Abstract: A process for the preparation of a polymer nanoparticle by a photoinduced emulsion polymerization includes preparing an emulsion comprising at least one surfactant, a dispersed phase and a continuous phase. The dispersed phase comprises at least one polymerizable monomer and the continuous phase comprises water and at least one photoinitiator. The at least one polymerizable monomer is polymerized by exposing the emulsion to an electromagnetic radiation having a wavelength so as to induce a generation of radicals from the at least one photoinitiator.

Abstract: The invention describes an emulsion polymer which can be obtained by polymerization of a mixture comprising a) from 5 to 99.9% by weight of one or more monomers having a solubility in water of <2% by weight at 20° C. and selected from the group consisting of monofunctional (meth)acrylate monomers, styrene and vinyl esters; b) from 0 to 70% by weight of one or more monomers which can be copolymerized with the monomers a); c) from 0 to 20% by weight of one or more doubly or multiply vinylically unsaturated compounds; d) from 0 to 20% by weight of one or more polar monomers having a solubility in water of >2% by weight at 20° C.; and e) 0.

Abstract: An adhesive composition which is reduced in gas generation upon heating (has low hygroscopicity), has high alkali resistance, has heat resistance of 200° C. or higher, and can be easily removed with a stripping liquid; and an adhesive film made with the adhesive composition. The adhesive composition is prepared using, at least as a major ingredient, an acrylic polymer produced from (a) styrene, (b) a (meth)acrylic ester monomer containing a cyclic skeleton, and (c) an alkyl (meth)acrylate monomer. The adhesive film has an adhesive composition layer formed from this adhesive composition.

Abstract: Styrenic (meth)acrylic oligomers that are prepared at lower temperature than conventional solid grade oligomers, or are hydrogenated, contain fewer terminal vinylic unsaturations, when compared to such conventional styrenic (meth)acrylic oligomers prepared by the customary high temperature processes. Styrenic (meth)acrylic oligomers that contain fewer terminal vinylic unsaturations demonstrate improved thermal stability and may provide improved resistance to UV weathering compared to the conventional and non-hydrogenated styrenic (meth)acrylic oligomers.

Abstract: A method of preparing polymer, the method comprising polymerising one or more ethylenically unsaturated monomers of formula (I) where U is selected from H, C1-C4 alkyl or halogen; V is halogen or of the form O-G where G is selected from —C(O)R1 and —R1, or V is of the form NGGa where G is as defined above and Ga is selected from H and R1, G and Ga form together with N a heterocyclic ring, or V is of the form CH2Gb where Gb is selected from H, R1, OH, OR1, NR12, PR12, P(O)R12, P(OR1)2, SR1, SOR1, and SO2R1; and where the or each R1 is independently selected from optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted aryl, optionally substituted heteroaryl, optionally substituted carbocyclyl, optionally substituted heterocyclyl, optionally substituted arylalkyl, optionally substituted heteroarylalkyl, optionally substituted alkylaryl, optionally substituted alkylheteroaryl, and an optionally substituted polymer chain, under the control of a RA

Abstract: The invention relates to methyl methacrylate characterized in that at least one portion of the carbons thereof is biologically sourced and, more specifically, in that it contains between 0.2×10?10 and 1.2×10?10 wt.-% of 14C in relation to total carbon weight according to the ASTM D6866 standard. The preparation method comprises the use of acetone cyanohydrin as a raw material, said acetone cyanohydrin being obtained by condensing cyanohydric acid on acetone, and the methyl methacrylate is prepared using a process involving the addition of methanol. According to the invention, at least one from among the acetone, cyanohydric acid and methanol is obtained by means of a reaction or series of reactions involving the biomass.

Abstract: A method for varying the transport properties of a film cast from a polymer having at least two polymer end blocks A and at least one polymer interior block B wherein each A block is a polymer block resistant to sulfonation and each B block is a polymer block susceptible to sulfonation, and wherein said A and B blocks do not contain any significant levels of olefinic unsaturation. The method includes casting the polymer using a solvent mixture having two or more solvents selected from the group consisting of polar solvents and non-polar solvents.

Abstract: The invention relates to the use of comb polymers comprising repeating units in the main chain which repeating units are derived from polyolefin-based macromonomers having a molecular weight of at least 500 g/mol, and repeating units which are derived from low-molecular monomers having a molecular weight of less than 500 g/mol as antifatigue additives in lubricants. The invention further relates to novel comb polymers and methods for the production thereof and to lubricating oils comprising said comb polymers.

Abstract: The present invention relates to an acrylic copolymer resin containing: 1) an alklyl (meth)acrylate-based monomer; 2) a (meth)acrylate-based monomer containing an aliphatic ring and/or an aromatic ring; and 3) at least an imide-based monomer or a styrene-based monomer, to a resin composition containing said acrylic copolymer resin and a resin containing an aromatic ring and/or an aliphatic ring in the main chain thereof, to an optical film comprising said resin composition, and to a liquid crystal display device comprising said optical film. The optical film according to the present invention has excellent heat resistance, optical transparency, etc.

Abstract: A sulfonated block copolymer which is solid and non-dispersible in water having at least two polymer end blocks A and at least one polymer interior block B wherein each A block is a polymer containing essentially no sulfonic acid or sulfonate functional groups and each B block is a polymer block containing 10 to 100 mol percent sulfonic acid or sulfonate functional groups based on the number of monomer units of the B block, and wherein said A and B blocks do not contain any significant levels of olefinic unsaturation. Also claimed are processes for making such block copolymers, and the various end uses and applications for such block copolymers.

Abstract: The present invention provides a block copolymer of styrene and an unsaturated cyclic anhydride, such as maleic anhydride, a process for making a copolymer using controlled free radical polymerization in which certain parameters are adjusted to control the microstructure and molecular weight of the copolymer, and a method for using the block copolymer, including as a compatibilizer. Microstructure and molecular weight in the block copolymer can be controlled by adjusting the ratio of stable free radical to initiator. The copolymer can be made in a one step process and has a controlled microstructure that allows one block to be reactive toward several chemical moieties available in engineering polymers and the other block to be fully miscible with polystyrene or polymers miscible with polystyrene or polymers miscible with polystyrene such as polyphenylene ether.

Abstract: A process for preparing sulfonated block copolymers that are solid in water having at least two polymer end blocks A and at least one polymer interior block B involving sulfonating the interior block B until substantially sulfonated. Each A block having one or more segments selected from polymerized (i) para-substituted styrene monomers, (ii) ethylene, (iii) alpha olefins of 3 to 18 carbon atoms; (iv) hydrogenated 1,3-cyclodiene monomers, (v) hydrogenated monomers of conjugated dienes having a vinyl content less than 35 mol percent prior to hydrogenation, (vi) acrylic esters, (vii) methacrylic esters, and (viii) mixtures thereof. Each B block having segments of one or more polymerized vinyl aromatic monomers selected from (i) unsubstituted styrene monomers, (ii) ortho-substituted styrene monomers, (iii) meta-substituted styrene monomers, (iv) alpha-methylstyrene, (v) 1,1-diphenylethylene, (vi) 1,2-diphenylethylene and (vii) mixtures thereof.

Abstract: An adhesive composition according to the present invention is an adhesive composition whose main component is a polymer obtained by copolymerization of a monomer composition, which monomer composition contains styrene, (meth)acrylic ester having a cyclic structure, and alkyl (meth)acrylate having a chain structure. The polymer thus having a styrene block segment allows improvement of thermal resistance, adhesive strength in a high temperature environment, alkaline resistance, and easiness in stripping following a high temperature process of the adhesive composition. As such, an adhesive composition is provided, which has high thermal resistance, adhesive strength in the high temperature environment, and alkaline resistance, and further which can easily carry out stripping of the adhesive composition after a high temperature process has been carried out to the adhesive composition.

Abstract: A sulfonated block copolymer which is solid and non-dispersible in water having at least two polymer end blocks A and at least one interior block B wherein each A block is a polymer block resistant to sulfonation and each B block is a polymer block susceptible to sulfonation, wherein the A and B blocks do not contain any significant levels of olefinic unsaturation. Each A block having one or more segments selected from (i) acrylic esters, (ii) methacrylic esters, and (viii) mixtures thereof; and each B block comprising segments of one or more polymerized vinyl aromatic monomers selected from (i) unsubstituted styrene monomers, (ii) ortho-substituted styrene monomers, (iii) meta-substituted styrene monomers, (iv) alpha-methylstyrene, (v) 1,1-diphenylethylene, (vi) 1,2-diphenylethylene and (vii) mixtures thereof.

Abstract: A multibranched polymer represented by the following formula (I), and a method for producing the multibranched polymer: where A represents an organic group having 3 or more branched chains, Xa represents a linking group containing any atom of Groups 14 to 16 in the Periodic Table, Y represents a functional group having a structure capable of having an active halogen atom, Q represents an arm moiety having a repeating unit derived from a polymerizable unsaturated bond, m1 represents any integer of 1 to the number of branched chains of A, m2 represents the number of branched chains of A, n1 represents an integer of 0 or 1 or more, and Ra represents an organic group that is not associated with the polymerization reaction.

Abstract: Aqueous treatment composition for use as anti-scalant and dispersant. The composition includes a polymer containing low amounts of sulfonate that prove as effective in carbonate and phosphate inhibition as polymers containing much higher amounts of sulfonate.

Abstract: The present invention provides a copolymer that includes at least one alkene monomer, at least one acrylate monomer and at least one the unsaturated organic acid monomer having one or more double bonds, and a method of manufacturing the same.

Abstract: According to an aspect of the present invention, implantable or insertable medical devices are provided, which contain one or more polymeric regions. These polymeric regions, in turn, contain one or more polymers, at least one of which is a copolymer that includes a styrene monomer and an isobutylene monomer. Moreover, the styrene monomer content of the copolymer typically ranges from 25 to 50 mol %.

Abstract: Disclosed herein is a resin composition for an organic insulating layer, a method of manufacturing the same, and a display panel including an insulating layer formed using the resin composition. The resin composition for an organic insulating layer is produced by polymerizing about 5 to about 35 wt % of an unsaturated carboxylic acid, an unsaturated carboxylic acid anhydride, or a mixture of the unsaturated carboxylic acid and the unsaturated carboxylic acid anhydride, about 5 to about 40 wt % of a styrene compound, about 5 to about 40 wt % of an epoxy compound, about 0.1 to about 10 wt % of an isobornyl compound, and about 20 to about 40 wt % of a dicyclopentadiene compound, based on the total weight of unsaturated carboxylic acid, unsaturated carboxylic acid anhydride, styrene compound, isobornyl compound, and dicyclopentadiene compound.

Abstract: The present invention provides coating systems for surfaces and methods for coating and repairing surfaces.

Abstract: A flame retardant molding composition includes a rubber modified aromatic vinyl resin, a polyphenylene ether resin, and a cyclic phosphonate ester compound. A shaped article and an electronic device can be made from the flame retardant molding composition.

Abstract: A polymer composition includes a rubber modified vinyl resin, a polyphenylene ether resin, a cyclic alkyl phosphate compound, and an aromatic phosphate ester. In some embodiments, the cyclic alkyl phosphate compound is able to impart good flame retardancy to the composition and thermal resistance to the polymer composition.

Abstract: Drug delivery of resistance reversal agents by polyacrylate nanoparticles for treatment of drug (e.g. chloroquine) resistant malaria. Also provided are drug delivery by polyacrylate nanoparticles of ciprofloxacin for treatment of anthrax.

Abstract: An adhesive composition according to the present invention is an adhesive composition whose main component is a polymer obtained by copolymerization of a monomer composition, which monomer composition contains styrene, (meth)acrylic ester having a cyclic structure, and alkyl (meth)acrylate having a chain structure. The polymer thus having a styrene block segment allows improvement of thermal resistance, adhesive strength in a high temperature environment, alkaline resistance, and easiness in stripping following a high temperature process of the adhesive composition. As such, an adhesive composition is provided, which has high thermal resistance, adhesive strength in the high temperature environment, and alkaline resistance, and further which can easily carry out stripping of the adhesive composition after a high temperature process has been carried out to the adhesive composition.

Abstract: A polymer composition includes a substantially transparent, rubber modified aromatic vinyl resin and a cyclic alkyl phosphate compound. In some embodiments, the cyclic alkyl phosphate compound is able to impart good flame retardancy, while maintaining a good balance of the other physical and mechanical properties of the resin including the transparency and impact strength of the resin.

Abstract: A polymer composition includes a rubber modified aromatic vinyl resin and a cyclic alkyl phosphate compound. In some embodiments, the cyclic alkyl phosphate compound is able to impart good flame retardancy to the composition, while maintaining a good balance of the other physical and mechanical properties of the resin including Vicat Softening Temperature and impact strength.

Abstract: A curable composition includes an olefinically unsaturated monomer and a poly(arylene ether) having two polymerizable groups and an intrinsic viscosity of about 0.05 to about 0.30 deciliters per gram. The composition exhibits an improved combination of high flow during molding and high post-cure stiffness and impact strength. The composition is particularly useful for fabricating plastic-packaged electronic devices.

Abstract: A polymer composition includes a rubber modified vinyl resin, a cyclic alkyl phosphate compound, and an aromatic phosphate ester. Some embodiments may additionally comprises a polyphenylene ether resin. In some embodiments, the compositions have good flame retardancy, color stability, impact resistance, and thermal stability.

Abstract: The present invention provides a copolymer that includes at least one alkene monomer, at least one acrylate monomer and at least one the unsaturated organic acid monomer having one or more double bonds, and a method of manufacturing the same.

Abstract: A method for the in-situ preparation of an ionic comonomer, such as zinc dimethacrylate, dissolved in styrene monomer, for use in production of polystyrene is disclosed. The method generally includes adding comonomer chemical precursors to a solution of styrene and nonionic surfactant. The resulting ionic comonomer may be further dissolved in styrene and polymerized to form a product that may have improved properties.

Abstract: UV-crosslinkable acrylic hotmelt pressure sensitive adhesives comprising acrylic and vinyl monomers, and a polymerizable UV photoinitiator. The photoinitiator comprises a spacer comprising both ethylene oxide and urethane, or urea, carbonate, or siloxane functional groups. The ethylene oxide is directly bonded to the chromophore (e.g., benzophenone) moiety, while the urethane (or urea, carbonate, siloxane) is closely linked to the polymerizable moiety (e.g., styrenic C?C double bond).

Abstract: The present invention concerns a controlled structure copolymer comprising at least two different parts, a first part A, amphoteric or zwitterionic, including anionic or potentially anionic units, and cationic or potentially cationic units, or zwitterionic units, and another part B, non amphoteric or zwitterionic. Said copolymer further exhibits a high potential for adaptation, through variation in its composition, in order to improve or modify the properties of compositions in which it is introduced.

Abstract: The invention relates to a process for production of methacrylic acid, to a process for production of methyl methacrylate comprising the process steps a) providing a feed composition comprising at least one C4 feed compound selected from isobutylene and tertiary butanol; b) providing methanol; c) subjecting the at least one C4 feed compound and the methanol to a first catalytic reaction zone to obtain a reaction phase comprising methyl tertiary butyl ether; d) separating at least a first part of methanol from the reaction phase to obtain a first methanol phase and a reaction phase depleted in methanol; e) subjecting at least one of the reaction phase and the reaction phase depleted in methanol to a second catalytic reaction zone to obtain a splitting phase comprising isobutylene and methanol; f) optionally separating at least a first part of isobutylene from the second reaction phase to obtain a first isobutylene phase and a splitting phase depleted in isobutylene; g) optionally subjecting the first isobutyle

Abstract: A polymer composition includes a rubber-modified aromatic vinyl resin and a cyclic phosphonate ester compound. Embodiments of the composition demonstrate good impact strength, flame retardancy, heat resistance. Some embodiments additionally demonstrate moisture resistance and low heat sag. A shaped article and an electronic device can be made from the flame retardant polymer composition.

Abstract: Alkyldiketene-containing aqueous polymer dispersions which are obtainable by miniemulsion polymerization of hydrophobic monoethylenically unsaturated monomers in the presence of alkyldiketenes, processes for the preparation of such polymer dispersions and the use of the thus obtainable dispersions as sizes for paper or as water repellents for leather, natural and/or manmade fibers and textiles.

Abstract: A polymeric dispersant having a block copolymer structure or a segmented oligomer structure wherein the block copolymer structure or segmented oligomer structure includes a segment polymerized by monomers according to Formula (I): wherein; R1 represents hydrogen or methyl; Y represents O, S, or NH; Aryl represents an aromatic group or a heteroaromatic group; and X represents hydrogen, an alkyl group, or a cation. A process for manufacturing the polymeric dispersant and the application of the polymeric dispersant in pigment dispersions, inkjet inks, and colored layers.

Abstract: Composition comprising at least one ethylenically unsaturated monomer to which a photochemically isomerizable or dimerizable molecule is covalently bonded, and at least one ethylenically unsaturated monomer to which a sensitizer is covalently bonded, are outstandingly suitable for producing polymeric alignment layers for liquid crystals.

Abstract: An object of the present invention is to provide a light diffuser plate (1) which can illuminate the front side more brightly when incorporated in a surface light source (3) constituting a transmissive image display (2). The light diffuser plate of the present invention comprises a transparent resin and a light diffuser dispersed in the transparent resin, wherein the transparent resin is a transparent resin which has a light transmittance [T600] at a wavelength of 600 nm of 85% or more measured with respect to a thickness of a 2 mm thick plate-shaped specimen, and a ratio [T365/T600] of a light transmittance [T365] at a wavelength of 365 nm to the light transmittance [T600] is 0.90 to 0.99. The transparent resin is polystyrene or the like, an average particle diameter of the light diffuser is from 0.5 to 5 ?m, an absolute value [|?n|] of a difference in a refractive index between the light diffuser and the transparent resin is 0.05 or more, an amount of the light diffuser is from 0.

Abstract: A thermoplastic transparent resin which is produced by hydrogenating 70% or more of aromatic double bonds of a copolymer. The copolymer is produced by polymerizing a monomer composition containing at least one (meth)acrylic ester monomer and at least one aromatic vinyl monomer and has a molar ratio (A/B) of from 1 to 4 wherein A is a molar amount of a constitutional unit derived from the (meth)acrylic ester monomer and B is a molar amount of a constitutional unit derived from the aromatic vinyl monomer. The thermoplastic transparent resin is suitable for the production of a molded article such as optical article having a good color tone because molding defect is less produced.

Abstract: A coating composition comprises at least one material dispersed in a vinyl or acrylic polymer, wherein the vinyl or acrylic polymer comprises (a) one or more anchor group monomer units (a) having an ionizable or active hydrogen functionality or a functionality that forms a covalent bond with the dispersed material, wherein the ionizable functionality is other than a carboxylic acid group in which the carbonyl carbon is separated from the closest ethylenically unsaturated carbon by at least four atoms and the anchor group monomer units (a) are other than those having polyoxyalkylene groups; (b) about 5% to about 45% by weight of one or more stabilizer monomer units (b) having a carboxylic acid group in which the carbonyl carbon is separated from the closest ethylenically unsaturated carbon by at least four atoms, having polyoxyalkylene groups, having gamma-hydroxy carbamate or beta-hydroxy carbamate groups, and combinations thereof; and (c) up to about 50 percent by weight of aromatic monomer units.

Abstract: The present invention relates to a process for preparing a resin binder for toner, comprising the steps of (A) carrying out an addition polymerization reaction of addition polymerization resin monomers including styrene in the presence or absence of an organic solvent; and (B) mixing the resulting reaction mixture from the step (A) with water at a rate of 0.002 to 0.5 parts by weight based on 100 parts by weight of the addition polymerization resin monomers per minute at a temperature of 100° to 300° C. during and/or after the step (A), wherein the amount of water to be mixed in the step (B) is 0.1 to 50 parts by weight based on 100 parts by weight of the addition polymerization resin monomers. The resin binder for a toner obtained according to the present invention can be used, for instance, for developing electrostatic latent images formed in electrophotography, electrostatic recording method, electrostatic printing method, and the like, and a toner containing the resin binder.

Abstract: Silicone-containing addition polymers having numerous uses are prepared by polymerizing addition polymerizable monomers in the presence of a silicone-containing polyvinyl alcohol, and/or by adding a silicone-containing polyvinyl alcohol to an aqueous addition polymer dispersion prior to spray drying, the silicone-containing polyvinyl alcohol containing at least one polymerizable group.

Abstract: A polymer composition for use in forming a stent is described. The composition includes a monomer of an aliphatic ester of acrylic acid which has a glass transition temperature less than 25° C. and a second monomer that copolymerizes with the first monomer and which has a glass transition temperature greater than 25° C. The components in the composition are mixed in amounts suitable to give a copolymer having a glass transition temperature less than 25° C., or in case of block copolymers, having at least one glass transition temperature less than 25° C. A stent including polymer members formed from the described composition is also disclosed.

Abstract: The present invention provides pressure-sensitive adhesives having a refractive index of at least 1.48. The pressure-sensitive adhesives comprise at least one monomer containing a substituted or an unsubstituted aromatic moiety.

Abstract: The present invention is directed to sulfine control agents for synthesizing polymers via controlled free radical polymerization and to the polymers resulting therefrom. Such polymers include repeat units derived from the controlled free radical polymerization, particularly reversible atom fragmentation transfer (RAFT) polymerization, of at least one vinyl-containing monomer, at least one conjugated diene monomer, or combinations thereof, in the presence of a sulfine compound having the formula: wherein R1 is alkyl, cycloalkyl, substituted alkyl, heteroalkyl, heterocycloalkyl or substituted heterocycloalkyl, and wherein Y is alkyl, cycloalkyl, substituted alkyl, heteroalkyl, heterocycloalkyl, substituted heterocycloalkyl, aryl, substituted aryl, heteroaryl, substituted heteroaryl, alkoxy, amino or thio.

Abstract: The present invention relates to a composition and process for enhancing the controlled radical polymerization in the presence of nitroxyls and nitroxylethers by adding a chain transfer agent selected from the group consisting of mercaptanes, thioethers and disulfides to the polymerizable mixture. A further subject of the invention is the use of mercaptanes, thioethers and disulfides for increasing rate and yield of controlled radical polymerizations in the presence of a nitroxyl or a nitroxylether.

Abstract: The present invention provides a block copolymer of styrene and an unsaturated cyclic anhydride, such as maleic anhydride, a process for making a copolymer using controlled free radical polymerization in which certain parameters are adjusted to control the microstructure and molecular weight of the copolymer, and a method for using the block copolymer, including as a compatibilizer. Microstructure and molecular weight in the block copolymer can be controlled by adjusting the ratio of stable free radical to initiator. The copolymer can be made in a one step process and has a controlled microstructure that allows one block to be reactive toward several chemical moieties available in engineering polymers and the other block to be fully miscible with polystyrene or polymers miscible with polystyrene or polymers miscible with polystyrene such as polyphenylene ether.

Abstract: The invention provides derivatives of poly(styrene-co-allylalcohol). These materials are useful as thermosetting monomers that can be incorporated into adhesive compositions. In some embodiments, the adhesive compositions are useful in the microelectronic packaging industry.

Abstract: A styrene copolymer composition comprising at least one alkyl acrylate and/or at least one alkyl methacrylate wherein the styrene copolymer composition has a bimodal molecular weight distribution. A method of producing a styrene copolymer comprising reacting styrene and at least one alkyl acrylate and/or at least one alkyl methacrylate, wherein the alkyl acrylate comprises an alkyl group having from 8 to 12 carbon atoms and the alkyl methacrylate comprises an alkyl group having equal to or greater than 10 carbon atoms. A method of increasing the molecular weight distribution in a styrene copolymer comprising incorporating at least one alkyl acrylate and/or at least one alkyl methacrylate wherein the styrene copolymer has a polydispersity index equal to or greater than 3.

Abstract: The invention relates to a polymer synthesized from 0.5 to 30% by weight of vinyl acetate (a), from 0.1 to 10% by weight of monomer containing at least one acid or acid anhydride group (b), from 5 to 70% by weight of at least one monomer other than (a) and (b), having a solubility of more than 5 g/l water (21° C., 1 bar) and a glass transition temperature of less than 15° C. (c), from 0 to 20% by weight of a vinylaromatic monomer having a solubility of less than 5 g/l water (d), from 0 to 90% by weight of at least one C1 to C20 alkyl (meth)acrylate (e) other than (a) to (d), and from 0 to 40% by weight of at least one further monomer (f) other than (a) to (e).