Two Or More Phenolic Reactants Patents (Class 528/193)
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Patent number: 12187947Abstract: An aromatic liquid crystal polyester, having repeating units represented by formulae (1) and (2), respectively: where R?, Ar1, Ar2, Ar3, X, Y1, Y2 and Z are those as defined in the specification. Also, a liquid crystal polyester composition including the aromatic liquid crystal polyester and a solvent. The composition has an improved viscosity stability. Also, a liquid crystal polyester film prepared from the liquid crystal polyester composition and a method for manufacturing the same. The liquid crystal polyester film has excellent properties such as a low hygroscopicity and a low dissipation factor (Df).Type: GrantFiled: May 28, 2021Date of Patent: January 7, 2025Assignee: ETERNAL MATERIALS CO., LTD.Inventors: Jia-Cheng Chang, Wei-Ting Yeh, Wen-Cheng Liu
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Patent number: 12063984Abstract: A knitted quilt fabric is made of a first layer of a first knit material and a second layer of a second knit material, with a filler material composed of a plurality of plaited lay-in fibers between the two layers. The first layer and second layer are joined at a plurality of locations with knits forming at least one linear quilt line. Each knit of the linear quilt line is formed around a plaited lay-in fiber by knitting a first fiber of the first material to the second material and returning to the first material and knitting a second fiber of the second material to the first material and returning to the second material. Each lay-in fiber is an elastic polyether-polyurea copolymer which is plaited with one or more natural or synthetic yarns.Type: GrantFiled: November 23, 2020Date of Patent: August 20, 2024Assignee: PURE MEDICAL, INC.Inventor: Israel Hernandez
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Patent number: 11932725Abstract: The present invention relates to a biodegradable polyester resin, in which the first repeat unit comprising a first diol residue and an aromatic dicarboxylic acid residue and the second repeat unit comprising a second diol residue and an aliphatic dicarboxylic acid residue satisfy a ratio of the number of repeat units in a specific range, and the softness index of the resin satisfies a specific range, and to a process for preparing the same. Since the biodegradable polyester resin can provide a biodegradable polyester sheet or film that can be simultaneously enhanced in productivity, processability, and moldability and is excellent in tensile strength, tear strength, and friction coefficient and excellent in biodegradability and water degradability, it can be utilized in more diverse fields.Type: GrantFiled: April 24, 2023Date of Patent: March 19, 2024Assignee: Ecovance Co. Ltd.Inventors: Kyung Youn Kim, Hoon Kim, Seong Dong Kim, Ji Yeon Ryu, Hyung Mo Kim
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Patent number: 11753831Abstract: A floor panel for an aircraft or spacecraft. The floor panel has a panel-like portion and an additional structure. A first side of the panel-like portion forms part of a floor surface in the aircraft or spacecraft. The additional structure is connected to the panel-like portion on a second side of the panel-like portion that is opposite the first side. The panel-like portion and the additional structure each comprise a matrix material formed by a thermoplastic material. Endless reinforcing fibers are embedded in the matrix material of the panel-like portion. Discontinuous reinforcing fibers are embedded in the matrix material of the additional structure. An aircraft or spacecraft may have a floor area which is formed by a planar arrangement of floor panels of this type. The method for producing a floor panel for an aircraft or spacecraft is provided.Type: GrantFiled: March 11, 2021Date of Patent: September 12, 2023Assignee: AIRBUS OPERATIONS GMBHInventor: Torsten Noebel
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Patent number: 11649203Abstract: Disclosed are new classes of diphenol compounds, derived from tyrosol or tyrosol analogues, which are useful as monomers for preparation of biocompatible polymers. Also disclosed are biocompatible polymers prepared from these monomeric diphenol compounds, including novel biodegradable and/or bioresorbable polymers of formula These biocompatible polymers or polymer compositions with enhanced bioresorbabilty and processibility are useful in a variety of medical applications, such as in medical devices and controlled-release therapeutic compositions. The invention also provides methods for preparing these monomeric diphenol compounds and biocompatible polymers.Type: GrantFiled: August 4, 2020Date of Patent: May 16, 2023Assignee: RUTGERS, THE STATE UNIVERSITY OF NEW JERSEYInventors: Durgadas Bolikal, Joachim B. Kohn
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Patent number: 11091592Abstract: The polymerizable composition of the present application may exhibit a wide process window to have excellent workability, and may form a phthalonitrile resin having excellent heat resistance or a prepolymer thereof.Type: GrantFiled: October 18, 2017Date of Patent: August 17, 2021Assignee: LG CHEM, LTD.Inventors: Ki Ho Ahn, Sang Woo Kim, Seung Hee Lee, Yulliana Kim
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Patent number: 10640606Abstract: A resin composition and method for installing a pipe liner that allows the liner to be fully wet out with a resin and activator and stored for a period of up to six months prior to installation and curing. A method of lining a pipe with a delayed curing resin composition is also provided that includes fully wetting out a liner with a blended two part epoxy composition such that the liner can be transported in a wet out fashion, placed in a pipe to be lined and repositioned as needed without concern for the resin composition to begin curing.Type: GrantFiled: August 10, 2018Date of Patent: May 5, 2020Assignee: Warren Environmental & Coating, LLCInventor: Danny Warren
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Patent number: 10428178Abstract: The invention relates to a polyester resin for toner to be used in the development of an electrostatic image or magnetic latent image in electrophotography, electrostatic recording, electrostatic printing, or the like, a method for producing a polyester resin for toner, and a toner, and an object of the invention is to provide, with excellent productivity and stability, a polyester resin for toner having excellent storage stability, hot offset resistance, and low temperature fixing property as toner while still considering the environmental protection and safety. A polyester resin for toner contains 40 mol % or more and 60 mol % or less of structural units derived from tri- or higher hydric carboxylic acids based on 100 mol % of structural units derived from all acid components, and has a metal content of 100 ppm or less.Type: GrantFiled: January 20, 2016Date of Patent: October 1, 2019Assignee: Mitsubishi Chemical CorporationInventors: Yoko Tamura, Tadahiro Ozawa, Akifumi Kondo
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Patent number: 9809735Abstract: The present invention relates to: (i) a resin composition having excellent thermal conductivity and capable of being processed into a thin-walled and flexible molded article, the resin composition containing: (a) a resin consisting of 40 to 60 mol % of a unit (A) having a biphenyl group, and 5 to 40 mol % of a linear unit (B), and 5 to 40 mol % of a linear unit (C), where a thermal conductivity of the resin itself is not less than 0.4 W/(m·K); and (b) an inorganic filler having thermal conductivity of not less than 1 W/(m·K), (ii) a heat-dissipating or heat-transferring resin material containing the resin composition, and (iii) a thermally conductive membrane containing the resin composition.Type: GrantFiled: November 13, 2014Date of Patent: November 7, 2017Assignee: Kaneka CorporationInventors: Shusuke Yoshihara, Syoji Ubukata, Kazuaki Matsumoto
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Patent number: 9464165Abstract: The present invention provides a method of preparing a polyester-based polymer and a polyester-based polymer prepared by the method. The method of preparing the polyester-based polymer includes a prepolymerization step of polymerizing a dicarboxylic acid compound (A), a diol compound (B), and an aromatic branching agent (C) at 160-220° C. to produce a prepolymer; and a condensation polymerization step of performing a condensation polymerization of the prepolymer at 200-250° C., under a vacuum pressure of 0.1 to 2 Torr.Type: GrantFiled: July 30, 2013Date of Patent: October 11, 2016Assignee: LOTTE FINE CHEMICAL CO., LTD.Inventors: Hee Soo Kim, Ye Jin Kim, Soo Youn Choi, Min Kyoung Kim, Ki Chull Yun
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Patent number: 9447059Abstract: The present invention pertains to a compound represented by a formula (I) and a method for producing thereof (in the formula, Ax is an organic group having 2 to 30 carbon atoms that includes at least one aromatic ring selected from a group consisting of an aromatic hydrocarbon ring and an aromatic hetero ring, Ay is a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, a cycloalkyl group, an alkenyl group having 2 to 18 carbon atoms, an organic group having 2 to 30 carbon atoms that includes at least one aromatic ring selected from a group consisting of an aromatic hydrocarbon ring and an aromatic hetero ring, or the like. Ax and Ay optionally bond to each other to form a ring, and Q is a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, or the like.).Type: GrantFiled: April 27, 2012Date of Patent: September 20, 2016Assignee: ZEON CORPORATIONInventors: Kei Sakamoto, Kumi Okuyama, Yasushi Nakano
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Patent number: 9238712Abstract: A polymer includes a monomeric repeat unit represented by Formula I: In Formula I, R1 is alkyl, alkenyl, alkynyl, aryl, heteroaryl, cycloalkyl, or heterocyclyl; R2 is alkyl, haloalkyl, alkenyl, alkynyl; R3 is alkyl, OH, halo, or alkoxy; R4 is alkyl, OH, halo, or alkoxy; Y is absent, C(O), C1-C4 alkylidene, or C1-C4 alkylideneamino; L is alkylidene, alkylidene-O-alkylidene, alkylidene-S-alkylidene, alkenylidene, cycloalkylidene, arylene, heteroarylene, C(O)O, or C(O)S; n1 is 0, 1, 2, 3, or 4; and n2 is 0, 1, 2, 3, or 4.Type: GrantFiled: March 14, 2013Date of Patent: January 19, 2016Assignee: EMPIRE TECHNOLOGY DEVELOPMENTS LLCInventors: William Brenden Carlson, Gregory David Phelan, Vincenzo Casasanta, III
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Patent number: 9096794Abstract: A liquid crystalline polymer composition that contains a liquid crystalline polymer and an aromatic amide oligomer is provided. The oligomer can serve as a flow aid by altering intermolecular polymer chain interactions, thereby lowering the overall viscosity of the polymer matrix under shear. The oligomer is also not easily volatized or decomposed during compounding, molding, and/or use, which minimizes off-gassing and the formation of blisters that would otherwise impact the final mechanical properties of a part made from the polymer composition. While providing the benefits noted, the aromatic amide oligomer does not generally react with the polymer backbone of the liquid crystalline polymer to any appreciable extent so that the mechanical properties of the polymer are not adversely impacted.Type: GrantFiled: August 27, 2012Date of Patent: August 4, 2015Assignee: Ticona LLCInventors: Kamlesh P. Nair, Joseph J. Grenci, Steven D. Gray
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Patent number: 9074133Abstract: A thermotropic liquid crystalline polymer melt polymerized in the presence of a viscosity modifier that can help increase the “low shear” viscosity of the resulting composition is provided. The increased “low shear” viscosity can minimize drooling of the polymer composition during processing and also allow it to possess a greater melt strength, which facilitates its ability to be processed in a wide variety of applications without losing its physical integrity. Despite having a relatively high “low shear” viscosity, the present inventors have discovered that the viscosity modifier does not substantially increase the “high shear” melt viscosity of the polymer composition. In this regard, the ratio of the “low shear” viscosity to the melt viscosity is generally very high, such as within a range of from about 50 to about 1000.Type: GrantFiled: August 27, 2012Date of Patent: July 7, 2015Assignee: Ticona LLCInventors: Kamlesh P. Nair, Steven D. Gray
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Patent number: 9040630Abstract: Provided herein are graft copolymers of polyfarnesenes with condensation polymers; and methods of making and using the graft copolymers disclosed herein. In certain embodiments, the condensation polymers include polyesters, polycarbonates, polyamides, polyethers, phenol-formaldehyde resins, urea-formaldehyde resins, melamine-formaldehyde resins and combinations thereof. In some embodiments, the polyfarnesenes include farnesene homopolymers derived from a farnesene, and farnesene interpolymers derived from a farnesene and at least a vinyl monomer. In certain embodiments, the farnesene is prepared from a sugar by using a microorganism.Type: GrantFiled: July 29, 2011Date of Patent: May 26, 2015Assignee: AMYRIS, INC.Inventor: Derek James McPhee
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Publication number: 20150119484Abstract: A method for producing particles, which contains: bringing a compressive fluid and a pressure plastic material into contact with each other to melt the pressure plastic material; and jetting a melt obtained by melting the pressure plastic material to form particles, wherein the jetting the melt is performed by a two-fluid nozzle or three-fluid nozzle.Type: ApplicationFiled: April 30, 2013Publication date: April 30, 2015Inventors: Keiko Osaka, Chiaki Tanaka
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Patent number: 9012593Abstract: Methods of preparing an aromatic liquid crystalline polyester resin and an aromatic liquid crystalline polyester resin compound are disclosed. A method of preparing an aromatic liquid crystalline polyester resin may include: acetylating a first monomer including an amino group by a reaction with a carboxylic acid anhydride; acetylating a second monomer including a hydroxyl group and not including an amino acid group with an additional carboxylic acid anhydride; and synthesizing an aromatic liquid crystalline polyester prepolymer by a condensation polymerization reaction of the acetylated first and second monomers with dicarboxylic acid. A method of preparing an aromatic liquid crystalline polyester resin compound may use the aromatic liquid crystalline polyester resin prepared according to the forgoing method.Type: GrantFiled: June 14, 2011Date of Patent: April 21, 2015Assignee: Shenzhen Wote Advanced Materials Co., Ltd.Inventors: Sun Hwa Chang, Sang Mi Kang, Dae Yeon Kim, Jin Kyu Lee
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Patent number: 9005475Abstract: An aromatic amide compound having the following general formula (I) is provided: wherein, X1 and X2 are independently C(O)HN or NHC(O); G1, G2 and G3 are independently hydrogen, C(O)HN-phenyl, or NHC(O)-phenyl, wherein at least one of G1, G2 and G3 is C(O)HN-phenyl or NHC(O)-phenyl; Q1, Q2, and Q3 are independently hydrogen, C(O)HN-phenyl, or NHC(O)-phenyl, wherein at least one of Q1, Q2, and Q3 is C(O)HN-phenyl or NHC(O)-phenyl; R5 is halo, haloalkyl, alkyl, alkenyl, aryl, heteroaryl, cycloalkyl, or heterocyclyl; and m is from 0 to 4.Type: GrantFiled: June 5, 2014Date of Patent: April 14, 2015Assignee: Ticona LLCInventors: Kamlesh P. Nair, Steven D. Gray
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Patent number: 8986846Abstract: A thermosetting oligomer or thermosetting polymer is provided. The thermosetting oligomer or thermosetting polymer contains repeating units, each of which has at least one thermosetting functional group in the side chain and is represented by Formula 1: where repeating units include X1, A1, and Y1 subunits, sidechain units include linking unit L and thermosetting functional group Z, and n is an integer from 1 to 4. The thermosetting oligomer or thermosetting polymer has a low coefficient of thermal expansion and high or no glass transition temperature, stiffness, processability, heat resistance and mechanical properties. The thermosetting oligomer or thermosetting polymer is highly soluble, wettable and dimensionally stable and is suitable for use in films, prepregs and printed circuit boards. Further provided are a thermosetting resin composition including the thermosetting oligomer or thermosetting polymer and a printed circuit board using the composition.Type: GrantFiled: June 23, 2009Date of Patent: March 24, 2015Assignee: Samsung Electro-Mechanics Co., Ltd.Inventors: Jae Jun Lee, Mahn Jong Kim, Kwang Hee Kim
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Patent number: 8975361Abstract: The present invention relates to water and solvent-free polymers, in particular water and solvent-free synthetic rubber products like styrene butadiene rubber products and butadiene rubber products as well as a process for the production thereof. The invention further relates to a device suitable to accomplish said process.Type: GrantFiled: March 23, 2011Date of Patent: March 10, 2015Assignee: LANXESS Deutschland GmbHInventors: Wolfgang Krumbe, Rolf Feller, Paul Wagner, Hanns-Ingolf Paul, Martin Siebuerger, Heike Kloppenburg, Alicia Le-Sattler, John Lovegrove
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LIQUID CRYSTAL POLYESTER AMIDE, LIQUID CRYSTAL POLYESTER AMIDE RESIN COMPOSITION, AND MOLDED ARTICLE
Publication number: 20150010744Abstract: A liquid crystal polyester amide of the present invention includes 10 mol % to 65 mol % of a structural unit represented by the following formula (1), 3 mol % to 17.5 mol % of a structural unit represented by the following formula (2), 5 mol % to 20 mol % of a structural unit represented by the following formula (3), 7.5 mol % to 42 mol % in total of at least one of a structural unit represented by the following formula (4-1) and a structural unit represented by the following formula (4-2), and 2.5 mol % to 40 mol % in total of at least one of a structural unit represented by the following formula (5-1) and a structural unit represented by the following formula (5-2), and has a melting point of 300° C. or higher.Type: ApplicationFiled: January 29, 2013Publication date: January 8, 2015Inventors: Satoshi Murouchi, Kiichiro Nishimura, Masatoshi Ando -
Publication number: 20150004409Abstract: A liquid crystalline polyester multifilament has a fusion degree between single fibers of 0 to 20. A method of producing a liquid crystalline polyester multifilament includes at least one step of a melt spinning step and a rewinding step, wherein an anti-fusion agent is deposited on a fiber surface of a melt-spun liquid crystalline polyester multifilament from application directions different from each other by 90 to 180° in a plane perpendicular to the yarn running direction.Type: ApplicationFiled: December 25, 2012Publication date: January 1, 2015Applicant: Toray Industries, Inc.Inventors: Ryosuke Sakae, Yoshitsugu Ogiwara, Takao Manabe
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Patent number: 8921507Abstract: Provided is a thermoplastic resin which (A) remarkably improves thermal conductivity of a resin composition when a thermally conductive filler is added and (B) can be injection-molded even by use of a general injection-molding die. The thermoplastic resin is a resin wherein: a main chain which mainly has a specific repeating unit; and 60 mol % or more ends of molecular chains are carboxyl groups.Type: GrantFiled: April 14, 2011Date of Patent: December 30, 2014Assignee: Kaneka CorporationInventors: Shusuke Yoshihara, Toshiaki Ezaki, Kazuaki Matsumoto
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Publication number: 20140378642Abstract: A composition having a mixture of the below compounds having a mole ratio of at least 1:20. Ar1 and Ar2 are independently selected aromatic groups. A composition comprising phthalonitrile compounds that comprise at least 5 mol % of the first compound below. A method of: providing a solution of a dichloroaromatic compound having an electron-withdrawing group bound to each aromatic ring containing one of the chloride groups; a dihydroxyaromatic compound or anion thereof; an organic transition metal complex or a transition metal salt; an alkaline hydroxide base; and a solvent; and heating the solution to a temperature at which the dichloroaromatic compound and the dihydroxyaromatic compound react to form a dimetallic salt of an aromatic ether oligomer. The molar ratio of the dihydroxyaromatic compound to the dichloroaromatic compound is greater than 2:1. Water formed during the heating is concurrently distilled from the solution.Type: ApplicationFiled: September 11, 2014Publication date: December 25, 2014Applicant: The Government of the United States of America, as represented by the Secretary of the NavyInventors: Teddy M. Keller, Matthew Laskoski
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Patent number: 8916673Abstract: The present invention provides a process for producing a liquid crystalline polyester resin, wherein an acetylation reaction and an oligomerization reaction of raw materials are carried out in an acetylation reaction vessel, and then a deacetylation polycondensation of a liquid after the oligomerization reaction is carried out in a polycondensation reaction vessel, wherein the acetylation reaction vessel used is a vessel having an inner wall surface composed of an alloy containing 50% by mass or more of Ni and 10% by mass or more of Mo; and the inner wall surface of the acetylation reaction vessel is divided into three or more band-like zones arrayed in the height direction of the vessel, and the oligomerization reaction is carried out while maintaining the temperatures of each band-like zone in a particular relationship.Type: GrantFiled: December 19, 2011Date of Patent: December 23, 2014Assignee: Toray Industries, Inc.Inventors: Kunihiko Miyauchi, Michiyoshi Matsumoto, Hideyuki Umetsu
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Patent number: 8859648Abstract: The present invention relates to a retardation film using polyester having a photoelastic coefficient of ?40×10?12 Pa?1 to 40×10?12 Pa?1. The present invention also relates to a polyester resin for optical use which contains a phosphorus compound, and an alicyclic component and a fluorene derivative component as constituents, and satisfies the following equations (6) and (7): 100° C.?glass transition temperature?150° C.??(6) and 1.0?(Ma/2+Mb+Mc)/P?5.0??(7), wherein Ma is the number of moles of an alkali metal element contained in 1 ton of the polyester resin, Mb is the number of moles of an alkaline earth metal element contained in 1 ton of the polyester resin, Mc is the sum of the number of moles of a zinc element (Zn), a cobalt element (Co) and a manganese element (Mn) contained in 1 ton of the polyester resin, and P is the number of moles of a phosphorus element contained in 1 ton of the polyester resin.Type: GrantFiled: May 23, 2006Date of Patent: October 14, 2014Assignee: Toray Industries, Inc.Inventors: Hideki Moriyama, Shigetoshi Maekawa, Jun Sakamoto, Akimitsu Tsukuda, Masahiro Kimura, Risa Taniguchi
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Patent number: 8859711Abstract: A method of preparing a wholly aromatic liquid crystalline polyester amide resin and a method of preparing a wholly aromatic liquid crystalline polyester amide resin compound. The method of preparing a wholly aromatic liquid crystalline polyester amide resin is performed using a monomer having both a hydroxyl group and an acetylamino group or using a monomer having a hydroxyl group and a monomer having an acetylamino group. In addition, the method of preparing a wholly aromatic liquid crystalline polyester amide resin compound is performed using a wholly aromatic liquid crystalline polyester amide resin that is prepared using the method.Type: GrantFiled: October 21, 2011Date of Patent: October 14, 2014Assignee: Samsung Fine Chemicals Co., Ltd.Inventors: Sun Hwa Chang, Sang Mi Kang, Dae Yeon Kim
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Patent number: 8853344Abstract: A film formed from a polymer composition containing one or more thermotropic liquid crystalline polymers is provided. The specific nature of the polymer or blend of polymers is selectively controlled so that the resulting polymer composition possesses both a low viscosity and high melt strength. The present inventor has discovered that this unique combination of thermal properties results in a composition that is both highly melt processible and stretchable, which allows the resulting film to be oriented to a degree greater than previously thought possible.Type: GrantFiled: September 20, 2013Date of Patent: October 7, 2014Assignee: Ticona LLCInventors: Young Shin Kim, Xinyu Zhao
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Patent number: 8829149Abstract: Processes for preparing polyester resins as toner production components. The processes include reacting an organic diol and a cyclic alkylene carbonate to produce carbon dioxide (CO2) and a polyalkoxy diol. The carbon dioxide is reacted with an alkylene glycol or alkylene oxide to produce additional cyclic alkylene carbonate having the same chemical structure as the cyclic alkylene carbonate used to produce the polyalkoxy diol. The additional cyclic alkylene carbonate is added with the cyclic alkylene carbonate used to produce the polyalkoxy diol. The polyalkoxy diol can be reacted with an organic diacid or diester in preparing a polyester resin. To prepare a toner, the polyester resin can be contacted with at least one toner production component.Type: GrantFiled: September 12, 2012Date of Patent: September 9, 2014Assignee: Xerox CorporationInventor: Guerino G. Sacripante
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Patent number: 8779081Abstract: The invention is directed to a method for producing poly(arylene) ethers with improved particle size characteristics. The improved particle size characteristics of the polyphenylene ether include one or both of: (i) up to about 50 weight percent of particles smaller than 38 micrometers; and a (ii) mean particle size greater than 100 or more micrometers.Type: GrantFiled: March 15, 2011Date of Patent: July 15, 2014Assignee: SABIC Global Technologies B.V.Inventors: Nitin Vilas Tople, Gerardo Rocha-Galicia, Hua Guo
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Publication number: 20140135469Abstract: A film formed from a polymer composition containing one or more thermotropic liquid crystalline polymers is provided. The specific nature of the polymer or blend of polymers is selectively controlled so that the resulting polymer composition possesses both a low viscosity and high melt strength. The present inventor has discovered that this unique combination of thermal properties results in a composition that is both highly melt processible and stretchable, which allows the resulting film to be oriented to a degree greater than previously thought possible.Type: ApplicationFiled: September 20, 2013Publication date: May 15, 2014Applicant: Ticona LLCInventors: Young Shin Kim, Xinyu Zhao
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Patent number: 8722813Abstract: A resin composition containing: an ester compound including a carboxylic acid ester obtained by using (1) a monohydric alcohol having an alkyl group having 1 to 4 carbon atoms; (2) a dicarboxylic acid having an alkylene group having 2 to 4 carbon atoms; and (3) a dihydric alcohol having an alkylene group having 2 to 6 carbon atoms, the ester compound having an acid value of 1.00 mgKOH/g or less, a hydroxyl value of 5.0 mgKOH/g or less, and a number-average molecular weight of from 300 to 700; and an aliphatic polyester. Since the resin composition of the present invention inhibits the generation of volatile compounds, the resin composition can be suitably used in various industrial applications, such as daily sundries, household electric appliance parts, and automobile parts.Type: GrantFiled: August 18, 2011Date of Patent: May 13, 2014Assignee: Kao CorporationInventors: Hiroki Sawada, Masahiro Mori
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Patent number: 8722843Abstract: Disclosed is a material for fiber manufacturing comprising a liquid crystal polyester satisfying the following requirements (a) and (b): (a) the weight-average molecular weight is equal to or less than 30000 and the polydispersity is equal to or less than 2.5; and (b) the melt viscosity measured at 360° C. with conditions of a nozzle pore diameter of 0.5 mm and a shear velocity of 1000 s?1 using a flow feature testing machine is equal to or less than 70 Pa·s.Type: GrantFiled: November 19, 2012Date of Patent: May 13, 2014Assignee: Sumitomo Chemical Company, LimitedInventors: Tomoya Hosoda, Mitsuo Maeda, Satoshi Okamoto
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Patent number: 8703011Abstract: The present invention provides a class of thermotropic liquid crystalline polyesters (TLCPs) and molding compositions comprising the polyesters and glass fiber. The TLCPs consist essentially of repeat units derived from p-hydroxybenzoic acid (HBA), 6-hydroxy-2-naphthoic acid (HNA), terephthalic acid (TA), and hydroquinone (HQ), and the mole percent of HBA, HNA, TA and HQ is 34-72%, 12-26%, 4-21% and 4-21%, respectively. The TLCPs have a melting temperature equal to or below 355° C., an inherent viscosity of 4.0-10.0 dL/g and a Heat Deflection Temperature (HDT) in the range of 260-285° C. when compounded with 30% by weight glass fiber. The optimum compositions, selected from the above-mentioned compositional ranges exhibit a relatively low melting temperature and a relatively high HDT. Specified compositions, selected from the above-mentioned compositional ranges have low melting point, which are useful to blend with conventional polymers such as poly (ethylene terephthalate) and nylon etc.Type: GrantFiled: November 17, 2009Date of Patent: April 22, 2014Inventors: Xiuzhen Wang, Haishan Bu, Wen Zhou
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Patent number: 8703899Abstract: The present invention relates to a method for producing a polyester, containing conducting a transesterification reaction of at least one compound selected from compounds represented by the following formulae (1) to (3) with a diol compound in the presence of a catalyst: wherein Ar is a divalent aromatic hydrocarbon group or the like; R1 is CX1Y1R4; R2 is a hydrogen atom or CX2Y2R5; R3 is a hydrogen atom or CX3Y3R6; R7 is a perfluoroalkylene group having 1 to 5 carbon atoms; X1 to X3 are a hydrogen atom, a fluorine atom or Rf; Y1 to Y3 are a fluorine atom or Rf; R4 to R6 are a fluorine atom, Rf, ORf or the like; and Rf is a fluoroalkyl group having 1 to 4 carbon atoms.Type: GrantFiled: August 30, 2013Date of Patent: April 22, 2014Assignee: Asashi Glass Company LimitedInventors: Jumpei Nomura, Hidekazu Okamoto, Atsushi Fujimori, Takashi Okazoe
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Publication number: 20140080993Abstract: The invention relates to polymeric fibers and a process of preparing polymeric fibers. The process comprises the steps of synthesizing a composite of thermotropic liquid crystalline polymer (TLCP) comprising multi-walled carbon nanotubes (MWNTs), and spinning the composite to form composite fibers. Specifically, the MWNTs are incorporated at a very low concentration. It is demonstrated that the as-spun TLCP/MWNTs composite fibers demonstrated significantly enhanced mechanical properties as compared with the control TLCP fibers without MWNTs. Fibers having 0.3 wt % MWNTs (C-3) demonstrated an increase of tensile modulus and strength by 38% and 32%, respectively, when compared with the control TLCP fiber without MWNTs.Type: ApplicationFiled: September 20, 2012Publication date: March 20, 2014Applicant: FIBRASTIC LIMITEDInventor: Willie Ka Yeung YU
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Patent number: 8669333Abstract: A thermosetting resin composition contains an active ester resin (A) and an epoxy resin (B) as essential components, the active ester resin (A) having a resin structure which includes a polyaryleneoxy structure (I) and in which aromatic carbon atoms in a plurality of the polyaryleneoxy structures (I) are linked through a structural site (II) represented by a structural formula 1 (wherein Ar represents a phenylene group, a phenylene group nuclear-substituted by 1 to 3 alkyl groups each having 1 to 4 carbon atoms, a naphthylene group, or a naphthylene group nuclear-substituted by 1 to 3 alkyl groups each having 1 to 4 carbon atoms).Type: GrantFiled: June 8, 2011Date of Patent: March 11, 2014Assignee: DIC CorporationInventors: Kazuo Arita, Etsuko Suzuki
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Patent number: 8669341Abstract: A method for forming a high molecular weight thermotropic liquid crystalline polymer is provided. The method includes melt polymerizing two or more monomers in the presence of a unique aromatic amide oligomer to form a prepolymer, and then solid-state polymerizing the prepolymer to achieve a target molecular weight. The present inventors have discovered that a unique aromatic amide oligomer can be employed to help increase the “low shear” complex viscosity of the resulting solid-state polymerized composition. This allows for the attainment of higher than conventional “low shear” complex viscosity values and/or a substantial reduction in the solid-state polymerization time needed to achieve a target complex viscosity. In addition, the oligomeric flow aid can also accelerate the extent to which the “high shear” melt viscosity is increased during solid-state polymerization, which may also contribute to a substantial reduction in the solid-state polymerization time needed to achieve a certain molecular weight.Type: GrantFiled: August 27, 2012Date of Patent: March 11, 2014Assignee: Ticona LLCInventors: Kamlesh P. Nair, Steven D. Gray
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Publication number: 20140039147Abstract: A polymer includes a monomeric repeat unit represented by Formula I: In Formula I, R1 is alkyl, alkenyl, alkynyl, aryl, heteroaryl, cycloalkyl, or heterocyclyl; R2 is alkyl, haloalkyl, alkenyl, alkynyl; R3 is alkyl, OH, halo, or alkoxy; R4 is alkyl, OH, halo, or alkoxy; Y is absent, C(O), C1-C4 alkylidene, or C1-C4 alkylideneamino; L is alkylidene, alkylidene-O-alkylidene, alkylidene-S-alkylidene, alkenylidene, cycloalkylidene, arylene, heteroarylene, C(O)O, or C(O)S; n1 is 0, 1, 2, 3, or 4; and n2 is 0, 1, 2, 3, or 4.Type: ApplicationFiled: March 14, 2013Publication date: February 6, 2014Applicant: Empire Technology Development LLCInventors: William Brendan CARLSON, Gregory David PHELAN, Vincenzo CASASANTA, III
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Patent number: 8637631Abstract: A polyphenylene ether which has a content of a metal magnetic material of 0.001 ppm or higher and lower than 1.000 ppm.Type: GrantFiled: February 24, 2011Date of Patent: January 28, 2014Assignee: Asahi Kasei Chemicals CorporationInventors: Tomohiro Kondo, Akinobu Nagai, Akira Mitsui
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Patent number: 8637630Abstract: Provided is a thermoplastic resin having excellent thermal conductivity, in which thermoplastic resin a change in number average molecular mass caused by progress of polymerization occurring when the thermoplastic resin material is melted and a change in thermal conductivity caused by the change in number average molecular mass are low. The thermoplastic resin has (A) a specific structure and (B) ends of molecular chains sealed by a monofunctional low molecular weight compound. The resin itself has excellent thermal conductivity. The change in number average molecular mass becomes small during melting of the thermoplastic resin material, so that the change in thermal conductivity of the resin itself becomes small.Type: GrantFiled: April 14, 2011Date of Patent: January 28, 2014Assignee: Kaneka CorporationInventors: Shusuke Yoshihara, Toshiaki Ezaki, Kazuaki Matsumoto
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Publication number: 20140017965Abstract: Provided are liquid crystal polyester fibers having a running tension variable width (R) of 5 cN or less and an oil component deposition rate of 3.0 wt % or less. Also provided is a method for producing liquid crystal polyester fibers whereby solid-phase polymerization is performed after applying inorganic particles (A) and phosphoric acid compound (B) to yarn obtained by melt spinning of liquid crystal polyester. Further provided is a mesh textile formed from the liquid crystal polyester fibers. By means of the liquid crystal polyester fibers, method for producing the same, and mesh textile, step transition and product yield during the weaving steps are excellent in that there is little scum and there is little variation of the running tension during the weaving steps.Type: ApplicationFiled: March 12, 2012Publication date: January 16, 2014Applicant: Toray Industries, Inc.Inventors: Chieko Kawamata, Yusuki Ono, Hiroo Katsuta, Yoshitsugu Funatsu
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Patent number: 8629234Abstract: This invention relates to a process of preparing a catalyst for the production of polyethylene terephthalate and for the production of high molecular weight PET comprising: a) reacting boric acid and a zinc salt in a solvent comprising at least one glycol selected from ethylene glycol, propylene glycol, and butylene glycol thereby forming a precipitate; and b) isolating the precipitate. In addition, the use of the catalyst for the production of polyethylene terephthalate and for the production of high molecular weight PET is disclosed.Type: GrantFiled: December 17, 2012Date of Patent: January 14, 2014Assignee: Saudi Basic Industries CorporationInventor: Bander Al-Farhood
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Patent number: 8614155Abstract: An enhanced prepreg for printed circuit board (PCB) laminates includes a substrate and a resin applied to the substrate. The resin includes a curable polymer and a polymerization initiator polymer having a backbone with a free radical initiator forming segment that breaks apart upon being subjected to heat to generate a plurality of non-volatile initiating species. This resin composition eliminates possible volatile loss of the free radical initiator during all processing steps in the preparation of PCB laminates. The resin may additionally include a cross-linking agent, flame retardant and viscosity modifiers. In one embodiment, a sheet of woven glass fibers is impregnated with the resin and subsequently dried or cured. The glass cloth substrate may include a silane coupling agent to couple the resin to the substrate. In another embodiment, resin coated copper (RCC) is prepared by applying the resin to copper and subsequently curing the resin.Type: GrantFiled: August 20, 2010Date of Patent: December 24, 2013Assignee: International Business Machines CorporationInventors: Dylan Joseph Boday, Joseph Kuczynski
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Patent number: 8609802Abstract: Disclosed are a production method for a wholly aromatic liquid crystalline polyester resin, a wholly aromatic liquid crystalline polyester resin produced using the method, and a compound of the wholly aromatic liquid crystalline polyester resin. The disclosed production method for a wholly aromatic liquid crystalline polyester resin comprises the steps of synthesizing a wholly aromatic liquid crystalline polyester resin by synthesizing a wholly aromatic liquid crystalline polyester prepolymer by a condensation polymerization of a monomer and then reducing the pressure inside a reaction vessel containing the synthesized prepolymer at a predetermined internal pressure reduction rate of the reaction vessel.Type: GrantFiled: January 12, 2011Date of Patent: December 17, 2013Assignee: Samsung Fine Chemicals Co., Ltd.Inventors: Hyun Min Kim, Jong Hwa Yun, Mahn Jong Kim
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Patent number: 8598300Abstract: The invention provides an amorphous polyester resin that can sufficiently achieve the reciprocal performance properties of hot offset resistance and cold offset resistance, which is a major issue for a toner for electrostatic image development, while allowing adequate blocking resistance to be obtained, as well as a binder resin for toner for electrostatic image development, and an amorphous polyester resin production method, the amorphous polyester resin being obtained by reaction between a polybasic carboxylic acid compound and a polyhydric alcohol, wherein the polybasic carboxylic acid compound comprises (a) the reaction product between an aromatic polybasic carboxylic acid compound and a C2-4 glycol at 60 mol % or greater based on the total amount of the polybasic carboxylic acid compound, and the amorphous polyester resin has a glass transition point of 55° C. to 75° C. and a weight-average molecular weight of 10,000 to 50,000.Type: GrantFiled: April 23, 2010Date of Patent: December 3, 2013Assignee: Nicca Chemical Co., Ltd.Inventors: Tatsuhiro Hishida, Koji Ogawa, Yasumichi Moriyama, Masaaki Hosoda, Kazuo Tanabe
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Patent number: 8586183Abstract: A laser composition comprises a combination of: (a) from more than 45 to less than 94 weight percent of a crystalline or semi-crystalline thermoplastic polyester component selected from poly(butylene terephthalate), poly(ethylene terephthalate), poly(butylene terephthalate) copolymers poly(ethylene terephthalate) copolymers, and combinations thereof; (b) from greater than 6 to less than 25 weight percent of an amorphous thermoplastic poly(ester) copolymer, poly(ester-carbonate), or combination thereof; (c) optionally, from 1 to 30 weight percent of a filler; and (d) optionally, from 0.01 to 5 weight percent of an antioxidant, mold release agent, colorant, stabilizer, or a combination thereof; wherein an article having a 2 mm thickness and molded from the composition has (i) a near infrared transmission at 960 nanometers of greater than 30 percent and (ii) a Vicat softening temperature of at least 170° C.Type: GrantFiled: January 13, 2011Date of Patent: November 19, 2013Assignee: Sabic Innovative Plastics IP B.V.Inventors: Tony Farrell, Johannes Hubertus G. M. Lohmeijer
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Patent number: 8585923Abstract: The present invention provides a wholly aromatic liquid-crystalline polyester resin, consisting of the repeating units shown by the formulae [I]-[V]: wherein p, q, r, s and t represent molar proportion (mol %) of repeating units respectively in the liquid-crystalline polyester resin and satisfy the following formulae: 25?p?45; 2?q?10; 10?r?20; 10?s?20; 20?t?40; r>s; p+q+r+s+t=100; having a ratio P1/P2 of equal to or lower than 3.0, wherein P1 is a melt viscosity at a crystalline melting temperature measured under the condition of shear rate 1000 sec?1 and P2 is a melt viscosity at a temperature of the crystalline melting temperature +20° C. measured under the same condition as P1; and having a deflection temperature under load (DTUL) of equal to or higher than 230° C.Type: GrantFiled: December 15, 2011Date of Patent: November 19, 2013Assignee: Ueno Fine Chemicals Industry, Ltd.Inventors: Satoru Yonezawa, Hisanari Fujiwara, Tetsuhide Sawada
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Publication number: 20130296523Abstract: The present invention provides a process for producing a liquid crystalline polyester resin, wherein an acetylation reaction and an oligomerization reaction of raw materials are carried out in an acetylation reaction vessel, and then a deacetylation polycondensation of a liquid after the oligomerization reaction is carried out in a polycondensation reaction vessel, wherein the acetylation reaction vessel used is a vessel having an inner wall surface composed of an alloy containing 50% by mass or more of Ni and 10% by mass or more of Mo; and the inner wall surface of the acetylation reaction vessel is divided into three or more band-like zones arrayed in the height direction of the vessel, and the oligomerization reaction is carried out while maintaining the temperatures of each band-like zone in a particular relationship.Type: ApplicationFiled: December 19, 2011Publication date: November 7, 2013Applicant: TORAY INDUSTRIES, INC.Inventors: Kunihiko Miyauchi, Michiyoshi Matsumoto, Hideyuki Umetsu
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Patent number: 8568950Abstract: There is provided a polyester resin for a toner, including: a polycondensate of a polyvalent carboxylic acid component and a polyhydric alcoholic component, wherein the polyhydric alcoholic component contains a rosin diol represented by the following Formula (1) and a content of the rosin diol is 80 mole % to 100 mole % based on the total polyhydric alcoholic component. wherein, each of R1 and R2 independently represents a hydrogen atom or a methyl group; L1 represents a divalent linking group having the following Formula (I); each of L2 and L3 independently represents a divalent linking group selected from the group consisting of carbonyl groups, carboxyl groups, ether groups, sulfonyl groups, substituted or unsubstituted chained alkylene groups, substituted or unsubstituted cyclic alkylene groups, substituted or unsubstituted arylene groups, and combinations thereof; and each of A1 and A2 independently represents a rosin ester group.Type: GrantFiled: September 25, 2012Date of Patent: October 29, 2013Assignee: Fuji Xerox Co., Ltd.Inventors: Hirofumi Shiozaki, Sumiaki Yamasaki, Satoshi Hiraoka, Yuki Sasaki, Susumu Yoshino, Hirotaka Matsuoka, Emi Miyata