With Reactant Having Only Carbon And Hydrogen Atoms Or Only Carbon, Hydrogen, And Halogen Atoms Patents (Class 528/160)
  • Patent number: 6770107
    Abstract: A curable resin composition comprises a poly(arylene ether), an acryloyl monomer, an allylic monomer, and an abrasive filler. The composition tolerates high filler contents, cures rapidly, and exhibits excellent toughness after curing. Useful articles prepared from the composition include grinding wheels and cut-off wheels having good wear characteristics.
    Type: Grant
    Filed: January 30, 2003
    Date of Patent: August 3, 2004
    Assignee: General Electric Company
    Inventors: Erich Otto Teutsch, Gary William Yeager, Kenneth Paul Zarnoch, Steven William Webb, Hua Guo
  • Patent number: 6593391
    Abstract: A curable resin composition comprises a poly(arylene ether), an acryloyl monomer, an allylic monomer, and an abrasive filler. The composition tolerates high filler contents, cures rapidly, and exhibits excellent toughness after curing. Useful articles prepared from the composition include grinding wheels and cut-off wheels having good wear characteristics.
    Type: Grant
    Filed: March 27, 2001
    Date of Patent: July 15, 2003
    Assignee: General Electric Company
    Inventors: Erich Otto Teutsch, Gary William Yeager, Kenneth Paul Zarnoch, Steven William Webb, Hua Guo
  • Patent number: 6200479
    Abstract: The invention is for a process of removing acid salt contaminants from a resin solution. The process comprises providing an organic solution of a phenolic resin having a portion of its phenolic hydroxyl groups condensed with an acid halide in the presence of a base catalyst. The organic solutions is then contacted with a strong acid cation exchange resin and a base anion exchange resin for a time sufficient to remove essentially all of said acid salt contaminants. Acid salt contamination is reduced to a level below normal detection limits.
    Type: Grant
    Filed: January 14, 1997
    Date of Patent: March 13, 2001
    Assignee: Shipley Company, L.L.C.
    Inventors: Anthony Zampini, Harold F. Sandford
  • Patent number: 5792826
    Abstract: A process for producing a highly reactive low-viscosity modified phenolic resin comprising the steps of polycondensating a petroleum heavy oil or pitch, a formaldehyde polymer, and a phenol in the presence of an acid catalyst to prepare a modified phenolic resin; and reacting the resultant modified phenolic resin with the phenols at a temperature higher than 120.degree. C. and not more than 200.degree. C. in the presence of the acid catalyst to lower the molecular weight of the modified phenolic resin. The highly reactive low-viscosity modified phenolic resin obtained according to this process has high reactivity with epoxy resins and low resin melt viscosity. In addition, this resin can be used for producing a molding material having good moldability and considerably low moisture absorption when combined with an epoxy resin.
    Type: Grant
    Filed: February 7, 1997
    Date of Patent: August 11, 1998
    Assignee: Kashima Oil Co. Ltd.
    Inventors: Masao Tashima, Hiromi Miyasita, Makoto Hasegawa, Kaneyoshi Oyama, Tomoaki Fujii
  • Patent number: 5368934
    Abstract: A composite material wherein a mixture of a phenolic or furan resin and an inorganic filler as matrix materials is incorporated in an inorganic fiber or heat-resistant organic fiber in the form of a long fiber bundle. The composite material has excellent characteristics such as heat resistance, strength and alkali resistance. The present invention can provide substitutes used in place of concrete reinforcing steel bars or steel frames which can be used in structures for building and civil engineering.
    Type: Grant
    Filed: July 19, 1993
    Date of Patent: November 29, 1994
    Assignees: Shimizu Corporation, Yamato Refractories & Co., Ltd.
    Inventors: Takayoshi Torii, Minoru Sugita, Toshiyuki Tachikawa
  • Patent number: 5334674
    Abstract: Copolycondensation of a hydroxyl group-containing naphthalene and xylene with an aldehyde compound gives a polyhydroxy aromatic compound. The hydroxyl group-containing naphthalene comprises at least one of naphthols and dihydroxynaphthalenes. In the polyhydroxy aromatic compound, the proportions of the naphthalene unit and xylene unit are 95 to 50:5 to 50 (mole percent), and each molecule contains 2 to 20 naphthalene units. The polyhydroxy aromatic compound is useful as an epoxy resin curing agent. Reaction of the polyhydroxy aromatic compound with an epihalohydrin gives an epoxy resin. An epoxy resin composition can be prepared from the epoxy resin and a curing agent.
    Type: Grant
    Filed: June 18, 1992
    Date of Patent: August 2, 1994
    Assignees: Dai-Ichi Kogyo Seiyaku Co., Ltd., Nitto Denko Corporation
    Inventors: Akihiro Naka, Shuichi Ito, Shinya Akizuki, Kiyoshi Saito
  • Patent number: 5270436
    Abstract: A polyester for electrophotography derived from(a) at least one component selected from tri- or tetra-basic acid components and tri- or tetra-hydric alcohols;(b) at least one component selected from dibasic carboxylic acids and lower alkyl esters thereof; and(c) at least one component selected from aromatic diols and alicyclic diolswherein the proportion of x (mole %) of component (a) to the whole acid components and the proportion y (mole %) of component (c) to the whole acid components satisfies the following formulae (1) and (2):y<(133m+51.5n) log x+(60m+25.43n) (1)y>(253m+170n) log x-(176m+162n) (2)wherein 0<y<100, 0.5<x<50 0.ltoreq.y.ltoreq.100, 0.5.ltoreq.x.ltoreq.50, m is a proportion of the tetrabasic acid or alcohol in component (a) (mole %), n is a proportion of the tribasic acid or alcohol in component (a) (mole %), and m+n=1. The polyester possesses a good resistance to off-setting and good grinding characteristics.
    Type: Grant
    Filed: June 6, 1991
    Date of Patent: December 14, 1993
    Assignee: Mitsubishi Rayon Company Ltd.
    Inventors: Shinji Kubo, Noriyuki Tajiri, Hitoshi Iwasaki, Masayuki Takyu, Masahiro Itoh, Hirokazu Ito
  • Patent number: 5234795
    Abstract: A block copolymer novolak resin composition comprising at least one unit of the reaction product of an alkali-soluble phenolic polymer and a reactive ortho, ortho bonded oligomer having the formula: ##STR1## wherein x is from 2 to 7; wherein R is selected from hydrogen a lower alkyl group or lower alkoxy group having 1-4 carbon atoms and a halogen group; and Y.sub.1 is either a hydroxyl group; an alkoxy group or a halogen group; and Y.sub.2 is hydrogen, alkyl, alkoxy, halogen, hydroxyl, --CH.sub.2 OH, --CH.sub.2 -- halogen, or --CH.sub.2 --alkoxy group.
    Type: Grant
    Filed: November 23, 1992
    Date of Patent: August 10, 1993
    Assignee: OCG Microelectronic Materials, Inc.
    Inventors: Alfred T. Jeffries, III, Kenji Honda, Andrew J. Blakeney, Sobhy Tadros
  • Patent number: 5232819
    Abstract: Block phenolic oligomers of the formula (I): ##STR1## These may be reacted alone or with selected phenolic monomers during or after the formation of a phenolic novolak resin thereby said resin having at least one unit of formula (II): ##STR2##
    Type: Grant
    Filed: December 3, 1992
    Date of Patent: August 3, 1993
    Assignee: OCG Microelectronic Materials, Inc.
    Inventors: Alfred T. Jeffries, III, Kenji Honda, Andrew J. Blakeney, Sobhy Tadros
  • Patent number: 5120817
    Abstract: An epoxy resin composition comprises an vicinal polyepoxide and a Mannich condensation reaction product curing agent. The curing agent is the Mannich condensation reaction product of a phenol, formaldehyde and a polyoxyethylenediamine of the formula:NH.sub.2 (CH.sub.2 CH.sub.2 O).sub.x --CH.sub.2 CH.sub.2 NH.sub.2,and wherein: x ranges from 1 to 3. These epoxy resin compositions are useful in coatings, adhesives, encapsulations and composite matrices.
    Type: Grant
    Filed: February 27, 1991
    Date of Patent: June 9, 1992
    Assignee: Texaco Chemical Company
    Inventors: George P. Speranza, Harold G. Waddill, Jiang-Jen Lin
  • Patent number: 5053479
    Abstract: A phenolic novolak resin comprising the product of a condensation reaction of an aldehyde comprising a haloacetaldehyde source or a mixture of a haloacetaldehyde source and a formaldehyde source with a phenolic monomer comprising at least one compound of the formula: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are individually selected from hydrogen or a one to four carbon alkyl group and wherein the ratio of total carbon atoms in the sum of R.sub.1, R.sub.2 and R.sub.3 to the total number of phenolic nuclei in said resin is from about 0.5:1 to about 1.5:1 in the presence of a solvent; said resin made by employing a molar ratio of total aldehyde to total phenolic monomers from about 0.33:1 to about 0.70:1. These phenolic resins are suitable for use in light-sensitive compositions (e.g. positive-working photoresists).
    Type: Grant
    Filed: June 18, 1990
    Date of Patent: October 1, 1991
    Assignee: OCG Microelectronic Materials, Inc.
    Inventors: Andrew J. Blakeney, Thomas Sarubbi, Joseph J. Sizensky
  • Patent number: 4920185
    Abstract: The present invention relates to a polyvalent metal-bound carboxyl-modified p-substituted phenol-xylene-formaldehyde resin composition produced by binding with a polyvalent metal a p-substituted phenol-xylene-formaldehyde co-condensate containing a carboxyl group, to produce a color developer for pressure-sensitive recording paper. The polyvalene metal is selected from the group magnesium, aluminum, calcium, cadmium, zinc, nickel and manganese.
    Type: Grant
    Filed: January 27, 1989
    Date of Patent: April 24, 1990
    Assignee: Sumitomo Durez Company, Ltd.
    Inventors: Yukio Tokunaga, Yukio Saeki
  • Patent number: 4920186
    Abstract: The present invention relates to a polyvalent metal-bound carboxyl-modified p-alkylphenol-mesitylene-formaldehyde resin composition produced by binding with a polyvalent metal a -alkylphenol-mesitylene-formaldehyde co-condensate containing a carboxyl group, to produce a color developer for pressure-sensitive recording paper.
    Type: Grant
    Filed: January 12, 1989
    Date of Patent: April 24, 1990
    Assignee: Sumitomo Durez Company, Ltd.
    Inventors: Yukio Tokunaga, Yukio Saeki
  • Patent number: 4816498
    Abstract: Oligomeric condensation products of certain dialdehydes and phenols can be end-capped with a vinylbenzyl moiety and certain other moieties, especially alkyl groups, to afford thermosetting resins particularly valuable in making laminated circuit boards. Resins prepared by the reaction of 1 molar proportion of glyoxal with from 3 to 4 molar proportions of phenol and end-capped with from 50 to 85% vinylbenzyl groups with the remainder being alkyls of 1 through 11 carbon atoms are particularly useful.
    Type: Grant
    Filed: November 30, 1987
    Date of Patent: March 28, 1989
    Assignee: Allied-Signal Inc.
    Inventors: Joseph J. Zupancic, Jean M. J. Frechet, Andrew M. Zweig, Jeffery P. Conrad
  • Patent number: 4395498
    Abstract: High temperature phenolic resins suited for use for example in an automotive or similar brake or in a clutch, are provided by a blend of the reaction product of a phenolic compound, naphthalenic compound, and formaldehyde with selected prior art resins. The mole ratio range of naphthalenic compound: phenolic compound: formaldehyde is about 1: 1:0.8-5:1-10. Friction particles and friction elements can be prepared from said reaction product optionally being blended with said selected prior art resins. An improved method of making friction elements is also provided which uses such binder.
    Type: Grant
    Filed: September 18, 1981
    Date of Patent: July 26, 1983
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Judith L. Benham
  • Patent number: 4350623
    Abstract: The varnish comprises a phenolated naphthalene formaldehyde resin having a molecular weight from 350 to 500 and a combined phenol content from 37 to 54%, a curing agent for the resin, and a lower secondary alcohol as the solvent, the varnish containing about 50% w/w of the resin. The varnish can be used to form glasscloth laminates for the production of printed circuit boards, copper clad laminates and blading for turbines.
    Type: Grant
    Filed: February 19, 1981
    Date of Patent: September 21, 1982
    Assignee: Coal Industry (Patents) Limited
    Inventors: Joseph G. Robinson, Sally A. Brain
  • Patent number: 4273891
    Abstract: Hydroxy aromatic compositions containing (a) a hydroxyl group bonded directly to a carbon of an aromatic nucleus, (b) a hydrocarbon-based substituent of at least about 50 aliphatic carbon atoms bonded directly to a carbon atom of an aromatic nucleus, (c) at least one methylol or lower hydrocarbyl substituted methylol substituent bonded directly to a carbon atom of an aromatic nucleus, and not having any alkylene linkages between carbon atoms of two aromatic nuclei are useful as additives for normally liquid fuels and lubricating oils. These hydroxy aromatic compositions are also useful as intermediates for preparing other additives for fuels and lubricants. Typical hydroxy aromatic compositions of the present invention are formed by reaction of formaldehyde with an alkenyl- or alkyl-substituted phenol wherein the alkyl or alkenyl substituent contains an average of about 50 carbon atoms.
    Type: Grant
    Filed: September 6, 1977
    Date of Patent: June 16, 1981
    Assignee: The Lubrizol Corporation
    Inventors: John F. Pindar, Jerome M. Cohen, Charles P. Bryant
  • Patent number: 4187369
    Abstract: The process according to the present invention comprises a continuous polycondensation of the anthracene fraction of coal tar boiling within the range of from 270.degree. C. to 350.degree. C., phenol and formaldehyde at a weight ratio between the components of 1:3-4:1-1.2 in the presence of 0.5 to 1.2% by weight of an acidic catalyst at a supply rate of a mixture of said components of 500-550 g/hr.The present invention makes it possible to continuously prepare the desired product, whereby its output from a unit production volume is substantially increased. The product has a high curing rate and a high coke value.
    Type: Grant
    Filed: September 6, 1978
    Date of Patent: February 5, 1980
    Inventors: Rudolf Z. Pavlikov, Natalya V. Shorygina, Vladimir A. Strupinsky, Anatoly A. Kruglikov, Jury G. Farbshtein, Iosif L. Klipinitser