Stretched Product Patents (Class 526/348.1)
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Patent number: 6512064Abstract: A fluororesin film, which has a dielectric constant of at most 5, and which has a tensile break strength of at least 40 MPa in each of MD direction and TD direction; a fluororesin film, wherein the ratio of the tensile break strength in each of MD and TD directions after stretching to the tensile break strength in each of MD and TD directions before stretching, is at least 1.5; and a fluororesin film, which has a tensile modulus of at least 3,000 MPa in each of MD and TD directions. The above-mentioned fluororesin films are obtained by using a method of biaxially stretching laminates of corresponding raw fabric films and readily stretchable films.Type: GrantFiled: November 9, 2001Date of Patent: January 28, 2003Assignee: Asahi Glass Company, LimitedInventors: Yoshiaki Higuchi, Yukio Jitsugiri
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Patent number: 6506867Abstract: Elastic ethylene polymers are disclosed which have processability similar to highly branched low density polyethylene (LDPE), but the strength and toughness of linear low density polyethylene (LLDPE). The polymers have processing indices (PI's) less than or equal to 70 percent of those of a comparative linear ethylene polymer and a critical shear rate at onset of surface melt fracture of at least 50 percent greater than the critical shear rate at the onset of surface melt fracture of a traditional linear ethylene polymer at about the same I2 and Mw/Mn. The novel polymers can also have from about 0.01 to about 3 long chain branches/1000 total carbons and have higher low/zero shear viscosity and lower high shear viscosity than comparative linear ethylene polymers. The novel polymers can also be characterized as having a melt flow ratio, I10/I2, ≧5.63, a molecular weight distribution, Mw/Mn, defined by the equation: Mw/Mn≦(I10/I2)−4.Type: GrantFiled: October 18, 2000Date of Patent: January 14, 2003Assignee: The Dow Chemical CompanyInventors: Shih-Yaw Lai, John R. Wilson, George W. Knight, James C. Stevens
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Publication number: 20030008980Abstract: The invention provides for polymerization catalyst compositions, and for methods for introducing the catalyst compositions into a polymerization reactor. More particularly, the method combines a catalyst component containing slurry and a catalyst component containing solution to form the completed catalyst composition for introduction into the polymerization reactor. The invention is also directed to methods of preparing the catalyst component slurry, the catalyst component solution and the catalyst compositions, to methods of controlling the properties of polymer products utilizing the catalyst compositions, and to polymers produced therefrom.Type: ApplicationFiled: December 4, 2000Publication date: January 9, 2003Inventors: Simon Mawson, Sun-Chueh Kao, Tae Hoon Kwalk, Timothy Roger Lynn, David H. McConville, Matthew Gary McKee, John Francis Szul, Kersten Anne Terry, Timothy T. Wenzel, Mark Gregory Goode, John Henry Oskam, Robert J. Jorgensen, Robert Harold Vogel
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Patent number: 6503993Abstract: The present invention concerns nucleated propylene polymers having a xylene soluble fraction at 23° C. of less than 2.5%, a crystallization temperature of over 124 ° C. and a tensile modulus of greater than 2,000 MPa. These polymers can be prepared by nucleating a propylene polymer with a polymeric nucleating agent containing vinyl compound units, and by polymerizing propylene optionally with comonomers in the presence of a Ziegler-Natta catalyst system primarily transesterified with a phthalic acid ester—a lower alcohol pair to provide said propylene polymer. The catalyst contains a strongly coordinating external donor.Type: GrantFiled: June 27, 2000Date of Patent: January 7, 2003Assignee: Borealis Technology OyInventors: Päivi Huovinen, Pirjo J{umlaut over (aa)}skeläinen, Amir Karbasi, Christer Lind, Bo Malm, John Haugen
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Patent number: 6500901Abstract: A novel composition is disclosed comprising about 80 to about 99 weight percent based on the composition, of a linear ultra low density polyethylene (LULDPE) and about 1 to about 20 weight percent of a propylene polymer comprising 0 to about 40 weight percent olefin comonomer units having 2 to 10 carbon atoms and from about 60 to about 100 weight percent propylene, based on the propylene polymer, the propylene polymer having a Brookfield Thermosel viscosity of about 1 to about 30,000 mpa·s at 190° C. and a needle penetration of about 5 to about 300 dmm at 23° C. Also disclosed are films produced from the composition, both blown and cast, and both monolayer and multilayer. Also disclosed are processes for stretch wrapping and forming blown and cast film.Type: GrantFiled: February 20, 2001Date of Patent: December 31, 2002Assignee: Eastman Chemical CompanyInventor: Marc Stacey Somers
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Patent number: 6500508Abstract: A flame-retardant resin composition for insulated wires, shielded wires and insulating tubes which are used in the field requiring high-frequency current transmission, for example, in the field of high-density wiring of internal circuits in electronic appliances. The composition comprises (a) a thermoplastic polyolefinic resin having a density of smaller than 0.89 g/cm3, which is prepared by copolymerizing ethylene and a non-polar &agr;-olefin in the presence of a single-site metallocene catalyst, (b) a halogen-containing flame retardant, and (c) zinc oxide. After crosslinking, the composition is used in forming an insulating coating for insulated wires and shielded wires, and in forming insulating tubes.Type: GrantFiled: February 12, 2001Date of Patent: December 31, 2002Assignee: Sumitomo Electric Fine Polymer, Inc.Inventors: Hiroshi Hayami, Yumi Kawabata, Satoshi Ebina
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Publication number: 20020188087Abstract: Disclosed is an ethylenic copolymer having Mw/Mn, as measured through GPC, of from 1.5 to 4, Mw of from 3,000 to 1,000,000, and a resin density of from 0.85 and 0.95 g/cm3. The relationship between the half width at the half maximum [W/2] of the curve as obtained through Gaussian distribution approximation relative to the essential peak of the compositional distribution curve of the copolymer obtained through temperature rising elution fractionation analysis, and the average, n, of short-chain branches existing in the copolymer satisfies an equation, 0.704+0.147n ≦W/2≦−0.055+0.577n. Also disclosed is an ethylenic copolymer having Mw/Mn of from 1.5 to 4 and a resin density of from 0.85 and 0.95 g/cm3.Type: ApplicationFiled: May 24, 2002Publication date: December 12, 2002Applicant: Idemitsu Kosan Co., Ltd.Inventors: Haruo Shikuma, Shuji Machida, Motoharu Ishikawa, Shinichi Kurokawa
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Patent number: 6492475Abstract: The present invention relates to an ethylene-&agr;-olefin copolymer; a composition thereof; a film thereof; a polar group-containing resin material; and productions and use of the ethylene-&agr;-olefin copolymer. The ethylene-&agr;-olefin copolymer of the present invention is characterized in satisfying the following conditions (A) to (E): (A) a density in the range of 0.92 to 0.96 g/cm3; (B) a melt flow rate (MFR) in the range of 0.01 to 200 g/10 min; (C) a molecular weight distribution (Mw/Mn) in the range of 1.5 to 5.Type: GrantFiled: December 19, 2000Date of Patent: December 10, 2002Assignee: Japan Polyolefins Co., Ltd.Inventors: Toshiaki Egashira, Reiji Higuchi, Kazuyuki Sakamoto, Kimiya Miyoshi, Masahiro Wakayama, Tatsuo Yamaguchi, Fumio Asada, Sinji Miwa, Kenichi Hiraki, Masaaki Ikeda, Yoshimi Shimizu
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Publication number: 20020182428Abstract: The present invention relates to single- or multilayer films and one or more layers comprising at least one polyolefin molding composition containing at least one polyolefin derived from at least one olefin having at least 2 carbon atoms, of the formula Ra—CH═CH—Rb, in which Ra and Rb are identical or different and are a hydrogen atom or a straight-chain or branched C1-C15-alkyl radical, or Ra and Rb, together with the atoms connecting them, form a ring or ring system, and the polyolefin has been prepared by means of metallocene catalysts. The present invention furthermore relates to a process for the production of films and layers in which a polyolefin molding composition having a particle size of from 20 &mgr;m to 5000 &mgr;m is used or prepared. The shaped polyolefin molding composition is melt-mixed with at least one additive and shaped. The melt-mixed and shaped material is melted at a temperature of from 150° C. to 300° C.Type: ApplicationFiled: December 20, 1996Publication date: December 5, 2002Inventors: ANDREAS WINTER, ERNST HOFMANN, GERHARD WIENERS, BERND BACHMANN
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Patent number: 6489033Abstract: Electrets can be produced from cycloolefin copolymers (COCs), and charges applied thereto are stable for long periods, even at high temperatures and high relative humidities. The reduction here in a positive charge applied to the COCs is smaller than that of negative charges applied to the COCs. The stability over time of the charges applied is impaired by adding polar additives, such as inorganic silicon compounds. Films, fibers or nonwovens produced from electrets can be processed to give filters.Type: GrantFiled: February 28, 2000Date of Patent: December 3, 2002Assignee: Ticona GmbHInventors: Wilfried Hatke, Gerhard Sessler, Guo-Mao Yang
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Patent number: 6486284Abstract: The subject invention provides a film having at least one layer comprising an interpolymer of ethylene and at least one comonomer selected from the group consisting of C3-C20 &agr;-olefins, dienes, and cycloalkenes, wherein the interpolymer is characteried as having a high degree of processability good optical performance, and good mechanical properties. The subject invention further provides film fabrication processes and polymer compositions which are useful in preparing the subject films.Type: GrantFiled: May 8, 2000Date of Patent: November 26, 2002Assignee: Dow Global Technologies Inc.Inventors: Seema V. Karande, Lonnie G. Hazlitt, Pradeep Jain, Kaelyn Koch, Shih-Yaw Lai, Li-Min Tau
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Publication number: 20020173602Abstract: Random copolymers of propylene with other 1-alkenes having up to 10 carbon atoms,Type: ApplicationFiled: January 14, 2002Publication date: November 21, 2002Inventors: David Appleyard, Franz Langhauser, Murray Horton, Roland Hingmann, Gunther Schweier, Volker Rauschenberger, Ingolf Hennig, Dieter Lilge, Werner Schone, Meinolf Kersting
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Patent number: 6476171Abstract: A polymer of ethylene and at least one alpha olefin having at least 5, carbon atoms obtainable by a continuous gas phase polymerization using supported catalyst of an activated molecularly discrete catalyst such as a metallocene in the substantial absence of an aluminum alkyl based scavenger which polymer has a Melt Index (MI) as herein defined of from 0.1 to 15; a Compositional Distribution Breadth Index (CDBI) as defined herein of at least 70%, a density of from 0.910 to 0.930 g/ml; a Haze value as herein defined of less than 20%; a Melt Index ratio (MIR) as herein defined of from 35 to 80; an averaged Modulus (M) as herein defined of from 20 000 to 60 000 psi (pounds per square inch) and a relation between M and the Dart Impact Strength in g/mil (DIS) complying with the formula: DIS≧0.8×[100+e(11.71-0.000268×M+2.183×10−9×M2)].Type: GrantFiled: October 3, 2000Date of Patent: November 5, 2002Assignee: ExxonMobil Chemical Patents Inc.Inventors: Ching-Tai Lue, Natalie A. Merrill, Michael E. Muhle, George Alan Vaughan
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Patent number: 6476172Abstract: A fiber product drawn from an isotactic propylene copolymer of a C2, C4, C5, C6, C7 or C8 &agr;-olefin monomer produced in the presence of a metallocene catalyst characterized by a bridged chiral and stereorigid cyclopentadienyl or substituted cyclopentadienyl ligand structure of a transitional metal selected from group 4b, 5b, or 6b metals of the Periodic Table of Elements, the copolymer having a MFR less than 35, suitably about 30 or less. The copolymer is heated to a molten state and extruded to form a fiber preform. The preform is subjected to spinning at a spinning speed of at least 300 meters per minutes and subsequent drawing at a speed of up to about 1500 meters per minute to provide a draw ratio of at least 1.5 up to 5:1 to produce a continuous fiber having high tenacity of about 3.5 grams per denier and greater and good hand.Type: GrantFiled: July 27, 2001Date of Patent: November 5, 2002Assignee: Fina Technology, Inc.Inventors: Darek Wachowicz, Cyril Chevillard, Lisa K. Albe
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Patent number: 6458910Abstract: Blown films of linear low density polyethylene are produced by a high stalk process comprising extruding the linear low density polyethylene through an annular die to form an extruded tube of molten material, cooling the extruded tube while drawing the tube so cooled, to maintain the tube diameter identical to that of the annular die and expanding the tube or bubble to attenuate the walls thereof by introducing a gas to the interior of the tube or bubble. The resulting films are characterized by superior impact strength and MD tear resistance.Type: GrantFiled: April 15, 1996Date of Patent: October 1, 2002Assignee: ExxonMobil Oil CorporationInventors: Vaseem Firdaus, Pradeep P. Shirodkar
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Patent number: 6458911Abstract: A class of relatively high molecular weight, high density ethylene polymers (HMW-HDPE) is disclosed capable of being formed into thin films of high strength, such polymers having a density of at least about 0.925 g/cc, a flow index (I21) no higher than about 15 g/10 min., a melt flow ratio (MFR) of at least about 65, and a dynamic elasticity at 0.1 rad./sec. of no higher than about 0.7 at a corresponding complex viscosity at 0.1 rad./sec. no higher than about 14×105 poises. The ethylene polymer is a bimodal of relatively high molecular weight (HMW) and low molecular weight (LMW) ethylene polymers.Type: GrantFiled: October 2, 2001Date of Patent: October 1, 2002Assignee: ExxonMobil Oil CorporationInventors: S. Christine Ong, Sandra D. Schregenberger, Pradeep P. Shirodkar
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Patent number: 6455642Abstract: The present invention concerns a process for producing homogeneous polyethylene materials and processes for making high density, medium density and low density films therefrom. The process involves producing a polyethylene composition in a multistage reaction sequence of successive polymerization stages in the presence of an ethylene-polymerizing catalyst system. According to the invention, the process is carried out using an unsupported catalyst having magnesium and titanium as active constituents, in at least one loop polymerization stage and at least one gas phase polymerization stage and, operated with different amounts of hydrogen and comonomers to produce a high molecular weight portion in one of the polymerization stages and a low molecular weight portion in another so as to provide a polyethylene composition with the low molecular weight part having a MFR2 of 250 g/10 min or more. With this process it is possible to obtain homogeneous bimodal polyethylene material.Type: GrantFiled: November 7, 2000Date of Patent: September 24, 2002Assignee: Borealis Technology OyInventors: Ole Jan Myhre, Auli Nummila-Pakarinen, Jarmo Lindroos, Päivi Waldvogel, Thomas Garoff
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Patent number: 6455659Abstract: Provided is a crystalline polypropylene of which the 0° C. soluble content, &agr; (% by weight), as measured through programmed-temperature fractionation and the molecular weight, Mp, for the peak in the molecular weight distribution curve as measured through gel permeation chromatography satisfy the relationship of the following formula (1): &agr;≦−0.42×ln(Mp)+7.3 (1), and the melting point, Tm (° C.), as measured through differential scanning calorimetry and Mp satisfy the relationship of the following formula (2): Tm>1.85×ln(Mp)+144.5 (2). Also provided are moldings and films of the crystalline polypropylene. The crystalline polypropylene and its moldings and films are highly rigid and have good heat resistance and good scratch resistance.Type: GrantFiled: January 13, 2000Date of Patent: September 24, 2002Assignee: Idemitsu Petrochemical Co., Ltd.Inventors: Itaru Kuramoto, Yutaka Obata, Tsuyoshi Ota, Toshio Isozaki
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Patent number: 6451936Abstract: A polypropylene random copolymer obtained by copolymerizing propylene and an &agr;-olefin or propylene, ethylene, and &agr;-olefin using a Ziegler-Natta catalyst substantially in the absence of solvent, wherein propylene content is from 92.3 to 75.0% by weight, the ethylene content (E) is from 0 to 2.7% by weight, and the &agr;-olefin content is from 5.0 to 25.0% by weight, and wherein the content (C) of 20° C. xylene-soluble components in the random copolymer satisfies following formulae (1) to (3); in the copolymer wherein the ethylene content (E) is less than 1.5% by weight, C≦12.0 (weight %) (1) in the copolymer wherein the ethylene content (E) is from 1.5% by weight to 1.8% by weight, C≦42.0−20.0×E (weight %) (2) and in the copolymer wherein the ethylene content (E) is from 1.8% by weight to 2.7% by weight, C≦6.0 (weight %) (3).Type: GrantFiled: June 5, 1995Date of Patent: September 17, 2002Assignee: Sumitomo Chemical Company, LimitedInventors: Hajime Sadatoshi, Seiichiro Ima, Kazuki Wakamatsu, Jiro Mori, Eisuke Shiratani
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Patent number: 6448355Abstract: Elastic fibers and fabrics made from homogeneously branched substantially linear ethylene polymers are disclosed which can be produced on conventional polypropylene or polyethylene fiber or fabric processes. They can be used to produce highly elastic structures that can have recycle compatibility between elastic and non-elastic components. The novel fibers have at least about 50% recovery at 100% strain. The fibers and fabrics are especially useful in making fabricated articles and components thereof (e.g., disposable diapers).Type: GrantFiled: July 30, 1996Date of Patent: September 10, 2002Assignee: The Dow Chemical CompanyInventors: George W. Knight, Rexford A. Maugans, Edward N. Knickerbocker
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Publication number: 20020120083Abstract: New precursors and processes to generate fluorinated poly(para-xylylenes) (“PPX”) and their chemically modified films suitable for fabrications of integrated circuits (“ICs”) of <0.15 &mgr;m are disclosed. The films so prepared have low dielectric constants (“∈”) and are able to keep the integrity of the dielectric, Cu, and the barrier metal, such as Ta. Hence, the reliability of ICs can be assured.Type: ApplicationFiled: February 26, 2001Publication date: August 29, 2002Inventor: Chung J. Lee
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Patent number: 6441116Abstract: A film formed of an ethylenic copolymer having Mw/Mn of 1.5 to 4, Mw of 3,000 to 1,000,000, and a resin density of 0.85 to 0.95 g/cm3. In the copolymer compositional distribution curve, the relationship between the half width at the half maximum [W/2] of the Gaussian distribution curve, and the average, n, of short-chain branches in the copolymer satisfies the equation, 0.704+0.147n≦W/2≦−0.055+0.577n. The tear strength (TS, kgf/cm) of the copolymer satisfies equations, TS≧131.5−155×log[{(B+C+D)/A}+0.1], and 0.1≦(B+C+D)/A≦1 where A is the area surrounding the Gaussian distribution curve and the base line of the compositional distribution curve; B is the area surrounding the compositional distribution curve, the curve obtained through Gaussian distribution approximation, and the base line, B being at an elution temperature higher than 32° C.Type: GrantFiled: October 18, 1999Date of Patent: August 27, 2002Assignee: Idemitsu Kosan Co., Ltd.Inventors: Haruo Shikuma, Shuji Machida, Motoharu Ishikawa, Shinichi Kurokawa
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Publication number: 20020107351Abstract: A propylene-based polymer having a melt flow rate of 0.1 to 20 g/10 min. and a melting point Tm (° C.) measured by using a differential scanning calorimeter (DSC) of 147 to 159° C., in which the half width HW (° C.) of the melting peak measured by using a differential scanning calorimeter (DSC) and the melting point Tm (° C.) satisfy the relation: HW≦(188−Tm)/5.Type: ApplicationFiled: October 23, 2001Publication date: August 8, 2002Inventors: Mitsuji Tsuji, Kenichiro Yada, Syunji Yunoki
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Publication number: 20020098371Abstract: An ethylene-tetrafluoroethylene copolymer film excellent in light transparency, which has a light transmittance of at least 90% at a wavelength of 300 nm when the film has a thickness of 25 &mgr;m.Type: ApplicationFiled: November 27, 2001Publication date: July 25, 2002Applicant: Asahi Glass Company, LimitedInventors: Yoshiaki Higuchi, Yukio Jitsugiri
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Publication number: 20020098352Abstract: A pressure-sensitive adhesive composition which comprises as a main component an acrylic polymer comprising as a monomer unit an aromatic ring-containing copolymerizable monomer, wherein the refractive index of the composition after drying, after curing or after drying and curing is 1.49 or more and 1.60 or less; a pressure-sensitive adhesive sheet used to stick and fix an optical film on the display panel of a display device, wherein a pressure-sensitive adhesive layer comprising the pressure-sensitive adhesive composition is formed on a release liner; and an optical film which comprises an optical film used to stick and fix on the display panel of a display device having formed on one face thereof the pressure-sensitive adhesive layer comprising the pressure-sensitive adhesive composition are described.Type: ApplicationFiled: December 3, 2001Publication date: July 25, 2002Applicant: NITTO DENKO CORPORATIONInventor: Hiroaki Kishioka
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Patent number: 6423808Abstract: A laminate containing a polyolefin resin composition containing ethylene-&agr;-olefin copolymer having: (A) a density d of 0.86 to 0.96 g/cm3; (B) a melt flow rate MFR of 0.01 to 200 g/10 min; (C) a molecular weight distribution Mw/Mn of 1.5 to 4.5; (D) a composition distribution parameter Cb of 1.08 to 2.00; and (E) an orthodichlorobenzene-soluble content X (wt %), at 25° C. a density of d (g/cm3) and a melt flow rate MFR (g/10 min) satisfying that: (i) when the density (d) and the melt flow rate MFR satisfy relationship (I): d−0.008×log MFR≧0.93 (I) the orthodichlorobenzene-soluble content X satisfies relationship (II): X<2.0 (II) (ii) when the density d and the melt flow rate MFR satisfy relationship (III): d−0.008×log MFR<0.93 (II) the orthodichlorobenzene-soluble content X satisfies relationship (IV): X<9.8×103×(0.9300−d+0.008×log MFR)2+2.Type: GrantFiled: August 22, 2000Date of Patent: July 23, 2002Assignee: Japan Polyolefins Co., Ltd.Inventors: Hideo Watanabe, Masahiko Sato, Masaaki Ikeda, Takaaki Hattori, Yoshihiro Hatakeyama, Naoki Miwa, Tatsuyuki Kamiya, Hisao Sakuma, Yuka Umeshima
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Publication number: 20020091217Abstract: A copolymer of ethylene and a vinyl compound (I) represented by the general formula CH2═CH—R, wherein R is a saturated hydrocarbon group, a steric parameter Es of the substituent R is from −2.77 to −1.64 and a steric parameter B1 of the substituent R is from 1.53 to 2.90, a molded article comprising the same, an adhesive comprising the same as an effective ingredient an laminate comprising the same.Type: ApplicationFiled: October 10, 2001Publication date: July 11, 2002Inventors: Nobuo Oi, Akihiro Kondo, Tatsuya Miyatake, Toshiki Mori
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Patent number: 6417301Abstract: There is described a process utilizing Ziegler-Natta catalysts for producing ethylene/olefin interpolymers which, for a given melt index and density, have a reduced melting peak temperature (Tm). The process involves contacting ethylene and at least one other olefin under polymerization conditions with a Ziegler-Natta catalyst and at least one modifier comprising at least one element from Group 15 and/or Group 16 in amounts sufficient to reduce the melting peak temperature of the ethylene/olefin interpolymer. Also described herein are novel ethylene/olefin interpolymers resulting from the process.Type: GrantFiled: August 31, 1999Date of Patent: July 9, 2002Assignee: Eastman Chemical CompanyInventors: Randal Ray Ford, Jeffrey James Vanderbilt, Darryl Stephen Williams
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Patent number: 6417308Abstract: A film containing at least 5 wt % of an aromatic vinyl compound-&agr;-olefin random copolymer having an aromatic vinyl compound content of from 1 to less than 99.9% by molar fraction and having head-to-tail chain structures comprising at least two aromatic vinyl compound units.Type: GrantFiled: February 20, 2001Date of Patent: July 9, 2002Assignee: Denki Kagaku Kogyo Kabushiki KaishaInventors: Toru Arai, Akihiko Nakamura, Shigeru Suzuki, Toshiaki Otsu, Akio Okamoto
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Patent number: 6407192Abstract: A process for producing high density polyethylene suitable for blow molding and having high environmental stress cracking resistance and rigidity copolymerizing ethylene and an alpha-olefinic comonomer comprising from 3 to 10 carbon atoms, in the presence of a chromium-based catalyst, having an alumina-containing support, and an organoboron compound, wherein the atomic ratio of boron in the organoboron compound to the chromium in the chromium-based catalyst is from around 0.2 to around 0.4.Type: GrantFiled: August 1, 2000Date of Patent: June 18, 2002Assignee: Fina Research, S.A.Inventors: Guy Debras, Philippe Bodart
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Publication number: 20020065384Abstract: Elastic fibers and fabrics made from homogeneously branched substantially linear ethylene polymers are disclosed which can be produced on conventional polypropylene or polyethylene fiber or fabric processes. They can be used to produce highly elastic structures that can have recycle compatibility between elastic and non-plastic components. The novel fibers have at least about 50% recovery at 100% strain. The fibers and fabrics are especially useful in making fabricated articles and components thereof (e.g., disposable diapers).Type: ApplicationFiled: July 16, 2001Publication date: May 30, 2002Inventors: George W. Knight, Edward N. Knickerbocker, Rexford A. Maugans
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Publication number: 20020052453Abstract: Catalyst compositions and methods, useful in polymerization processes, utilizing at least two metal compounds are disclosed. At least one of the metal compounds is a Group 15 containing metal compound and the other metal compound is preferably a bulky ligand metallocene-type catalyst. The invention also discloses a new polyolefin, generally polyethylene, particularly a multimodal polymer and more specifically, a bimodal polymer, and its use in various end-use applications such as film, molding and pipe.Type: ApplicationFiled: May 24, 2001Publication date: May 2, 2002Inventors: Donald R. Loveday, David H. McConville, John F. Szul, Kersten Anne Erickson, Simon Mawson, Tae Hoon Kwack, Frederick J. Karol, David James Schreck
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Publication number: 20020042472Abstract: A class of relatively high molecular weight, high density ethylene polymers (HMW-HDPE) is disclosed capable of being formed into thin films of high strength, such polymers having a density of at least about 0.935 g/cc, a flow index (I21) no higher than about 15 g/10 min., a melt flow ratio (MFR) of at least about 65, and a dynamic elasticity at 0.1 rad./sec. of no higher than about 0.7 at a corresponding complex viscosity at 0.1 rad./sec. no higher than about 14E5, i.e., about 14×105 poises.Type: ApplicationFiled: October 2, 2001Publication date: April 11, 2002Inventors: S. Christine Ong, Sandra D. Schregenberger, Pradeep P. Shirodkar
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Publication number: 20020042490Abstract: High density polyethylene barrier grade films comprising at least one layer of polymer wherein the polymer comprises a density greater than about 0.955 g/cc and a rheological breadth parameter of greater than about 0.22 are disclosed. Methods for producing such films on a film line with a neck height configuration of greater than about 15 inches are disclosed.Type: ApplicationFiled: June 29, 2001Publication date: April 11, 2002Inventors: Michael McLeod, Nguong van Nguyen
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Publication number: 20020040100Abstract: A polypropylene-based resin film of a resin composition (C) comprising:Type: ApplicationFiled: July 11, 2001Publication date: April 4, 2002Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Takanori Kume, Shigeki Kishiro, Eisuke Shiratani
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Publication number: 20020040114Abstract: The present invention relates to a process for the polymerization of monomers utilizing a bulky ligand hafnium transition metal metallocene-type catalyst compound, to the catalyst compound itself and to the catalyst compound in combination with an activator. The invention is also directed to an ethylene copolymer composition produced by using the bulky ligand hafnium metallocene-type catalysts of the invention, in particular a single reactor polymerization process.Type: ApplicationFiled: March 14, 2001Publication date: April 4, 2002Inventors: Donald R. Loveday, Moses Olukayode Jejelowo, Sun-Chueh Kao
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Patent number: 6365689Abstract: The present invention provides propylene/ethylene random copolymers characterized in that: an ethylene content (Ew) is 0.1-10 wt %, a relationship between an isolated ethylene content (E1) and the ethylene content (Ew) is represented by the following equation E1>0.85−0.01 Ew 2,1- and 1,3-propylene units present in a polymer chain are 0-1 mol %, a weight average molecular weight (Mw) is in the range of 40,000-1,000,000, and a ratio (Mw/Mn) of the weight average molecular weight (Mw) to a number average molecular weight(Mn) is in the range of 1.5-3.8. The copolymers are suitable for a base resin for a molding material for the production of a wide variety of molded articles which are high in randomness and excellent in stiffness, heat resistance and transparency.Type: GrantFiled: February 15, 2000Date of Patent: April 2, 2002Assignee: Chisso CorporationInventors: Tsutomu Ushioda, Jun Saito, Mototake Tsutsui, Yoshitoyo Yasuda, Hiroyuki Fujita, Yoshiyuki Oogi, Minoru Adachi, Yoshitaka Morimoto, Taketo Hirose, Youichi Kugimiya, Yasuhiro Shiraishi
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Publication number: 20020035227Abstract: An ethylene-&agr;-olefin copolymer which is a copolymer of ethylene with a C3-20 &agr;-olefin and which satisfies the following conditions (a) to (c):Type: ApplicationFiled: August 20, 2001Publication date: March 21, 2002Applicant: Mitsubishi Chemical CorporationInventors: Yumito Uehara, Yoshiyuki Ishihama, Yukitaka Goto
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Patent number: 6359050Abstract: A novel composition is provided comprising a specified polyethylene component and a filler such that a film formed from the composition is characterized by having increased moisture vapor transmission rate.Type: GrantFiled: July 28, 2000Date of Patent: March 19, 2002Assignee: Eastman Chemical CompanyInventors: Kathryn Kobes Dohrer, Wesley Raymond Hale, Irving Daniel Sand, Mark Alan Edmund, Martin Ray Tant, Emmett Dudley Crawford, Edward Philip Savitski, Dennis Brannon Barr
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Publication number: 20020032295Abstract: A single-ply or laminar biaxially oriented polypropylene film structure is described. The n-hexane-insoluble fraction of the film has a chain isotaxy index, measured by means of 13C-NMR spectroscopy, of at least 95%. The base ply of the laminar structure (or the single ply of the single-ply structure) contains essentially no hydrocarbon resin or low molecular weight resin. The modulus of elasticity of the film structure in the longitudinal direction is greater than 2,500 N/mm2. The modulus of elasticity of the film structure in the transverse direction is greater than 4,00 N/mm2.Type: ApplicationFiled: September 26, 1994Publication date: March 14, 2002Inventors: HERBERT PEIFFER, THOMAS DRIES, URSULA MURSCHALL, GUNTER SCHLOEGL
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Patent number: 6348272Abstract: Uses of syndiotactic/atactic block polypropylene are provided in which the molecular weight thereof is preferably at least 120 kD. The syndiotactic/atactic block polypropylene may be used as a polypropylene modifier, a component in an adhesive composition, a shock absorber component, a waterproof membrane component, a packaging film or component thereof, a shapable composition component, and an acoustic absorbent material component, a composition for moulding into a footwear component, a bitumen modifier, a compatibiliser, an emulgator or an emulsifier, as a viscosity improver, and as a spilled oil absorber.Type: GrantFiled: January 20, 1999Date of Patent: February 19, 2002Assignee: Fina Research, S.A.Inventors: Bernard Haveaux, Thierry Coupin
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Publication number: 20020010292Abstract: A novel process for the polymerization of olefins is provided. The process involves contacting at least one olefin with a Ziegler-Natta type catalyst in the presence of a specified compound that results in the production of polymeric products having a narrower molecular weight distribution. Also provide is a process for narrowing the molecular weight distribution of a polyolefin comprising contacting an olefin, a Ziegler-Natta catalyst and a compound specified herein. Further provided are novel polyethylenes, and films and articles produced therefrom.Type: ApplicationFiled: July 27, 2001Publication date: January 24, 2002Inventors: Randal Ray Ford, Richard Kingsley Stuart
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Patent number: 6340532Abstract: Shrink films having an outstanding balance of physical properties and shrink properties are manufactured from “pseudohomogeneous” linear low density polyethylene resin. The preferred pseudohomogeneous resins used in the present invention are prepared with an advanced Ziegler Natta catalyst (having a magnesium component and a titanium component), preferably in medium pressure solution polymerization process. The films of this invention may be employed in a variety of uses, including, 1) “overwrap” packaging to protect goods during transportation, distribution, handling and display; and 2) food packaging, such as shrink wrap for frozen poultry, primal meat cuts and processed meat and cheese products.Type: GrantFiled: January 31, 2001Date of Patent: January 22, 2002Assignee: Nova Chemicals (International) S.A.Inventors: James Chin-Kuang Huang, Peter Andrew Sipos, Lawrence Thomas Kale, Patrick R. Thomas, James Arthur Auger
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Publication number: 20020007024Abstract: A novel process for producing homopolymers and copolymers of ethylene which involves contacting ethylene and/or ethylene and at least one or more other olefin(s) under polymerization conditions with a Ziegler-Natta type catalyst. at least one halogenated hydrocarbon, at least one compound of the formula XnER3-n as a co-catalyst and at least one compound containing at least one carbon-oxyen-carbon linkage (C—O—C) of the formula R1—O(—R2—O)n—R3 as an external electron donor. Also provided are films and articles produced therefrom.Type: ApplicationFiled: July 24, 2001Publication date: January 17, 2002Inventors: Randal Ray Ford, William Albert Ames, Kenneth Alan Dooley, Jeffrey James Vanderbilt, Alan George Wonders
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Patent number: 6337377Abstract: A process for producing an olefin polymer using a catalyst in which (A) is a solid catalyst component which includes magnesium, titanium, halogen and an electron donative compound as essential constituents; (B) is an organoaluminum component; and (C) is at least two electron donative compounds (&agr;) and (&bgr;), wherein the pentad stereoregularity of a xylene insoluble fraction of a homopolyproylene is 0<mmrr/mmmm≦0.0068 when electron donative compound (&agr;) is used in combination with (A) and (B), and the pentad stereoregularity of a xylene insoluble fraction homoproplyene of a is 0.0068<mmrr/mmmm ≦0.0320 when electron donative compound (&bgr;) is used in combination with (A) and (B). A polypropylene produced in the process can be used to obtain a biaxially oriented film. (A) and (B). A polypropylene produced in the process can be used to obtain a biaxially oriented film.Type: GrantFiled: February 7, 2000Date of Patent: January 8, 2002Assignee: Sumitomo Chemical Company, Ltd.Inventors: Takeshi Ebara, Koji Mizunuma, Toshio Sasaki, Kazuki Wakamatsu, Junichi Kimura, Yoichi Obata
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Publication number: 20010053453Abstract: Disclosed are a binary random copolymer of propylene and ethylene, and a film to be formed by sheeting the copolymer. The film has good heat-sealability, high stiffness, good anti-blocking and slipping properties, and high transparency. As having excellent heat-sealability at low-temperature, the copolymer and its film are favorably used as sealant layers of laminate films.Type: ApplicationFiled: October 14, 1997Publication date: December 20, 2001Inventors: YASUSHI SETA, SATOSHI NAKATSUKA, MICHIHIRO SAWADA, RYOICHI TSUNORI, TOKUTARO KIMURA, YUTAKA MINAMI
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Publication number: 20010053837Abstract: The copolymerization reaction of one or more olefin monomers, such as propylene, with &agr;,&ohgr;-diene units and the resulting copolymers are provided. More specifically, the copolymer may have from 90 to 99.999 weight percent of olefins and from 0.001 to 2.000 weight percent of &agr;,&ohgr;-dienes. The copolymer may have a weight average molecular weight in the range from 50,000 to 2,000,000, a crystallization temperature (without the use of externally added nucleating agents) in the range from 115° C. to 135° C. and a melt flow rate in the range from 0.1 dg/min to 100 dg/min. These copolymers may be employed in a wide variety of applications, the articles of which include, for example, films, fibers, such as spunbonded and meltblown fibers, fabrics, such as nonwoven fabrics, and molded articles. The copolymer may further include at least two crystalline populations.Type: ApplicationFiled: February 20, 2001Publication date: December 20, 2001Inventors: Pawan Kumar Agarwal, Weiqing Weng, Aspy K. Mehta, Armenag H. Dekmezian, Main Chang, Rajan K. Chudgar, Christopher R. Davey, Charlie Y. Lin, Michael C. Chen, Galen C. Richeson
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Publication number: 20010039314Abstract: This invention relates generally to crystalline propylene polymers, to methods for their production and to methods for their use in film applications. Specifically, this invention relates to crystalline propylene polymers comprising both propylene homopolymer and propylene copolymer. The compositions are prepared using metallocene catalyst systems comprising at least two metallocenes in a polymerization process that involves the sequential or parallel polymerization of propylene homopolymer and copolymer using propylene with a small amount of comonomer, preferably ethylene. The polymerization is catalyzed by a dual metallocene catalyst system. The resulting polymers have a broad, bimodal molecular weight distribution. The resulting polymers are excellent for use in the production of biaxially oriented films or non-oriented films.Type: ApplicationFiled: March 6, 2001Publication date: November 8, 2001Inventors: Aspy K. Mehta, Michael C. Chen, James J. McAlpin, Anthony N. Speca, Kelly Tormaschy, Chon Y. Lin
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Publication number: 20010039317Abstract: Random copolymers including vinylidene fluoride and hexafluoropropylene that exhibit a large electrostrictive response when subjected to an electric field, articles including such polymers, and methods of preparing the polymers and articles. Electrostrictive responses greater than about 4 percent are obtainable at electric field strengths of 50 megavolts per meter.Type: ApplicationFiled: March 5, 2001Publication date: November 8, 2001Inventor: Jerry I. Scheinbeim
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Publication number: 20010037006Abstract: A method for the preparation of gel-free poly 2-hydroxyethyl methacrylate substantially in the absence of a chain transfer agent, comprising introducing monomeric 2-hydroxyethyl methacrylate containing ethylene glycol dimethacrylate impurities in the range of about 0.05 to 0.1% by weight into a solution of alcohol and water and polymerizing. The present invention also provides a method for the preparation of gel-free homopolymer of 4-hydroxybutyl acrylate substantially in the absence of a chain transfer agent in an alcohol or in solution of alcohol and water. The present invention also provides a method for the preparation of gel-free copolymer of 2-hydroxyethyl methacrylate and 4-hydroxybutyl acrylate substantially in the absence of a chain transfer agent, comprising introducing monomeric 2-hydroxyethyl methacrylate containing ethylene glycol dimethacrylate impurities in the range of about 0.05 to 0.1 % by weight with monomeric 4-hydroxybutyl acrylate into a solution of alcohol and water.Type: ApplicationFiled: January 10, 2001Publication date: November 1, 2001Inventor: Daniel L. Holguin