Material Is A Nitrogen-containing Compound Patents (Class 528/182)
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Molded article with selectively varied core layer geometry and hot runner nozzles for producing same
Patent number: 11850779Abstract: A molded article suitable for subsequent blow-molding into a final-shaped container. The article includes a neck portion; a gate portion; and a body portion extending between the neck portion and the gate portion, at least a majority of the body portion having an overall shape which is symmetric about a body axis extending longitudinally through a center of the body portion. The body portion includes an inner exterior layer and an outer exterior layer of a first polymeric material; and a core layer of a second polymeric material disposed between the inner exterior layer and the outer exterior layer. A radial thickness or a material of the core layer is selectively varied to govern non-uniform blow molding of the molded article into the final-shaped container.Type: GrantFiled: June 21, 2018Date of Patent: December 26, 2023Assignee: HUSKY INJECTION MOLDING SYSTEMS LTD.Inventors: Jean-Christophe Witz, Christophe Simon Pierre Beck, Joachims Johannes Niewels, Lee Richard Riddle -
Patent number: 10779429Abstract: A method for forming a flameproof transmitter is disclosed. The transmitter includes a flameproof housing including an interior surface, a display aperture and a shoulder adjacent to the aperture at first end of the housing. A transparent panel including an outer face and a perimeter is inserted into the housing from a second end to threadingly engage a fastener feature located on the interior surface of the housing such that the fastener element contacts the transparent panel and retains the transparent panel against the shoulder. A perimeter interface region between the perimeter of the transparent panel and the interior surface of the flameproof housing creates a perimeter gap that does not exceed a predetermined flameproof gap limit and a face interface region between the outer face of the transparent panel and the shoulder creates a face gap that does not exceed the predetermined flameproof gap limit.Type: GrantFiled: November 13, 2018Date of Patent: September 15, 2020Assignee: Micro Motion, Inc.Inventors: David Clarke, Atul Vasant Deshpande
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Patent number: 10761375Abstract: The present invention provides the following: a photo alignment method-use liquid crystal aligning agent used to obtain a photo alignment method-use liquid crystal alignment film that does not cause bright spots even when negative liquid crystals are used, and that is capable of achieving good after-image characteristics; a liquid crystal alignment film obtained from the liquid crystal aligning agent; and a liquid crystal display element provided with the liquid crystal aligning agent. Provided is the liquid crystal aligning agent which contains a polyimide or polyimide precursor obtained from a reaction between: a tetracarboxylic acid dianhydride represented by formula (1) (in the formula, X1 is as set forth in the present specification) or a derivative thereof; and a diamine component that contains a diamine represented by formula (2) (in the formula, R1, Z1 and n are as set forth in the present specification).Type: GrantFiled: September 13, 2016Date of Patent: September 1, 2020Assignee: NISSAN CHEMICAL INDUSTRIES, LTD.Inventors: Kanako Suzuki, Yuta Kawano, Kohei Goto, Masaaki Katayama
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Patent number: 10246556Abstract: A polyimide polymer is provided. The polyimide polymer includes a repeating unit represented by formula 1.Type: GrantFiled: August 16, 2017Date of Patent: April 2, 2019Assignee: TAIFLEX Scientific Co., Ltd.Inventors: Ching-Hung Huang, Kuang-Ting Hsueh, Chiu-Feng Chen, Yi-Kai Fang, Chun-Cheng Wan
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Patent number: 9754427Abstract: Embodiments of the present disclosure disclose a Black box with Satellite Transmitter (BSAT) for underwater vehicles. The BSAT provides a mission data backup of sunken under water vehicles and it is akin to a black box recorder of aircrafts. The BSAT comprising a sealed enclosure to receive and transmit IR and electromagnetic signals, a Global Positioning System (GPS) with an antenna to provide GPS parameters of the BSAT, a transmit antenna to transmit the GPS parameters and parameters associated with the underwater vehicle, an ejection mechanism to eject the BSAT from the underwater vehicle on detecting a pre-defined condition, by an electronic controller. The electronic controller to perform at least one of sending control signals, communicating using IR transceiver, acquire and store underwater vehicle parameters, identifying an ejection instant, acquiring and storing data GPS parameters, scheduling data transmission through a satellite after ejection of the BSAT from the underwater vehicle.Type: GrantFiled: July 30, 2014Date of Patent: September 5, 2017Assignee: THE DIRECTOR GENERAL, DEFENCE RESEARCH & DEVELOPMENT ORGANISATION (DRDO)Inventors: Varughese Abraham, Mailapalli Nirmala, Prasad Parvathaneni Shiva, Attara Sanjay, Chakraborti Debasish
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Patent number: 9267004Abstract: An object of the present invention is to provide (a) a polyimide precursor solution which is curable at low temperatures (not more than 200° C.) and which has excellent long-term storage stability, (b) a photosensitive resin composition, a photosensitive resin film, a thermosetting resin composition, and a polyimide insulating film, each of which is obtainable from the polyimide precursor solution and each of which is preferably usable as an insulating material for electric and electronic purposes, and (c) a printed wiring board provided with the insulating film. The above object is achievable by use of a polyimide precursor composition solution containing at least a partially imidized polyimide precursor having a urethane bond.Type: GrantFiled: July 15, 2009Date of Patent: February 23, 2016Assignee: KANEKA CORPORATIONInventors: Koji Okada, Yoshihide Sekito
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Publication number: 20150045481Abstract: The present invention relates to a novel diamine compound, wherein two substituents R and R? are introduced asymmetrically, and a polymer thereof. The polymer may have excellent solubility in the organic solvent and allows for easy processibility after imidization, thus giving proper film maintaining superior properties, such as thermal, mechanical, and optical properties for applications in electrical, electronic, or optical materials.Type: ApplicationFiled: December 5, 2012Publication date: February 12, 2015Inventors: Sang Youl Kim, Sun Dal Kim, Im Sik Chung
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Patent number: 8927659Abstract: The invention provides biocompatible resorbable polymers, comprising monomer units having formula (I), formula (II), formula (III) or formula (IV). The polymers degrade over time when implanted in the body, and are useful as components of implantable medical devices.Type: GrantFiled: April 22, 2013Date of Patent: January 6, 2015Assignee: TYRX, Inc.Inventors: Arikha Moses, Satish Pulapura, Arthur Schwartz, Qing Ge, Irene Shatova
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Publication number: 20140343244Abstract: The invention relates to methods and systems for preparing macrocyclic polyester oligomer (MPO) via base catalysis. It is found that base catalysts are effective in the production of MPO, and they reduce the potential for undesired byproducts such as furans (e.g., THF) and acetaldehyde, which result from diol side reactions.Type: ApplicationFiled: March 13, 2014Publication date: November 20, 2014Applicant: Liquid Thermo Plastics, Inc.Inventors: Jimmy Lynn Webb, John Lippert, III, James Mihalich
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Patent number: 8716428Abstract: An fluorinated polyester compound is disclosed. The fluorinated polyester compound can be made by combining ingredients comprising a hydroxyl terminated polyphenyl ether; a carboxylic acid terminated perfluoropolyether; an acid catalyst; and a solvent. A coating solution comprising the fluorinated polyester compound and a method of coating a substrate therewith are also disclosed.Type: GrantFiled: April 10, 2012Date of Patent: May 6, 2014Assignee: Xerox CorporationInventors: Jin Wu, Lanhui Zhang, Lin Ma, David W. Martin
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Publication number: 20140088247Abstract: A crosslinkable aromatic polyester that is formed by polymerizing certain precursor monomers in the presence of a biaromatic crosslinking agent is provided. The crosslinkable aromatic polyester can have a relatively high melting temperature. For example, the melting temperature of the crosslinkable polyester may be from about 200° C. to about 370° C. While having a relatively high melting temperature, the crosslinkable polyester can maintain a relatively low melt viscosity so that it can be readily removed from the polymerization reactor without solidifying therein.Type: ApplicationFiled: September 17, 2013Publication date: March 27, 2014Applicant: Ticona LLCInventor: Kamlesh P. Nair
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Publication number: 20140088284Abstract: A crosslinkable liquid crystalline polymer that is formed by polymerizing a precursor monomer in the presence of an aromatic crosslinking agent is provided.Type: ApplicationFiled: September 17, 2013Publication date: March 27, 2014Applicant: Ticona LLCInventor: Kamlesh P. Nair
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Publication number: 20130266732Abstract: An fluorinated polyester compound is disclosed. The fluorinated polyester compound can be made by combining ingredients comprising a hydroxyl terminated polyphenyl ether; a carboxylic acid terminated perfluoropolyether; an acid catalyst; and a solvent. A coating solution comprising the fluorinated polyester compound and a method of coating a substrate therewith are also disclosed.Type: ApplicationFiled: April 10, 2012Publication date: October 10, 2013Applicant: XEROX CORPORATIONInventors: Jin Wu, Lanhui Zhang, Lin Ma, David W. Martin
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Patent number: 8501897Abstract: The present invention provides a method for producing a liquid-crystalline polyester, which comprises melt-polymerizing monomers in a reactor having a draw outlet to obtain a polymer melt and drawing the polymer melt through the draw outlet, characterized in that the monomers comprise a compound selected from an aromatic hydroxycarboxylic acid and derivatives thereof, a compound selected from an aromatic dicarboxylic acid and derivatives thereof and a compound selected from an aromatic diol, an aromatic hydroxyamine, an aromatic diamine and derivatives thereof; the amount of units derived from a compound containing a 1,2-phenylene and/or a 1,3-phenylene skeleton(s) in the polyester is from 0 to 10 mol %; the melt polymerization is performed in the presence of a heterocyclic compound containing two or more nitrogen atoms; and the polymer melt has a flow initiation temperature of from 220 to 250° C.Type: GrantFiled: July 24, 2012Date of Patent: August 6, 2013Assignee: Sumitomo Chemical Co., Ltd.Inventors: Tomoya Hosoda, Eiji Hosoda, Masanobu Matsubara
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Patent number: 8492500Abstract: The present invention provides a method for producing a liquid-crystalline polyester, the method comprising: a step of melt-polymerizing raw monomers in a melt polymerization vessel to obtain a polymer melt; a step of drawing the polymer melt from the melt polymerization vessel and granulating the polymer melt to obtain a granulate; a step of allowing the granulate to undergo solid phase polymerization in a solid phase polymerization vessel to obtain a solid phase polymer; and a step of making an impact on the solid phase polymerization vessel containing the solid phase polymer, and taking out the solid phase polymer from the solid phase polymerization vessel.Type: GrantFiled: July 24, 2012Date of Patent: July 23, 2013Assignee: Sumitomo Chemical Company, LimitedInventors: Tomoya Hosoda, Eiji Hosoda, Masanobu Matsubara
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Patent number: 8471054Abstract: The invention provides biocompatible resorbable polymers, comprising monomer units having formula (I), formula (II), formula (III) or formula (IV). The polymers degrade over time when implanted in the body, and are useful as components of implantable medical devices.Type: GrantFiled: March 7, 2012Date of Patent: June 25, 2013Assignee: Tyrx, Inc.Inventors: Arikha Moses, Satish Pulapura, Arthur Schwartz, Qing Ge, Irene Shatova
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Patent number: 8445627Abstract: The invention provides new aliphatic diester-di-acid-containing PEA polymer compositions with significant improvement in hydrolytic degradation rates as compared to aliphatic di-acid-containing PEA polymers. The di-acids used in the invention PEA compositions include non-toxic fatty aliphatic homologs. These molecules inherently contain two-ester groups, which easily can be cleaved by biotic (enzymatic) and abiotic hydrolysis. Additional di-acid-type compounds useful for active polycondensation are ?,?-alkylene dicarboxylates composed of short aliphatic non toxic diols and di-acids. In addition, the invention PEA polymer compositions optionally can include a second monomer, such as a C-protected L-lysine-based monomer, to introduce additional chain flexibility into the polymer. The invention PEA polymer compositions are useful for delivery of bioactive agents when administered internally.Type: GrantFiled: March 22, 2007Date of Patent: May 21, 2013Assignee: Medivas, LLCInventors: Ramaz Katsarava, Natia Mazanashvili, Zaza D. Gomurashvili, Turner Daniel Jenkins, Nino Mchedlishvili
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Publication number: 20130059985Abstract: The present invention provides a method for producing a polybenzoxazole precursor having reduced contents of residual aprotic polar solvent and residual halogen without discharging a large amount of waste water during purification. The present invention specifically relates to a method for producing a polybenzoxazole precursor, which comprises synthesizing a polybenzoxazole precursor in an aprotic polar solvent, adding and mixing water and a water-insoluble solvent with the resulting polybenzoxazole precursor solution to still stand the solution, and then separating a water layer from the solution to reduce a content of impurities remaining in the polybenzoxazole precursor.Type: ApplicationFiled: August 30, 2012Publication date: March 7, 2013Applicant: Toho Chemical Industry Co., Ltd.Inventor: Naoya Kutsuzawa
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Publication number: 20130030142Abstract: The present invention provides a method for producing a liquid-crystalline polyester, the method comprising: a step of melt-polymerizing raw monomers in a melt polymerization vessel to obtain a polymer melt; a step of drawing the polymer melt from the melt polymerization vessel and granulating the polymer melt to obtain a granulate; a step of allowing the granulate to undergo solid phase polymerization in a solid phase polymerization vessel to obtain a solid phase polymer; and a step of making an impact on the solid phase polymerization vessel containing the solid phase polymer, and taking out the solid phase polymer from the solid phase polymerization vessel.Type: ApplicationFiled: July 24, 2012Publication date: January 31, 2013Inventors: Tomoya HOSODA, Eiji Hosoda, Masanobu Matsubara
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Publication number: 20130030141Abstract: The present invention provides a method for producing a liquid-crystalline polyester, which comprises melt-polymerizing monomers in a reactor having a draw outlet to obtain a polymer melt and drawing the polymer melt through the draw outlet, characterized in that the monomers comprise a compound selected from an aromatic hydroxycarboxylic acid and derivatives thereof, a compound selected from an aromatic dicarboxylic acid and derivatives thereof and a compound selected from an aromatic diol, an aromatic hydroxyamine, an aromatic diamine and derivatives thereof; the amount of units derived from a compound containing a 1,2-phenylene and/or a 1,3-phenylene skeleton(s) in the polyester is from 0 to 10 mold; the melt polymerization is performed in the presence of a heterocyclic compound containing two or more nitrogen atoms; and the polymer melt has a flow initiation temperature of from 220 to 250° C.Type: ApplicationFiled: July 24, 2012Publication date: January 31, 2013Inventors: Tomoya HOSODA, Eiji HOSODA, Masanobu MATSUBARA
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Publication number: 20120329975Abstract: Disclosed is a method for producing a liquid crystal polyester, which includes the following steps of: (1) melt-polycondensing a compound as a monomer in a polymerization tank to produce a prepolymer; (2) discharging the prepolymer from the polymerization tank in a molten state, and solidifying the prepolymer through cooling to produce a sheet in which a portion having a thickness of 1.6 to 2 mm accounts for 80% by mass or more (of 100% by mass of the entire sheet); (3) crushing the sheet; and (4) subjecting the crushed product to solid-phase polymerization through heating.Type: ApplicationFiled: June 5, 2012Publication date: December 27, 2012Applicant: Sumitomo Chemical Company, LimitedInventors: Tomoya HOSODA, Eiji HOSODA, Masanobu MATSUBARA
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Publication number: 20120244306Abstract: A heat-resistant label containing a liquid crystalline polyester base material, wherein the liquid crystalline polyester in this liquid crystalline polyester base material contains a structural unit represented by the following formula (1), a structural unit represented by the following formula (2) and a structural unit represented by the following formula (3), and wherein the amount of structural units containing a 2,6 naphthalenediyl group is at least 40 mol % based on the total amount of all the structural units: (1) —O—Ar1—CO— (2) —CO—Ar2—CO— and (3) —O—Ar3—O— (wherein, Ar1 represents a 2,6-naphthalenediyl group, a 1,4-phenylene group, or a 4,4?-biphenylylene group; each of Ar2 and Ar3 independently represents a 2,6-naphthalenediyl group, a 1,4-phenylene group, a 1-3-phenylene group, or a 4,4?-biphenylylene group; and hydrogen atoms which are in the group represented by Ar1, Ar2 or Ar3 may be each independently substituted with a halogen atom, an alkyl group having 1 to 10 carbon atoms, or an aryl groType: ApplicationFiled: December 6, 2010Publication date: September 27, 2012Inventors: Tomoya Hosoda, Satoshi Okamoto
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Patent number: 8153837Abstract: The invention provides biocompatible resorbable polymers, comprising monomer units having formula (I), formula (II), formula (III) or formula (IV). The polymers degrade over time when implanted in the body, and are useful as components of implantable medical devices.Type: GrantFiled: November 3, 2006Date of Patent: April 10, 2012Assignee: TYRX, Inc.Inventors: Arikha Moses, Satish Pulapura, Arthur Schwartz, Qing Ge, Irene Shatova
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Patent number: 8114951Abstract: The present invention is directed to polyarylates comprising repeating units having the structure: as well as their preparation and use as cell growth substrates.Type: GrantFiled: July 31, 2009Date of Patent: February 14, 2012Assignee: Rutgers, The State University of New JerseyInventors: Ken James, Stephen Brochini, Varawut Tangpasuthadol, Joachim Kohn
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Patent number: 7999059Abstract: The invention relates to an optical film containing aromatic polymer which shows high solubility to solvents, and methods for production thereof. Further, the invention also relates to an optical laminate, a polarizing plate, and an image display device each using the optical film. The optical film may be attained by using polyester with a specific structure. The polyester with a specific structure may be obtained by condensation polymerization of bisphenol compound(s) and dicarboxylic acid compound(s) with biphenyl structure, and preferably has no halogen atom in its chemical structure. The optical film of the invention advantageously has not only high solubility in solvents but also a high level of heat resistance and birefringence producing capability. When the content of the biphenyl structure is high, the optical film of the invention can also have large wavelength dispersion of birefringence.Type: GrantFiled: November 6, 2008Date of Patent: August 16, 2011Assignee: Nitto Denko CorporationInventors: Tomoyuki Hirayama, Toshiyuki Iida, Yutaka Ohmori, Miyuki Kurogi, Hisae Shimizu
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Patent number: 7923525Abstract: A polyester resin and a fabrication method thereof are provided. The fabrication method includes providing a diphenol monomer and a diacid monomer. The diphenol monomer is acetylated and then melt pre-polymerized with diacid monomer to form a pre-polymer. Then, the pre-polymer is polymerized by solid state polymerization to form a heat-resistant and transparent polyester resin.Type: GrantFiled: May 18, 2009Date of Patent: April 12, 2011Assignee: Industrial Technology Research InstituteInventors: Chih-Hsiang Lin, Hsin-Ching Kao
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Patent number: 7794706Abstract: The present invention provides wound dressings, optionally surgically implantable, containing biodegradable, polymers and hydrogels having allogenic or autologous precursor cells, such as stem cells and progenitor cells dispersed within. Alternatively, the wound dressings can have conditioned medium obtained from the precursor cells dispersed within. The wound dressings promote tissue restoration processes at a site of application or implantation. Additional bioactive agents can also be dispersed within the polymer/hydrogel matrix, which can be formulated to biodegrade at a controlled rate by adjusting the composition. Methods are also provided for using such biodegradable wound dressings as a delivery device or carrier for the precursor cells, conditioned medium and bioactive agents, or as coatings on implantable medical devices, to promote tissue restoration at a lesion site.Type: GrantFiled: April 26, 2007Date of Patent: September 14, 2010Assignee: Medivas, LLCInventors: Kenneth W. Carpenter, William G. Turnell, Kristin M. DeFife, Kathryn A. Grako, Ramaz Katsarava
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Publication number: 20100197883Abstract: A polyester resin and a fabrication method thereof are provided. The fabrication method includes providing a diphenol monomer and a diacid monomer. The diphenol monomer is acetylated and then melt pre-polymerized with diacid monomer to form a pre-polymer. Then, the pre-polymer is polymerized by solid state polymerization to form a heat-resistant and transparent polyester resin.Type: ApplicationFiled: May 18, 2009Publication date: August 5, 2010Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTEInventors: Chih-Hsiang Lin, Hsin-Ching Kao
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Patent number: 7722896Abstract: Biocompatible polyarylates of diphenol compounds and poly(alkylene oxide) dicarboxylic acids, articles formed therefrom and therapeutic uses are disclosed.Type: GrantFiled: September 17, 2007Date of Patent: May 25, 2010Assignee: Rutgers, The State University of New JerseyInventors: Joachim B. Kohn, Satish Pulapura, Arthur Schwartz, Raman Bahulekar
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Patent number: 7709592Abstract: Processes for preparing polyestercarbonates are disclosed. The processes allow for the consistent incorporation of adipic acid into a polymer generated from a dihydroxy compound, such as bisphenol-A, at levels greater than 99%. The polyestercarbonates so produced, as well as articles formed from the polyestercarbonates, are also disclosed herein.Type: GrantFiled: April 11, 2008Date of Patent: May 4, 2010Assignee: SABIC Innovative Plastics IP B.V.Inventor: James Alan Mahood
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Patent number: 7585929Abstract: The present invention is directed to polyarylates comprising repeating units having the structure: as well as their preparation and use as cell growth substrates.Type: GrantFiled: July 13, 2004Date of Patent: September 8, 2009Assignee: Rutgers, The State University of New JerseyInventors: Ken James, Stephen Brocchini, Varawut Tangpasuthadol, Joachim B. Kohn
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Publication number: 20090036634Abstract: The present invention relates to a process for preparing polyarylate, and more specifically, to a process for preparing polyarylate by interfacial polymerization of a bivalent phenol compound and an aromatic dicarboxylic acid or a halide thereof, which comprises mixing a cationic catalyst for the phase transition and a nonionic surfactant in a predetermined ratio, to further increase the yield of polyarylate, as compared with the case of using each of the nonionic surfactant and the cationic catalyst for the phase transition alone.Type: ApplicationFiled: February 16, 2007Publication date: February 5, 2009Inventors: Dae-Woo Nam, Dong-Ryul Kim, Hyo-Sun Lee, Boong-Goon Jeong, Sang-Uk Ryu, Hee-Jung Kim, Ju-Eun Cha
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Patent number: 7408018Abstract: The invention provides elastomeric copolyester amides, elastomeric copolyester urethanes, and methods for making the same. The polymers are based on ?-amino acids and possess physical, chemical and biodegradation properties that render them suitable for use in the human body. The polymers are useful as carriers of drugs or other bioactive substances. The polymers can also be linked, intermixed, or a combination thereof, to one or more drugs. Additionally, the polymers can be used to coat stents, for example, to suppress restenosis. Furthermore, the biodegradation of the copolyester amides and copolyester urethanes allows for the delivery of essential ?-amino acids to sites in the body, for example, to facilitate wound repair of injured tissues.Type: GrantFiled: October 5, 2006Date of Patent: August 5, 2008Assignee: Cornell Research Foundation, Inc.Inventors: Chih-Chang Chu, Ramaz Katsarava
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Patent number: 7361727Abstract: A polymerization process to derive a thermal-stabilized poly(1,4-dioxan-2-one) and cyclic ester monomer copolymer using a coordination-insertion catalyst/initiator. 1,4-dioxan-2-one and cyclic ester monomer, each containing less than 100-ppm water and having an acid value less than 0.5 mg KOH/g, and preferably less than 0.2 mg KOH/g, are copolymerized. Preferably the cyclic ester monomer is ?-caprolactone and the reaction is in an extruder.Type: GrantFiled: August 8, 2005Date of Patent: April 22, 2008Assignee: Board of Trustees of Michigan State UniversityInventors: Ramani Narayan, Jean-Marie Raquez, Sunder Balakrishnan, Philippe Dubois, Philippe Degee
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Patent number: 7304122Abstract: The present invention provides elastomeric copolyester amides, elastomeric copolyester urethanes, and methods for making the same. The polymers that are based on ?-amino acids and possess suitable physical, chemical and biodegradation properties. The polymers are useful as carriers of drugs or other bioactive substances. The polymers can be linked, intermixed, or a combination thereof, to one or more drugs.Type: GrantFiled: August 30, 2001Date of Patent: December 4, 2007Assignee: Cornell Research Foundation, Inc.Inventors: Chih-Chang Chu, Ramaz Katsarava
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Patent number: 7271234Abstract: Biocompatible polyarylates of tyrosine-derived diphenol compounds and poly(alkylene oxide) dicarboxylic acids, articles formed therefrom and therapeutic uses are disclosed.Type: GrantFiled: April 24, 2003Date of Patent: September 18, 2007Assignee: Rutgers, The State University of New JerseyInventors: Joachim B. Kohn, Satish Pulapura, Arthur Schwartz, Raman Bahulekar
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Patent number: 7041778Abstract: A novel polyimide resin consisting essentially of 3,3?,4,4?-benzophenonetetracarboxylic dianhydride (BTDA), 3,4,3?,4?-biphenyltetracarboxylic dianhydride (BPDA), 2,2 bis (3?,4?-dicarboxy phenyl) hexafluoro propane dianhydride (6FDA), 2-(3,4-dicarboxyphenyl)-1-phenylacetylene anhydride (4-PEPA) and an aromatic diamine.Type: GrantFiled: May 18, 2004Date of Patent: May 9, 2006Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: David B. Curliss, Jason E. Lincoln, Katie E. Thorp
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Patent number: 7009026Abstract: The object is to provide liquid crystalline polyester which gives molded articles without generating acetic acid gas, and a method for producing the liquid crystalline polyester. This object is achieved by a method for producing a liquid crystalline polyester comprising melt-polymerizing aromatic hydroxycarboxylic acid represented by the formula (I), aromatic diol represented by the formula (II), and aromatic dicarboxylic acid represented by the formula (III) with using a diaryl carbonate represented by the formula (IV).Type: GrantFiled: August 26, 2003Date of Patent: March 7, 2006Assignee: Sumitomo Chemical Company, LimitedInventors: Satoshi Okamoto, Manabu Hirakawa
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Patent number: 6784275Abstract: Disclosed is an active energy ray-curable polyimide resin composition which comprises a polymerizable polyimide resin (I) having an isocyanurate ring, an alicyclic structure, an imide ring and a (meth)acryloyl group and being capable of patterning with a dilute alkali aqueous solution.Type: GrantFiled: June 27, 2002Date of Patent: August 31, 2004Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Eiju Ichinose, Yohzoh Yamashina, Hidenobu Ishikawa
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Patent number: 6750317Abstract: Polyhydroxyamides are polymerized to form highly-crosslinked, temperature-stable polymers. The polyhydroxyamides include as their central, parent structure a benzenetricarboxylic acid to which side chains containing a terminal reactive group are attached by an amide bond. By way of this reactive group, highly crosslinked polymers can be formed. In addition, the polyhydroxyamide can be added as an additive to polymers in order to bring about three-dimensional crosslinking.Type: GrantFiled: May 31, 2002Date of Patent: June 15, 2004Assignee: Infineon Technologies AGInventors: Marcus Halik, Holger Hösch, Sezi Recai, Andreas Walter
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Patent number: 6555238Abstract: A polyimide film is manufactured from a random copolymeric, block copolymeric or interpenetrating polymer network-type polyamic acid prepared from pyromellitic dianhydride in combination with 22 to 78 mol % of 4,4′-oxydianiline and 22 to 78 mol % of 3,4′-oxydianiline, based on the overall diamine. The polyimide film, when used as a metal interconnect board substrate in flexible circuits, chip scale packages (CSP), ball grid arrays (BGA) or tape-automated bonding (TAB) tape by providing metal interconnects on the surface thereof, achieves a good balance between a high elastic modulus, a low thermal expansion coefficient, alkali etchability and film formability.Type: GrantFiled: August 10, 2001Date of Patent: April 29, 2003Assignee: DuPont-Toray Co. Ltd.Inventors: Kenji Uhara, Naofumi Yasuda, Kouichi Sawasaki
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Patent number: 6518390Abstract: A precursor of a polybenzoxazole resin which comprises a crosslinking group in a molecule and has a specific structure, a polybenzoxazole resin obtained from the precursor by the condensation reaction and the crosslinking reaction, an insulating film comprising the polybenzoxazole resin and a semiconductor device comprising an insulating interlayer film in multi-layer wiring or a film for protecting surfaces which comprises the above insulating film. The precursor exhibits excellent processability due to excellent solubility in solvents and, after the ring closure, excellent heat stability in applications. The resin exhibits excellent electric, physical and mechanical properties and is advantageously used for insulating interlayer films of semiconductor devices and the like applications.Type: GrantFiled: March 28, 2001Date of Patent: February 11, 2003Assignee: Sumitomo Bakelite Company, Ltd.Inventors: Masako Okanuma, Tatsuhiro Yoshida, Hidenori Saito, Nobuhiro Higashida, Masanori Fujimoto, Tadahiro Ishikawa
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Patent number: 6503538Abstract: The present invention provides elastomeric copolyester amides, elastomeric copolyester urethanes, and methods for making the same. The polymers that are based on &agr;-amino acids and possess suitable physical, chemical and biodegradation properties. The polymers are useful as carriers of drugs or other bioactive substances.Type: GrantFiled: August 30, 2000Date of Patent: January 7, 2003Assignee: Cornell Research Foundation, Inc.Inventors: Chih-Chang Chu, Ramaz Katsarava
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Patent number: 6475477Abstract: Iodinated and/or brominated derivatives of aromatic dihydroxy monomers are prepared and polymerized to form radio-opaque polymers. The monomers may also be copolymerized with other dihydroxy monomers. The iodinated and brominated aromatic dihydroxy monomers can be employed as radio-opacifying, biocompatible non-toxic additives for other polymeric biomaterials. Radio-opaque medical implants and drug delivery devices for implantation prepared from the polymers of the present invention are also disclosed.Type: GrantFiled: July 3, 2000Date of Patent: November 5, 2002Assignee: Rutgers, The State UniversityInventors: Joachim B. Kohn, Durgadas Bolikal, Sanyog M. Pendharkar
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Publication number: 20020151668Abstract: A multi-dimensional copolymer array of a plurality of copolymers, polymerized from at least two independently variable sets of monomers, wherein the polymerization is characterized by:Type: ApplicationFiled: April 13, 1999Publication date: October 17, 2002Inventors: KEN JAMES, BROCCHINI STEPHEN, VARAWUT TANGPASUTHADOL, JOACHIM KOHN
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Publication number: 20020055607Abstract: A method for producing a liquid crystalline polyester comprising the steps ofType: ApplicationFiled: August 27, 2001Publication date: May 9, 2002Inventors: Satoshi Okamoto, Manabu Hirakawa
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Publication number: 20020052463Abstract: A process for production of polyimide powder, which comprises reacting an aromatic diamine with a partial ester of a biphenyltetracarboxylic dianhydride, which is a partial ester of a biphenyltetracarboxylic dianhydride with a primary alcohol of 1-5 carbon atoms of which at least 30 mole percent is a 2,3,3′,4′-biphenyltetracarboxylic acid component, in the presence of the primary alcohol, separating out and collecting the resulting solid polyimide precursor and heating for dehydrating ring closure, polyimide powder obtained thereby, molded bodies of the polyimide powder, and a process for production of the molded bodies.Type: ApplicationFiled: October 29, 2001Publication date: May 2, 2002Applicant: Ube Industries, Ltd.Inventors: Hiroaki Yamaguchi, Fumio Aoki
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Publication number: 20020052464Abstract: A process for production of polyimide powder, which comprises reacting a biphenyltetracarboxlic dianhydride and an aromatic diamine in an amide-based solvent optionally containing a water-soluble ketone, in the presence of an imidazole at 1-100 equivalent percent based on the carboxylic acid content of the polyimide precursor, separating and collecting the produced polyimide precursor powder from a water-soluble ketone solvent containing 3-30 wt % of an amide-based solvent, and heating the polyimide precursor powder to an imidation rate of 90% or greater, as well as polyimide powder obtained thereby, molded bodies of the polyimide powder, and a process for production of the molded bodies.Type: ApplicationFiled: October 29, 2001Publication date: May 2, 2002Applicant: Ube Industries, Ltd.Inventors: Hiroaki Yamaguchi, Fumio Aoki
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Patent number: 6346597Abstract: A process for preparing a polyester carbonate is provided. The process comprises the steps of: (I) reacting a diacid with a carbonic acid diester and a catalyst in the presence of a polycarbonate oligomer via melt condensation polymerization to form a pre-polymer; and (II) reacting the pre-polymer via solid state polymerization to form a polyester carbonate.Type: GrantFiled: December 27, 1999Date of Patent: February 12, 2002Assignee: General Electric CompanyInventors: Timothy Edward Banach, Gregory Ronald Gillette
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Patent number: 6265521Abstract: Polyether polymers such as polyetherimides are prepared by a two-step reaction. The first step is the reaction between an alkali metal salt of a dihydroxy-substituted aromatic hydrocarbon, such as bisphenol A disodium salt, and a substituted aromatic compound such as 1,3-bis[N-(4-chlorophthalimido)]benzene, the alkali metal salt being employed in an amount less than stoichiometric. The intermediate low molecular weight polymer thus produced then undergoes reaction with additional alkali metal salt. By this method, a polyether polymer of closely controlled molecular weight can be conveniently prepared.Type: GrantFiled: August 7, 2000Date of Patent: July 24, 2001Assignee: General Electric CompanyInventors: Thomas Joseph Fyvie, Peter David Phelps, Paul Edward Howson, Donald Frank Rohr, Ganesh Kailasam, Elliott West Shanklin