Material Is A Metal-containing Material Patents (Class 528/14)
  • Patent number: 10287454
    Abstract: The present invention relates to coating compositions comprising A) alkoxy-functional arylpolysiloxanes and/or alkoxy-functional aryl-alkylpolysiloxanes, B) at least one crosslinking catalyst and optionally C) at least one alkoxysilane and D) optionally further auxiliaries and additives, where the fraction of the alkoxy groups is at least 10 wt %, based on the sum of components A) and C).
    Type: Grant
    Filed: July 30, 2014
    Date of Patent: May 14, 2019
    Assignee: Evonik Degussa GmbH
    Inventors: Thomas Klotzbach, Michael Fiedel, Michael Ferenz
  • Patent number: 10093750
    Abstract: The invention relates to a modified diene elastomer comprising predominantly the entity functionalized in the middle of the chain by an alkoxysilane group, optionally partially or completely hydrolyzed to give silanol, bearing a tertiary amine functional group and the silicon atom of which bonds the two pieces of the chain, the chain ends of the modified diene elastomer being functionalized to at least 70 mol %, with respect to the number of moles of chain end, by an amine functional group.
    Type: Grant
    Filed: August 4, 2014
    Date of Patent: October 9, 2018
    Assignees: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE S.A.
    Inventors: Charlotte Dire, Jean Marc Marechal, Nicolas Seeboth
  • Patent number: 10000664
    Abstract: An underlayer film-forming composition used for an underlayer for a self-assembled film, including a polysiloxane and a solvent. The polysiloxane may be a hydrolysis-condensation product of a silane containing a phenyl group-containing silane, or a hydrolysis-condensation product of a silane containing a silane of Formula (1) in a ratio of 10 to 100% by mol relative to the total silane, or a hydrolysis-condensation product of silanes containing the silane of Formula (1), silane of Formula (2) [R4Si(R3)3 (2)], and silane of Formula (3) [Si(R5)4 (3)] in a ratio of silane of Formula (1): silane of Formula (2): silane of Formula (3) of 10 to 100:0 to 90:0 to 50 in terms of % by mol relative to the total silane.
    Type: Grant
    Filed: March 22, 2013
    Date of Patent: June 19, 2018
    Assignee: NISSAN CHEMICAL INDUSTRIES, LTD.
    Inventors: Hiroyuki Wakayama, Makoto Nakajima, Rikimaru Sakamoto
  • Patent number: 9724451
    Abstract: The present invention provides a silicone rubber-based curable composition with which a silicone rubber having excellent tensile strength and tear strength is obtained, a method for producing a silicone rubber using the silicone rubber-based curable composition, a silicone rubber, a molded article using the silicone rubber, and a tube for medical use formed from the molded article. The silicone rubber-based curable composition of the present invention is characterized in that it includes a vinyl group-containing organopolysiloxane (A), an organohydrogen polysiloxane (B), silica particles (C), a silane coupling agent (D), and platinum or a platinum compound (E).
    Type: Grant
    Filed: March 29, 2012
    Date of Patent: August 8, 2017
    Assignee: SUMITOMO BAKELITE CO., LTD.
    Inventors: Kazunobu Senoo, Jun Okada, Motoyoshi Tsujimoto
  • Patent number: 9701783
    Abstract: Described herein is a polydiorganosiloxane polyurethane, linear, block copolymer and methods of making thereof. The copolymers comprise soft segments that are polydioranosiloxane units and hard segments which are polyurethane residues.
    Type: Grant
    Filed: October 25, 2013
    Date of Patent: July 11, 2017
    Assignee: 3M Innovative Properties Company
    Inventors: Yu Yang, Suresh S. Iyer, Yongshang Lu
  • Patent number: 9644124
    Abstract: A silicon-containing compound having an alkoxysilyl-ethylene group at its terminal including at least one silyl-ethylene bond represented by the following structural formula (a) in one molecule, and according to this compound, a novel base polymer used in a room temperature-curable polyorganosiloxane composition capable of providing a cured product that is particularly excellent in rapid curability, storage stability and durability can be provided.
    Type: Grant
    Filed: December 10, 2013
    Date of Patent: May 9, 2017
    Assignee: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Takafumi Sakamoto, Takahiro Yamaguchi
  • Patent number: 9550866
    Abstract: An aryl group-containing siloxane composition is formed by introducing an alkaline earth-metal as a part of the reaction product of an organopolysiloxane having at least two alkenyl groups per molecule and an organopolysiloxane having at least two silicon-bonded hydrogen atoms per molecule in the presence of a hydrosilylation catalyst, wherein at least one of the organopolysiloxanes includes an aryl group. The alkaline earth metal may be introduced via a heat stability composition or may alternatively be pre-reacted with the organopolysiloxane having at least two alkenyl groups per molecule. The aryl group-containing siloxane compositions may be utilized as an encapsulating layer for a light emitting device.
    Type: Grant
    Filed: March 14, 2014
    Date of Patent: January 24, 2017
    Assignee: DOW CORNING CORPORATION
    Inventors: Randall Schmidt, Kasumi Takeuchi, Shengqing Xu
  • Patent number: 9512271
    Abstract: The present invention relates to silicone copolymers of the formula (I) which are obtained by reaction of siloxanes having SiH groups with specific compounds having one or more groups reactive toward SiH groups, especially groups having C—C multiple bonds, and optionally at least one OH group, compositions comprising these silicone copolymers, a process for producing a polyurethane foam in which an appropriate silicone copolymer or a corresponding composition is used, polyurethane foam obtainable by the process, and articles comprising or consisting of a corresponding polyurethane foam.
    Type: Grant
    Filed: February 6, 2013
    Date of Patent: December 6, 2016
    Assignee: EVONIK DEGUSSA GMBH
    Inventors: Roland Hubel, Annegret Terheiden
  • Patent number: 9447125
    Abstract: Disclosed herein are cobalt complexes containing terdentate pyridine di-imine ligands and their use as efficient, reusable, and selective dehydrogenative silylation, crosslinking, and tandem dehydrogenative silylation-hydrogenation catalysts.
    Type: Grant
    Filed: May 6, 2014
    Date of Patent: September 20, 2016
    Assignee: Momentive Performance Materials Inc.
    Inventors: Aroop Kumar Roy, Crisita Carmen Hojilla Atienza, Paul J. Chirik, Kenrick M. Lewis, Keith J. Weller, Susan Nye, Johannes G. P. Delis, Julie L. Boyer, Tianning Diao, Eric Pohl
  • Patent number: 9394325
    Abstract: A transition metal-containing compound having a tridentate chiral ligand bound to iron, cobalt, or nickel. The tridentate ligands are bound to the metal via nitrogen, phosphorus, and/or arsenic atoms. The tridentate ligand has a chiral group bound at least one of the nitrogen, phosphorus, and arsenic atoms, and a blocking group may be bound to another one of the nitrogen, phosphorus, and arsenic atoms. The transition metal-containing compound is useful for the catalyzing the asymmetric hydrogenation of olefins.
    Type: Grant
    Filed: August 20, 2012
    Date of Patent: July 19, 2016
    Assignee: The Trustees of Princeton University
    Inventors: Paul J. Chirik, Sebastien Monfette, Jordan M. Hoyt, Max R. Friedfeld
  • Patent number: 9371339
    Abstract: The present invention relates to processes for the synthesis of saturated and unsaturated silahydrocarbons using iron-containing or cobalt-containing catalysts. The processes of the invention can produce tetraalkylsilanes, phenyltrialkylsilanes, substituted phenyltrialkylsilanes and their mixtures, which are useful as lubricants and hydraulic fluids, as well as alkyl alkenylsilanes, phenyl alkenylsilanes and substituted phenyl alkenylsilanes and their mixtures, which are useful in the synthesis of saturated silahydrocarbons and other organofunctional silanes.
    Type: Grant
    Filed: April 2, 2014
    Date of Patent: June 21, 2016
    Assignees: Momentive Performance Materials Inc., Princeton University
    Inventors: Kenrick Martin Lewis, Crisita Carmen Hojilla Atienza, Julie L. Boyer, Paul J. Chirik, Johannes G. P. Delis, Aroop Kumar Roy
  • Patent number: 9249313
    Abstract: A functional fluorinated polyhedral oligomeric silsesquioxane (“F-POSS”). The F-POSS, has a chemical structure: where Rf represents a nonreactive organic group and at least one of R1 and R2 represents a chain comprising at least three carbon atoms.
    Type: Grant
    Filed: September 21, 2012
    Date of Patent: February 2, 2016
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Timothy S. Haddad, Joseph M. Mabry, Sean Ramirez
  • Patent number: 9188703
    Abstract: Curable composition providing, upon curing, an abrasion resistant, transparent, antistatic coating comprising: a) at least one conductive polymer, b) colloidal particles of at least one non-conductive oxide, c) at least one binder comprising at least one epoxysilane having at least two hydrolysable groups directly linked to the Si atom of the epoxysilane, and/or its hydrolysis product, said at least one conductive polymer and said colloidal particles of at least one non-conductive oxide being substantially not agglomerated, the content of said conductive polymer in the dry extract of said curable composition ranging from 0.1 to 10% by weight, preferably from 0.2 to 10% by weight and the content of the dry extract of said at least one epoxysilane in the dry extract of said curable composition ranging from 20 to 80% preferably 25 to 60% by weight based on the total weight of the dry extract.
    Type: Grant
    Filed: December 19, 2012
    Date of Patent: November 17, 2015
    Assignee: Essilor International (Compagnie Générale d'Optique)
    Inventor: Haipeng Zheng
  • Patent number: 9181398
    Abstract: The present invention relates to a drainage aid composition and its use in pulp washing process. More particulary, this invention relates to drainage aid composition of silicone polyethers prepared via zinc catalized dehydrogenative coupling of alcohol terminated polyethers with silicone oligomers and polymers comprising of at least one silicon bonded hydrogen. The compostion of this invention exhibit excellent drainage properties.
    Type: Grant
    Filed: April 25, 2012
    Date of Patent: November 10, 2015
    Assignee: Solenis Technologies, L.P.
    Inventors: Zoha Al-badri, Todd S. Bolton
  • Patent number: 9117985
    Abstract: One purpose is to provide a silicone resin composition which provides a cured product having a large Abbe's number and a high brightness. A silicone resin composition including (A-1) an organopolysiloxane having a three-dimensional crosslinked structure, at least two alkenyl groups, and at least one monovalent aromatic hydrocarbon group bonded to a silicon atom, (A-2) a linear organopolysiloxane having alkenyl groups at at least both terminals of a molecular chain and at least one monovalent aromatic hydrocarbon group bonded to a silicon atom, (B-1) a linear organohydrogen polysiloxane having at least one silphenylene skeleton in a molecular chain and hydrosilyl groups at least both terminals of the molecular chain, in an amount such that a ratio of the number of the hydrosilyl groups in component (B-1) to a total number of the alkenyl groups in components (A-1) and (A-2) is 0.5 to 2, and (C) a hydrosilylation catalyst in a catalytic amount.
    Type: Grant
    Filed: November 18, 2014
    Date of Patent: August 25, 2015
    Assignee: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Yoshihira Hamamoto, Tsutomu Kashiwagi
  • Patent number: 9091920
    Abstract: [Object] To provide a photosensitive siloxane resin composition excellent in alkali-solubility and in sensitivity, and also to provide a pattern-formation method employing that. [Means] The present invention provides a photosensitive siloxane resin composition comprising: a siloxane resin having silanol groups or alkoxysilyl groups, a crown ether, a photosensitive material, and an organic solvent. This photosensitive composition is cast on a substrate, subjected to imagewise exposure, treated with an alkali aqueous solution, and cured to form a pattern.
    Type: Grant
    Filed: May 17, 2012
    Date of Patent: July 28, 2015
    Assignee: Merck Patent GmbH
    Inventors: Takashi Sekito, Daishi Yokoyama, Takashi Fuke, Yuki Tashiro, Toshiaki Nonaka, Yasuaki Tanaka
  • Patent number: 9063475
    Abstract: To provide an intermediate transfer belt for use in an electrophotographic apparatus, including as an outermost surface thereof: uniform convex regions formed by aligning independent spherical resin particles in a surface direction; and depressed regions formed of a lubricant layer which respectively lie between the convex regions.
    Type: Grant
    Filed: May 17, 2011
    Date of Patent: June 23, 2015
    Assignee: RICOH COMPANY, LTD.
    Inventors: Jun Aoto, Hidetaka Kubo, Kenichi Mashiko, Sayaka Katoh, Shinichi Nitta
  • Patent number: 9012585
    Abstract: A composition is capable of curing via condensation reaction. The composition uses a new condensation reaction catalyst. The new condensation reaction catalyst is used to replace conventional tin catalysts. The composition can react to form a gum, gel, rubber, or resin.
    Type: Grant
    Filed: July 19, 2012
    Date of Patent: April 21, 2015
    Assignee: Dow Corning Corporation
    Inventors: Kurt Brandstadt, Simon Cook, Gary Diamond, Keith Hall, Loren Lower, Avril Surgenor, Richard Taylor, James Tonge, Ming-Shin Tzou
  • Patent number: 8937141
    Abstract: The present invention provides curable compositions comprising non-Sn organo-metal catalysts that accelerate the condensation curing of moisture curable silicones/non-silicones. In particular, the present invention provides Mn(III) complexes that are particularly suitable as replacements for organotin for sealant and RTV formulations. The Mn(III) complexes are comparable or superior to organotin such as DBTDL, superior to Mn(II) compounds, and exhibit certain behavior in the presence of components that allow for tuning or adjusting the cure characteristics of the present compositions and provide good adhesion and storage stability.
    Type: Grant
    Filed: September 8, 2011
    Date of Patent: January 20, 2015
    Assignee: Momentive Performance Materials Inc.
    Inventors: Sumi, Edward J. Nesakumar, Anantharaman Dhanabalan, Shahid Murtuza, Shayne J. Landon
  • Patent number: 8927673
    Abstract: Disclosed are a method for polymerizing polysilsesquioxane from a trialkoxysiloxane monomer, including: preparing an aqueous organic solution including a trialkoxysiloxane monomer, an organic solvent, water and a catalyst; and selectively preparing a polysilsesquioxane with a cage structure or a polysilsesquioxane with a ladder structure by adjusting the amount of the organic solvent or water in the aqueous organic solution, and a polysilsesquioxane with a cage structure or a polysilsesquioxane with a ladder structure prepared therefrom.
    Type: Grant
    Filed: September 14, 2010
    Date of Patent: January 6, 2015
    Assignee: Korea Institute of Science and Technology
    Inventors: Seung Sang Hwang, Soon Man Hong, Soon Jong Kwak, Kyung Youl Baek, Chong Min Koo, Seung Sock Choi, Albert S. Lee
  • Patent number: 8925626
    Abstract: A substrate is surface treated using a composition for forming a film that comprises (A) an organoalkoxysilane, (B) an organopolysiloxane having a silicon-bonded hydrogen atom, and (C) a condensation reaction catalyst. This composition for forming a film can form a highly hydrophobic water repellent film provided with sufficient water shedding performance. It is possible to provide a highly hydrophobic substrate such as a heat dissipating body.
    Type: Grant
    Filed: April 4, 2012
    Date of Patent: January 6, 2015
    Assignee: Dow Corning Toray Co., Ltd.
    Inventors: Keiichi Akinaga, Tadashi Okawa, Kazuhiro Nishijima, Eiji Kitaura
  • Patent number: 8927674
    Abstract: Disclosed herein are cobalt complexes containing terdentate pyridine di-imine ligands and their use as efficient and selective dehydrogenative silylation and crosslinking catalysts.
    Type: Grant
    Filed: August 14, 2013
    Date of Patent: January 6, 2015
    Assignees: Princeton University, Momentive Performance Materials Inc.
    Inventors: Cristia Carmen Hojilla Atienza, Paul J. Chirik, Susan Nye, Kenrick M. Lewis, Keith J. Weller, Julie L. Boyer, Johannes G. P. Delis, Aroop Roy, Eric Pohl
  • Patent number: 8921505
    Abstract: The present invention relates to a method for preparing poly(organic oxidized silicon) particles having UV-absorbing groups, including reacting an organoalkoxysilane precursor having a UV-absorbing group selected from a group consisting of organotrialkoxysilane, diorganoalkoxysilane and a mixture thereof, in the presence of a base, with a silane compound selected from a group consisting of tetraalkoxysilane, alkyltrialkoxysilane, tetraalkoxysilane, aryltrialkoxysilane, dialkyldialkoxysilane, diaryldialkoxysilane, arylalkyldialkoxysilane and a mixture thereof, serving as a crosslinking regulator and UV stability enhancer, so as to prepare poly(organic oxidized silicon) particles selected from a group consisting of polysilsesquioxane, silsesquioxane-siloxane copolymer, silsesquioxane-silica copolymer, silsesquioxane-siloxane-silica copolymer and silsesquioxane-siloxane copolymer, having UV-absorbing groups.
    Type: Grant
    Filed: July 15, 2011
    Date of Patent: December 30, 2014
    Assignee: Nano and Micro Technologies Co., Ltd.
    Inventors: Young Baek Kim, Goo Jin Jeong, In Whan Kim
  • Patent number: 8921437
    Abstract: Prepolymers having more than one alkoxysilyl function per chain end reactive towards epoxide groups as a constituent of curable compositions, and their use for producing adhesive-bonding and coating compositions, which may also be foamable, and also polymeric materials produced therefrom.
    Type: Grant
    Filed: September 17, 2009
    Date of Patent: December 30, 2014
    Assignee: Evonik Goldschmidt GmbH
    Inventors: Wilfried Knott, Frank Schubert, Martin Glos, Carsten Schiller, Matthias Naumann
  • Patent number: 8900654
    Abstract: Compositions and methods for controlled polymerization and/or oligomerization of silane (and optionally cyclosilane) compounds, including those of the general formulae SinH2n and SinH2n+2, as well as halosilanes and arylsilanes, to produce soluble polysilanes, polygermanes and/or polysilagermanes having low levels of carbon and metal contaminants, high molecular weights, low volatility, high purity, high solubility and/or high viscosity. The polysilanes, polygermanes and/or polysilagermanes are useful as a precursor to silicon- and/or germanium-containing conductor, semiconductor and dielectric films.
    Type: Grant
    Filed: July 29, 2011
    Date of Patent: December 2, 2014
    Assignee: Thin Film Electronics, Inc.
    Inventors: Klaus Kunze, Gregory Nyce, Wenzhuo Guo
  • Patent number: 8889342
    Abstract: This disclosure relates to a polymer having the formula: wherein x is between 1 and about 100 an y is between about 99 and about 1, and x+Y=about 100. The disclosure also includes the use of the polymer in photovoltaic devices.
    Type: Grant
    Filed: February 6, 2014
    Date of Patent: November 18, 2014
    Assignee: Brookhaven Science Associates, LLC
    Inventors: Yang Qin, Robert B. Grubbs, Young Suk Park
  • Patent number: 8865850
    Abstract: A reaction product is formed utilizing a method that includes the step of combining a metal silicide and an aliphatic hydrocarbyl halide at a temperature of from 200° C. to 600° C. The aliphatic hydrocarbyl halide has the formula HaCbXc, wherein a is 0 or more, b is 1 or more, c is one or more, and X is halo. The method allows the reaction product to be formed in a predictable and controlled manner. Moreover, the components used in this method can be easily recycled and/or re-used in other processes.
    Type: Grant
    Filed: November 29, 2012
    Date of Patent: October 21, 2014
    Assignee: Dow Corning Corporation
    Inventors: Dimitris Katsoulis, Robert Morgan, Wendy Sparschu
  • Patent number: 8859709
    Abstract: A mixture of at least two polyhedral oligomeric silsesquioxane (POSS) compounds is formed in the presence of rhenium on cerium(IV) oxide. The POSS compounds are formed utilizing a method that includes the step of combining (a) a trihalosilane, (b) hydrogen gas, and (c) the rhenium on cerium(IV) oxide, in a reactor at a temperature of from 250° C. to 600° C. to form the mixture. The trihalosilane has the formula RSiX3 wherein R is an alkyl group having from 1 to 4 carbon atoms, an aryl group, and wherein X is a halo atom. This method allows for the efficient, predictable, and accurate production of the POSS compounds with a minimized need for use of expensive separation techniques. In addition, this method produces the POSS compounds in commercially useful quantities as major reaction products thereby avoiding the need to run multiple reactions.
    Type: Grant
    Filed: December 22, 2011
    Date of Patent: October 14, 2014
    Assignee: Dow Corning Corporation
    Inventors: Dimitris Katsoulis, Robert Thomas Larsen
  • Patent number: 8852844
    Abstract: There is disclosed a thermosetting composition for forming a silicon-containing film to form a silicon-containing film formed in a multilayer resist process used in lithography, including at least (A) a silicon-containing compound obtained by hydrolyzing and condensing a hydrolyzable silicon compound using an acid as a catalyst, (B) a thermal crosslinking accelerator (C) a monovalent or bivalent or more organic acid having 1 to 30 carbon atoms, (D) trivalent or more alcohol and (E) an organic solvent. There can be provided a composition for a silicon-containing film which can form a good pattern in a photoresist film, can form a silicon-containing film for an etching mask having a good dry etching resistance, can give a good storage stability and can be delaminated with a solution used in a delamination process in a multilayer resist process used for lithography, a substrate on which the silicon-containing film is formed, and further a method for forming a pattern.
    Type: Grant
    Filed: August 10, 2009
    Date of Patent: October 7, 2014
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Tsutomu Ogihara, Takafumi Ueda, Toshiharu Yano
  • Publication number: 20140296459
    Abstract: Disclosed is a method for producing a conjugated diene-based polymer capable of affording a polymer composition useful as a material for tires excellent in fuel economy. Specifically, there is disclosed a method comprising polymerizing monomer components comprising a conjugated diene compound and an aromatic vinyl compound using an alkali metal-based polymerization initiator in the presence of a hydrocarbon solvent and an ether compound represented by the following formula (1), wherein R represents an alkyl group having 1 to 8 carbon atoms.
    Type: Application
    Filed: March 26, 2014
    Publication date: October 2, 2014
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventor: Koichiro TAJIMA
  • Patent number: 8835590
    Abstract: The present invention relates to an organopolysiloxane composition that can be vulcanized at room temperature into an elastomer that is crosslinked by polycondensation and that does not contain alkyltin-based catalysts and also to novel organopolysiloxane polycondensation catalysts.
    Type: Grant
    Filed: December 18, 2008
    Date of Patent: September 16, 2014
    Assignee: Bluestar Silicones France SAS
    Inventors: Christian Maliverney, Laurent Saint-Jalmes
  • Patent number: 8829139
    Abstract: A method for easily producing high-purity polydimethylsilane or polydiphenylsilane, where by-products such as alkali metal salt and alkaline earth metal salt can be efficiently removed, is provided. Dimethyldichlorosilane or diphenyldichlorosilane is reacted with an alkali metal such as metal sodium and metal magnesium and/or an alkaline earth metal in an organic solvent such as toluene to obtain crude polydimethylsilane or crude polydiphenylsilane, methanol having dissolved therein an ether ester-type nonionic surfactant or a surfactant such as alkylbenzenesulfonate is added to the crude polydimethylsilane or the crude polydiphenylsilane to deactivate the remaining alkali metal and alkaline earth metal, and the crude polydimethylsilane or the crude polydiphenylsilane is washed with water in the presence of a surfactant to efficiently remove an alkali metal salt, an alkaline earth metal salt and the like, whereby high-purity polydimethylsilane or polydiphenylsilane is obtained.
    Type: Grant
    Filed: May 15, 2009
    Date of Patent: September 9, 2014
    Assignee: Nippon Soda Co., Ltd.
    Inventors: Kimihiko Oohata, Satoru Yamazaki, Masamichi Yasuhara, Jyunichi Kawachi
  • Patent number: 8772428
    Abstract: RTV-organopolysiloxane compositions are crosslinkable by polycondensation and are devoid of alkyltin-based catalysts; novel organopolysiloxane polycondensation catalysts are useful therefor.
    Type: Grant
    Filed: December 18, 2008
    Date of Patent: July 8, 2014
    Assignee: Bluestar Silicones France SAS
    Inventors: Christian Maliverney, Delphine Blanc, Rachid Ferhat
  • Publication number: 20140187733
    Abstract: An organopolysiloxane which forms a cured product having a high refractive index, high transparency, and excellent heat resistance when subjected to a hydrosilylation reaction and which is represented by the following average unit formula: (R13SiO1/2)a(R12SiO2/2)b(R2SiO3/2)c(SiO4/2)d wherein, R1 are alkyl groups, alkenyl groups, phenyl groups, or hydrogen atoms; R2 is a group represented by R1 or a condensed polycyclic aromatic group or a group containing a condensed polycyclic aromatic group, but at least one of R1 or R2 in a molecule is an alkenyl group or a hydrogen atom, at least one R2 in a molecule is a condensed polycyclic aromatic group or a group containing a condensed polycyclic aromatic group; and a, b, c and d are numbers that satisfy: 0.01?a?0.8, 0?b?0.5, 0.2?c?0.9, 0?d<0.2 and a+b+c+d=1.
    Type: Application
    Filed: July 4, 2012
    Publication date: July 3, 2014
    Applicant: Dow Corning Toray Co., Ltd.
    Inventors: Tadashi Okawa, Kazuhiro Nishijima, Masaaki Amako, Maki Itoh, Yoshitsugu Mortia
  • Patent number: 8748552
    Abstract: The present invention relates to polyalkylsilsesquioxane particulates and a method of preparing the same, and more particularly provides the polyalkylsilsesquioxane particulates, of which moisture content is low, water repellency is high, and hygroscopic property in storage is low, and a method of preparing the same by end-capping silanol groups (SiOH) on the surface of the polyalkylsilsesquioxane particulates with alkyl groups by adding an alkoxytrialkylsilane having a triorganosilyl group thereto.
    Type: Grant
    Filed: May 20, 2008
    Date of Patent: June 10, 2014
    Assignee: Kolon Industries, Inc.
    Inventors: Jong-Han Kim, Seol-A Yu, Young-Seo Yoon
  • Patent number: 8729207
    Abstract: The invention relates to new types of polyester-polysiloxane block copolymers, to processes for their preparation and to their use.
    Type: Grant
    Filed: July 7, 2011
    Date of Patent: May 20, 2014
    Assignee: Evonik Degussa GmbH
    Inventors: Christian Hartung, Michael Ferenz, Wilfried Knott, Helmut Ritter, Michael Fiedel
  • Publication number: 20140107309
    Abstract: One object of the present invention is to provide a method for preparing a polyorganosiloxane without using any catalyst having corrosivity and toxicity such as an alkaline earth metal catalyst in a condensation reaction of at least one organic silicon compound having a silanol group and/or an alkoxy silyl group. The present invention is a method for preparing a polyorganosiloxane, wherein the method includes a step of condensation reacting at least one organic silicon compound having at least one —OX group bonding to a silicon atom in the molecule, wherein X is a hydrogen atom, an alkyl group having 1 to 10 carbon atoms or an alkoxyalkyl group having 2 to 10 carbon atoms, in the presence of a catalyst, wherein the catalyst is at least one selected from the group having hydroxides or oxides of elements in Groups 3-15 of the periodic table.
    Type: Application
    Filed: October 3, 2013
    Publication date: April 17, 2014
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Takayuki KUSUNOKI, Yuusuke TAKAMIZAWA, Tsutomu KASHIWAGI
  • Patent number: 8679730
    Abstract: The invention relates azide functionalized poly(3-hexylthiophene)s. Various azide functionalized poly(3-hexylthiophene)s and intermediates are disclosed and described, as well as method for making novel monomers that are synthesized and transformed into P3HT-Nmp for use as organic conducting polymers in organic photovoltaic devices.
    Type: Grant
    Filed: July 29, 2011
    Date of Patent: March 25, 2014
    Assignee: Brookhaven Science Associates, LLC
    Inventors: Yang Qin, Robert B. Grubbs, Young Suk Park
  • Patent number: 8680216
    Abstract: Hardener composition for condensation-crosslinking RTV-2 silicone compositions contain: (A) at least one crosslinker, (B) at least one catalyst, (C) at least one extender polymer, wherein the sum of the molar proportions of T and Q units in the extender polymer (C) is at least 25%.
    Type: Grant
    Filed: July 1, 2011
    Date of Patent: March 25, 2014
    Assignee: Wacker Chemie AG
    Inventor: Torsten Sixt
  • Patent number: 8637626
    Abstract: Disclosed herein are manganese, iron, cobalt, or nickel complexes containing 2,8-bis(imino)quinoline ligands and their use as catalysts or catalysts precursors for hydrosilylation reactions.
    Type: Grant
    Filed: November 22, 2011
    Date of Patent: January 28, 2014
    Assignee: Momentive Performance Materials Inc.
    Inventors: Aaron M. Tondreau, Paul J. Chirik, Johannes G. P. Delis, Keith J. Weller, Kenrick M. Lewis, Susan A. Nye
  • Patent number: 8623985
    Abstract: A silicone composition is described that includes components having SiH/SiOH groupings and that can be polymerized/cross-linked by a dehydrogenative condensation reaction in the presence of a zinc catalyst and requiring a low activation temperature.
    Type: Grant
    Filed: June 15, 2010
    Date of Patent: January 7, 2014
    Assignee: Bluestar Silicones France SAS
    Inventor: Christian Maliverney
  • Patent number: 8618245
    Abstract: The present invention relates to an obtainment process of biodegradable polymers from a citric residue resulting from the processing of orange juice. The polymers obtained are polyesters classified as polyhydroxyalkanoates including, among them the poly(3-hydroxybutyrate) and poly(3-hydroxybutyrate-co-3-hydroxyvalerate). The biodegradable polymer is obtained from the batch culture process or fed batch culture process with or without recirculation of the cells, using as a carbon source the pre-treated pressing liquor and/or the citric molasses. The polyhydroxyalkanoates, herein described, can be used as substitutes of the synthetic polyesters in different areas, including the food, pharmaceutical, medical, agricultural and other areas.
    Type: Grant
    Filed: November 18, 2008
    Date of Patent: December 31, 2013
    Assignees: Citrosuco S/A Agroindustria, Universidade Federal de Santa Catarina
    Inventors: Glaucia Maria Falcão de Aragão, Willibaldo Schimidell Netto, Jaciane Lutz Ienczak, Mônica Lady Fiorese, Francieli Dalcaton, Franciny Schmidt, Ricardo Deucher, Cinthia Vecchi, Rafael Costa Rodrigues
  • Patent number: 8603588
    Abstract: Disclosed is a composition comprising a hydrolysate of an alkoxysilane compound, a hydrolysate of a siloxane compound represented by Formula (1), a surfactant, and an element having an electronegativity of 2.5 or less. In Formula (1), RA and RB independently represent a hydrogen atom, a phenyl group, —CaH2a+1, —(CH2)b(CF2)cCF3 or —CdH2d?1, RA and RB are not both hydrogen atoms simultaneously, RC and RD independently represent a single bond that links a silicon atom and an oxygen atom to form a cyclic siloxane structure, or each independently represent a hydrogen atom, a phenyl group, —CaH2a+1, —(CH2)b(CF2)cCF3, or —CdH2d?1, a represents an integer of 1 to 6, b represents an integer of 0 to 4, c represents an integer of 0 to 10, d represents an integer of 2 to 4, and n represents an integer of 3 or greater.
    Type: Grant
    Filed: March 30, 2009
    Date of Patent: December 10, 2013
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Kazuo Kohmura, Hirofumi Tanaka
  • Patent number: 8598294
    Abstract: Hardener composition for condensation-crosslinking RTV-2 silicone compositions contain (A) at least one crosslinker, (B) at least one crosslinking catalyst which is an alkali metal or alkaline earth metal compound which is not a hydroxide, and (D) at least one functional silane as a coupling agent.
    Type: Grant
    Filed: October 17, 2011
    Date of Patent: December 3, 2013
    Assignee: Wacker Chemie AG
    Inventors: Torsten Sixt, Franz Neuhauser
  • Patent number: 8592545
    Abstract: A polyorganosiloxane polyoxyalkylene block copolymer having one or more polyorganosiloxane blocks and one or more polyoxyalkylene blocks linked to each other via divalent radicals which comprises at least two silicon-bonded alkoxy groups, preferably of the form PS (A PO)m (A PS)n, wherein PO is a polyoxyalkylene block, PS represents a polyorganosiloxane block, A is a divalent radical, m and n have independently a value of at least 1, comprising at least one alkoxy-substituted siloxane unit of the formula (R?)q(OR)—SiO3?q/2 ?, wherein R represents an alkyl group having 1 to 4 carbon atoms and each R? represents an alkyl group having 1 to 6 carbon atoms, a phenyl group, or an alkoxy group of the formula —OR and q has a value of 0, 1 or 2, provided at least two silicon-bonded groups OR are present in the block copolymer.
    Type: Grant
    Filed: April 30, 2008
    Date of Patent: November 26, 2013
    Assignee: Dow Corning Corporation
    Inventors: Iain A. Mackinnon, Sarah O'Hare, Francois De Buyl, Geraldine Durand
  • Patent number: 8586691
    Abstract: Carbanionic polymer chains that contain polyene mer can be provided with a block derived from one or more ethylenically unsaturated functional monomers after being reacted to include, at their respective termini, one or more, although preferably one, unit that is the radical of a cyclic compound, the ring structure of the cyclic compound comprising silicon atoms alternating with O, S or N atoms.
    Type: Grant
    Filed: July 30, 2012
    Date of Patent: November 19, 2013
    Assignee: Bridgestone Corporation
    Inventor: Yuan-Yong Yan
  • Patent number: 8563129
    Abstract: The invention relates polysilazane-containing coatings for increasing the light permeability of sun-facing covers of solar cells. The coating for surfaces contains at least one polysilazane of formula (1) —(SiRR?R?—NR??1)n- (1), wherein R?, R?, R?? are the same or different or represent an optionally substituted alkyl, aryl, vinyl or (trialkoxysilyl)alkyl group, n being an integer and n being chosen in such a manner that the perhydropolysilazane has a number average molecular weight of 150 to 150,000 g/mol, a solvent and a catalyst. The cured coating has a thickness of at least 0.50-10 micrometer, preferably 0.2 to 5 micrometer, especially preferred 0.5 to 1.5 micrometer. It is especially suitable as transmission-promoting coating for use in sun-facing covers of solar cells.
    Type: Grant
    Filed: April 17, 2009
    Date of Patent: October 22, 2013
    Assignee: AZ Electronic Materials (Luxembourg) S.a.r.l.
    Inventors: Klaus Rode, Hartmut Wiezer, Sandra Stojanovic, Hubert Liebe, Lars Blankenburg
  • Patent number: 8487061
    Abstract: Provided is a process for making a saturated star hydrocarbon polymer. The process has the following steps: (A) hydrosilylating tetraethylene silicon with methyldichlorosilane in the presence of a hydrosilylating catalyst to form a chlorosilane dendrimer; (B) reacting the chlorosilane dendrimer with vinylmagnesium bromide in the presence of a lithium and/or organolithium initiator stepwise to build a higher generation chlorosilane dendrimer; (C) anionically polymerizing polybutadiene in the presence of a lithium and/or organolithium initiator to form living poly(butadienyl)lithium; (D) attaching the living poly(butadienyl)lithium to the higher generation dendrimer to form a star polybutadiene; and (E) hydrogenating the star polybutadiene to form the saturated star hydrocarbon polymer. There is also provided a saturated star hydrocarbon polymer made according to the above process and a polymer composition of a matrix ethylene polymer and the saturated star hydrocarbon polymer.
    Type: Grant
    Filed: May 17, 2011
    Date of Patent: July 16, 2013
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Andy H. Tsou, Nikos Hadjichristidis, Pamela J. Wright, Johannes M. Soulages
  • Patent number: 8480929
    Abstract: A corrosion protection composition includes a mixture of three different silanes selected to interact and form a coating on metal substrates that has improved adhesion and durability as well as UV protection properties. Methods of manufacturing the corrosion protection composition include mixing the silanes together and further combining the silane mixture with other mixtures to arrive at the corrosion protection composition. Sonication may be a preferred manner of mixing together the various components of the mixtures.
    Type: Grant
    Filed: July 5, 2012
    Date of Patent: July 9, 2013
    Inventors: Lloyd H. Hihara, Atul Tiwari
  • Patent number: RE44683
    Abstract: The invention provides branched copolymers as precursors for preparing silicon carbide (SiC) ceramics represented by the general formulae: [Si(˜)RC(˜)H]xn[SiR1R2CH2]yn,??Formula Type-I wherein n is the degree of polymerization, 0.1?x<0.8, 0.2?y<0.9 and x+y=1; and R=methyl or H, R1 and R2 are randomly composed of hydrogen (H), allyl, methyl (Me), phenyl (Ph), propargyl or vinyl. Another branched copolymer is represented by the general formula: [Si(˜)RC(˜)H]xn[SiR1R2CH2]yn[SiR3R4CH2]zn??Formula Type-II wherein n is the degree of polymerization, 0.1?x<0.8, 0?y<0.8, 0.2?z<0.8 and x+y+z=1; and R=methyl or H, R1 and R2 are randomly composed of hydrogen (H), methyl (Me) and phenyl; R3 and R4 are randomly composed of H, allyl, methyl, phenyl (Ph), propargyl, and vinyl. The invention also provides methods for the preparation of such branched copolymers.
    Type: Grant
    Filed: May 7, 2012
    Date of Patent: December 31, 2013
    Assignee: Starfire Systems Inc.
    Inventor: Qionghua Shen