With Reactant Having Halo-c(=o)-halo, Halo-c(=o)-o-, Or -o-c(=o)-o- Group Patents (Class 528/196)
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Patent number: 12112781Abstract: There is provided an optical recording medium substrate including a polycarbonate in which an average molecular weight is in a range from 15000 to 16000, and mass per unit volume at 25° C. is in a range from 1.1930 g/cm3 to 1.2000 g/cm3.Type: GrantFiled: July 23, 2019Date of Patent: October 8, 2024Assignee: SONY CORPORATIONInventors: Hiroshi Nakayama, Hiroyuki Takemoto, Minoru Kikuchi, Minoru Matsuura
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Patent number: 12104014Abstract: Disclosed is a polycarbonate resin composition containing (a) an aromatic polycarbonate, (b) a polyester, and (c) a polymer having an epoxy group. The following requirements are satisfied. (1) A content of the (a) aromatic polycarbonate is 75% by mass or more based on a mass of the polycarbonate resin composition. (2) A mass ratio of a content of the (c) polymer having an epoxy group with respect to a content of the (b) polyester is 0.8 or more. (3) A content of a sum of the (b) polyester and the (c) polymer having an epoxy group is 25 parts by mass or less with respect to 100 parts by mass of the (a) aromatic polycarbonate.Type: GrantFiled: May 22, 2019Date of Patent: October 1, 2024Assignee: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Sho Kitagawa, Mitsuhiro Okada
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Patent number: 12091499Abstract: A polyester is provided. The polyester comprises: at least one repeating unit represented by formula (i), wherein R1 is a C6-C16 aromatic hydrocarbyl; and repeating units derived from diols, wherein the repeating units derived from diols comprise at least one repeating unit represented by the following formula (ii) and at least one repeating unit represented by the following formula (iii), and wherein R2 to R5 in formula (ii) are independently hydrogen, methyl, or ethyl, wherein based on the total moles of the repeating units derived from diols, the amount of the repeating unit represented by the formula (ii) is 5 mol % to 50 mol %.Type: GrantFiled: April 19, 2023Date of Patent: September 17, 2024Assignee: CHANG CHUN PLASTICS CO., LTD.Inventor: Ching-Jui Huang
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Patent number: 12077635Abstract: A method for the continuous multi-stage manufacture of an end-capped polycarbonate includes, i) preparing a monomer mixture in a monomer mixing stage by mixing a bisphenol, a diaryl carbonate and optionally a transesterification catalyst in at least one monomer mixing device, ii) preparing a carbonate oligomer in an oligomerisation stage by reacting the monomer mixture in at least one oligomerisation reactor, and iii) preparing the polycarbonate in a polymerisation stage by further reacting the carbonate oligomer of the oligomerisation stage in at least one polymerisation reactor, in which an end-capping agent different from phenol and having a single phenolic hydroxy group is added to the monomer mixture in the monomer mixing stage and/or to at least one oligomerisation reactor in the oligomerisation stage.Type: GrantFiled: September 12, 2019Date of Patent: September 3, 2024Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventor: Ignacio Vic Fernandez
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Patent number: 12024629Abstract: Provided is a polycarbonate-based resin having a ratio of an amine terminal to all terminal groups of 1.0 mol % or more.Type: GrantFiled: May 31, 2019Date of Patent: July 2, 2024Assignee: IDEMITSU KOSAN CO., LTD.Inventors: Koichi Suga, Yumi Nakayama, Aki Yamada
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Patent number: 12006398Abstract: A terminally modified polycarbonate resin that has ultraviolet absorbing capability is provided. More specifically, the terminally modified polycarbonate resin has a structure represented by general formula (A) and a constituent unit that is derived from a dihydric phenol. (In general formula (A), R1 represents a hydrogen atom or an alkyl group having 1-6 carbon atoms; R2 represents an alkylene group having 1-6 carbon atoms; R3 represents a hydrogen atom or a methyl group; R4 represents a hydrogen atom or a halogen atom; and * represents the bonding position to the main chain of the polycarbonate resin.Type: GrantFiled: March 30, 2020Date of Patent: June 11, 2024Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Shun Ishikawa, Noriyoshi Ogawa
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Patent number: 11993714Abstract: The invention relates to a copolymer containing rigid polyamide PA blocks and flexible blocks, characterized in that it includes at least one carboxylic acid chain end blocked with a polycarbodiimide, said copolymer according to the invention being in noncrosslinked linear form. The invention also relates to the use of a polycarbodiimide in a process for manufacturing a copolymer containing rigid polyamide PA blocks and flexible blocks, including at least one carboxylic acid chain end, for improving the extrudability of the copolymer, the drawability of the copolymer, the abrasion resistance, the tear strength and the durability of the copolymer, without increasing its dispersity.Type: GrantFiled: November 16, 2018Date of Patent: May 28, 2024Assignee: ARKEMA FRANCEInventors: Quentin P. Pineau, Philippe Denis H. Blondel, Jean-Jacques Flat
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Patent number: 11970608Abstract: Provided are copolycarbonate compositions including a stabilizer package which comprise a phosphorous-containing acid, an ester of phosphorous-containing acid, and an organosulfonic stabilizer where the phosphorous-containing acid and the ester of a phosphorous-containing acid are present in a molar ratio of 1 to 2. The total stabilization package is for example, in the amount by weight of 4 to 32 ppm, 8 to 24 ppm, or 8 to 16 ppm and the organosulfonic stabilizer is, e.g., of 2 to 30 ppm, or 4 to 24 ppm, or 8 to 16 ppm.Type: GrantFiled: July 31, 2019Date of Patent: April 30, 2024Assignee: SHPP GLOBAL TECHNOLOGIES B.V.Inventors: Wei Zhao, Roy Ray Odle, Paul Dean Sybert
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Patent number: 11945909Abstract: The invention relates to a method for producing a polycarbonate and the reaction of one or more diaryl carbonates with one or more aromatic compounds, wherein a catalyst combination is used in the process. The invention further relates to a catalyst combination and to the use thereof in a process for producing a polycarbonate.Type: GrantFiled: October 12, 2017Date of Patent: April 2, 2024Assignee: EPC Engineering & Technologies GMBHInventor: Michael Streng
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Patent number: 11926732Abstract: In various aspects, the disclosure relates to polycarbonate compositions exhibiting improved impact strength, both multi axial and notched Izod, as well as thin-walled flame resistance while free or substantially free of bromine or chlorine flame retardant additives. The polycarbonate compositions may comprise non-bonding glass fiber, butyl tosylate, and/or a phosphorous based stabilizer.Type: GrantFiled: November 18, 2022Date of Patent: March 12, 2024Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Snezana Grcev, Joshua Arie van den Bogerd
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Patent number: 11913617Abstract: An internal part for a lighting tool for a vehicle, including: an entering portion for light; an emitting portion for light; and a light-guiding portion to guide the light from the entering portion to the emitting portion, the part being arranged at a distance of 5 mm or less from a light source, wherein the part is a molded body formed of a resin composition, wherein a 5-millimeter thick plate, obtained by subjecting the resin composition to injection molding at a cylinder temperature of 260° C., a die temperature of 80° C., a cycle time of 50 seconds, and a retention time of 230 seconds, a total light transmittance of 80% or more, and a ratio (X/Y) of a spectral light transmittance (X) of the 5-millimeter thick plate at a wavelength of 350 nm to a spectral light transmittance (Y) thereof at a wavelength of 400 nm is 0.75 or more.Type: GrantFiled: April 6, 2021Date of Patent: February 27, 2024Assignee: IDEMITSU KOSAN CO., LTD.Inventors: Junichi Tsuzuki, Toshio Isozaki
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Patent number: 11884777Abstract: Provided is a diol compound of the following Chemical Formula 1, a polycarbonate comprising the diol compound, and a method of producing the polycarbonate:Type: GrantFiled: September 11, 2019Date of Patent: January 30, 2024Assignee: LG Chem, Ltd.Inventors: Young Young Hwang, Mooho Hong, Ki Jae Lee
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Patent number: 11873437Abstract: Disclosed are a method for preparing a fluorescent nanomaterial-polymer composite and a wavelength converting element, and a light emitting device. The method for preparing the fluorescent nanomaterial-polymer composite includes: at least one precursor provided, the precursor includes a fluorescent nanomaterial and a polymer; and in a first temperature at or higher than a melting point of the polymer, the precursor is mixed, and then cooled.Type: GrantFiled: January 24, 2019Date of Patent: January 16, 2024Assignee: SUZHOU XINGSHUO NANOTECH CO., LTD.Inventors: Yunjun Wang, Bo Ma
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Patent number: 11859047Abstract: Provided is a polycarbonate resin composition and a molded product comprising same. The polycarbonate resin composition comprises a linear polycarbonate resin, a branched polycarbonate resin, a fluorinated sulfonate-based metal salt, a phenyl methyl silicone oil, and a phenyl methyl silicone resin. The linear polycarbonate resin and branched polycarbonate resin include a repeating unit of the following Chemical Formula 1: wherein in Chemical Formula 1: R1 to R4 are each independently hydrogen, C1-10 alkyl, C1-10 alkoxy, or halogen; and Z is C1-10 alkylene unsubstituted or substituted with phenyl, C3-15 cycloalkylene unsubstituted or substituted with C1-10 alkyl, O, S, SO, SO2, or CO.Type: GrantFiled: November 6, 2019Date of Patent: January 2, 2024Assignee: LG Chem, Ltd.Inventors: Hyong Min Bahn, Un Ko, Jungmoon Bae, Daehyeon Hwang, Mooho Hong, Sugil Yum
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Patent number: 11857387Abstract: The invention discloses an improved dental dam (10) for use in dental restoration processes. The dam (10) includes a substantially planar membrane (12), having location portions (14) disposed on the membrane (12) and a guide formation (16) which runs along a major surface of the membrane (12). Additionally the dam (10) includes a clamp arrangement (20), which is engageable with and slidably movable along the guide formation (16). Both the membrane (12) and the clamp arrangement (20) are formed of a shape memory polymer.Type: GrantFiled: January 29, 2018Date of Patent: January 2, 2024Inventor: Wafa Abdalla Sabeal Mohamed Al Bloushi
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Patent number: 11834577Abstract: A composition includes specific amounts of a reinforcing filler and a copolycarbonate containing bisphenol A carbonate units and second carbonate units of the formula wherein Ra, Rb, R3, R4, j, p, and q are defined herein. The composition is useful for fabricating articles that exhibit a desirable balance of heat resistance, printability in large format additive manufacturing, and good surface appearance in printed parts. Also described is a method of additive manufacturing utilizing the composition.Type: GrantFiled: April 25, 2019Date of Patent: December 5, 2023Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Eddie Kebin Geng, Rabeh Elleithy, Timothy Allessio, Peter Vollenberg, Walter R. Thompson, David Voorde
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Patent number: 11746229Abstract: Provided is a resin composition containing: a thermoplastic resin having a polar group; and a heterocyclic compound containing two or more heteroatoms, wherein the resin composition exhibits a different behavior in elastic strength with a glass transition temperature as a boundary.Type: GrantFiled: November 22, 2019Date of Patent: September 5, 2023Assignee: Konica Minolta, Inc.Inventors: Minori Tamagawa, Sho Osawa, Tatsuya Hattori
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Patent number: 11732129Abstract: Provided is a polycarbonate resin composition, including: an aromatic polycarbonate resin (A); an alicyclic epoxy compound (B); a predetermined antioxidant (C); and a predetermined phosphorus compound (D), wherein, with respect to 100 parts by mass of the component (A), a content of the component (B) is 0.01 part by mass or more and 0.1 part by mass or less, a content of the component (C) is 0.01 part by mass or more and 0.1 part by mass or less, and a content of the component (D) is 0.01 part by mass or more and 0.05 part by mass or less.Type: GrantFiled: October 5, 2021Date of Patent: August 22, 2023Assignee: IDEMITSU KOSAN CO., LTD.Inventors: Toshio Isozaki, Takahiro Torii, Yasunobu Yamazaki, Naoto Okubo
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Patent number: 11702506Abstract: The present disclosure relates to a polycarbonate and a preparation method thereof, which has a novel structure with an improvement in weather resistance and refractive index, while having excellent mechanical properties.Type: GrantFiled: August 9, 2019Date of Patent: July 18, 2023Assignee: LG Chem, Ltd.Inventors: Ki Jae Lee, Young In Yang, Youngwook Son, Mooho Hong, Byoungkue Jeon, Young Young Hwang
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Patent number: 11697732Abstract: Provided is a polycarbonate resin composition, including: an aromatic polycarbonate resin (A); an alicyclic epoxy compound (B); a predetermined antioxidant (C); and a predetermined phosphorus compound (D), wherein, with respect to 100 parts by mass of the component (A), a content of the component (B) is 0.01 part by mass or more and 0.1 part by mass or less, a content of the component (C) is 0.01 part by mass or more and 0.1 part by mass or less, and a content of the component (D) is 0.01 part by mass or more and 0.05 part by mass or less.Type: GrantFiled: October 5, 2021Date of Patent: July 11, 2023Assignee: IDEMITSU KOSAN CO., LTD.Inventors: Toshio Isozaki, Takahiro Torii, Yasunobu Yamazaki, Naoto Okubo
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Patent number: 11666520Abstract: The present invention relates to compositions for and methods of retarding hair loss or facilitating hair growth comprising a hair growth active, a mixture of C12-C15 alkyl lactates and a viscosity modifying agent comprising at least one cellulose and/or a cellulose derivative. Clear compositions are also disclosed.Type: GrantFiled: December 21, 2016Date of Patent: June 6, 2023Assignee: Johnson & Johnson Consumer Inc.Inventor: Jeffrey M. Wu
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Patent number: 11634546Abstract: Ways of preparing a partially crystalline polycarbonate powder are provided that include dissolving an amorphous polycarbonate in a polar aprotic solvent to form a first solution of solubilized polycarbonate at a first temperature. The first solution is then cooled to a second temperature, the second temperature being lower than the first temperature, where a portion of the solubilized polycarbonate precipitates from the first solution to form a second solution including the partially crystalline polycarbonate powder. Certain partially crystalline polycarbonate powders resulting from such methods are particularly useful in additive manufacturing processes, including powder bed fusion processes.Type: GrantFiled: March 2, 2021Date of Patent: April 25, 2023Assignee: Jabil Inc.Inventors: Thomas Gardner, Travis Hislop, Victoria H. Pyle
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Patent number: 11623976Abstract: A process for the production of a thermoplastic elastomer containing hard segments (a) of a polyester and soft segments (b) containing repeating units derived from an aliphatic carbonate, in which process a precursor thermoplastic elastomer is subjected to solid state post condensation at a temperature between 140 and 170° C. Also claimed is the thermoplastic elastomer.Type: GrantFiled: November 12, 2020Date of Patent: April 11, 2023Assignee: DSM IP ASSETS B.V.Inventors: Ellen Van Hemelrijck, Wilhelmus Petrus Johannes Appel
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Patent number: 11591437Abstract: Provided is a polycarbonate polyol used as a raw material of a polyurethane that yields a polyurethane solution having good storage stability and exhibits excellent flexibility and solvent resistance. This polycarbonate polyol is a polycarbonate diol that includes structural units represented by the following Formulae (A) and (B), wherein, R1 and R2 each independently represent an alkyl group having 1 to 4 carbon atoms and, in this range of the number of carbon atoms, optionally have an oxygen atom, a sulfur atom, a nitrogen atom, a halogen atom, or a substituent containing these atoms; and R3 represents a linear aliphatic hydrocarbon having 3 or 4 carbon atoms. This polycarbonate diol has a molecular weight of 500 to 5,000, and the value of the following Formula (I) is 0.3 to 20.0: (Content ratio of branched-chain moiety in polymer)/(Content ratio of carbonate group in polymer)×100(%) (I).Type: GrantFiled: July 10, 2019Date of Patent: February 28, 2023Assignee: MITSUBISHI CHEMICAL CORPORATIONInventors: Yoshikazu Kanamori, Yuta Hioki
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Patent number: 11578168Abstract: The purpose of the present invention is to provide a high temperature/humidity resistant polycarbonate resin without using bisphenol A as a raw material. The present invention relates to a polycarbonate resin comprising the repeating units of formulas (1), (2) and (3), wherein the content of the repeating unit of formula (3) is 5 mol% to 50 mol%, and the refractive index is 1.570 to 1.600. {In formula (1), R1 and R2 each represent a hydrogen atom or a C1-10 hydrocarbon group.} {In formula (3), n ranges from 0 to 8, and the R symbols are each selected from C1-3 alkyl groups}.Type: GrantFiled: March 20, 2019Date of Patent: February 14, 2023Assignee: TEIJIN LIMITEDInventors: Tatsuya Oyama, Kazuyoshi Ogasawara, Atsushi Umeki, Keisuke Sato, Manabu Matsui
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Patent number: 11535705Abstract: A method for preparing a polycarbonate ester includes feeding a monomer mixture containing (i) at least one compound selected from the group consisting of compounds of the following Formulae 1 and 3; (ii) a compound of the following Formula 2; and (iii) a 1,4:3,6-dianhydrohexitol to a polycondensation reactor and allowing the monomers and the 1,4:3,6-dianhydrohexitol to react to prepare the polycarbontate ester.Type: GrantFiled: January 24, 2019Date of Patent: December 27, 2022Assignee: SK CHEMICALS CO., LTD.Inventors: Kwang Sei Oh, Jong-In Lee
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Patent number: 11535706Abstract: In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having two or more sites that can initiate polymerization. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups and a high percentage of carbonate linkages. The compositions are further characterized in that they contain polymer chains having an embedded polyfunctional moiety linked to a plurality of individual polycarbonate chains.Type: GrantFiled: November 12, 2020Date of Patent: December 27, 2022Assignee: Saudi Aramco Technologies CompanyInventors: Scott D. Allen, Geoffrey W. Coates, Anna E. Cherian, Chris A. Simoneau, Alexei A. Gridnev, Jay J. Farmer
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Patent number: 11485820Abstract: A polycarbonate polyester includes residues of following formula (1), formula (2) and formula (3): in which R1 is C2-C15 hydrocarbon group; R2 is C4-C16 hydrocarbon group; a molar ratio of the residue of the formula (2) to the residue of the formula (1) is in a range of greater than 0.05 to less than 0.8; * represents a linking bond.Type: GrantFiled: December 30, 2020Date of Patent: November 1, 2022Assignee: Chang Chun Plastics Co., Ltd.Inventors: Ching-Jui Huang, Ping-Chieh Wang
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Patent number: 11479640Abstract: A bio-based polycarbonate ester resin is environment friendly by not containing a bisphenol, and exhibits excellent heat resistance, transparency, strength, hardness, dimensional stability and chemical resistance. Thus, the bio-based polycarbonate ester resin is suitable for use in an eyeglass frame. In addition, various colors may be painted and coated on during post-processing, a separate additive is not required during a molding process, and processing is undergone at a temperature lower than that for conventional plastic materials for an eyeglass frame, and thus manufacturing costs may be reduced.Type: GrantFiled: July 2, 2019Date of Patent: October 25, 2022Assignee: SK CHEMICALS CO., LTD.Inventors: Kwang Sei Oh, Jong-In Lee
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Patent number: 11459424Abstract: A process for preparing polycarbonate by the phase interface process in the presence of at least one catalyst, wherein immediately after the optionally first addition of the at least one catalyst, from 0.01 to 20 J/kg of mixing energy is introduced into the system comprising the at least one catalyst within a time of from 2 to 1200 s. A mixture, an organic phase, and a process for distributing at least one catalyst in a system comprising an organic phase and an aqueous phase are also disclosed herein.Type: GrantFiled: December 12, 2018Date of Patent: October 4, 2022Assignee: COVESTRO DEUTSCHLAND AGInventors: Jan Heijl, Rolf Bachmann, Volker Michele, Felix Cock
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Patent number: 11440991Abstract: The present application provides a polycarbonate resin composition which has a high refractive index and a low Abbe number, and high thermal stability. The polycarbonate resin composition according to one embodiment of the present application includes a polycarbonate resin and an antioxidant, wherein the polycarbonate resin contains a constituent unit represented by general formula (1) (in general formula (1), X represents an alkylene group having 1-4 carbon atoms, and a and b each independently represent an integer of 1-10), and the antioxidant content is 1-3000 ppm.Type: GrantFiled: January 18, 2019Date of Patent: September 13, 2022Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Munenori Shiratake, Kentaro Ishihara, Koji Hirose, Shinya Ikeda, Noriyuki Kato, Mitsuteru Kondo, Shoko Suzuki, Kensuke Oshima, Shuya Nagayama
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Patent number: 11352493Abstract: A resin composition includes a polycarbonate-based resin and a polyethylene terephthalate resin, and the resin composition has a resin phase-separated structure including a continuous phase containing the polycarbonate-based resin and a dispersed phase containing the polyethylene terephthalate resin, in which a number average diameter in a longitudinal direction of the dispersed phase is 1.5 ?m or less, a number average diameter in a lateral direction of the dispersed phase is 0.8 ?m or less, and an aspect ratio of the number average diameter in the longitudinal direction to the number average diameter in the lateral direction is 2.5 or less.Type: GrantFiled: July 29, 2020Date of Patent: June 7, 2022Assignee: FUJIFILM Business Innovation Corp.Inventor: Akira Imada
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Patent number: 11345132Abstract: An optical sheet of the present invention includes a specific wavelength absorption layer that contains a polycarbonate as a main material and a light absorbing agent that absorbs light of a specific wavelength out of light in a wavelength range of 350 nm to 740 nm, in which the polycarbonate has a viscosity average molecular weight Mv of 20,000 to 30,000. In addition, the specific wavelength absorption layer further includes an ultraviolet absorbing agent that absorbs light in a wavelength range of 100 nm to 420 nm.Type: GrantFiled: September 27, 2018Date of Patent: May 31, 2022Assignee: SUMITOMO BAKELITE CO., LTD.Inventors: Takuya Oyama, Tetsuya Ishikawa
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Patent number: 11312822Abstract: A method of preparing a polycarbonate composition, including: melt polymerizing in a polymerization unit a dihydroxy compound with a diaryl carbonate and removing a stream of color inducing species containing an isopropenyl phenyl-containing group from the polymerization unit, to form a polycarbonate composition, wherein the polycarbonate has a color inducing species containing an isopropenyl phenyl-containing group level below 170 ppm is provided.Type: GrantFiled: January 16, 2018Date of Patent: April 26, 2022Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Aaron David Bojarski, Jorge A. Garcia Agudo
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Patent number: 11230625Abstract: Described herein are methods of preparing poly(alkylene carbonate) polymers comprising an increased ratio of primary hydroxyl end groups to secondary hydroxyl end groups, and compositions thereof.Type: GrantFiled: April 18, 2019Date of Patent: January 25, 2022Assignee: Saudi Aramco Technologies CompanyInventors: James Eagan, Christopher A. Simoneau, Jay J. Farmer
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Patent number: 11220600Abstract: Provided is a polycarbonate resin composition, including: an aromatic polycarbonate resin (A); an alicyclic epoxy compound (B); a predetermined antioxidant (C); and a predetermined phosphorus compound (D), wherein, with respect to 100 parts by mass of the component (A), a content of the component (B) is 0.01 part by mass or more and 0.1 part by mass or less, a content of the component (C) is 0.01 part by mass or more and 0.1 part by mass or less, and a content of the component (D) is 0.01 part by mass or more and 0.05 part by mass or less.Type: GrantFiled: March 30, 2018Date of Patent: January 11, 2022Assignee: IDEMITSU KOSAN CO., LTD.Inventors: Toshio Isozaki, Takahiro Torii, Yasunobu Yamazaki, Naoto Okubo
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Patent number: 11203664Abstract: Provided is a polycarbonate-based resin composition, including: 50 mass % or more to 99 mass % or less of a polycarbonate-based resin (S) containing 0.1 mass % or more to 100 mass % or less of a polycarbonate-polyorganosiloxane copolymer (A), which contains a polycarbonate block (A-1) formed of a specific repeating unit and a polyorganosiloxane block (A-2) containing a specific repeating unit, and 0 mass % or more to 99.9 mass % or less of an aromatic polycarbonate-based resin (B) except the polycarbonate-polyorganosiloxane copolymer (A); 1 mass % or more to 50 mass % or less of a polyester-based resin (C); and 0.001 part by mass or more to 1 part by mass or less of an amide compound (D) with respect to 100 parts by mass of a total amount of the polycarbonate-based resin (S) and the polyester-based resin (C).Type: GrantFiled: September 6, 2018Date of Patent: December 21, 2021Assignee: IDEMITSU KOSAN CO., LTD.Inventor: Yasuhiro Ishikawa
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Patent number: 11198759Abstract: The present invention provides a polycarbonate copolymer having low specific gravity and high surface hardness.Type: GrantFiled: June 20, 2018Date of Patent: December 14, 2021Assignee: TEIJIN LIMITEDInventors: Hideyuki Tsunemori, Kenta Imazato, Katsuhiro Yamanaka
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Patent number: 11180609Abstract: In one aspect, the present invention encompasses compositions of sustainable polycarbonate polymers, methods of producing such polymers, and methods for evaluating whether certain constituents of a polymer chain are derived from biomass or a fossil carbon source.Type: GrantFiled: August 1, 2019Date of Patent: November 23, 2021Assignee: Saudi Aramco Technologies CompanyInventor: Jay J. Farmer
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Patent number: 11149115Abstract: Disclosed is a method for preparing polylactone by ring opening, belonging to the technical fields of organic catalysis and polymer materials. The invention proposes a new catalytic mechanism, wherein an organic alcohol is used as an initiator to initiate ring opening polymerization of a cyclic monomer under the catalysis of an organic catalyst to obtain a polylactone; and the catalyst is a pyridinium salt. The present invention has the advantages of non-toxic reaction, simple conditions and controllable process; further, the invention can obtain a narrow molecular weight distribution in the absence of solution polymerization, and can effectively inhibit the occurrence of the transesterification compared with the catalysis of 4-(N,N-dimethylamino)pyridine.Type: GrantFiled: April 24, 2018Date of Patent: October 19, 2021Assignee: NANJING TECH UNIVERSITYInventors: Kai Guo, Hui Zhu, Zhenjiang Li, Fulan Wei, Siming Chen, Yu Gao
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Patent number: 11149116Abstract: The present invention relates to a process for producing a polycarbonate from a diphenol or two or more different diphenols and a carbonyl halide by the interfacial process. It is a feature of the process according to the invention that it is carried out on the basis of a chlorohydrocarbon or a mixture of a mixture of two or more chlorohydrocarbons using an organic solvent. An organic solvent is also provided.Type: GrantFiled: December 12, 2018Date of Patent: October 19, 2021Assignee: COVESTRO DEUTSCHLAND AGInventors: Jan Heijl, Erik Sluyts, Xiaoxin Yao
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Patent number: 11141913Abstract: A composition for use in powder bed fusion includes a thermoplastic powder that itself includes an induced crystalline polycarbonate or an induced crystalline polyetherimide. The thermoplastic powder is recycled powder, which means that it is recovered from a powder bed that had undergone a powder bed fusion process. Also described is a method of making an article, the method including: placing an induced crystalline polymeric (polycarbonate or polyetherimide) powder in a powder bed, fusing a portion of the induced crystalline polymeric powder in the powder bed, recovering a least a portion of the crystalline polymeric powder from the powder bed, wherein the recovered powder is not fused, placing the recovered induced crystalline polymeric powder in a second powder bed, and fusing at least a portion of the recovered induced crystalline polymeric powder in the second powder bed to form an amorphous polymer article.Type: GrantFiled: September 21, 2018Date of Patent: October 12, 2021Assignee: SHPP GLOBAL TECHNOLOGIES B.V.Inventors: Elena Miloskovska, Bruke Jofore
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Patent number: 11111386Abstract: Provided is a polycarbonate-polyorganosiloxane copolymer including polycarbonate blocks (A-1) each formed of a specific repeating unit and polyorganosiloxane blocks (A-2) each containing a specific repeating unit, wherein the polycarbonate-polyorganosiloxane copolymer satisfies the following expression (F1a): 15?wM1??(F1a) wherein wM1 represents the average content of the polyorganosiloxane blocks (A-2) in polycarbonate-polyorganosiloxane copolymers each having a molecular weight determined by using a polycarbonate as a conversion reference of from 56,000 or more to 200,000 or less among polycarbonate-polyorganosiloxane copolymers obtained through the separation of the polycarbonate-polyorganosiloxane copolymer by gel permeation chromatography.Type: GrantFiled: March 1, 2018Date of Patent: September 7, 2021Assignee: IDEMITSU KOSAN CO., LTD.Inventors: Yasuhiro Ishikawa, Tomoko Abe, Takafumi Akimoto
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Patent number: 11084915Abstract: Provided is a means capable of realizing a surface-roughening method for modifying the surface of a resin molded article to form a surficial layer, such as a coating or plating, or to impart a function derived from the surface configuration. The method comprises adding a resin composition and performing a post-treatment and is thus simpler and easier than conventional methods. The resin composition is a composition for resin surface roughening that contains an aliphatic polycarbonate and an alkali metal salt.Type: GrantFiled: December 26, 2016Date of Patent: August 10, 2021Assignees: Sumitomo Seika Chemicals Co., Ltd., Osaka Research Institute of Industrial Science and TechnologyInventors: Kiyoshi Nishioka, Hiroki Maeda, Kei Ishikura, Kimihiro Matsukawa, Yukiyasu Kashiwagi, Masashi Saitoh
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Patent number: 11072703Abstract: Provided is a polycarbonate-based resin composition, including: 50 mass % or more to 99 mass % or less of a polycarbonate-based resin (S) containing a polycarbonate-polyorganosiloxane copolymer (A) containing a polycarbonate block (A-1) formed of a specific repeating unit and a polyorganosiloxane block (A-2) containing a specific repeating unit, and an aromatic polycarbonate-based resin (B) except the polycarbonate-polyorganosiloxane copolymer (A); and 1 mass % or more to 50 mass % or less of a polyester-based resin (C), wherein the polyorganosiloxane block (A-2) has an average chain length of from 50 or more to 500 or less.Type: GrantFiled: March 1, 2018Date of Patent: July 27, 2021Assignee: IDEMITSU KOSAN CO., LTD.Inventors: Yasuhiro Ishikawa, Tomoko Abe, Yohei Koori
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Patent number: 11021571Abstract: Provided is a manufacturing method for a high molecular weight aromatic polycarbonate resin that has superior fluidity and for which a good color and a sufficiently high molecular weight can be achieved. A manufacturing method for a high molecular weight aromatic polycarbonate resin includes: a step in which a dialcohol compound expressed by general formula (1) and a catalyst are mixed to obtain a catalyst composition; a step in which the obtained catalyst composition is kept in a molten state, and is mixed with an aromatic polycarbonate prepolymer within ten hours after obtaining the catalyst composition, to obtain a prepolymer mixture; and a high molecular weight achievement step in which the obtained prepolymer mixture is heat-treated under reduced pressure conditions to obtain a high molecular weight aromatic polycarbonate resin.Type: GrantFiled: March 24, 2017Date of Patent: June 1, 2021Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Yoshinori Isahaya, Atsushi Hirashima, Hidefumi Harada, Maki Ito, Jun-ya Hayakawa, Takehiko Isobe, Yousuke Shinkai, Keisuke Shimokawa
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Patent number: 11001709Abstract: A polycarbonate copolymer contains aromatic carbonate units; optionally siloxane units; and resorcinol arylate ester units. The resorcinol arylate ester units of the polycarbonate copolymer are derived from a resorcinol composition having a hydroquinone content of 50 to 1200 parts per million, a catechol content of 5 to 29 parts per million, and a phenol content of 0 to 2400, each as determined by high performance liquid chromatography, and further comprising an acid stabilizer.Type: GrantFiled: May 5, 2017Date of Patent: May 11, 2021Assignee: SHPP GLOBAL TECHNOLOGIES B.V.Inventors: Christopher Luke Hein, Rahul Patil, Bing Zhou, Guangxin Lin, Chelsea Schmidt, David Zoller, Shuailei Ma, Chester Hassman
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Patent number: 10975194Abstract: Provided is a polycarbonate resin, including, as a raw material, a bisphenol A having 100 ppm by mass or less of isopropenylphenol and 250 ppm by mass or less of 2-(2-hydroxyphenyl)-2-(4-hydroxyphenyl)propane, each detected after heating in air at 175° C. for 1 hour.Type: GrantFiled: April 5, 2019Date of Patent: April 13, 2021Assignee: IDEMITSU KOSAN CO., LTD.Inventor: Nobuhiro Watanabe
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Patent number: 10962793Abstract: The present invention provides a method for producing a thermoplastic resin by reacting reactants comprising a dihydroxy compound. In this production method, the dihydroxy compound comprises a dihydroxy compound represented by the following formula (1), and at least one of a compound represented by the following formula (A), a compound represented by the following formula (B), and a compound represented by the following formula (C), wherein the total weight of the compound represented by the formula (A), the compound represented by the formula (B), and the compound represented by the formula (C) is 1,500 ppm or more, based on the weight (100 parts by weight) of the dihydroxy compound represented by the formula (1).Type: GrantFiled: April 12, 2019Date of Patent: March 30, 2021Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Noriyuki Kato, Mitsuteru Kondo, Munenori Shiratake, Kentaro Ishihara, Koji Hirose, Shinya Ikeda
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Patent number: 10955680Abstract: The present invention provides a method for producing a thermoplastic resin by reacting reactants comprising a dihydroxy compound. In this production method, the dihydroxy compound comprises a dihydroxy compound represented by the following formula (1), and at least one of a compound represented by the following formula (A), a compound represented by the following formula (B), and a compound represented by the following formula (C), wherein the total weight of the compound represented by the formula (A), the compound represented by the formula (B), and the compound represented by the formula (C) is 1,500 ppm or more, based on the weight (100 parts by weight) of the dihydroxy compound represented by the formula (1).Type: GrantFiled: November 2, 2016Date of Patent: March 23, 2021Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Noriyuki Kato, Mitsuteru Kondo, Munenori Shiratake, Kentaro Ishihara, Koji Hirose, Shinya Ikeda