Abstract: A method is described for producing a polycarbonate by reacting one or more diaryl carbonates with one or more aromatic hydroxy compounds, which are first mixed in a mixing device and enter, as a raw material mixture, a raw material mixture container to subsequently react in one or more reactors under reduced pressure and increased temperature to form polycarbonate, wherein the mixture of diaryl carbonate and aromatic hydroxy compound is subjected to a purification by an inert gas in a countercurrent process, in a stripping device, before entering the raw material mixture container. The present invention also relates to a stripping device which is particularly suitable for purifying a raw material mixture stream, and to the use of such a stripping device in a method for producing polycarbonate.

Abstract: Provided are a novel polyorganosiloxane capable of preparing copolycarbonate with improved weather resistance and flowability while maintaining the intrinsic physical properties of polycarbonate resin, and a copolycarbonate prepared by using the same.

Abstract: Melt polymerization processes for producing photoactive additives are disclosed. The photoactive additives are cross-linkable polycarbonate resins formed from a benzophenone, a dihydroxy chain extender, a carbonate precursor, and a catalyst. The additives can be produced without the use of phosgene or dichloromethane, and can be cross-linked with other polymers upon exposure to UV radiation.

Abstract: Embodiments methods and compositions involving inhibitors of the immunoreceptor Natural Killer Group 2, Member D, (NKG2D) for inhibiting tumor progression and treating cancer.

Abstract: Provided are a copolycarbonate having superior weather resistance as well as excellent mechanical properties, and a preparation method thereof.

Abstract: The present invention relates to a method for preparing branched polycarbonate with a continuous two-phase interface phosgene method. Firstly, an aqueous solution of alkali metal hydroxide with triphenol and polyphenol dissolved therein reacts with a certain amount of phosgene in the present of inert organic solvent to prepare a prepolymer, and then a coupling reaction is performed among the prepolymer, an aqueous solution of alkali metal hydroxide with bisphenol and phosgene dissolved therein to finally obtain a polycarbonate resin. The method can avoid a cross-linking reaction, reduce the cost and improve the quality of the product, while improving the conversion ratio of the branching agent and the branching degree of the product.

Abstract: A method for producing a condensation polymerization reaction polymer, comprising a guide polymerization step in which a molten prepolymer is supplied to the top edge of a wire guide to obtain the condensation polymerization reaction polymer, the wire guide comprising a vertical wire group consisting of a plurality of vertical wires extending in the vertical direction, which are mutually spaced in alignment at an arrangement pitch L1 (mm). In the guide polymerization step, the molten prepolymer aggregates so that a molten prepolymer mass is formed on the vertical wire, and a molten prepolymer mass is formed wherein, the width of the molten prepolymer mass measured in an alignment direction of the vertical wires at a position 200 mm below the top edge being represented as L2 (mm), the width L2 of at least a portion of the molten prepolymer mass satisfies the inequality (1).

Abstract: Disclosed herein are alkoxy polycarbonates, ortho alkoxy bisphenol monomers, polymer compositions comprising ortho alkoxy bisphenol monomers, methods of preparing the ortho alkoxy bisphenol monomers, polymer compositions and articles made thereof. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.

Abstract: A polycarbonate copolymer includes a repeating unit A represented by a formula (1) below and a repeating unit B represented by a formula (2) below, in which an abundance ratio represented by Ar1/(Ar1+Ar2) is in a range of 35 mol % to 75 mol % and an abundance ratio represented by Ar2/(Ar1+Ar2) is in a range of 25 mol % to 65 mol %,

Abstract: A polycarbonate of the present invention includes repeating units represented by, Formula 1, Formula 2 and Formula 3, respectively, and thus, may have excellent scratch resistance, chemical resistance and impact property.

Abstract: It is an object of the present invention to provide an optical film which has reverse chromatic dispersibility that its retardation becomes smaller as the wavelength becomes shorter and a low photoelastic constant.

Abstract: A molded article produced by molding a coating solution that contains a polycarbonate resin represented by the following formula (1) has excellent transparency, good water repellency and oil repellency, a lower friction coefficient and excellent surface lubricity, having a capability of improving abrasion resistance. In the formula (1), Rf represents a perfluoroalkyl group having 5 or more carbon atoms and 11 or more fluorine atoms or a perfluoroalkyl group having a specific structure; and W represents a divalent group including therein a specific structural unit.

Abstract: A polycarbonate resin includes a repeat unit represented by Formula 1; a repeat unit represented by Formula 2; and a repeat unit represented by Formula 3, wherein the polycarbonate resin has a weight average molecular weight of about 15,000 g/mol to about 60,000 g/mol and a melt index of about 3 g/10 min to about 40 g/10 min.: wherein R1, R2, R3, R4, a, b, c, and d are the same as defined in the specification. The polycarbonate resin for film can exhibit excellent scratch resistance, elongation, chemical resistance and heat resistance, and can be used to prepare a film in roll form without any protective film.

Abstract: A copolymerized polycarbonate resin includes a repeat unit represented by Formula 1; a repeat unit represented by Formula 2; and a repeat unit represented by Formula 3, wherein the repeat unit represented by Formula 1 is different than the repeat unit represented by Formula 3, and wherein Formula 1, 2, and 3 are the same as defined in the specification. The copolymerized polycarbonate resin can have excellent properties in terms of chemical resistance, thermal resistance, and/or external appearance.

Abstract: This invention provides a branched polycarbonate resin obtained from a dihydric phenol compound, a branching agent, monohydric phenols and phosgene by an interfacial polymerization reaction method in the presence of an alkali aqueous solution and an organic solvent, the branched polycarbonate resin having features that: (i) the branching agent content (X) thereof is over 0.70 mol % but 1.50 mol % or less, (ii) the branching agent content (X) and the melt tension (Y) thereof at 280° C. satisfy the following expression (1), 3.8X?2.4?Y?3.8X+4.5 (1), and (iii) the entire N content in the branched polycarbonate resin is 0 to 7 ppm.

Abstract: A polycarbonate polymer or copolymer comprising pendant silylated dihydroxy aromatic compound of the formula (1a); wherein Ga and Gb are each independently C1-12 alkyl, —OSi(C1-12 alkyl)3, C1-12 arylalkyl, or —OSi(C1-12 arylalkyl)3; Za and Zb are each independently a straight or branched C2-18 is alkylene, a C8-18 arylalkylene, or a C8-18 alkylarylene, Xa is a direct bond, a heteroatom-containing group, or a C1-18 organic group, and r and s are each independently 1 or 2 is disclosed.

Abstract: This invention describes the use of resveratrol and curcumin, representatives of naturally occurring polyphenols, in their native form, after hydrogenation, and as their respective allyl derivatives, individually, in combination with themselves and other commercial monomers, to make representative varieties of polymers, e.g., polycarbonates (PC), polyurethanes (PU), co-polymers and biodegradable polymers.

Abstract: A method for producing a condensation polymerization reaction polymer, comprising a guide polymerization step in which a molten prepolymer is supplied to the top edge of a wire guide to obtain the condensation polymerization reaction polymer, the wire guide comprising a vertical wire group consisting of a plurality of vertical wires extending in the vertical direction, which are mutually spaced in alignment at an arrangement pitch L1 (mm). In the guide polymerization step, the molten prepolymer aggregates so that a molten prepolymer mass is formed on the vertical wire, and a molten prepolymer mass is formed wherein, the width of the molten prepolymer mass measured in an alignment direction of the vertical wires at a position 200 mm below the top edge being represented as L2 (mm), the width L2 of at least a portion of the molten prepolymer mass satisfies the inequality (1).

Abstract: The present invention relates to polycarbonates comprising imide-containing aryl mono- or dihydroxy compounds as chain terminators and, respectively, monomer units, and also to compositions comprising the said polycarbonates, to their use for the production of mouldings, and to mouldings obtainable therefrom.

Abstract: A copolycarbonate-polyester, comprising units of formula wherein at least 60 percent of the total number of R1 groups are divalent aromatic organic radicals and the balance thereof are divalent aliphatic or alicyclic radicals; units of formula wherein T is a C7-20 divalent alkyl aromatic radical or a C6-20 divalent aromatic radical, and D is a divalent C6-20 aromatic radical; and units of the formula wherein R2 and R3 are each independently a halogen or a C1-6 alkyl group, R4 is a methyl or phenyl group, each c is independently 0 to 4, and T is as described above. A method of making a copolycarbonate-polyester is also disclosed.

Abstract: The invention relates to aromatic polycarbonates which comprise dioxydiarylcycloalkane structural units, and which have improved optical and thermal properties. It also relates to an improved process to produce the said polycarbonates from dihydroxydiphenylcyloalkanes, and also to mixtures of these polycarbonates with polymers, with fillers, with dyes and with conventional additives.

Abstract: A polycarbonate resin having at least one terminal group which is represented by formula (1), and a resin composition and an optical material comprising the polycarbonate resin are disclosed. In the formula, R1-R9 each independently represent a hydrogen atom, halogen atom or an alkyl group. X1 represents a direct bond or alkylene group.

Abstract: Methods of forming polycarbonate graft copolymers are provided. In particular, a polycarbonate polymer or copolymer containing allyl groups provides the backbone for the graft copolymer, and pendant chains are attached to the copolymer through the allyl groups. The graft copolymers exhibit a combination of high transparency, good graft levels, good scratch resistance, and/or good anti-fog properties.

Abstract: Polycarbonate includes repeat units represented by Formula 1, Formula 2 and Formula 3, respectively: wherein: R1 and R2 are the same or different and are each independently substituted or unsubstituted C1 to C6 alkyl, substituted or unsubstituted C3 to C6 cycloalkyl, substituted or unsubstituted C6 to C12 aryl or halogen, a and b are the same or different and are each independently an integer from 0 to 4, and Q is substituted or unsubstituted C5 to C10 cycloalkyl.

Abstract: Polycarbonate includes repeat units represented by Formula 1, Formula 2 and Formula 3, respectively: wherein: R1 and R2 are the same or different and are each independently substituted or unsubstituted C1 to C6 alkyl, substituted or unsubstituted C3 to C6 cycloalkyl, substituted or unsubstituted C6 to C12 aryl or halogen, a and b are the same or different and are each independently an integer from 0 to 4, and Q is substituted or unsubstituted C5 to C10 cycloalkyl.

Abstract: A copolycarbonate-polyester, comprising units of formula wherein at least 60 percent of the total number of R1 groups are divalent aromatic organic radicals and the balance thereof are divalent aliphatic or alicyclic radicals; units of formula wherein T is a C7-20 divalent alkyl aromatic radical or a C6-20 divalent aromatic radical, and D is a divalent C6-20 aromatic radical; and units of the formula wherein R2 and R3 are each independently a halogen or a C1-6 alkyl group, R4 is a methyl or phenyl group, each c is independently 0 to 4, and T is as described above. A method of making a copolycarbonate-polyester is also disclosed.

Abstract: The invention seeks to provide a branched polycarbonate resin having a high branching agent content, which has a good melt tension, virtually causes no drawdown and permits stable molding when it is molded in extrusion molding, blow molding, injection molding, vacuum molding, etc., and a process for producing the same. This invention provides a branched polycarbonate resin obtained from a dihydric phenol compound, a branching agent, monohydric phenols and phosgene by an interfacial polymerization reaction method in the presence of an alkali aqueous solution and an organic solvent, the branched polycarbonate resin having features that: (i) the branching agent content (X) thereof is over 0.70 mol % but 1.50 mol % or less, (ii) the branching agent content (X) and the melt tension (Y) thereof at 280° C. satisfy the following expression (1), 3.8X?2.4?Y—3.8X+4.5??(1), and (iii) the entire N content in the branched polycarbonate resin is 0 to 7 ppm.

Abstract: This invention describes the use of resveratrol and curcumin, representatives of naturally occurring polyphenols, in their native form, after hydrogenation, and as their respective allyl derivatives, individually, in combination with themselves and other commercial monomers, to make representative varieties of polymers, e.g., polycarbonates (PC), polyurethanes (PU), co-polymers and biodegradable polymers.

Abstract: A polycarbonate copolymer includes a repeating unit represented by a formula (1) below and a molar copolymer composition represented by Ar2/(Ar1+Ar2) in a range of 25 mol % to 50 mol %. In the formula (1): Ar1 and Ar2 represent a divalent aromatic group; a chain end is terminated by a monovalent aromatic group or a monovalent fluorine-containing aliphatic group; and n represents an average repeating number of an Ar1 block and is a numeral of 1.0 to 3.0, provided that Ar1 and Ar2 are not the same.

Abstract: A melt phase process for making a polyester polymer melt phase product by adding an antimony containing catalyst to the melt phase, polycondensing the melt containing said catalyst in the melt phase until the It.V. of the melt reaches at least 0.75 dL/g. Polyester polymer melt phase pellets containing antimony residues and having an It.V. of at least 0.75 dL/g are obtained without solid state polymerization. The polyester polymer pellets containing antimony residues and having an It.V. of at least 0.70 dL/g obtained without increasing the molecular weight of the melt phase product by solid state polymerization are fed to an extruder, melted to produce a molten polyester polymer, and extruded through a die to form shaped articles. The melt phase products and articles made thereby have low b* color and/or high L* brightness, and the reaction time to make the melt phase products is short.

Abstract: The present invention relates to copolycarbonates with improved surface hardness, processes for producing the same, and use of the same for producing blends, moldings, and extrudates, foil (layers), foil laminates, and cards.

Abstract: An optical lens which can be produced by injection molding on an industrial scale, and which has a high refractive index, a low Abbe's number, a low birefringence index, a high transparency and a high glass transition temperature. The optical lens can be produced by injection molding of a polycarbonate resin (preferably having a reduced viscosity of 0.2 dl/g or higher and a glass transition temperature of 120 to 160° C.), wherein the polycarbonate resin is produced by reacting a diol component comprising 99 to 51 mol % of 9,9-bis(4-(2-hydroxyethoxy)phenyl)fluorene and 1 to 49 mol % of bisphenol A with a carbonate diester. It becomes possible to produce an optical lens preferably having a refractive index of 1.60 to 1.65, an Abbe's number of 30 or smaller, a birefringence index of 300 nm or lower and an all light transmittance of 85.0% or higher.

Abstract: Disclosed herein is a method of preparing a polycarbonate composition comprising melt blending a first polycarbonate prepared by interfacial polymerization and having hydroxy end groups that are capped with endcapping groups, with a second polycarbonate prepared by melt polymerization and having hydroxy end groups that are capped with endcapping groups, wherein the second polycarbonate has a lower mole percent of endcapping groups than that of the first polycarbonate; wherein an article having a thickness of 3.2 mm and molded from the polycarbonate composition has a haze of less than 3 according to ASTM D1003-00; and wherein a flat article molded from the polycarbonate composition has a surface charge of ?2 to +2 kV. A polycarbonate composition and complex article prepared according to the method are also disclosed.

Abstract: Copolycarbonates comprising alkylphenolchain terminator groups for adjusting the molecular weight, compositions of these copolycarbonates with additives chosen from the group of heat stabilizers and mold release agents, the use thereof for the production of moldings and moldings obtained therefrom.

Abstract: A melt phase process for making a polyester polymer melt phase product by adding an antimony containing catalyst to the melt phase, polycondensing the melt containing said catalyst in the melt phase until the It.V. of the melt reaches at least 0.75 dL/g. Polyester polymer melt phase pellets containing antimony residues and having an It.V. of at least 0.75 dL/g are obtained without solid state polymerization. The polyester polymer pellets containing antimony residues and having an It.V. of at least 0.70 dL/g obtained without increasing the molecular weight of the melt phase product by solid state polymerization are fed to an extruder, melted to produce a molten polyester polymer, and extruded through a die to form shaped articles. The melt phase products and articles made thereby have low b* color and/or high L* brightness, and the reaction time to make the melt phase products is short.

Abstract: An injection molded article comprising a polycarbonate composition. The polycarbonate composition is scratch resistant, flame retardant, has a low chlorine and bromine content and is dark colored.

Abstract: A method of increasing the branching and polydispersity of a polycarbonate includes the steps of: (a) including in the polycarbonate at least one species of an alkyl substituted monomer, and (b) treating the polycarbonate at an elevated temperature and for a sufficient time to increase the branching and polydispersity relative to an otherwise equivalent polycarbonate without alkyl substituents.

Abstract: A multi-layer article is disclosed. The article contains a base layer that contains at least one thermoplastic resin and a second layer containing a thermoplastic (co)polyformal superimposed over the base layer. The (co)polyformal conforms to formulae (1a) or (1b), in which O-D-O and O-E-O independently denote a diphenolate group, -D- and -E- independently denote an aromatic group having 6 to 40 carbon atoms, k is a whole number from 1 to 1500, o stands for numbers from 1 to 1500, and m is z/o and n is (o-z)/o wherein z is 0 to o.

Abstract: The present invention relates to a miscible transparent polymer blend, specifically, a polycarbonate blend which comprises homopolycarbonates and/or copolycarbonates. In particular, high aspect ratio monomers confer unique miscibility properties on polycarbonates. Miscible, transparent blends have been found to form from polycarbonate mixtures containing as components of the mixture (1) polycarbonates of bisphenol A monomers copolymerized with a variety of bisphenols, and (2) polycarbonates containing high aspect ratio monomers.

Abstract: A silylated polycarbonate comprises silylated carbonate units, where the silylated carbonate units can be derived from a silylated dihydroxy aromatic compound of the formula (1a): wherein Ga and Gb are each independently C1-12 alkyl, —OSi(C1-12 alkyl)3, C1-12 arylalkyl, or —OSi(C1-12 arylalkyl)3; Za and Zb are each independently a straight or branched C2-18 alkylene, a C8-18 arylalkylene, or a C8-18 alkylarylene, Xa is a direct bond, a heteroatom-containing group, or a C1-18 organic group, and r and s are each independently 1 or 2. A method of forming the silylated dihydroxy aromatic compound, and for forming the silylated polycarbonate, are disclosed. Also disclosed is a thermoplastic composition comprising the silylated polycarbonate, and an article comprising the thermoplastic composition.

Abstract: A polycarbonate prepolymer for solid state polymerization, which is produced by an oxidative carbonylation reaction of an aromatic dihydroxy compound, a monohydric phenol having a boiling point of 330° C. or below, carbon monoxide and oxygen, the polycarbonate prepolymer being characterized by that (a) a ratio of aryl carbonate groups and hydroxyl groups each constituting terminal groups of the prepolymer is from 2:8 to 8:2, and (b) a molecular weight distribution (Mw/Mn) is from 1.1 to 2.1; and a process of producing polycarbonates including a step of solid state-polymerizing the prepolymer so as to increase the molecular weight thereof. According to the present invention, the prepolymer having a controlled molecular weight distribution suitable for solid state polymerization is provided, and a high quality polycarbonate is efficiently produced in environmentally friend manner.

Abstract: The invention includes embodiments that relate to a method of improving the abrasion resistance of a plastic article. The method comprises: (a) providing a composition comprising at least one e-beam active thermoplastic polymeric material; (b) forming an article from the composition of step (a); and (c) exposing the article formed in step (b) to an electron beam source. The invention also includes embodiments that relate to an article comprising an abrasion resistant surface.

Abstract: The above-described and other deficiencies of the art are met by a method of making a polycarbonate polymer comprising isosorbide carbonate units, comprising melt reacting a dihydroxy compound comprising an isosorbide of the general formula (2a): and an activated carbonate, in the presence of a catalyst consisting essentially of a sodium salt capable of providing a hydroxide ion, wherein the polycarbonate polymer comprises greater than or equal to 50 mol % isosorbide carbonate units, and wherein the polycarbonate polymer has a Mw of greater than or equal to about 40,000 g/mol as determined by gel-permeation chromatography relative to polystyrene standards. Polycarbonates comprising the isosorbide carbonate unit, including isosorbide homopolycarbonate and an isosorbide-based polyester-polycarbonate, are also disclosed, as are a thermoplastic composition and an article including the isosorbide-based polycarbonate polymer.

Abstract: A copolycarbonate-polyester, comprising units of formula wherein at least 60 percent of the total number of R1 groups are divalent aromatic organic radicals and the balance thereof are divalent aliphatic or alicyclic radicals; units of formula wherein T is a C7-20 divalent alkyl aromatic radical or a C6-20 divalent aromatic radical, and D is a divalent C6-20 aromatic radical; and units of the formula wherein R2 and R3 are each independently a halogen or a C1-6 alkyl group, R4 is a methyl or phenyl group, each c is independently 0 to 4, and T is as described above.

Abstract: An optical data storage comprising a thermoplastic copolycarbonate is disclosed. The copolycarbonate contains at least one unit derived from dihydroxydiphenyl ether and at least one unit derived from at least one member selected from the group consisting of 4,4?dihydroxybiphenyl and 1,1-bis-(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane.

Abstract: A polycarbonate prepolymer for solid state polymerization, which is produced by an oxidative carbonylation reaction of an aromatic dihydroxy compound, a monohydric phenol having a boiling point of 330° C. or below, carbon monoxide and oxygen, the polycarbonate prepolymer being characterized by that (a) a ratio of aryl carbonate groups and hydroxyl groups each constituting terminal groups of the prepolymer is from 2:8 to 8:2, and (b) a molecular weight distribution (Mw/Mn) is from 1.1 to 2.1; and a process of producing polycarbonates including a step of solid state-polymerizing the prepolymer so as to increase the molecular weight thereof. According to the present invention, the prepolymer having a controlled molecular weight distribution suitable for solid state polymerization is provided, and a high quality polycarbonate is efficiently produced in environmentally friend manner.

Abstract: An object of the present invention is to provide a polycarbonate copolymer having excellent heat resistance and dimensional stability and heat resistant parts comprising the copolymer and suitable for use in various applications. The present invention is a polycarbonate copolymer comprising 5 to 95 mol % of recurring unit (component a) represented by the following general formula (I): and 95 to 5 mol % of recurring unit (component b) represented by the following general formula (II): (wherein Ra to Rd are each independently a hydrogen atom, a hydrocarbon group which may contain an aromatic group having 1 to 9 carbon atoms or a halogen atom, and W is a single bond, a hydrocarbon group which may contain an aromatic group having 1 to 20 carbon atoms or an O, SO, SO2, CO or COO group), and various heat resistant parts comprising the copolymer.

Abstract: It is to provide a branched aromatic polycarbonate excellent in hue and excellent in melt properties such as melt strength.

Abstract: A polycarbonate resin composition which has excellent flame retardancy, even when containing neither any phosphorus compound flame retardant nor any halogenated flame retardant, and which is highly reflective and has light-shutting properties and excellent thermal stability. The polycarbonate resin composition comprises 5 to 98 parts by weight of a polycarbonate/polyorganosiloxane copolymer, 0 to 93 parts by weight of a polycarbonate resin, 2 to 50 parts by weight of titanium oxide, 0 to 1.0 parts by weight of a fibril-forming polytetrafluoroethylene, and 0.05 to 2.0 parts by weight of an organosiloxane, the sum of the ingredients (A), (B), and (C) is 100 parts by weight.

Abstract: A polycarbonate resin composition obtained by blending a polycarbonate resin (A) obtained by forming a carbonate bond from 95 to 5 mol % of a dihydroxy compound having a fluorene structure represented by the general formula (1) and 5 to 95 mol % of a dihydroxy compound having a dimethanol structure represented by the general formula (2) and a carbonic diester and a polycarbonate resin (B) obtained by forming a carbonate bond from bisphenol A and a carbonic acid diester or phosgene in a ratio of (100×(A)/((A)+(B))=1 to 99% by weight and a polarizing sheet used the same.