With Reactant Having Only Carbon And Hydrogen Atoms Or Only Carbon, Hydrogen, And Halogen Atoms Patents (Class 528/160)
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Patent number: 6770107Abstract: A curable resin composition comprises a poly(arylene ether), an acryloyl monomer, an allylic monomer, and an abrasive filler. The composition tolerates high filler contents, cures rapidly, and exhibits excellent toughness after curing. Useful articles prepared from the composition include grinding wheels and cut-off wheels having good wear characteristics.Type: GrantFiled: January 30, 2003Date of Patent: August 3, 2004Assignee: General Electric CompanyInventors: Erich Otto Teutsch, Gary William Yeager, Kenneth Paul Zarnoch, Steven William Webb, Hua Guo
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Patent number: 6593391Abstract: A curable resin composition comprises a poly(arylene ether), an acryloyl monomer, an allylic monomer, and an abrasive filler. The composition tolerates high filler contents, cures rapidly, and exhibits excellent toughness after curing. Useful articles prepared from the composition include grinding wheels and cut-off wheels having good wear characteristics.Type: GrantFiled: March 27, 2001Date of Patent: July 15, 2003Assignee: General Electric CompanyInventors: Erich Otto Teutsch, Gary William Yeager, Kenneth Paul Zarnoch, Steven William Webb, Hua Guo
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Patent number: 6200479Abstract: The invention is for a process of removing acid salt contaminants from a resin solution. The process comprises providing an organic solution of a phenolic resin having a portion of its phenolic hydroxyl groups condensed with an acid halide in the presence of a base catalyst. The organic solutions is then contacted with a strong acid cation exchange resin and a base anion exchange resin for a time sufficient to remove essentially all of said acid salt contaminants. Acid salt contamination is reduced to a level below normal detection limits.Type: GrantFiled: January 14, 1997Date of Patent: March 13, 2001Assignee: Shipley Company, L.L.C.Inventors: Anthony Zampini, Harold F. Sandford
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Patent number: 5792826Abstract: A process for producing a highly reactive low-viscosity modified phenolic resin comprising the steps of polycondensating a petroleum heavy oil or pitch, a formaldehyde polymer, and a phenol in the presence of an acid catalyst to prepare a modified phenolic resin; and reacting the resultant modified phenolic resin with the phenols at a temperature higher than 120.degree. C. and not more than 200.degree. C. in the presence of the acid catalyst to lower the molecular weight of the modified phenolic resin. The highly reactive low-viscosity modified phenolic resin obtained according to this process has high reactivity with epoxy resins and low resin melt viscosity. In addition, this resin can be used for producing a molding material having good moldability and considerably low moisture absorption when combined with an epoxy resin.Type: GrantFiled: February 7, 1997Date of Patent: August 11, 1998Assignee: Kashima Oil Co. Ltd.Inventors: Masao Tashima, Hiromi Miyasita, Makoto Hasegawa, Kaneyoshi Oyama, Tomoaki Fujii
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Patent number: 5368934Abstract: A composite material wherein a mixture of a phenolic or furan resin and an inorganic filler as matrix materials is incorporated in an inorganic fiber or heat-resistant organic fiber in the form of a long fiber bundle. The composite material has excellent characteristics such as heat resistance, strength and alkali resistance. The present invention can provide substitutes used in place of concrete reinforcing steel bars or steel frames which can be used in structures for building and civil engineering.Type: GrantFiled: July 19, 1993Date of Patent: November 29, 1994Assignees: Shimizu Corporation, Yamato Refractories & Co., Ltd.Inventors: Takayoshi Torii, Minoru Sugita, Toshiyuki Tachikawa
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Patent number: 5334674Abstract: Copolycondensation of a hydroxyl group-containing naphthalene and xylene with an aldehyde compound gives a polyhydroxy aromatic compound. The hydroxyl group-containing naphthalene comprises at least one of naphthols and dihydroxynaphthalenes. In the polyhydroxy aromatic compound, the proportions of the naphthalene unit and xylene unit are 95 to 50:5 to 50 (mole percent), and each molecule contains 2 to 20 naphthalene units. The polyhydroxy aromatic compound is useful as an epoxy resin curing agent. Reaction of the polyhydroxy aromatic compound with an epihalohydrin gives an epoxy resin. An epoxy resin composition can be prepared from the epoxy resin and a curing agent.Type: GrantFiled: June 18, 1992Date of Patent: August 2, 1994Assignees: Dai-Ichi Kogyo Seiyaku Co., Ltd., Nitto Denko CorporationInventors: Akihiro Naka, Shuichi Ito, Shinya Akizuki, Kiyoshi Saito
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Patent number: 5270436Abstract: A polyester for electrophotography derived from(a) at least one component selected from tri- or tetra-basic acid components and tri- or tetra-hydric alcohols;(b) at least one component selected from dibasic carboxylic acids and lower alkyl esters thereof; and(c) at least one component selected from aromatic diols and alicyclic diolswherein the proportion of x (mole %) of component (a) to the whole acid components and the proportion y (mole %) of component (c) to the whole acid components satisfies the following formulae (1) and (2):y<(133m+51.5n) log x+(60m+25.43n) (1)y>(253m+170n) log x-(176m+162n) (2)wherein 0<y<100, 0.5<x<50 0.ltoreq.y.ltoreq.100, 0.5.ltoreq.x.ltoreq.50, m is a proportion of the tetrabasic acid or alcohol in component (a) (mole %), n is a proportion of the tribasic acid or alcohol in component (a) (mole %), and m+n=1. The polyester possesses a good resistance to off-setting and good grinding characteristics.Type: GrantFiled: June 6, 1991Date of Patent: December 14, 1993Assignee: Mitsubishi Rayon Company Ltd.Inventors: Shinji Kubo, Noriyuki Tajiri, Hitoshi Iwasaki, Masayuki Takyu, Masahiro Itoh, Hirokazu Ito
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Patent number: 5234795Abstract: A block copolymer novolak resin composition comprising at least one unit of the reaction product of an alkali-soluble phenolic polymer and a reactive ortho, ortho bonded oligomer having the formula: ##STR1## wherein x is from 2 to 7; wherein R is selected from hydrogen a lower alkyl group or lower alkoxy group having 1-4 carbon atoms and a halogen group; and Y.sub.1 is either a hydroxyl group; an alkoxy group or a halogen group; and Y.sub.2 is hydrogen, alkyl, alkoxy, halogen, hydroxyl, --CH.sub.2 OH, --CH.sub.2 -- halogen, or --CH.sub.2 --alkoxy group.Type: GrantFiled: November 23, 1992Date of Patent: August 10, 1993Assignee: OCG Microelectronic Materials, Inc.Inventors: Alfred T. Jeffries, III, Kenji Honda, Andrew J. Blakeney, Sobhy Tadros
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Patent number: 5232819Abstract: Block phenolic oligomers of the formula (I): ##STR1## These may be reacted alone or with selected phenolic monomers during or after the formation of a phenolic novolak resin thereby said resin having at least one unit of formula (II): ##STR2##Type: GrantFiled: December 3, 1992Date of Patent: August 3, 1993Assignee: OCG Microelectronic Materials, Inc.Inventors: Alfred T. Jeffries, III, Kenji Honda, Andrew J. Blakeney, Sobhy Tadros
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Patent number: 5120817Abstract: An epoxy resin composition comprises an vicinal polyepoxide and a Mannich condensation reaction product curing agent. The curing agent is the Mannich condensation reaction product of a phenol, formaldehyde and a polyoxyethylenediamine of the formula:NH.sub.2 (CH.sub.2 CH.sub.2 O).sub.x --CH.sub.2 CH.sub.2 NH.sub.2,and wherein: x ranges from 1 to 3. These epoxy resin compositions are useful in coatings, adhesives, encapsulations and composite matrices.Type: GrantFiled: February 27, 1991Date of Patent: June 9, 1992Assignee: Texaco Chemical CompanyInventors: George P. Speranza, Harold G. Waddill, Jiang-Jen Lin
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Patent number: 5053479Abstract: A phenolic novolak resin comprising the product of a condensation reaction of an aldehyde comprising a haloacetaldehyde source or a mixture of a haloacetaldehyde source and a formaldehyde source with a phenolic monomer comprising at least one compound of the formula: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are individually selected from hydrogen or a one to four carbon alkyl group and wherein the ratio of total carbon atoms in the sum of R.sub.1, R.sub.2 and R.sub.3 to the total number of phenolic nuclei in said resin is from about 0.5:1 to about 1.5:1 in the presence of a solvent; said resin made by employing a molar ratio of total aldehyde to total phenolic monomers from about 0.33:1 to about 0.70:1. These phenolic resins are suitable for use in light-sensitive compositions (e.g. positive-working photoresists).Type: GrantFiled: June 18, 1990Date of Patent: October 1, 1991Assignee: OCG Microelectronic Materials, Inc.Inventors: Andrew J. Blakeney, Thomas Sarubbi, Joseph J. Sizensky
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Patent number: 4920185Abstract: The present invention relates to a polyvalent metal-bound carboxyl-modified p-substituted phenol-xylene-formaldehyde resin composition produced by binding with a polyvalent metal a p-substituted phenol-xylene-formaldehyde co-condensate containing a carboxyl group, to produce a color developer for pressure-sensitive recording paper. The polyvalene metal is selected from the group magnesium, aluminum, calcium, cadmium, zinc, nickel and manganese.Type: GrantFiled: January 27, 1989Date of Patent: April 24, 1990Assignee: Sumitomo Durez Company, Ltd.Inventors: Yukio Tokunaga, Yukio Saeki
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Patent number: 4920186Abstract: The present invention relates to a polyvalent metal-bound carboxyl-modified p-alkylphenol-mesitylene-formaldehyde resin composition produced by binding with a polyvalent metal a -alkylphenol-mesitylene-formaldehyde co-condensate containing a carboxyl group, to produce a color developer for pressure-sensitive recording paper.Type: GrantFiled: January 12, 1989Date of Patent: April 24, 1990Assignee: Sumitomo Durez Company, Ltd.Inventors: Yukio Tokunaga, Yukio Saeki
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Patent number: 4816498Abstract: Oligomeric condensation products of certain dialdehydes and phenols can be end-capped with a vinylbenzyl moiety and certain other moieties, especially alkyl groups, to afford thermosetting resins particularly valuable in making laminated circuit boards. Resins prepared by the reaction of 1 molar proportion of glyoxal with from 3 to 4 molar proportions of phenol and end-capped with from 50 to 85% vinylbenzyl groups with the remainder being alkyls of 1 through 11 carbon atoms are particularly useful.Type: GrantFiled: November 30, 1987Date of Patent: March 28, 1989Assignee: Allied-Signal Inc.Inventors: Joseph J. Zupancic, Jean M. J. Frechet, Andrew M. Zweig, Jeffery P. Conrad
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Patent number: 4395498Abstract: High temperature phenolic resins suited for use for example in an automotive or similar brake or in a clutch, are provided by a blend of the reaction product of a phenolic compound, naphthalenic compound, and formaldehyde with selected prior art resins. The mole ratio range of naphthalenic compound: phenolic compound: formaldehyde is about 1: 1:0.8-5:1-10. Friction particles and friction elements can be prepared from said reaction product optionally being blended with said selected prior art resins. An improved method of making friction elements is also provided which uses such binder.Type: GrantFiled: September 18, 1981Date of Patent: July 26, 1983Assignee: Minnesota Mining and Manufacturing CompanyInventor: Judith L. Benham
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Patent number: 4350623Abstract: The varnish comprises a phenolated naphthalene formaldehyde resin having a molecular weight from 350 to 500 and a combined phenol content from 37 to 54%, a curing agent for the resin, and a lower secondary alcohol as the solvent, the varnish containing about 50% w/w of the resin. The varnish can be used to form glasscloth laminates for the production of printed circuit boards, copper clad laminates and blading for turbines.Type: GrantFiled: February 19, 1981Date of Patent: September 21, 1982Assignee: Coal Industry (Patents) LimitedInventors: Joseph G. Robinson, Sally A. Brain
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Patent number: 4273891Abstract: Hydroxy aromatic compositions containing (a) a hydroxyl group bonded directly to a carbon of an aromatic nucleus, (b) a hydrocarbon-based substituent of at least about 50 aliphatic carbon atoms bonded directly to a carbon atom of an aromatic nucleus, (c) at least one methylol or lower hydrocarbyl substituted methylol substituent bonded directly to a carbon atom of an aromatic nucleus, and not having any alkylene linkages between carbon atoms of two aromatic nuclei are useful as additives for normally liquid fuels and lubricating oils. These hydroxy aromatic compositions are also useful as intermediates for preparing other additives for fuels and lubricants. Typical hydroxy aromatic compositions of the present invention are formed by reaction of formaldehyde with an alkenyl- or alkyl-substituted phenol wherein the alkyl or alkenyl substituent contains an average of about 50 carbon atoms.Type: GrantFiled: September 6, 1977Date of Patent: June 16, 1981Assignee: The Lubrizol CorporationInventors: John F. Pindar, Jerome M. Cohen, Charles P. Bryant
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Patent number: 4187369Abstract: The process according to the present invention comprises a continuous polycondensation of the anthracene fraction of coal tar boiling within the range of from 270.degree. C. to 350.degree. C., phenol and formaldehyde at a weight ratio between the components of 1:3-4:1-1.2 in the presence of 0.5 to 1.2% by weight of an acidic catalyst at a supply rate of a mixture of said components of 500-550 g/hr.The present invention makes it possible to continuously prepare the desired product, whereby its output from a unit production volume is substantially increased. The product has a high curing rate and a high coke value.Type: GrantFiled: September 6, 1978Date of Patent: February 5, 1980Inventors: Rudolf Z. Pavlikov, Natalya V. Shorygina, Vladimir A. Strupinsky, Anatoly A. Kruglikov, Jury G. Farbshtein, Iosif L. Klipinitser