Stretched Product Patents (Class 526/348.1)
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Patent number: 11643546Abstract: Polymeric compositions comprising a polybutylene terephthalate; a low-density polyolefin selected from a low-density polyethylene, a polyolefin elastomer, or combinations thereof; and a maleated ethylene-based polymer. Optical cable components fabricated from the polymeric composition. Optionally, the polymeric composition can further comprise one or more additives, such as a filler. The optical fiber cable components can be selected from buffer tubes, core tubes, and slotted core tubes, among others.Type: GrantFiled: July 18, 2018Date of Patent: May 9, 2023Assignees: UNION CARBIDE CORPORATION, ROHM AND HAAS COMPANYInventors: Michael Q. Tran, Mohamed Esseghir
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Patent number: 11535012Abstract: Laminated film structure including at least one first film having a thin ceramic or metal coating, being laminated to a second film and whereby the laminated film structure is based on polyethylene only, i.e. polymers other than polyethylene are substantially absent and whereby the laminated film structure has good barrier properties.Type: GrantFiled: December 13, 2016Date of Patent: December 27, 2022Assignee: Borealis AGInventors: Peter Niedersüss, Nina Ackermans, Paulo Cavacas, Willem De Wever, Johan Defoer
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Patent number: 11326005Abstract: Catalyst compositions containing a metallocene compound, a solid activator, and a co-catalyst, in which the solid activator or the supported metallocene catalyst has a d50 average particle size of 15 to 50 ?m and a particle size distribution of 0.5 to 1.5, can be contacted with an olefin in a loop slurry reactor to produce an olefin polymer. A representative ethylene-based polymer produced using the catalyst composition has excellent dart impact strength and low gels, and can be characterized by a HLMI from 4 to 10 g/10 min, a density from 0.944 to 0.955 g/cm3, a higher molecular weight component with a Mn from 280,000 to 440,000 g/mol, and a lower molecular weight component with a Mw from 30,000 to 45,000 g/mol and a ratio of Mz/Mw ranging from 2.3 to 3.4.Type: GrantFiled: July 8, 2021Date of Patent: May 10, 2022Assignee: Chevron Phillips Chemical Company LPInventors: Max P. McDaniel, Carlton E. Ash, Kathy S. Clear, Eric D. Schwerdtfeger, Carlos A. Cruz, Jeremy M. Praetorius, Youlu Yu
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Patent number: 11066499Abstract: An ethylene alpha-olefin copolymer having (a) a density of from about 0.910 g/cc to about 0.940 g/cc; (b) a weight average molecular weight of from about 150,000 g/mol to about 300,000 g/mol; and (c) a melt index at a load of 2.16 kg of from about 0.01 dg/10 min. to about 0.5 dg/min.; wherein a 1 mil blown film formed from the polymer composition is characterized by (i) a Dart Impact strength greater than about 175 g/mil; (ii) an Elmendorf machine direction tear strength greater than about 20 g/mil; and (iii) an Elmendorf transverse direction tear strength greater than about 475 g/mil.Type: GrantFiled: October 12, 2020Date of Patent: July 20, 2021Assignee: Chevron Phillips Chemical Company LPInventors: Ashish M. Sukhadia, Guylaine St. Jean, Qing Yang, Max P. McDaniel
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Patent number: 10954360Abstract: A process for extruding polypropylene comprising extruding a composition comprising a polypropylene and a second acid scavenger and less than about 10 ppm of a nucleating agent.Type: GrantFiled: May 24, 2018Date of Patent: March 23, 2021Assignee: Milliken & CompanyInventors: Kemper D. Lake, Jr., Christopher T. Kochanowicz, Joseph J. Peterson, Clifford S. Bynum, Keith A. Keller
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Patent number: 10844206Abstract: The present invention relates to a polypropylene-based resin composition which exhibits mechanical properties such as excellent strength and more improved impact strength, and a molded article comprising the same. The polypropylene-based resin composition comprises: a polypropylene-based resin; and an olefin-based copolymer, and shows two or more elution temperatures at a predetermined temperature range when analyzing the olefin-based copolymer by temperature rising elution fractionation (TREF).Type: GrantFiled: September 18, 2017Date of Patent: November 24, 2020Assignee: LG Chem, Ltd.Inventors: Hyo Ju Kim, In Sung Park, Sang Eun Park, Hae Woong Park, Kyung Bok Bae, Choong Hoon Lee
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Patent number: 10793707Abstract: A composition having a) an ethylene-based copolymer made of units derived from ethylene and units derived from at least one comonomer of Structure I, wherein R is a C1-C2 hydrocarbyl group and R? is a C1-C4 hydrocarbyl group; b) at least one antioxidant; c) from greater than 0 wt % to less than 3 wt % of an organic peroxide, based on the total weight of the composition; d) optionally, at least one co-agent; and e) optionally, at least one tree retardant, wherein the ethylene-based copolymer has a melt temperature (Tm) (° C.) and a comonomer content in moles per 100 grams ethylene-based copolymer (mol/100 g) (comonomer) that satisfies the relationship Tm<?73.022 (comonomer)+109.3.Type: GrantFiled: November 16, 2017Date of Patent: October 6, 2020Assignee: Dow Global Technologies LLCInventors: Yabin Sun, Jeffrey M. Cogen, Manish Mundra, Timothy J. Person
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Patent number: 10494748Abstract: A non-woven fabric that absorbs only a small amount of volatile low molecular weight compound, and that has good texture when used as a non-woven fabric that makes contact with human skin. This thermal bond non-woven fabric containing cyclic olefin resin includes at least: fibers (A) containing at least 50 mass % of a cyclic olefin resin (A1) having a glass transition temperature TgA1° C.; and fibers (B) containing at least 10 mass % of either a cyclic olefin resin (B1) having a glass transition temperature TgB1° C., or a crystalline thermoplastic resin (B2) having a melting point MpB2° C.; the fibers (A) and the fibers (B) being heat-spliced together; wherein TgA1>TgB1 or TgA1>MpB2, and either the difference between the glass transition temperature TgA1° C. and the glass transition temperature TgB1° C. or the difference between the glass transition temperature TgA1° C. and the melting point MpB2° C. exceeds 20° C.Type: GrantFiled: May 10, 2016Date of Patent: December 3, 2019Assignee: Polyplastics Co., Ltd.Inventor: Hidetoshi Okawa
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Patent number: 10435551Abstract: Injection molded article comprising at least 60 wt.-% of a heterophasic propylene copolymer, said polymer comprises a matrix being a polypropylene, said polypropylene comprises at least three polypropylene fractions, the three polypropylene fractions differ from each other by the melt flow rate and at least one of the three polypropylene fractions has a melt flow rate in the range of 1.0 to 20.0 g/10 min, and an elastomeric propylene copolymer dispersed in said matrix, wherein said heterophasic propylene copolymer has a melt flow rate of equal or more than 20.0 g/10 min and the amorphous phase of the xylene cold soluble fraction of the heterophasic propylene copolymer has an intrinsic viscosity of equal or higher than 2.0 dl/g.Type: GrantFiled: January 31, 2013Date of Patent: October 8, 2019Assignee: Borealis AGInventors: Cornelia Tranninger, Stefan Schiesser, Balakantha rao Kona, Andreas Hauer
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Patent number: 10287408Abstract: Provided is a resin film having excellent size stability in a high-temperature environment. A resin film formed of a resin containing an alicyclic structure-containing polymer having crystallizability, wherein an absolute value of a thermal size change ratio when the film is heated at 150° C. for 1 hour is 1% or less in any in-plane direction of the film. The alicyclic structure-containing polymer may preferably be a hydrogenated product of a ring-opened polymer of dicyclopentadiene. Also provided is a method for producing the resin film including a step of relaxing strain of the crystallized film while the crystallized. film is kept flat.Type: GrantFiled: October 9, 2015Date of Patent: May 14, 2019Assignee: ZEON CORPORATIONInventors: Toshihide Murakami, Satoshi Yamada, Yasunori Ii
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Patent number: 10280242Abstract: The present application relates to a propylene ethylene random copolymer exhibiting two melting temperatures (Tm) which differ from each other.Type: GrantFiled: May 28, 2014Date of Patent: May 7, 2019Inventors: Joko Priatmoko, Vassilios Galiatsatos
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Patent number: 10087268Abstract: Disclosed are methods for polymerizing olefin monomers comprising contacting one or more olefin monomers with a cosupported catalyst system and an activator. Also disclosed are polymers produced using the catalyst systems and methods disclosed herein. The polymers have a multimodal molecular weight distribution and may be produced in a single reactor.Type: GrantFiled: August 31, 2016Date of Patent: October 2, 2018Assignee: ExxonMobil Chemical Patents Inc.Inventors: Glen E. Alliger, Laughlin G. McCullough
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Patent number: 9963525Abstract: [Problem] To provide an ethylene-?-olefin copolymer having high mechanical strength and good molding properties. [Solution] Provided is an ethylene-?-olefin copolymer having a specific MFR, a specific density, and a specific molecular weight distribution, containing a suitable amount of a long-chain branching structure characterized by a branching index, and having a specific composition distribution structure characterized by solvent fractionation behavior.Type: GrantFiled: March 31, 2015Date of Patent: May 8, 2018Assignee: JAPAN POLYETHYLENE CORPORATIONInventors: Yoshiyuki Ishihama, Ryotaro Harada, Masaru Aoki, Kenji Iiba, Kazushi Kodama, Hiroto Hayashi
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Patent number: 9752021Abstract: The instant invention provides an ethylene/alpha-olefin interpolymer composition suitable for blown film applications, and blown films made therefrom. The ethylene/alpha-olefin interpolymer composition suitable for blown film applications according to the present invention comprises greater than 80 percent by weight of units derived from ethylene and 20 percent or less by weight of units derived from one or more alpha olefin co-monomers, wherein said ethylene/alpha-olefin interpolymer has a density in the range of from 0.910 to 0.918 g/cm3, a melt index I2 in the range of from 0.5 to 1.1 g/10 minutes, a melt flow ratio I10/I2 in the range of from 8 to 10, a melt strength in the range of from 3 to 6 cN, a highest temperature fraction in the range of from 11 to 14 percent determined by CEF, a highest peak temperature fraction by CEF in range of from 96 to 100° C.Type: GrantFiled: March 13, 2014Date of Patent: September 5, 2017Assignee: DOW GLOBAL TECHNOLOGIES LLCInventors: Mehmet Demirors, Teresa P. Karjala, Julie W. Mckenna, Douglas S. Ginger
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Patent number: 9403928Abstract: A high pressure polymerization process to form an ethylene-based polymer comprises the steps of: A. Injecting a first feed comprising ethylene and optionally a chain transfer agent system (CTA system) into a first autoclave reactor zone operating at polymerization conditions to produce a first zone reaction product, the CTA system of the first reactor zone having a transfer activity Z1; and B. (1) Transferring at least part of the first zone reaction product to a second reactor zone selected from a second autoclave reactor zone or a tubular reactor zone and operating at polymerization conditions, and, optionally, (2) freshly injecting a second feed into the second reactor zone to produce a second zone reaction product, with the proviso that the second reactor zone contains a CTA system having a transfer activity Z2; and with the proviso that the ratio of Z1/Z2 is less than 1.Type: GrantFiled: April 28, 2014Date of Patent: August 2, 2016Assignee: Dow Global Technologies LLCInventors: Otto J. Berbee, Cornelis Den Doelder, Egbert Nijhof, Mehmet Demirors, Sjoerd A. De Vries
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Patent number: 9316465Abstract: The invention relates to a method for producing a highly oriented, high molecular weight polymer tape. The method comprises forming and compression-molding a polymer powder bed at a temperature below the melting point of the polymer to form a sheet; at a temperature below the melting point of the polymer, rolling and stretching the sheet in a calendar unit to form a partially oriented polymer web; at a temperature below the melting point of the polymer, drawing the partially oriented polymer web in a drawing unit; and, optionally repeating step c) to form a more fully oriented non-fibrous high molecular weight polymer tape, the method being discontinuous in that the ingoing line speed of one of the method steps b) to d) differs from the outgoing line speed of the preceding method step.Type: GrantFiled: March 26, 2010Date of Patent: April 19, 2016Assignee: DSM IP ASSETS B.V.Inventor: Reinard Jozef Maria Steeman
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Patent number: 9216538Abstract: Methods of enhancing one or more physical properties of a thermoplastic film include incrementally stretching thermoplastic films in the machine direction and/or transverse direction. In one or more implementations, methods of incrementally stretching thermoplastic films include reducing the gauge of the films without reducing the films' machine-direction tear resistance. The methods can involve cold stretching the films and imparting rib patterns into the film. The linear ribs can have alternating thick and thin gauges. Incrementally stretched thermoplastic films can have a machine-direction tear resistance that is approximately equal to or greater than the machine-direction tear resistance of the film prior to stretching.Type: GrantFiled: July 26, 2011Date of Patent: December 22, 2015Assignee: The Glad Products CompanyInventor: Michael G. Borchardt
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Patent number: 9206312Abstract: A heat-shrinkable film having a layer made of a mixed resin containing a polylactic acid resin and a polyolefin resin as the main components, wherein the mass ratio of the polylactic acid resin and the polyolefin resin is 95/5 to 50/50, the polylactic acid resin is a copolymer of D-lactic acid and L-lactic acid or a mixed resin of the copolymer, the D/L ratio of D-lactic acid and L-lactic acid is 3/97 to 15/85 or 85/15 to 97/3, the storage elastic modulus of the polyolefin resin or the soft acrylic resin at 20° C. is ?100 MPa as measured at an oscillation frequency of 10 Hz and a strain of 0.1%, the film is stretched in at least one direction, and the heat shrinkage ratio of the film in the main shrinking direction is ?20% as measured after the film is immersed in 80° C. water for 10 seconds.Type: GrantFiled: February 26, 2013Date of Patent: December 8, 2015Assignee: MITSUBISHI PLASTICS, INC.Inventors: Takashi Hiruma, Takeyoshi Yamada
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Patent number: 9057148Abstract: A method for producing a polypropylene fiber, which can produce a high strength polypropylene fiber without using a special raw material and/or means is provided. The method for producing a polypropylene fiber includes the step of spinning a melt extruded fiber, the step of keeping cold, and the step of drawing, in which a ratio of a take-off speed with respect to an extrusion speed in the step of spinning the melt-extruded fiber is 50 to 750.Type: GrantFiled: May 30, 2011Date of Patent: June 16, 2015Assignees: TOYOTA JIDOSHA KABUSHIKI KAISHA, THE UNIVERSITY OF TOKYOInventors: Tatsuya Kitagawa, Tadahisa Iwata, Chizuru Hongo
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Publication number: 20150038663Abstract: The invention relates to a multistage drawing process for the drawing of polymeric elongated objects, containing a first drawing stage and a final drawing stage and optionally containing at least one intermediate drawing stage subsequent to the first drawing stage and prior to the final drawing stage, comprising in the following order the steps of: a. providing a polymeric elongated feed object; b. drawing the elongated object in the first drawing stage with a draw ratio of between 30% and 90% of the maximum drawing ratio achievable in the first drawing step; c. optionally drawing the elongated object in the at least one intermediate drawing stage with a draw ratio of between 30% and 90% of the maximum drawing ratio achievable in the at least one intermediate drawing step; d. drawing the elongated object in the final drawing stage with a draw ratio of at most 5, preferably of at most 3.Type: ApplicationFiled: February 17, 2012Publication date: February 5, 2015Applicant: DSM IP ASSETS B.V.Inventors: Reinard Jezef Maria Steeman, Joseph Arnold Paul Maria Simmelink
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Patent number: 8901260Abstract: An interpolymer of ethylene and at least one alpha-olefin is claimed, wherein the ethylene interpolymer is characterized as having an average Mv and a valley temperature between the interpolymer and high crystalline fraction, Thc, such that the average Mv for a fraction above Thc from ATREF divided by average Mv of the whole polymer from ATREF (Mhc/Mp) is less then about 1.95 and wherein the interpolymer has a CDBI of less than 60%. The interpolymer of ethylene and at least one alpha-olefin can also be characterized as having a high density (HD) fraction and an overall density such that % HD fraction<?2733.3+2988.7x+144111.5 (x?0.92325)2 where x is the density in grams/cubic centimeter. Fabricated articles comprising the novel interpolymers are also disclosed.Type: GrantFiled: March 30, 2010Date of Patent: December 2, 2014Assignee: Dow Global Technologies LLCInventors: Ayush A. Bafna, Mehmet Demirors, Sylvie Desjardins, Douglas S. Ginger, Colleen M. Tice, Terry A. Pearce
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Patent number: 8883947Abstract: A vinylidene fluoride homopolymer represented by the formula (4): CF3-(A1)-I??(4) wherein A1 represents a structural unit of vinylidene fluoride homopolymer which includes crystal form I alone or as main component and has a number average degree of polymerization of 5 to 12.Type: GrantFiled: April 30, 2013Date of Patent: November 11, 2014Assignee: Daikin Industries, Ltd.Inventors: Takayuki Araki, Tetsuhiro Kodani
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Patent number: 8852748Abstract: A polymeric resin having a density of greater than about 0.960 g/cc, a melt index of from about 1.3 g/10 min. to about 2.8 g/10 min., a zero shear viscosity of from about 1×104 Pa*s to about 1×105 Pa*s, a recoverable shear parameter of from about 220 to about 370, and a CY-a parameter of from about 0.155 to about 0.200. A polymeric resin having an initial tension defined by the equation IT??1.67*(MI)+b where b is 5.17 and a percent decrease in the extrusion pressure of the resin of about 30% when compared to polymer resin of similar melt index prepared with a catalyst that has not undergone an activation comprising an oxidation, reduction, oxidation sequence wherein the resin when formed into a film has a moisture vapor transmission rate of from about 0.21 g.mil/100 in2/day to about 0.33 g.mil/100 in2/day.Type: GrantFiled: February 27, 2009Date of Patent: October 7, 2014Assignee: Chevron Phillips Chemical Company LPInventors: Ashish M. Sukhadia, Max P. McDaniel, Ted Cymbaluk, Rajendra K. Krishnaswamy, Lawrence Szmutko
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Patent number: 8802802Abstract: Disclosed is a method for producing polyethylene films which have high resistance to deformation or elongation under loading in tension. The method comprises orienting in the machine direction (MD) a high density polyethylene film at a drawdown ratio effective to give the film an MD tensile strength at yield greater than or equal to 50,000 psi, wherein the HDPE has a density greater than 0.940 g/cm3.Type: GrantFiled: April 16, 2013Date of Patent: August 12, 2014Assignee: Equistar Chemicals, LPInventor: D. Ryan Breese
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Publication number: 20140194587Abstract: A polymeric sheet having low density and comprising a low to non-existent amount of cyclic olefinic polymers (COP) and/or cyclic olefinic copolymers (COC). The overall density of the sheet may be lower than water. The sheet may be stretched and then heat shrinked onto an article. The sheet may be used as a label or package to wrap articles therewith.Type: ApplicationFiled: March 13, 2014Publication date: July 10, 2014Applicant: Polysack Plastic Industries Ltd.Inventors: Maor Segal, Yoav Guthman, Aharon Ben-Soussane, Yiftach Nir
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Patent number: 8728616Abstract: A polymer sheet according to at least one embodiment of the present invention is a polymer sheet whose main component is oriented nanocrystals of a polymer, and which satisfies the following conditions (I), (II), and (III): (I) having a crystallinity of not less than 70%; (II) having a tensile strength at break of not less than 100 MPa and a tensile modulus of not less than 3 GPa; and (III) having an average thickness of not less than 0.15 mm. According to at least one embodiment of the present invention, it is possible to provide a polymer sheet excelling in properties such as mechanical strength, heat tolerance, and transparency, particularly a polymer sheet having excellent properties such as mechanical strength, heat tolerance, and transparency in general-purpose plastics such as polypropylene.Type: GrantFiled: January 21, 2010Date of Patent: May 20, 2014Assignees: Hiroshima University, Sunallomer Ltd.Inventors: Masamichi Hikosaka, Kiyoka Okada, Kaori Watanabe, Junichiro Washiyama, Hideharu Kimura, Koji Yamada, Takeshi Nakajima, Akihiro Otsubo
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Patent number: 8697207Abstract: The inventive heat-shrinkable polyolefin film is high in shrinkability in the longitudinal direction that is its main shrinkage direction and excellent in finish properties after shrinkage, perforated line openability, and thermal blocking resistance. The heat-shrinkable polyolefin film is characterized by particular values with respect to hot-water heat shrinkage ratio in the longitudinal and width directions, right angle tear strength in the width direction, and heat-resistant peel strength.Type: GrantFiled: December 19, 2007Date of Patent: April 15, 2014Assignee: Toyo Boseki Kabushiki KaishaInventors: Shigetomo Yamamoto, Yukinobu Mukoyama, Kyoko Inagaki, Kenji Kawai, Masatoshi Hashimoto, Katsuhiko Nose
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Patent number: 8623982Abstract: Fibers and methods of forming the fibers are described herein. The fibers generally include an ethylene based polymer exhibiting a molecular weight distribution of from about 2 to about 8.Type: GrantFiled: December 1, 2008Date of Patent: January 7, 2014Assignee: Fina Technology, Inc.Inventors: Cyril Chevillard, Wyman Stephens, John Ashbaugh, Fengkui Li
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Patent number: 8618232Abstract: There are provided an infrared absorbing thin film that efficiently absorbs infrared rays and has good versatility by controlling the absorption intensity of titanium oxide in an infrared region and a method for producing the infrared absorbing thin film. The infrared absorbing thin film containing a rutile-type titanium oxide crystal.Type: GrantFiled: March 31, 2011Date of Patent: December 31, 2013Assignees: DIC Corporation, Kawamura Institute of Chemical ResearchInventors: Ren-Hua Jin, Pei-Xin Zhu
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Publication number: 20130284006Abstract: The invention relates to a process for compacting a polymeric powder in a press, wherein the polymeric powder is supported during compaction by a powder carrier, characterized in that said powder carrier comprises a layer of thickness (T), said layer comprising a material with a static coefficient of friction (COF), and wherein T?COF is at least 10 ?m. The invention also relates to a compacted polymeric powder obtainable with the above process.Type: ApplicationFiled: September 29, 2011Publication date: October 31, 2013Applicant: DSM IP ASSETS B.V.Inventors: Martin Antonius Van Es, Niels Hubertus Maria Eussen, Ronny Jacob Jensz
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Patent number: 8545980Abstract: A polypropylene resin having: (1) a melt flow rate (MFR) of 6 to 100 g/10 minutes, (2) a molecular weight distribution (Mw/Mn), measured by gel permeation chromatography, of 3 to 6, and (3) a 116° C. non-eluted component content (100-W116(%)) of 50% or more and a content of components eluted at 90° C. or less (W90) of 10 to 30%, measured by temperature-rising fractional chromatography (TREF).Type: GrantFiled: October 31, 2005Date of Patent: October 1, 2013Assignee: Idemitsu Kosan Co., Ltd.Inventors: Takeharu Tajima, Toshitaka Kanai, Tomoaki Takebe, Yutaka Minami
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Patent number: 8507628Abstract: Injection stretch blow molded (ISBM) articles and methods of forming the same are provided herein. In one embodiment, the ISBM articles generally include a propylene based random copolymer having a molecular weight distribution of from about 9 to about 20. In another embodiment, the ISBM articles generally include a propylene based random copolymer formed from a Ziegler-Natta catalyst including a succinate internal donor.Type: GrantFiled: October 2, 2007Date of Patent: August 13, 2013Assignee: Fina Technology, Inc.Inventors: Michael Musgrave, Dang Le, Luyi Sun, David Smith
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Publication number: 20130189465Abstract: Injection stretch blow molded (ISBM) articles and methods of forming the same are described herein. The ISBM articles generally include a propylene-based impact copolymer.Type: ApplicationFiled: March 11, 2013Publication date: July 25, 2013Applicant: FINA TECHNOLOGY, IncInventor: Luyi Sun
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Publication number: 20130184403Abstract: A reflector reflects incident light and comprises crystalline plastic in which a crystal region and an amorphous region are mixed, wherein the amorphous region includes a plurality of orientation layers comprising amorphous particles that are oriented in a predetermined direction. The reflector, which has high reflectance, is formed by extending a crystalline plastic material exhibiting a superior extensibility to extend the amorphous particles in the amorphous region in the predetermined direction so as to form a plurality of extension layers in the amorphous region. Since a reflector having a superior performance with a very improved reflectance can be provided due to a high diffuse reflectance by the extension layers in the amorphous region without a foaming process or an additional additive to increase the reflectance, the manufacturing process of the reflector is simplified and the manufacturing cost is reduced so that productivity can be greatly improved.Type: ApplicationFiled: July 26, 2012Publication date: July 18, 2013Applicant: ALPHAVISION CO., LTD.Inventor: Jae-Dong Yoon
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Patent number: 8475899Abstract: The present invention provides a polymerization process which is conducted by contacting an olefin monomer and at least one olefin comonomer in the presence of hydrogen and a metallocene-based catalyst composition. Polymers produced from the polymerization process are also provided, and these polymers have a reverse comonomer distribution, low levels of long chain branches, and a ratio of Mw/Mn from about 3 to about 6.Type: GrantFiled: December 5, 2011Date of Patent: July 2, 2013Assignee: Chevron Phillips Chemical Company LPInventors: Qing Yang, Max P. McDaniel, Joel L. Martin, Tony R. Crain, Randy S. Muninger, Jerry T. Lanier, Jeff S. Fodor, Paul J. Deslauriers, Chung C. Tso, David C. Rohlfing
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Patent number: 8450439Abstract: There is provided a method of forming a thin film of vinylidene fluoride homopolymer having crystal form I which is applicable to various substrates in relatively easy way (coating conditions, application method, etc.), a process for preparing a vinylidene fluoride homopolymer having crystal form I efficiently at high purity, and novel vinylidene fluoride homopolymers which can give a thin film being excellent in ferroelectricity. The method of forming a thin film of vinylidene fluoride homopolymer comprises (i) a step for preparing a green powder product of vinylidene fluoride homopolymer comprising crystal form I alone or as main component by subjecting vinylidene fluoride to radical polymerization in the presence of a bromine compound or iodine compound having 1 to 20 carbon atoms which contains at least one moiety represented by —CRf1Rf2X1, wherein X1. is iodine atom or bromine atom; Rf1. and Rf2.Type: GrantFiled: December 17, 2009Date of Patent: May 28, 2013Assignee: Daikin Industries, Ltd.Inventors: Takayuki Araki, Tetsuhiro Kodani
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Publication number: 20130129997Abstract: An oriented monolayer or multilayer film, wherein the monolayer film comprises a copolymer (A1) of propylene with hexene-1 containing from 4 to 10% by weight of hexene-1 and having MFR from 0.5 to 10 g/10 min., and the multilayer film comprises at least 30% by weight of said copolymer (A1), both the monolayer and the multilayer film being obtainable with a process comprising a drawing step wherein the film is drawn with a draw ratio of at least 3, in at least one direction.Type: ApplicationFiled: November 5, 2010Publication date: May 23, 2013Applicant: BASELL POLIOLEFINE ITALIA S.R.L.Inventors: Michele Grazzi, Paolo Bassi, Andrea Felisati, Giampaolo Pellegatti
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Patent number: 8427810Abstract: The present invention relates to a capacitor film comprising a biaxially oriented polypropylene wherein a) said polypropylene has a draw ratio in machine direction of at least 4.0 and a draw ratio in transverse direction of at least 4.0, and b) said polypropylene has an electrical breakdown strength EB63% according to IEC 60243-part 1 (1988) of at least 300 kV/mm at a draw ratio in machine direction and in transverse direction of 4.0.Type: GrantFiled: May 7, 2008Date of Patent: April 23, 2013Assignee: Borealis Technology OyInventors: Manfred Stadlbauer, Eberhard Ernst, Lauri Huhtanen, Yvo Daniels, Franck Jacobs
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Patent number: 8420743Abstract: A propylene-based copolymer is composed of 60 to 90% by weight of Component (A) that is a polymer component whose major structural unit is a structural unit derived from propylene and 10 to 40% by weight of Component (B) that is a propylene-ethylene copolymer component whose content of a structural unit derived from ethylene is 50 to 80% by weight, wherein the sum total of Component (A) and Component (B) is 100% by weight, wherein the ratio of the intrinsic viscosity of Component (B) ([?]B) to the intrinsic viscosity of Component (A) ([?]A)([?]B/[?]A) satisfies a formula: 1.3<[?]B/[?]A?2.0, and the melt flow rate, measured at a temperature of 230° C. and a load of 21.18 N, of the copolymer is not less than 5 g/10 minutes and not more than 30 g/10 minutes.Type: GrantFiled: February 4, 2011Date of Patent: April 16, 2013Assignee: Sumitomo Chemical Company, LimitedInventors: Kenji Ikeda, Shigeki Kishiro
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Patent number: 8399581Abstract: Metallocene catalyzed polyethylenes are found to have improved physical properties, improved processability and improved balance of properties. Surprisingly, there is a direct relationship between MD shrinkage, and MD tear. Additionally, MD tear is greater than TD tear, and MD tear is also greater than intrinsic tear. MD tear to TD tear ratios are above 0.9, and dart drop impact is above 500 g/mil. The polyethylenes have a relatively broad composition distribution and relatively broad molecular weight distribution.Type: GrantFiled: June 15, 2004Date of Patent: March 19, 2013Assignee: Univation Technologies, LLCInventors: James McLeod Farley, John F. Szul, Matthew Gary McKee
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Publication number: 20130064995Abstract: A polymer filament or fiber comprising a polyethylene material (I) having the following features: a) a density of 0.900 g/cm3 or higher; b) a MI21 value of 25 g/10 min.; c) a MFR value from 25 to 60; the said fiber being stretched by drawing with a draw ratio from 1.5 to 10.Type: ApplicationFiled: April 21, 2011Publication date: March 14, 2013Applicant: BASELL POLYOLEFINE GMBHInventors: Gianni Perdomi, Fabiana Fantinel, Roberto Vanzini, Shahram Mihan, Roberto De Palo
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Patent number: 8316904Abstract: This disclosure relates to a vulcanizable layered composition comprising at least two layers and at least one tie layer. The first of the two layers comprises a fluid permeation prevention layer and the second comprises at least one high diene rubber. The tie layer comprises, a mixture, in parts by weight relative to 100 weight parts of rubber, of suitable amounts of: (1) epoxidized natural rubber; (2) at least one high diene elastomer; (3) at least one filler; (4) least one tackifier; and (5) a rubber curing system. The fluid permeation prevention layer preferably comprises suitable amounts of: (A) at least one thermoplastic engineering resin component, preferably one or more nylon resins; and (B) at least one elastomer component, preferably a brominated isobutylene p-methylstyrene copolymer/and where the total amount of (A) and (B) is not less than 30% by weight, and wherein (B) is dispersed in a vulcanized or partially vulcanized state, as a discontinuous phase, in a matrix of component (A).Type: GrantFiled: October 26, 2006Date of Patent: November 27, 2012Assignees: The Yokohama Rubber Co., Ltd., ExxonMobil Chemical Patents, Inc.Inventors: Yoshihiro Soeda, Yoshiaki Kirino, Tomoyuki Sakai, Andy Haishung Tsou
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Patent number: 8299193Abstract: The present invention provides a film including, in at least a part thereof, a layer comprising an ethylene-based resin, which is a copolymer of ethylene and an ?-olefin of 4 to 10 carbon atoms, and satisfies the following requirements (1) to (5) at the same time or an ethylene-based resin composition containing the resin; (I) the melt flow rate at 190° C. under a load of 2.16 kg is in the range of 0.1 to 50 g/10 min, (II) the density is in the range of 875 to 970 kg/m3, (III) the ratio of a melt tension at 190° C. to a shear viscosity at 200° C. and an angular velocity of 1.0 rad/sec is in the range of 1.00×10?4 to 9.00×10?4, (IV) the sum of the number of methyl branches and the number of ethyl branches, each number being based on 1000 carbon atoms and measured by 13C-NMR, is not more than 1.8, and (V) the zero shear viscosity [?0(P)] at 200° C. and the weight-average molecular weight (Mw) as measured by a GPC-viscosity detector method (GPC-VISCO) satisfy the following relational formula (Eq-1): 0.Type: GrantFiled: July 31, 2007Date of Patent: October 30, 2012Assignee: Mitsui Chemicals, Inc.Inventors: Masao Suzuki, Yasuo Satoh, Takahiro Akashi, Tsutomu Tasaki, Shinya Matsubara, Hideki Bando
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Patent number: 8288495Abstract: [Object] To provide a propylene homopolymer suitable for capacitor films having high withstand voltage and a stretched film formed by stretching the propylene homopolymer. [Solution] A propylene homopolymer of the present invention for capacitors satisfies the following requirements (i) to (v) and (ix): (i) the MFR is 1 to 10 g/10 minutes; (ii) the meso pentad fraction (mmmm) measured by 13C-NMR is 0.940 to 0.995; (iii) the integrted amount of elution at 90° C. by CFC using o-dichlorobenzene is 0.5% by weight or less; (iv) the melting point measured using DSC is 152° C. or more; (v) the chlorine content is 2 ppm by weight or less; and (ix) in an elution temperature-elution volume curve measured by cross-fractionation chromatography (CFC) using o-dichlorobenzene, the maximum peak has a peak top temperature in the range of 105° C. to 130° C. and half width of 7.0° C. or less.Type: GrantFiled: January 26, 2010Date of Patent: October 16, 2012Assignees: Mitsui Chemicals, Inc., Prime Polymer Co., Ltd.Inventors: Satoshi Tamura, Keita Itakura, Satoshi Hashizume
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Patent number: 8283426Abstract: The present invention relates to a process for the production of fibers and filaments with polypropylene having a broad polydispersity index. The present invention also relates to high elongation nonwoven prepared from such fibers and filaments. It further relates to films and laminates prepared from high elongation nonwoven.Type: GrantFiled: February 20, 2009Date of Patent: October 9, 2012Assignee: Total Petrochemicals Research FeluyInventors: Hugues Haubruge, Guillaume Pavy, Alain Standaert
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Patent number: 8273839Abstract: Antiballistic or composite products include high strength polyethylene films or tapes produced in a process including the steps of providing a quantity of disentangled polyethylene, applying a pressure of at least 20 bar to the quantity of disentangled polyethylene and a temperature between the ?-relaxation temperature and the melting temperature of the disentangled polyethylene Tm PE resulting in a block of disentangled polyethylene, skiving a film or tape off the block of disentangled polyethylene and drawing the film or tape in a single or multi stage drawing step at a total draw ratio of at least 1:20.Type: GrantFiled: March 14, 2012Date of Patent: September 25, 2012Assignee: Novameer B.V.Inventors: Jan Adolph Dam Backer, Bart Clemens Kranz, Benjamin Slager
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Patent number: 8242220Abstract: Copolymer of ethylene and an alpha-olefin having (a) a density in the range 0.900-0.940 g/cm3, (b) a melt index MI2 (2.16 kg, 190° C.) in the range of 0.01-50 g/10 min, (c) a molecular weight distribution (Mw/Mn) in the range 3.5 to 4.5, and (d) a melt elastic modulus G?(G?=500 Pa) in the range 40 to 150 Pa. The copolymer has a melt index MI2 (2.16 kg, 190° C.) Dow Rheology Index (DRI) and melt elastic modulus G?(G?=500 Pa) satisfying the equations of [DRI/MI2]>0 and [DRI/MI2]<0.0225G??0.745.Type: GrantFiled: December 11, 2007Date of Patent: August 14, 2012Assignee: Ineos Europe LimitedInventor: Choon Kool Chai
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Patent number: 8236912Abstract: Provided is a gas-barrier film having a high barrier property when it is folded. The gas barrier film is characterized in that an organic layer comprises a resin obtained by curing a monomer as a polymerizing ingredient and the monomer has a structure of pentahydric alcohol or more polyhydric alcohol having a molecular weight of from 200 to 800 in which at least 5 hydroxyl groups are substituted with an aliphatic carbonyloxy group of the following general formula (1): wherein R represents a hydrogen atom or a methyl group; L represents a linking group having a chain length of at least 4 atoms; n indicates 0 or 1; provided that at least 3 hydroxyl groups of the polyhydric alcohol are substituted with the aliphatic carbonyloxy group of formula (1), when n =1.Type: GrantFiled: October 14, 2008Date of Patent: August 7, 2012Assignee: Fujifilm CorporationInventors: Tomoo Murakami, Yuya Agata
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Patent number: 8211514Abstract: A reverse dispersion retardation film is formed by stretching a film containing a norbornene-based ring-opening copolymer containing a structural unit (A) represented by a general formula (1) and a structural unit (B) represented by a general formula (2), wherein a total amount of the structural unit (A) and an exo-form structural unit, among the structural units (B), is not less than 20 mol % but not more than 65 mol % of all the structural units.Type: GrantFiled: December 24, 2009Date of Patent: July 3, 2012Assignee: JX Nippon Oil & Energy CorporationInventors: Tadahiro Kaminade, Shinichi Komatsu, Hisashi Sone, Takeshi Koike, Sayako Kawahama
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Patent number: 8207285Abstract: Mono-oriented film having a shrink rate at 100° C. of at least 15% and at least one layer of which comprises a propylene copolymer with ethylene and optionally other olefins of formula CH2?CHR in which R is an alkyl group containing from 2 to 10 carbon atoms, having at least 5.5% wt of ethylene, a melt flow rate according to ISO 1133 (230° C., 2.16 Kg) of less than 10, and a fraction of polymer soluble in xylene at 25° C. ranging from 14 to 30% weight based on the total weight of said copolymer. The said films are particularly suited for the manufacturing of shrink labels.Type: GrantFiled: December 5, 2007Date of Patent: June 26, 2012Assignee: Basell Poliolefine Italia s.r.l.Inventors: Michele Grazzi, Claudio Cavalieri