Non-1,2-epoxy, Or Nonphenolic Reactant Is An Alcohol, Inorganic Alcoholate, Or Ether Patents (Class 528/110)
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Patent number: 12351668Abstract: Polymerizable compositions suitable for use for 3D printed (e.g. orthodontic) articles, especially orthodontic alignment trays, are described. The polymerizable composition comprises a) 30-70 parts by weight of (meth)acrylate monomer(s); and b) urethane (meth)acrylate polymer; wherein the reaction product comprises at least 1 wt. % polymerized units of a multifunctional compound comprising pendent cyclic moieties. The orthodontic article comprises the reaction product of a polymerizable composition as described herein. The urethane (meth)acrylate polymer typically comprises polymerized units of a multifunctional compound comprising pendent cyclic moieties and/or at least one (meth)acrylate monomer comprises polymerized units of a multifunctional compound comprising pendent cyclic moieties. Also described are methods of making an article, non-transitory machine-readable medium comprising data representing a three-dimensional model of an article, and systems.Type: GrantFiled: May 19, 2020Date of Patent: July 8, 2025Assignee: Solventum Intellectual Properties CompanyInventors: Thomas P. Klun, Chad M. Amb, Richard J. Pokorny, Saswata Chakraborty, Benjamin C. Mac Murray, Tianyu Wu, Ahmed S. Abuelyaman, Yongshang Lu, Daniel J. Skamser, Karl J. L. Geisler, John M. Riedesel
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Patent number: 12122871Abstract: The present application is directed to a method for preparing a cyclic carbonate functional polyester, said method comprising the stages of (A) reacting glycerine carbonate with an anhydride to form an Adduct (A), (B) reacting said Adduct (A) with at least one polyepoxide compound to form an Adduct (B), and (C) reacting said Adduct (B) with at least one polycarboxylic acid to form said cyclic carbonate functional polyester.Type: GrantFiled: June 14, 2021Date of Patent: October 22, 2024Assignee: Henkel AG & Co. KGaAInventors: Jose Garcia Miralles, Sonia Flores Penalba, Marta Rodriguez Ble, Vito Maltese, Miguel Paradas-Palomo, Rosa Maria Sebastian Perez, Jorge Marquet Cortes
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Patent number: 12060482Abstract: A curable resin composition includes a polyether polyol resin represented by general formula (1) and having an epoxy equivalent of 7,000 to 100,000 g/eq, an epoxy resin having a functionality of 3 or more, and an epoxy resin curing agent. Provided is a curable resin composition that is excellent in heat resistance and also excellent in bending resistance in a well-balanced manner and that is applicable in various fields that require heat resistance and toughness, particularly, electrical and electronic fields. n is an integer of 1 or more. A1 and A2 are each a divalent organic group having an aromatic structure and/or an alicyclic structure. B is a hydrogen atom or a glycidyl group.Type: GrantFiled: April 6, 2021Date of Patent: August 13, 2024Assignee: Mitsubishi Chemical CorporationInventors: Yosuke Tsuge, Kotaro Nozawa, Kenta Yamamoto, Hayato Ogasawara
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Patent number: 11525059Abstract: An intumescent composition capable of withstanding temperature cycling as low as ?60° C. without cracking is contemplated. The composition also exhibits enhanced durability due to its resistance to water absorption, its acceptable cure times, and (when exposed to fire conditions) its well-adhered, foamed char layer.Type: GrantFiled: October 15, 2019Date of Patent: December 13, 2022Assignee: SWIMC, LLCInventor: Sharon L. Hilton
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Patent number: 8980979Abstract: A curable composition including (a) at least one cyclic diamine, (b) at least one non-heterocyclic amine that has a pKa value of approximately 9.5 to about 12 at 25° C. for the most basic amine group in the non-heterocyclic amine molecule, (c) at least one epoxy resin, and (d) at least one alkylated phenol; (i) wherein the equivalents of the amine hydrogens from the cyclic diamine compared to the total amine hydrogens from both the cyclic diamine and the non-heterocyclic amine in the composition are greater than about 5%; (ii) wherein the ratio of the equivalents of the total amine hydrogens in the composition to the equivalents of the total epoxies in the composition is greater than or equal to about 1; and (iii) wherein the alkylated phenol is in an amount greater than about 10 wt % of the curable composition.Type: GrantFiled: February 16, 2010Date of Patent: March 17, 2015Assignee: Dow Global Technologies LLCInventors: Marvin L. Dettloff, James R. Lowrey, Hemant A. Naik, Maurice J. Marks
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Patent number: 8791211Abstract: High refractive polymers, optical elements, and optical elements employing the same are provided. The polymer includes a repeat unit represented by Formula (I): wherein: R1 is independently an H, C1-8 alkyl group, C1-8 alkoxy group, or halides; R2 is independently an C1-8 alkyl group, C1-8 alkoxy group, or C1-8 alkanol group; n is 0, or 1; Y is R3 and R4 are each independently an H, C1-8 alkyl group, C1-8 alkoxy group, cycloalkyl group, aryl group, heteroaryl group, or heterocycloalkyl group, and two adjacent R3 groups are optionally combined with the carbon atoms which they are attached thereto, to form a cycloalkyl group, aryl group, heteroaryl group, or heterocycloalkyl group; and Z is independently a residual group of polycaprolactone diol, or a residual group of polyethylene glycol.Type: GrantFiled: June 14, 2011Date of Patent: July 29, 2014Assignee: Industrial Technology Research InstituteInventors: Ming-Jyh Chang, Zhi-Long Chen
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Patent number: 8722769Abstract: A light-curing resin composition includes an epoxy resin having two or more epoxy groups in one molecule; a photopolymerization initiator including an anion component and a cation component; and an aralkyl compound having an alcoholic hydroxyl group.Type: GrantFiled: December 19, 2011Date of Patent: May 13, 2014Assignee: Nitto Denko CorporationInventors: Yukiko Higo, Hiroshi Noro
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Patent number: 8349924Abstract: The present invention relates to a group of new plasticizers for thermoplastics such as polypropylene, copolymers of polypropylene, polyethylene, polyethylene terephthalates, polystyrene and/or other polymers or mixtures of polymers containing organic and/or inorganic fillers, where the plasticizer is used for obtaining polyvinyl chloride like aspects and improved processability as well as for obtaining a better flexibility and a lower energy consumption during the processing step.Type: GrantFiled: January 15, 2010Date of Patent: January 8, 2013Assignee: JJI Technologies, LLCInventors: Anton Constantinescu, Jose Reyes
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Publication number: 20120027973Abstract: Process for manufacturing a polymer by polycondensation of a hydroxy acid, said polymer comprising at least 80% by weight of units that correspond to the hydroxy acid, according to which at least one polyfunctional reactant capable of giving rise to the formation of a three-dimensional polymer network is mixed with the hydroxy acid, and according to which the mixture is subjected to temperature and pressure conditions and for a duration which are all suitable for giving rise to the formation of the network. Poly(hydroxy acid) (PHA) obtainable by such a process.Type: ApplicationFiled: April 2, 2010Publication date: February 2, 2012Applicant: SOLVAY SAInventor: Henri Wautier
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Publication number: 20110130537Abstract: In an improved process for preparation of glycidyl ether resins that are solid at room temperature, sometimes referred to as solid epoxy resins”, from a reaction mixture of an aromatic hydroxyl-containing compound, an epihalohydrin and an inorganic hydroxide, add a reaction solvent that has both a ether moiety ad an alcohol moiety to the reaction mixture and use mole-equivalent ratio of moles (one mole-equivalent) epihalohydrin to hydroxyl moieties of the aromatic hydroxyl-containing compound that falls within a range of from 0.5:1 to 1:1.Type: ApplicationFiled: July 7, 2009Publication date: June 2, 2011Applicant: DOW GLOBAL TECHNOLOGIES LLDInventors: Philip J. Carlberg, Ha Q. Pham, Lemimg Gu, Eric B. Rippiinger, David H. West, William G. Worley, Thomas C. Young
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Patent number: 7669720Abstract: Membranes comprising functional polyarylether having structural units of formula I are useful for hemodialysis and hemofiltration: wherein X is selected from Br, NR4R5, OOCR6, OR7, NR4CONR5R6, NR4COOR5R6 and combinations thereof; R1, R2 and R3 are independently at each occurrence CH2X, H, halo, cyano, nitro, a C1-C12aliphatic radical, a C3-C12cycloaliphatic radical, a C3-C12aromatic radical or a combination thereof; R4 and R5 are independently H, a C1-10 aliphatic radical, a C3-C12cycloaliphatic radical, a C3-C12 aromatic radical, or a combination thereof; R6 is H, a C2-10 aliphatic radical, a C3-C12 cycloaliphatic radical, a C3-C12 aromatic radical or a combination thereof; R7 is OCH2CH2(OCH2CH2)nOH or OOCCH2(OCH2CH2)nCH3; Z is a direct bond, O, S, SO, SO2, CO, phenylphospinyl oxide, alkenyl, alkynyl, a C1-C12aliphatic radical, a C3-C12cycloaliphatic radical, a C3-C12 aromatic radical or a combination thereof; a, b, and c are independently 1 or 2; and m, n and p are independently 0 or 1.Type: GrantFiled: December 15, 2006Date of Patent: March 2, 2010Assignee: General Electric CompanyInventors: Yanshi Zhang, Daniel Steiger, Joseph Anthony Suriano, Gary William Yeager
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Patent number: 7514507Abstract: The present invention provides a comb-shaped epoxy resin represented by the following formula (1): in the formula (1), X1 and X2 represent a divalent group having a residue selected from xanthene residue, biphenylene residue, hydrogenated bisphenol residue, alkylene residue and polyoxyalkylene residue, each may having a methyl group or a ethyl group as a substituent, and at least one of them is an aromatic residue, Y represents a polymer chain such as linear polymer chain, a number average polymerization degree being 5 to 2000, and n (number average polymerization degree) represents an integer within a range of 3 to 200, and to a method for preparing the comb-shaped epoxy resin.Type: GrantFiled: March 23, 2005Date of Patent: April 7, 2009Assignees: Dainippon Ink and Chemicals, Inc., Kawamura Institute of Chemical ResearchInventors: Yuji Ohashi, Ren-Hua Jin, Seungtaeg Lee
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Patent number: 7501087Abstract: An epoxy resin composition comprises (a) an epoxy resin, (b) an anionic polymerization initiator and (c) from 1 to 30 parts by weight per 100 parts by weight of epoxy resin (a) of an aromatic ring-containing proton donor of a polyhydric alcohol and/or a polymercaptan.Type: GrantFiled: October 26, 2006Date of Patent: March 10, 2009Assignee: Toray Industries, Inc.Inventors: Toshiya Kamae, Hiroki Oosedo, Go Tanaka, Shigeo Iwasawa
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Publication number: 20090018303Abstract: A process for producing a low-molecular polyphenylene ether having a content of components with molecular weights of 20,000 or more of 10 mass % or less and a number average molecular weight of 4,000 or less by a redistribution reaction which involves reacting a raw polyphenylene ether having a number average molecular weight of 10,000 or more with a polyphenol compound and a radical initiator, characterized in that the redistribution reaction step is a step conducted in a solvent; the ratio of the raw polyphenylene ether to the solvent (raw polyphenylene ether:solvent) (mass ratio) is provided at 0.4:100 to 40:100 (mass ratio); and the ratio of the radical initiator to the solvent (radical initiator:solvent) (mass ratio) is provided at 0.5:100 to 5:100 (mass ratio).Type: ApplicationFiled: February 14, 2007Publication date: January 15, 2009Applicant: Asahi Kasei Chemicals CorporationInventors: Kenzo Onizuka, Minoru Sakurai
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Patent number: 7408015Abstract: The present invention relates to silane adducts having a relatively higher adhesive strength as expressed formula X3SiR1, and manufacturing method thereof. wherein X is a hydrogenated form selected from one of epoxy compounds, amino compounds and bisphenolic, and R1 is selected from one of glycidyloxypropyl group, 2-(3,4-epoxycyclohexyl)ethyl group, 3-acryloxypropyl group, 3-methacryloxypropyl group, amino-propyl group, 3-[2-(2-aminoethylamino)ethylamino]propyl group, N-methylaminopropyl group, N-phenylaminopropyl group, N,N-dimethyl-3-aminopropyl group, mercapto-propyl group, cyano-propyl group, and isocyanato-propyl group.Type: GrantFiled: December 19, 2005Date of Patent: August 5, 2008Assignee: LG Cable, LtdInventors: Byoung Un Kang, Hyuk Soo Moon, Jong Kul Lee, Kyoung Tae Wi, Tae Sung Kim
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Patent number: 7390540Abstract: Various embodiments of the present invention are directed to methods for manufacturing complex, anisotropic materials with desirable properties for information storage, processing, and display. Certain of these methods involve employing a magnetic field during manufacture to induce desired orientations of precursors, subunits, and/or molecular subassemblies. The applied magnetic field steers the precursors, subunits, and/or molecular subassemblies into desirable orientations while the precursors, subunits, and/or molecular subassemblies are assembled or self-assemble into a complex, anisotropic material. One embodiment of the present invention is a class of new, complex, well-ordered, network-like materials that include a ferromagnetic-material-based framework in which organic and/or organometallic compounds are organized.Type: GrantFiled: July 21, 2004Date of Patent: June 24, 2008Assignee: Hewlett-Packard Development Company, L.P.Inventors: Patricia A. Beck, Sean Zhang
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Publication number: 20070282081Abstract: An adhesive composition comprising 100 parts by weight of (A) a phenoxy resin having, per molecule, at least one alkoxy silane residue represented by the following formula (1) wherein R1 may be the same with or different from each other and is a substituted or unsubstituted C1-4 alkyl group, and R2 is a substituted or unsubstituted C1-9 monovalent group comprising a moiety selected from the group consisting of amino, cyanato, glycidoxy and thiol groups; 5 to 200 parts by weight of (B) an epoxy resin; a catalytic amount of (C) catalyst for curing the epoxy resin; and (D) an inorganic filler in an amount of from 33 to 300 parts by weight per total 100 parts by weight of the components (A), (B) and (C).Type: ApplicationFiled: June 4, 2007Publication date: December 6, 2007Inventor: Nobuhiro Ichiroku
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Patent number: 7241504Abstract: A polyol monomer comprising the formula: R1 is aliphatic or aromatic, R2 is aliphatic, aromatic, ester, ether, or acrylic, and R1 contains a hydroxyl group, R2 contains —O—CH2—CH(OH)—, or both. R1 is not a C4 or larger linear, unsubstituted aliphatic when R2 is a residue of a bisphenol. The polyol monomer may be made by reacting an epoxy and an alcohol. Either the epoxy contains more than one epoxide groups, the alcohol is a polyol, or both. A thermoset made by reacting the polyol monomer with a polyisocyanate.Type: GrantFiled: January 17, 2003Date of Patent: July 10, 2007Assignee: The United States of America as represented by the Secretary of the NavyInventors: Jozef Verborgt, Arthur Anthony Webb
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Patent number: 7217779Abstract: A phosphoric ester demulsifier composition prepared by reacting one or more alkylphenol-formaldehyde resin alkoxylates or one or more polyalkylene glycols, or a mixture thereof, with about 0.001 to about 1.0 molar equivalents of one or more phosphorous compounds selected from phosphorous oxychloride, phosphorous pentoxide and phosphoric acid and a method of using the demulsifier composition to resolve water-in-oil emulsions.Type: GrantFiled: March 14, 2003Date of Patent: May 15, 2007Assignee: Nalco CompanyInventor: Frank T. Lang
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Patent number: 7217769Abstract: A medical device with a hydrophilic and lubricious coating, wherein the coating includes a hydrophilic polymeric unit layer deposited on the medical device and cross-linked with a plasma deposited double bond monomer. The hydrophilic polymeric unit can include ethylene oxide with one or more primary or secondary alcohol groups or glycosaminoglycans such as hyaluronic acid, and the double bond monomer includes monomers containing at least one double bond, preferably a C?C, C?N or C?O bond, including N-trimethylsilyl-allylamine, ethylene, propylene and allyl alcohol.Type: GrantFiled: July 16, 2004Date of Patent: May 15, 2007Assignee: BioSurface Engineering Technologies, Inc.Inventors: Paul O. Zamora, Meng Chen, Shigemasa Osaki, Ting-Ting Hsieh, Ray Tsang
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Patent number: 7148294Abstract: An epoxy resin composition comprises (a) an epoxy resin, (b) an anionic polymerization initiator and (c) from 1 to 30 parts by weight per 100 parts by weight of epoxy resin (a) of an aromatic ring-containing proton donor of a polyhydric alcohol and/or a polymercaptan.Type: GrantFiled: March 27, 2002Date of Patent: December 12, 2006Assignee: Toray Industries, Inc.Inventors: Toshiya Kamae, Hiroki Oosedo, Go Tanaka, Shigeo Iwasawa
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Patent number: 7112635Abstract: Non-gelled polymeric polyols are prepared by the acid catalyzed copolymerization of water, tetrahydrofuran and multifunctional epoxy resins. The polyols can be cured with OH reactive crosslinkers such as amino resins and polyisocyanates to yield thermosetting coatings with useful properties.Type: GrantFiled: March 12, 2004Date of Patent: September 26, 2006Assignee: Air Products and Chemicals, Inc.Inventor: Frederick Herbert Walker
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Patent number: 7105625Abstract: The present invention relates to silane adducts having a relatively higher adhesive strength as expressed formula X3SiR1, and manufacturing method thereof. wherein X is a hydrogenated form selected from one of epoxy compounds, amino compounds and bisphenolic, and R1 is selected from one of glycidyloxypropyl group, 2-(3,4-epoxycyclohexyl)ethyl group, 3-acryloxypropyl group, 3-methacryloxypropyl group, amino-propyl group, 3-[2-(2-aminoethylamino)ethylamino]propyl group, N-methylaminopropyl group, N-phenylaminopropyl group, N,N-dimethyl-3-aminopropyl group, mercapto-propyl group, cyano-propyl group, and isocyanato-propyl group.Type: GrantFiled: August 29, 2003Date of Patent: September 12, 2006Assignee: LG Cable LTDInventors: Byoung Un Kang, Hyuk Soo Moon, Jong Kul Lee, Kyoung Tae Wi, Tae Sung Kim
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Patent number: 6987161Abstract: Hardeners are provided for curing epoxies at lower temperatures than currently available hardeners while retaining superior mechanical and thermal properties. A first component is selected from imidazole, dicyandiamide, or a mixture of polyamines and tertiary amines. A poiyol mixture is then selected. The first component is combined with the polyol mixture to form a hardener. The hardener is combined with epoxy resin and is cured. A method for selecting a hardener to yield an epoxy-hardener system with good properties after curing at a specified temperature and time includes selecting components for the hardener so the glass transition temperature of the cured epoxy-hardener system is not significantly lower than 45° C. above the cure temperature. The method includes steps for adjusting and controlling the ultimate glass transition temperature to maximize the mechanical properties of the epoxy-hardener system. The method regularly produces hardened epoxy systems having about 90% or more epoxy groups reactect.Type: GrantFiled: April 25, 2003Date of Patent: January 17, 2006Assignee: Ardes Enterprise, Inc.Inventor: Richard D. Schile
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Patent number: 6765069Abstract: A method for making a hydrophilic and lubricious coating, the coating so made and a medical device including such coating, wherein the coating includes a hydrophilic polymeric unit layer cross-linked with a plasma deposited double bond monomer. The hydrophilic polymeric unit can include ethylene oxide with one or more primary or secondary alcohol groups or glycosaminoglycans such as hyaluronic acid, and the double bond monomer includes monomers containing at least one double bond, preferably a C═C, C═N or C═O bond, including N-trimethylsilyl-allylamine, ethylene, propylene and allyl alcohol. The invention also provides products containing such coatings and their uses in medical, pharmaceutical and cosmetic applications.Type: GrantFiled: September 27, 2002Date of Patent: July 20, 2004Assignee: BioSurface Engineering Technologies, Inc.Inventors: Paul O. Zamora, Meng Chen, Shigemas Osaki, Ting-Ting Hsieh, Ray Tsang
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Patent number: 6743375Abstract: An epoxy resin hardener having a cure temperature of between about 60° C. and 100° C. comprises a mixture of: a) an imidazole or a trihydric compound having methylol groups at the 2- and 6-positions formed by reacting a 4-alkylphenol with 2 moles of formaldehyde, b) trimethylopropane, and c) tetramethylguanidine or a tetramethylguanidine derived from the reaction of a monepoxide, a diepoxide, a phenol and formaldehyde, or a dihydric phenol and formaldehyde.Type: GrantFiled: March 8, 2002Date of Patent: June 1, 2004Assignee: Ardes Enterprises, Inc.Inventor: Richard D. Schile
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Patent number: 6734260Abstract: The present invention provides a cationic coating composition capable of forming a coating film which is excellent in an electrodepositablly coating property and an adhesive property toward a rust preventive steel plate, a corrosion resistance and a low temperature curability. The cationic coating composition described above comprises as a vehicle component, a xylene-formaldehyde resin-modified, amino group-containing epoxy resin obtained by reacting an epoxy resin (A) having an epoxy equivalent of 180 to 2500 with a xylene-formaldehyde resin (B) and an amino group-containing compound (C).Type: GrantFiled: November 15, 2002Date of Patent: May 11, 2004Assignee: Kansai Paint Co., Ltd.Inventors: Shigeo Nishiguchi, Koji Kamikado, Susumu Midogochi, Akira Tominaga, Akihiko Shimasaki, Hideki Iijima
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Patent number: 6642344Abstract: A method for making flexible epoxy resins by curing an epoxide and a bis-phenol with an aliphatic secondary diamine having the structural formula (I) or (II): where R1 and R2 are each individually an alkyl, alkenyl, aryl, or arylalkyl group having from about 1 to about 20 carbon atoms, and R3 and R4 are each individually an alkyl or alkenyl group having from about 1 to about 20 carbon atoms, or hydrogen.Type: GrantFiled: January 22, 2002Date of Patent: November 4, 2003Assignee: Dorf Ketal Chemicals, LLCInventors: David W. House, Ray V. Scott, Jr.
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Patent number: 6620908Abstract: A method for making 2,6-xylenol is described. One embodiment of the method comprises: preparing a magnesium-based solid catalyst composition by dry-blending basic magnesium carbonate with at least one filler; forming the catalyst composition into a suitable catalyst-shape; calcining the shaped catalyst at a temperature in the range of about 350° C. to about 550° C.; and reacting phenol and methanol in the presence of the catalyst, to form 2,6-xylenol. The level of chlorides in the magnesium carbonate is less than about 250 ppm, and the level of calcium in the magnesium carbonate is less than about 2,500 ppm.Type: GrantFiled: March 11, 2002Date of Patent: September 16, 2003Assignee: General Electric ComapanyInventors: Beth A. Watson, Narsi Devanathan
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Patent number: 6491845Abstract: Hardeners for epoxy resins are disclosed which have the capability of curing at lower temperatures than currently available hardeners while retaining superior mechanical and thermal properties. These novel hardeners include a range of reactivity which results in a range of pot lives from minutes to months. These materials co-cure readily with polyamines and have little or no amine odor. Mixture viscosity can be controlled over a wide range independent of filler concentration which allows a broad range of applications from coating and casting to adhesives. Class I hardeners contain a mixture of polyols, polyamines and tertiary amines and cure at temperatures between 20-50° C., while class II hardeners have the same polyols mixed with one or more tertiary amines and cure between 65-100° C. Class III hardeners contain the same polyols combined with either imadazole or dicyandiamide, and optionally, a tertiary amine and cure at 120° C.Type: GrantFiled: November 16, 2000Date of Patent: December 10, 2002Inventor: Richard D. Schile
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Patent number: 6395806Abstract: Hardeners for epoxy resins produced by reacting one or more &agr;,&bgr;-unsaturated carboxylic acid esters with one or more hydroxy compounds, reacting the thus formed intermediate with one or more aminopolyalkylene oxide compounds, reacting the thus formed intermediate with one or more polyepoxide compounds, and reacting the thus formed intermediate with one or more amines are described. Processes for their production, aqueous dispersions containing the same and methods for their use are also described.Type: GrantFiled: May 7, 2001Date of Patent: May 28, 2002Assignee: Cognis Deutschland GmbHInventors: Horst Sulzbach, Thomas Huver, Hans-Josef Thomas, Vincenzo Foglianisi
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Patent number: 6395871Abstract: A method for preparing a solid catalyst composition is described. A magnesium reagent which yields magnesium oxide upon calcination, and which includes reduced levels of chlorides and calcium, is dry-blended with at least one filler. Dry-blending is usually carried out in the absence of a promoter. A method for selectively alkylating at least one hydroxyaromatic compound by using the catalyst is also described. A typical product is 2,6-xylenol. Related processes for preparing polyphenylene ethers are described.Type: GrantFiled: October 18, 2000Date of Patent: May 28, 2002Assignee: General Electric CompanyInventors: Beth A. Watson, Narsi Devanathan
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Patent number: 6350843Abstract: Conductive thermosetting epoxy resins are produced by mixing a metallic salt or oxide with an inorganic acid to form a metallic ion solution. An alcohol is added to effect a secondary dehydration and form a complex ion polymer with double bonds and p electrons. The mixture is neutralized to produce a high molecular weight polymer of low electronic impedance. This polymer is then copolymerized with an epoxy resin.Type: GrantFiled: June 2, 1999Date of Patent: February 26, 2002Inventor: Hsu San Fa
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Patent number: 6294499Abstract: A method for preparing a solid catalyst composition is described. A magnesium reagent which yields magnesium oxide upon calcination, and which includes reduced levels of chlorides and calcium, is dry-blended with at least one filler. Dry-blending is usually carried out in the absence of a promoter. A method for selectively alkylating at least one hydroxyaromatic compound by using the catalyst is also described. A typical product is 2,6-xylenol. Related processes for preparing polyphenylene ethers are described.Type: GrantFiled: October 20, 2000Date of Patent: September 25, 2001Assignee: General Electric CompanyInventors: Beth A. Watson, Narsi Devanathan
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Patent number: 6261987Abstract: A method for preparing a solid catalyst composition is described. A magnesium reagent which yields magnesium oxide upon calcination, and which includes reduced levels of chlorides and calcium, is dry-blended with at least one filler. Dry-blending is usually carried out in the absence of a promoter. A method for selectively alkylating at least one hydroxyaromatic compound by using the catalyst is also described. A typical product is 2,6-xylenol. Related processes for preparing polyphenylene ethers are described.Type: GrantFiled: February 29, 2000Date of Patent: July 17, 2001Assignee: General Electric CompanyInventors: Beth A. Watson, Narsi Devanathan
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Patent number: 6218481Abstract: An acetylide-form propargyl-containing resin composition for cationic electrocoating, which comprises a resin having a skeleton of epoxy resin and has a number average molecular weight of 500 to 20,000, and which contains, per 100 grams of the resin composition solids, 5 to 400 millimoles of sulfonium group and 10 to 495 millimoles of propargyl group, the total content of the sulfonium and propargyl groups being not more than 500 millimoles per 100 grams of the resin composition solids, said propargyl group being partly in the form of an acetylide. This resin composition may further contain unsaturated double bonds.Type: GrantFiled: July 22, 1999Date of Patent: April 17, 2001Assignee: Nippon Paint Co., LTDInventors: Hiroyuki Sakamoto, Toshitaka Kawanami, Ichiro Kawakami, Takayuki Kokubun, Takao Saito, Saori Yoshimatsu
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Patent number: 6201070Abstract: Methods are disclosed for enhancing the toughness, e.g., resistance to cracking upon flexation, of coatings made from cycloaliphatic epoxide derivatives wherein the cycloaliphatic epoxide derivative is a cycloaliphatic epoxide ester of a hydroxy-functional compound containing at least one branched, 1,2-alkylene oxide unit. Processes for making the cycloaliphatic epoxide derivatives and coating formulations comprising the cycloaliphatic epoxide derivatives are also disclosed.Type: GrantFiled: November 20, 1996Date of Patent: March 13, 2001Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Naofumi Kumabe, Thomas Andrew Upshaw, Robert Francis Eaton, Bharat Kanaiyalal Patel, John Kellis Braddock
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Patent number: 6197916Abstract: A method for preparing bisphenol A is disclosed, with a selectivity for the p,p′-isomer of greater than about 97%. The method involves reacting phenol with p-isopropenylphenol or 2-(4-hydroxyphenyl)-2-propanol in the presence of a catalyst, at a reaction temperature of no greater than about 65° C. The bisphenol A product is preferably purified by a technique which omits the use of adduct crystallization.Type: GrantFiled: August 30, 1999Date of Patent: March 6, 2001Assignee: General Electric CompanyInventors: Eric James Pressman, Joseph Richard Wetzel
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Patent number: 6169159Abstract: A halogenated flame retardant for a thermoplastic resin with carbonyl linkages in the main chain such as polyethylene terephthalate or polybutylene terephthalate is obtained by the modification of a brominated bisphenol A epoxy resin optionally advanced with brominated bisphenol A by reaction of the epoxy groups with a C1-C8 alcohol such as methanol or butanol to the extent that the ratio of unmodified epoxy groups to alcohol-modified epoxy groups is from 2/1 to 1/2.Type: GrantFiled: February 20, 1998Date of Patent: January 2, 2001Assignee: Tohto Kasei Co., Ltd.Inventors: Toshihiko Kawamoto, Tetsunori Sato, Yoshiyuki Morikawa
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Patent number: 6169158Abstract: The present invention is directed to a polyglycidyl compound having on average more than two, preferably more than two and a half, particularly preferably more than three, glycidyl groups per molecule and a Tg value (determined by DSC, heating rate=20° C./min) higher than 20° C.Type: GrantFiled: April 23, 1999Date of Patent: January 2, 2001Assignee: Vantico, Inc.Inventors: Christoph Rickert, Hugh Stephen Laver
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Patent number: 6077929Abstract: The present invention pertains to coating compositions including a particular class of internally blocked polyamines as replacement for traditional blocked and unblocked polyamine crosslinkers. The use of these internally blocked polyamines results in better appearance characteristics and a lower VOC than are generally available with the traditional blocked varieties.Type: GrantFiled: April 7, 1998Date of Patent: June 20, 2000Assignee: Akzo Nobel N.V.Inventors: Johannes Adrianus Pardoen, Wincenty Lambertus Stanislaw Pilaszek, Jan Wilhelm Ernst Moos, Keimpe Jan Van Den Berg
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Patent number: 6001483Abstract: A composition useful as an encapsulating material for photosemiconductor elements such as a photodetector or light emmitor comprises an epoxy resin, a hardener and at least one compound represented by the following general formula (1) or (2):CH.sub.3 CH.sub.2 --(--CH.sub.2 --CH.sub.2 --).sub.x --CH.sub.2 --CH.sub.2 --O--(--CH.sub.2 --CH.sub.2 --O--).sub.n --Y.sub.1 (1)[CH.sub.3 CH.sub.2 --(--CH.sub.2 --CH.sub.2 --).sub.x --CH.sub.2 --CH.sub.2 --O--(--CH.sub.2 --CH.sub.2 --O--).sub.n --RCOO--].sub.m --Y.sub.2(2)wherein Y.sub.1 represents --H, --RCOOH, --COR' or --R'; R' is an alkyl group with not more than 30 carbon atoms; R is a divalent organic group; Y.sub.2 represents a metal atom having a valence of at least one; the mean value for x is from 8-200; and n is set such that the weight ratio of the repeating unit --CH.sub.2 --CH.sub.2 --O-- accounts for from 25-95% by weight based on the whole compound; and m is a positive integer corresponding to the valence of Y.sub.2.Type: GrantFiled: September 23, 1996Date of Patent: December 14, 1999Assignee: Nitto Denko CorporationInventors: Tadaaki Harada, Shinjirou Uenishi, Hirokatsu Kouyama, Takahiko Maruhashi, Katsumi Shimada, Satoshi Tanigawa
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Patent number: 5981687Abstract: Polymer compositions made by reacting a polyol with an aromatic hydrocarbon containing only a single reactive functionality have been discovered to be useful demulsifiers for crude oil compositions. The aromatic hydrocarbon should have at least one aryl group and only one functionality reactive with a hydroxyl. The polyol may optionally be crosslinked prior to reaction with the aromatic hydrocarbon, and the crosslinking agent may be a diepoxide.Type: GrantFiled: May 23, 1997Date of Patent: November 9, 1999Assignee: Baker Hughes IncorporatedInventors: Patrick J. Breen, James W. Towner
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Patent number: 5959061Abstract: Water-dispersible curing agents for epoxy resins are disclosed which, as a mixture with epoxy resins, have a potlife indication by showing the end of the processing time by a clear increase in viscosity, and which comprise reaction products (ABC) of adducts of aliphatic polyols (A) with a weight-average molar mass of from 200 to 20, 000 g/mol, comprising at least one polyol (A1) having a molar mass of less than 4000 g/mol, and at least one polyol (A2) having a molar mass of more than 4000 g/mol, and at least one epoxide compound (B) having at least two epoxide groups per molecule, and a specific epoxide group content of from 500 to 10 000 mmol/kg, (A1) and (A2) being reacted separately or as a mixture with (B), and then reacting this adduct with one or more polyamines (C) having at least three amine hydrogen atoms and at least one primary amino group per molecule, the ratio of the number of hydroxyl groups of component (A) to the number of epoxide groups of component (B) being 1:3 to 1:10, and the ratio of thType: GrantFiled: July 25, 1997Date of Patent: September 28, 1999Assignee: Vianova Resins GmbHInventors: Uwe Neumann, Martin Gerlitz
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Patent number: 5940570Abstract: A method for encapsulating segments of signal transmission devices such as splices, pressure blocks and end blocks with a room-temperature curable composition comprising:(1) a hydroxy-functional compound having a molecular weight of greater than 500 and a hydroxy functionality of 2 or more;(2) an epoxy-functional compound having an epoxy functionality of 2 or more; and(3) a curative catalyst, in an amount effective to crosslink the epoxy and hydroxy components of the respective epoxy-functional and hydroxy-functional compounds.Type: GrantFiled: August 8, 1997Date of Patent: August 17, 1999Assignee: Uniroyal Chemical Company, Inc.Inventors: William Davis Sigworth, Thomas Harald Peter
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Patent number: 5936057Abstract: Modified epoxy resins are obtained by reaction of an epoxy resin with up to one mol equivalent per epoxy group of an alkyl or alkenyl substituted, hydroxy substituted aromatic acid, especially by reaction of a bisphenol A based epoxy resin with an alkylated salicylic acid. Also are described a process for the production of such modified resins, curable compositions comprising the modified epoxy resin and products provided with the cured composition, especially in coating applications and civil engineering applications.Type: GrantFiled: January 7, 1998Date of Patent: August 10, 1999Assignee: Shell Oil CompanyInventors: Francoise Jacqueline Aline Baudoul, Seetha Maha Lakshmi Coleman-Kammula
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Patent number: 5925725Abstract: An emulsifier composition for water-dilutable epoxy resins comprise condensation products of an aliphatic polyol component having a weight-average molar mass (M.sub.w) of from 200 to 20,000 g/mol, where a mass fraction of at least 5%, has a weight-average molar mass (M.sub.w) of at least 4000 g/mol, and an epoxide component having of at least one epoxide compound having at least two epoxide groups per molecule and an epoxide group content of from 500 to 10,000 mmol/kg, the ratio of the number of hydroxyl groups to that of the epoxide groups (OH):(EP) being from 1:3.51 to 1:10. When the emulsifier is used for the preparation of aqueous epoxy resin systems, the end of the pot life is indicated by a sharp rise in viscosity.Type: GrantFiled: September 26, 1996Date of Patent: July 20, 1999Assignee: Vianova Resins GmbHInventors: Armin Pfeil, Dieter Dreischhoff, Stefan Petri, Claus Godau
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Patent number: 5904888Abstract: A two-component system for producing two or more different curable mixtures in which the first component A is common to each mixture and comprises:1. a liquid epoxy2. an acid anhydride hardener and3. at least one fillerand the second component B is selected from two or more different components B, each of which comprises:1. an accelerator, and optionally2. a colourant, and optionally3. a non-volatile solvent/extender for the accelerator4. a flexibiliser for the epoxy-anhydride cure5. a acid anhydride hardener.Type: GrantFiled: December 18, 1997Date of Patent: May 18, 1999Assignee: Ciba Specialty Chemicals CorporationInventors: Barry James Hayes, Paul Terrence Wombwell, Philip David Willis
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Patent number: 5905103Abstract: The invention relates to a process for the preparation of pigment paste resins for cathodically depositable coating compositions, wherein diepoxide compounds which contain polyoxyalkylene structures and alkyl and/or alkylene and/or hydroxyalkyl radicals having more than 3 carbon atoms are first reacted to form epoxy resin/amine adducts and final products with oxazolidine structures are obtained by a partial or complete reaction of secondary amino groups with formaldehyde.Type: GrantFiled: March 15, 1993Date of Patent: May 18, 1999Assignee: Vianova Resins, AGInventors: Helmut Honig, Georg Pampouchidis, Willibald Paar, Herbert Matzer, Manfred Valtrovic
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Patent number: 5859164Abstract: Uretdione-functional polyaddition compounds of the formula: ##STR1## where: ##STR2## R.sup.1 is R or linear, branched or cyclic alkylene radicals of 2-16 carbon atoms,R.sup.2 and R.sup.3 are identical or different hydrocarbon radicals of 1-14 carbon atoms,R.sup.4 is R.sup.Type: GrantFiled: September 15, 1997Date of Patent: January 12, 1999Assignee: Huels AktiengesellschaftInventors: Rainer Gras, Joern Volker Weiss, Elmar Wolf, Felix Schmitt