Thickener Or Dispersant For Aqueous System Patents (Class 526/932)
  • Patent number: 5634971
    Abstract: A process of dispersing a pigment consists of agitating a pigment in water with a polyoxyalkylated ether dispersant. The polyoxyalkylated ether comprises Units of the formulae A and B whereinUnit A is an alkyl group of the formula: ##STR1## and; Unit B is an oxyalkylate of the formula:(OCH.sub.2 CHR.sub.2).sub.y OR.sub.3 (IB)wherein R and R.sub.1 individually represent hydrogen or a C.sub.1 -C.sub.10 alkyl group; R.sub.2 is --H or a C.sub.1 -C.sub.5 alkyl group; x represents a number from about 9 to about 75; R.sub.3 is --H or a C.sub.1 -C.sub.5 alkyl group; and y is between about 1 to about 475.
    Type: Grant
    Filed: October 25, 1995
    Date of Patent: June 3, 1997
    Assignee: Petrolite Corporation
    Inventor: Timothy J. Baker
  • Patent number: 5552519
    Abstract: Surfactant obtainable by and method for the production thereof comprising (1) esterifying a rosin with an alcohol to an acid value of less than 30, (2a) grafting the rosin ester with an unsaturated carboxylic acid or anhydride, the mole ratio carboxylic acid or anhydride/rosin (calculated as each rosin associated with a rosin ester) being from 0.05:1-1.5:1, (3a) esterifying the grafted rosin ester with a polyethylene glycol with an Mw of 1000-20000 the mole ratio glycol/free carboxylic acid group being from 0.2:1-1:1 to an acid value of less than 30, alternatively (2b) esterifying an unsaturated carboxylic acid or anhydride with a polyethylene glycol with a Mw of 1000-20000 the mole ratio glycol/free carboxylic acid group or anhydride being from 0.2:1-1:1 to an acid value less than 30, (3b) grafting the rosin ester from (1) with the ester from (2b), the mole ratio ester from (2b)/rosin ester (calculated as in (2a)) being from 0.05:1-1.5:1.
    Type: Grant
    Filed: May 16, 1995
    Date of Patent: September 3, 1996
    Assignee: EKA Nobel, AB
    Inventors: Paul N. Hemmings, Long Wang
  • Patent number: 5486312
    Abstract: Gels stable in a subterranean formation at a temperature greater than about 175.degree. F. are formed using, inter alia, a stabilizing agent (e.g., a buffer having a buffering capacity at a pH of at least about 8 and/or a chelating agent).
    Type: Grant
    Filed: September 10, 1993
    Date of Patent: January 23, 1996
    Assignee: Union Oil Company of California
    Inventors: Burton B. Sandiford, Hoai T. Dovan, Richard D. Hutchins
  • Patent number: 5476885
    Abstract: A cement additive composed of a crosslinked polymer in which, between main chains having a water-soluble polymer structure of a molecular weight from 500 to 100,000, there is a bond having as a structural unit at least one divalent group having the following formula (I): ##STR1## where R.sup.1 and R.sup.2 independently denote any one of the following: ##STR2## where R.sup.1 is not required, if R.sup.2 is the following: ##STR3## and where R and R' independently denote an alkyl group of carbon number of 1 to 5.
    Type: Grant
    Filed: March 25, 1991
    Date of Patent: December 19, 1995
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Hideyuki Tahara, Hiroshi Ito, Yasuhiro Mori, Makoto Mizushima
  • Patent number: 5440000
    Abstract: A dispersant/antioxidant bound, Viscosity Index-improving methacrylate polymer composition having a molecular weight ranging from about 20,000 to about 2,500,000. The composition comprises a base oil and methacrylate monomers and antioxidant monomer with inherent dispersancy. The composition being prepared by:(a) mixing a antioxidant/dispersant monomer with alkyl methacrylates and an oil solvent to provide an intermediate reaction mixture;(b) stirring and purging said reaction mixture by nitrogen ebullation for about 25-35 minutes at about 200 ml/min;(c) heating said purged mixture to about 75.degree.-85.degree. C.;(d) adding both a chain transfer agent and a radical polymerization catalyst to said heated mixture and then after about 2.0 hours adding an additional amount of said catalyst to said heated mixture, and then heating said heated mixture for an additional 2.0 hours;(e) increasing the temperature of said heated mixture to about 95.degree.-105.degree. C.
    Type: Grant
    Filed: July 18, 1994
    Date of Patent: August 8, 1995
    Assignee: Texaco Inc.
    Inventors: Shailaja M. Shirodkar, Nicholas Benfaremo, Rosemary J. Jennejahn
  • Patent number: 5418271
    Abstract: Coating formulations which behave as elastic solids having reversible stress-induced fluidity are prepared by creating a fluid having distributed therein effective amounts of ionic charge sites and countercharge sites. For instance, elastic solids having reversible stress-induced fluidity are prepared by combining liquid formulations with a dispersion of a small, but effective, amount of at least one crystalline mixed metal hydroxide conforming substantially to the formulaLi.sub.m D.sub.d T(OH).sub.(m+2d+3+n.multidot.a) (A.sup.n).sub.a .multidot.xH.sub.2 Owhere m is zero to one, D is a divalent metal, d is from zero to 4, T is a trivalent metal, A represents at least one anion or negative-valence radical of valence n and a is the amount of A, where n is 1 or more, (m+2d+3+n.multidot.a) is equal to or greater than 3, (m+d) is greater than zero, and xH.sub.2 O represents excess waters of hydration, if any.
    Type: Grant
    Filed: October 11, 1991
    Date of Patent: May 23, 1995
    Assignee: The Dow Chemical Company
    Inventors: John L. Burba, III, Peter A. Doty, Christopher P. Christenson, Susan K. Falcone, Andrea H. Hazlitt, Thomas M. Knobel, Wilfred C. Meyer, Arthur E. Read, Jr., Edgar F. Hoy, Avis L. McCrary, Ha Q. Pham, Stanley F. Simpson, Steve A. Sims, Betty J. Smith
  • Patent number: 5374687
    Abstract: A pourable, liquid antisettling composition comprises at least one low molecular weight copolymer of ethylene and an alpha, beta-ethylenically unsaturated carboxylic acid that has been neutralized with a neutralizing agent and water. The composition can be an additive in aqueous coating compositions and provides excellent pigment suspension and rheological properties to aqueous based coating and ink compositions.
    Type: Grant
    Filed: December 28, 1993
    Date of Patent: December 20, 1994
    Assignee: Rheox, Inc.
    Inventors: Murray C. Cooperman, William W. Reichert
  • Patent number: 5349036
    Abstract: An amphipathic co-polymer having a weight average molecular weight of from 2,500 to 20,000 inclusive and comprising an addition polymer backbone and at least one C.sub.1-4 alkoxy polyethylene or polyethylene copropylene glycol acrylate or methacrylate stabilizer unit where the backbone comprises up to 30% by weight of non-functional structural units and at least 70% by weight in total of stabilizer units and functional units where the functional units are optionally substituted styrene-containing units, hydroxy group-containing units and carboxyl group containing units, such that the proportions of hydroxy groups to carboxyl groups to styrene groups to propylene-oxy or ethylene-oxy groups are respectively 1 : 0.10-26.1; 0.28-25.0; 0.80-66.1.
    Type: Grant
    Filed: April 16, 1993
    Date of Patent: September 20, 1994
    Assignee: Imperial Chemical Industries PLC
    Inventors: Michael A. D. Simpson, Trevor S. B. Sayer
  • Patent number: 5332524
    Abstract: Particles of water soluble polymers such as poly(olefin oxides) are formulated to readily dissolve without agglomerating by associating polymer particles with particles of gas producing compounds, suitably a bicarbonate and an acid salt, which are non-reactive to the polymer but produce gas when wetted with water whereby the generated gas maintains polymer particles in separation as the particles dissolve.
    Type: Grant
    Filed: April 20, 1992
    Date of Patent: July 26, 1994
    Assignee: Valkyrie Scientific Proprietary, L.C.
    Inventor: Joseph B. Kaylor
  • Patent number: 5300600
    Abstract: Disclosed are high concentration aqueous dispersions of normally solid organic peroxides using a dispersion agent comprising an alkylaryl polyether alcohol and an oxyalkylated phenolic resin. Optional components such as thickening agents, anionic emulsifiers and a partial ester of a carboxylic acid copolymer may also be included. Dispersions having concentrations of up to about 65% weight percent organic peroxide can be prepared. Dispersions having concentrations of up to about 40 weight percent organic peroxide are sprayable. Also disclosed are the curing of polyester resins and the suspension polymerization of vinyl monomers using these dispersions.
    Type: Grant
    Filed: May 7, 1992
    Date of Patent: April 5, 1994
    Assignee: Witco Corporation
    Inventors: Lawrence A. Bock, Ronald L. Pastorino, Douglas Nordhaus
  • Patent number: 5298570
    Abstract: The invention provides biodegradable crosslinked polymers, which have a chelating effect and a dispersing effect to disperse an oily substance and an inorganic substance hardly soluble in water and are excellent in dispersion into water. The crosslinked polymers comprise; an ingredient of molecular weight 5,000 or less in 50% by weight, a bond having at least one of a group (II) represented by the chemical formula --CO--O-- and a group (III) represented by the chemical formula --CO--NH-- as a composition unit between main chains having a water-soluble oligomer structure having the functional group (I) represented by the general formula --COOM (here, M denotes anyone of a hydrogen atom, monovalent metal, divalent metal, trivalent metal, an ammonium group and organic amine group.), and showing a viscosity of 1,000 cP or less at 20.degree. C. by a 20% by weight aqueous solution of the crosslinked polymer.
    Type: Grant
    Filed: August 20, 1992
    Date of Patent: March 29, 1994
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Hideyuki Tahara, Hiroshi Ito, Masahito Takagi, Yoshio Irie, Keishi Tsuboi, Shigeru Yamaguchi
  • Patent number: 5244475
    Abstract: An emulsion composition with a polymerizing and/or crosslinking agent and method for its use in improving the manufacturing, packaging, transporting, storage placement and blasting characteristics of explosives containing an emulsion. More specifically, compositions and methods directed to controlling the rheology of an emulsion or explosive containing an emulsion by polymerizing and/or crosslinking the continuous phase of the emulsion by employing hydroxy-terminated polybutadiene and polymerizing agents and/or maleic anhydride adducted polybutadiene and crosslinking agents, but without compromising the integrity of the explosive reaction.Explosive materials comprised of a water-in-oil emulsion containing a continuous carbonaceous fuel phase at least partially polymerized and/or crosslinked.
    Type: Grant
    Filed: December 4, 1990
    Date of Patent: September 14, 1993
    Assignee: Mining Services International Corporation
    Inventors: C. Mick Lownds, Steven C. Grow
  • Patent number: 5073591
    Abstract: A method for producing an acidic, concentrated, polymeric emulsion that can be diluted and thereafter neutralized to provide a novel polymeric thickener is disclosed. The method comprises emulsion-polymerizing, in acidic aqueous media, a first monomer mixture which comprises an acidic moiety-containing monomer and an ethylenically-unsaturated monomer copolymerizable with the acidic moiety-containing monomer, for producing an alkali-soluble dispersion in the acidic aqueous media. The ethylenically-unsaturated monomer is selected from the group consisting of a mono vinylidene aromatic monomer, an alpha beta ethylenically-unsaturated carboxylic acid ester and its derivatives, a vinyl ester and its derivatives, an ethylenically-unsaturated dicarboxylic anhydride and its derivatives, and mixtures thereof.
    Type: Grant
    Filed: September 17, 1990
    Date of Patent: December 17, 1991
    Assignee: S. C. Johnson & Son, Inc.
    Inventor: Sheng-Liang Tsaur
  • Patent number: 5063052
    Abstract: Cosmetic and dermatological application of polysiloxanes containing a diester functional group and compositions employed.The invention relates to the use in cosmetics and in dermatology of diorganopolysiloxanes containing a diester functional group carrying, per molecule, at least one unit of formula:ZR.sub.a SiO.sub.(3-a)/2where a is 0, 1 or 2, Z is a radical of formula: ##STR1## the symbols R', which are identical or different, denote a C.sub.1 -C.sub.12 monovalent saturated hydrocarbon, C.sub.2 -C.sub.12 alkoxyalkyl or C.sub.8 -C.sub.12 aryl, alkylaryl or aralkyl radical, X denotes H or CH.sub.3 ; W is a covalent bond or a C.sub.1 -C.sub.4 alkylene radical; and the symbols R, which are identical or different, denote C.sub.1 -C.sub.20 alkyl, vinyl, phenyl, 3,3,3-trifluoropropyl or hydroxyl, provided that only one radical R per silicon atom denotes hydroxyl.
    Type: Grant
    Filed: September 26, 1989
    Date of Patent: November 5, 1991
    Assignee: L'Oreal
    Inventors: Jean F. Grollier, Claude Dubief
  • Patent number: 5053448
    Abstract: A method for producing an acidic, concentrated polymeric emulsion that can be diluted and thereafter neutralized to provide a novel polymeric thickener is disclosed. The method comprises emulsion-polymerizing, in acidic aqueous media, a first monomer mixture which comprises an acidic moiety-containing monomer and an ethylenically-unsaturated monomer copolymerizable with the acidic moiety-containing monomer, for producing an alkali-soluble dispersion in the acidic aqueous media. The ethylenically-unsaturated monomer is selected from the group consisting of a mono vinylidene aromatic monomer, an alpha beta ethylenically-unsaturated carboxylic acid ester and its derivatives, a vinyl ester and its derivatives, an ethylenically-unsaturated dicarboxylic anhydride and its derivatives, and mixtures thereof.
    Type: Grant
    Filed: July 21, 1989
    Date of Patent: October 1, 1991
    Assignee: S. C. Johnson & Son, Inc.
    Inventor: Sheng-Liang Tsaur
  • Patent number: 5034062
    Abstract: A stabilized aqueous suspension of calcined clay and a method for preparing the same are provided. The method involves an aqueous suspension of calcined clay containing at least 10% by weight clay, and at least 0.05% by weight of a high charge density crosslinked or uncrosslinked acid containing alkali-soluble acrylic copolymer.
    Type: Grant
    Filed: August 23, 1990
    Date of Patent: July 23, 1991
    Assignee: Rohm and Haas Company
    Inventors: George M. Lein, Robert C. Mahar
  • Patent number: 5013787
    Abstract: A thickened aqueous copolymer solution useful for thickening and improving the properties of latex systems comprising a copolymer having as monomeric units: about 79-99 percent of a (meth)acrylic acid salt of sodium, potassium, or ammonium; about 0-20 percent of (meth)acrylic acid; about 0-20 percent of a lower alkyl ester of (meth)acrylic acid; about 1-21 percent of surfactant units selected from the urea reaction product of a monoethylenically unsaturated monoisocyanate with a nonionic surfactant having amine functionality; and about 0-1 percent of a copolymerizable polyethylenically unsatured monomer, said percentages being by weight based on the total weight of monomeric units in said copolymer.
    Type: Grant
    Filed: December 29, 1989
    Date of Patent: May 7, 1991
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Milagros C. Barron, Ronald L. Swope, John M. Wilkerson, III
  • Patent number: 4916183
    Abstract: A thickened aqueous copolymer solution useful for thickening and improving the properties of latex systems comprising a copolymer having as monomeric units: about 79-99 percent of a (meth)acrylic acid salt of sodium, potassium, or ammonium; about 0-20 percent of (meth)acrylic acid; about 0--20 percent of a lower alkyl ester of (meth)acrylic acid; about 1-21 percent of surfactant units selected from the urea reaction product of a monoethylenically unsaturated monoisocyanate with a nonionic surfactant having amine functionality; and about 0-1 percent of a copolymerizable polyethylenically unsatured monomer, said percentages being by weight based on the total weight of monomeric units in said copolymer.
    Type: Grant
    Filed: March 2, 1989
    Date of Patent: April 10, 1990
    Assignee: National Starch and Chemical Corporation
    Inventors: Milagros C. Barron, Ronald L. Swope, John M. Wilkerson, III, Charles G. Ruffner
  • Patent number: 4880565
    Abstract: Shear stable antimisting properties are provided to a wide variety of formulations comprising aqueous liquids through the use of a viscoelastic surfactant which comprises a surfactant compound having a hydrophobic moiety chemically bonded to an ionic, hydrophilic moiety and an electrolyte having a moiety that is capable of associating with the surfactant ion. Optionally, an additional amount of electrolyte can be added to the viscoelastic surfactant to further reduce misting. The viscoelastic surfactant can also be a nonionic surfactant.
    Type: Grant
    Filed: April 12, 1985
    Date of Patent: November 14, 1989
    Assignee: The Dow Chemical Company
    Inventors: Gene D. Rose, Arthur S. Teot, Keith G. Seymour
  • Patent number: 4839166
    Abstract: Thickening agent resulting from the interaction of a copolymer of cellulose or of a cellulose derivative which are grafted with a quaternary ammonium salt of a water-soluble monomer and of a carboxylic anionic polymer and cosmetic compositions in which it is present.
    Type: Grant
    Filed: May 15, 1987
    Date of Patent: June 13, 1989
    Assignee: L'Oreal
    Inventors: Jean F. Grollier, Claude Dubief, Jean Mondet
  • Patent number: 4800220
    Abstract: The invention relates to the chemistry of polymers and to cross-linked carboxylic copolymers obtained by copolymerization of an unsaturated carboxylic monomer, a cross-linking agent, an acrylic or methacrylic acid ester with a polyalkylene glycol and, optionally, an alkyl acrylate or methacrylate. Utilization as thickeners, particularly of media containing dissolved salts.
    Type: Grant
    Filed: November 2, 1987
    Date of Patent: January 24, 1989
    Assignee: Manufacture de Produits Chimiques Protex
    Inventor: Alain Ribba
  • Patent number: 4769167
    Abstract: Aqueous functional fluids, in particular hydraulic and metal-working fluids, containing a copolymer which is prepared by emulsion or solution copolymerization, initiated by free radicals, of unsaturated, copolymerizable monomers, the copolymers being built up from:(a) 1-60% by weight of ethylenically unsaturated carboxylic acids,(b) 0.5-30% by weight of a surface-active unsaturated ester,(c) 30-85% by weight of methacrylic acid esters or acrylic acid esters of aliphatic (C.sub.1 -C.sub.18)-alcohols,(d) 0-40% by weight of other ethylenically unsaturated comonomers,(e) 0-3% by weight of polyethylenically unsaturated compounds, and(f) 0-5% by weight of molecular weight regulators, and, if appropriate, the free acid groups of the copolymers subsequently having been partly or completely neutralized by addition of bases, and converted into water-soluble or colloidally water-dispersible copolymer salts.
    Type: Grant
    Filed: December 5, 1986
    Date of Patent: September 6, 1988
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Raimund Haas, Dieter Engel, Rainer Helwerth
  • Patent number: 4656222
    Abstract: Water soluble salts of acrylic acid are polymerized and co-polymerized with acrylamide by an inverse emulsion polymerization in a water/hydrocarbon emulsion without catalyst to yield high molecular weight polymers.
    Type: Grant
    Filed: May 16, 1985
    Date of Patent: April 7, 1987
    Assignee: Celanese Corporation
    Inventor: Charles A. DeFazio