Thickener Or Dispersant For Aqueous System Patents (Class 526/932)
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Patent number: 9034996Abstract: The present invention relates to a production method for efficiently obtaining an acrylic acid-based polymer having a narrow molecular mass distribution and a low molecular mass, without using a large amount of chain transfer agent. A method for continuously producing an acrylic acid-based polymer obtained by continuously polymerizing a monomer having acrylic acid as an essential component, characterized in that a liquid feed pump applies a mechanical load of 0.5 to 2.5 kJ/L to the liquid discharged from the outlet of a reactor. An acrylic acid-based polymer having fewer high-molecular-mass components, excellent dispersion and other properties, and a low molecular mass is thereby obtained.Type: GrantFiled: October 29, 2012Date of Patent: May 19, 2015Assignee: TOAGOSEI CO., LTD.Inventor: Masahiro Fujiwara
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Patent number: 8883945Abstract: A compound of the formula R1.[(AO)n.—R2]m (I) where: R1 is the residue of a group having at least m active hydrogen atoms; AO is an alkylene oxide residue; each n is independently from 1 to 100; m is at least 2; and each R2 is independently H, a C1 to C21 hydrocarbyl, or an acyl group —OC.R3, where R3 is a C1 to C21 hydrocarbyl group, wherein on average greater than one of the R2 groups is or comprises a C4 to C21 hydrocarbyl group comprising at least two ethylenic double bonds. The compounds are particularly suitable for use in preparing aqueous emulsions or dispersions of resins and polymers, especially alkyd resins.Type: GrantFiled: December 15, 2004Date of Patent: November 11, 2014Assignees: Croda International PLC, Croda Americas LLCInventors: William Harry McNamee, Trevor Graham Blease, Johnny Denis Grade, Hanamanthsa Shankarsa Bevinakatti
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Patent number: 8859656Abstract: Emulsions containing acrylic associative thickening agents which, when polymerized in the presence of particular polyglycerols, have a thickening power which is remarkably stable over time.Type: GrantFiled: October 25, 2012Date of Patent: October 14, 2014Assignee: CoatexInventors: Jean-Marc Suau, Denis Ruhlmann
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Patent number: 8063265Abstract: A hydrogel having a floatability where from 40% to 90% of a solution and/or suspension to be thickened are thickened starting from the surface of the liquid and the rest of the solution and/or suspension to be thickened is thickened starting from the bottom of the container, a process for preparing the hydrogel and also its use for absorbing blood and/or body fluids, especially in hygiene articles, or for thickening aqueous solutions and/or suspensions, especially for thickening medical wastes.Type: GrantFiled: October 28, 2004Date of Patent: November 22, 2011Assignee: BASF AktiengesellschaftInventors: Martin Beck, Volker Frenz, Anna Kowalski, Elisabeth Selzer, Ernst Jürgen Bauer, Harald Keller, Bernhard Steinmetz
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Patent number: 6995221Abstract: A process for producing organic peroxide initiators useful in the polymerization of ethylenically unsaturated monomers. The process for making the organic peroxides includes forming an aqueous emulsion of the organic peroxide. The organic peroxide is dispersed as small droplets of from 1 to 10 microns in size in the aqueous emulsion. The organic peroxide may be added to a polymerization reactor containing an ethylenically unsaturated monomer. The organic peroxide functions as a free radical initiator to polymerize the monomer. The organic peroxide may be substantially free of organic solvents and plasticizers. The resulting polymers are of high quality.Type: GrantFiled: May 6, 2003Date of Patent: February 7, 2006Assignee: Oxy Vinyls, L.P.Inventors: Ross J. Cozens, Qi Wang, M. Frederick V. Glock, Jr., Daniel A. Zust
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Patent number: 6974852Abstract: An emulsifier system comprising a) a salt of a sulfuric monoester of a C9-C15 alcohol or of an alkoxylated C9-C15 alcohol, and b) an alkoxylated C8-C16 alcohol, and the use of this emulsifier system for preparing aqueous polymer dispersions.Type: GrantFiled: July 13, 2004Date of Patent: December 13, 2005Assignee: BASF AktiengesellschaftInventors: Bernd Stanger, Peter Keller, Eckehardt Wistuba, Andree Dragon
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Publication number: 20040249097Abstract: A process for producing organic peroxide initiators useful in the polymerization of ethylenically unsaturated monomers. The process for making the organic peroxides includes forming an aqueous emulsion of the organic peroxide. The organic peroxide is dispersed as small droplets of from 1 to 10 microns in size in the aqueous emulsion. The organic peroxide may be added to a polymerization reactor containing an ethylenically unsaturated monomer. The organic peroxide functions as a free radical initiator to polymerize the monomer. The organic peroxide may be substantially free of organic solvents and plasticizers. The resulting polymers are of high quality.Type: ApplicationFiled: May 6, 2003Publication date: December 9, 2004Inventors: Ross J. Cozens, Qi Wang, M. Frederick V. Glock, Daniel A. Zust
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Patent number: 6770719Abstract: A process for producing peroxydicarbonates comprising first reacting at least one inorganic peroxide with at least one alkali metal hydroxide to form at least one alkali metal peroxide. The at least one alkali metal peroxide is added to a mixture of at least one haloformate, at least one dispersant and water. The mixture is homogenized during the entire reaction to form a peroxydicarbonate. The peroxydicarbonate is dispersed as small droplets of from 1 to 10 microns in size in the aqueous mixture. The entire mixture is added to a polymerization reactor containing an ethylenically unsaturated monomer. The peroxydicarbonate functions as the free radical initiator to polymerize the monomer. The peroxydicarbonate is substantially free of organic solvents and plasticizers. The resulting polymers are of high quality.Type: GrantFiled: April 25, 2002Date of Patent: August 3, 2004Assignee: Oxy Vinyls, L.P.Inventor: Ross James Cozens
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Patent number: 6673885Abstract: Disclosed in the present invention is a process for preparing a (meth)acrylic acid-based polymer having a stable quality and suitable as a dispersant for cement. That is, the present invention provides a process for preparing a (meth)acrylic acid-based polymer, comprising the steps of the stage 1 of introducing (meth)acrylic acid and a polyalkylene glycol monoalkyl ether at a molar ratio in the range of 3:l to 50:1, subjecting them to an esterification reaction in the presence of an acid catalyst and a polymerization inhibitor and deactivating the acid catalyst with an alkaline agent in order to obtain an esterification product containing a (meth)acrylate and (meth)acrylic acid residues and the stage 2 of copolymerizing the (meth)acrylate and the (meth)acrylic acid residues at a pH value in the range of 1.5 to 3.5.Type: GrantFiled: April 15, 2002Date of Patent: January 6, 2004Assignee: Kao CorporationInventors: Kengo Shibata, Haruya Minou, Haruyuki Sato, Toshinao Ukena, Yoshinao Kono
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Patent number: 6660252Abstract: The invention relates to multiple emulsions comprising a primary emulsion in an external phase, and comprising a principle water phase and a principle oil phase, the multiple emulsion containing no more than about 1% of an emulsifier having an HLB of about 16 to about 20.Type: GrantFiled: February 28, 2001Date of Patent: December 9, 2003Assignee: Color Access, Inc.Inventors: Michelle Matathia, Charles Craig Tadlock
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Patent number: 6623658Abstract: An additive for controlling the detrimental effects of secondary recycled contaminants in the papermaking process. In the preferred embodiment, the additive includes a first low molecular weight, cationic water-soluble polymer and a second low molecular weight, cationic, water-soluble polymer, wherein the first low molecular weight, cationic, water-soluble polymer and the second low molecular weight, cationic, water-soluble polymer are co-reacted. In the preferred embodiment, the effective amount of the additive is determined by measuring about a 50 PPM reduction in soluble charge of the liquid base after adding the additive to the liquid base. In the most preferred embodiment, the reduction in soluble charge is between about 50 and 150 PPM as measured by determining the electrophoretic mobility of the liquid base with and without the additive.Type: GrantFiled: September 22, 2000Date of Patent: September 23, 2003Assignee: Industrial Chemical ConsultantsInventor: Charles William Robinson, Jr.
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Patent number: 6620880Abstract: An environmentally friendly stable aqueous optionally structured water-resistant architectural coating composition (especially a paint) containing a film-forming binder polymer composed of a starch modified by the presence of carboxylic acid or inorganic carboxylate groups and bonded (probably grafted) to chains of copolymerized mono-ethylenically unsaturated monomers (e.g. “acrylic”, “vinyl” or “styrenic” copolymers) permitting a stable aqueous dispersion of the binder polymer to be made which retains good water-resistance in the dried paint. The modified starch allows paints to be made with less dependence on materials obtained from non-renewable resources whilst retaining a low water-sensitivity.Type: GrantFiled: January 16, 2002Date of Patent: September 16, 2003Assignee: Imperial Chemical Industries PLCInventors: Susan Mary Horley, Stephen Arthur Wheeler
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Patent number: 6620870Abstract: Pressure-sensitive adhesives comprising an aqueous polymer dispersions wherein the polymer is composed of from 50 to 99.9% by weight of at least one C1-C12 alkyl (meth)acrylate (monomers a) from 0.05 to 20% by weight of at least one vinylaromatic compound (monomers b) from 0.05 to 10% by weight of at least one ethylenically unsaturated hydroxy compound (monomers c) from 0 to 10% by weight of an ethylenically unsaturated acid or an acid anhydride (monomers d) and from 0 to 30% by weight of other ethylenically unsaturated compounds (monomers e) the weight percentages being based on the polymer, and the polymer dispersion comprising an emulsifier consisting to the extent of at least 5% by weight of aromatic carbon atoms (and called aromatic emulsifier for short) or an emulsifier mixture consisting to the extent of at least 10% by weight of an aromatic emulsifier.Type: GrantFiled: November 6, 2001Date of Patent: September 16, 2003Assignee: BASF AktiengesellschaftInventors: Matthias Gerst, Gerhard Auchter, Bernhard Schuler
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Publication number: 20030153787Abstract: Compounds of the formula R2.[(AO)n.R3]m, where R2 is a residue of a group having at least m active hydrogen atoms derived from hydroxyl and/or amino and/or amido groups, AO is alkyleneoxy, n is 2 to 200; R3 includes residue(s) of alkenyl succinic acids and optionally other acids, and m is 2 to 10, but when m is 2 there are other restrictions in the definitions, are disclosed as useful thickeners and/or dispersants in aqueous systems. The use of such materials as thickeners is also disclosed.Type: ApplicationFiled: December 10, 2002Publication date: August 14, 2003Applicant: Imperial Chemical Industries PLCInventors: Neil Michael Carpenter, Steven John Anderson, Richard Robert Tenore, Peter Glynn Hibbert
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Patent number: 6602950Abstract: A hydrophilic, highly swellable hydrogel based on (co)polymerized monomers or based on graft (co)polymers and prepared by a) free-radically (co)polymerizing one-or more hydrophilic monomers or graft (co)polymerizing one or more hydrophilic monomers onto a grafting base, the average degree of neutralization of the acid-functional monomers being from 0 to 40 mol %, b) comminuting the acidic hydrogel, c) neutralizing the acidic hydrogel to an ultimate degree of neutralization of 50-85 mol % by adding a neutralizing agent, d) drying, grinding and sieving the hydrogel particles characterized by a centrifuge retention and a vertical absorption swell height, each having a specified minimum.value, coupled with an extractables content having a specified maximum value or a centrifuge retention and a vertical absorption swell height, each having a specified minimum value and an extractables content having a specified maximum value.Type: GrantFiled: April 6, 2001Date of Patent: August 5, 2003Assignee: BASF AktiengesellschaftInventors: Joachim Dentler, Rüdiger Funk, Norbert Herfert, Mariola Wanior, Friedrich Engelhardt
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Patent number: 6569976Abstract: Polymer compositions derived from selected monoethylenically unsaturated (C3-C6)carboxylic acid monomers, (C1-C4)alkyl (meth)acrylate ester monomers and alkoxylated (meth)acrylate monomers used in certain weight ratios to provide enhanced detergent and cleaning performance are disclosed. Polymer compositions containing from 5 to 40% of monoethylenically unsaturated (C3-C6)carboxylic acid monomer, from 35 to 65% of (C1-C4)alkyl (meth)acrylate ester monomer and from 20 to 60% of alkoxylated (meth)acrylate monomer provide improved cleaning performance in laundry detergent formulations relative to conventional polymer compositions.Type: GrantFiled: May 1, 2001Date of Patent: May 27, 2003Assignee: Rohm and Haas CompanyInventors: Steven Michael Baxter, Thomas Cleveland Kirk, Curtis Schwartz, Barry Weinstein
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Patent number: 6565768Abstract: Water-swellable hydrophilic polymers are prepared by neutralization of the acidic hydrogel having a degree of neutralization of 0-40 mol % to an ultimate degree of neutralization of 60-85 mol % by mixing with a neutralizing agent in a mincer comprising a system of screw, rotating blade, restricted flow zone and breaker plate, wherein the mincer has a power output of from 1000 to 6000 Wh/m3 the hydrogel passes through a zone having-an energy dissipation density of from 400 to 800 W/1 of mixing volume the average residence time of the hydrogel in the mincer is from 5 to 30 seconds the breaker plate has an open area of from 20 to 40%.Type: GrantFiled: April 6, 2001Date of Patent: May 20, 2003Assignee: BASF AktiengesellschaftInventors: Joachim Dentler, Norbert Herfert, Rudolf Schliwa, Uwe Stüven, Fritz Engelhardt
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Patent number: 6476168Abstract: Disclosed is an emulsion useful in an inversion process. The emulsion is a water-in-oil emulsion and has an aqueous phase having a water-soluble polymer, an oil phase and an activating agent of the following formula: wherein n=0 to 10 and m=2 to 25 and the oxypropylene and oxyethylene units are of block distribution or intermixed in random or tapered distribution. Further disclosed is a process according to the following: a) providing an water-in-oil emulsion having a water-soluble polymer in the aqueous phase and the activating agent; b) introducing the emulsion into an aqueous medium and c) allowing sufficient time for the emulsion to invert. Further disclosed is another process according to the following: a) providing an water-in-oil emulsion having a water-soluble polymer in the aqueous phase; b) introducing the emulsion into an aqueous medium having the activating agent and c) allowing sufficient time for the emulsion to invert.Type: GrantFiled: September 14, 2001Date of Patent: November 5, 2002Assignee: Rhodia, Inc.Inventors: Manilal S. Dahanayake, Fang Li, Jean-Luc Joye
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Patent number: 6469204Abstract: These compounds are represented by the formulae (Ia) and (Ib). To prepare them, in a first stage, p-xylylene dichloride is reacted with a compound (II) to produce a compound (III) and, in a second stage, the compound (III) thus obtained is reacted with a compound of formula (IVa) or (IVb), resulting in an aqueous solution of the compound (Ia) or (Ib) respectively, the water of which is removed, if appropriate.Type: GrantFiled: October 30, 2001Date of Patent: October 22, 2002Assignee: AtofinaInventors: Alain Riondel, Vladimir Chaplinski
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Patent number: 6423130Abstract: The invention relates to phosphoric esters of the general formula I where X is 1 or 2; n is from 2 to 18; m and o are each from 2 to 100; k is from 2 to 4; R″ is H or a linear or branched alkyl radical; and R′ is an alkyl, alkaryl, alkenyl, or sulfopropyl radical, and to there use as dispersants for pigments and fillers in aqueous or organic media.Type: GrantFiled: April 10, 2001Date of Patent: July 23, 2002Assignee: Th. Goldschmidt AGInventors: Tammo Boinowitz, Eberhard Esselborn, Arno Knebelkamp, Christian Psiorz, Stefan Silber, Stefan Stadtmüller, Ellen Wallhorn
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Publication number: 20020077395Abstract: Aqueous emulsion polymer compositions stabilized with the reaction product of alkoxylated alcohols and an epihalohydrin or a trihaloalkanes.Type: ApplicationFiled: November 7, 2001Publication date: June 20, 2002Inventors: Marcie Natale, Rudolph Klima, Thomas Hopkins, Michael Wiggins
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Patent number: 6399718Abstract: The present invention provides a polyurethane resin obtainable by (A) in a first reaction stage (A) reacting (a) one or more di- and/or polyisocyanates, (b) one or more compounds (b) which have at least one group which ensures dispersibility in water and more than one group which is reactive toward isocyanate groups, and (c) if desired, one or more compounds having at least 2 and not more than 3 OH groups to give an intermediate (A) having free isocyanate groups and having urethane groups, (B) in a second reaction stage (B) adding (d) one or more monoisocyanates to the intermediate (A) obtained in stage (A), and (C) subsequently reacting the resulting mixture (B) with one or more hydroxyl-containing polymers (D) to give the polyurethane resin (P), using less than 20% by weight, based on the weight of the polyurethane resin (solids content), of polyalkylene oxide diols and/or polyalkylene oxide polyols to prepare the polyurethane resin.Type: GrantFiled: February 21, 2000Date of Patent: June 4, 2002Assignee: BASF Coatings AGInventors: Heinz-Peter Rink, Horst Hintze-Brüning, Peter Weinert
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Patent number: 6388038Abstract: The present invention provides a method for producing a cement dispersant having high percentage in water reduction rate and appropriate air-entraining property. This method for producing a polycarboxylic acid for a cement dispersant is characterized in that alkylene oxide is added at a specific temperature range.Type: GrantFiled: November 28, 2000Date of Patent: May 14, 2002Assignee: Nippon Shokubai Co., Ltd.Inventors: Tsuyoshi Hirata, Tsutomu Yuasa, Katsuhisa Shiote, Koichiro Nagare, Syogo Iwai
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Patent number: 6384132Abstract: An environmentally friendly stable aqueous optionally structured water-resistant architectural coating composition (especially a paint) containing a film-forming binder polymer composed of a starch modified by the presence of carboxylic acid or inorganic carboxylate groups and bonded (probably grafted) to chains of copolymerized mono-ethylenically unsaturated monomers (e.g. “acrylic”, “vinyl” or “styrenic” copolymers) permitting a stable aqueous dispersion of the binder polymer to be made which retains good water-resistance in the dried paint. The modified starch allows paints to be made with less dependence on materials obtained from non-renewable resources while retaining a low water-sensitivity.Type: GrantFiled: April 5, 1999Date of Patent: May 7, 2002Assignee: Imperial Chemical Industries, PlcInventors: Susan Mary Horley, Stephen Arthur Wheeler
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Patent number: 6369118Abstract: A biocompatible emulsifier for forming stable emulsions is disclosed. The emulsifier is particularly useful for emulsions of biological fluids, such as artificial blood, and for emulsions as drug delivery vehicles.Type: GrantFiled: September 9, 1998Date of Patent: April 9, 2002Assignee: University of PittsburghInventor: Toby J. Chapman
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Patent number: 6369117Abstract: Compositions comprising, in an aqueous phase, at least one amphiphilic polymer comprising at least one fatty chain and hydrophilic units, and at least one polyoxyalkylene, and optionally comprising a thickening system for use in particular in cosmetics.Type: GrantFiled: July 13, 1999Date of Patent: April 9, 2002Assignee: L'OrealInventors: Claude Dubief, Christine Dupuis
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Patent number: 6362259Abstract: Aqueous emulsion polymer compositions stabilized with the reaction product of alkoxylated alcohols and an epihalohydrin or a trihaloalkanes.Type: GrantFiled: July 29, 1999Date of Patent: March 26, 2002Assignee: Cognis CorporationInventors: Marcie Natale, Rudolph Klima, Thomas Hopkins, Michael Wiggins
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Publication number: 20020013494Abstract: Compounds of the formula R2.[(AO)n.R3]m, where R2 is a residue of a group having at least m active hydrogen atoms derived from hydroxyl and/or amino and/or amido groups, AO is alkyleneoxy, n is 2 to 200; R3 includes residue(s) of alkenyl succinic acids and optionally other acids, and m is 2 to 10, but when m is 2 there are other restrictions in the definitions, are disclosed as useful thickeners and/or dispersants in aqueous systems. The use of such materials as thickeners is also disclosed.Type: ApplicationFiled: August 25, 1999Publication date: January 31, 2002Inventors: NEIL MICHAEL CARPENTER, STEVEN JOHN ANDERSON, RICHARD ROBERT TENORE, PETER GLYNN HIBBERT
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Patent number: 6323259Abstract: The present invention is directed to an acrylic resin composition obtained by adding a non-crosslinked polymer powder having a bulk density within the range from 0.1 to 0.7 g/ml, an oil absorption based on linseed oil within the range from 60 to 200 ml/100 g and a degree of swelling by methyl methacrylate of 16-fold or more as a thickening agent to acrylic syrup; and acrylic premix obtained by mixing an inorganic filler with this composition; and acrylic premix obtained by extruding constituent components by a kneading extruder to continuously form the mixture; and a method for producing an acrylic artificial marble in which these acrylic premixes are cured.Type: GrantFiled: October 19, 1998Date of Patent: November 27, 2001Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Yukihiro Ikegami, Seiya Koyanagi, Yuichiro Kishimoto, Yoshihito Nakahara
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Patent number: 6310143Abstract: The present invention is directed to derivatized polycarboxylate dispersants for cementitious mixtures, including those mixtures with high percentages of pozzolan cement replacement and dry cast applications. In particular, the invention is directed to a cementitious mixture comprising cement, including cements with high percentages of pozzolan cement replacement, water, coarse aggregate, fine aggregate, and including a dispersant, wherein said dispersant is a derivatized polycarboxylate dispersant, or combination of polycarboxylate dispersants, which is a derivatized polymer comprising a backbone having moieties derived from (a) an unsaturated hydrocarbon; (b) at least one of a substituted carboxylic acid monomer, a substituted ethylenically unsaturated monomer, and maleic anhydride; and (c) optionally including an N-polyoxyalkylene succinimide; and wherein derivative moieties are pendant to the backbone monomer by at least one ester linkage and at least one amide linkage.Type: GrantFiled: December 16, 1998Date of Patent: October 30, 2001Assignee: MBT Holding AGInventors: Thomas M. Vickers, Jr., Rainer Packe-Wirth, Jeffrey R. Bury, Jesse Osborne, Runhai Lu, John Moreau, Lynn E. Brower, Samy M. Shendy, John Pickett
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Patent number: 6297337Abstract: Improved crosslinked ionic polymers or salts thereof having a soluble polymer fraction of less than about 15 wt %, and methods for making the same. The polymers are useful as bioadhesives, thickeners, emulsifiers, suspending aids, and pharmaceutical controlled release excipients.Type: GrantFiled: May 19, 1999Date of Patent: October 2, 2001Assignee: PMD Holdings Corp.Inventors: Nancy S. Marchant, Simon Hsaio-Pao Yu, Zahid Amjad
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Patent number: 6265495Abstract: A method for the production of an esterified product is provided which affords an esterified product with high quality by repressing, during the esterification reaction of an alcohol with (meth)acrylic acid, the occurrence of impurities, particularly gel, to be formed owing to the polymerization of the alcohol and the (meth)acrylic acid as raw materials, the esterified product consequently formed, or the mixture thereof.Type: GrantFiled: September 20, 1999Date of Patent: July 24, 2001Assignee: Nippon Shokubai Co., Ltd.Inventors: Tsuyoshi Hirata, Tsutomu Yuasa
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Patent number: 6174963Abstract: Provided is a method for producing an amphoteric resin which comprises reacting (1) a copolymerizable basic prepolymer A2 which is obtained by reacting a prepolymer A1 being obtained by polymerization of an amino group-containing &agr;, &bgr;-ethylenically polymerizable compound, other &agr;, &bgr;-ethylenically polymerizable compound and a polymerization initiator containing a carboxyl group at an end, with a compound having an epoxy group represented by the following formula (I): (wherein R1 represents H or a methyl group, and R represents a straight or branched chain alkyl group of 1-10 carbon atoms) in an amount of 0.1-1.0 equivalent for the amino group equivalent of the prepolymer A1 and (2) an &agr;, &bgr;-ethylenically polymerizable acidic prepolymer B2 which is obtained by carrying out the reaction in the same manner as above with (3) other &agr;, &bgr;-ethylenically polymerizable compound C.Type: GrantFiled: July 14, 1999Date of Patent: January 16, 2001Assignee: Taisei Chemical Industries, Ltd.Inventors: Mitsuo Tamazawa, Yasuo Kuroda
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Patent number: 6174950Abstract: Concentrated and low viscosity aqueous dispersions, e.g., opaque emulsions, well suited as flocculants for water treatment, comprise the water-soluble polymerizate of at least one water-soluble hydrophilic monomer A, optionally, at least one amphiphilic comonomer B and/or, also optionally, at least one hydrophobic comonomer C, in the presence of at least one polymeric dispersant incompatible therewith, for example an imidized and salified styrene/maleic anhydride copolymer or poly(diallyldimethylammonium chloride).Type: GrantFiled: January 26, 1998Date of Patent: January 16, 2001Assignee: Elf Atochem S.A.Inventors: Denis Tembou Nzudie, Didier Vanhoye
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Patent number: 6174980Abstract: The present invention provides a method for producing a cement dispersant having high percentage in water reduction-rate and appropriate air-entraining property. This method for producing a polycarboxylic acid for a cement dispersant is characterized in that alkylene oxide is added at a specific temperature range.Type: GrantFiled: December 16, 1997Date of Patent: January 16, 2001Assignee: Nippon Shokubai Co., Ltd.Inventors: Tsuyoshi Hirata, Tsutomu Yuasa, Katsuhisa Shiote, Koichiro Nagare, Syogo Iwai
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Patent number: 6156833Abstract: An improved emulsification base and a method for manufacturing same for non-aqueous chemical additives comprisesa mixture of water from 68 to 92 percent, of 2-amino-2 methyl-1 propanol from 0.1 to 0.2 percent, of an emulsifying surfactant blend from about 2.2 to 3.2 percent, of methyl esters of soybean oil from about 15-20 percent and of a 30% solution of polymer thickener from about 0.25 to 0.50 percent.Type: GrantFiled: February 12, 1999Date of Patent: December 5, 2000Assignee: PCI Group, Inc.Inventor: Thomas E. Rauls
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Patent number: 6140435Abstract: Cross-linked copolymers possessing high thickening and suspending properties obtainable by polymerization of monomeric systems comprising a) 10-97% of at least one unsaturated carboxylic acid, b) 0-80% of at least one alkyl ester of an unsaturated acid, c) 0.5-80% of an associative monomer, d) 0-20% of an unsaturated amide, e) 0.2-20% of a suitable cross-linking agent and f) 0-20% of an unsaturated sulfonic acid; processes for their preparation, which comprise polymerization by precipitation, suspension and solution polymerizations or emulsion polymerization; latexes comprising up to 50% or more of said copolymers; said cross-linked copolymers and said latexes whenever prepared by the above polymerization processes; their use as thickening agents of aqueous, or substantially aqueous systems; and the new cross-linking agents.Type: GrantFiled: April 8, 1998Date of Patent: October 31, 2000Assignee: 3V, Inc.Inventor: Matteo Zanotti-Russo
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Patent number: 6103786Abstract: Stable polymer dispersions with polymer particle sizes of 0.1 to 10 .mu.m are prepared by dissolving a water-in-oil emulsion, comprising a polymer dissolved in an organic solvent which is immiscible with water (organic phase) and an aqueous phase, wherein the viscosity of the organic phase is 1.0 to 20,000 mPas (measured at 25.degree. C.), the surface tension between organic and aqueous phase is 0.01 to 30 mN/m, the particle size of the water emulsified in the organic phase is 0.2 to 50 .mu.m and the ratio by volume of organic phase to aqueous phase is in the range 80:20 to 20:80, subjecting this emulsion to a shear process at a shear power of 1.times.10.sup.3 to 1.times.10.sup.8 Watts per cm.sup.3, wherein the water-in-oil emulsion is converted into an oil-in-water emulsion.Type: GrantFiled: February 24, 1998Date of Patent: August 15, 2000Assignee: Bayer AktiengesellschaftInventors: Martin Hoch, Rainer Elbert, Bernd Klinksiek
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Patent number: 6051159Abstract: This invention relates to a preferred composition for use in preparation of flexible cold packs which are useful for medicinal, research and other uses where cooling to low temperatures is required.Type: GrantFiled: March 2, 1998Date of Patent: April 18, 2000Inventor: Jie Hao
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Patent number: 6051160Abstract: This invention relates to a liquid composition for the control of pitch deposition in pulp and paper making comprising an aqueous solution of (1) a derivatized cationic guar, and (2) styrene maleic anhydride copolymer. The invention also relates to a process for inhibiting pitch deposition in pulp and papermaking systems and on papermaking equipment.Type: GrantFiled: April 15, 1998Date of Patent: April 18, 2000Assignee: Ashland Inc.Inventors: Linda M. Hlivka, George K. Wai
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Patent number: 6002049Abstract: Latexes are thickened by compounds of the formula ##STR1## wherein R.sup.1 is an aliphatic, substituted aliphatic, aromatic, or substituted aromatic radical having a valence of from 2 to 8; each of B.sub.1 -B.sub.8 is independently an ester, amide, amine, ether, sulfide, disulfide, thiocarbamate, urea, thiourea, urethane, sulfate, phosphate, carbonyl, methylene, thioamide, carbonate, or imide linkage; each of X.sup.1 -X.sup.8 is independently --A.sub.1 --R.sup.2 --A.sub.2 -- or --A.sub.1 -- wherein each of A.sub.1 and A.sub.2 is independently an ester, amide, amine, ether, sulfide, disulfide, urethane, thiocarbamate, urea, thiourea, sulfate, phosphate, carbonyl, methylene, thioamide, carbonate, or imide linkage and R.sup.2 is a divalent aliphatic, substituted aliphatic, aromatic, or substituted aromatic radical with the proviso that only one of B.sub.1 -B.sub.8 is urethane and that when one of B.sub.1 -B.sub.8 is urethane, one of A.sub.1 and A.sub.Type: GrantFiled: June 12, 1997Date of Patent: December 14, 1999Assignee: Henkel CorporationInventors: Michael S. Wiggins, Reuben H. Grinstein, Stephen A. Fischer
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Patent number: 5965213Abstract: Disclosed is an aqueous dispersion of a transparent powder coating consisting of a solid powder component and an aqueous component. The solid powder component includes at least one epoxy group-containing binder, at least one crosslinking agent, and optionally catalysts, adjuvants, or additives typical for transparent powder coatings. The binder contains 30-45% glycidyl-containing monomers and optionally vinylaromatic compounds such as styrene. The crosslinking agent is preferably a straight-chain aliphatic dicarboxylic acid and/or a carboxy-functional polyester. The aqueous component includes at least one nonionic thickener and optional materials such as catalysts, adjuvants, and/or other such materials. The nonionic thickener is preferably a nonionic associative thickener. The invention also provides a process for preparing the aqueous dispersion of the invention and a process for coating a vehicle body with the aqueous dispersion of the invention.Type: GrantFiled: February 2, 1998Date of Patent: October 12, 1999Assignee: BASF Coatings AGInventors: Lawrence Sacharski, Joachim Woltering, Peter Clark, Heinrich Wonnemann
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Patent number: 5910529Abstract: A water based gel guide coat composition and a method of using is provided. The composition comprises:aqueous dispersion(s) comprising a binder(s), aqueous emulsion(s) comprising a binder(s), and/or combinations thereof, having a minimum film forming temperature of 22.degree. C. or less;thickening agent of a type and in a sufficient amount to provide the composition with Bingham plastic properties upon shear;optionally additional water;water dispersible inorganic pigment(s); andoptional pH adjusting agent;the composition pH being about 6 to about 9.Type: GrantFiled: December 20, 1996Date of Patent: June 8, 1999Assignee: Minnesota Mining & Manufacturing Co.Inventor: Mark R. Wollner
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Patent number: 5874495Abstract: Novel aqueous thickener or thixotropic polymers are prepared by the copolymerization of (A) about 15-60 weight percent of a C.sub.3 -C.sub.8 alpha, beta-ethylenically unsaturated carboxylic acid monomer, preferably acrylic or methacrylic acid or a mixture thereof with itaconic or fumaric acid, (B) about 15-80 weight percent of a nonionic copolymerizable C.sub.2 -C.sub.12 alpha, beta-ethylenically unsaturated monomer, preferably a monovinyl ester such as ethyl acrylate or a mixture thereof with styrene, acrylonitrile, vinyl chloride or vinyl acetate, and (C) about 1-30 weight percent of a new and novel nonionic ethylenically unsaturated nonionic biphillic monomer such as tristyrylpoly(ethyleneoxy).sub.x methyl acrylate, to provide a stable aqueous colloidal dispersion at an acid pH lower than about 5.0 but becoming an effective thickener for aqueous systems upon adjustment to a pH of about 5.5-10.5 or higher. These polymers adjusted to a pH of about 5.Type: GrantFiled: June 7, 1995Date of Patent: February 23, 1999Assignee: Rhodia Inc.Inventor: Fred Robinson
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Patent number: 5849219Abstract: The invention relates to a stable aqueous dispersion of particles which can be flocculated by increasing the temperature to a value above the transition temperature. The invention is characterized in that the dispersion comprises a polymer selected from the group consisting of polyvinyl methyl ether and a block copolymer of polyvinyl methyl ether and a polyvinyl ether, the ether group bonded to the main chain via the oxygen atom being adsorbed onto the surface of the particles. The invention also relates to a block polymer of the above-mentioned type and to a method of manufacturing such a block copolymer. The invention enables very fine powders of ceramic particles having a very high homogeneity to be obtained.Type: GrantFiled: January 24, 1997Date of Patent: December 15, 1998Assignee: U.S. Philips CorporationInventors: Antonius W. M. De Laat, Hermannus F. M. Schoo
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Patent number: 5837272Abstract: A process for compatibly hydrating a fragmented solid which forms a gel with an aqueous composition, said process comprising:a. generating a first aqueous composition and a second oily composition containing the said fragmented solid;b. combining the first and second compositions in an at least the essential absence of air; andc. contacting the combined composition with a means for vibratorily mixing the combined composition, thereby causing the combined composition to be sufficiently mixed so as to hydrate the said fragmented solid to the extent that it is compatibilized into the composition and provides a stable gelled aqueous composition.Type: GrantFiled: December 13, 1996Date of Patent: November 17, 1998Assignee: Colgate Palmolive CompanyInventors: Louis Anthony Fierro, Jr., Gregory M. Renga, Joseph Frank Stima
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Patent number: 5833807Abstract: A process is disclosed for making aqueous aramid dispersion and aramid sheets of improved uniformity by utilizing water with a pH of greater than 10.Type: GrantFiled: April 17, 1997Date of Patent: November 10, 1998Assignee: E. I. du Pont de Nemours and CompanyInventors: Seshadri Ramachandran, Ronnie Aaron Allen
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Patent number: 5753731Abstract: A viscosity conditioner is disclosed which comprises a compound structured to have a group of the following formula (1) ##STR1## where R is a hydrocarbyl group, R' is a branched or secondary hydrocarbyl group, and n ranges from 1 to 500. The specified viscosity conditioner is conducive to reduced temperature dependence and hence constant viscosity in a certain range suited for all environmental conditions and good coatability at all seasons. Also disclosed are an emulsion composition and an emulsion paint composition, each of which include of the viscosity conditioner.Type: GrantFiled: August 30, 1996Date of Patent: May 19, 1998Assignee: Asahi Denka Kogyo K.K.Inventors: Toyotaro Yoshioka, Kaoru Komiya
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Patent number: 5723063Abstract: The invention relates to composition for use in preparation of cold packs which are useful for medicine, research and other uses where cooling to a low temperature is required, said composition comprising 70-85% water, 4-10% salt, 8-15% glycerine and 2-6% polyacrylamide.Type: GrantFiled: June 26, 1996Date of Patent: March 3, 1998Inventor: Hae Jie
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Patent number: RE39746Abstract: The invention relates to phosphoric esters of the general formula I where X is 1 or 2; n is from 2 to 18; m and o are each from 2 to 100; k is from 2 to 4; R? is H or a linear or branched alkyl radical; and R? is an alkyl, alkaryl, alkenyl, or sulfopropyl radical, and to there use as dispersants for pigments and fillers in aqueous or organic media.Type: GrantFiled: May 25, 2004Date of Patent: July 31, 2007Assignee: Goldschmidt GmbHInventors: Tammo Boinowitz, Eberhard Esselborn, Arno Knebelkamp, Christian Psiorz, Stefan Silber, Stefan Stadtmüller, Ellen Wallhorn