Reactant Contains A Fused- Or Bridged-ring Other Than Solely As A Polycarboxylic Acid Anhydride Group Patents (Class 528/190)
  • Publication number: 20130231453
    Abstract: A method of preparing a wholly aromatic liquid crystalline polyester amide resin and a method of preparing a wholly aromatic liquid crystalline polyester amide resin compound. The method of preparing a wholly aromatic liquid crystalline polyester amide resin is performed using a monomer having both a hydroxyl group and an acetylamino group or using a monomer having a hydroxyl group and a monomer having an acetylamino group. In addition, the method of preparing a wholly aromatic liquid crystalline polyester amide resin compound is performed using a wholly aromatic liquid crystalline polyester amide resin that is prepared using the method.
    Type: Application
    Filed: October 21, 2011
    Publication date: September 5, 2013
    Applicant: SAMSUNG FINE CHEMICALS CO., LTD.
    Inventors: Sun Hwa Chang, Sang Mi Kang, Dae Yeon Kim
  • Patent number: 8524855
    Abstract: Environmentally-friendly, biodegradable polyol:carboxylic acid polyester solid-phase products may be produced utilizing microwave heating. In this process, a di- or tricarboxylic acid is reacted with a polyol such as a glycerol or a sugar alcohol, or an ester thereof with the application of heating by microwave energy. Sufficient microwave heating is provided to esterify the polyol with the carboxylic acids, while removing as steam the water by-product which is generated during the reaction. The polyesters so-produced are resistant to high temperatures and solvents, and may by cured and/or molded.
    Type: Grant
    Filed: May 16, 2012
    Date of Patent: September 3, 2013
    Assignee: The United States of America, as represented by the Secretary of Agriculture
    Inventors: Brent Tisserat, Ronald A. Holser, Rogers E. Harry-O'Kuru
  • Patent number: 8497342
    Abstract: A liquid crystal block copolymer comprising at least one liquid crystal polymer block comprising a polymer of diethylene glycol bis(4-hydroxybenzoate) and diphenyl 2,6-naphthalene dicarboxylate and at least one non-liquid crystal polymer block.
    Type: Grant
    Filed: April 19, 2012
    Date of Patent: July 30, 2013
    Assignee: Boston Scientific Scimed, Inc.
    Inventors: John J. Chen, Daniel J. Horn, Zhikuan Lu, Dong Zhang, Jiaokai Jing, Frank W. Harris
  • Patent number: 8497344
    Abstract: A method for obtaining a composition of an aromatic polyamide containing para-phenylene terephthalamide and 2-(p-phenylene)benzimidazole terephthalamide units, the method including copolymerizing: i) a mole % of para phenylenediamine; ii) b mole % of 5(6)-amino-2-(p-aminophenyl)benzimidazole; and iii) 90-110 mole % of terephthaloyl dichloride in a mixture of N-methyl pyrrolidone and containing c wt. % of calcium chloride, wherein c is within the range from 1 to 20, and wherein the ratio a:b ranges from 1:20 to 20:1, a+b is 100 mole %, and i), ii), and iii) together comprise 1-20 wt. % of the mixture, wherein the product b·c is at least 50 and less than 215 and that the composition is a crumb with a relative viscosity ?rel of at least 4, wherein the crumb is defined as non-sticky particles at least 95% of which having an average diameter of 0.7-15 mm.
    Type: Grant
    Filed: November 11, 2004
    Date of Patent: July 30, 2013
    Assignee: Teijin Aramid B.V.
    Inventor: Johannes Bos
  • Patent number: 8487068
    Abstract: The present invention provides a method for producing a polybenzoxazole precursor having reduced contents of residual aprotic polar solvent and residual halogen without discharging a large amount of waste water during purification. The present invention specifically relates to a method for producing a polybenzoxazole precursor, which comprises synthesizing a polybenzoxazole precursor in an aprotic polar solvent, adding and mixing water and a water-insoluble solvent with the resulting polybenzoxazole precursor solution to still stand the solution, and then separating a water layer from the solution to reduce a content of impurities remaining in the polybenzoxazole precursor.
    Type: Grant
    Filed: August 30, 2012
    Date of Patent: July 16, 2013
    Assignee: Toho Chemical Industry Co., Ltd.
    Inventor: Naoya Kutsuzawa
  • Publication number: 20130172433
    Abstract: A method for the manufacture of a polymer is provided, the method comprising: Providing a first monomer, the first monomer comprising a bicyclic diamine moiety, a first nucleophilic group provided on a carbon atom of an aromatic moiety, and a second nucleophilic group provided on a carbon atom of an aromatic moiety; Providing a bridging compound comprising at least two sites vulnerable to nucleophilic attack; and Contacting the first monomer with the bridging compound. Polymers made by said method and uses of such polymers are also disclosed.
    Type: Application
    Filed: September 15, 2011
    Publication date: July 4, 2013
    Applicant: UNIVERSITY COLLEGE CARDIFF CONSULTANTS LIMITED
    Inventors: Neil Bruce McKeown, Mariolino Carta
  • Patent number: 8466253
    Abstract: A method of purifying a capped poly(phenylene ether) includes mixing a poly(phenylene ether) capping reaction mixture comprising a capped poly(phenylene ether), a capping agent, a capping byproduct, a capping catalyst, and a poly(phenylene ether) solvent, and first washing solvents comprising a C1-C4 alkanol and water to form a first liquid phase comprising the capped poly(phenylene ether) and poly(phenylene ether) solvent, and a second liquid phase comprising C1-C4 alkanol and water; and separating the first liquid phase from the second liquid phase. Capped poly(phenylene ether) having reduced levels of residual capping agent, capping byproduct, and capping catalyst is produced from poly(phenylene ether) capping reaction mixtures by this method.
    Type: Grant
    Filed: June 29, 2012
    Date of Patent: June 18, 2013
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Prashant Kumar, Alvaro Carrillo, Scott Michael Fisher, Nitin Vilas Tople
  • Publication number: 20130123381
    Abstract: The invention includes a new photopolymerizable resin system for dental restorative materials. The resin system utilizes a thiol-ene component as the reactive diluent in dimethacrylate systems. The ternary resin system comprises a thiol monomer, an ene monomer and a dimethacrylate monomer. The system of the invention has enhanced overall functional group conversion, improved polymer mechanical properties, and reduced shrinkage stress of the ternary system when compared to either traditional dimethacrylate or thiol-ene resin systems.
    Type: Application
    Filed: January 7, 2013
    Publication date: May 16, 2013
    Applicant: The Regents of the University of Colorado, a body Corporate
    Inventor: The Regents of the University of Colorado, a body Corporate
  • Patent number: 8440780
    Abstract: A wholly aromatic liquid crystalline polyester contains 2.0 to 15.0 mole percent of a hydroquinone-derived structural unit relative to a total amount of structural units. The wholly aromatic liquid crystalline polyester has sum of an amount (a) of terminal hydroxyl group and an amount (b) of terminal acetyl group in a range of 50 to 350 equivalents/(g·10?6), and has a ratio [(a)+(b)]/(c) of the sum of the amount (a) of terminal hydroxyl group and the amount (b) of terminal acetyl group to an amount (c) of terminal carboxyl group in a range of 1.05 to 2.00.
    Type: Grant
    Filed: September 14, 2012
    Date of Patent: May 14, 2013
    Assignee: Toray Industries, Inc.
    Inventors: Mitsushige Hamaguchi, Kohei Miyamoto, Hideyuki Umetsu
  • Publication number: 20130116397
    Abstract: Methods of preparing an aromatic liquid crystalline polyester resin and an aromatic liquid crystalline polyester resin compound are disclosed. A method of preparing an aromatic liquid crystalline polyester resin may include: acetylating a first monomer including an amino group by a reaction with a carboxylic acid anhydride; acetylating a second monomer including a hydroxyl group and not including an amino acid group with an additional carboxylic acid anhydride; and synthesizing an aromatic liquid crystalline polyester prepolymer by a condensation polymerization reaction of the acetylated first and second monomers with dicarboxylic acid. A method of preparing an aromatic liquid crystalline polyester resin compound may use the aromatic liquid crystalline polyester resin prepared according to the forgoing method.
    Type: Application
    Filed: June 14, 2011
    Publication date: May 9, 2013
    Inventors: Sun Hwa Chang, Sang Mi Kang, Dae Yeon Kim, Jin Kyu Lee
  • Publication number: 20130112409
    Abstract: The invention pertains to improved proppant particles comprising an aromatic polycondensation polymer having a glass transition temperature (Tg) of at least 120° C. when measured according to ASTM 3418 [polymer (P)] and a method of treating a subterranean formation using said proppant particles.
    Type: Application
    Filed: November 2, 2012
    Publication date: May 9, 2013
    Applicant: SOLVAY SPECIALTY POLYMERS USA, LLC
    Inventor: SOLVAY SPECIALTY POLYMERS USA, LLC
  • Publication number: 20130071785
    Abstract: It is an object of the present invention to provide a new alcohol compound, a polyester resin, an unsaturated polyester resin, a resin particle and an electrophotographic toner using the compound capable of using the renewable resources as a part of a raw material. An alcohol compound according to the present invention is characterized by representing the chemical formula [Chemical 1]. Furthermore, the polyester resin or the unsaturated polyester resin according to the present invention, is characterized in that the compound (wherein X is an aliphatic or an aromatic residue, Y is a refined rosin residue, a disproportionated rosin residue or a hydrogenated rosin residue, and n=0 to 1 in the formula.) is an essential component of an alcohol component. Further, the resin particle of the present invention is characterized by comprising the polyester resin.
    Type: Application
    Filed: March 2, 2011
    Publication date: March 21, 2013
    Applicant: Japan U-Pica Company, Ltd.
    Inventors: Tetsuji Moroiwa, Nobutaka Yoshida, Hiroshi Aihara, Akira Yamane, Kei Yamasaki, Keiko Taniuchi
  • Patent number: 8389662
    Abstract: Disclosed herein is a polycarbonate polymer comprising: an isosorbide unit, a polysiloxane unit, and an aliphatic unit different from the isosorbide unit, wherein the isosorbide unit, polysiloxane unit, and aliphatic unit are each carbonate, or a combination of carbonate and ester units, the aliphatic unit different from the isosorbide unit is derived from an aliphatic oligomer having a molecular weight of 900 to 4000, and the calculated bio-content is greater than or equal to 40 weight percent, based on the total weight of the polycarbonate polymer.
    Type: Grant
    Filed: September 29, 2010
    Date of Patent: March 5, 2013
    Assignee: SABIC Innovative Plastics IP B.V.
    Inventors: Hans de Brouwer, Robert Dirk van de Grampel, Jan Henk Kamps, Jan-Pleun Lens, Hendrik Theodurus van de Grampel
  • Publication number: 20130053531
    Abstract: A method for lowering melt viscosity of a liquid crystalline polymer as it is formed in a reactor vessel. More particularly, a reaction mixture is initially supplied to the reactor vessel that contains two or more precursor monomers (e.g., acetylated or non-acetylated). The reaction mixture is heated to an elevated temperature under agitation to initiate formation of the polymer. After a certain period of time, an aromatic amide oligomer is added to the reaction mixture. Among other things, the present inventors have discovered that such an oligomer can serve as a flow aid by altering intermolecular polymer chain interactions, thereby lowering the overall viscosity of the polymer matrix under shear. This minimizes the likelihood of “freeze off” of the polymer within the reactor vessel and limits the impact of process disruptions on the production of the liquid crystalline polymer.
    Type: Application
    Filed: August 27, 2012
    Publication date: February 28, 2013
    Applicant: TICONA LLC
    Inventors: Kamlesh P. Nair, Steven D. Gray
  • Publication number: 20130048908
    Abstract: A thermotropic liquid crystalline polymer composition capable of exhibiting both a low melting temperature and good heat resistance without the use of conventional naphthenic acids is provided. The melting temperature may, for example, range from about 250° C. to about 400° C. Even at such low melting temperatures, the present inventors have surprisingly discovered that the ratio of the deflection temperature under load (“DTUL”), a measure of short term heat resistance, to the melting temperature may remain relatively high. The specific DTUL values may range from about 200° C. to about 300° C. The ability to form a polymer composition with the properties noted above may be achieved, at least in part, by the use of an aromatic amide oligomer.
    Type: Application
    Filed: August 27, 2012
    Publication date: February 28, 2013
    Applicant: TICONA LLC
    Inventors: Steven D. Gray, Kamlesh P. Nair, Joseph J. Grenci
  • Patent number: 8372943
    Abstract: Provided herein are isosorbide-based bisphenol polymer structural units and methods of making the same. These structural units may be polymerized with one or more other types of structural units to form polymers, such as polycarbonates.
    Type: Grant
    Filed: December 10, 2010
    Date of Patent: February 12, 2013
    Assignee: SABIC Innovative Plastics IP B.V.
    Inventor: Jean Francois Morizur
  • Patent number: 8337719
    Abstract: The present invention provides a resin composition containing a liquid crystalline polyester and a high dielectric material filler. The present invention also provides a molded article of the liquid crystalline polyester resin composition. The liquid crystalline polyester resin composition of the present invention comprises 50 to 80% by volume of a liquid crystalline polyester which has 40% by mol or more of a 2,6-naphthalenediyl group as an aromatic group, also has a flow initiation temperature of 280° C. or higher, and shows a melt tension of 1 g or more measured at a temperature higher than flow initiation temperature; and 20 to 50% by volume of a high dielectric material filler. The liquid crystalline polyester resin composition can be formed into composition pellets easily and stably by a strand method, and a molded article obtained from the liquid crystalline polyester resin composition is excellent in flexural strength and dielectric characteristics.
    Type: Grant
    Filed: December 2, 2008
    Date of Patent: December 25, 2012
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Tomoya Hosoda, Tomoko Uehara, Satoshi Okamoto
  • Publication number: 20120301725
    Abstract: An intermediate transfer member that includes spirodilactam polycarbonates, mixtures of spirodilactam polycarbonates or copolymers of spirodilactam polycarbonates, an optional polysiloxane, and an optional conductive filler component.
    Type: Application
    Filed: May 24, 2011
    Publication date: November 29, 2012
    Applicant: XEROX CORPORATION
    Inventor: Jin WU
  • Publication number: 20120277398
    Abstract: The invention relates to an insulating film for an electromagnetic coil which is composed of a liquid crystal polyester, in which the liquid crystal polyester has a structural unit represented by the following formula (1), a structural unit represented by the following formula (2), and a structural unit represented by the following formula (3), and the amount of the structural units including a 2,6-naphthalenediyl group is 40 mol % or more with respect to the total amount of all the structural units.
    Type: Application
    Filed: December 6, 2010
    Publication date: November 1, 2012
    Inventors: Tomoya Hosoda, Satoshi Okamoto
  • Publication number: 20120216859
    Abstract: An object of the present invention is to provide a back sheet for a solar cell that improves weather resistance while also being advantageous in terms of cost. In a back sheet 7 for a solar cell of a preferred embodiment, a liquid crystal polyester that composes a liquid crystal polyester base material is formed of structural units represented by the following formulas (1), (2) and (3).
    Type: Application
    Filed: August 10, 2010
    Publication date: August 30, 2012
    Inventors: Satoshi Okamoto, Tomoya Hosoda
  • Patent number: 8247519
    Abstract: The invention is directed to shaped articles fabricated from polyamides comprising fluoroether functionalized aromatic moieties. Particular polyamides include nylon 6, 6 and nylon 6 copolyamides that comprise fluoroether functionalized aromatic amide repeat units. The shaped articles hereof are characterized by reduced surface tension and are useful for imparting soil resistant films, molded parts, fibers, fabrics, and carpets.
    Type: Grant
    Filed: June 22, 2011
    Date of Patent: August 21, 2012
    Assignee: E I du Pont de Nemours and Company
    Inventors: Neville Everton Drysdale, David Neil Marks, Fredrik Nederberg
  • Patent number: 8247518
    Abstract: A multi-layer polymer film for printing and copying of the present invention comprising a two-layer polymer base film composed of layer A and layer B laminated on one side of the layer A, the layer B containing a filler in an amount of 50 to 3000 ppm and the layer A containing no filler or a filler in an amount of at least 1000 ppm and less than the B layer; an image receiving layer coated on the exposed surface of the layer A; and an antistatic layer coated on the exposed surface of the layer B, wherein the layer A having the image receiving coating layer and the layer B having the antistatic coating layer have average degrees of surface roughness (Ra) ranging from 10 to 60 nm and 50 to 150 nm, respectively, exhibits improved properties in terms of runnability, printing, optical (haze), antistatic, friction coefficient and anti-blocking properties, which can be advantageously used as an OHP film.
    Type: Grant
    Filed: May 29, 2009
    Date of Patent: August 21, 2012
    Assignee: SKC Inc.
    Inventors: Taehoung Jeong, Kwang Soo Choi, Mary Elizabeth Klima
  • Patent number: 8207287
    Abstract: Disclosed are polymers derived from units of bisphenol compounds, such as tetramethylcyclobutane diol-bisphenol, and processes for making and using them.
    Type: Grant
    Filed: June 7, 2011
    Date of Patent: June 26, 2012
    Assignee: SABIC Innovative Plastics IP B.V.
    Inventor: Jean-Francois Morizur
  • Publication number: 20120119142
    Abstract: A liquid crystalline polyester has a specifically high fluidity, a low anisotropy, a high toughness, a low gas property, an excellent heat resistance and a high dielectric breakdown resistance. The liquid crystalline polyester includes 38 to 74 mol % of structural unit(s) obtained from a hydroxycarboxylic acid, 31 to 13 mol % of a structural unit obtained from 4,4?-dihydroxybiphenyl and 31 to 13 mol % of a structural unit obtained from 2,6-naphthalenedicarboxylic acid (100 mol % in total), characterized in that the hydroxycarboxylic acid structural units include a structural unit obtained from 2-hydroxy-6-naphthoic acid in an amount of 89 mol % or more and the average sequence length of the structural unit obtained from 2-hydroxy-6-naphthoic acid is 0.1 to 1.
    Type: Application
    Filed: August 11, 2009
    Publication date: May 17, 2012
    Applicant: TORAY INDUSTRIES, INC.
    Inventors: Keiko Osato, Koji Tachikawa, Hideyuki Umetsu
  • Patent number: 8178646
    Abstract: The present invention provides a method for producing a liquid-crystalline polyester powder, the method comprising: carrying out melt polycondensation of monomers and/or its acylated monomers to obtain a corresponding polyester having a flow initiation temperature of 240 to 300° C.; spreading and solidifying the polyester so as to be a layer thereof with a thickness of 1 cm or more: crushing the solidified substance to obtain a powder having a volume average particle diameter of 3 to 30 ?m; and subjecting the powder to a heat treatment to obtain a powder having a flow initiation temperature higher than the flow initiation temperature of the liquid-crystalline polyester after the melt polycondensation.
    Type: Grant
    Filed: March 28, 2011
    Date of Patent: May 15, 2012
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Yusaku Kohinata, Tomoya Hosoda, Satoshi Okamoto
  • Patent number: 8138300
    Abstract: There is disclosed an intermediate transfer member that includes a layer of a poly(imide-carbonate) copolymer having dispersed therein conductive particles. The layer can be a surface layer.
    Type: Grant
    Filed: September 21, 2010
    Date of Patent: March 20, 2012
    Assignee: Xerox Corporation
    Inventors: Yu Qi, Nan-Xing Hu, Jin Wu
  • Patent number: 8129493
    Abstract: There is provided an aromatic polyester suitable for optical applications, which has not only high heat resistance and transparency, but also enhanced fluidity at a relatively low molding temperature of less than 300° C. despite its high molecular weight to be substantially colorless after the molding process. The aromatic polyester of the present invention comprises polyhydric phenol residues and residues of aromatic polycarboxylic acid, acid halide or acid anhydride thereof; wherein the polyhydric phenol residues comprise polyhydric phenol residues represented by Formula (I): —O—Ar—W1x—Ar—O— and/or Formula (II): —O—Ar—O—, and bulky polyhydric phenol residues represented by Formula (III): —O—Ar—W2—Ar—O—; wherein the molar ratio of the polyhydric phenol residues represented by Formula (I) and/or Formula (II) to the polyhydric phenol residues represented by Formula (III) is in the range of 100:0 to 30:70 (exclusive of 100:0).
    Type: Grant
    Filed: August 30, 2010
    Date of Patent: March 6, 2012
    Assignees: Muroran Institute of Technology, Nitta Corporation
    Inventors: Masayoshi Tabata, Takayoshi Yamazaki
  • Patent number: 8124225
    Abstract: An aqueous floor care composition comprising water, polymer particles wherein the polymer particles include units derived from a conjugated diene monomer, units derived from an acidic monomer, and units derived from a hard, non-acidic monomer, an external crosslinking agent, and optionally one or more of a leveling agent, surfactant, polyurethane, alkali-soluble resin, coalescing agent, plasticizer, and wax.
    Type: Grant
    Filed: July 17, 2007
    Date of Patent: February 28, 2012
    Assignee: OMNOVA Solutions Inc.
    Inventors: Kyung Don Kim, James Gaston, II
  • Patent number: 8084569
    Abstract: A liquid-phase process is provided for the synthesis from glutarimidines of diaminopyridines and related compounds, which are used industrially as compounds and as components in the synthesis of a variety of useful materials. The synthesis proceeds by means of a dehydrogenative aromatization process.
    Type: Grant
    Filed: December 18, 2007
    Date of Patent: December 27, 2011
    Assignee: E.I. DuPont de Nemours and Company
    Inventors: Aaron Minter, Berlin Stokes
  • Patent number: 8071711
    Abstract: The present invention provides a liquid-crystalline polyester having a structural unit represented by the formula (i), a structural unit represented by the formula (ii) and a structural unit represented by the formula (iii): wherein Ar1 is, at each occurrence, a member selected from the group consisting of a 2,6-naphthalenediyl group, a 1,4-phenylene group and a 4,4?-biphenylene group; and Ar2 and Ar3 are, at each occurrence, a member selected from the group consisting of a 2,6-naphthalenediyl group, a 1,4-phenylene group, a 1,3-phenylene group and a 4,4?-biphenylene group; wherein 40% by mole or more of all the groups Ar1, Ar2 and Ar3 are 2,6-naphthalenediyl groups; and wherein the polyester has a flow initiation temperature of from about 280 to about 320° C.
    Type: Grant
    Filed: August 10, 2009
    Date of Patent: December 6, 2011
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Tomoya Hosoda, Yusaku Kohinata, Satoshi Okamoto
  • Publication number: 20110282025
    Abstract: A diol from which a resin material having high processability and a high refractive index can be manufactured, a polycarbonate resin and a polyester resin which is a polymer of the diol, and a molded article and an optical element formed of the polymer. The diol is represented by the general formula (1) shown below; the polycarbonate resin and the polyester resin are polymers thereof; and the molded article and the optical element are formed of the polymers, wherein R1 and R2 each independently denote one of a hydrogen atom and an alkyl group having 1 or more and 6 or less carbon atoms; Q denotes one of an oxyethylene group, a thioethylene group and a single bond.
    Type: Application
    Filed: March 10, 2010
    Publication date: November 17, 2011
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Katsumoto Hosokawa, Takahiro Kojima, Toshikazu Takata, Kazuko Nakazono, Yasuhiro Kohsaka, Yasuhito Koyama, Toshihide Hasegawa, Ryota Seto
  • Publication number: 20110240353
    Abstract: The present invention provides a method for producing a liquid-crystalline polyester powder, the method comprising: carrying out melt polycondensation of monomers and/or its acylated monomers to obtain a corresponding polyester having a flow initiation temperature of 240 to 300° C.; spreading and solidifying the polyester so as to be a layer thereof with a thickness of 1 cm or more: crushing the solidified substance to obtain a powder having a volume average particle diameter of 3 to 30 ?m; and subjecting the powder to a heat treatment to obtain a powder having a flow initiation temperature higher than the flow initiation temperature of the liquid-crystalline polyester after the melt polycondensation.
    Type: Application
    Filed: March 28, 2011
    Publication date: October 6, 2011
    Inventors: Yusaku KOHINATA, Tomoya HOSODA, Satoshi OKAMOTO
  • Patent number: 8030441
    Abstract: A loose mixture formed of one or more solid inert materials and a hardenable resin dissolved in an organic solvent, in particular the remainder of the initial mix used for the manufacture of conglomerate stone sheets, is rendered inert by means of dielectric heating at a frequency of less than 300 MHz. A plant for implements a method where a loose mixture is formed of one or more solid inert materials and a hardenable resin dissolved in an organic solvent, in particular the remainder of the initial mix used for the manufacture of conglomerate stone sheets, is rendered inert by means of dielectric heating at a frequency of less than 300 MHz.
    Type: Grant
    Filed: July 10, 2007
    Date of Patent: October 4, 2011
    Inventor: Dario Toncelli
  • Publication number: 20110233462
    Abstract: The present invention provides a class of thermotropic liquid crystalline polyesters (TLCPs) and molding compositions comprising the polyesters and glass fiber. The TLCPs consist essentially of repeat units derived from p-hydroxybenzoic acid (HBA), 6-hydroxy-2-naphthoic acid (HNA), terephthalic acid (TA), and hydroquinone (HQ), and the mole percent of HBA, HNA, TA and HQ is 34-72%, 12-26%, 4-21% and 4-21%, respectively. The TLCPs have a melting temperature equal to or below 355° C., an inherent viscosity of 4.0-10.0 dL/g and a Heat Deflection Temperature (HDT) in the range of 260-285° C. when compounded with 30% by weight glass fiber. The optimum compositions, selected from the above-mentioned compositional ranges exhibit a relatively low melting temperature and a relatively high HDT. Specified compositions, selected from the above-mentioned compositional ranges have low melting point, which are useful to blend with conventional polymers such as poly (ethylene terephthalate) and nylon etc.
    Type: Application
    Filed: November 17, 2009
    Publication date: September 29, 2011
    Applicant: Shanghai Pret Composites Co., Ltd.
    Inventors: Haishan Bu, Xiuzhen Wang, Wen Zhou
  • Patent number: 8022167
    Abstract: A liquid-phase process is provided for the manufacture from glutaronitriles and related compounds of 2,6-diaminopyridine and related compounds, which are used industrially as compounds and as components in the synthesis of a variety of useful materials. The synthesis proceeds by means of a dehydrogenative aromatization process.
    Type: Grant
    Filed: December 18, 2007
    Date of Patent: September 20, 2011
    Inventors: Aaron Minter, Berlin Stokes
  • Patent number: 8013104
    Abstract: Hyperbranched polymers and methods for preparing the same are disclosed. The polymers are obtained based on monomers synthesized via reacting a substituted or unsubstituted cyclic anhydride with a bifunctional amine.
    Type: Grant
    Filed: August 13, 2009
    Date of Patent: September 6, 2011
    Assignee: Designer Molecules, Inc.
    Inventor: Stephen M. Dershem
  • Patent number: 7999059
    Abstract: The invention relates to an optical film containing aromatic polymer which shows high solubility to solvents, and methods for production thereof. Further, the invention also relates to an optical laminate, a polarizing plate, and an image display device each using the optical film. The optical film may be attained by using polyester with a specific structure. The polyester with a specific structure may be obtained by condensation polymerization of bisphenol compound(s) and dicarboxylic acid compound(s) with biphenyl structure, and preferably has no halogen atom in its chemical structure. The optical film of the invention advantageously has not only high solubility in solvents but also a high level of heat resistance and birefringence producing capability. When the content of the biphenyl structure is high, the optical film of the invention can also have large wavelength dispersion of birefringence.
    Type: Grant
    Filed: November 6, 2008
    Date of Patent: August 16, 2011
    Assignee: Nitto Denko Corporation
    Inventors: Tomoyuki Hirayama, Toshiyuki Iida, Yutaka Ohmori, Miyuki Kurogi, Hisae Shimizu
  • Patent number: 7999057
    Abstract: A gas-phase, continuous process is provided for the manufacture of 2,6-diaminopyridine and related compounds from glutaronitriles, which are used industrially as compounds and as components in the synthesis of a variety of useful materials. The synthesis proceeds by means of a dehydrogenative aromatization process.
    Type: Grant
    Filed: July 8, 2008
    Date of Patent: August 16, 2011
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Keith W. Hutchenson, Aaron Minter, Gregg Sunshine
  • Patent number: 7999055
    Abstract: The present invention can provide a polycarbonate resin containing a structural unit represented by the following formula (1). wherein R represents one selected from an alkyl group having 1 to 9 carbon atoms, an aryl group having 6 to 12 carbon atoms, an alkenyl group having 2 to 5 carbon atoms, an alkoxy group having 1 to 5 carbon atoms, an aralkyl group having 7 to 17 carbon atoms, and halogen; and n represents the number of substituting R's on a benzene ring and is an integer of 0 to 4. Y represents an alkylene group having 1 to 4 carbon atoms; and p is an integer of 0 to 4.
    Type: Grant
    Filed: May 19, 2008
    Date of Patent: August 16, 2011
    Assignee: Mitsubishi Gas Chemical Company, Inc
    Inventors: Shu Yoshida, Toshiaki Yamada
  • Patent number: 7956154
    Abstract: A polymer containing a polyester polymer unit having the formula -(I-III-II)-, wherein III is derived form a di-carboxylic acid, wherein I is derived from 1,3 cyclohexanedimethanol, wherein II is derived from 1,4 cyclohexanedimethanol and wherein the polymer is a solid at room temperature.
    Type: Grant
    Filed: September 26, 2006
    Date of Patent: June 7, 2011
    Inventors: John N. Argyropoulos, Marcos Pini Franca, Gary E. Spilman
  • Publication number: 20110092662
    Abstract: There is provided an aromatic polyester suitable for optical applications, which has not only high heat resistance and transparency, but also enhanced fluidity at a relatively low molding temperature of less than 300° C. despite its high molecular weight to be substantially colorless after the molding process. The aromatic polyester of the present invention comprises polyhydric phenol residues and residues of aromatic polycarboxylic acid, acid halide or acid anhydride thereof; wherein the polyhydric phenol residues comprise polyhydric phenol residues represented by Formula (I): —O—Ar—W1x—Ar—O— and/or Formula (II): —O—Ar—O—, and bulky polyhydric phenol residues represented by Formula (III): —O—Ar—W2—Ar—O—; wherein the molar ratio of the polyhydric phenol residues represented by Formula (I) and/or Formula (II) to the polyhydric phenol residues represented by Formula (III) is in the range of 100:0 to 30:70 (exclusive of 100:0).
    Type: Application
    Filed: August 30, 2010
    Publication date: April 21, 2011
    Inventors: Masayoshi TABATA, Takayoshi Yamazaki
  • Patent number: 7906212
    Abstract: This invention relates to thermoplastic article having one or more decorative materials embedded therein which is obtained by applying heat and pressure to one or more laminates wherein at least one of said laminates comprises, in order, (1) an upper sheet material; (2) one or more decorative materials; and (3) a lower sheet material; wherein the upper and lower sheet materials are formed from a polyester/aromatic polycarbonate blend wherein the thermoplastic article comprises at least one polyester composition comprising at least one polyester which comprises terephthalic acid and 2,2,4,4-tetramethyl-1,3,-cyclobutanediol.
    Type: Grant
    Filed: March 16, 2010
    Date of Patent: March 15, 2011
    Assignee: Eastman Chemical Company
    Inventors: Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell
  • Patent number: 7906211
    Abstract: This invention relates to thermoplastic article having one or more decorative materials embedded therein which is obtained by applying heat and pressure to one or more laminates wherein at least one of said laminates comprises, in order, (1) an upper sheet material; (2) one or more decorative materials; and (3) a lower sheet material; wherein the upper and lower sheet materials are formed from a polyester/aromatic polycarbonate blend wherein the thermoplastic article comprises at least one polyester composition comprising at least one polyester which comprises terephthalic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol.
    Type: Grant
    Filed: March 16, 2010
    Date of Patent: March 15, 2011
    Assignee: Eastman Chemical Company
    Inventors: Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell
  • Patent number: 7897720
    Abstract: Disclosed is a method for removing a metallic compound catalyst residue from a polymer solution which is prepared in the presence of a catalyst containing metal of Group 10 using a thiourea compound, a polymer from which the metallic compound catalyst residue is removed using the method, and a film produced using the method.
    Type: Grant
    Filed: November 7, 2007
    Date of Patent: March 1, 2011
    Assignee: LG Chem, Ltd.
    Inventors: Sung-Cheol Yoon, Hye-Young Jung, Sung-Ho Chun
  • Patent number: 7884173
    Abstract: To provide an aromatic polyester which is formed into a film having excellent heat resistance, color, mechanical properties, dimensional stability and gas barrier properties and a manufacturing process thereof; the aromatic polyester comprises a dicabroxylic acid component and a diol component, wherein (i) the dicarboxylic acid component contains 50 to 100 mol % of a recurring unit represented by the following formula (A): ?wherein R is an alkylene group having 2 to 10 carbon atoms, (ii) the aromatic polyester has an intrinsic viscosity measured at 35° C. by using a mixed solvent of P-chlorophenol and 1,1,2,2-tetrachloroethane (weight ratio of 40/60) of 0.4 to 3.0; (iii) the aromatic polyester has a content of a recurring unit represented by the following formula (D) of less than 10 mol %: —O—CH2CH2—O—CH2CH2—O—??(D) (iv) the aromatic polyester has a terminal carboxyl group concentration of 200 eq/ton or less; and (v) the aromatic polyester has an alkali metal content of 300 ppm or less.
    Type: Grant
    Filed: July 19, 2007
    Date of Patent: February 8, 2011
    Assignee: Teijin Limited
    Inventors: Kazuteru Kohno, Eiji Kinoshita, Tomoyuki Kishino
  • Publication number: 20110006294
    Abstract: Disclosed is a layered structure including a first electrode and a second electrode, a light-emitting layer or a charge separation layer between the first electrode and the second electrode, and a layer containing a conjugated polymer compound between the light-emitting layer or the charge separation layer and the first electrode, wherein the conjugated polymer compound contains a repeating unit selected from the group consisting of a repeating unit represented by formula (1): wherein Ar1 represents a divalent aromatic group, R1 represents a substituent group having a group represented by formula (2), Ar1 may have a substituent group other than R1, and n1 represents an integer of 1 or more; -(R2)c1-(Q1)n2-Y1(M1)a1(Z1)b1??(2) wherein R2 represents a divalent aromatic group which may have a substituent group, Q1 represents a divalent organic group which may have a substituent group, Y1 represents a carbocation, an ammonium cation, a phosphonyl cation or a sulfonyl cation, M1 represents F?, Cl?, Br?, I?,
    Type: Application
    Filed: March 5, 2009
    Publication date: January 13, 2011
    Applicant: Sumitomo Chemical Company, Limited
    Inventors: Masanobu Tanaka, Kenta Tanaka, Shohgo Yamauchi, Hideyuki Higashimura
  • Patent number: 7858728
    Abstract: Disclosed herein is a polycarbonate comprising a terminal olefin group of the formula wherein R1 is a C1-C40 hydrocarbon that can be unsubstituted or substituted with a halogen, olefin, ether, ketone, or C4-C30 polyoxyalkylene functionality in which the alkylene groups contain 2 to 6 carbon atoms, R2 to R4 are each independently a hydrogen or a C1-C40 hydrocarbon that can be unsubstituted or substituted with a halogen, olefin, ether, ketone, or a C4-C30 polyoxyalkylene functionality in which the alkylene groups contain 2 to 6 carbon atoms, and optionally wherein any two of R1 to R4 together form a monocyclic, bicyclic, or tricyclic ring system optionally substituted with a heteroatom in each ring.
    Type: Grant
    Filed: October 19, 2007
    Date of Patent: December 28, 2010
    Assignee: SABIC Innovative Plastics IP B.V.
    Inventors: Hans-Peter Brack, Bernard Jansen, Jan Henk Kamps, Hans Looij, Han Vermeulen, Dennis Willemse
  • Patent number: 7848025
    Abstract: Disclosed herein is a camera lens comprising a thermoplastic composition comprising a poly(aliphatic ester)-polycarbonate copolymer comprising soft block ester units derived from an alpha, omega C6-20 aliphatic dicarboxylic acid or derivative thereof, a dihydroxyaromatic compound, and a carbonate source, wherein the thermoplastic composition has a melt volume rate of 13 to 25 cc/10 min at 250° C. and under a load of 1.2 Kg and a dwell time of 6 minutes, according to ASTM D1238-04, and wherein the camera lens has an effective lens area of 0.5 to 100 mm2. A method of making the camera lens, and a camera lens comprising a thermoplastic composition comprising a redistribution product of a poly(aliphatic ester)-polycarbonate, are also disclosed.
    Type: Grant
    Filed: December 31, 2008
    Date of Patent: December 7, 2010
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Akira Hatano, Theodorus Lambertus Hoeks, Dennis Karlik, Ken Kuriki, Jon M. Malinoski, Sriramakrishna Maruvuda
  • Patent number: 7838602
    Abstract: A multilayer article comprises a substrate layer, and a coating layer in contiguous superposed contact with the substrate layer, the coating layer comprising a thermostable, weatherable polymer comprising structural units derived from at least one 1,3-dihydroxybenzene moiety, at least one aromatic dicarboxylic acid moiety, at least one bisphenol moiety, and at least one soft-block moiety derived from a siloxane oligomer, in which the multilayer article comprises the substrate layer and the coating layer, or the substrate layer with coating layers on each side of the substrate layer.
    Type: Grant
    Filed: January 26, 2007
    Date of Patent: November 23, 2010
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Gary C Davis, Brian D Mullen, Paul D Sybert
  • Patent number: 7816014
    Abstract: The present invention provides a liquid crystalline polyester comprising (a) a repeating unit derived from aromatic hydroxycarboxylic acid, (b) a repeating unit derived from aromatic dicarboxylic acid and (c) a repeating unit represented by —X—Ar1-O—Ar1-Y—, wherein Ar1 represents 1,4-phenylene which may be substituted by a halogen atom, an alkyl group having 1 to 10 carbon atoms or an aryl group having 6 to 20 carbon atoms, and X and Y independently represent O or NH. The polyester in the preset invention has a sufficiently low dielectric constant and/or is a sufficiently high resistance in hydrolysis.
    Type: Grant
    Filed: January 13, 2006
    Date of Patent: October 19, 2010
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Toyonari Ito, Tomoya Hosoda, Satoshi Okamoto