Abstract: There is provided herein a silylated organo-modified compound which comprises: at least one moiety having the formula (A): wherein the subscript a is 1 or 2, each D is independently NH or O, each of X, Y and Z are independently an unsubstituted or substituted C or N, the dashed lines between X, Y, and Z indicate an optional double bond between either X and Y or Y and Z, with the proviso that when any of X, Y, or Z is a substituted N atom, such substituted N atom does not participate in a double bond, and each Q is independently O or S; and, at least two moieties having the formula (B):

Abstract: The present invention provides: a highly transparent optical member which is formed from a silicone resin or a silicone rubber, and which has less mass change and excellent heat resistance without causing contact faults, or deterioration or contamination of the surface of other members due to adhesion to an electronic circuit or the surfaces of other members; and a production method for producing said optical member. According to the production method, the content of low-molecular-weight siloxanes D3-D20 in a optical member is reduced to an infinitesimal amount with use of a plurality of different low-molecular-weight siloxane removal steps.

Abstract: The invention relates to a process for preparing polyorganosiloxanes by (i) condensation polymerization of at least one linear organosiloxane which has at least one hydroxy group or hydrolysable group bound to a silicon atom, (ii) ring-opening polymerization of at least one cyclosiloxane, or (iii) ring-opening polymerization and condensation polymerization of a mixture of at least one linear organosiloxane which has at least one hydroxy group or hydrolysable group bound to a silicon atom and at least one cyclosiloxane with a basic initiator and a hydroxy group-containing compound in the presence of a polar aprotic solvent, wherein the obtained polyorganosiloxanes are not miscible in the polar aprotic solvent at room temperature.

Abstract: The present disclosure relates to methods for preparing a hydrophilic composition including intimately mixing a silicone component including at least one polysiloxane and a polymer component, and to hydrophobic polymer compositions prepared thereby. One aspect of the disclosure provides an article having a major exterior surface, the article comprising an intimate mixture of a silicone component including at least one polysiloxane; and a polymer component including at least one hydrophilic polymer having a water-absorption capacity of at least 50 wt. %; wherein the silicone component and the polymer component are present in the mixture in a dry weight ratio within the range of 99.9:0.1 to 30:70. In certain desirable embodiments as otherwise described herein, the intimate mixture is disposed at an exterior surface of the article, e.g., at the major exterior surface of the article.

Abstract: The field of the invention is that of the preparation of release and water-repellent coatings on a support, preferably a flexible support, such as a support made of paper or of synthetic polymer film, preferably of the polyolefin, polypropylene, polyethylene or polyester type. The release coatings taken into consideration are more especially those based on silicone elastomer crosslinked after coating on these supports.

Abstract: Novel polymers are depolymerizable by metathesis of a cleavable unit. As an example, a series of linear and crosslinked polyurethanes were prepared that can be selectively depolymerized under mild conditions. Two unique polyols were synthesized bearing unsaturated units in a configuration designed to favor ring-closing metathesis to five- and six-membered cycloalkenes. These polyols were co-polymerized with toluene diisocyanate to generate linear polyurethanes and trifunctional hexamethylene- and diphenylmethane-based isocyanates to generate crosslinked polyurethanes. The polyol design is such that the ring-closing metathesis reaction cleaves the backbone of the polymer chain. Upon exposure to dilute solutions of Grubbs' catalyst under ambient conditions, the polyurethanes were rapidly depolymerized to low molecular weight, soluble products bearing vinyl and cycloalkene functionalities. These functionalities enabled further re-polymerization by traditional strategies for polymerization of double bonds.

Abstract: One of the purposes of the present invention is to provide a silicone which has polymerizable groups at the both terminals and an amphiphilic side chain and which provides a copolymer having high surface wettability.

Abstract: An electromagnetic wave absorbing thermally conductive composition contains a matrix resin component, metal soft magnetic particles, and thermally conductive particles. The metal soft magnetic particles are carbonyl iron particles and are present in an amount of 30% by volume or more when the electromagnetic wave absorbing thermally conductive composition is a population parameter. A value of an imaginary part (??) of relative permeability of the electromagnetic wave absorbing thermally conductive composition is 0.9 or more in at least some bands in a frequency range of 18 to 26.5 GHz. The electromagnetic wave absorbing thermally conductive composition in the form of a sheet has a thermal conductivity of 2.0 W/m·K or more in the thickness direction. A sheet of the present invention incudes the above composition in the form of a sheet.

Abstract: Polymers including multi-stage polymers that combine the structural integrity of a polymer with a high glass transition temperature (Tg) with a softer, lower molecular weight polymer that coalesces quickly and is flexible to maintain scrubbability are disclosed. Architectural compositions containing these film-forming polymers exhibit anti-blocking properties within one hour from being applied to a substrate.

Abstract: An electronic device includes a first part, and a circuit plate including a circuit substrate, a plating film made of a plating material and being disposed on a front surface of the substrate. The plating film includes a first part region on which the first part is disposed via a first solder, and a liquid-repellent region extending along a periphery side of the first part region in a surface layer of the plating film, and having a liquid repellency greater than a liquid repellency of the plating film. The liquid-repellent region includes a resist region. The plating film includes a remaining portion between the liquid-repellent region and the front surface of the circuit substrate in a thickness direction of the plating film orthogonal to the front surface. The remaining portion is made of the plating material and is free of the oxidized plating material.

Abstract: A method of fabricating a light emitting device comprises providing a mold having an unpolished surface with an arithmetic mean roughness Ra in a range from 0.1 ?m to 10 ?m, depositing a thin polymer film over the surface of the mold, wherein the film has a thickness in a range from 1 ?m to 100 ?m, positioning a light emitting body onto the thin polymer film, wherein the light emitting body includes an anode, a cathode, and a light emitting layer positioned between the anode and the cathode, and separating the thin polymer film with the light emitting body from the mold. A light emitting device is also described.

Abstract: Silicone resins are reproducibly prepared in a four step process in which alcohol recovered in a second step is recycled to the first step, and an aqueous phase recovered in the fourth step contains very little HCl, alcohol, or organopolysiloxane, and can be directed to waste treatment without any prior processing.

Abstract: A curable composition is provided, comprising: (A) a binder composition; and (B) a polysiloxane resin comprising aromatic functional groups and terminal active hydrogen groups. The composition may be used to prepare articles of manufacture and coated articles, such as footwear components. The composition may additionally be used to mitigate dirt build-up on a substrate.

Abstract: Branched organopolysiloxanes and organopolysiloxanes with low alkoxy content are produced in a first reaction unit by continuous feed of organohalosilanes and alcohol to a reaction vessel surmounted by a distillation column, the vessel containing an excess of water relative to the halogen content of the organohalosilanes. A second reaction unit for removing volatiles from the product from the first reaction unit is also preferably employed.

Abstract: Provided is a carbonate-containing silane compound having a characteristic structure that at least two silicon atoms are linked by a carbon chain. The silane compound is chemically stable. When used as an additive to a nonaqueous electrolyte solution, the silane compound does not jeopardize the safety of lithium ion secondary batteries.

Abstract: A composition is provided comprising (a) a polysilazane having a monovalent hydrocarbon group, (b) untreated metal oxide nanoparticles, metal oxide nanoparticles having a monovalent hydrocarbon group, or metal oxide nanoparticles having an alkylsilyl or alkoxysilyl group, and (c) an aprotic solvent. The composition has storage stability and is suitable for forming a film having water repellent, especially superhydrophobic properties.

Abstract: An energy-sensitive composition including at least one of a silane compound monomer capable of forming a polysilane compound, a silane compound oligomer and the polysilane compound, and a base generator (B) represented by the following formula (1): in which R1 to R11 each independently represents a hydrogen atom, a halogen atom, a nitro group, an alkyl group, an aryl group, an arylalkyl group or an alkoxy group, R5 and R6 may be connected to each other via a single bond or a divalent linking group, Zq+ represents a q-valent counter cation composed of a base having a pKa of 24 or more, and q represents an integer of 1 or more.

Abstract: According to an embodiment, a template includes a flat plate-shaped first member, a flat plate-shaped second member including a pattern arrangement face, and a flat plate-shaped third member provided with an opening at a position corresponding to an arrangement position of the second member. The template is dividable at a position of at least one of a first boundary between the first member and the second member and a second boundary between the first member and the third member.

Abstract: This invention relates to novel ligands for metal complexes used in OLED devices. These ligands comprise an aryl ketone or aldehyde and lead to improved device properties including increased efficiency of dopants, increased lifetimes, and the ability to tune emission colors.

Abstract: The present invention relates to a Y-type discrete polyethylene glycol derivative as shown by Formula (I). The Y-type discrete polyethylene glycol derivative has the advantages of a determined molecular weight and number of segments in the chain, and can avoid the defects where the polyethylene glycol derivative itself is a mixture and the molecular weight is not homogeneous. The Y-type polyethylene glycol of the present invention can solve the problem of insufficient water solubility caused by an increase in the loading capacity when the discrete polyethylene glycol modifies an insoluble drug while increasing the drug loading capacity.

Abstract: The invention relates to a curable composition comprising a) at least one polymer having at least one terminal group of the general formula (I) -An-R—SiXYZ??(I), wherein A is a divalent bonding group containing at least one heteroatom, R is selected from divalent hydrocarbon residues having 1 to 12 carbon atoms, X, Y, Z are, independently of one another, selected from the group consisting of a hydroxyl group and C1 to C8 alkyl, C1 to C8 alkoxy, and C1 to C8 acyloxy groups, wherein X, Y, Z are substituents directly bound with the Si atom or the two of the substituents X, Y, Z form a ring together with the Si atom to which they are bound, and at least one of the substituents X, Y, Z is selected from the group consisting of a hydroxyl group, C1 to C8 alkoxy or C1 to C8 acyloxy groups, and n is 0 or 1; and b) at least one compound of the general formula (II) wherein R? is same or different and is, independently from one another, selected from the group consisting of a hydrogen atom and hydrocarbon residues

Abstract: A thermoplastic resin composition of the present invention contains: a polycarbonate resin; a siloxane copolymer comprising a repeat unit represented by chemical formula 1 and a repeat unit represented by chemical formula 2; a metal aromatic sulfonate; a fluorinated olefin-based resin; and an inorganic filler having a difference in refractive index with the polycarbonate resin of approximately 0-0.01. The thermoplastic resin composition has excellent flame retardancy, transparency, stiffness, heat resistance, balance of these physical properties, and the like.

Abstract: Porous hybrid inorganic/organic materials comprising ordered domains are disclosed wherein the ordered domains are ordered radially, and having the formula (A)x(B)y(C)z (Formula I) or the formula [A]y[B]x (Formula III), wherein A, B, C, x, y and z in Formula I and A, B, x and y in Formula III are further defined herein, and wherein diffraction peak maxima observed for the material exhibit a 2? position that excludes diffraction peaks resulting from atomic-range order that are associated with amorphous material. Methods of making the materials and use of the materials for chromatographic applications are also disclosed.

Abstract: An organic silicon compound is disclosed which is represented by a formula: (R13SiO)3SiR2—[SiR32O]y[SiR32]w—R4—R5, wherein each of R1 and R3 is a group independently selected from the group consisting of alkyl groups, alkenyl groups, aryl groups, aralkyl groups and alkoxy groups having 1 to 20 carbon atoms, R2 is a divalent hydrocarbon group or an oxygen atom, R4 is a divalent hydrocarbon group, or a direct bond to a silicon (Si) atom, R5 is a monovalent group represented by (R6O)qR7(3-q)Si or a monovalent hydrocarbon group having 1 to 20 carbon atoms, and each of R6 and R7 is a group independently selected from the group consisting of alkyl groups, alkenyl groups, aryl groups, aralkyl groups and alkoxy groups having 1 to 20 carbon atoms, and q is an integer between 1 and 3, y is an integer between 0 and 200, and w is 0 or 1.

Abstract: A method of manufacturing an electrochemical cell having a gel electrolyte. An electrochemical cell is provided having a cell casing, and a first electrode, a second electrode, an electrolyte solution and a temperature activated gelling agent disposed within the cell casing. A gel electrolyte comprising the electrolyte solution and the gelling agent is formed by passing a current through the electrochemical cell such that the temperature of the gelling agent exceeds the activation temperature of the gelling agent.

Abstract: A ceramic matrix composite having improved operating characteristics includes a barrier layer.

Abstract: Provided are an organic silicon resin composition, prepreg and laminate using the same. The organic silicon resin composition glue solution contains a condensation silicon resin, a catalyst, an auxiliary agent, a white filler and a solvent as necessary components, and is impregnated in a reinforced material such as a sheet-like fiberglass fiber base material and then dried to prepare the prepreg. The prepreg has a net structure via crosslinking of the silicon resin using a condensation reaction. Since the organic silicon resin has ultrahigh heat resistance and yellowing resistance, the present invention applies the silicon resin to a white LED copper-clad laminate instead of a traditional organic resin, satisfying the demand for high heat resistance, and replacing the ceramic substrate to be a new heat-dissipating substrate base material.

Abstract: An object of the present invention is to provide a rubber composition from which a crosslinked rubber molded product excellent in the resilience performance can be obtained. The present invention provides a rubber composition containing (a) a base rubber, (b) a co-crosslinking agent and (c) a crosslinking initiator, wherein (b) the co-crosslinking agent contains a complex represented by a general formula (1). ((RCOO)8M5(OH)2)n??(1) [In the formula (1), M is a metal atom, R is a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, an alkenyl group having 2 to 18 carbon atoms or an alkynyl group having 2 to 18 carbon atoms, and n is an integer of 1 or more. A plurality of R and M may be identical to or different from each other. At least one of R is the alkenyl group having 2 to 18 carbon atoms or the alkynyl group having 2 to 18 carbon atoms.

Abstract: The present invention relates to an organic silicone resin composition and a prepreg, a laminate, and an aluminum substrate that use the composition. The organic silicone resin composition comprises in terms of parts by weight: 100 parts of a condensation-type silicone resin, 0.0001-2 parts of a catalyst, and 0.001-10 parts of an additive. The organic silicone resin composition has the advantages of high heat resistance, halogen-free and phosphorus-free flame retardancy, improved peel strength with copper foil, and low coefficient of expansion, and is applicable in manufacturing the pre-preg, the laminate, and the aluminum substrate for used in a high-performance printed circuit.

Abstract: Polyimide formed from at least one dianhydride and at least one diamine, wherein at least 50 wt. % of the diamine is comprised of dimer fatty diamine, and a process of making the polyimide. The dianhydride is preferably a tetracarboxylic acid in which carbonyl groups are attached in pair to adjacent carbon atoms, and the dimer fatty diamine may be formed from a corresponding dimer fatty acid, especially the dimerisation products of C10 to C30 fatty acids such as oleic acid, linoleic acid, linolenic acid, palmitoleic acid, and elaidic acid. Also polyimide pre-polymer being polyamic acid formed by reaction of the dinhydride, and diamine comprised of dimer fatty diamine. The polyimide may be formed in to coatings, adhesives, or polymer films, said compositions in particular being self-healing.

Abstract: In an aspect of the present invention, there is provided a water/oil repellent coating film, the water/oil repellent coating film being formed on a surface of a solid object, wherein the water/oil repellent coating film is terminated with a group expressed by chemical formula (A) and a three-dimensional crosslinking structure of siloxane bond is formed.

Abstract: Compositions and methods using same for forming a silicon-containing film such as without limitation a silicon oxide, silicon nitride, silicon oxynitride, a carbon-doped silicon nitride, or a carbon-doped silicon oxide film on at least a surface of a substrate having a surface feature. In one aspect, the composition comprises at least one compound is selected from the group consisting of a siloxane, an trisilylamine-based compound, an organoaminodisilane compound, and a cyclic trisilazane compound.

Abstract: The present invention provides a silicon-containing condensate comprising one or more repeating units selected from a repeating unit shown by the following general formula (A1), a repeating unit shown by the following general formula (A2), and a repeating unit shown by the following general formula (A3), wherein R1 represents a group shown by the following general formula (A-1) or (A-2); R2 and R3 each independently represent the same group as R1, a hydrogen atom, or a monovalent organic group having 1 to 30 carbon atoms other than R1. There can be provided a silicon-containing condensate to give a composition for forming a silicon-containing resist under layer film which can form a resist under layer film with good adhesiveness to any resist pattern, whether the pattern is formed by negative development or positive development.

Abstract: Presently described are dental compositions comprising one or more fatty mono(meth)acrylates, methods of use, dental articles, and methods of making dental compositions. It has been found that a relatively low concentration of a fatty mono(meth)acrylate can improve the handling characteristics of a dental composition by reducing the tendency of the composition to stick to a dental instrument and/or by reducing the tendency of a dental composition to string when being manipulated by a dental instrument. In one embodiment, a hardenable dental composition is described comprising a polymerizable resin composition comprising at least one multifunctional ethylenically unsaturated monomer; 0.2 to 10 wt-% of one or more fatty mono(meth)acrylate monomers; and at least 50 wt-% of inorganic oxide filler.

Abstract: A cosmetic preparation containing a crosslinkable silicone rubber emulsion comprising (A) 100 parts by weight of a straight chain or branched organopolysiloxane containing at least two hydroxyl groups bonded to the silicon atom per molecule prepared by ring-opening polymerization of a cyclic organosiloxane in the presence of an alkoxysilane or its partial hydrolytic condensate or an ?,?-dihydroxy or dialkoxy siloxane oligomer by using a catalyst selected from citric, lactic, and ascorbic acids and an anionic surfactant emulsifier; and (B) 0.5 to 20 parts by weight of a reaction product of an amino group-containing organoxysilane and an acid anhydride.

Abstract: Highly condensed silicon resins are obtained by a three step continuous procedure without the use of organic solvent, by preliminarily forming a partial alkoxylate by reacting a chlorosilane with alcohol containing no or a minimal amount of water, feeding the partial alkoxylate to a reaction column to form a silicone resin of low degree of condensation, and further condensing the silicone resin intermediate thus formed to produce a silicone resin product.

Abstract: A metal complex including at least one metal atom chosen from the metals of Groups 8, 9 and 10 of the Periodic Table of the Elements and one or more ligands, wherein at least one ligand includes a cyclic silylene structure and a Lewis base which donates an electron pair to the silicon atom of the cyclic silylene structure.

Abstract: Provided is an addition-curable liquid silicone rubber composition which is suppressed in thickening over time even in cases where a silicone raw rubber is added into a liquid silicone rubber composition, thereby having excellent storage stability, and which provides a silicone rubber that has a low hardness after being cured. An addition-curable liquid silicone rubber composition which contains: (A) an alkenyl group-containing organopolysiloxane having an average polymerization degree of 1,500 or less, which is in a liquid state at room temperature; (B) an organopolysiloxane having an average polymerization degree of 2,000 or more, which is in the form of a raw rubber at room temperature; (C) an organohydrogen polysiloxane; (D) a fumed silica having a BET specific surface area of 130 m2/g or more; (E) an organosilane and/or organopolysiloxane having a silanol group; and (F) an addition reaction catalyst.

Abstract: The present disclosure is directed to resins and to polymers, copolymers, and blends formed therefrom.

Abstract: The present invention relates to a copolycarbonate and a composition comprising the same, and more specifically to a technique for improving flame retardance and chemical resistance while maintaining inherent impact strength and melt index of the copolycarbonate, by comprising a branched repeating unit in the copolycarbonate structure.

Abstract: Provided is an addition-curable liquid silicone rubber composition which is suppressed in thickening over time even in cases where a silicone raw rubber is added into a liquid silicone rubber composition, thereby having excellent storage stability, and which provides a silicone rubber that has a low hardness after being cured. An addition-curable liquid silicone rubber composition which contains: (A) an alkenyl group-containing organopolysiloxane having an average polymerization degree of 1,500 or less, which is in a liquid state at room temperature; (B) an organopolysiloxane having an average polymerization degree of 2,000 or more, which is in the form of a raw rubber at room temperature; (C) an organohydrogen polysiloxane; (D) a fumed silica having a BET specific surface area of 130 m2/g or more; (E) an organosilane and/or organopolysiloxane having a silanol group; and (F) an addition reaction catalyst.

Abstract: The present invention relates to novel free-radically curable dental compositions, comprising chain-like and/or cyclic and/or cage-type polysiloxanes substituted by free-radically polymerizable groups and having at least 3 silicon atoms and/or mixed forms thereof, disiloxanes substituted by free-radically polymerizable groups, optionally one, two, three or more free-radically curable dental monomers having no silicon atom, fillers, initiators and/or catalysts for free-radical polymerization, and also further customary additives, to the cured dental products formed from the dental compositions of the invention, and to the respective use thereof as dental material, especially as flowable filling composites (called “flow materials”), core buildup materials and luting cements. The invention further relates to a method for producing the dental compositions and to a process for producing a respective dental product.

Abstract: The present invention relates to the use of free-radically curable compositions, comprising chain-like and/or cyclic and/or cage-type polysiloxanes substituted by free-radically polymerizable groups and having at least 3 silicon atoms and/or mixed forms thereof, disiloxanes substituted by free-radically polymerizable groups, optionally one, two, three or more free-radically curable monomers having no silicon atom, fillers, initiators and/or catalysts for free-radical polymerization, and also further customary additives, in additive manufacturing methods, preferably in stereolithography (SL) and digital light processing (DLP). The present invention further relates to the use of the cured free-radically curable compositions, preferably for production of dental products.

Abstract: The disclosure provides a coating composition, a film made of the coating composition, and method for preparing the coating composition. The coating composition includes a product prepared from cross-linking a (a) polysilsesquioxane with a (b) compound with the structure represented by Formula (I): wherein R is independently a hydroxyl group, or C1-8 alkoxy group, R1 is a C3-12 epoxy group, C3-12 acrylate group, C3-12 alkylacryloxy group, C3-12 aminoalkyl group, C3-12 isocyanate-alkyl group, C3-12 alkylcarboxylic acid group, C3-12 alkyl halide group, C3-12 mercaptoalkyl group, C3-12 alkyl group, or C3-12 alkenyl group, and R2 is a hydroxyl group, C1-8 alkyl group, or C1-8 alkoxy group.

Abstract: A method of treating a preceramic material includes providing a preceramic polycarbosilane or polycarbosiloxane material that includes a moiety Si—O-M, where Si is silicon, O is oxygen and M is at least one metal that includes at least one transition metal, and thermally converting the preceramic polycarbosilane or polycarbosiloxane that includes the moiety Si—O-M material into a ceramic material.

Abstract: Vapor deposition methods to form Group 8-containing films are disclosed. The vapor of a Group-8 containing film forming composition is introduced into a reactor containing a substrate. The Group 8-containing film forming compositions comprise silylamide-containing precursors, particularly {Fe[N(SiMe3)2]2}2. At least part of the silylamide-containing precursor is deposited onto the substrate to from the Group 8-containing film.

Abstract: Novel polyurea siloxane coating compositions are contemplated, the compositions being the reaction products of isocyanate prepolymers and resin blends, with the resin blends containing siloxane copolymers in addition to conventional polyurea monomer and polymer resin reactants. Specifically, it has been found that reaction products having superior gloss retention, water resistance, temperature resistance, and chemical resistance may be formed from isocyanate prepolymers and resin blends having various amounts of poly[(3-aminopropyl)methylsiloxane-co-diphenylsiloxane] in addition to aromatic and/or aliphatic polyamines.

Abstract: The present technology provides compositions, methods, and processes to form polysiloxanes. In one aspect, the present technology provides a process for the ring opening polymerization of a cyclosiloxane comprising contacting a cyclosiloxane with a bicyclic guanidine compound. The guanidine-containing compounds useful in the ring opening reaction include a fused ring structure comprising a guanidine functional group as part of the fused ring.

Abstract: A method for treating a hydrophobic release layer of an intermediate transfer member for use in a printing process in which a negatively charged aqueous inkjet ink is jetted onto the surface of this layer. The method comprises contacting the release layer with a chemical agent which is an amine functionalized silicone. Transfer members comprising such a treated release layer and images printed therefrom are also disclosed.

Abstract: An apparatus for mixing a vaporized precursor with a gas for producing silica particles is provided. The apparatus includes a mixer housing, a precursor delivery chamber having an output in communication with the mixer housing for delivering a vaporized precursor in the mixer housing, and an oxidizing gas delivery chamber having an output in communication with the mixer housing for delivering an oxidizing gas to be mixed with the vaporized precursor. The apparatus further includes a flashback member disposed within the mixer housing and between the output of the precursor delivery chamber and the output of the oxidizing gas delivery chamber. The flashback member is located at a minimum distance from the output of the oxidizing gas delivery chamber defined by Lminimum (cm)=0.453U (Re)?0.5567, wherein U is the flow rate in cm/sec of precursor and Re is the flow Reynolds number. The flashback member may include a tapered surface on at least one side to reduce recirculation of vaporized gas.