With Hydrocarbon Monomer Patents (Class 526/318.6)
  • Publication number: 20100096072
    Abstract: A support material feedstock comprising a first copolymer and a polymeric impact modifier, where the first copolymer includes a first monomer unit comprising a carboxyl group and a second monomer unit comprising a phenyl group.
    Type: Application
    Filed: July 24, 2009
    Publication date: April 22, 2010
    Applicant: STRATASYS, INC.
    Inventors: Paul E. Hopkins, William R. Priedeman, JR., Jeffrey F. Bye
  • Patent number: 7691260
    Abstract: The present invention provides method for recovering fossil-based materials from oil sources using multifunctional, multipolymeric continuous composition spectrum surfactant mixtures. The invention also provides methods for reducing the loss of volatile organic compounds (VOCs) from oil storage containers using multifunctional, multipolymer surfactants. The multifunctional, multipolymer surfactants are characterized by a hydrophobic part and a hydrophilic part. The hydrophobic part of the polymer surfactants includes functionalities that impart a polarity of greater than 0 Debye to the hydrophobic part. The polymer surfactants are further characterized by molecular weights that are above their entanglement weights. The result is polymer surfactants and their continuous composition surfactant-thickener mixtures with demulsifying characteristics.
    Type: Grant
    Filed: February 9, 2007
    Date of Patent: April 6, 2010
    Assignee: Nanochemical Oil Company
    Inventor: Gerard Caneba
  • Patent number: 7683128
    Abstract: The present invention provides an ionomer composition for a golf ball providing a golf ball which is excellent in abrasion-resistance, durability and resilience, and a golf ball using the same. An ionomer composition for a golf ball of the present invention comprises a binary copolymer obtained by copolymerizing an olefin monomer having 2 to 8 carbon atoms with an unsaturated monomer having an acid functional group and/or a ternary copolymer obtained by copolymerizing an olefin monomer having 2 to 8 carbon atoms, an unsaturated monomer having an acid functional group and an unsaturated carboxylic acid ester, wherein a functional group is introduced in both terminals of the copolymers.
    Type: Grant
    Filed: January 9, 2007
    Date of Patent: March 23, 2010
    Assignee: SRI Sports Limited
    Inventors: Toshiyuki Tarao, Takashi Sasaki, Satoko Okabe
  • Patent number: 7666963
    Abstract: Hybrid copolymers for use as anti-scalant and dispersant. The polymers are useful in compositions used in aqueous systems. The polymers include at least one synthetic monomeric constituent that is chain terminated by a naturally occurring hydroxyl containing moiety. A process for preparing these hybrid copolymers is also provided.
    Type: Grant
    Filed: July 18, 2006
    Date of Patent: February 23, 2010
    Assignee: Akzo Nobel N.V.
    Inventors: Klin A. Rodrigues, Darin K. Griffith
  • Publication number: 20100041840
    Abstract: The present invention relates to a method for preparing an unsaturated ethylene-diene copolymer by high pressure radical-initiated polymerisation, said method providing an improved conversion of added diene into pendant vinyl groups.
    Type: Application
    Filed: November 6, 2007
    Publication date: February 18, 2010
    Inventors: Kenneth Johansson, Peter Rydin, Annika Smedberg
  • Publication number: 20090324836
    Abstract: The present invention provides an industrially advantageous method for producing an unsaturated carboxylic acid-modified vinyl alcohol polymer, and a gas barrier film obtained by using the same.
    Type: Application
    Filed: May 31, 2007
    Publication date: December 31, 2009
    Applicant: TOHCELLO CO., LTD.
    Inventors: Kou Tsurugi, Yoshihisa Inoue, Isao Hara, Hiroyoshi Watanabe, Tomoyoshi Hakamata, Akira Nomoto, Osamu Nakamura
  • Publication number: 20090318647
    Abstract: This invention relates to a process to functionalize propylene co-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene a co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(?0.94 (mol % ethylene incorporated)+100), when 10 to 60 mol % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mol % ethylene is present in the co-oligomer, and 3) X=(1.83*(mol % ethylene incorporated)?83), when 70 to 90 mol % ethylene is present in the co-oligomer.
    Type: Application
    Filed: June 19, 2009
    Publication date: December 24, 2009
    Inventors: John R. Hagadorn, Matthew W. Holtcamp, Andrew G. Narvaez, JR., Donna J. Crowther, Patrick Brant
  • Publication number: 20090270551
    Abstract: There is disclosed a polymer (Polymer P) which is obtained and/or is obtainable from a monomer composition comprising (a) from about 5% to about 95% by weight of at least one C2-12alkyl acrylate; (b) from about 2.5% to about 60% by weight of at least one polymer precursor selected from the group consisting of: C1-30 alkyl(meth)acrylates, C2-30 vinyl aromatic compounds, C2-30 vinyl halides, C2-30 vinyl nitriles, C2-30 vinyl esters of carboxylic acids and mixtures thereof; with the provisos that (i) the homopolymers of each of said polymer precursor(s) have a Tg above about ?25° C.; and (ii) each of said polymer precursor(s) comprises other than a functional group selected from the group consisting of: hydroxy, carboxy, acid anhydride, nitro, epoxy and amino; (c) from about 0.
    Type: Application
    Filed: September 7, 2006
    Publication date: October 29, 2009
    Inventors: Olivier Dupont, Singa Tobing, Hui Liu
  • Patent number: 7605211
    Abstract: The present invention provides a golf ball with excellent abrasion-resistance, durability and resilience having an ionomer resin cover therein. The ionomer composition for the golf ball of the invention comprises a reaction product obtained by reacting a telechelic copolymer having functional groups introduced in both terminals of a binary copolymer formed by copolymerizing an olefin monomer having 2 to 8 carbon atoms and an unsaturated carboxylic acid having 2 to 18 carbon atoms, and/or a ternary copolymer formed by copolymerizing an olefin monomer having 2 to 8 carbon atoms, an unsaturated carboxylic acid having 2 to 18 carbon atoms and an unsaturated carboxylic acid ester with a hydroxyl group-containing compound or an isocyanate group-containing compound, wherein at least 10 mole % of a carboxylic group in said reaction product is neutralized with an inorganic metal.
    Type: Grant
    Filed: January 9, 2007
    Date of Patent: October 20, 2009
    Assignee: SRI Sports Limited
    Inventors: Satoko Okabe, Takashi Sasaki, Toshiyuki Tarao
  • Publication number: 20090239050
    Abstract: A methacrylic resin comprising 80 to 98.5 wt % of methyl methacrylate monomer unit and 1.5 to 20 wt % of at least one different vinyl monomer unit copolymerizable with methyl methacrylate, characterized in that the methacrylic resin has a weight average molecular weight measured by gel permeation chromatography (GPC) of 60,000 to 230,000 and comprises 7 to 30% of a component having a weight average molecular weight of ? or less of a peak weight average molecular weight (Mp) obtained from a GPC elution curve based on the methacrylic resin component.
    Type: Application
    Filed: November 17, 2006
    Publication date: September 24, 2009
    Applicant: Asahi Kasei Chemicals Corporation
    Inventors: Naoki Azuma, Kohei Okumura, Kazunori Kozawa
  • Publication number: 20090221729
    Abstract: This invention provides a water-soluble macromonomer having terminal unsaturation obtained by polymerization of monomers in the presence of inclusion complex of chain transfer agent in aqueous system. Hydrophobic chain transfer agent AMSD forms an inclusion complex with methylated cyclodextrin. The complexation enhances its solubility in water and enables the polymerization of water-soluble monomers in aqueous medium. After polymerization cyclodextrin is removed and the macromer with terminal unsaturation obtained can be used further for copolymerization with any vinyl monomer.
    Type: Application
    Filed: March 28, 2007
    Publication date: September 3, 2009
    Applicant: COUNCIL OF SCIENTIFIC AND INDUSTRIAL RESEARCH
    Inventors: Mohan Gopalkrishna Kulkarni, Prerana Maruti Patil
  • Publication number: 20090186231
    Abstract: A method of coating surfaces of plastic or metal, which comprises treating the plastic or metal surface in question with an aqueous dispersion comprising (A) at least one ethylene copolymer having a molecular weight Mn in the range from 2000 to 20 000 g/mol, selected from ethylene copolymers comprising as comonomers in copolymerized form (a) 15.5% to 19.9% by weight of at least one ethylenically unsaturated C3-C10 carboxylic acid and (b) 80.1% to 84.5% by weight of ethylene, (B) at least one base, in one step and subsequently providing in at least one further step the metal or plastic surface in question with at least one further coat.
    Type: Application
    Filed: May 22, 2007
    Publication date: July 23, 2009
    Applicant: BASF SE
    Inventors: Heike Pfistner, Andreas Fechtenkotter, Frank-Olaf Mähling, Helmut Witteler, Frank Dietsche, Stefan Fassbender, Claudia Simon
  • Publication number: 20090076233
    Abstract: A novel hybrid polymer has a structure in which a polyolefin segment and a polar polymer segment are connected not via a bonding group containing a heteroatom. A method of the invention produces the hybrid polymer with industrial advantages. The hybrid polymer includes a polyolefin segment (A) and a polar polymer segment (B), the polar polymer segment being obtained by radical polymerization of a radically polymerizable monomer.
    Type: Application
    Filed: February 21, 2006
    Publication date: March 19, 2009
    Applicant: MITSUI CHEMICALS, INC.
    Inventors: Hideyuki Kaneko, Shinichi Kojoh, Nobuo Kawahara, Shingo Matsuo, Tomoaki Matsugi, Norio Kashiwa
  • Publication number: 20090040618
    Abstract: An object of the present invention is to provide a light diffuser plate (1) which can illuminate the front side more brightly when incorporated in a surface light source (3) constituting a transmissive image display (2). The light diffuser plate of the present invention comprises a transparent resin and a light diffuser dispersed in the transparent resin, wherein the transparent resin is a transparent resin which has a light transmittance [T600] at a wavelength of 600 nm of 85% or more measured with respect to a thickness of a 2 mm thick plate-shaped specimen, and a ratio [T365/T600] of a light transmittance [T365] at a wavelength of 365 nm to the light transmittance [T600] is 0.90 to 0.99. The transparent resin is polystyrene or the like, an average particle diameter of the light diffuser is from 0.5 to 5 ?m, an absolute value [|?n|] of a difference in a refractive index between the light diffuser and the transparent resin is 0.05 or more, an amount of the light diffuser is from 0.
    Type: Application
    Filed: August 7, 2008
    Publication date: February 12, 2009
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventor: Hironobu Iyama
  • Publication number: 20090005529
    Abstract: A s,s?-bis-(?,??-disubstituted-??-acetic acid)-trithiocarbonate and derivatives thereof can be used as an initiator, chain transfer agent, or terminator for polymerization of monomers such as free radical polymerizable monomers. Homopolymers, copolymers, and the like as well as block copolymers can be made utilizing the trithio carbonate compound such as in a living free radical polymerization as well as to form telechelic polymers.
    Type: Application
    Filed: October 9, 2007
    Publication date: January 1, 2009
    Inventor: John T. Lai
  • Publication number: 20080275203
    Abstract: The present invention relates to resin compositions for radical curing comprising a component (I) containing reactive carbon-carbon unsaturations and a component (II) containing XH-groups, with X not being C or O, which resin compositions (a) are substantially free of photoinitiators; (b.) have an average number of reactive carbon-carbon unsaturations of component (I) higher than 2; (c) have an average number of XH-groups of component (II) equal to or higher than 2, with at least one of the XH-groups of the XH-component being a thiol group, and; (d) whereby at least one of the average numbers of (b) and (c) is higher than 2; (e) and at most 5 mol % of the reactive unsaturations is capable of undergoing homopolymerisation; (f) respectively is present in the form of a mono-ene functional alkylene; and (g) the molar ratio of the XH-groups and of the reactive unsaturations is in the range of from 4:1 to 1:4; with the proviso that the RU component is not tris-(norborn-5-ene-2-carboxy) propoxypropane.
    Type: Application
    Filed: April 6, 2005
    Publication date: November 6, 2008
    Inventors: Johan Franz Gradus Antonius Jansen, Michael Alphonsus Cornelis Johannes Van Dijck, Marco Marcus Matheus Driessen
  • Publication number: 20080269447
    Abstract: Disclosed is a method of preparing hollow particles comprising polymerizing a hydrophobic monomer to form a particulate resin exhibiting a number average molecular weight of from 20,000 to 500,000, dispersing the particulate resin in an aqueous medium to form a resin particle dispersion and adding thereto a hydrophobic cross-linkable monomer in an amount of from 0.1 to 50 parts by mass based on 1 part by mass of the particulate resin to polymerize the cross-linkable monomer to form hollow particles.
    Type: Application
    Filed: March 6, 2008
    Publication date: October 30, 2008
    Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.
    Inventors: Aya SHIRAI, Mitsutoshi NAKAMURA, Tatsuya NAGASE, Motoi NISHIMURA
  • Publication number: 20080242809
    Abstract: The invention relates to a process for the preparation of a copolymer of ethylene and a monomer copolymerisable therewith. The polymerisation takes place in a tubular reactor at a peak temperature between 290° C. and 350° C., the co monomer is a di- or higher functional (meth)acrylate and the co monomer is applied in an amount between 0.008 mol % and 0.200 mol % relative to the amount of ethylene copolymer.
    Type: Application
    Filed: February 27, 2006
    Publication date: October 2, 2008
    Inventors: Peter Neuteboom, Geert Imelda Valerie Bonte, Jacobus Christinus Josephus Franciscus Tacx, Marcellinus Guilliame Marie Neilen
  • Publication number: 20080234456
    Abstract: The present invention aims at providing a stretched film of an olefin polymer excellent in anti-static property, which is obtained from an olefin polymer composition comprising an olefin polymer and potassium salt of an ethylene-unsaturated carboxylic acid copolymer, and a gist in construction resides in a stretched film of an olefin polymer, which has been obtained from an olefin polymer composition (C) comprising an olefin polymer (A) and potassium salt of an ethylene-unsaturated carboxylic acid copolymer (B) and has been stretched at a stretching factor in terms of plane factor of at least 3 times. Stretching is preferably biaxially stretching and the olefin polymer composition (C) is preferably comprised of 99-60% by weight of the olefin polymer (A) and 1-40% by weight of potassium salt of an ethylene-unsaturated carboxylic acid copolymer (B).
    Type: Application
    Filed: December 20, 2005
    Publication date: September 25, 2008
    Applicant: Dupont-Mitsui Polychemicals Co., Ltd.
    Inventors: Tohru Sawai, Masaru Shimizu, Masanobu Sato
  • Publication number: 20080051541
    Abstract: According to an aspect of the present invention, implantable or insertable medical devices are provided that contain at least one covalently crosslinked polymeric region, which contains at least one block copolymer comprising at least one low Tg block and at least one high Tg block.
    Type: Application
    Filed: June 1, 2007
    Publication date: February 28, 2008
    Inventors: Frederick H. Strickler, Mark Boden
  • Publication number: 20080051542
    Abstract: According to an aspect of the present invention, implantable or insertable medical devices are provided, which contain at least one polymeric region in contact with a metallic region. The polymeric region contains at least one block copolymer that contains at least one low Tg block and at least one high Tg block. The polymeric region contains at least one polymer that contains at least one adhesion promoting group selected from one or more of halo-silane, alkoxy-silane, epoxy, anhydride, phenoxy, hydroxyl, amino, sulfonate and carboxyl groups, which at least one polymer may correspond to the block copolymer, a supplemental polymer, or both.
    Type: Application
    Filed: June 1, 2007
    Publication date: February 28, 2008
    Inventor: Frederick H. Strickler
  • Patent number: 6903157
    Abstract: A thickened aqueous coating composition (preferably paints and the like or adhesives) containing a film-forming polymeric binder which produces dried coatings having less sensitivity to water by using a thickener which is autoxidisable. Preferred autoxidisable moieties are provided by derivatives of long chain fatty acids of the type used in alkyd paints and association is the preferred thickener mechanism. The moieties may form part of a compound which can take part in a copolymerisation to form a polymeric backbone for the thickener and if the compound is not very soluble in water, the copolymerisation mixture is subjected to intensive agitation to form droplets of less than 500 nm which compensates for the lack of solubility. The thickener may serve as its own binder if sufficient amounts are used.
    Type: Grant
    Filed: July 19, 2001
    Date of Patent: June 7, 2005
    Assignee: Imperial Chemical Industries PLc
    Inventors: Manish Sarkar, Stephane Patrick Belmudes
  • Patent number: 6894134
    Abstract: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc.
    Type: Grant
    Filed: June 22, 2001
    Date of Patent: May 17, 2005
    Assignees: E. I. duPont de Nemours and Company, University of North Carolina at Chapel Hill
    Inventors: Maurice S. Brookhart, Lynda Kaye Johnson, Christopher Moore Killian, Elizabeth Forrester McCord, Stephan James McLain, Samuel David Arthur
  • Patent number: 6835269
    Abstract: A laminated film exhibiting excellent interlayer adhesiveness obtained by extrusion-laminating a resin directly on a polyester film without effecting anchor-coating or without treating the molten film of the extrusion-laminated resin with ozone. The laminated film is obtained by extrusion-laminating, onto the polyester film, an ethylene copolymer containing an unsaturated carboxylic acid and a (meth)acrylic acid ester, which may be further blended with a small amount of an ethylene/&agr;-olefin copolymer having a density of 840 to 900 kg/m3, the amount of the unsaturated carboxylic acid component being from 1 to 12% by weight and the amount of the (meth)acrylic acid ester component being from 2 to 25% by weight.
    Type: Grant
    Filed: March 29, 2001
    Date of Patent: December 28, 2004
    Assignee: DuPont-Mitsui Polychemicals Co., Ltd.
    Inventors: Kenji Miharu, Naozumi Suzuki
  • Patent number: 6822062
    Abstract: Methods for preparing olefin polymers, and catalysts for preparing olefin polymers are disclosed. The polymers can be prepared by contacting the corresponding monomers with a Group 8-10 transition metal catalyst and a solid support. The polymers are suitable for processing in conventional extrusion processes, and can be formed into high barrier sheets or films, or low molecular weight resins for use in synthetic waxes in wax coatings or as emulsions.
    Type: Grant
    Filed: October 30, 2001
    Date of Patent: November 23, 2004
    Assignee: Eastman Chemical Company
    Inventors: Peter Borden Mackenzie, Leslie Shane Moody, Christopher Moore Killian, Gino Georges Lavoie
  • Patent number: 6806333
    Abstract: An aqueous dispersion of a fluorocopolymer, which is excellent in stability and film-forming properties as an aqueous dispersion, and which gives a coating film excellent in mechanical strength and improved in transparency, water resistance and stain resistance. A stable aqueous dispersion of a fluorocopolymer obtained in such a manner that a fluorocopolymer comprising polymerized units based on a vinyl monomer having a reactive group as the base is subjected to a composite treatment or a mixing treatment with a (meth)acrylate containing a reactive group capable of forming a bond by reaction with the above reactive group or the like.
    Type: Grant
    Filed: January 27, 2003
    Date of Patent: October 19, 2004
    Assignee: Asahi Glass Company, Limited
    Inventors: Toru Ishida, Naomi Ichikuni
  • Patent number: 6765072
    Abstract: The invention relates to a process for the preparation of aqueous dispersions of latex particles having a heterogeneous morphology by a semicontinuous emulsion polymerization, comprising the emulsion polymerizing of ethylenically unsaturated (co)monomers, accompanied by, the addition of cationic and/or anionic and/or nonionic emulsifiers and/or protective colloids as stabilizers, which are directly used as such or synthesized in situ, the semicontinuous emulsion polymerization being performed in the presence of the stabilizer or stabilizers with a monomer mixture, which a) contains at least one nonionic, ethylenically unsaturated monomer with a glass transition temperature Tg above about 30° C. in a quantity of about 10 to 70 wt. %, based on the total weight of ethylenically unsaturated (co)monomers and b) at least one hydrophilic, ethylenically unsaturated monomer in a quantity of about 5 to 30 wt. %, based on the total weight of ethylenically unsaturated (co)monomers.
    Type: Grant
    Filed: March 21, 2001
    Date of Patent: July 20, 2004
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Hongli Willimann, Robert Koelliker
  • Patent number: 6759490
    Abstract: The invention provides a process for preparing an aqueous polymer dispersion of a copolymer CP of at least two different monomers M1 and M2 by free-radical aqueous emulsion polymerization of the monomers M in the presence of at least one initiator, at least 80% of the monomers M and at least 75% of the initiator being supplied continuously to the polymerization reaction during its course, which comprises changing the rate at which the initiator is supplied to the polymerization reaction a number of times, or continuously, during the polymerization reaction. The invention further provides the polymer dispersions obtainable by this process, polymer powders prepared therefrom, and for the use of the dispersions and/or of the polymer powders to prepare pressure sensitive adhesives.
    Type: Grant
    Filed: February 19, 2002
    Date of Patent: July 6, 2004
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Gerst, Gerhard Auchter, Bernhard Schuler
  • Patent number: 6740703
    Abstract: A thickened aqueous coating composition (preferably paints and the like or adhesives) containing a film-forming polymeric binder which produces dried coatings having less sensitivity to water by using a thickener which is autoxidizable. Preferred autoxidizable moieties are provided by long chain fatty acids of the type used in alkyd paints and association is the preferred thickener mechanism. The moieties may form part of a compound which can take part in a copolymerization to form a cellulose-free polymeric backbone for the thickener and if the compound is not very soluble in water, the copolymerization mixture is subjected to intensive agitation to form droplets of less than 500 nm number average diameter which compensates for the lack of solubility. The thickener may serve as a binder if sufficient amounts are used.
    Type: Grant
    Filed: February 6, 2002
    Date of Patent: May 25, 2004
    Assignee: Imperial Chemical Industries PLC
    Inventors: Manish Sarkar, Stephane Patrick Belmudes
  • Patent number: 6627325
    Abstract: A polymer latex composition suitable for rubber articles comprises about 5 to about 65 weight percent of an aromatic vinyl monomer, about 35 to about 90 weight percent of a conjugated diene monomer, and about 0.5 to about 10 weight percent of a component selected from the group consisting of an unsaturated acid monomer, a partial ester of an unsaturated polycarboxylic acid, and mixtures thereof. The polymer latex composition has a gel content of no more than about 85 percent.
    Type: Grant
    Filed: August 4, 1998
    Date of Patent: September 30, 2003
    Assignee: Dow Reichhold Specialty Latex LLC
    Inventors: Kanchan Ghosal, Venkataram Krishnan
  • Patent number: 6617387
    Abstract: Ammonia-free polymer dispersions containing at least one copolymer which contains, as polymerized monomers, a) from 40 to 80% by weight of at least one ester of acrylic acid with C2-C12-alkanols, b) from 10 to 40% by weight of at least one vinylaromatic monomer and/or at least one ester of methacrylic acid with C1-C4-alkanols, c) from 2 to 15% by weight of at least one monoester of a C2-C10-alkanediol with acrylic acid or methacrylic acid, d) not more than 1% by weight of ethylenically unsaturated monomers which have at least one acid group, or salts thereof, e) less than 5% by weight of &agr;,&bgr;-ethylenically unsaturated nitrites and f) less than 1% by weight of amides of &agr;,&bgr;-ethylenically unsaturated mono- and dicarboxylic acids, and the polymer powders or polymer granules obtainable from the polymer dispersion, are used as additives for building materials based on hydraulic binders.
    Type: Grant
    Filed: August 20, 2001
    Date of Patent: September 9, 2003
    Assignee: BASF Aktiengesellschaft
    Inventors: Stefan Dreher, Joachim Pakusch, Bernd Reck
  • Publication number: 20030114616
    Abstract: An aqueous dispersion of a fluorocopolymer, which is excellent in stability and film-forming properties as an aqueous dispersion and which gives a coating film excellent in mechanical strength and improved in transparency, water resistance and stain resistance.
    Type: Application
    Filed: January 27, 2003
    Publication date: June 19, 2003
    Applicant: ASAHI GLASS COMPANY LIMITED
    Inventors: Toru Ishida, Naomi Ichikuni
  • Patent number: 6579956
    Abstract: A method for producing a polymer by coordination polymerization, comprising the steps of (a) reacting an unsaturated polar monomer having a functional group releasing a proton or a salt of the unsaturated polar monomer, with a masking agent comprising a halogenated organometallic compound or a organoaluminum compound capable of masking the functional group to form a corresponding masked monomer; and (b) polymerizing the masked monomer either alone or in combination with another monomer in the presence of the coordination polymerization catalyst to obtain the polymer.
    Type: Grant
    Filed: June 7, 2001
    Date of Patent: June 17, 2003
    Assignees: Kabushiki Kaisha Toyota Chuo Kenkyusho, University of Massachusetts
    Inventors: Hiromitsu Tanaka, Bruce M. Novak
  • Patent number: 6562779
    Abstract: Emulsifiable ethylene polymers comprising copolymers of from 90 to 95% by weight of ethylene, from 4 to 10% by weight of one or more C3-C12 alkenecarboxylic acids, and from 0 to 1.2% by weight of one or more tertiary esters of the corresponding C3-C12 alkenecarboxylic acids, where the wax has a cinematic melt viscosity of from 800 to 3000 mm2/s, measured at 120° C.; and a process for preparing the novel emulsifiable ethylene polymers, emulsions comprising the novel ethylene polymers, a process for preparing the emulsions from the novel ethylene polymers, and also floor cleaners, car cleaners, leather cleaners and stone cleaners, and coatings for surfaces made from wood, metal, paper, glass or from plastics, comprising aqueous emulsions of the novel emulsifable waxes.
    Type: Grant
    Filed: February 14, 2001
    Date of Patent: May 13, 2003
    Assignee: BASF Aktiengesellschaft
    Inventors: Lars Wittkowski, Andreas Deckers, Wilhelm Weber, Stefan Weiss, Michael Ehle, Siegfried Gast
  • Patent number: 6531556
    Abstract: A radical (co)polymerization of ethylene is carried out under high pressure in the presence of at least one initiating free radical (Z•) and of at least one controlling stable free radical (SFR•) which comprises the indoline nitroxide backbone represented by the formula (I). A is a hydrocarbonaceous chain forming an aromatic ring with the two carbon atoms to which it is attached, this ring being able to carry substituents or being able to carry one or more rings placed side by side, which rings are aromatic or aliphatic and optionally substituted, the carbon atoms forming the nitrogenous ring and in the alpha- and beta-position with respect to the nitrogen atom being able to carry hydrogen atoms or substituents.
    Type: Grant
    Filed: January 23, 2001
    Date of Patent: March 11, 2003
    Assignee: Atofina
    Inventors: Eric Minaux, Lucedio Greci, Michael Buback, Paul Tordo, Thierry Senninger, Pierluigi Stipa, Patricia Carloni, Elisabetta Damiani, Giampaolo Tommasi
  • Patent number: 6531563
    Abstract: Polymerization of a fatty acid or fatty acid derivatives containing conjugated double bonds and alkenes or alkynes containing electron acceptor substituents provides compositions useful as coatings, adhesives, sealants, fillers and the like.
    Type: Grant
    Filed: June 10, 1999
    Date of Patent: March 11, 2003
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Johann Klein, Kai Boege, Wolfgang Klauck
  • Patent number: 6512055
    Abstract: Copolymers I carrying functional groups and comprising a) 20-60 mol % of at least one monoethylenically unsaturated C4-C6-dicarboxylic acid or an anhydride thereof, b) 10-70 mol % of at least one oligomer of propene or of a branched 1-olefin of 4 to 10 carbon atoms, having an average molecular weight Mw of from 300 to 5000, and c) 1-50 mol % of at least one monoethylenically unsaturated compound which is copolymerizable with the monomers a) and b), a process for their preparation, oil-soluble reaction products obtainable therefrom by reaction with an amine and the use of said reaction products as additives for lubricants and fuels.
    Type: Grant
    Filed: May 4, 2001
    Date of Patent: January 28, 2003
    Assignee: BASF Aktiengesellschaft
    Inventors: Wolfgang Günther, Knut Oppenländer, Walter Denzinger, Heinrich Hartmann, Helmut Mach, Harald Schwahn, Hans Peter Rath
  • Patent number: 6495648
    Abstract: Toner binder resins with low odor and excellent charging stability as toners, containing styrene-acrylic copolymers or mixtures thereof, wherein the total content of volatile components is no greater than about 1,500 ppm, the content of volatile components with benzene rings is no greater than about 1,400 ppm, and the content of volatile components with benzene rings and boiling point of below about 200° C. is no greater than about 500 ppm.
    Type: Grant
    Filed: April 28, 2000
    Date of Patent: December 17, 2002
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Motoshi Inagaki, Koji Shimizu, Yoko Harada, Junya Nakamura
  • Publication number: 20020177068
    Abstract: Disclosed is a polymer for use in a chemically amplified resist, a resist composition including such a polymer is suitable for use in a chemically amplified resist, which is sensitive to far ultraviolet rays such as KrF or ArF excimer laser and forms a photoresist pattern having low dependence on and good adhesion to substrate, high transparency in the wavelength range of the above radiation, strong resistance to dry etching, and excellencies in sensitivity, resolution and developability. The resist composition can have a stronger etching resistance with a maximized content of unsaturated aliphatic ring in the polymer and a reduced edge roughness of the photoresist pattern with an alkoxyalkyl acrylate monomer employed.
    Type: Application
    Filed: February 11, 2002
    Publication date: November 28, 2002
    Inventors: Joohyeon Park, Dongchul Seo, Jongbum Lee, Hyunpyo Jeon, Seongju Kim
  • Patent number: 6482907
    Abstract: Olefins containing selected functional groups such as silyl, ether and alkenyl, and often containing a blocking group, may be copolymerized with unsubstituted olefins such as ethylene and propylene in the presence of certain coordination compounds of nickel or palladium. The resulting polymers are useful as molding resins, elastomers, in adhesives and for films.
    Type: Grant
    Filed: February 1, 2000
    Date of Patent: November 19, 2002
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Lin Wang, Samuel David Arthur, Elizabeth Forrester McCord, Yueli Wang, Peter Arnold Morken, Lynda Kaye Johnson
  • Patent number: 6476170
    Abstract: Described is a process for making acrylic resins suitable as polymeric surfactants used in emulsion polymerization, as pigment grinding resins and for preparing dispersions used as overprint varnishes. The feedstock is styrene, &agr;-methyl styrene, acrylic acid and a polymerization initiator and is preferably free of solvent. This mix is passed through a continuous tube reactor run at a controlled range of pressure and relatively low residence time and temperature. Optimally, when the polymer/unreacted monomers blend exits the reactor and is devolatilized, the recovered monomers are used to make up part of the feedstock.
    Type: Grant
    Filed: November 28, 2000
    Date of Patent: November 5, 2002
    Assignee: Cook Composites & Polymers Co.
    Inventors: George Roth, George A. Smith, Reuben Grinstein, Paul D. Whyzmuzis, Shruti Singhal, Steve Boucher, Brenda Taipale, Roger Lovald, David Devore, James P. Yosh, Jr., Stephen A. Fischer, Michael S. Wiggins
  • Patent number: 6350827
    Abstract: Disclosed is a process for pressurizing ethylenically unsaturated monomers to 200-5000 bar in the absence of a polymerization initiator, which comprises effecting said pressurizing in the presence of nitroxyl compounds of the formula I where R1 and R2 are singly C1-C4-alkyl or combine with the joining carbon atom to form a 5- or 6-membered saturated hydrocarbon ring, R3 is C1-C4-alkyl, and R4 is hydrogen or C1-C12-alkyl. Also disclosed are a process for preparing copolymers by such pressurization and subsequent polymerization and copolymers obtainable thereby.
    Type: Grant
    Filed: December 2, 1999
    Date of Patent: February 26, 2002
    Assignee: BASF Aktiengesellschaft
    Inventors: Heinz Friedrich Sutoris, Andreas Deckers, Wilhelm Weber
  • Patent number: 6331598
    Abstract: A process for preparing an emulsion polymer comprising placing a first mixture of monomers in a feed tank B which is connected directly to a reactor, placing a second mixture of monomers in a feed tank A which is connected to the feed tank B, and continuously varying the composition ratio of the monomers of feed tanks A and B in the emulsion polymer. The composition ratio is varied by varying the rate of feeding of the second mixture of monomers present in tank A into tank B while simultaneously varying the rate of feeding of the first mixture of monomers present in tank B into the reactor. The polymerization occurs as the first and second mixtures of monomers are simultaneously fluxed in the reactor while stirring.
    Type: Grant
    Filed: August 24, 1999
    Date of Patent: December 18, 2001
    Assignee: Korea Chemical Co., Ltd.
    Inventors: Jong-Myung Park, Chang-Ho Choi, Jung-Kwon Oh, Seung-Min Hong
  • Patent number: 6319978
    Abstract: The present invention is directed to improved vinyl acetate ethylene pressure sensitive adhesive emulsion polymers. The improvement in the aqueous based, emulsion polymerized pressure sensitive adhesives resides in: a high ethylene content copolymer having a Tg of from −25 to −70° C.; a tensile storage modulus measured at one hertz and at a temperature of −20° C. embraced by the points on a plot of storage modulus and temperature of from 1 times 106 and the points 4 times 109 dynes/cm2 and less that 1 times 107 dynes/cm2 measured at 50° C.
    Type: Grant
    Filed: October 1, 1998
    Date of Patent: November 20, 2001
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Christian Leonard Daniels, Chung-Ling Mao, Richard Henry Bott, Menas Spyros Vratsanos
  • Patent number: 6310163
    Abstract: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc.
    Type: Grant
    Filed: July 10, 1997
    Date of Patent: October 30, 2001
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Maurice S. Brookhart, Lynda Kaye Johnson, Christopher Moore Killian, Samuel David Arthur, Jerald Feldman, Elizabeth Forrester McCord, Stephan James McLain, Kristina Ann Kreutzer, Alison Margaret Anne Bennett, Edward Bryan Coughlin, Steven Dale Ittel, Anju Parthasarathy, Daniel Joseph Tempel
  • Publication number: 20010034428
    Abstract: The invention relates to a gelling aqueous composition comprising block copolymers containing at least one water-soluble block and at least one block predominantly hydrophobic in nature, and forming a viscoelastic gel.
    Type: Application
    Filed: February 20, 2001
    Publication date: October 25, 2001
    Inventors: Mathias Destarac, Mathieu Joanicot, Roland Reeb
  • Patent number: 6268442
    Abstract: A process for the reduction of reactor fouling at radical initiated high pressure polymerisation of ethylene (co)polymers is described. The process is characterised in that an adhesion reducing silicon containing compound is added to the polymerisation reactor, preferably in an amount of 0.001-3% by weight, based on the amount of polymer produced. Preferably the silicon containing compound is hexadecyl trimethoxy silane.
    Type: Grant
    Filed: September 8, 1999
    Date of Patent: July 31, 2001
    Assignee: Borealis A/S
    Inventors: Bill Gustafsson, Ruth Dammert, Jussi Laurell, Erik van Praet
  • Patent number: 6242540
    Abstract: Particles of a copolymer of a vinyl arene and a copolymerizable compound containing a polar moiety and a vinyl moiety containing water may be prepared by forming a mixture of monomers and small amounts of water and polymerizing under agitation to 20 to 70% conversion and then suspending the mass in water and finishing the polymerization. The resulting polymer beads contain finely dispersed water which is useful as an environmentally acceptable blowing agent.
    Type: Grant
    Filed: December 30, 1998
    Date of Patent: June 5, 2001
    Assignee: Nova Chemicals (International) S.A.
    Inventors: Jeroen Joost Crevecoeur, Eric Wilhelmus Johannes Frederik Neijman, Laurentius Nicolaas Ida Hubertus Nelissen, Johannes Maria Zijderveld
  • Patent number: 6197884
    Abstract: This invention is directed towards golf balls comprising at least a cover and a core, and optionally one or more intermediate layers, wherein the cover and/or the intermediate layer(s) are formed from a high crystalline copolymer or its ionomer derivatives and blends thereof, wherein the high crystalline copolymer is formed from an ethylene/carboxylic acid copolymer comprising about 5 to about 35 percent by weight acrylic or methacrylic acid, wherein the copolymer is polymerized at a temperature of about 130° C. to 200° C. at pressures of at least 20,000 psi to about 50,000 psi, wherein up to about 70 percent of the acid groups are neutralized with a metal ion.
    Type: Grant
    Filed: March 23, 1999
    Date of Patent: March 6, 2001
    Assignee: Acushnet Company
    Inventors: Murali Rajagopalan, Robert Joseph Statz
  • Patent number: 6197879
    Abstract: A polymer useful as an inorganic pigment dispersant is provided. The polymer is derived from monomers consisting essentially of an ethylenically unsaturated aromatic monomer, an ethylenically unsaturated dicarboxylic acid monomer, and an ethylenically unsaturated monocarboxylic acid monomer. The total amount of said ethylenically unsaturated acid monomers is sufficient to permit said polymer to associate with an inorganic pigment in an aqueous medium in a manner which disperses said inorganic pigment in said aqueous medium to form a stable aqueous dispersion of said inorganic pigment, and the amount of said ethylenically unsaturated aromatic monomer is sufficient to reduce the water sensitivity of a dried coating of a latex paint comprised of said stable aqueous dispersion of said inorganic pigment. A process of preparing a polymer useful as an inorganic pigment dispersant and a method of preparing an inorganic pigment dispersion useful in the preparation of latex paints are also provided.
    Type: Grant
    Filed: September 13, 1996
    Date of Patent: March 6, 2001
    Assignee: Henkel Corporation
    Inventors: Stephen A. Fischer, Michael S. Wiggins, Bruce Matta, Eric Nowicki