Aldehyde Or Derivative Is Ethylenically Unsaturated Patents (Class 528/157)
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Patent number: 8674019Abstract: Composite products made with binder compositions that include one or more tannins, one or more multifunctional aldehydes, and one or more Lewis acids and methods for making same. The method can include contacting a plurality of substrates with the binder composition and at least partially curing the binder composition to produce a composite product. The one or more multifunctional aldehyde compounds can include (1) two or more carbon atoms and two or more aldehyde functional groups, or (2) two or more carbon atoms, at least one aldehyde functional group, and at least one functional group other than an aldehyde functional group. A carbon atom of at least one aldehyde functional group can have a first bond with a first tannin molecule and a second bond with (a) the first tannin molecule, (b) a second tannin molecule, or (c) an oxygen atom of the at least one aldehyde functional group.Type: GrantFiled: April 24, 2013Date of Patent: March 18, 2014Assignee: Georgia-Pacific Chemicals LLCInventors: Bobby L. Williamson, Feng Jing
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Publication number: 20130046065Abstract: Embodiments of the present disclosure include polycyclopentadiene compounds represented by Formula (I): in which each X is either a hydrogen or a cyano group (N?C—), n has an average value from zero to 20; each m independently has a value of zero to 3; p has a value of zero to 20; each R is independently a halogen, a nitrile group, a nitro group, an alkyl group, an alkoxy group, an alkenyl group, or an alkenyloxy group, where the alkyl group, the alkoxy group, the alkenyl group, and the alkenyloxy group each independently contain 1 to 6 carbon atoms; and each Q is independently hydrogen or an alkyl group containing 1 to 6 carbon atoms. Embodiments of the present disclosure also include a curable composition that includes the polycyclopentadiene compound(s) of Formula (I) and a curing amount of a resin or a catalyst amount of a catalyst and/or a cure accelerating amount of an accelerating agent.Type: ApplicationFiled: April 21, 2011Publication date: February 21, 2013Applicant: DOW GLOBAL TECHNOLOGIES LLCInventors: Robert E. Hefner, JR., Michael J. Mullins, Michael L. Tulchinsky, Ernesto Occhiello
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Publication number: 20090198008Abstract: It is a main object of the present invention to provide an alkylphenol resin for rubber compounding to obtain a rubber composition having high tackiness, and a rubber composition using the same. The present invention solves the above object by providing a resin for rubber compounding synthesized from a phenol having a para-substituted alkyl group having 1 to 18 carbon atoms and an aldehyde other than formaldehyde.Type: ApplicationFiled: March 8, 2007Publication date: August 6, 2009Applicant: SUMITOMO BAKELITE COMPANY, LTDInventor: Yasunobu Matsumoto
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Patent number: 6864344Abstract: Sulfonated condensation products that are stable in storage and have increased thermal stability are based on aminoplastic formers having at least two amino groups or naphthalene and formaldehyde and, optionally include organic nitrogen bases which additionally contain, as nitrogenous formulation auxiliary agents, compounds of general formula (I) R1—NH—X—Y—R2, wherein R1 and R2 independently represent H, —CH3, —C2H5, —C3H7, —(CH2)n—CH2—; X?—CH2, CO, CS; Y?S, NH, —(CH2)m—; n=0 to 9; m=1 to 4; and/or compounds of general formula (II), wherein Z?—OCH3, —SO3—H, —SO3Na+, —NO2, —NH2, —NH—NH2, —CO2—Na+, —CHO. The mole ratio of aminoplastic formers: formaldehyde: sulfite: nitrogenous formulation auxiliary agents rangin from 1:1.9 to 6.0:1.0 to 2.0:0.01 to 1.5 and/or the mole ratio of naphthalene sulfonic acid: formaldehyde; nitrogenous formulation auxiliary agents equals 1:0.7 to 3.0:0.01 to 1.5. Method for preparing these condensation products of using them, e.g.Type: GrantFiled: September 29, 2000Date of Patent: March 8, 2005Assignee: SKW Polymers GmbHInventors: Uwe Holland, Martin Matzinger, Johann Plank
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Patent number: 6083657Abstract: Phenolic compound (a) is polycondensed with mixed aldehyde (b) consisting essentially of 5-30 mol % of unsaturated aliphatic aldehyde (b-1) and 70-95 mol % of saturated aliphatic aldehyde (b-2) to give alkali-soluble novolak resin (A) as the product of polycondensation reaction. The alkali-soluble novolak resin (A) is used with quinonediazido group containing compound (B) to produce a positive photoresist composition. According to the present invention, there are specifically provided a positive photoresist composition that has high feature integrity in spite of high sensitivity and which yet provides a great depth of focus, a process for producing such positive photoresist composition, as well as an alkali-soluble novolak resin that can advantageously be used in such composition, and a method of forming patterns with high reproducibility using such positive photoresist composition.Type: GrantFiled: January 15, 1999Date of Patent: July 4, 2000Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Shinichi Kono, Yasuo Masuda, Atsushi Sawano, Hayato Ohno, Hidekatsu Kohara, Toshimasa Nakayama
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Patent number: 6015873Abstract: A polyphenol composition is provided comprising trisphenol represented by the following formula (I): ##STR1## wherein R is a methyl group, X is independently an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms or a halogen atom, and m and n are an integer of 0 to 2 which has an excellent balance between heat resistance and water resistance as a curing agent for epoxy resins.Type: GrantFiled: June 26, 1997Date of Patent: January 18, 2000Assignee: Shell Oil CompanyInventors: Mareki Miura, Yoshinobu Ohnuma
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Patent number: 5989391Abstract: A product obtained by reacting a sulfonated amino resin and an amino group-containing substance in a weight ratio of from 1:0.05 to 1:3.Type: GrantFiled: October 27, 1997Date of Patent: November 23, 1999Assignee: Nissan Chemical Industries, Ltd.Inventors: Yoshitane Watanabe, Kiyomi Ema, Takaichi Sugiyama, Hisanobu Urahata, Michie Kaneko
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Patent number: 5719228Abstract: The present invention relates to a glass fiber binding composition having an effective binding amount of an aqueous compatible furan resin mixed with sufficient water to result in a binding composition having from 0.5 to 80% nonvolatile. The aqueous compatible furan resin is the reaction product of a source of ammonia and a first reaction product, the first reaction product being derived from the reaction of an acidic furan resin, a source of reactable formaldehyde, and a formaldehyde scavenger. The invention further pertains to a process of binding glass fibers at junctions of the fibers comprising the steps of providing glass fibers, applying an effect binding amount of the binding composition of the invention to the glass fibers such that the binder is present at a portion of the junctions, and curing the resin at the junctions of the glass fibers.Type: GrantFiled: January 6, 1995Date of Patent: February 17, 1998Assignees: Schuller International, Inc., QO Chemicals Inc.Inventors: Thomas John Taylor, William Henry Kielmeyer, Carl A. Rude
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Patent number: 5534612Abstract: The present invention relates to a glass fiber binding composition having an effective binding amount of an aqueous compatible furan resin mixed with sufficient water to result in a binding composition having from 0.5 to 80% nonvolatile. The aqueous compatible furan resin is the reaction product of a source of ammonia and a first reaction product, the first reaction product being derived from the reaction of an acidic furan resin, a source of reactable formaldehyde, and a formaldehyde scavenger. The invention further pertains to a process of binding glass fibers at junctions of the fibers comprising the steps of providing glass fibers, applying an effect binding amount of the binding composition of the invention to the glass fibers such that the binder is present at a portion of the junctions, and curing the resin at the junctions of the glass fibers.Type: GrantFiled: May 19, 1993Date of Patent: July 9, 1996Assignee: Schuller International, Inc.Inventors: Thomas J. Taylor, William H. Kielmeyer
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Patent number: 5378791Abstract: This invention relates to a process for producing low molecular weight phenol-aldehyde resin which has predominantly 4 phenolic units in a chain and in which the phenolic ring has a substituent R which is an alkyl group and optionally contains methylol groups on either end of the chain, by reacting formaldehyde with p-alkyl phenol in the presence of ammonia as base in a liquid reaction medium. The resins can be used in producing demulsifiers.Type: GrantFiled: May 5, 1993Date of Patent: January 3, 1995Assignee: BP Chemicals LimitedInventors: Michael Lancaster, David J. Moreton, Alexander F. Psaila
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Patent number: 5326665Abstract: A positive type resist composition comprising an alkali-soluble resin and a quinonediazide compound, wherein the alkali-soluble resin containing resin (A) is obtainable through a condensation reaction with at least one phenol compound represented by the following general formula (I): ##STR1## wherein R.sub.1 to R.sub.3 independently of one another each represent a hydrogen atom or an alkyl or alkoxy group having 1-4 carbon atoms and k represents 1 or 2, at least one compound represented by the following general formula (II): ##STR2## wherein R.sub.4 represents a hydrogen atom, an alkyl group having 1-4 carbon atoms or a phenyl group, R.sub.5 to R.sub.7 independently of one another each represent a hydrogen atom or an alkyl or alkoxy group having 1-4 carbon atoms and n represents 1 or 2, and an aldehyde compound. This composition is excellent in the balance between performances such as sensitivity, heat resistance and profile, and is free from scum.Type: GrantFiled: March 1, 1993Date of Patent: July 5, 1994Assignee: Sumitomo Chemical Company, LimitedInventors: Haruyoshi Osaki, Hiroshi Moriuma, Yasunori Uetani
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Patent number: 5319063Abstract: A phenolic resin can be obtained by a condensation reaction between a specific trifunctional aromatic compound and a phenolic compound. This resin can be reacted with a curing agent such as a hexamine to give cured articles having excellent heat resistance, electrical properties, wear resistance and chemical resistance, and the phenolic resin is also much more excellent in curing reactivity as compared with conventional techniques.Type: GrantFiled: January 15, 1993Date of Patent: June 7, 1994Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Shinji Ando, Yukio Fukui, Shigeru Iimuro
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Patent number: 5216112Abstract: A phenolic resin can be obtained by a condensation reaction between a specific trifunctional aromatic compound and a phenolic compound. This resin can be reacted with a curing agent such as a hexamine to give cured articles having excellent heat resistance, electrical properties, wear resistance and chemical resistance, and the phenolic resin is also much more excellent in curing reactivity as compared with conventional techniques.Type: GrantFiled: August 15, 1991Date of Patent: June 1, 1993Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Shinji Ando, Yukio Fukui, Shigeru Iimuro
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Patent number: 5216111Abstract: An essentially aromatic alkali soluble novolak resin comprising the product resulting from the acid condensation of an aromatic aldehyde and a phenol where the resin has a molecular weight in excess of 1500 and a glass transition temperature in excess of 125.degree. C. If desired, the aromatic novolak resin may be blended with a conventional novolak resin to regulate the glass transition temperature of the resin. The aromatic novolak resin and blends formed therefrom are especially suitable as coating resins and are useful for the formation of photoresist coating compositions.Type: GrantFiled: October 22, 1990Date of Patent: June 1, 1993Assignee: Shipley Company Inc.Inventor: Anthony Zampini
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Patent number: 5095076Abstract: Preparation of conductive polymers, particularly polyanilines having good solubility in organic solvents and high electrical conductivity, by providing a mixture of aniline, dianiline and a flexible diamine such as 1,3-bis (3-aminophenoxy)benzene or triethylene tetramine. The mixture is reacted in the presence of an oxidant such as ammonium persulfate and a protonic (Bronsted) acid, e.g. tosic acid, to polymerize the mixture and form a conductive polyaniline in which the conjugation is interrupted by an intermediate diamine group, and which renders the resulting polymer more flexible than polyaniline per se. The conductive polymer so produced also has terminal primary amino groups which aid solubility and which are further reactive. The conductive polyaniline product of the invention can be blended with non-conductive resins such as polyimides to provide cured conductive resin blends having good mechanical properties.Type: GrantFiled: November 5, 1990Date of Patent: March 10, 1992Assignee: Lockheed CorporationInventors: Sandra K. Clement, Deanne P. Yamato, Randy E. Cameron
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Patent number: 4990590Abstract: An anionic emulsifier obtained from the reaction products of an alkyl phenol, polyamine, and formaldehyde or of an alkyl phenol, fatty acid/polyamine condensate, and formaldehyde followed by the reaction of such products with acrylic acid, and the uses of the emulsifier in anionic bituminous emulsions and paving slurry seal mixtures are disclosed.Type: GrantFiled: November 27, 1989Date of Patent: February 5, 1991Assignee: Westvaco CorporationInventor: Peter Schilling
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Patent number: 4990592Abstract: An anionic emulsifier obtained from the reaction products of an alkyl phenol, polyamine, and formaldehyde or of an alkyl phenol, fatty acid/polyamine condensate, and formaldehyde followed by the reaction of such products with acrylic acid, and the uses of the emulsifier in anionic bituminous emulsions and paving slurry seal mixtures are disclosed.Type: GrantFiled: November 27, 1989Date of Patent: February 5, 1991Assignee: Westvaco CorporationInventor: Peter Schilling
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Patent number: 4990591Abstract: An anionic emulsifier obtained from the reaction products of an alkyl phenol, polyamine, and formaldehyde or of an alkyl phenol, fatty acid/polyamine condensate, and formaldehyde followed by the reaction of such products with acrylic acid, and the uses of the emulsifier in anionic bituminous emulsions and paving slurry seal mixtures are disclosed.Type: GrantFiled: April 7, 1989Date of Patent: February 5, 1991Assignee: Westvaco CorporationInventor: Peter Schilling
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Patent number: 4722991Abstract: A terpolymer is prepared from phenol, furfuryl alcohol and formaldehyde wherein a substantial amound of the furfuryl alcohol is catalytically reacted by means of a water soluble multivalent metal salt catalyst, and wherein the reaction is carried out under essentially hydrous conditions.Type: GrantFiled: May 23, 1986Date of Patent: February 2, 1988Assignee: Acme Resin CorporationInventor: David R. Armbruster
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Patent number: 4713294Abstract: A foundry shell core and mold composition comprises particulate matter coated with a curable phenolic-furan resin. The process for making the resin coated particulate matter substantially eliminates the sue of hexamethylene tetramine.Type: GrantFiled: May 23, 1986Date of Patent: December 15, 1987Assignee: Acme Resin CorporationInventors: David R. Armbruster, Calvin K. Johnson
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Patent number: 4680375Abstract: Tricarbocyanine polymeric dyes have formulae I and II: ##STR1## where Y can be ##STR2## --S--, --Se-- or --O--, A can be ##STR3## in which R.sup.19 can be alkyl or --Cl, and p can be 0 or 1, R.sup.6 and R.sup.7 independently can be alkyl of (C.sub.1 -C.sub.30), preferably (C.sub.1 -C.sub.18),R.sup.4 and R.sup.5 independently can be --H, C.sub.6 H.sub.5 SO.sub.2 --, or CF.sub.3 SO.sub.2 --,Z can be --SO.sub.2 --, --CH.sub.2).sub.m, or vinylene,W can be I.sup.-, Br.sup.-, Cl.sup.-, ClO.sub.4.sup.-, PECHS.sup.- (polyethylcyclohexylsulfonate), F.sub.3 CSO.sub.3.sup.- (trifluoromethanesulfonate), or other commonly used dye anions,m is an integer of 1 to 20, andn is an integer of 5 to 10,000.Type: GrantFiled: March 11, 1985Date of Patent: July 14, 1987Assignee: Minnesota Mining and Manufacturing CompanyInventor: Mohamed A. Elmasry
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Patent number: 4626569Abstract: The process and product derived therefrom use the moldable composition derived from intimate co-reacted mixtures of powder or otherwise blendable form of 20-80% by weight of a phenolic-furfuraldehyde Novolac resin and of 20-80% by weight of a phenolic-aldehyde resol resin dispersed in water, either in solution or suspension, the percentages being based on the combined weight of the Novolac and resol resins, and the aldehyde in said Novolac resin comprising at least 50 molar percent, preferably substantially 100 percent, furfuraldehyde. The composition advantageously contains an amine such as hexamethylenetetramine ("hexa") in an amount equivalent to 1-15%, preferably 2-10% of hexamethylenetetramine based on the total amount of phenolic component. The composition is made by adding the preformed phenol-furfuraldehyde Novolac to the resol resin prior to dehydration of the resol resin to produce a grafted polymerization product of improved properties.Type: GrantFiled: October 1, 1985Date of Patent: December 2, 1986Assignee: Plastics Engineering CompanyInventors: Phillip A. Waitkus, Louis L. Korb
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Patent number: 4500691Abstract: Phenol-novolaks containing amino groups of formulas VI and VII ##STR1## wherein R.sup.1 is halogen, nitro, alkyl, alkoxy or phenyl, R.sup.2 is hydrogen, alkyl, cycloalkyl, phenyl or furfuryl, R.sup.3 is hydrogen or alkyl, R.sup.4 and R.sup.5 independently are alkyl, halogen, nitro or cyano, and x is 1 to 8, are obtained by reacting the corresponding phenol-novolak with an aldehyde or ketone of formula II ##STR2## and with a substituted aniline of formula III or IV ##STR3## in a molar ratio of 1 mol of phenol-novolak to 2 mols of compound of formula II and to 2 mols of compound of formula III or IV in an acid medium at a pH value of 0.5 to 3.0. The phenol-novolaks containing amino groups are useful curing agents for epoxy resins and are also suitable as starting compounds for the preparation of epoxy resins.Type: GrantFiled: January 6, 1984Date of Patent: February 19, 1985Assignee: Ciba-Geigy CorporationInventors: Friedrich Stockinger, Theobald Haug
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Patent number: 4500690Abstract: Heat resistant thermosetting prepolymers are prepared by reacting one or more methylated pyridines or pyrazines with one or more aromatic dialdehydes, and isopropenyl phenols. The prepolymers can be further reacted with bismaleimides to make prepolymers with lower cure temperatures and faster cure rates. The total number of methyl groups on the pyridine or pyrazine can vary from 2 to 4. The prepolymers are cured to produce heat resistant polymers and laminates with conventional fibers such as carbon fibers.Type: GrantFiled: May 11, 1984Date of Patent: February 19, 1985Assignee: The Dow Chemical CompanyInventor: Randy J. LaTulip
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Patent number: 4454298Abstract: A granular or powdery resin which is a condensation product of a phenol and an aldehyde and optionally a nitrogen-containing compound having at least two active hydrogens, said granular or powdery resin being characterized by(A) containing spherical primary particles and secondary particles resulting from the agglomeration of the primary particles, each of said particles having a particle diameter of 0.1 to 150 microns,(B) having such a size that at least 50% by weight thereof can pass through a 100 Tyler mesh sieve,(C) having a free phenol content, determined by liquid chromatography, of not more than 500 ppm, and(D) having a methanol solubility (S) of more than 20% by weight when about 10 g of the resin is heated under reflux in 500 ml of substantially anhydrous methanol.Type: GrantFiled: December 23, 1982Date of Patent: June 12, 1984Assignee: Kanebo Ltd.Inventors: Hiroaki Koyama, Shigeo Shimizu
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Patent number: 4414379Abstract: A granular or powdery nitrogen-containing phenol-aldehyde copolymer resin which is a condensation product of a phenol, a nitrogen-containing compound having at least two active hydrogen atoms and an aldehyde, said granular or powdery resin being characterized by(A) containing spherical primary particles and secondary particles resulting from the agglomeration of the primary particles, each of said particles having a particle diameter of 0.1 to 100 microns,(B) having such a size that at least 50% by weight thereof can pass through a 150 Tyler mesh sieve,(C) having a free phenol content, determined by liquid chromatography, of not more than 50 ppm, and(D) having a D.sub.960-1020 /D.sub.1450-1500 ratio of from 0.1 to 2.0 in its infrared absorption spectrum.Type: GrantFiled: June 16, 1982Date of Patent: November 8, 1983Assignees: Kanebo Ltd., Mitsubishi Chemical Industries LimitedInventors: Hiroaki Koyama, Shigeo Shimizu
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Patent number: 4404334Abstract: The present invention comprises a new phenolic-aldehyde based resinous, thermosetting polyol and a method for its production. According to the invention, phenol is condensed using acid catalysis, under freely evaporative atmospheric conditions with a molar excess of aldehyde, in the presence of polyhydroxyl component.Type: GrantFiled: November 18, 1982Date of Patent: September 13, 1983Assignee: Georgia-Pacific CorporationInventor: Leopold F. Bornstein
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Patent number: 4309527Abstract: Flame retardant polymer resins formed by an acid condensation reaction from a mixture of resorcinol and furfural with a molar excess of the aldehyde. In one particular embodiment the resin is formed of a mixture of two prepolymer solutions with at least a boric acid catalyst, one or both of the prepolymer solutions being an acid-condensation reaction product of resorcinol and furfural with excess aldehyde functionality, or one of the prepolymers being a mix of substantially unreacted resorcinol and furfural with a slight molar excess of aldehyde.Type: GrantFiled: February 9, 1981Date of Patent: January 5, 1982Assignee: Fiber Materials, Inc.Inventors: Lawrence E. McAllister, Herbert Dietrich
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Patent number: 4187368Abstract: For the production of a powder-like furan resin use is made of a mixture of a ketone pertaining to the furan series, phenol-formaldehyde resin and, if desired, furfurol taken in a weight ratio of 10:3- 15:2-5 respectively. The mixture of said components is heated to a temperature within the range of from 130.degree. to 200.degree. C., whereupon the desired product is formed. The process may be conducted in the presence of a catalyst comprising a mixture of tin dichloride and hexamethylene diamine.The resulting powder-like furna resin is resistant against highly-aggressive media at a temperature of up to 120.degree. C.; it is also resistant against the effect of oxidizing agents at a temperature of up to 80.degree. C. Martens yield temperature of the powder-like furna resin of the present invention is as high as 300.degree. C. The resin yield is as high as 93%.Type: GrantFiled: June 26, 1978Date of Patent: February 5, 1980Inventors: Ildgam A. Bekbulatov, Juldash Mamatov, Gennady D. Varlamov, Shavkat Madaliev, Valery M. Gaibov