ene-2-carboxy) propoxypropane.Type: ApplicationFiled: April 6, 2005Publication date: November 6, 2008Inventors: Johan Franz Gradus Antonius Jansen, Michael Alphonsus Cornelis Johannes Van Dijck, Marco Marcus Matheus Driessen
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Publication number: 20080269447Abstract: Disclosed is a method of preparing hollow particles comprising polymerizing a hydrophobic monomer to form a particulate resin exhibiting a number average molecular weight of from 20,000 to 500,000, dispersing the particulate resin in an aqueous medium to form a resin particle dispersion and adding thereto a hydrophobic cross-linkable monomer in an amount of from 0.1 to 50 parts by mass based on 1 part by mass of the particulate resin to polymerize the cross-linkable monomer to form hollow particles.Type: ApplicationFiled: March 6, 2008Publication date: October 30, 2008Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.Inventors: Aya SHIRAI, Mitsutoshi NAKAMURA, Tatsuya NAGASE, Motoi NISHIMURA
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Publication number: 20080242809Abstract: The invention relates to a process for the preparation of a copolymer of ethylene and a monomer copolymerisable therewith. The polymerisation takes place in a tubular reactor at a peak temperature between 290° C. and 350° C., the co monomer is a di- or higher functional (meth)acrylate and the co monomer is applied in an amount between 0.008 mol % and 0.200 mol % relative to the amount of ethylene copolymer.Type: ApplicationFiled: February 27, 2006Publication date: October 2, 2008Inventors: Peter Neuteboom, Geert Imelda Valerie Bonte, Jacobus Christinus Josephus Franciscus Tacx, Marcellinus Guilliame Marie Neilen
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Publication number: 20080234456Abstract: The present invention aims at providing a stretched film of an olefin polymer excellent in anti-static property, which is obtained from an olefin polymer composition comprising an olefin polymer and potassium salt of an ethylene-unsaturated carboxylic acid copolymer, and a gist in construction resides in a stretched film of an olefin polymer, which has been obtained from an olefin polymer composition (C) comprising an olefin polymer (A) and potassium salt of an ethylene-unsaturated carboxylic acid copolymer (B) and has been stretched at a stretching factor in terms of plane factor of at least 3 times. Stretching is preferably biaxially stretching and the olefin polymer composition (C) is preferably comprised of 99-60% by weight of the olefin polymer (A) and 1-40% by weight of potassium salt of an ethylene-unsaturated carboxylic acid copolymer (B).Type: ApplicationFiled: December 20, 2005Publication date: September 25, 2008Applicant: Dupont-Mitsui Polychemicals Co., Ltd.Inventors: Tohru Sawai, Masaru Shimizu, Masanobu Sato
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Publication number: 20080051541Abstract: According to an aspect of the present invention, implantable or insertable medical devices are provided that contain at least one covalently crosslinked polymeric region, which contains at least one block copolymer comprising at least one low Tg block and at least one high Tg block.Type: ApplicationFiled: June 1, 2007Publication date: February 28, 2008Inventors: Frederick H. Strickler, Mark Boden
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Publication number: 20080051542Abstract: According to an aspect of the present invention, implantable or insertable medical devices are provided, which contain at least one polymeric region in contact with a metallic region. The polymeric region contains at least one block copolymer that contains at least one low Tg block and at least one high Tg block. The polymeric region contains at least one polymer that contains at least one adhesion promoting group selected from one or more of halo-silane, alkoxy-silane, epoxy, anhydride, phenoxy, hydroxyl, amino, sulfonate and carboxyl groups, which at least one polymer may correspond to the block copolymer, a supplemental polymer, or both.Type: ApplicationFiled: June 1, 2007Publication date: February 28, 2008Inventor: Frederick H. Strickler
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Patent number: 6903157Abstract: A thickened aqueous coating composition (preferably paints and the like or adhesives) containing a film-forming polymeric binder which produces dried coatings having less sensitivity to water by using a thickener which is autoxidisable. Preferred autoxidisable moieties are provided by derivatives of long chain fatty acids of the type used in alkyd paints and association is the preferred thickener mechanism. The moieties may form part of a compound which can take part in a copolymerisation to form a polymeric backbone for the thickener and if the compound is not very soluble in water, the copolymerisation mixture is subjected to intensive agitation to form droplets of less than 500 nm which compensates for the lack of solubility. The thickener may serve as its own binder if sufficient amounts are used.Type: GrantFiled: July 19, 2001Date of Patent: June 7, 2005Assignee: Imperial Chemical Industries PLcInventors: Manish Sarkar, Stephane Patrick Belmudes
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Patent number: 6894134Abstract: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc.Type: GrantFiled: June 22, 2001Date of Patent: May 17, 2005Assignees: E. I. duPont de Nemours and Company, University of North Carolina at Chapel HillInventors: Maurice S. Brookhart, Lynda Kaye Johnson, Christopher Moore Killian, Elizabeth Forrester McCord, Stephan James McLain, Samuel David Arthur
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Patent number: 6835269Abstract: A laminated film exhibiting excellent interlayer adhesiveness obtained by extrusion-laminating a resin directly on a polyester film without effecting anchor-coating or without treating the molten film of the extrusion-laminated resin with ozone. The laminated film is obtained by extrusion-laminating, onto the polyester film, an ethylene copolymer containing an unsaturated carboxylic acid and a (meth)acrylic acid ester, which may be further blended with a small amount of an ethylene/&agr;-olefin copolymer having a density of 840 to 900 kg/m3, the amount of the unsaturated carboxylic acid component being from 1 to 12% by weight and the amount of the (meth)acrylic acid ester component being from 2 to 25% by weight.Type: GrantFiled: March 29, 2001Date of Patent: December 28, 2004Assignee: DuPont-Mitsui Polychemicals Co., Ltd.Inventors: Kenji Miharu, Naozumi Suzuki
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Patent number: 6822062Abstract: Methods for preparing olefin polymers, and catalysts for preparing olefin polymers are disclosed. The polymers can be prepared by contacting the corresponding monomers with a Group 8-10 transition metal catalyst and a solid support. The polymers are suitable for processing in conventional extrusion processes, and can be formed into high barrier sheets or films, or low molecular weight resins for use in synthetic waxes in wax coatings or as emulsions.Type: GrantFiled: October 30, 2001Date of Patent: November 23, 2004Assignee: Eastman Chemical CompanyInventors: Peter Borden Mackenzie, Leslie Shane Moody, Christopher Moore Killian, Gino Georges Lavoie
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Patent number: 6806333Abstract: An aqueous dispersion of a fluorocopolymer, which is excellent in stability and film-forming properties as an aqueous dispersion, and which gives a coating film excellent in mechanical strength and improved in transparency, water resistance and stain resistance. A stable aqueous dispersion of a fluorocopolymer obtained in such a manner that a fluorocopolymer comprising polymerized units based on a vinyl monomer having a reactive group as the base is subjected to a composite treatment or a mixing treatment with a (meth)acrylate containing a reactive group capable of forming a bond by reaction with the above reactive group or the like.Type: GrantFiled: January 27, 2003Date of Patent: October 19, 2004Assignee: Asahi Glass Company, LimitedInventors: Toru Ishida, Naomi Ichikuni
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Patent number: 6765072Abstract: The invention relates to a process for the preparation of aqueous dispersions of latex particles having a heterogeneous morphology by a semicontinuous emulsion polymerization, comprising the emulsion polymerizing of ethylenically unsaturated (co)monomers, accompanied by, the addition of cationic and/or anionic and/or nonionic emulsifiers and/or protective colloids as stabilizers, which are directly used as such or synthesized in situ, the semicontinuous emulsion polymerization being performed in the presence of the stabilizer or stabilizers with a monomer mixture, which a) contains at least one nonionic, ethylenically unsaturated monomer with a glass transition temperature Tg above about 30° C. in a quantity of about 10 to 70 wt. %, based on the total weight of ethylenically unsaturated (co)monomers and b) at least one hydrophilic, ethylenically unsaturated monomer in a quantity of about 5 to 30 wt. %, based on the total weight of ethylenically unsaturated (co)monomers.Type: GrantFiled: March 21, 2001Date of Patent: July 20, 2004Assignee: National Starch and Chemical Investment Holding CorporationInventors: Hongli Willimann, Robert Koelliker
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Patent number: 6759490Abstract: The invention provides a process for preparing an aqueous polymer dispersion of a copolymer CP of at least two different monomers M1 and M2 by free-radical aqueous emulsion polymerization of the monomers M in the presence of at least one initiator, at least 80% of the monomers M and at least 75% of the initiator being supplied continuously to the polymerization reaction during its course, which comprises changing the rate at which the initiator is supplied to the polymerization reaction a number of times, or continuously, during the polymerization reaction. The invention further provides the polymer dispersions obtainable by this process, polymer powders prepared therefrom, and for the use of the dispersions and/or of the polymer powders to prepare pressure sensitive adhesives.Type: GrantFiled: February 19, 2002Date of Patent: July 6, 2004Assignee: BASF AktiengesellschaftInventors: Matthias Gerst, Gerhard Auchter, Bernhard Schuler
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Patent number: 6740703Abstract: A thickened aqueous coating composition (preferably paints and the like or adhesives) containing a film-forming polymeric binder which produces dried coatings having less sensitivity to water by using a thickener which is autoxidizable. Preferred autoxidizable moieties are provided by long chain fatty acids of the type used in alkyd paints and association is the preferred thickener mechanism. The moieties may form part of a compound which can take part in a copolymerization to form a cellulose-free polymeric backbone for the thickener and if the compound is not very soluble in water, the copolymerization mixture is subjected to intensive agitation to form droplets of less than 500 nm number average diameter which compensates for the lack of solubility. The thickener may serve as a binder if sufficient amounts are used.Type: GrantFiled: February 6, 2002Date of Patent: May 25, 2004Assignee: Imperial Chemical Industries PLCInventors: Manish Sarkar, Stephane Patrick Belmudes
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Patent number: 6627325Abstract: A polymer latex composition suitable for rubber articles comprises about 5 to about 65 weight percent of an aromatic vinyl monomer, about 35 to about 90 weight percent of a conjugated diene monomer, and about 0.5 to about 10 weight percent of a component selected from the group consisting of an unsaturated acid monomer, a partial ester of an unsaturated polycarboxylic acid, and mixtures thereof. The polymer latex composition has a gel content of no more than about 85 percent.Type: GrantFiled: August 4, 1998Date of Patent: September 30, 2003Assignee: Dow Reichhold Specialty Latex LLCInventors: Kanchan Ghosal, Venkataram Krishnan
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Patent number: 6617387Abstract: Ammonia-free polymer dispersions containing at least one copolymer which contains, as polymerized monomers, a) from 40 to 80% by weight of at least one ester of acrylic acid with C2-C12-alkanols, b) from 10 to 40% by weight of at least one vinylaromatic monomer and/or at least one ester of methacrylic acid with C1-C4-alkanols, c) from 2 to 15% by weight of at least one monoester of a C2-C10-alkanediol with acrylic acid or methacrylic acid, d) not more than 1% by weight of ethylenically unsaturated monomers which have at least one acid group, or salts thereof, e) less than 5% by weight of &agr;,&bgr;-ethylenically unsaturated nitrites and f) less than 1% by weight of amides of &agr;,&bgr;-ethylenically unsaturated mono- and dicarboxylic acids, and the polymer powders or polymer granules obtainable from the polymer dispersion, are used as additives for building materials based on hydraulic binders.Type: GrantFiled: August 20, 2001Date of Patent: September 9, 2003Assignee: BASF AktiengesellschaftInventors: Stefan Dreher, Joachim Pakusch, Bernd Reck
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Publication number: 20030114616Abstract: An aqueous dispersion of a fluorocopolymer, which is excellent in stability and film-forming properties as an aqueous dispersion and which gives a coating film excellent in mechanical strength and improved in transparency, water resistance and stain resistance.Type: ApplicationFiled: January 27, 2003Publication date: June 19, 2003Applicant: ASAHI GLASS COMPANY LIMITEDInventors: Toru Ishida, Naomi Ichikuni
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Patent number: 6579956Abstract: A method for producing a polymer by coordination polymerization, comprising the steps of (a) reacting an unsaturated polar monomer having a functional group releasing a proton or a salt of the unsaturated polar monomer, with a masking agent comprising a halogenated organometallic compound or a organoaluminum compound capable of masking the functional group to form a corresponding masked monomer; and (b) polymerizing the masked monomer either alone or in combination with another monomer in the presence of the coordination polymerization catalyst to obtain the polymer.Type: GrantFiled: June 7, 2001Date of Patent: June 17, 2003Assignees: Kabushiki Kaisha Toyota Chuo Kenkyusho, University of MassachusettsInventors: Hiromitsu Tanaka, Bruce M. Novak
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Patent number: 6562779Abstract: Emulsifiable ethylene polymers comprising copolymers of from 90 to 95% by weight of ethylene, from 4 to 10% by weight of one or more C3-C12 alkenecarboxylic acids, and from 0 to 1.2% by weight of one or more tertiary esters of the corresponding C3-C12 alkenecarboxylic acids, where the wax has a cinematic melt viscosity of from 800 to 3000 mm2/s, measured at 120° C.; and a process for preparing the novel emulsifiable ethylene polymers, emulsions comprising the novel ethylene polymers, a process for preparing the emulsions from the novel ethylene polymers, and also floor cleaners, car cleaners, leather cleaners and stone cleaners, and coatings for surfaces made from wood, metal, paper, glass or from plastics, comprising aqueous emulsions of the novel emulsifable waxes.Type: GrantFiled: February 14, 2001Date of Patent: May 13, 2003Assignee: BASF AktiengesellschaftInventors: Lars Wittkowski, Andreas Deckers, Wilhelm Weber, Stefan Weiss, Michael Ehle, Siegfried Gast
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Patent number: 6531556Abstract: A radical (co)polymerization of ethylene is carried out under high pressure in the presence of at least one initiating free radical (Z•) and of at least one controlling stable free radical (SFR•) which comprises the indoline nitroxide backbone represented by the formula (I). A is a hydrocarbonaceous chain forming an aromatic ring with the two carbon atoms to which it is attached, this ring being able to carry substituents or being able to carry one or more rings placed side by side, which rings are aromatic or aliphatic and optionally substituted, the carbon atoms forming the nitrogenous ring and in the alpha- and beta-position with respect to the nitrogen atom being able to carry hydrogen atoms or substituents.Type: GrantFiled: January 23, 2001Date of Patent: March 11, 2003Assignee: AtofinaInventors: Eric Minaux, Lucedio Greci, Michael Buback, Paul Tordo, Thierry Senninger, Pierluigi Stipa, Patricia Carloni, Elisabetta Damiani, Giampaolo Tommasi
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Patent number: 6531563Abstract: Polymerization of a fatty acid or fatty acid derivatives containing conjugated double bonds and alkenes or alkynes containing electron acceptor substituents provides compositions useful as coatings, adhesives, sealants, fillers and the like.Type: GrantFiled: June 10, 1999Date of Patent: March 11, 2003Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Johann Klein, Kai Boege, Wolfgang Klauck
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Patent number: 6512055Abstract: Copolymers I carrying functional groups and comprising a) 20-60 mol % of at least one monoethylenically unsaturated C4-C6-dicarboxylic acid or an anhydride thereof, b) 10-70 mol % of at least one oligomer of propene or of a branched 1-olefin of 4 to 10 carbon atoms, having an average molecular weight Mw of from 300 to 5000, and c) 1-50 mol % of at least one monoethylenically unsaturated compound which is copolymerizable with the monomers a) and b), a process for their preparation, oil-soluble reaction products obtainable therefrom by reaction with an amine and the use of said reaction products as additives for lubricants and fuels.Type: GrantFiled: May 4, 2001Date of Patent: January 28, 2003Assignee: BASF AktiengesellschaftInventors: Wolfgang Günther, Knut Oppenländer, Walter Denzinger, Heinrich Hartmann, Helmut Mach, Harald Schwahn, Hans Peter Rath
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Patent number: 6495648Abstract: Toner binder resins with low odor and excellent charging stability as toners, containing styrene-acrylic copolymers or mixtures thereof, wherein the total content of volatile components is no greater than about 1,500 ppm, the content of volatile components with benzene rings is no greater than about 1,400 ppm, and the content of volatile components with benzene rings and boiling point of below about 200° C. is no greater than about 500 ppm.Type: GrantFiled: April 28, 2000Date of Patent: December 17, 2002Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Motoshi Inagaki, Koji Shimizu, Yoko Harada, Junya Nakamura
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Publication number: 20020177068Abstract: Disclosed is a polymer for use in a chemically amplified resist, a resist composition including such a polymer is suitable for use in a chemically amplified resist, which is sensitive to far ultraviolet rays such as KrF or ArF excimer laser and forms a photoresist pattern having low dependence on and good adhesion to substrate, high transparency in the wavelength range of the above radiation, strong resistance to dry etching, and excellencies in sensitivity, resolution and developability. The resist composition can have a stronger etching resistance with a maximized content of unsaturated aliphatic ring in the polymer and a reduced edge roughness of the photoresist pattern with an alkoxyalkyl acrylate monomer employed.Type: ApplicationFiled: February 11, 2002Publication date: November 28, 2002Inventors: Joohyeon Park, Dongchul Seo, Jongbum Lee, Hyunpyo Jeon, Seongju Kim
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Patent number: 6482907Abstract: Olefins containing selected functional groups such as silyl, ether and alkenyl, and often containing a blocking group, may be copolymerized with unsubstituted olefins such as ethylene and propylene in the presence of certain coordination compounds of nickel or palladium. The resulting polymers are useful as molding resins, elastomers, in adhesives and for films.Type: GrantFiled: February 1, 2000Date of Patent: November 19, 2002Assignee: E.I. du Pont de Nemours and CompanyInventors: Lin Wang, Samuel David Arthur, Elizabeth Forrester McCord, Yueli Wang, Peter Arnold Morken, Lynda Kaye Johnson
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Patent number: 6476170Abstract: Described is a process for making acrylic resins suitable as polymeric surfactants used in emulsion polymerization, as pigment grinding resins and for preparing dispersions used as overprint varnishes. The feedstock is styrene, &agr;-methyl styrene, acrylic acid and a polymerization initiator and is preferably free of solvent. This mix is passed through a continuous tube reactor run at a controlled range of pressure and relatively low residence time and temperature. Optimally, when the polymer/unreacted monomers blend exits the reactor and is devolatilized, the recovered monomers are used to make up part of the feedstock.Type: GrantFiled: November 28, 2000Date of Patent: November 5, 2002Assignee: Cook Composites & Polymers Co.Inventors: George Roth, George A. Smith, Reuben Grinstein, Paul D. Whyzmuzis, Shruti Singhal, Steve Boucher, Brenda Taipale, Roger Lovald, David Devore, James P. Yosh, Jr., Stephen A. Fischer, Michael S. Wiggins
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Patent number: 6350827Abstract: Disclosed is a process for pressurizing ethylenically unsaturated monomers to 200-5000 bar in the absence of a polymerization initiator, which comprises effecting said pressurizing in the presence of nitroxyl compounds of the formula I where R1 and R2 are singly C1-C4-alkyl or combine with the joining carbon atom to form a 5- or 6-membered saturated hydrocarbon ring, R3 is C1-C4-alkyl, and R4 is hydrogen or C1-C12-alkyl. Also disclosed are a process for preparing copolymers by such pressurization and subsequent polymerization and copolymers obtainable thereby.Type: GrantFiled: December 2, 1999Date of Patent: February 26, 2002Assignee: BASF AktiengesellschaftInventors: Heinz Friedrich Sutoris, Andreas Deckers, Wilhelm Weber
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Patent number: 6331598Abstract: A process for preparing an emulsion polymer comprising placing a first mixture of monomers in a feed tank B which is connected directly to a reactor, placing a second mixture of monomers in a feed tank A which is connected to the feed tank B, and continuously varying the composition ratio of the monomers of feed tanks A and B in the emulsion polymer. The composition ratio is varied by varying the rate of feeding of the second mixture of monomers present in tank A into tank B while simultaneously varying the rate of feeding of the first mixture of monomers present in tank B into the reactor. The polymerization occurs as the first and second mixtures of monomers are simultaneously fluxed in the reactor while stirring.Type: GrantFiled: August 24, 1999Date of Patent: December 18, 2001Assignee: Korea Chemical Co., Ltd.Inventors: Jong-Myung Park, Chang-Ho Choi, Jung-Kwon Oh, Seung-Min Hong
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Patent number: 6319978Abstract: The present invention is directed to improved vinyl acetate ethylene pressure sensitive adhesive emulsion polymers. The improvement in the aqueous based, emulsion polymerized pressure sensitive adhesives resides in: a high ethylene content copolymer having a Tg of from −25 to −70° C.; a tensile storage modulus measured at one hertz and at a temperature of −20° C. embraced by the points on a plot of storage modulus and temperature of from 1 times 106 and the points 4 times 109 dynes/cm2 and less that 1 times 107 dynes/cm2 measured at 50° C.Type: GrantFiled: October 1, 1998Date of Patent: November 20, 2001Assignee: Air Products and Chemicals, Inc.Inventors: Christian Leonard Daniels, Chung-Ling Mao, Richard Henry Bott, Menas Spyros Vratsanos
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Patent number: 6310163Abstract: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc.Type: GrantFiled: July 10, 1997Date of Patent: October 30, 2001Assignee: E. I. du Pont de Nemours and CompanyInventors: Maurice S. Brookhart, Lynda Kaye Johnson, Christopher Moore Killian, Samuel David Arthur, Jerald Feldman, Elizabeth Forrester McCord, Stephan James McLain, Kristina Ann Kreutzer, Alison Margaret Anne Bennett, Edward Bryan Coughlin, Steven Dale Ittel, Anju Parthasarathy, Daniel Joseph Tempel
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Publication number: 20010034428Abstract: The invention relates to a gelling aqueous composition comprising block copolymers containing at least one water-soluble block and at least one block predominantly hydrophobic in nature, and forming a viscoelastic gel.Type: ApplicationFiled: February 20, 2001Publication date: October 25, 2001Inventors: Mathias Destarac, Mathieu Joanicot, Roland Reeb
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Patent number: 6268442Abstract: A process for the reduction of reactor fouling at radical initiated high pressure polymerisation of ethylene (co)polymers is described. The process is characterised in that an adhesion reducing silicon containing compound is added to the polymerisation reactor, preferably in an amount of 0.001-3% by weight, based on the amount of polymer produced. Preferably the silicon containing compound is hexadecyl trimethoxy silane.Type: GrantFiled: September 8, 1999Date of Patent: July 31, 2001Assignee: Borealis A/SInventors: Bill Gustafsson, Ruth Dammert, Jussi Laurell, Erik van Praet
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Patent number: 6242540Abstract: Particles of a copolymer of a vinyl arene and a copolymerizable compound containing a polar moiety and a vinyl moiety containing water may be prepared by forming a mixture of monomers and small amounts of water and polymerizing under agitation to 20 to 70% conversion and then suspending the mass in water and finishing the polymerization. The resulting polymer beads contain finely dispersed water which is useful as an environmentally acceptable blowing agent.Type: GrantFiled: December 30, 1998Date of Patent: June 5, 2001Assignee: Nova Chemicals (International) S.A.Inventors: Jeroen Joost Crevecoeur, Eric Wilhelmus Johannes Frederik Neijman, Laurentius Nicolaas Ida Hubertus Nelissen, Johannes Maria Zijderveld
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Patent number: 6197884Abstract: This invention is directed towards golf balls comprising at least a cover and a core, and optionally one or more intermediate layers, wherein the cover and/or the intermediate layer(s) are formed from a high crystalline copolymer or its ionomer derivatives and blends thereof, wherein the high crystalline copolymer is formed from an ethylene/carboxylic acid copolymer comprising about 5 to about 35 percent by weight acrylic or methacrylic acid, wherein the copolymer is polymerized at a temperature of about 130° C. to 200° C. at pressures of at least 20,000 psi to about 50,000 psi, wherein up to about 70 percent of the acid groups are neutralized with a metal ion.Type: GrantFiled: March 23, 1999Date of Patent: March 6, 2001Assignee: Acushnet CompanyInventors: Murali Rajagopalan, Robert Joseph Statz
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Patent number: 6197879Abstract: A polymer useful as an inorganic pigment dispersant is provided. The polymer is derived from monomers consisting essentially of an ethylenically unsaturated aromatic monomer, an ethylenically unsaturated dicarboxylic acid monomer, and an ethylenically unsaturated monocarboxylic acid monomer. The total amount of said ethylenically unsaturated acid monomers is sufficient to permit said polymer to associate with an inorganic pigment in an aqueous medium in a manner which disperses said inorganic pigment in said aqueous medium to form a stable aqueous dispersion of said inorganic pigment, and the amount of said ethylenically unsaturated aromatic monomer is sufficient to reduce the water sensitivity of a dried coating of a latex paint comprised of said stable aqueous dispersion of said inorganic pigment. A process of preparing a polymer useful as an inorganic pigment dispersant and a method of preparing an inorganic pigment dispersion useful in the preparation of latex paints are also provided.Type: GrantFiled: September 13, 1996Date of Patent: March 6, 2001Assignee: Henkel CorporationInventors: Stephen A. Fischer, Michael S. Wiggins, Bruce Matta, Eric Nowicki