Reactant Contains A Fused- Or Bridged-ring Other Than Solely As A Polycarboxylic Acid Anhydride Group Patents (Class 528/190)
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Patent number: 12162982Abstract: The present invention relates to a highly bio-based polycarbonate ester and a method for producing same. The highly bio-based polycarbonate ester has a bio-based carbon content of 80% or more since the highly bio-based polycarbonate ester is obtained by copolymerization of 1,4:3,6-dianhydrohexitol, which is a bio-based monomer derived from biomass, and 1,4-cyclohexanedicarboxylate and/or terephthalate, and therefore, the highly bio-based polycarbonate ester is not only human-friendly and environmentally friendly, but also advantageous in terms of biodegradability.Type: GrantFiled: September 26, 2019Date of Patent: December 10, 2024Assignee: SK CHEMICALS CO., LTD.Inventor: Kwang Sei Oh
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Patent number: 12017980Abstract: Provided are a monofunctional phenolic compound used for producing an active ester resin capable of forming a cured product having excellent dielectric properties and excellent heat resistance, an active ester resin and a method for producing the active ester resin, and a thermosetting resin composition and a cured product of the thermosetting resin composition. Specifically, provided are a monofunctional phenolic compound including one or more vinylbenzyl groups and an active ester resin including a vinylbenzyl structure attached to a terminal group of the molecular chain and derived from the monofunctional phenolic compound. The vinylbenzyl structure preferably includes a vinylbenzyl-modified aryloxycarbonyl group.Type: GrantFiled: September 12, 2019Date of Patent: June 25, 2024Assignee: DIC CorporationInventors: Masaki Hazama, Koji Hayashi
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Patent number: 11866632Abstract: Liquid-crystal polymer is composed of the following repeating units: 10 mol % to 35 mol % of 10 mol % to 35 mol % of 10 mol % to 50 mol % of and 10 mol % to 40 mol % of 10 mol % to 40 mol % of or a combination thereof. Each of AR1, AR2, AR3, and AR4 is independently AR5 or AR5-Z-AR6, in which each of AR5 and AR6 is independently or a combination thereof, and Z is —O—, or C1-5 alkylene group. Each of X and Y is independently H, C1-5 alkyl group, CF3, or wherein R2 is H, CH3, CH(CH3)2, C(CH3)3, CF3, or n=1 to 4; and wherein R1 is C1-5 alkylene group.Type: GrantFiled: July 1, 2020Date of Patent: January 9, 2024Assignee: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTEInventors: Yu-Lin Chu, Jen-Chun Chiu, Zu-Chiang Gu, Po-Hsien Ho, Meng-Hsin Chen, Chih-Hsiang Lin
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Patent number: 11746182Abstract: A resin composition and method for installing a pipe liner that allows the liner to be fully wet out with a resin and activator and stored for a period of up to six months prior to installation and curing. A method of lining a pipe with a delayed curing resin composition is also provided that includes fully wetting out a liner with a blended two part epoxy composition such that the liner can be transported in a wet out fashion, placed in a pipe to be lined and repositioned as needed without concern for the resin composition to begin curing.Type: GrantFiled: September 17, 2021Date of Patent: September 5, 2023Assignee: Warren Environmental & Coatings, LLCInventor: Danny Warren
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Patent number: 11667751Abstract: The present invention relates to a biodegradable polyester resin, in which the first repeat unit comprising a first diol residue and an aromatic dicarboxylic acid residue and the second repeat unit comprising a second diol residue and an aliphatic dicarboxylic acid residue satisfy a ratio of the number of repeat units in a specific range, and the softness index of the resin satisfies a specific range, and to a process for preparing the same. Since the biodegradable polyester resin can provide a biodegradable polyester sheet or film that can be simultaneously enhanced in productivity, processability, and moldability and is excellent in tensile strength, tear strength, and friction coefficient and excellent in biodegradability and water degradability, it can be utilized in more diverse fields.Type: GrantFiled: May 25, 2022Date of Patent: June 6, 2023Assignee: ECOVANCE CO. LTD.Inventors: Kyung Youn Kim, Hoon Kim, Seong Dong Kim, Ji Yeon Ryu, Hyung Mo Kim
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Patent number: 11566102Abstract: The purpose of the present invention is to provide a polyester resin or polyester carbonate resin, which has high refractive index, while achieving an excellent balance between heat resistance and low birefringence. A polyester resin or a polyester carbonate resin, which contains repeating units represented by the following formulae (1) and (2), and wherein the ratio of the repeating unit represented by formula (1) to the repeating unit represented by formula (2) is 15:85 to 85:15.Type: GrantFiled: March 11, 2019Date of Patent: January 31, 2023Assignee: TEIJIN LIMITEDInventors: Kyosuke Yamada, Manabu Matsui, Takatsune Yanagida, Kazuyoshi Ogasawara, Kazunori Nunome, Keisuke Sato, Tatsuya Oyama
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Patent number: 11525192Abstract: The present invention relates to a method for manufacturing a wholly aromatic liquid-crystalline polyester fiber with enhanced spinnability, and more specifically, to a method for manufacturing a wholly aromatic liquid-crystalline polyester fiber including: pelletizing a resin manufactured by adding 1.08 equivalents to 1.12 equivalents of acetic anhydride to raw material monomers including hydroxy benzoic acid, hydroxy naphthoic acid, biphenol, terephthalic acid, and isophthalic acid, followed by solid-phase polycondensation, and melt-spinning under oil conditions in which winding-up improving oil is diluted to 0.5% to 2% and silicone spinning oil for high temperature is diluted to 0.5% to 2%, respectively, with water as a solvent.Type: GrantFiled: November 18, 2019Date of Patent: December 13, 2022Assignee: SEYANG POLYMERInventors: Sun Hwa Jang, Tae-Young Ha, Sung-Eun Kim, Youn Eung Lee
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Patent number: 11427523Abstract: A bisphenol composition including a specific amount of aromatic alcohol sulfonate, and a simple method of producing it are provided. Also provided is a method of producing a polycarbonate resin in which, by using the bisphenol composition including a specific amount of aromatic alcohol sulfonate, melt polymerization reaction can be efficiently allowed to proceed to produce a polycarbonate resin having an excellent color tone. A bisphenol composition including an aromatic alcohol sulfonate at not less than 0.1 ppb by mass with respect to a bisphenol. A method of producing a bisphenol composition, including reacting a ketone or an aldehyde with an aromatic alcohol in the presence of sulfuric acid to produce a bisphenol composition. A method of producing a polycarbonate resin, including producing a polycarbonate resin using the bisphenol composition. A polycarbonate resin including a specific amount of aromatic alcohol sulfonate.Type: GrantFiled: February 21, 2020Date of Patent: August 30, 2022Assignee: MITSUBISHI CHEMICAL CORPORATIONInventors: Kei Uchiyama, Takayuki Yoshida, Rie Konishi, Kazuo Hirowatari, Takaharu Oono
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Patent number: 11382218Abstract: In a printed wiring board, when a plurality of wiring base bodies are collectively stacked, a constituent material of a first layer of an insulating resin film has a low melting point, so that the first layer is easily melted. Therefore, thermal welding on an upper surface of the wiring base body is reliably performed, and the wiring base bodies are bonded to each other with high reliability.Type: GrantFiled: May 24, 2019Date of Patent: July 5, 2022Assignee: TDK CORPORATIONInventors: Takaaki Morita, Seiichi Tajima, Takashi Kariya
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Patent number: 11359068Abstract: The present invention relates to an enzymatic process for depolymerization of post-consumer poly(ethylene terephthalate) by a glycolysis reaction. This invention also relates to a process for recycling post-consumer poly(ethylene terephthalate) and to the recycled poly(ethylene terephthalate) obtained by said process.Type: GrantFiled: September 14, 2017Date of Patent: June 14, 2022Assignee: PETROLEO BRASILEIRO S.A.—PETROBRASInventors: Aline Machado De Castro, Adriano Carniel De Oliveira, Erika de Araújo Valoni, Danielle Altomari Teixeira, Cesar Rezende Da Motta
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Patent number: 11339249Abstract: Provided are a novel compound having a fluorene skeleton, and a method for manufacturing the same, the compound having a low palladium content or other content of a specific metal or content of a specific compound in a raw material alcohol, and being excellent in hue or various characteristics (optical characteristics, heat resistance, moldability, and other characteristics) as a raw material or in a resin that uses the raw material.Type: GrantFiled: January 29, 2019Date of Patent: May 24, 2022Assignee: TEIJIN LIMITEDInventor: Yasuhiko Tomonari
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Patent number: 11261294Abstract: The purpose of the present invention is to provide a thermoplastic resin that has a high refractive index and enables low birefringence and balanced heat resistance and moldability. This thermosetting resin includes repeating units represented by formula (1). (In the formula, the rings Z are the same or different and represent an aromatic hydrocarbon ring, R1 and R2 independently represent a C1-C12 hydrocarbon group optionally including a hydrogen atom, a halogen atom, and an aromatic group, Ar1 and Ar2 represent a C6-C10 aromatic group optionally having a substituent, L1 and L2 independently represent a divalent linking group, j and k independently represent an integer of 0 or more, m and n independently represent 0 or 1, and W is at least one selected from the groups represented by formulae (2) and (3).) (In the formula, X represents a divalent linking group.Type: GrantFiled: July 13, 2018Date of Patent: March 1, 2022Assignee: TEIJIN LIMITEDInventors: Kyosuke Yamada, Manabu Matsui, Takatsune Yanagida, Kazuyoshi Ogasawara, Kazunori Nunome, Keisuke Sato, Yasuhiko Tomonari
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Patent number: 11142609Abstract: A resin composition and method for installing a pipe liner that allows the liner to be fully wet out with a resin and activator and stored for a period of up to six months prior to installation and curing. A method of lining a pipe with a delayed curing resin composition is also provided that includes fully wetting out a liner with a blended two part epoxy composition such that the liner can be transported in a wet out fashion, placed in a pipe to be lined and repositioned as needed without concern for the resin composition to begin curing.Type: GrantFiled: July 3, 2019Date of Patent: October 12, 2021Assignee: Warren Environmental & Coating, LLCInventor: Danny Warren
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Patent number: 11118009Abstract: The purpose of the present invention is to provide an aromatic polycarbonate oligomer solid with substantially reduced low-molecular-weight components, no or a substantially reduced amount of chlorine-containing compounds, high loose bulk density, and ease of handling. The aromatic polycarbonate oligomer solid contains a repeating unit represented by general formula (1), has a weight average molecular weight of 500 to 10000, low-molecular-weight components less than or equal to 5.0 area % measured with high-speed liquid chromatography, and a loose bulk density of greater than or equal to 0.30 g/cm3.Type: GrantFiled: May 17, 2018Date of Patent: September 14, 2021Assignee: HONSHU CHEMICAL INDUSTRY CO., LTD.Inventors: Mitsutaka Ozaki, Miwa Hashimoto, Takeru Suto, Ryoto Kano
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Patent number: 11008434Abstract: Embodiments relate to a heat shrinkable film and a process for regenerating a polyester container using the same. The heat shrinkable film comprises a copolymerized polyester resin comprising a diol component and a dicarboxylic acid component and has a heat shrinkage rate of 30% or more in the main shrinkage direction upon thermal treatment at a temperature of 80° C. for 10 seconds and a melting point of 190° C. or higher as measured by differential scanning calorimetry. It not only solves the environmental problems by improving the recyclability of the polyester container, but also is capable of enhancing the yield and productivity.Type: GrantFiled: November 18, 2019Date of Patent: May 18, 2021Assignees: SKC INC., SKC CO., LTD.Inventors: Daeyong Shin, Yongdeuk Kim, Jung Kyu Lee, Jaehyong Son, Eugene Jung
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Patent number: 10968311Abstract: [Problem] To provide a wholly aromatic liquid crystalline polyester resin having an excellent heat resistance and processability while having an extremely low dielectric tangent [Solving means] A wholly aromatic liquid crystalline polyester resin according to the present invention comprises, structural unit (I) derived from p-hydroxybenzoic acid, structural unit (II) derived from 6-hydroxy-2-naphthoic acid, structural unit (III) derived from an aromatic diol compound, structural unit (IV) derived from an aromatic dicarboxylic acid, wherein the composition ratio (mol %) of said structural units (I) to (IV) satisfies the following conditions: 2 mol %?structural unit (I)?9 mol % 40 mol %?structural unit (II)?75 mol % 9 mol %?structural unit (III)?24 mol % 9 mol %?structural unit (IV) 24 mol %.Type: GrantFiled: March 28, 2018Date of Patent: April 6, 2021Assignee: JXTG NIPPON OIL & ENERGY CORPORATIONInventor: Gosuke Washino
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Patent number: 9605107Abstract: The object of the present invention is to provide a modified polyalkylene oxide capable of yielding an aqueous solution excellent in transparency with high viscosity, even when combined with a cationic surfactant.Type: GrantFiled: July 5, 2013Date of Patent: March 28, 2017Assignee: SUMITOMO SEIKA CHEMICALS CO., LTD.Inventors: Hitoshi Ozawa, Tsuyoshi Masuda, Yusuke Nishikawa
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Patent number: 9447234Abstract: Provided is an aliphatic polycarbonate copolymer including repeating units of Formula 1 described in the specification. In Formula 1, A is a substituted or unsubstituted C3-C60 alkylene or a substituted or unsubstituted C3-C60 heteroalkylene and the O-A-O units in one polymer chain may be identical to or different from each other, B is a substituted or unsubstituted C5-C20 arylene or a substituted or unsubstituted C5-C20 heteroarylene and the —C(O)—B—C(O)— units in one polymer chain may be identical to or different from each other, and x and y are real numbers representing mole fractions.Type: GrantFiled: May 28, 2013Date of Patent: September 20, 2016Assignee: LOTTE CHEMICAL CORPORATIONInventors: Bun Yeoul Lee, Jong Yeob Jeon, Jung Jae Lee, Ji Hae Park
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Patent number: 9040630Abstract: Provided herein are graft copolymers of polyfarnesenes with condensation polymers; and methods of making and using the graft copolymers disclosed herein. In certain embodiments, the condensation polymers include polyesters, polycarbonates, polyamides, polyethers, phenol-formaldehyde resins, urea-formaldehyde resins, melamine-formaldehyde resins and combinations thereof. In some embodiments, the polyfarnesenes include farnesene homopolymers derived from a farnesene, and farnesene interpolymers derived from a farnesene and at least a vinyl monomer. In certain embodiments, the farnesene is prepared from a sugar by using a microorganism.Type: GrantFiled: July 29, 2011Date of Patent: May 26, 2015Assignee: AMYRIS, INC.Inventor: Derek James McPhee
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Publication number: 20150126702Abstract: A polyester resin is a polymer of a carboxylic acid component and an alcohol component including a rosin diol represented by the formula (1), wherein an acid value is from 10 mg KOH/g to 30 mg KOH/g, a content of carboxylic acid having a rosin skeleton in the resin is 1% by weight or less, and a content of carboxylic acid except carboxylic acid having the rosin skeleton in the resin is 1% by weight or less: wherein, R1 and R2 each independently represent hydrogen or a methyl group, L1, L2 and L3 each independently represent a divalent linking group selected from the group consisting of a carbonyl group, a carboxyl group, an ether group, a sulphonyl group, a chain alkylene group, a cyclic alkylene group, an arylene group, and combinations thereof, and A1 and A2 represent a rosin ester group.Type: ApplicationFiled: May 20, 2014Publication date: May 7, 2015Applicant: FUJI XEROX CO., LTD.Inventors: Shiori CHONAN, Sumiaki YAMASAKI, Susumu YOSHINO, Yuki SASAKI
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Patent number: 9012593Abstract: Methods of preparing an aromatic liquid crystalline polyester resin and an aromatic liquid crystalline polyester resin compound are disclosed. A method of preparing an aromatic liquid crystalline polyester resin may include: acetylating a first monomer including an amino group by a reaction with a carboxylic acid anhydride; acetylating a second monomer including a hydroxyl group and not including an amino acid group with an additional carboxylic acid anhydride; and synthesizing an aromatic liquid crystalline polyester prepolymer by a condensation polymerization reaction of the acetylated first and second monomers with dicarboxylic acid. A method of preparing an aromatic liquid crystalline polyester resin compound may use the aromatic liquid crystalline polyester resin prepared according to the forgoing method.Type: GrantFiled: June 14, 2011Date of Patent: April 21, 2015Assignee: Shenzhen Wote Advanced Materials Co., Ltd.Inventors: Sun Hwa Chang, Sang Mi Kang, Dae Yeon Kim, Jin Kyu Lee
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Patent number: 9005475Abstract: An aromatic amide compound having the following general formula (I) is provided: wherein, X1 and X2 are independently C(O)HN or NHC(O); G1, G2 and G3 are independently hydrogen, C(O)HN-phenyl, or NHC(O)-phenyl, wherein at least one of G1, G2 and G3 is C(O)HN-phenyl or NHC(O)-phenyl; Q1, Q2, and Q3 are independently hydrogen, C(O)HN-phenyl, or NHC(O)-phenyl, wherein at least one of Q1, Q2, and Q3 is C(O)HN-phenyl or NHC(O)-phenyl; R5 is halo, haloalkyl, alkyl, alkenyl, aryl, heteroaryl, cycloalkyl, or heterocyclyl; and m is from 0 to 4.Type: GrantFiled: June 5, 2014Date of Patent: April 14, 2015Assignee: Ticona LLCInventors: Kamlesh P. Nair, Steven D. Gray
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Patent number: 8986846Abstract: A thermosetting oligomer or thermosetting polymer is provided. The thermosetting oligomer or thermosetting polymer contains repeating units, each of which has at least one thermosetting functional group in the side chain and is represented by Formula 1: where repeating units include X1, A1, and Y1 subunits, sidechain units include linking unit L and thermosetting functional group Z, and n is an integer from 1 to 4. The thermosetting oligomer or thermosetting polymer has a low coefficient of thermal expansion and high or no glass transition temperature, stiffness, processability, heat resistance and mechanical properties. The thermosetting oligomer or thermosetting polymer is highly soluble, wettable and dimensionally stable and is suitable for use in films, prepregs and printed circuit boards. Further provided are a thermosetting resin composition including the thermosetting oligomer or thermosetting polymer and a printed circuit board using the composition.Type: GrantFiled: June 23, 2009Date of Patent: March 24, 2015Assignee: Samsung Electro-Mechanics Co., Ltd.Inventors: Jae Jun Lee, Mahn Jong Kim, Kwang Hee Kim
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Patent number: 8981035Abstract: There is provided a production method of poly(phenylene ether ether ketone). The production method makes a cyclic poly(phenylene ether ether ketone) composition subjected to thermal ring-opening polymerization in the presence of a metal alkoxide and/or a metal phenoxide. The cyclic poly(phenylene ether ether ketone) composition includes 60% by weight or more of cyclic poly(phenylene ether ether ketone) and has a melting point of 270° C. or lower.Type: GrantFiled: June 22, 2012Date of Patent: March 17, 2015Assignee: Toray Industries, Inc.Inventors: Keiko Ichinose, Kohei Yamashita, Makito Yokoe, Koji Yamauchi
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Patent number: 8975361Abstract: The present invention relates to water and solvent-free polymers, in particular water and solvent-free synthetic rubber products like styrene butadiene rubber products and butadiene rubber products as well as a process for the production thereof. The invention further relates to a device suitable to accomplish said process.Type: GrantFiled: March 23, 2011Date of Patent: March 10, 2015Assignee: LANXESS Deutschland GmbHInventors: Wolfgang Krumbe, Rolf Feller, Paul Wagner, Hanns-Ingolf Paul, Martin Siebuerger, Heike Kloppenburg, Alicia Le-Sattler, John Lovegrove
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Patent number: 8951646Abstract: A layered structure including a first electrode and a second electrode, a light-emitting layer or a charge separation layer between the first electrode and the second electrode, and a layer containing a conjugated polymer compound between the light-emitting layer or the charge separation layer and the first electrode, wherein the conjugated polymer compound contains a repeating unit selected from the group consisting of a repeating unit of formula (1).Type: GrantFiled: March 5, 2009Date of Patent: February 10, 2015Assignee: Sumitomo Chemical Company, LimitedInventors: Masanobu Tanaka, Kenta Tanaka, Shohgo Yamauchi, Hideyuki Higashimura
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Patent number: 8906258Abstract: A thermotropic liquid crystalline polymer composition capable of exhibiting both a low melting temperature and good heat resistance without the use of conventional naphthenic acids is provided. The melting temperature may, for example, range from about 250° C. to about 400° C. Even at such low melting temperatures, the present inventors have surprisingly discovered that the ratio of the deflection temperature under load (“DTUL”), a measure of short term heat resistance, to the melting temperature may remain relatively high. The specific DTUL values may range from about 200° C. to about 300° C. The ability to form a polymer composition with the properties noted above may be achieved, at least in part, by the use of an aromatic amide oligomer.Type: GrantFiled: August 27, 2012Date of Patent: December 9, 2014Assignee: Ticona LLCInventors: Steven D. Gray, Kamlesh P. Nair, Joseph J. Grenci
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Patent number: 8883953Abstract: A copolymer that includes a repeating unit A having a repeating unit represented by Chemical Formula 1, a repeating unit represented by Chemical Formula 2, or a combination thereof; and a repeating unit B having a repeating unit represented by Chemical Formula 3, a repeating unit represented by Chemical Formula 4, or a combination thereof, an article including the same, and a display device including the article.Type: GrantFiled: January 24, 2013Date of Patent: November 11, 2014Assignee: Samsung Electronics Co., Ltd.Inventors: Byung Hee Sohn, Hyun Jeong Jeon, Sang Soo Lee, Jae Jun Lee
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Patent number: 8859711Abstract: A method of preparing a wholly aromatic liquid crystalline polyester amide resin and a method of preparing a wholly aromatic liquid crystalline polyester amide resin compound. The method of preparing a wholly aromatic liquid crystalline polyester amide resin is performed using a monomer having both a hydroxyl group and an acetylamino group or using a monomer having a hydroxyl group and a monomer having an acetylamino group. In addition, the method of preparing a wholly aromatic liquid crystalline polyester amide resin compound is performed using a wholly aromatic liquid crystalline polyester amide resin that is prepared using the method.Type: GrantFiled: October 21, 2011Date of Patent: October 14, 2014Assignee: Samsung Fine Chemicals Co., Ltd.Inventors: Sun Hwa Chang, Sang Mi Kang, Dae Yeon Kim
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Patent number: 8859648Abstract: The present invention relates to a retardation film using polyester having a photoelastic coefficient of ?40×10?12 Pa?1 to 40×10?12 Pa?1. The present invention also relates to a polyester resin for optical use which contains a phosphorus compound, and an alicyclic component and a fluorene derivative component as constituents, and satisfies the following equations (6) and (7): 100° C.?glass transition temperature?150° C.??(6) and 1.0?(Ma/2+Mb+Mc)/P?5.0??(7), wherein Ma is the number of moles of an alkali metal element contained in 1 ton of the polyester resin, Mb is the number of moles of an alkaline earth metal element contained in 1 ton of the polyester resin, Mc is the sum of the number of moles of a zinc element (Zn), a cobalt element (Co) and a manganese element (Mn) contained in 1 ton of the polyester resin, and P is the number of moles of a phosphorus element contained in 1 ton of the polyester resin.Type: GrantFiled: May 23, 2006Date of Patent: October 14, 2014Assignee: Toray Industries, Inc.Inventors: Hideki Moriyama, Shigetoshi Maekawa, Jun Sakamoto, Akimitsu Tsukuda, Masahiro Kimura, Risa Taniguchi
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Patent number: 8846858Abstract: The disclosure provides a method for alcoholysis of a polycarbonate-containing composition comprising a polycarbonate and a component comprising a phosphorus-containing flame retardant, an acrylonitrile-butadiene-styrene, or a combination of the phosphorus-containing flame retardant and acrylonitrile-butadiene-styrene. The method comprises contacting the composition with a solvent that forms a solution or a filterable suspension of the component but not the polycarbonate; separating the solution or the filterable suspension from the polycarbonate; and heating the polycarbonate in the presence of an alcohol and a catalyst at a temperature from 70° C. to 200° C., and a pressure from 5 mbar to 40 bar for a time sufficient to depolymerize the polycarbonate and produce a dihydroxy aromatic compound and a dialkyl carbonate.Type: GrantFiled: December 21, 2012Date of Patent: September 30, 2014Assignee: Saudi Basic Industries CorporationInventors: Philip Wesley Bell, Alexander Stanislaus, Venkata Ramanarayanan Ganapathy Bhotla, Rathinam Jothi Mahalingam
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Patent number: 8828636Abstract: It is an object of the present invention to provide a new alcohol compound, a polyester resin, an unsaturated polyester resin, a resin particle and an electrophotographic toner using the compound capable of using the renewable resources as a part of a raw material. An alcohol compound according to the present invention is characterized by representing the chemical formula [Chemical 1]. Furthermore, the polyester resin or the unsaturated polyester resin according to the present invention, is characterized in that the compound (wherein X is an aliphatic or an aromatic residue, Y is a refined rosin residue, a disproportionated rosin residue or a hydrogenated rosin residue, and n=0 to 1 in the formula.) is an essential component of an alcohol component. Further, the resin particle of the present invention is characterized by comprising the polyester resin.Type: GrantFiled: March 2, 2011Date of Patent: September 9, 2014Assignee: Japan U-Pica Company, Ltd.Inventors: Tetsuji Moroiwa, Nobutaka Yoshida, Hiroshi Aihara, Akira Yamane, Kei Yamasaki, Keiko Taniuchi
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Publication number: 20140242385Abstract: A fiber formed from a polymer composition that comprises a liquid crystalline polymer and an aromatic amide oligomer is provided. The present inventors have discovered that the oligomer can act as a flow aid for the polymer, which can provide a variety of different benefits. For example, the use of the oligomer during polymerization can lower the melt viscosity of the polymer as it is formed. This enables the formation of high molecular weight polymers that do not solidify within the reactor vessel. The formation of high molecular weight polymers during melt polymerization can, in turn, provide a variety of benefits, such as allowing for higher molecular weight polymers to be formed through additional processing (e.g., solid state polymerization) than conventionally possible, as well as enhancing the melt strength of the polymer composition and thereby aiding in the fiber formation process.Type: ApplicationFiled: February 19, 2014Publication date: August 28, 2014Applicant: Ticona LLCInventors: Kamlesh P. Nair, Joseph J. Grenci, Steven D. Gray
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Patent number: 8779081Abstract: The invention is directed to a method for producing poly(arylene) ethers with improved particle size characteristics. The improved particle size characteristics of the polyphenylene ether include one or both of: (i) up to about 50 weight percent of particles smaller than 38 micrometers; and a (ii) mean particle size greater than 100 or more micrometers.Type: GrantFiled: March 15, 2011Date of Patent: July 15, 2014Assignee: SABIC Global Technologies B.V.Inventors: Nitin Vilas Tople, Gerardo Rocha-Galicia, Hua Guo
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Publication number: 20140170555Abstract: The present disclosure provides a polyester toner resin comprising a polyhydroxylated cardanol derivative, that may be used in manufacturing an emulsion aggregation (EA) toner for imaging devices.Type: ApplicationFiled: December 18, 2012Publication date: June 19, 2014Applicant: XEROX CORPORATIONInventors: Jordan H. Wosnick, Guerino G. Sacripante, Ke Zhou, Edward G. Zwartz, Michael S. Hawkins
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Patent number: 8741399Abstract: The birefringent film of the present invention contains an aromatic polyester having a repeating unit represented by the following general formula (1). In the general formula (1), A(s), B(s), C(s), and D(s) are each independently represent a group selected from a halogeno group, an alkyl group which has 1 to 6 carbon atoms, and an aryl group. Also, a and b each represent an integer of 0 to 4, and c and d each represent an integer of 0 to 3. R1 represents a hydrogen atom, or an alkyl group which has 1 to 10 carbon atoms. R2 represents an alkyl group which has 2 to 10 carbon atoms. R3 to R6 each independently represent a group or atom selected from a hydrogen atom, a halogeno group, an alkyl group which has 1 to 6 carbon atoms, and an aryl group. Furthermore, l and m each represent an integer of 2 or more.Type: GrantFiled: March 25, 2009Date of Patent: June 3, 2014Assignee: Nitto Denko CorporationInventors: Tomoyuki Hirayama, Toshiyuki Iida, Yutaka Ohmori, Satoru Suzuki, Miyuki Kurogi, Hisae Shimizu
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Patent number: 8722813Abstract: A resin composition containing: an ester compound including a carboxylic acid ester obtained by using (1) a monohydric alcohol having an alkyl group having 1 to 4 carbon atoms; (2) a dicarboxylic acid having an alkylene group having 2 to 4 carbon atoms; and (3) a dihydric alcohol having an alkylene group having 2 to 6 carbon atoms, the ester compound having an acid value of 1.00 mgKOH/g or less, a hydroxyl value of 5.0 mgKOH/g or less, and a number-average molecular weight of from 300 to 700; and an aliphatic polyester. Since the resin composition of the present invention inhibits the generation of volatile compounds, the resin composition can be suitably used in various industrial applications, such as daily sundries, household electric appliance parts, and automobile parts.Type: GrantFiled: August 18, 2011Date of Patent: May 13, 2014Assignee: Kao CorporationInventors: Hiroki Sawada, Masahiro Mori
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Patent number: 8722843Abstract: Disclosed is a material for fiber manufacturing comprising a liquid crystal polyester satisfying the following requirements (a) and (b): (a) the weight-average molecular weight is equal to or less than 30000 and the polydispersity is equal to or less than 2.5; and (b) the melt viscosity measured at 360° C. with conditions of a nozzle pore diameter of 0.5 mm and a shear velocity of 1000 s?1 using a flow feature testing machine is equal to or less than 70 Pa·s.Type: GrantFiled: November 19, 2012Date of Patent: May 13, 2014Assignee: Sumitomo Chemical Company, LimitedInventors: Tomoya Hosoda, Mitsuo Maeda, Satoshi Okamoto
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Publication number: 20140127621Abstract: Disclosed is a polyester resin containing the polycondensation product of (a) at least one diacid, acid ester, or diester, and (b) at least two diols. The at least two diols include a disproportionated rosin diol and 2,2-bis(4-hydroxyphenyl)propane. Also disclosed is a toner composition having particles which include the disclosed polyester resin. Further disclosed is a method of preparing the disclosed polyester resin, and a method of forming toner particles that includes the disclosed polyester resin.Type: ApplicationFiled: November 7, 2012Publication date: May 8, 2014Applicant: XEROX CORPORATIONInventors: Ke ZHOU, Guerino G. SACRIPANTE, Yulin WANG, Michael D'AMATO
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Patent number: 8703899Abstract: The present invention relates to a method for producing a polyester, containing conducting a transesterification reaction of at least one compound selected from compounds represented by the following formulae (1) to (3) with a diol compound in the presence of a catalyst: wherein Ar is a divalent aromatic hydrocarbon group or the like; R1 is CX1Y1R4; R2 is a hydrogen atom or CX2Y2R5; R3 is a hydrogen atom or CX3Y3R6; R7 is a perfluoroalkylene group having 1 to 5 carbon atoms; X1 to X3 are a hydrogen atom, a fluorine atom or Rf; Y1 to Y3 are a fluorine atom or Rf; R4 to R6 are a fluorine atom, Rf, ORf or the like; and Rf is a fluoroalkyl group having 1 to 4 carbon atoms.Type: GrantFiled: August 30, 2013Date of Patent: April 22, 2014Assignee: Asashi Glass Company LimitedInventors: Jumpei Nomura, Hidekazu Okamoto, Atsushi Fujimori, Takashi Okazoe
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Patent number: 8703011Abstract: The present invention provides a class of thermotropic liquid crystalline polyesters (TLCPs) and molding compositions comprising the polyesters and glass fiber. The TLCPs consist essentially of repeat units derived from p-hydroxybenzoic acid (HBA), 6-hydroxy-2-naphthoic acid (HNA), terephthalic acid (TA), and hydroquinone (HQ), and the mole percent of HBA, HNA, TA and HQ is 34-72%, 12-26%, 4-21% and 4-21%, respectively. The TLCPs have a melting temperature equal to or below 355° C., an inherent viscosity of 4.0-10.0 dL/g and a Heat Deflection Temperature (HDT) in the range of 260-285° C. when compounded with 30% by weight glass fiber. The optimum compositions, selected from the above-mentioned compositional ranges exhibit a relatively low melting temperature and a relatively high HDT. Specified compositions, selected from the above-mentioned compositional ranges have low melting point, which are useful to blend with conventional polymers such as poly (ethylene terephthalate) and nylon etc.Type: GrantFiled: November 17, 2009Date of Patent: April 22, 2014Inventors: Xiuzhen Wang, Haishan Bu, Wen Zhou
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Publication number: 20140100341Abstract: Disclosed in the present invention is a fluorine-containing polymerizable compound of the general formula (1): where a and b each independently represent an integer of 0 to 2 and satisfy a relationship of a+b=2; c represents an integer of 0 to 3; d and e each independently represents an integer of 0 to 2 and satisfy a relationship of 1?d+e?4; and the moiety of the following formula may have a carbon atom replaced by a heteroatom (a nitrogen atom, an oxygen atom or a sulfur atom) and may have a hydrogen atom substituted with a substituent that may contain a nitrogen atom, an oxygen atom or a sulfur atomType: ApplicationFiled: May 29, 2012Publication date: April 10, 2014Applicant: Central Glass Company, LimitedInventors: Junya Nakatsuji, Makoto Matsuura, Kazuhiro Yamanaka
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Patent number: 8680226Abstract: The disclosure provides a method for recovering a dihydroxy aromatic compound and a dialkyl carbonate from a polycarbonate-containing composition comprising a polycarbonate and acrylonitrile-butadiene-styrene. The method comprises heating the composition in the presence of an alcohol and a transesterification catalyst at a temperature of 70° C. to 200° C. and a pressure of 50 mbar to 40 bar in a reactor for a time sufficient to depolymerize the polycarbonate producing a dihydroxy aromatic compound and a dialkyl carbonate; removing the dihydroxy aromatic compound and the dialkyl carbonate from the reactor, the acrylonitrile-butadiene-styrene remaining as a coating on the surfaces of the reactor; adding a solvent to the reactor; and heating the solvent to remove the acrylonitrile-butadiene-styrene from the surfaces of the reactor.Type: GrantFiled: December 21, 2012Date of Patent: March 25, 2014Assignee: Saudi Basic Industries CorporationInventors: Philip Wesley Bell, Alexander Stanislaus, Venkata Ramanarayanan Ganapathy Bhotla, Tukaram Gunale, Darshan Jayanna
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Patent number: 8669341Abstract: A method for forming a high molecular weight thermotropic liquid crystalline polymer is provided. The method includes melt polymerizing two or more monomers in the presence of a unique aromatic amide oligomer to form a prepolymer, and then solid-state polymerizing the prepolymer to achieve a target molecular weight. The present inventors have discovered that a unique aromatic amide oligomer can be employed to help increase the “low shear” complex viscosity of the resulting solid-state polymerized composition. This allows for the attainment of higher than conventional “low shear” complex viscosity values and/or a substantial reduction in the solid-state polymerization time needed to achieve a target complex viscosity. In addition, the oligomeric flow aid can also accelerate the extent to which the “high shear” melt viscosity is increased during solid-state polymerization, which may also contribute to a substantial reduction in the solid-state polymerization time needed to achieve a certain molecular weight.Type: GrantFiled: August 27, 2012Date of Patent: March 11, 2014Assignee: Ticona LLCInventors: Kamlesh P. Nair, Steven D. Gray
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Patent number: 8669333Abstract: A thermosetting resin composition contains an active ester resin (A) and an epoxy resin (B) as essential components, the active ester resin (A) having a resin structure which includes a polyaryleneoxy structure (I) and in which aromatic carbon atoms in a plurality of the polyaryleneoxy structures (I) are linked through a structural site (II) represented by a structural formula 1 (wherein Ar represents a phenylene group, a phenylene group nuclear-substituted by 1 to 3 alkyl groups each having 1 to 4 carbon atoms, a naphthylene group, or a naphthylene group nuclear-substituted by 1 to 3 alkyl groups each having 1 to 4 carbon atoms).Type: GrantFiled: June 8, 2011Date of Patent: March 11, 2014Assignee: DIC CorporationInventors: Kazuo Arita, Etsuko Suzuki
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Patent number: 8637631Abstract: A polyphenylene ether which has a content of a metal magnetic material of 0.001 ppm or higher and lower than 1.000 ppm.Type: GrantFiled: February 24, 2011Date of Patent: January 28, 2014Assignee: Asahi Kasei Chemicals CorporationInventors: Tomohiro Kondo, Akinobu Nagai, Akira Mitsui
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Patent number: 8609802Abstract: Disclosed are a production method for a wholly aromatic liquid crystalline polyester resin, a wholly aromatic liquid crystalline polyester resin produced using the method, and a compound of the wholly aromatic liquid crystalline polyester resin. The disclosed production method for a wholly aromatic liquid crystalline polyester resin comprises the steps of synthesizing a wholly aromatic liquid crystalline polyester resin by synthesizing a wholly aromatic liquid crystalline polyester prepolymer by a condensation polymerization of a monomer and then reducing the pressure inside a reaction vessel containing the synthesized prepolymer at a predetermined internal pressure reduction rate of the reaction vessel.Type: GrantFiled: January 12, 2011Date of Patent: December 17, 2013Assignee: Samsung Fine Chemicals Co., Ltd.Inventors: Hyun Min Kim, Jong Hwa Yun, Mahn Jong Kim
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Publication number: 20130331540Abstract: Provided is a method of preparing a wholly aromatic liquid crystalline polyester resin and a wholly aromatic liquid crystalline polyester resin prepared by the method, and a compound of the wholly aromatic liquid crystalline polyester resin. The disclosed method of preparing the wholly aromatic liquid crystalline polyester resin includes a step (a first temperature increasing step) of increasing the temperature of a reaction mixture including at least one monomer at a first temperature increasing rate up to a first temperature; a step (an isothermal maintaining step) of maintaining the reaction mixture that passed through the first temperature increasing step at the first temperature for a first time; and a step (a second temperature increasing step) of increasing the temperature of the reaction mixture that passed through the isothermal maintaining step at a second temperature increasing rate.Type: ApplicationFiled: November 28, 2011Publication date: December 12, 2013Applicant: SAMSUNG FINE CHEMICALS CO., LTD.Inventors: Hyun Min Kim, Jong Hwa Yun, Mahn Jong Kim
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Patent number: 8598300Abstract: The invention provides an amorphous polyester resin that can sufficiently achieve the reciprocal performance properties of hot offset resistance and cold offset resistance, which is a major issue for a toner for electrostatic image development, while allowing adequate blocking resistance to be obtained, as well as a binder resin for toner for electrostatic image development, and an amorphous polyester resin production method, the amorphous polyester resin being obtained by reaction between a polybasic carboxylic acid compound and a polyhydric alcohol, wherein the polybasic carboxylic acid compound comprises (a) the reaction product between an aromatic polybasic carboxylic acid compound and a C2-4 glycol at 60 mol % or greater based on the total amount of the polybasic carboxylic acid compound, and the amorphous polyester resin has a glass transition point of 55° C. to 75° C. and a weight-average molecular weight of 10,000 to 50,000.Type: GrantFiled: April 23, 2010Date of Patent: December 3, 2013Assignee: Nicca Chemical Co., Ltd.Inventors: Tatsuhiro Hishida, Koji Ogawa, Yasumichi Moriyama, Masaaki Hosoda, Kazuo Tanabe
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Publication number: 20130302586Abstract: Disclosed are a copolymer that includes a repeating unit A having a repeating unit represented by Chemical Formula 1, a repeating unit represented by Chemical Formula 2, or a combination thereof; and a repeating unit B having a repeating unit represented by Chemical Formula 3, a repeating unit represented by Chemical Formula 4, or a combination thereof, as disclosed in the specification, an article including the same, and a display device including the article.Type: ApplicationFiled: January 24, 2013Publication date: November 14, 2013Applicant: SAMSUNG ELECTRONICS CO., LTD.Inventors: Byung Hee SOHN, Hyun Jeong JEON, Sang Soo LEE, Jae Jun LEE