Phenolic Reactant Contains A Nitrogen Atom Patents (Class 528/149)
  • Patent number: 11655366
    Abstract: A transparent polyimide mixture is disclosed. The transparent polyimide mixture includes a transparent polyimide, an additive, and a solvent. A molecular chain of the transparent polyimide includes an active hydrogen atom. The additive includes a carbodiimide group. An equivalent ratio of the active hydrogen atom and the carbodiimide group is in a range of 1:0.8 to 1:1.2. A method for preparing the transparent polyimide mixture, a transparent polyimide film, and a method for preparing a transparent polyimide film are also disclosed.
    Type: Grant
    Filed: December 3, 2020
    Date of Patent: May 23, 2023
    Assignee: Zhen Ding Technology Co., Ltd.
    Inventors: Kuan-Wei Lee, Pei-Jung Wu, Szu-Hsiang Su, Shou-Jui Hsiang
  • Publication number: 20150104579
    Abstract: Polyhexahydrotriazine (PHT) film layers are formed by a process comprising heating a first mixture comprising i) a solvent, ii) paraformaldehyde, and iii) a diamine monomer comprising two primary aromatic amine groups at a temperature of about 20° C. to less than 150° C. This heating step forms a stable polyhemiaminal (PHA) in solution, which can be cast on a surface of a substrate, thereby forming an initial film layer comprising the PHA. The initial film layer is heated at a temperature of 180° C. to about 280° C., thereby converting the PHA film layer to a PHT film layer. Young's moduli of about 8 GPA to about 14 GPA have been observed for the PHT film layers.
    Type: Application
    Filed: October 10, 2013
    Publication date: April 16, 2015
    Applicant: International Business Machines Corporation
    Inventors: James L. Hedrick, Hans W. Horn, Gavin O. Jones, Jeannette M. O'Brien, Kumar R. Virwani
  • Publication number: 20130324662
    Abstract: The present invention provides a polybenzoxazole resin containing a repeating unit represented by the following general formula (1): wherein R1 is a tetravalent aromatic group; N atoms and O atoms which are bonded to R1 are present in the form of pairs each consisting of an N atom and an O atom such that the N atom and the O atom in each pair are respectively bonded to adjacent two carbon atoms constituting the same aromatic ring in R1; R2 is an alkanediyl group having 1 to 6 carbon atoms; and n is an integer of 2 to 10000, which is excellent in electrical insulating properties, heat resistance, mechanical properties, physical properties, dimensional stability and the like, as well as a polybenzoxazole precursor capable of producing the polybenzoxazole resin which is excellent in solubility in solvents and storage stability.
    Type: Application
    Filed: April 4, 2012
    Publication date: December 5, 2013
    Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.
    Inventor: Eiichi Honda
  • Publication number: 20120041146
    Abstract: The present invention provides methods to functionalize and solubilize WCNT with a phenolic polymer such as a lignin or a PF resin followed by in-situ integration of this functionalized CNT in the presence of formaldehyde and phenol and/or lignin to generate either CNT-reinforced phenol-formaldehyde polymer or CNT-reinforced lignin-phenol-formaldehyde polymer in either liquid or powder form suitable as an adhesive in the manufacture of a lignocellulosic composite material such as OSB and plywood.
    Type: Application
    Filed: July 27, 2011
    Publication date: February 16, 2012
    Applicants: NATIONAL RESEARCH COUNCIL OF CANADA, FPINNOVATIONS
    Inventors: Yaolin ZHANG, Xiang-Ming WANG, Martin FENG, Gilles BRUNETTE, Fuyong CHENG, Benoit SIMARD
  • Patent number: 7910640
    Abstract: Disclosed is a polycondensation product that is a reaction product of A) an aromatic or heteroaromatic compound containing 5 to 10 C atoms or heteroatoms and is provided with an average of 1 to 300 oxyethylene groups and/or oxypropylene groups per molecule which are linked to the aromatic or heteroaromatic compound via an O atom or N atoms, and B) an aromatic compound and C) an aldehyde selected among the group of formaldehyde, glyoxylic acid, and benzaldehyde or mixtures thereof. Surprisingly, the inventive polycondensation product causes very good liquefaction of hydraulic binding agents, eg. Cement, resulting in substantially improved liquefaction of the construction material at a lower dose while pourability can be maintained over a longer period of time as opposed to naphthalene sulfonates or melamine sulfonates.
    Type: Grant
    Filed: October 14, 2005
    Date of Patent: March 22, 2011
    Assignee: Construction Research & Technology GmbH
    Inventors: Philipp Wieland, Alexander Kraus, Gerhard Albrecht, Kerstin Becher, Harald Grassl
  • Patent number: 7834099
    Abstract: An imide-naphthoxazine copolymer comprising a repeating unit represented by General Formula (1) below: (wherein X and Y independently represent a single bond, an oxygen atom, a carbonyl group, or an organic group which may be substituted by a heteroatom; R represents CH3 or H, n represents an integer from 1 to 10; and m represents an integer from 1 to 20).
    Type: Grant
    Filed: September 6, 2007
    Date of Patent: November 16, 2010
    Assignees: Sekisui Chemical Co., Ltd., Case Western Reserve University
    Inventors: Hatsuo Ishida, Masanori Nakamura
  • Patent number: 6790934
    Abstract: Aromatic polyethers are prepared by displacement polymerization reaction in the presence of a water-immiscible solvent with boiling point at atmospheric pressure of greater than 110° C. and a density ratio to water of greater than 1.1:1 at 20-25° C. The polyethers are purified by processes comprising aqueous extraction, or filtration, or a combination thereof.
    Type: Grant
    Filed: December 21, 2001
    Date of Patent: September 14, 2004
    Assignee: General Electric Company
    Inventors: Norman Enoch Johnson, Raul Eduardo Ayala, Thomas Joseph Fyvie, Amy Rene Freshour, David Winfield Woodruff, Peter David Phelps, Ganesh Kailasam, Paul Edward Howson, Elliott West Shanklin, Lioba Maria Kloppenburg, David Bruce Hall, Pradeep Jeevaji Nadkarni, Daniel Joseph Brunelle
  • Patent number: 6613848
    Abstract: A hardener for an epoxy resin comprises a phenolic, thiophenolic, aminophenyl, tris-phenolic, tris-thiophenolic, tris-aminophenyl, tetrakis-phenolic, tetrakis-thiophenolic, or tetrakis-aminophenyl compounds; or phenol-formaldehyde or phenol-formaldehyde/melamine-formaldehyde resins wherein the phenyl rings are substituted with at least one of the structures wherein R1 and R2 independently are H, C1-C18 alkyl, C6-C18 aryl, C6-C18 substituted aryl, C6-C18 aryl methylene, or C6-C18 substituted aryl methylene; X is O, S or NH and Ar is wherein R is C1-C4 alkyl and n=0-5.
    Type: Grant
    Filed: May 16, 2000
    Date of Patent: September 2, 2003
    Assignee: National Science Council
    Inventors: Chun-Shan Wang, Jeng-Yueh Shieh
  • Patent number: 6613493
    Abstract: Photoresist polymers having nitro groups (—NO2), and photoresist compositions containing the same. A photoresist pattern having excellent endurance, etching resistance, reproducibility and resolution can be formed by the use of the photoresist copolymer comprising polymerization repeating units represented by Chemical Formula 1a or 1b: wherein, R1, a, b, c, d, e, f, g and h is defined in the specification. Having nitro groups in the polymer, the photoresist polymer results in a low absorbance in the range of 157 nm wavelength, so that it is extremely useful for a photolithography process using, in particular, VUV light source.
    Type: Grant
    Filed: January 4, 2002
    Date of Patent: September 2, 2003
    Assignee: Hynix Semiconductor Inc
    Inventors: Geun Su Lee, Jae Chang Jung, Ki Soo Shin
  • Patent number: 6465601
    Abstract: Compounds active as accelerators for curable epoxy and polyurethane systems, those compounds having been prepared by means of a transamination reaction by reacting (a) a substituted phenolic compound (Mannich base) having at least one substituent of formula R1(R2)N—CH(R3)—  (A), wherein R1 and R2 are each independently of the other linear or branched C1-4alkyl and R3 is hydrogen, methyl, ethyl or phenyl, with (b) a compound of formula R4(R5)N—CnH2n—(NH—CnH2n)q—NH2  (B), wherein R4 and R5 are each independently of the other C1-C6alkyl or together form a radical of formula —(CH2)5— or —(CH2)2—O—(CH2)2—, n is an integer from 2 to 5 and q is zero, 1, 2 or 3, and the compound obtained or the compounds present in the mixture obtained has/have on average, per molecule, at least one substituent of formula (R4)(R5)N—CnH2n—(NH—CnH2n)q—NH—CH(R3)—, and the use of those compounds as acceler
    Type: Grant
    Filed: June 15, 2001
    Date of Patent: October 15, 2002
    Assignee: Vantico Inc.
    Inventors: Rolf Wiesendanger, Walter Fischer, Bryan Dobinson
  • Patent number: 6005064
    Abstract: A novel thermosetting compound which is speedily curable, generates no by-products during curing and gives cured products having excellent heat resistance and inflammability.A thermosetting compound characterized in containing, per molecule, at least one structural unit represented by the formula (A) and at least one structural unit represented by the formula (B) in a (A)/(B) molar ratio of 1/0.25 to 1/9, said structural units being bonded directly or via at least one organic group with one another; ##STR1## wherein R.sup.1 is a methyl group, a cyclohexyl group, a nonsubstituted phenyl group or a phenyl group substituted with at least one substituent, and each hydrogen atom on the aromatic rings of (A) and (B), except for one of hydrogen atoms on ortho-positions of the hydroxy group in the aromatic ring of (A), may optionally be replaced with a substituent.
    Type: Grant
    Filed: July 6, 1998
    Date of Patent: December 21, 1999
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Yasuyuki Hirai, Teruki Aizawa, Yukio Yoshimura
  • Patent number: 5985507
    Abstract: A high thermal alkali-soluble novolak binder resin, comprising the addition-condensation reaction product of a phenolic mixture with at least one aldehyde source, the feedstock of the phenolic mixture for the reaction comprising:(1) about 25 to about 40 weight percent of the phenolic mixture being a monomer selected from meta-cresol 2,5-xylenol or the combination thereof;(2) about 50 to about 70 weight percent of the phenolic mixture being para-cresol; and(3) about 3 to about 20 weight percent of the phenolic mixture being acetamidophenol; all percentages based on the weight of total phenol monomer feedstock.The invention is also directed to a positive working photoresist made from the composition.
    Type: Grant
    Filed: February 18, 1998
    Date of Patent: November 16, 1999
    Assignee: Olin Microelectronic Chemicals, Inc.
    Inventors: Andrew J. Blakeney, Sanjay Malik, Medhat A. Toukhy, Joseph Sizensky
  • Patent number: 5973072
    Abstract: The present invention is directed to a polymeric vehicle, the formulated coating composition and a coating binder made from the polymeric vehicle and a method for making the polymeric vehicle where the polymeric vehicle includes a phenolic urethane reactive diluent. The phenolic urethane reactive diluent may be made from a phenolic ester alcohol having at least one aliphatic hydroxyl group.
    Type: Grant
    Filed: March 21, 1996
    Date of Patent: October 26, 1999
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: Frank N. Jones, Vijay Swarup, Ramachandran P. Subrayan, Suru Zhang
  • Patent number: 5952447
    Abstract: Disclosed is a phenol resin composition containing a specific triazines-modified novolak phenol resin comprising phenols, triazines and aldehydes, and a method for producing the triazines-modified novolak phenol resin comprising the steps of as a first step reaction, successively effecting processes (i), (ii) and (iii), wherein said process (i) is a process for adjusting a pH of a system of a mixture of phenols, triazines and aldehydes in a range of 5 to 10, said process (ii) is a process for reacting said mixture under the condition that the aldehydes are not volatilized and said process (iii) is a process for removing a reaction water in the system; then as a second step reaction, successively effecting said processes (ii) and (iii) at a higher temperature than that of the first step reaction; thereafter as a third step reaction, successively effecting said processes (ii) and (iii) at a higher temperature than that of the second step reaction; and further, depending upon a necessity, repeating the second st
    Type: Grant
    Filed: May 8, 1998
    Date of Patent: September 14, 1999
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventor: Takashi Ikeda
  • Patent number: 5728780
    Abstract: In a novel method of homo- or copolymerization of vinyl chloride, a specified coating agent is applied on the surfaces of the portions which will become into contact with the vinyl chloride monomer during the polymerization process. The coating agent is in a form of an aqueous solution of a modified condensation product of phenol and aldehyde, the pH of the solution being adjusted in a range that the product is dissolved at an ambient temperature upon coating of the solution and separates out of the solution upon being heated on the surfaces. The wall surface of the polymerization tank and the like is then coated with a thin film of the coating agent having a uniform thickness and being strongly adhered to the wall surface, thereby providing an excellent effect of preventing adhesion of the product polymer to the wall surface.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: March 17, 1998
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Seiichi Masuko, Ichisaburo Nakamura, Yasuyuki Hatakeyama
  • Patent number: 5723067
    Abstract: Tris-(cyanato)-s-triazines having the formula: ##STR1## wherein R.sub.1 and R.sub.2 independently of one another, represent halogen, in particular, chlorine, bromine and fluorine, hydrogen or a methyl group or ethyl group. The monomers disclosed always provide an anisotropic network. Methods for the polycyclotrimerization of polycyanates to obtain the inventive compounds are also disclosed.
    Type: Grant
    Filed: May 1, 1996
    Date of Patent: March 3, 1998
    Assignee: Europaeische Wirtschaftsgemeinschaft
    Inventors: Werner Mormann, Joerg Zimmermann
  • Patent number: 5688631
    Abstract: Methods for producing solutions of polybenzoxazol precursors that are soluble in alkali and resist solutions based on such precursors. A dicarboxylic acid halogenide is reacted with a bis-(o-aminophenol) in an organic solvent and in the presence of a polymer with a tertiary N atom, which is insoluble in the solvent. Excess polymer and hydrohalogenide are separated from the reaction solution. The reaction solution is optionally mixed with a photoactive component.
    Type: Grant
    Filed: March 19, 1996
    Date of Patent: November 18, 1997
    Assignee: Siemens Aktiengesellschaft
    Inventors: Recai Sezi, Hellmut Ahne, Eva Rissel
  • Patent number: 5674482
    Abstract: A biologically active polymeric compound comprising an alkylaryl or heteroalkylaryl backbone having about 5 to about 50 repeating aromatic ring-containing units and which, according to the computer program marketed as SYBYL.RTM. version 5.2 running on a DEC VAX.RTM. 11/750 computer, is capable of forming a linear backbone having a helical secondary structure, and wherein the maximum diameter of the helical structure, as measured by the alkylaryl or heteroalkylaryl backbone, is less than 3 times greater than the maximum diameter of the aryl group of the alkylaryl or heteroalkylaryl backbone.
    Type: Grant
    Filed: August 9, 1991
    Date of Patent: October 7, 1997
    Assignee: Rhone-Poulenc Rorer Pharmaceuticals, Inc.
    Inventors: John R. Regan, Michael N. Chang, Jack Newman, Schmuel Ben-Sasson
  • Patent number: 5652081
    Abstract: Provided is a positive working photoresist composition which comprises an alkali-soluble resin and a 1,2-quinonediazide compound, with the resin being a novolak resin obtained by the condensation reaction of monomers comprising specified phenol compounds with formaldehyde.
    Type: Grant
    Filed: September 5, 1996
    Date of Patent: July 29, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shiro Tan, Shinji Sakaguchi, Yasumasa Kawabe
  • Patent number: 5639396
    Abstract: A process for producing an oil soluble interpolymer polymer of 1,2-alkylenediamine such as N-ethyl ethylenediamine, aldehyde-provider such as formaldehyde, and ortho-unsubstituted hydroxyaromatics such as 4-polyalkylene phenol is disclosed. The decyclized Mannich Base monomer units provide a higher viscosity material which is suitably substituted with a long chain hydrocarbyl para substituent such as polyisobutylene or ethylene/alpha-olefin polymer. Various ortho-substituted hydroxyaromatics such as o-cresol may be used to control the degree of polymerization. The polymers are useful as dispersants or other lubricant additives.
    Type: Grant
    Filed: June 26, 1996
    Date of Patent: June 17, 1997
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Warren A. Thaler, Stephen Zushma, Antonio Gutierrez
  • Patent number: 5608029
    Abstract: A process for producing an oil soluble interpolymer polymer of 1,2-alkylenediamine such as N-ethyl ethylenediamine, aldehyde-provider such as formaldehyde, and ortho-unsubstituted hydroxyaromatics such as 4-polyalkylene phenol is disclosed. The decyclized Mannich Base monomer units provide a higher viscosity material which is suitably substituted with a long chain hydrocarbyl para substituent such as polyisobutylene or ethylene/alpha-olefin polymer. Various ortho-substituted hydroxyaromatics such as o-cresol may be used to control the degree of polymerization. The polymers are useful as dispersants or other lubricant additives.
    Type: Grant
    Filed: March 10, 1995
    Date of Patent: March 4, 1997
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Warren A. Thaler, Stephen Zushma, Antonio Gutierrez
  • Patent number: 5605986
    Abstract: Novel aminoplast anchored UV stabilizers are provided. Compared to unanchored stabilizers, the anchored stabilizers disclosed herein have increased compatibility with coating resins and have reduced volatility due to higher molecular weights resulting from anchoring. A process for preparing the anchored stabilizers by the reaction of unanchored stabilizers with alkoxymethylated aminoplasts in a sulfuric acid medium is also provided. The unanchored stabilizers include 2-(2-hydroxyaryl)benzotriazoles, 2-hydroxybenzophenones, 2-(2-hydroxyaryl)-4,6-diaryl-1,3,5-triazines, salicylic acid derivatives, 2-hydroxyoxanilides, and blocked derivatives thereof as well as mixtures of two or more stabilizers. The aminoplasts include alkoxymethylated derivatives of glycolurils, melamines, and benzoguanamines.
    Type: Grant
    Filed: May 23, 1995
    Date of Patent: February 25, 1997
    Assignee: Cytec Technology Corp.
    Inventors: Jeno G. Szita, Paul S. Waterman
  • Patent number: 5571506
    Abstract: This invention relates to aromatic oligomeric compounds useful in the treatment of cardiovascular, bone metabolic, hypolipidaemic, neuronal, gastrointestinal and elastase-mediated connective tissue degradation disorders and disorders which may be treated by agents effective in binding DNA, to processes for preparation of such oligomeric compounds, to pharmaceutical compositions including such oligomeric compounds, and to their use in the treatment of such disorders.
    Type: Grant
    Filed: September 10, 1993
    Date of Patent: November 5, 1996
    Assignee: Rhone-Poulenc Rorer Pharmaceuticals Inc.
    Inventors: John R. Regan, Daniel G. McGarry, Michael N. Chang, Jeffrey N. Barton, Jack Newman, Schmuel Ben-Sasson
  • Patent number: 5512641
    Abstract: What is disclosed an aromatic oligoimine having a recurring unit composed of an aromatic dialdehyde having a phenolic hydroxyl group and an aromatic diamine and a number-average degree of polymerization of 2 to 20 and a process for preparing the same, and an aromatic polyimine made by thermally dehydrating the aromatic oligoimine and a process for preparing the same.
    Type: Grant
    Filed: March 24, 1995
    Date of Patent: April 30, 1996
    Assignee: Arakawa Kagaku Kogyo Kabushiki Kaisha
    Inventor: Yoichiro Ezaki
  • Patent number: 5380800
    Abstract: Process for the preparation of modified phenolic resins in which the starting components used for preparation of these modified phenolic resins are subjected to a condensation reaction under pressure and in the presence of an inert organic solvent which forms an azeotrope with water, and in which the water is removed from the reaction mixture continuously by azeotropic distillation. An improved space/time yield is achieved by this pressure distillation.
    Type: Grant
    Filed: March 16, 1994
    Date of Patent: January 10, 1995
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Albert Bender, Wolfgang Dathe
  • Patent number: 5302687
    Abstract: A process for preparing a polymeric composition comprising reacting a mixture of at least one phenolic compound and at least one oxazoline compound in the presence of a catalytic amount of at least one ammonium salt and a tetracarbyl phosphonium salt, and optionally also in the presence of an alkyl halide is described.
    Type: Grant
    Filed: March 29, 1993
    Date of Patent: April 12, 1994
    Assignee: Ashland Oil, Inc.
    Inventors: Billy M. Culbertson, Omar Tiba, Gilbert M. Gynn
  • Patent number: 5260405
    Abstract: A binding agent for molding compositions and molded bodies produced by reacting a low molecular weight lignin from the Organosolv process with phenol in a weight ratio of 1:20 to 3:1 at 100.degree. to 180.degree. C., adjusting the pH to an acidic value and condensing the mixture with 0.2 to 0.9 moles of formaldehyde per mole of phenol at 60.degree. to 120.degree. C. to form the binding agent useful for producing curable molding compositions, high-temperature molding compositions, refractory products, textile fleeces and friction coatings as well as carbon materials.
    Type: Grant
    Filed: October 26, 1992
    Date of Patent: November 9, 1993
    Assignee: Rutgerswerke Aktiengesellschaft AG
    Inventors: Arno Gardziella, Achim Hansen, Stephan Schroter, Josef Suren
  • Patent number: 5254639
    Abstract: A binding agent for molded bodies and molding compositions produced by prereacting a mixture of 5 to 60% by weight of lignin or a lignin fraction produced by the Organosolv process and 40 to 95% by weight of a phenol novolac resin and subjecting the latter to high shear forces in a kneader or extruder and optionally mixing the same with a curing agent useful in molding compositions and high temperature-stable molded products such as refractory products, friction coatings, textile fleeces and carbon or graphite materials.
    Type: Grant
    Filed: October 26, 1992
    Date of Patent: October 19, 1993
    Assignee: Rutgerswerke Aktiengesellschaft AG
    Inventors: Arno Gardziella, Achim Hansen, Stephan Schroter, Josef Suren
  • Patent number: 5153299
    Abstract: A production method of novel condensates comprising bisphenols and aromatic aminosulfonic acids, in particular, novel 4-aminobenzenesulfonic acid-2, 2-bis(4-hydrocyphenyl)propaneformaldehyde type condensate and said condensate itself are disclosed. Uses of condensates as a dispersant for disperse dye, additive for carbonaceous fine powder-water slurry and water-reducing agent for cement are also claimed.
    Type: Grant
    Filed: August 14, 1990
    Date of Patent: October 6, 1992
    Assignee: Sanyo-Kokusaku Pulp Co., Ltd.
    Inventors: Masanobu Kawamura, Shinji Hamada, Takashi Date, Toshihiro Sugiwaki, Nobuhiro Hanada
  • Patent number: 5106936
    Abstract: This invention provides thermoplastic polymeric materials comprising polycarbonate and polyestercarbonte resins and oriented polymeric compositions thereof which exhibit nonlinear optical properties.
    Type: Grant
    Filed: May 3, 1991
    Date of Patent: April 21, 1992
    Assignee: The Dow Chemical Company
    Inventors: Robert J. Gulotty, Stephen E. Bales
  • Patent number: 5104961
    Abstract: Polymers comprising perfluoroalkyl groups, reproduction layers containing these polymers and use thereof for waterless offset printing. The novel perfluoroalkyl group-containing polymers comprise polymers or polycondensates and have, in each case as substituents on different carbon atoms of benzene rings, phenolic OH groups and perfluoroalkyl groups which are optionally attached through intermediate members. In particular, at least 10% of the polymer units carry perfluoroalkyl groups. These polymers are either formed by condensation of substituted phenols (e.g., 4-hydroxybenzoic acid-perfluoroalkyl ester) with an aldehyde, a ketone, or a reactive bismethylene compound or by reacting polymers containing phenolic OH groups (e.g., hydroxypolystyrene) or polycondensates containing reactive OH groups (e.g., phenol-formaldehyde resins) with a perfluoroalkyl group-containing compound (e.g., 2,2-dihydroperfluorodecanoic acid chloride).
    Type: Grant
    Filed: December 19, 1990
    Date of Patent: April 14, 1992
    Assignee: Hoechst Celanese Corporation
    Inventor: Werner H. Muller
  • Patent number: 5098986
    Abstract: Normally liquid polyfunctional final Mannich condensates that are useful as curing agents for epoxy resins are prepared by reacting a para C.sub.1 -C.sub.15 alkyl phenol with formaldehyde and a first polyoxyalkylene diamine to form an intermediate Mannich condensate that is reacted, in turn, with formaldehyde and a second polyoxyalkylene diamine to form the final Mannich condensate, the first polyoxyalkylene diamine having the formula: ##STR1## wherein: n represents a positive number having a value of 1 to about 6, andR' independently represents hydrogen or a methyl group, the second polyoxyalkylene diamine having the formula: ##STR2## wherein n and n' represent positive numbers having a value of 1 to about 6,R' independently represents hydrogen or a methyl group, andR"' represents an alkyl group containing 1 to 4 carbon atoms or a cyanoethyl group.
    Type: Grant
    Filed: November 19, 1990
    Date of Patent: March 24, 1992
    Assignee: Texaco Chemical Company
    Inventors: George P. Speranza, Jiang-Jen Lin
  • Patent number: 5075415
    Abstract: A novel adhesive composition capable of bonding strongly polyester fibers and rubbers with reduced adhesive deterioration even at high temperatures is provided which comprises, as a predominant component, a co-condensation resin obtained by co-condensing at least one member selected from compounds (I) represented by the following general formula, ##STR1## wherein R.sub.1 and R.sub.2 are hydrogen atoms, alkyl groups or alkoxy groups, the sum of carbon atoms of R.sub.1 and R.sub.2 being 0 to 4, at least one member selected from compounds (II) represented by the following general formula, ##STR2## wherein R.sub.3, R.sub.4 and R.sub.5 are hydrogen atoms or alkyl groups, the sum of carbon atoms of R.sub.3, R.sub.4 and R.sub.5 being 0 to 4, and aldehyde.
    Type: Grant
    Filed: November 15, 1989
    Date of Patent: December 24, 1991
    Assignee: Bridgestone Corporation
    Inventors: Toshihiro Yotsumoto, Koichi Morita, Takeshi Kinoshita
  • Patent number: 5037935
    Abstract: This invention provides thermoplastic polymeric materials comprising polycarbonate and polyestercarbonate resins and oriented polymeric compositions thereof which exhibit nonlinear optical properties.
    Type: Grant
    Filed: June 8, 1990
    Date of Patent: August 6, 1991
    Assignee: The Dow Chemical Company
    Inventors: Robert J. Gulotty, Stephen E. Bales
  • Patent number: 4939229
    Abstract: A method for preparing branched novolak polymers possessing excellent lithographic performance is provided. The method involves the acid catalyzed reaction of a phenol with a tris- or tetrakis(dialkylaminoalkyl)phenol followed by purification of the reaction product. The branched novolaks are soluble in aqueous base and organic solvent solutions and are particularly useful as the polymeric component of either positive acting or negative acting photoresist compositions.
    Type: Grant
    Filed: May 12, 1989
    Date of Patent: July 3, 1990
    Assignee: Rohm and Haas Company
    Inventor: Leonard E. Bogan, Jr.
  • Patent number: 4902770
    Abstract: The undercoating composition of the invention, useful for providing an undercoating layer for a top coat of a photosensitive resist layer on a substrate surface, comprises, as a principal ingredient thereof, a condensation product obtained by the condensation reaction between a hydroxy-substituted diphenylamine and a melamine compound substituted on the nitrogen atoms with methylol groups and/or alkoxymethyl groups. The undercoating obtained of the composition is highly resistant against the attack by the overcoating solution applied thereon so that the fidelity of the pattern reproduction by the photolithographic technique is greatly improved by virtue of the absence of any disorder at the interface between the undercoating and top coat layers. The advantage is further increased when the undercoating composition further comprises a photoextinctive agent, e.g. a dye, having absorptivity in the wave length region where the photosensitive resist of the top coat has sensitivity.
    Type: Grant
    Filed: May 20, 1987
    Date of Patent: February 20, 1990
    Assignee: Tokyo Ohka Kogyo Co., Ltd.
    Inventors: Wataru Ishii, Shozo Miyazawa, Shinji Tsuchiya, Hisashi Nakane, Akira Yokota
  • Patent number: 4888409
    Abstract: Thermotropic copolyazomethines having a mesophase temperature range lying within a desired range of values are obtained by copolymerizing terephthalic aldehyde with at least two different 1,n-bis(4-aminophenoxy)alkanes.Such copolyazomethines are particularly useful as reinforcing materials for the usual thermoplastic polymers, such as polycarbonate, polybutyleneterephthalate, polyethyleneterephthalate and polyamides.
    Type: Grant
    Filed: December 6, 1988
    Date of Patent: December 19, 1989
    Assignee: Eniricerche S.p.A.
    Inventors: Ugo Pedretti, Cesarina Bonfanti, Enrico Montani, Hassan A. Hakemi, Arnaldo Roggero
  • Patent number: 4841002
    Abstract: Compositions have melting points below 100.degree. C. which are useful in the formation of resins by reaction with polyphenolic compounds consisting of a mixture of more than two compounds having the formula ##STR1## wherein A represents a cyclic or acyclic aliphatic or substituted cyclic or acyclic aliphatic moiety having from 1 to 20 carbon atoms or an aromatic mono- or multi-nuclear or aliphatic substituted aryl residue having from 6 to 20 carbon atoms,R independently represents H, CH.sub.3, CH.sub.2 CH.sub.3 or C.sub.6 H.sub.5,R.sup.1 independently represents H or CH.sub.3,R.sup.2 independently represents H or CH.sub.3, andx represents an integer from 0 to 2are described.
    Type: Grant
    Filed: November 8, 1988
    Date of Patent: June 20, 1989
    Assignee: Ashland Oil, Inc
    Inventors: Billy M. Culbertson, Omar Tiba
  • Patent number: 4839446
    Abstract: A polymerizable thermosetting composition which is a flowable liquid at moderate temperatures which comprises a mixture of:(A) from about 75% to about 95% by weight of a mixture of:(1) from about 80% to about 20% by weight of a bisoxazoline and(2) from about 20% to about 80% by weight of a polyphenolic compound and(B) from about 5% to about 25% by weight of at least one member selected from the group consisting of a monooxazoline and a monooxazine,a method for forming thermoset products therefrom and the novel thermoset products resulting from said method are described.
    Type: Grant
    Filed: August 8, 1988
    Date of Patent: June 13, 1989
    Assignee: Ashland Oil, Inc.
    Inventors: Billy M. Culbertson, Omar Tiba
  • Patent number: 4806267
    Abstract: Compositions having melting points below 100.degree. C. which are useful in the formation of resins by reaction with polyphenolic compounds consisting of a mixture of more than two compounds having the formula ##STR1## wherein A represents a cyclic or acyclic aliphatic or substituted cyclic or acyclic aliphatic moiety having from 1 to 20 carbon atoms or an aromatic mono- or multi-nuclear or aliphatic substituted aryl residue having from 6 to 20 carbon atoms,R independently represents H, CH.sub.3, CH.sub.2 CH.sub.3 or C.sub.6 H.sub.5,R.sup.1 independently represents H or CH.sub.3,R.sup.2 independently represents H or CH.sub.3, andx represents an integer from 0 to 2as described.
    Type: Grant
    Filed: January 15, 1988
    Date of Patent: February 21, 1989
    Assignee: Ashland Oil, Inc.
    Inventors: Billy M. Culbertson, Omar Tiba
  • Patent number: 4792355
    Abstract: This invention relates to an aqueous, acidic composition useful to deposit a corrosion inhibiting and adhesion promoting coating on a metal substrate and a method for doing same. The composition has a pH of between about 2 and about 6 and comprises water-soluble or water-dispersible metal-chelating o-hydroxybenzylamine compound, wherein the amine moiety contains pendant ethanol or propanol moiety.
    Type: Grant
    Filed: January 20, 1987
    Date of Patent: December 20, 1988
    Assignee: Ford Motor Company
    Inventors: Walter O. Siegl, Mohinder S. Chattha
  • Patent number: 4790878
    Abstract: This invention relates to an aqueous composition useful to deposit a corrosion inhibiting and adhesion promoting coating on a corrodible metal substrate and a method for doing same. The composition has a pH of between about 2 and about 10 and comprises water-soluble or water-dispersible metal-chelating diphenolamine compounds.
    Type: Grant
    Filed: January 20, 1987
    Date of Patent: December 13, 1988
    Assignee: Ford Motor Company
    Inventors: Walter O. Siegl, Mohinder S. Chattha
  • Patent number: 4746718
    Abstract: Diamines of the structure ##STR1## Wherein X is --SO.sub.2 -- or --CO--, Y is O or S, and Ar is a linear aryl ether moiety comprising from 1 to 80 aryl rings, are epoxy resin curing agents providing cured resins with improved moisture resistance and toughness. The resins are particularly useful in preparing prepregs and composites.
    Type: Grant
    Filed: April 6, 1987
    Date of Patent: May 24, 1988
    Assignee: Amoco Corporation
    Inventors: Hugh C. Gardner, Linda A. Domeier
  • Patent number: 4739029
    Abstract: A polymeric tricarbocyanine dye has a rigidized chain having tricarbocyanine polymeric dye units of formula II: ##STR1## wherein Y is ##STR2## --S--, --Se--, or --O--, A is ##STR3## in which R.sup.19 is alkyl, --Cl, amino, alkyl (C.sub.1 to C.sub.4) substituted amino, phenyl, or cyclic amino, andp is 0 or 1,R.sup.4 and R.sup.5 independently are --H, C.sub.6 H.sub.5 SO.sub.2 --, or CF.sub.3 SO.sub.2 --,W is a dye anion,m is an integer 1 to 20, andn is an integer 2 to 10,000.
    Type: Grant
    Filed: April 16, 1987
    Date of Patent: April 19, 1988
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Mohamed A. Elmasry
  • Patent number: 4698401
    Abstract: A polyfunctional reaction product having functional phenolic OH groups is made available by reacting a phenol and an alkoxylated amino-aldehyde condensation product in the presence of a solvent and of an acid catalyst. This method makes it possible to prepare a polyfunctional phenolic reaction product which is soluble in organic solvents at a low ratio of phenolic OH groups to alkoxy groups without gelling. The reaction product is particularly useful as a curing agent for epoxy resins.
    Type: Grant
    Filed: September 9, 1985
    Date of Patent: October 6, 1987
    Assignee: The Dow Chemical Company
    Inventors: Dieter H. Klein, Raymond Koenig
  • Patent number: 4680375
    Abstract: Tricarbocyanine polymeric dyes have formulae I and II: ##STR1## where Y can be ##STR2## --S--, --Se-- or --O--, A can be ##STR3## in which R.sup.19 can be alkyl or --Cl, and p can be 0 or 1, R.sup.6 and R.sup.7 independently can be alkyl of (C.sub.1 -C.sub.30), preferably (C.sub.1 -C.sub.18),R.sup.4 and R.sup.5 independently can be --H, C.sub.6 H.sub.5 SO.sub.2 --, or CF.sub.3 SO.sub.2 --,Z can be --SO.sub.2 --, --CH.sub.2).sub.m, or vinylene,W can be I.sup.-, Br.sup.-, Cl.sup.-, ClO.sub.4.sup.-, PECHS.sup.- (polyethylcyclohexylsulfonate), F.sub.3 CSO.sub.3.sup.- (trifluoromethanesulfonate), or other commonly used dye anions,m is an integer of 1 to 20, andn is an integer of 5 to 10,000.
    Type: Grant
    Filed: March 11, 1985
    Date of Patent: July 14, 1987
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Mohamed A. Elmasry
  • Patent number: 4650839
    Abstract: Modified phenolic resins and cured resins prepared therefrom.
    Type: Grant
    Filed: January 23, 1986
    Date of Patent: March 17, 1987
    Assignee: Allied Corporation
    Inventors: Sajal Das, Dusan C. Prevorsek
  • Patent number: 4608431
    Abstract: A method for making polyimide polymers is provided by effecting reaction between an aliphatically unsaturated imide, such as maleimide, formaldehyde, and an organic polyamine, for example trimethylene bis(4-aminobenzoate), for example in refluxing ethanol. The polyimides produced by the simple one-step method are pure, and exhibit superior toughness, and reduced shrinkage upon cure by heating. The new product are useful as molding compounds, laminating resins, and the like, being especially suitable for airplane parts, advanced composites, high performance adhesives and printed circuit boards.
    Type: Grant
    Filed: January 29, 1985
    Date of Patent: August 26, 1986
    Assignee: American Cyanamid Co.
    Inventor: Dalip K. Kohli
  • Patent number: 4444942
    Abstract: A bath composition for cataphoretic electrocoating of conductive surfaces contains coating agents which have been rendered soluble or dispersible with acid, contain basic nitrogen groups and carry groups of the general formulae (1) and (11) ##STR1## and, optionally, also groups of the general formulae (III) and/or (IV) ##STR2## where R.sup.1 and R.sup.2 are each alkyl, hydroxyalkyl or alkoxyalkyl, R.sup.3 and R.sup.4 are each hydrogen or methyl, R.sup.5 and R.sup.6 are each hydrogen, alkyl or a divalent radical of a polymer molecule which is bonded to a phenol or phenol ether, n.sup.1 is 1, 2 or 3 and n.sup.2 is 1 or 2, and where the oxygen bonded to the phenyl radical is either in the form of the OH group or etherified.
    Type: Grant
    Filed: June 15, 1982
    Date of Patent: April 24, 1984
    Assignee: BASF Aktiengesellschaft
    Inventors: Fritz E. Kempter, Eberhard Schupp, Gunther Sabelus
  • Patent number: 4430491
    Abstract: Thermoplastic and thermoset polymeric compositions, having particular utility in the area of molding applications, are obtained by reacting a compound containing a plurality of oxazoline groups with a phenol or a phenolic resin each containing a plurality of aromatic hydroxyl groups.
    Type: Grant
    Filed: September 30, 1982
    Date of Patent: February 7, 1984
    Assignee: Ashland Oil, Inc.
    Inventors: Billy M. Culbertson, Timothy A. Tufts